25-07-2023 дата публикации
Номер: CN116474825A
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The invention discloses a catalyst for catalytic synthesis of lactide, a preparation method and a method for catalytic synthesis of lactide, the catalyst is prepared by a sol-gel method to obtain a ZnO-SnO substrate, and SO4 < 2-> is introduced for modification; meanwhile, in the process of preparing the catalyst, the polymerization inhibitor shown in the formula I is loaded on the catalyst. The prepared catalyst is high in thermal stability, easy and convenient to regenerate and capable of replacing an organic zinc/tin catalyst. The catalyst is used for high-temperature depolymerization of a lactic acid prepolymer to obtain lactide, the product yield is high, the optical purity is high, no high-molecular-weight kettle residue polymer is generated, the influence of the high-molecular-weight kettle residue polymer on recycling is avoided, the reaction process can be effectively simplified, the production cost is reduced, and the method is suitable for industrial production.
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