23-11-2011 дата публикации
Номер: CN0102255083A
Принадлежит:
The invention relates to a layered manganese-based composite material Li(MnxNiyCo1-x-y)O2 for power-type lithium ion batteries and a preparation method thereof; the cathode material adopts a lithium source, a manganese source, a nickel source, a cobalt source as raw materials, adopts a sodium salt as a medium; the molar ratio of Na:Mn:Ni:Co is 1:(0.5<=x<1.0):(0<=y<=0.5):(1-x-y), and the amount of substance of the mixed lithium source is 4-10 times the mole number of the sodium salt. The preparation method comprises the following steps: 1) weighing the lithium source, the manganese source, the nickel source, the cobalt source, and the sodium salt according to the above molar ratio respectively; 2) pulverizing the manganese source, the nickel source, and the cobalt source, dissolving in water, dropwisely adding excessive NH4OH into the solution to form a M(OH)2 coprecipitate, wherein M=(Mn, Ni and Co), performing suction filtration, washing to be neutral, and drying in an oven; 3) adding ...
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