29-03-2012 дата публикации
Номер: US20120076928A1
Polycrystalline monolithic magnesium aluminate spinels are disclosed. The polycrystalline monolithic magnesium aluminate spinels have small grain sizes and may be deposited on substrates as thick one-piece deposits. The polycrystalline monolithic magnesium aluminate spinels may be prepared and deposited by chemical vapor deposition. Articles made with the polycrystalline monolithic magnesium aluminate spinels also are disclosed. 1. (canceled)2. A method comprising:a) providing gaseous precursors of polycrystalline monolithic magnesium aluminate;b) reacting the gaseous precursors; andc) depositing polycrystalline monolithic magnesium aluminate on a substrate at a deposition rate of 0.5 μm/minute to 5 μm/minute.34-. (canceled)5. A method comprising:a) providing a first layer of polycrystalline monolithic magnesium aluminate with a grain size of 70 μm or less and a thickness of at least 0.5 mm;b) depositing an electrically conductive and selectively passivated pattern on the first layer of the polycrystalline monolithic magnesium aluminate with a grain size of 70 μm or less and a thickness of at least 0.5 mm;c) depositing a second layer of polycrystalline monolithic magnesium aluminate with a grain size of 70 μm or less and a thickness of at least 0.5 mm on the electrically conductive and selectively passivated pattern opposite the first layer of polycrystalline monolithic magnesium aluminate to form an article.6. The method of claim 5 , wherein the electrically conductive and selectively passivated pattern comprises one or more metal layers7. The method of claim 6 , wherein the one or more metal or metal alloy layers is deposited on the pattern by CVD claim 6 , PVD claim 6 , CCVD claim 6 , CACCVD claim 6 , or electrolytic deposition. This application is a Divisional of U.S. Non-Provisional application Ser. No. 12/229,745 filed Aug. 26, 2008 which application claims the benefit of priority under 35 U.S.C. §119(e) to U.S. Provisional Application No. 60/966,313, filed ...
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