16-05-2019 дата публикации
Номер: US20190144395A1
2-substituted benzimidazoles and methods of preparing the same are disclosed. The compositions may include a compound or salt thereof, an acid, and a polar aprotic solvent. The compositions may be used to inhibit corrosion of a metal surface in contact with an aqueous system, and provide enhanced protection against corrosion of metals in the aqueous system. 2. The composition of claim 1 , further comprising water.3. The composition of claim 1 , whereinX is independently hydrogen or halogen;{'sup': '1', 'Ris hydrogen;'}{'sup': '2', 'Ris absent; and'}{'sup': 3', '4, 'Ris CHR.'}4. The composition of claim 1 , wherein at least one Z is nitrogen.5. The composition of claim 1 , wherein Ris a bond and at least one Z is nitrogen.7. The composition of claim 1 , wherein the acid is selected from sulfuric acid claim 1 , hydrochloric acid claim 1 , nitric acid claim 1 , methanesulfonic acid claim 1 , phosphoric acid claim 1 , sulfamic acid claim 1 , aminomethylphosphonic acid claim 1 , p-toluenesulfonic acid claim 1 , and any combination thereof.8. The composition of claim 1 , wherein the polar aprotic solvent is selected from acetonitrile claim 1 , N claim 1 ,N-dimethylformamide claim 1 , acetone claim 1 , dimethylsulfoxide claim 1 , sulfolane claim 1 , N-methylpyrrolidinone claim 1 , methylsulfonylmethane claim 1 , chlorobenzene claim 1 , o-dichlorobenzene claim 1 , nitromethane claim 1 , an ionic liquid claim 1 , and any combination thereof.9. The composition of claim 1 , wherein the composition is homogenous liquid.10. The composition of claim 1 , further comprising a high temperature stable phase transfer catalyst.11. The composition of claim 10 , wherein the high temperature stable phase transfer catalyst is selected from the group consisting of an alkyl guanidinium salt claim 10 , an aryl guanidinium salt claim 10 , an alkyl phosphonium salt claim 10 , an aryl phosphonium salt claim 10 , a peralkylated phosphazenium salt claim 10 , and any combination thereof.13. The ...
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