Lead-acid battery formulations containing discrete carbon nanotubes

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.

BINDERS, ELECTROLYTES AND SEPARATOR FILMS FOR ENERGY STORAGE AND COLLECTION DEVICES USING DISCRETE CARBON NANOTUBES

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices.

LITHIUM ION BATTERIES USING DISCRETE CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene. 1. A composition useful for lithium ion batteries comprising:discrete carbon nanotubes, the discrete carbon nanotubes having crystals or layers of lithium ion active material attached to their surface.2. The composition of claim 1 , wherein the crystals or layers of lithium ion active material comprise a lithium metal salt and an element selected from the group consisting of: iron claim 1 , manganese claim 1 , cobalt claim 1 , copper claim 1 , nickel claim 1 , vanadium claim 1 , titanium claim 1 , and mixtures thereof.3. The composition of claim 2 , wherein the lithium metal salt has an olivine crystal structure.4. The composition of claim 1 , wherein the crystals or layers of lithium ion active material comprise tin claim 1 , silicon claim 1 , copper claim 1 , antimony claim 1 , aluminum claim 1 , germanium claim 1 , titanium claim 1 , or mixtures thereof.5. The composition of claim 1 , wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.6. The composition of claim 1 , further comprising graphene or oxygenated graphene.7. The composition of claim 6 , wherein the weight ratio of grapheme to carbon nanotube is in the range of 0.1:99.9 to 99.9:0.1.8. A process for the production of the discrete carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface claim 6 , comprising the steps of:a) selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level 1% to 15% percent by weight;b) mixing the carbon nanotubes with a high boiling point liquid;c) adding reagents in correct balance to synthesize a lithium salt;d) reacting the ...

POLYURETHANE POLYMERS AND COMPOSITIONS MADE USING DISCRETE CARBON NANOTUBE MOLECULAR REBAR

In various embodiments a urethane/molecular rebar formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/molecular rebar composition includes improved foams and adhesives. 1. A composition comprising at least one urethane based polymer or pre-polymer and at least a portion of discrete carbon nanotube molecular rebar to form or polymerize into a polyurethane/molecular rebar formulation.2. A composition comprising at least one urethane based polymer or pre-polymer and at least a portion of discrete carbon nanotube molecular rebar , wherein the urethane polymer or pre-polymer comprises at least one polyol and/or at least one cyanate , and wherein the discrete carbon nanotube molecular rebar is contacted with at least one of the polyol , the urethane polymer or pre-polymer.3. The composition of wherein the discrete carbon nanotube molecular rebar is contacted with the polyol.4. The composition of wherein the discrete carbon nanotubes are contacted with the polyol prior to claim 2 , during and/or after polymerization.5. The composition of wherein the discrete carbon nanotube molecular rebar is contacted with the cyanate prior to claim 2 , during and/or after polymerization.6. The composition of wherein the cyanate comprises aromatic or aliphatic groups.7. A foam comprising the formulation of claim 1 , wherein the foam at a given density has increased rigidity claim 1 , increased strength claim 1 , improved ability to form foams claim 1 , improved crush resistance claim 1 , and improved static electricity transmission claim 1 , compared to a formulation in the absence of discrete carbon nanotube molecular rebar.8. An adhesive comprising the formulation of claim 1 , wherein the adhesive has improved adhesion and cohesion and improved electrical properties versus a comparison adhesive made with an absence of discrete carbon nanotube molecular rebar.9 ...

Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

RHEOLOGICAL MOLECULAR REBAR

In various embodiments a carbon nanotube molecular rebar formulation comprising a specific composition is disclosed. The composition comprises discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (TCL) to number average tube end-end length) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved composites, engineered materials, foams, sealants, coatings and adhesives, energy devices such as photovoltaics, batteries and capacitors, sensors and separation membranes.

LITHIUM ION BATTERIES USING DISCRETE CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene. 17-. (canceled)8. A process for the production of discrete carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface , comprising the steps of:a) selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level 1% to 15% percent by weight;b) mixing the carbon nanotubes with a high boiling point liquid;c) adding reagents in correct balance to synthesize a lithium salt;d) reacting the mixture at a temperature to form the lithium salt while sonicating the mixture;e) separating the solid discrete carbon nanotube salts from the liquid; andf) drying and annealing the solid discrete carbon nanotube salts under an inert atmosphere at sufficient temperature to obtain an olivine crystal structure.9. A process for the production of discrete carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface , comprising the steps of:selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level of 1% to 15% by weight;b) mixing the carbon nanotubes and a lithium salt in a liquid with surfactant;c) sonicating the liquid carbon nanotube/lithium salt mixture;d) separating the solid salts from the liquid; ande) drying and annealing the solid discrete carbon nanotubes with attached lithium salts under an inert atmosphere at sufficient temperature to obtain an olivine crystal structure.1013-. (canceled)14. A composition useful for lithium ion batteries comprising:discrete carbon nanotubes having crystals or layers of lithium ion active material attached to their surface, wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of ...

Polymer blend and fabricated article made from diverse ethylene interpolymers

This invention is directed to an ethylene polymer blend comprising at least two diverse ethylene interpolymers wherein one interpolymer has a lower number of carbons than the at least one other interpolymer. The ethylene polymer blend preferably comprises at least one homogeneously branched ethylene/α-olefin interpolymer blended with at least one heterogeneously branched ethylene/α-olefin interpolymer and is characterized as having a density greater than or equal to 0.90 g/cm 3 and in particularly preferred embodiments is further characterized as having an intrinsic tear value greater than or equal to 150 grams. The inventive ethylene polymer blend can be used to make various fabricated articles, especially extruded forms and most especially films such as high strength thin gauge packaging film, impact resistant shrink film and heat sealable packaging film.

MODIFIED CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

The present invention relates to the exfoliation and dispersion of carbon nanotubes resulting in high aspect ratio, surface-modified carbon nanotubes that are readily dispersed in various media. A method is disclosed for their production in high yield. Further modifications by surface active or modifying agents are also disclosed. Application of the carbon nanotubes of this invention as composites with materials such as elastomers, thermosets and thermoplastics are also described. 1. A plurality of carbon nanotubes comprising carbon nanotube fibers having an aspect ratio of from about 25 to about 500 , and a oxidation level of from about 3 weight % to about 15 weight %.2. The fibers of wherein a neutralized water treatment of the fibers results in a pH of from about 3 to about 9 claim 1 , preferably from about 4 to about 8.3. The fibers of wherein the oxidation species comprises carboxylic acid or derivative carboxylate groups.4. The fibers of wherein the fibers are discrete individual fibers claim 1 , not entangled as a mass.5. A plurality of carbon nanotubes comprising discrete carbon nanotube fibers having an aspect ratio of from about 25 to about 250 and a oxidation level of from about 3 wt % to about 15 wt % claim 1 , wherein the fibers are mixed claim 1 , blended claim 1 , sonicated claim 1 , or a combination step thereof claim 1 , with at least one epoxy resin to form an epoxy/nanotube composite.6. A plurality of carbon nanotubes comprising discrete carbon nanotube fibers having an aspect ratio of from about 25 to about 250 and a oxidation level of from about 3 wt % to about 15 wt % claim 1 , wherein the fibers are mixed claim 1 , blended claim 1 , sonicated claim 1 , or a combination step thereof claim 1 , with at least one rubber compound to form a rubber/nanotube composite.7. The fibers of comprising a residual metal concentration of less than about 1000 ppm.8. The fibers of comprising a residual metal concentration of less than about 100 ppm.9. The fibers ...

Polymer blend and fabricated article made from diverse ethylene interpolymers

Polymer blends are disclosed that include from about 5 percent (by weight of the total composition) to about 95 percent (by weight of the total composition) of at least one first ethylene interpolymer having at least one first comonomer, and from about 95 percent (by weight of the total composition) to about 5 percent (by weight of the total composition) of at least one second ethylene interpolymer having at least one second comonomer. In the disclosed blends, the first comonomer is different from the second comonomer and the melt index (I₂) of the first ethylene interpolymer is less than or equal to the melt index (I₂) of the second ethylene interpolymer. The blend are also characterized as having a density of greater than or equal to 0.90 g/cc. Articles made from such blends are also disclosed.

LEAD-ACID BATTERY FORMULATIONS CONTAINING DISCRETE CARBON NANOTUBES

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes. 1. A composition for lead-acid battery construction comprising:a plurality of discrete carbon nanotube fibers, the nanotubes having an aspect ratio of about 10 to about 500, and an oxidation level from about 1 weight percent to about 15 weight percents;wherein the discrete carbon nanotubes are open ended.2. (canceled)3. The composition of claim 1 , further comprising at least one surfactant or dispersing aid claim 1 , wherein the surfactant or dispersing aid contains a sulfate moiety.4. The composition of claim 1 , further comprising water claim 1 , wherein the nanotube fibers are dispersed in the water to form an expander material or battery paste.5. The composition of claim 3 , wherein the surfactant or dispersing aid is a sulfonated polymer selected from the group consisting of: ligno-sulfonate claim 3 , sulfonated polystyrene claim 3 , and combinations thereof.6. A material for a battery paste for a lead-acid battery claim 3 , comprising:a plurality of discrete carbon nanotube fibers having an aspect ratio of about 10 to about 500, and an oxidation level from about 1 weight percent to about 15 weight percents;an organic material;an inorganic salt; anda non-fiber carbon moiety.7. The composition of claim 6 , wherein the inorganic salt is selected from the group consisting of: barium sulfate claim 6 , lead sulfate claim 6 , calcium sulfate claim 6 , and tin oxide.8. The composition of claim 6 , wherein the non-fiber carbon moiety is selected from the group consisting of: carbon black claim 6 , graphite claim 6 , and graphene.9. A process for producing a lead-acid battery material claim 6 , comprising the steps of:(a) selecting discrete carbon nanotube fibers having an aspect ratio from 10 to 500;(b) selecting discrete carbon nanotube fibers having an oxidation level from 1-15% by weight;(c ...

LITHIUM ION BATTERIES USING DISCRETE CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene. 17-. (canceled)8. A process for the production of the discrete carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface , comprising the steps of:a) selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level 1% to 15% percent by weight;b) mixing the carbon nanotubes with a high boiling point liquid;c) adding reagents in correct balance to synthesize a lithium salt;d) reacting the mixture at a temperature to form the lithium salt while sonicating the mixture;e) separating the solid discrete carbon nanotube salts from the liquid; andf) drying and annealing the solid discrete carbon nanotube salts under an inert atmosphere at sufficient temperature to obtain an olivine crystal structure.9. A process for the production of the discrete carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface , comprising the steps of:a) selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level of 1% to 15% by weight;b) mixing the carbon nanotubes and a lithium salt in a liquid with surfactant;c) sonicating the liquid carbon nanotube/lithium salt mixture;d) separating the solid salts from the liquid; ande) drying and annealing the solid discrete carbon nanotubes with attached lithium salts under an inert atmosphere at sufficient temperature to obtain an olivine crystal structure.1013-. (canceled)14. A composition useful for lithium ion batteries comprising:discrete carbon nanotubes having crystals or layers of lithium ion active material attached to their surface, wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by ...

NANOPLATE-NANOTUBE COMPOSITES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

Elastomer formulations comprising discrete carbon nanotube fibers

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment.

NANOPLATE-NANOTUBE COMPOSITES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions. 1. A composition comprising:inorganic plates with individual plate thickness less than 10 nanometers:wherein the inorganic plates are interspersed with discrete nanotubes, the nanotubes having a diameter ranging from about 1 nanometer to 150 nanometers, and the nanotubes having an aspect ratio ranging from about 10 to 500.2. The composition of claim 1 , wherein the inorganic plates are graphene nanoplates.3. The composition of claim 1 , wherein the inorganic plates and discrete tubes are present at a weight ratio of about 1:100 to 100:1.4. The composition of claim 1 , further comprising a polymer selected from the group consisting of: thermoplastics claim 1 , thermosets and elastomers.5. The composition of claim 1 , further comprising inorganic materials selected from the group consisting of: ceramics claim 1 , clays claim 1 , silicates claim 1 , metal complexes and salts.6. The composition of further comprising at least one electroactive material.7. The composition of further comprising at least one transition metal complex or active catalyst species.8. A method of preparing graphene carbon nanotube composites claim 1 , comprising the steps of:a) suspending non-discrete graphene and non-discrete carbon nanotube fibers in an acidic solution for a time period to form a suspension;b) agitating the suspension;c) sonically treating the suspension of graphene-carbon nanotubes to form graphene-discrete carbon nanotube fibers; andd) isolating the graphene-discrete carbon nanotube fibers from the acidic solution prior to further treatment using solid/liquid separations:wherein the solid/liquid separations comprise filtration.9. A method of preparing ...

Polymer blend and fabricated article made from diverse ethylene interpolymers

Polymer blends are described that include at least one first ethylene interpolymer and at least one second ethylene interpolymer wherein the difference in the number of carbon atoms in the comonomer of the first interpolymer and the comonomer of the second interpolymer is at least two, wherein the first interpolymer and/or the second interpolymer has molecular weight distribution of from about 1.8 to about 2.8; and wherein the polymer blend has a density greater than or equal to 0.90 g/cm 3 . Articles made from such blends are also disclosed.

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

EXFOLIATED CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

In various embodiments, exfoliated carbon nanotubes are described in the present disclosure. The carbon nanotubes maintain their exfoliated state, even when not dispersed in a medium such as a polymer or a liquid solution. Methods for making the exfoliated carbon nanotubes include suspending carbon nanotubes in a solution containing a nanocrystalline material, precipitating exfoliated carbon nanotubes from the solution and isolating the exfoliated carbon nanotubes. Nanocrystalline materials may include nanorods, hydroxyapatite and various hydroxyapatite derivatives. In some embodiments, methods for making exfoliated carbon nanotubes include preparing a solution of carbon nanotubes in an acid and filtering the solution through a filter to collect exfoliated carbon nanotubes on the filter. In some embodiments, a concentration of carbon nanotubes in the acid is below the percolation threshold. In other various embodiments, energy storage devices and polymer composites containing exfoliated ...

High performance energy storage and collection devices containing exfoliated microtubules and spatially controlled attached nanoscale particles and layers

The present disclosure relates to energy storage or collection devices and methods for making such devices having electrode materials containing exfoliated nanotubes with attached electro- or photoactive nanoscale particles or layers. The exfoliated nanotubes and attached nanoscale particles or layers may be easily fabricated by methods such as coating, solution or casting or melt extrusion to form electrodes. Electrolytes may also be used for dispersing nanotubes and also in a polymeric form to allow melt fabrication methods.

Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

LEAD-ACID BATTERY FORMULATIONS CONTAINING DISCRETE CARBON NANOTUBES

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.

Elastomer formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing.

Elastomer Formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing. 1. A mixture comprising discrete nanotubes , an elastomer and , as optional components , a dispersing agent and/or an antioxidant.2. The mixture according to claim 1 , wherein the elastomer is selected from the group consisting of natural rubbers claim 1 , polyisobutylene claim 1 , polybutadiene claim 1 , styrene-butadiene rubber claim 1 , ethylene propylene diene rubbers claim 1 , butyl rubber claim 1 , polyisoprene claim 1 , nitrile rubbers claim 1 , hydrogenated nitrile rubbers claim 1 , polyurethanes claim 1 , polyethers claim 1 , halogen containing elastomers claim 1 , fluoroelastomers and combinations thereof.3. The mixture according to claim 1 , further comprising a dispersing agent is selected from the group consisting of anionic claim 1 , non-ionic or cationic surfactants claim 1 , and mixtures thereof.4. The mixture according to further comprising an antioxidant selected from primary and secondary antioxidants claim 1 , and mixtures thereof.5. The mixture according to claim 1 , wherein the nanotubes have an aspect ratio of 10 or more.6. The mixture according to claim 1 , wherein the nanotubes are further functionalised.7. The mixture according to claim 6 , wherein the nanotubes comprise an oxidation level of 2.5 to 15 weight percent.8. A method of making a mixture containing discrete nanotubes and an elastomer comprising mixing the elastomer and the discrete nanotubes at a temperature of 20 to 200° C.9. The method according to claim 8 , wherein the mixing is performed in the presence of a solvent.10. The method according to claim 9 , comprising forming a master batch of ...

Elastomer Formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing. 1. A composition comprising a cured elastomer containing discrete nanotubes.2. A composition according to claim 1 , wherein the nanotubes have an aspect ratio of 10 or more.3. A composition according to claim 1 , wherein the nanotubes are further functionalised.4. A composition according to claim 1 , wherein the cured elastomer is cured by free radical or ionisation agents.5. A composition according to claim 4 , wherein the cured elastomer is vulcanized during fabrication and/or form fixing.6. An article made from a composition according to .7. An article according to claim 6 , which is selected from a tire claim 6 , a gum chafer claim 6 , a tire sidewall claim 6 , a tire tread or casing claim 6 , a hose claim 6 , a belt claim 6 , a seal claim 6 , an automotive anti-vibration part claim 6 , a windshield wiper blade claim 6 , and a tank track pad claim 6 , wheel claim 6 , bushings or backer plate components.8. An article according to claim 7 , which is a tire for off-road and passenger car applications claim 7 , which tire contains rubber and reinforcing fillers including carbon black and/or silica.9. A method for adjusting the wear resistance claim 1 , the strength and/or the stiffness of elastomeric articles comprising providing a composition according to .10. (canceled)11. A method for adjusting the wear resistance claim 1 , the strength and/or the stiffness of a tire or part thereof comprising providing a composition according to .12. The method according to claim 11 , wherein the tire has a concentration of discrete nanotubes in the range of 0.7 vol. % and 30 vol. % and a ...

BINDERS, ELECTROLYTES AND SEPARATOR FILMS FOR ENERGY STORAGE AND COLLECTION DEVICES USING DISCRETE CARBON NANOTUBES

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes, their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices. 1. A composition for use as a binder material , an electrolyte material or a separator film material of an energy storage or collection device , comprising:a plurality of discrete carbon nanotube fibers, said fibers having an aspect ratio of from about 10 to about 500, and wherein at least a portion of the discrete carbon nanotube fibers are open ended.2. The composition of claim 1 , wherein the portion of discrete carbon nanotubes that are open ended are ion conducting.3. The composition of claim 1 , further comprising at least one polymer.4. The composition of claim 1 , wherein the carbon nanotubes are further functionalized.5. The composition of claim 1 , further comprising at least one dispersion aid.6. The composition of claim 3 , wherein the polymer is selected from the group consisting of vinyl polymers claim 3 , poly(styrene-butadiene) claim 3 , partially or fully hydrogenated poly(styrene butadiene) containing copolymers claim 3 , functionalized poly(styrene butadiene) copolymers such as carboxylated poly(styrene butadiene) claim 3 , poly(styrene-isoprene) claim 3 , poly(methacrylic acid) claim 3 , poly(methylmethacrylate) claim 3 , poly(acrylic acid) claim 3 , poly(vinylalcohols) ...

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

Discrete carbon nanotubes with targeted oxidation levels and stable gel formulations thereof

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

NANOPLATE-NANOTUBE COMPOSITES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions. 1. A composition comprising:inorganic plates with individual plate thickness less than 10 nanometers;wherein the inorganic plates are interspersed with discrete nanotubes, the nanotubes having a diameter ranging from about 1 nanometer to 150 nanometers, and the nanotubes having an aspect ratio ranging from about 10 to 500.2. The composition of claim 1 , wherein the inorganic plates are graphene nanoplates.3. The composition of claim 1 , wherein the inorganic plates and discrete tubes are present at a weight ratio of about 1:100 to 100:1.4. The composition of claim 1 , further comprising a polymer selected from the group consisting of: thermoplastics claim 1 , thermosets and elastomers.5. The composition of claim 1 , further comprising inorganic materials selected from the group consisting of: ceramics claim 1 , clays claim 1 , silicates claim 1 , metal complexes and salts.6. The composition of further comprising at least one electroactive material.7. The composition of further comprising at least one transition metal complex or active catalyst species.8. A method of preparing graphene carbon nanotube composites claim 1 , comprising the steps of:a) suspending non-discrete graphene and non-discrete carbon nanotube fibers in an acidic solution for a time period to form a suspension;b) agitating the suspension;c) sonically treating the suspension of graphene-carbon nanotubes to form graphene-discrete carbon nanotube fibers; andd) isolating the graphene-discrete carbon nanotube fibers from the acidic solution prior to further treatment using solid/liquid separations;wherein the solid/liquid separations comprise filtration.9. A method of preparing ...

DISPERSIONS COMPRISING DISCRETE CARBON NANOTUBE FIBERS

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment. 1. A dispersion comprising a plurality of oxidized , discrete carbon nanotubes and at least one additive , wherein the oxidized , discrete carbon nanotubes have an aspect ratio of 25 to 500 , are multiwall , and are present in the range of up to about 30% by weight based on the total weight of the dispersion.2. The dispersion of wherein at least 70 percent by weight of the nanotubes are discrete.3. The dispersion of in the form of free flowing particles.4. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes comprise an oxidation species selected from carboxylic acid or a derivative carbonyl containing species wherein the derivative carbonyl species is selected from ketones claim 1 , quaternary amines claim 1 , amides claim 1 , esters claim 1 , acyl halogens claim 1 , and monovalent metal salts.5. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes comprise an oxidation species selected from hydroxyl or derived from hydroxyl containing species.6. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes are present in the range of 15% to about 25% by weight based on the total weight of the dispersion.7. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes are present in the range of 18% to about 22% by weight based on the total weight of the dispersion.8. The dispersion of claim 1 , wherein the additive is selected from the group consisting of dicarboxylic/tricarboxylic esters claim 1 , timellitates claim 1 , adipates claim 1 , ...

BINDERS, ELECTROLYTES AND SEPARATOR FILMS FOR ENERGY STORAGE AND COLLECTION DEVICES USING DISCRETE CARBON NANOTUBES

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices. 1. A composition for use as a binder material , an electrolyte material or a separator film material of an energy storage or collection device , comprising:a plurality of discrete carbon nanotube fibers, said fibers having an aspect ratio of from about 10 to about 500, and wherein at least a portion of the discrete carbon nanotube fibers are open ended.2. The composition of claim 1 , wherein the portion of discrete carbon nanotubes that are open ended are ion conducting.3. The composition of claim 1 , further comprising at least one polymer.4. The composition of claim 1 , wherein the carbon nanotubes are further functionalized.5. The composition of claim 1 , further comprising at least one dispersion aid.6. The composition of claim 3 , wherein the polymer is selected from the group consisting of vinyl polymers claim 3 , poly(styrene-butadiene) claim 3 , partially or fully hydrogenated poly(styrene butadiene) containing copolymers claim 3 , functionalized poly(styrene butadiene) copolymers such as carboxylated poly(styrene butadiene) claim 3 , poly(styrene-isoprene) claim 3 , poly(methacrylic acid) claim 3 , poly(methylmethacrylate) claim 3 , poly(acrylic acid) claim 3 , poly(vinylalcohols) ...

Water Treatment Process

A process for removing oil and other organics, especially naphthalenic acid, is disclosed. The process involves use of electrical fields using electrodes in the device, inducing gas bubbles which force contaminants to the surface of the solutions to be skimmed off and recovered.

CARBON NANOTUBE NANO-THERAPY COMPOSITES WITH PACLITAXEL

In various embodiments a payload molecule or drug molecule delivery system is disclosed for delivering paclitaxel. The system comprises a plurality of functionalized discrete carbon nanotubes having specific properties. The composition can comprise a plurality of discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (T) to number average tube end-end length (T)) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved payload molecule delivery, such as drug delivery, into body of an animal, such as human. 1. A composition comprising: a plurality of functionalized discrete multi-wall carbon nanotubes having an innermost wall and an outermost wall , the innermost wall defining an interior cavity , and at least one type of payload molecule; wherein the functionalized discrete carbon nanotubes are open on at least one end; and wherein greater than 30 weight percent of the at least one type of payload molecule is within the interior cavity of the discrete multi-wall carbon nanotubes , and wherein the payload molecule comprises paclitaxel.2. The composition of claim 1 , wherein the functionalizing groups are selected from the group consisting of bio-compatible surfactants.3. The composition of claim 2 , wherein the bio-compatible surfactants are selected from the group consisting of polylactic acids claim 2 , polyvinyl alcohols claim 2 , polyethylene oxides claim 2 , polyglycolic acid claim 2 , polyvinylpyrrolidone claim 2 , polyacrylic acids claim 2 , carboxy methyl cellulose claim 2 , peptides claim 2 , polysaccharides claim ...

Elastomer formulations comprising discrete carbon nanotube fibers

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment.

Printing ink dispersions comprising discrete carbon nanotubes

This present invention relates to oxidized, discrete carbon nanotubes in dispersions, especially for use in printing inks. The dispersions can include materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a dispersion of oxidized, discrete carbon nanotubes that are electrically conductive.

SHIELDING FORMULATIONS USING DISCRETE CARBON NANOTUBES WITH TARGETED OXIDATION LEVELS AND FORMULATIONS THEREOF

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in electromagnetic and radio frequency shielding applications, especially where the shielding is essentially constant over a relatively wide range of frequencies. Additives such as plasticizers, can be used in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties. 1. An electromagnetic shielding composition comprising a plurality of discrete carbon nanotubes and at least one magnetic metal and/or alloy thereof , wherein the discrete carbon nanotubes comprise an interior and exterior surface , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content , wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20% , and as high as 100%.2. The electromagnetic shielding composition of claim 1 , wherein the interior surface oxidized species content comprises from about 0.01 to less than about 0.8 percent relative to carbon nanotube weight and the exterior surface oxidized species content comprises more than about 1.2 to about 3 percent relative to carbon nanotube weight.3. The electromagnetic shielding composition of claim 1 , wherein the magnetic metal and/or alloy thereof is selected from the group consisting of iron claim 1 , chromium claim 1 , aluminum claim 1 , uranium claim 1 , platinum claim 1 , copper claim 1 , cobalt claim 1 , lithium claim 1 , nickel claim 1 , neodymium claim 1 , and samarium.4. The electromagnetic shielding ...

EPOXY RESIN COMPOSITES

The present invention relates to epoxy/nanotube composites. The composites have at least one epoxy resin. The composites also have a plurality of discrete oxidized carbon nanotubes. The nanotubes have an aspect ratio of from about 25 to about 250. The epoxy/nanotube composite may be bonded or adhered to a substrate. 1. An epoxy/nanotube composite comprising a plurality of discrete oxidized carbon nanotubes having an aspect ratio of from about 25 to about 250 , and at least one epoxy resin.2. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes have an oxidation level of from about 3 wt % to about 15 wt %.3. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes have an average diameter of 6-12 nm and a length from about 400 nm to about 1 claim 1 ,200 nm.4. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes comprise a derivative carbonyl species selected from the group consisting of a ketone claim 1 , quaternary amine claim 1 , amide claim 1 , ester claim 1 , acyl halogen claim 1 , and metal salts.5. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes comprise an oxidation species select from the group consisting of carboxylic acid and derivative carboxylate groups.6. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes comprise a residual metal concentration of less than about 1000 ppm.7. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes comprise a residual metal concentration of less than about 100 ppm.8. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes are open ended.9. The epoxy/nanotube composite of wherein the plurality of discrete oxidized carbon nanotubes are at least partially surface modified or coated with at least one surfactant or at least one modifier.10. The epoxy/nanotube ...

Waste Water Treatment Process

A waste water treatment system utilizing a series of individual modules which, when assembled, form a beginning contaminate collection chamber attached at the starting end of a main fluid treatment tank, in which is housed an array of anodes and cathodes. A center contaminate collection chamber can be attached at the oppose end of the main treatment tank which provides an internal fluid pathway to allow fluid transfer from the first treatment tank into a second treatment tank. Alternatively, the center contaminate collection chamber can be used when multiples of treatment tanks are assembled to work in tandem, or an ending contaminate collection chamber can be attached to an ending treatment module to complete the expandable waste water treatment system. 1. An expandable waste water treatment system comprising a series of at least one or more treatment modules , preferably not more than two treatment modules , and at least one up to a plurality of contaminant collection modules;at least one contaminant collection module comprises a contaminant collection chamber; at least one treatment module comprises a treatment tank having an inlet and an outlet,and at least one treatment tank houses an anode and cathode array comprising a material selected from the group consisting of a mixed metal oxide, ion donating materials such as titanium, and a combination thereof;the plurality of contaminant collection modules includes a first contaminant collection module, a last contaminant collection module, and/or one or more intermediate contaminant collection modules;the series can begin with a first contaminant collection module, ends with the last contaminant collection module, and, optionally includes an intermediate contaminant collection module between treatment modules in the series;optionally the series can begin with a treatment module followed by a contaminant collection module optionally followed by a treatment module;the intermediate contaminant collection module ...

DISPERSIONS COMPRISING HIGH SURFACE AREA NANOTUBES AND DISCRETE CARBON NANOTUBES

The present application pertains to dispersions comprising oxidized, discrete carbon nanotubes and high-surface area carbon nanotubes. The oxidized, discrete carbon nanotubes comprise an interior and exterior surface, each surface comprising an interior surface oxidized species content and an exterior surface oxidized species content. The interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20%, and as high as 100%. The high-surface area nanotubes are generally single-wall nanotubes. The BET surface area of the high-surface area nanotubes is from about 550 m/g to about 1500 m/g according to ASTM D6556-16. The aspect ratio is at least about 500 up to about 6000. The dispersions comprise from about 0.1 to about 30% by weight nanotubes based on the total weight of the dispersion. 1. A dispersion comprising:oxidized, discrete carbon nanotubes wherein the discrete carbon nanotubes comprise an interior and exterior surface, each surface comprising an interior surface oxidized species content and an exterior surface oxidized species content, wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20%, and as high as 100%; and{'sup': 2', '2, 'high-surface area carbon nanotubes, wherein the high-surface area nanotubes are single-wall nanotubes, wherein the BET surface area of the high-surface area nanotubes is from about 550 m/g to about 1500 m/g according to ASTM D6556-16 and wherein the aspect ratio is at least about 500 up to about 6000;'}wherein the sum of the weight of the oxidized, discrete carbon nanotubes and the high surface area carbon nanotubes is in the range of from about 0.1 to about 30% by weight based on the total weight of the dispersion.2. The dispersion of claim 1 , wherein the interior surface oxidized species content of the oxidized claim 1 , discrete carbon nanotubes is less than the exterior surface oxidized species content.3 ...

Stem Cell, Bone, Tissue and Nerve Scaffolding from Discrete Carbon Nanotubes

Stem cell, bone and nerve scaffolding comprising discrete carbon nanotubes is disclosed. The discrete carbon nanotubes may be have targeted, or selective oxidation levels and/or content on the interior and exterior of the tube walls. The described scaffolding may be used to guide, target and protect stem cells upon injection into the body.

Discrete Carbon Nanotubes with Targeted Oxidation Levels and Formulations Thereof

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties. 1. A composition comprising a plurality of discrete carbon nanotubes , wherein the discrete carbon nanotubes comprise an interior and exterior surface , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content , wherein the interior surface oxidized species content comprises from about 0.01 to less than about 1 percent relative to carbon nanotube weight and the exterior surface oxidized species content comprises more than about 1 to about 3 percent relative to carbon nanotube weight.2. The composition of wherein the discrete carbon nanotubes comprises a plurality of open ended tubes.3. A composition comprising a plurality of discrete carbon nanotubes claim 1 , wherein the discrete carbon nanotubes comprise an interior and exterior surface claim 1 , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content claim 1 , wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20% claim 1 , and as high as 100%.4. The composition of wherein the plurality of discrete carbon nanotubes comprises a plurality of open ended tubes.5. The composition of wherein the interior surface oxidized species content is less than the exterior surface ...

LITHIUM ION BATTERIES USING DISCRETE CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF AND PRODUCTS OBTAINED THEREFROM

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene. 1. A process for the production of solid discrete carbon nanotubes used in lithium ion batteries , comprising the steps of:a) selecting discrete carbon nanotubes of aspect ratio 10 to 500 and oxidation level 1% to 15% percent by weight to give selected carbon nanotubes;b) mixing the selected carbon nanotubes with a liquid to give a carbon nanotubes/liquid mixture;c) adding reagents to the carbon nanotubes/liquid mixture in correct balance for synthesis of a lithium salt in a new mixture;d) reacting the new mixture at a temperature to form the lithium salt while sonicating the new mixture;e) separating solid discrete carbon nanotubes, having the lithium salt attached thereon from the liquid; andf) drying the solid discrete carbon nanotubes having the lithium salt attached thereon under an inert atmosphere at sufficient temperature to obtain the solid discrete carbon nanotubes used in lithium ion batteries.2. (canceled)3. A process for the production of solid discrete carbon nanotubes used in lithium ion batteries , comprising the steps of:a) selecting carbon nanotubes of aspect ratio 10 to 500 and oxidation level of 1% to 15% by weight to give selected carbon nanotubes;b) mixing the selected carbon nanotubes and a lithium salt in a liquid with a surfactant to give a liquid carbon nanotube/lithium salt mixture;c) sonicating the liquid carbon nanotube/lithium salt mixture;d) separating solid discrete carbon nanotubes, having the lithium salt attached thereon from the liquid; ande) drying the solid discrete carbon nanotubes having lithium salts attached thereon under an inert atmosphere at sufficient temperature to obtain the solid discrete carbon nanotubes used in ...

TRANSDERMAL PATCHES WITH DISCRETE CARBON NANOTUBES

A transdermal patch comprising discrete open-ended carbon nanotubes is disclosed. 1. A transdermal patch comprising a plurality of discrete carbon nanotubes wherein a plurality of the discrete carbon nanotubes are open-ended at least at one end.2. The transdermal patch of claim 1 , wherein the plurality of discrete carbon nanotubes are dispersed within a medium fabricated into a fiber or film.3. The transdermal patch of claim 1 , wherein the plurality of discrete open-ended carbon nanotubes further comprise an amount of functional groups of at least about 1 percent by weight of the dry open-ended discrete carbon nanotubes.4. The transdermal patch of claim 1 , wherein the plurality of discrete open-ended carbon nanotubes are substantially cleaned of catalytic residues.5. The transdermal patch of claim 1 , wherein the plurality of discrete open-ended carbon nanotubes have a length less than about 4 micrometers claim 1 , preferably less than about 3 micrometers and more preferably less than about 2 micrometers.6. The transdermal patch of claim 1 , wherein the plurality of discrete open-ended carbon nanotubes have a length distribution modality claim 1 , preferably bimodal.7. The transdermal patch of claim 1 , wherein the plurality of discrete open-ended carbon nanotubes have a diameter distribution modality claim 1 , preferably bimodal.8. The transdermal patch of wherein the plurality of discrete open-ended carbon nanotubes have an aspect ratio of from about 10 to about 500 claim 1 , preferably about 25 to about 200 and most preferably about 50 to about 120.9. The transdermal patch of further comprising a medicament.10. The transdermal patch of claim 1 , wherein the discrete carbon nanotubes are further associated with a polymer.11. The transdermal patch of claim 10 , wherein the polymer is selected from a group of polymers that do not exhibit substantial cytotoxity.12. The transdermal patch of wherein the polymer is selected from a group of polymers that are ...

RHEOLOGICAL MOLECULAR REBAR

In various embodiments a carbon nanotube molecular rebar formulation comprising a specific composition is disclosed. The composition comprises discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (TCL) to number average tube end-end length) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved composites, engineered materials, foams, sealants, coatings and adhesives, energy devices such as photovoltaics, batteries and capacitors, sensors and separation membranes. 1. A composition comprising discrete carbon nanotubes wherein at least a portion of discrete nanotubes has a ratio of number average value of ((tube contour length (T)):(tube end to end length (T))) of from about 1.1 to about 3.2. A composition comprising discrete carbon nanotubes wherein at least a portion of discrete nanotubes has a number average tube contour length (T) of at least 10% greater than , and up to about 300% of , a number average tube end to end length (T) , wherein the number average Tand Tare obtained from the same batch of discrete carbon nanotubes.3. In a composition comprising discrete carbon nanotubes having an average actual aspect ratio , the improvement comprising at least about 5% (volume) of the discrete carbon nanotubes having an apparent aspect ratio from about 50% to about 99% of the average actual aspect ratio of the discrete carbon nanotubes.4. The composition of claim 3 , wherein at least about 10% (volume) of the discrete carbon nanotubes have an apparent aspect ratio from about 50% to about 99% of the actual aspect ratio of ...

LEAD-ACID BATTERY FORMULATIONS CONTAINING DISCRETE CARBON NANOTUBES

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes. 1. A composition for lead-acid battery construction comprising:a plurality of discrete carbon nanotubes, not entangled as a mass, the nanotubes having an aspect ratio of about 10 to about 500;wherein the discrete carbon nanotubes are open ended; andwherein the discrete carbon nanotubes have an oxidation level of from about 1 weight percent to about 15 weight percent.2. The composition of claim 1 , further comprising at least one surfactant or dispersing aid.3. The composition of claim 1 , further comprising at least one surfactant or dispersing aid claim 1 , wherein the surfactant or dispersing aid contains a sulfate moiety.4. The composition of claim 1 , further comprising a sulfonated polymer selected from the group consisting of: ligno-sulfonate claim 1 , sulfonated polystyrene claim 1 , and combinations thereof.5. The composition of claim 1 , further comprising conducting polymers selected from the group consisting of: polyaniline claim 1 , polyphenylene vinylene claim 1 , polyvinylpyrollidone claim 1 , polyacetylene polythiophene claim 1 , polyphenylene sulfide claim 1 , and blends claim 1 , copolymers claim 1 , and derivatives thereof.6. The composition of claim 1 , further comprising water and wherein the nanotubes are dispersed in the water to form an expander material or battery paste.7. The composition of claim 1 , further comprising a non-fiber carbon moiety.8. The composition of claim 1 , further comprising an organic material; an inorganic salt; and a non-fiber carbon moiety.9. The composition of wherein when said composition is employed as a battery paste the battery paste exhibits (1) at least 10% improved adhesion to carbon/lead electrodes claim 8 , lead electrodes claim 8 , or carbon electrodes claim 8 , than pastes without carbon nanotubes; or (2) a 10% or greater increase ...

Discrete carbon nanotubes with targeted oxidation levels and stable gel formulations thereof

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

Dispersions for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

PRINTING INK DISPERSIONS COMPRISING DISCRETE CARBON NANOTUBES

This present invention relates to oxidized, discrete carbon nanotubes in dispersions, especially for use in printing inks. The dispersions can include materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a dispersion of oxidized, discrete carbon nanotubes that are electrically conductive. 1. A dispersion suitable for coatings or printing inks wherein the dispersion comprises a plurality of oxidized , discrete carbon nanotubes and at least one polymeric dispersing agent , wherein the oxidized , discrete carbon nanotubes have an aspect ratio of 25 to 500 , are multiwall , and are present in the range of greater than zero and up to about 30% by weight based on the total weight of the dispersion.2. The dispersion of wherein at least 70 percent by weight of the nanotubes in the dispersion are discrete based on the total weight of nanotubes in the dispersion.3. The dispersion of wherein at least a portion of the oxidized claim 1 , discrete carbon nanotubes comprise an oxidation species selected from carboxylic acid or a derivative carbonyl containing species wherein the derivative carbonyl species is selected from ketones claim 1 , quaternary amines claim 1 , amides claim 1 , esters claim 1 , acyl halogens claim 1 , and metal salts.4. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes comprise an oxidation species selected from hydroxyl or derived from hydroxyl containing species.5. The dispersion of wherein the dispersion further comprises a bonded or unbonded a component selected from the group consisting of proteins claim 1 , antibodies claim 1 , deoxyribonucleic acids claim 1 , ribonucleic acids claim 1 , metal salts claim 1 , metal oxides claim 1 , or combinations thereof.6. The dispersion of wherein the polymeric dispersing agent comprises one or more components selected from the group consisting of ...

PAYLOAD MOLECULE DELIVERY USING MOLECULAR REBAR

In various embodiments a payload molecule or drug molecule delivery system is disclosed. The system comprises a plurality of functionalized discrete carbon nanotubes having specific properties. The composition can comprise a plurality of discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (T) to number average tube end-end length (T)) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved payload molecule delivery, such as drug delivery, into body of an animal, such as human. 1. A composition comprising:a plurality of functionalized discrete multi-wall carbon nanotubes having an innermost wall and an outermost wall, the innermost wall defining an interior cavity, and at least one type of payload molecule;wherein the functionalized discrete carbon nanotubes are open on at least one end; andwherein greater than 30 weight percent of the at least one type of payload molecule is within the interior cavity of the discrete multi-wall carbon nanotubes.2. The composition of claim 1 , wherein the functionalizing groups are selected from the group consisting of bio-compatible surfactants.3. The composition of claim 2 , wherein the bio-compatible surfactants are selected from the group consisting of polylactic acids claim 2 , polyvinyl alcohols claim 2 , polyethylene oxides claim 2 , polyglycol acid claim 2 , polyvinylpyrrolidone claim 2 , polyacrylic acids claim 2 , carboxy methyl cellulose claim 2 , peptides claim 2 , polysaccharides claim 2 , proteins and combinations thereof.4. The composition of claim 1 , wherein the multi- ...

Polyurethane polymers and compositions made using discrete carbon nanotube molecular rebar

In various embodiments a urethane/molecular rebar formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/molecular rebar composition includes improved foams and adhesives.

Binders, Electrolytes and Separator Films for Energy Storage and Collection Devices Using Discrete Carbon Nanotubes

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices. 1. A composition for use as a binder material , an electrolyte material or a separator film material of an energy storage or collection device , comprising:a plurality of discrete carbon nanotube fibers, said fibers having an aspect ratio of from about 10 to about 500, and wherein at least a portion of the discrete carbon nanotube fibers are open ended.2. The composition of claim 1 , wherein the portion of discrete carbon nanotubes that are open ended are ion conducting.3. The composition of claim 1 , further comprising at least one polymer.4. The composition of claim 1 , wherein the carbon nanotubes are further functionalized.5. The composition of claim 1 , further comprising at least one dispersion aid.6. The composition of claim 3 , wherein the polymer is selected from the group consisting of vinyl polymers claim 3 , poly(styrene-butadiene) claim 3 , partially or fully hydrogenated poly(styrene butadiene) containing copolymers claim 3 , functionalized poly(styrene butadiene) copolymers such as carboxylated poly(styrene butadiene) claim 3 , poly(styrene-isoprene) claim 3 , poly(methacrylic acid) claim 3 , poly(methylmethacrylate) claim 3 , poly(acrylic acid) claim 3 , poly(vinylalcohols) ...

Treatment Composition for Contaminated Soil or Ground Water

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in treatment compositions for contaminated soil and ground water. Additives such as plasticizers, can be used in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

DISCRETE CARBON NANOTUBES WITH TARGETED OXIDATION LEVELS AND FORMULATIONS THEREOF

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties. 1. A composition comprising a plurality of discrete carbon nanotubes , wherein the discrete carbon nanotubes comprise an interior and exterior surface , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content , wherein the interior surface oxidized species content comprises from about 0.01 to less than about 1 percent relative to carbon nanotube weight and the exterior surface oxidized species content comprises more than about 1 to about 3 percent relative to carbon nanotube weight.2. The composition of wherein the discrete carbon nanotubes comprises a plurality of open ended tubes.3. A composition comprising a plurality of discrete carbon nanotubes claim 1 , wherein the discrete carbon nanotubes comprise an interior and exterior surface claim 1 , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content claim 1 , wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20% claim 1 , and as high as 100%.4. The composition of wherein the plurality of discrete carbon nanotubes comprises a plurality of open ended tubes.5. The composition of wherein the interior surface oxidized species content is less than the exterior surface ...

EPOXY RESIN DISPERSIONS COMPRISING DISCRETE CARBON NANOTUBES

This present invention relates to oxidized, discrete carbon nanotubes in dispersions, especially for use in epoxy compositions. The dispersions can include materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a dispersion of oxidized, discrete carbon nanotubes with epoxy that are resistant to weather and/or crack propagation. 1. A dispersion comprising at least one epoxy resin and a plurality of oxidized , discrete carbon nanotubes , wherein the discrete carbon nanotubes comprise an interior and exterior surface , each surface comprising an interior surface oxidized species content and an exterior surface oxidized species content , wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20% , and as high as 100% and are present in the range of from about 0.1 to about 30% by weight based on the total weight of the dispersion.2. The dispersion of wherein the interior surface oxidized species content is less than the exterior surface oxidized species content.3. The dispersion of wherein the interior surface oxidized species content is up to 3 weight percent relative to carbon nanotube weight claim 1 , preferably from about 0.01 to about 3 weight percent relative to carbon nanotube weight claim 1 , more preferably from about 0.01 to about 2 claim 1 , most preferably from about 0.01 to about 1.4. The dispersion of wherein the discrete carbon nanotubes have an aspect ratio that is bimodal.5. The dispersion of claim 1 , further comprising at least one epoxy resin diluent.6. The dispersion of claim 5 , wherein the epoxy resin diluent is selected from the group consisting of a diglycidyl ether of cis-1 claim 5 ,3-cyclohexanedimethanol claim 5 , a diglycidyl ether of trans-1 claim 5 ,3-cyclohexanedimethanol claim 5 , a diglycidyl ether of cis-1 claim 5 ,4- ...

DISPERSIONS COMPRISING DISCRETE CARBON NANOTUBE FIBERS

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment. 1. A dispersion comprising: a plurality of oxidized , discrete carbon nanotubes fibers , wherein the discrete carbon nanotubes fibers are open on at least one end , have an aspect ratio of from about 25 to about 500 , and are multiwall , and wherein said fibers are present up to about 30% by weight based on the total weight of the dispersion wherein the dispersion further comprises water and an additive.2. The dispersion of wherein the additive comprises at least one surfactant or dispersing aid.3. The dispersion of wherein at least 70 percent by weight of the nanotube fibers are fully exfoliated.4. The dispersion of wherein at least 80 percent by weight of the nanotube fibers are fully exfoliated.5. The dispersion of wherein the plurality of oxidized claim 1 , discrete carbon nanotubes fibers comprise an oxidation level from about 0.5 weight percent to about 3 weight percent based on the total weight of discrete carbon nanotubes.6. The dispersion of wherein the oxidized claim 1 , discrete carbon nanotubes comprise an oxidation species selected from carboxylic acid or derivative carbonyl containing species.7. The dispersion of wherein the additive is selected from the group consisting of a drug molecule claim 1 , a radiotracer molecule claim 1 , a radiotherapy molecule claim 1 , a diagnostic imaging molecule claim 1 , a fluorescent tracer molecule claim 1 , a protein molecule claim 1 , and combinations thereof.8. The dispersion of wherein at least a portion of the additive molecules fit within the interior of the ...

STEM CELL, BONE, TISSUE AND NERVE SCAFFOLDING FROM DISCRETE CARBON NANOTUBES

Stem cell, bone and nerve scaffolding comprising discrete carbon nanotubes is disclosed. The discrete carbon nanotubes may be have targeted, or selective oxidation levels and/or content on the interior and exterior of the tube walls. The described scaffolding may be used to guide, target and protect stem cells upon injection into the body. 1. A scaffold for transplanting a stem cell , which comprises discrete carbon nanotubes; wherein the scaffold does not exhibit cytotoxicity.2. The scaffold of claim 1 , wherein the discrete carbon nanotubes comprise an amount of functional groups of at least about 1 percent by weight of the dry discrete carbon nanotubes.3. The scaffold of wherein a plurality of the discrete carbon nanotubes are open ended.4. The scaffold of wherein a plurality of the discrete carbon nanotubes are substantially cleaned of catalytic residues.5. The scaffold of further comprising a polymer.6. The scaffold of claim 1 , wherein the discrete carbon nanotubes comprise functional groups that increase the affinity of biological moieties to the discrete carbon nanotube surface.7. A composition for stem cell therapy claim 1 , which comprises: (a) at least one stem cell; and (b) discrete carbon nanotubes serving as a stem cell scaffold without cytotoxicity.8. The composition according to claim 7 , wherein the at least one stem cell comprises an embryonic stem cell claim 7 , an adult stem cell claim 7 , or a combination thereof.9. The composition according to claim 7 , wherein the at least one stem cell comprises a neuronal stem cell and the composition is one for treating neuronal diseases.10. The composition according to claim 9 , wherein the neuronal disease is selected from the group consisting of neurodegenerative disorders.11. The composition according to claim 7 , wherein the discrete carbon nanotubes are in the form of a suspension.12. The composition according to claim 7 , wherein the composition can be deposited in a body tissue such that the ...

DOSE RESPONSE, SURFACE MODIFIED NANOTUBES

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels or content and a functionalized surface coating are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful for delivery and controlled release of drugs, chemicals, compounds, small molecules, oligonucleotides, peptides, proteins, enzymes, macromolecular gene-editing assemblies, other biologics and combinations of thereof. The functionalized surface coating may be utilized to preferentially direct the nanotubes to particular tissues, organs or regions of the body for controlled delivery and or release of a payload molecule. 1. A composition comprising a plurality of discrete carbon nanotubes , wherein the discrete carbon nanotubes comprise an interior and exterior surface , the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content , wherein the interior surface oxidized species content comprises from about 0.01 to less than about 1 percent relative to carbon nanotube weight and the exterior surface oxidized species content comprises more than about 1 to about 10 percent relative to carbon nanotube weight , wherein a biocompatible surface coating is attached to at least a portion of the exterior surface of the discrete carbon nanotubes.2. The composition of claim 1 , wherein the biocompatible surface coating is derived from a precursor selected from PEG (polyethylene glycol) claim 1 , PLA (polylactic acid) claim 1 , PVOH (polyvinyl alcohol) claim 1 , PEO (polyethylene oxide) claim 1 , PGLA (polyglycolic acid) claim 1 , CMC (carboxymethyl cellulose) claim 1 , PVP (polyvinylpyrrolidone) claim 1 , PAA (polyacrylic acid) claim 1 , aminoacids claim 1 , peptides claim 1 , polysaccharides claim 1 , nucleic acids and proteins ...

Polymer blend and fabricated article made from diverse ethylene interpolymers

This invention is directed to an ethylene polymer blend comprising at least two diverse ethylene interpolymers wherein one interpolymer has a lower number of carbons than the at least one other interpolymer. The ethylene polymer blend preferably comprises at least one homogeneously branched ethylene/α-olefin interpolymer blended with at least one heterogeneously branched ethylene/α-olefin interpolymer and is characterized as having a density greater than or equal to 0.90 g/cm3 and in particularly preferred embodiments is further characterized as having an intrinsic tear value greater than or equal to 150 grams. The inventive ethylene polymer blend can be used to make various fabricated articles, especially extruded forms and most especially films such as high strength thin gauge packaging film, impact resistant shrink film and heat sealable packaging film.

Improved polyethylene resin compositions having low mi and high melt strength

Polymer blend and fabricated article made from diverse ethylene interpolymers

Exfoliated carbon nanotubes, methods for production thereof and products obtained therefrom

In various embodiments, exfoliated carbon nanotubes are described in the present disclosure. The carbon nanotubes maintain their exfoliated state, even when not dispersed in a medium such as a polymer or a liquid solution. Methods for making the exfoliated carbon nanotubes include suspending carbon nanotubes in a solution containing a nanocrystalline material, precipitating exfoliated carbon nanotubes from the solution and isolating the exfoliated carbon nanotubes. Nanocrystalline materials may include nanorods, hydroxyapatite and various hydroxyapatite derivatives. In some embodiments, methods for making exfoliated carbon nanotubes include preparing a solution of carbon nanotubes in an acid and filtering the solution through a filter to collect exfoliated carbon nanotubes on the filter. In some embodiments, a concentration of carbon nanotubes in the acid is below the percolation threshold. In other various embodiments, energy storage devices and polymer composites containing exfoliated carbon nanotubes are described herein. The energy storage device may be a battery containing at least two electrodes and an electrolyte in contact with the at least two electrodes. At least one of the electrodes in the energy storage device advantageously contains exfoliated carbon nanotubes. The polymer composites are prepared by mixing exfoliated carbon nanotubes with a polymer material. After being mixed in the polymer material, the carbon nanotubes maintain their exfoliated state.

Preparation of cyanoacetamide and 2,2 -dibromo-3-nitrilopropionamide compositions

ABSTRACT OF THE DISCLOSURE DBNPA (i.e. 2,2-dibromo-3-nitrilopropionamide is formed in situ by treating cyanoacetamide which may be formed in situ by reaction of an alkyl .alpha.-cyanoacetate with ammonia) in glycol with an appropriate mixture of bromine and an alkali metal bromate at about 10°C-40°C and stable antimicrobial compositions may then be prepared by incorporating in the resultant 2,2-dibromo-3-nitrilopro-pionamide-containing reaction mass an appropriate quantity of paraformaldehyde or equivalent satisfactory stabilizer at a suitably adjusted pH level. 28,311-F

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

Binders, electrolytes and separator films for energy storage and collection devices using discrete carbon nanotubes

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices.

Improved elastomer formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing.

High performance energy storage and collection devices containing exfoliated microtubules and spatially controlled attached nanoscale particles and layers

The present disclosure relates to energy storage or collection devices and methods for making such devices having electrode materials containing exfoliated nanotubes with attached electro- or photoactive nanoscale particles or layers. The exfoliated nanotubes and attached nanoscale particles or layers may be easily fabricated by methods such as coating, solution or casting or melt extrusion to form electrodes. Electrolytes may also be used for dispersing nanotubes and also in a polymeric form to allow melt fabrication methods.

Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

Binders, electrolytes and separator films for energy storage and collection devices using discrete carbon nanotubes

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices.

Binders, electrolytes and separator films for energy storage and collection devices using discrete carbon nanotubes

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices.

Lead-acid battery formulations containing discrete carbon nanotubes

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

binders, electrolytes and separation films for solar energy storage and collection devices using discrete carbon nanotubes

LIGANTES, ELETRÓLITOS E PELÍCULAS DE SEPARAÇÃO PARA DISPOSITIVOS DE ARMAZENAMENTO E COLETA DE ENERGIA SOLAR USANDO NANOTUBOS DE CARBONO DISCRETOS. A presente invenção refere-se, em várias formas de realização, a uma composição de ligante melhorada, composição de eletrólitos e uma composição de película de separação usando nanotubos de carbono discretos. São descritos seus métodos de produção e utilidade para armazenamento de energia e dispositivos de coleta, como baterias, capacitores e fotovoltaicos. A composição de ligante, de eletrólitos ou de separação pode ainda compreender polímeros. Os nanotubos de carbono discretos compreendem ainda pelo menos uma parte dos tubos sendo de extremidades abertas e / ou funcionalizada. A utilidade da composição de ligante, de eletrólitos ou de película de separação inclui melhor capacidade, poder ou durabilidade no armazenamento de energia e dispositivos de coleta. A utilidade das composições de eletrólitos e ou de película de separação inclui melhor transporte de íons no armazenamento de energia e dispositivos de coleta. BINDERS, ELECTROLYTES AND FILM OF SEPARATION FOR SOLAR ENERGY COLLECTION AND STORAGE DEVICES USING DISCRETE CARBON NANOTUBES. The present invention refers, in various embodiments, to an improved binder composition, electrolyte composition and a separation film composition using discrete carbon nanotubes. Its methods of production and utility for energy storage and energy devices. such as batteries, capacitors and photovoltaics. the composition of binder, electrolyte or separation may also comprise polymers. Discrete carbon nanotubes also comprise the at least a part of the tubes being open ended and/or functionalized. The utility of binder, electrolyte or of separation film includes better capacity, power or durability in energy storage and collection devices. The usefulness of electrolyte and/or separating film compositions include better ion transport in energy storage and collection devices.

Improved elastomer formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing.

Lead-acid battery formulations containing discrete carbon nanotubes

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.

Dispersions comprising high surface area nanotubes and discrete carbon nanotubes

The present application pertains to dispersions comprising oxidized, discrete carbon nanotubes and high-surface area carbon nanotubes. The oxidized, discrete carbon nanotubes comprise an interior and exterior surface, each surface comprising an interior surface oxidized species content and an exterior surface oxidized species content. The interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20%, and as high as 100%. The high-surface area nanotubes are generally single-wall nanotubes. The BET surface area of the high-surface area nanotubes is from about 550 m2/g to about 1500 m2/g according to ASTM D6556-16. The aspect ratio is at least about 500 up to about 6000. The dispersions comprise from about 0.1 to about 30% by weight nanotubes based on the total weight of the dispersion.

Dispersions and manufacturing technologies for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Improved elastomer formulations

This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing.

Dispersible discrete carbon nanotubes in dry fabrication processes for energy storage and collection devices

Provided are compositions of bundles or clumps of a reaggregated plurality of discrete carbon nanotubes with an additive whereupon the bundles or clumps disaggregate during a fabrication process that uses less than 10,000 ppm of aqueous or non-aqueous solvent. The composition can be mixed further with electroactive material to make electrodes for energy storage or collection devices.

Compositions with carbon nanotubes for low hysteresis elastomers

The present application is directed to novel discrete carbon nanotubes with a surface modification that disperses well in elastomers and crosslinks elastomers to the surface of the discrete carbon nanotubes, or in the vicinity of the discrete carbon nanotube surface. Significant improvements in the performance of elastomeric formulations with a plurality of discrete carbon nanotubes with a surface modification and silica and/or carbon black result, for example, improved abrasion resistance while at the same time providing a reduced hysteresis effect on cyclic deformation. These improved properties are highly desired for fuel efficient and longer wear life tire formulations.

Dispersions and manufacturing technologies for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Dispersions for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Discrete carbon nanotubes with targeted oxidation levels and formulations thereof

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

Compositions with carbon nanotubes for low hysteresis elastomers

The present application is directed to novel discrete carbon nanotubes with a surface modification that disperses well in elastomers and crosslinks elastomers to the surface of the discrete carbon nanotubes, or in the vicinity of the discrete carbon nanotube surface. Significant improvements in the performance of elastomeric formulations with a plurality of discrete carbon nanotubes with a surface modification and silica and/or carbon black result, for example, improved abrasion resistance while at the same time providing a reduced hysteresis effect on cyclic deformation. These improved properties are highly desired for fuel efficient and longer wear life tire formulations.

Dispersions for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Dispersions and manufacturing technologies for additive manufacturing comprising discrete carbon nanotubes

Baterías de iones de litio que usan nanotubos de carbono discretos, métodos para su producción y productos obtenidos a partir de ellas

Composiciones y métodos para obtenerlas, útiles para baterías de iones de litio que comprenden nanotubos de carbono oxidados discretos que tienen adheridos a su superficie materiales activos de iones de litio en forma de cristales o capas de tamaño nanométrico. La composición puede comprender además grafeno o grafeno oxigenado. (Traducción automática con Google Translate, sin valor legal)

Dispersions and manufacturing technologies for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Polyurethane polymers and compositions made using discrete carbon nanotube molecular rebar

In various embodiments a urethane/molecular rebar formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/molecular rebar composition includes improved foams and adhesives. A further embodiment is a cement comprising molecular rebar, wherein the cement has improved crack resistance.

Dispersions and manufacturing technologies for additive manufacturing comprising discrete carbon nanotubes

The present invention is directed to additive manufacturing compositions and methods for producing additive manufacturing composite blends with oxidized discrete carbon nanotubes with dispersion agents bonded to at least one sidewall of the oxidized discrete carbon nanotubes. Such compositions are especially useful when radiation cured, sintered or melt fused.

Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

目標酸化レベルを有する離散カーボンナノチューブを用いた遮蔽調合物及びその調合方法

【課題】チューブ壁の内部及び外部における目標とする又は選択的な酸化レベル及び／又は含量を有する離散個片化カーボンナノチューブが求められる。【解決手段】本発明のカーボンナノチューブは、内部チューブ面の酸化をほとんど又は全く有さず、チューブの内部表面と外部表面とで異なる量及び／又は種類の酸化を有する。これらの新規の離散カーボンナノチューブは、特に遮蔽が比較的広範囲の周波数で実質的に一定である電磁及び無線周波数遮蔽用途において有用である。可塑剤などの添加物が、機械的、電気的及び熱的特性の向上のための弾性、熱可塑性及び熱硬化性複合体の合成及び調合において使用可能である。【選択図】図１

Payload molecule delivery using functionalized discrete carbon nanotubes

In various embodiments a payload molecule or drug molecule delivery system is disclosed. The system comprises a plurality of functionalized discrete carbon nanotubes having specific properties. The composition can comprise a plurality of discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (TCL) to number average tube end-end length (TEE)) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved payload molecule delivery, such as drug delivery, into body of an animal, such as human.

Payload molecule delivery using functionalized discrete carbon nanotubes

In various embodiments a payload molecule or drug molecule delivery system is disclosed. The system comprises a plurality of functionalized discrete carbon nanotubes having specific properties. The composition can comprise a plurality of discrete carbon nanotubes that have at least a portion of the carbon nanotubes with a number average (ratio of number average contour length to end to end length) of greater than 1.1 and up to about 3. These discrete carbon nanotubes having the specified ratio of number average (tube contour length (TCL) to number average tube end-end length (TEE)) ratio are not only discrete (separated) from one another, but are also controlled in their alignment such that processability and mechanical strength properties are both enhanced. Utility of the molecular rebar composition includes, but is not limited to improved payload molecule delivery, such as drug delivery, into body of an animal, such as human.

Dispersible discrete carbon nanotubes in dry fabrication processes for energy storage and collection devices

Provided are compositions of bundles or clumps of a reaggregated plurality of discrete carbon nanotubes with an additive whereupon the bundles or clumps disaggregate during a fabrication process that uses less than 10,000 ppm of aqueous or non-aqueous solvent. The composition can be mixed further with electroactive material to make electrodes for energy storage or collection devices.

Discrete carbon nanotubes with targeted oxidation levels and formulations thereof

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in plasticizers, which can then be used as an additive in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

Dispersiones y tecnologías de fabricación para fabricación aditiva que comprenden nanotubos de carbono discretos.

La presente invención se refiere a composiciones y métodos de fabricación aditiva para producir mezclas compuestas de fabricación aditiva con nanotubos de carbono discretos oxidados con agentes de dispersión unidos a al menos una pared lateral de los nanotubos de carbono discretos oxidados. Estas composiciones son especialmente útiles cuando se curan por radiación, se sinterizan o se funden.

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.

Binders, electrolytes and separator films for energy storage and collection devices using discrete carbon nanotubes

In various embodiments an improved binder composition, electrolyte composition and a separator film composition using discrete carbon nanotubes. Their methods of production and utility for energy storage and collection devices, like batteries, capacitors and photovoltaics, is described. The binder, electrolyte, or separator composition can further comprise polymers. The discrete carbon nanotubes further comprise at least a portion of the tubes being open ended and/or functionalized. The utility of the binder, electrolyte or separator film composition includes improved capacity, power or durability in energy storage and collection devices. The utility of the electrolyte and or separator film compositions includes improved ion transport in energy storage and collection devices.

Lead-acid battery formulations containing discrete carbon nanotubes

Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.

Polyurethane polymers and compositions made using discrete carbon nanotubes

In various embodiments a urethane/MOLECULAR REBAR formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/MOLECULAR REBAR composition includes improved foams and adhesives.

Dispersions comprising discrete carbon nanotube fibers

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment.

Dispersions comprising discrete carbon nanotube fibers

This present invention relates to the carbon nanotubes as composites with materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing equipment.

Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom

Compositions and methods of producing discrete nanotubes and nanoplates and a method for their production. The discrete nanotube/nanoplate compositions are useful in fabricated articles to provide superior mechanical and electrical performance. They are also useful as catalysts and catalyst supports for chemical reactions.