24-10-2019 дата публикации
Номер: US20190321803A1
Принадлежит:
Disclosed herein are methods of controlling the amount of carboxyl groups attached to a hydrochar, the methods including subjecting a composition that includes a stover composition to hydrothermal carbonization to form a hydrochar, wherein the amount of carboxyl groups attached to the hydrochar can be controlled by the amount of lipids in the composition. Methods of removing ammonia from a gas using disclosed hydrochars and the hydrochars themselves are also disclosed. 1. A method of removing ammonia from a gas , the method comprising:subjecting a composition comprising a stover composition to hydrothermal carbonization to form a hydrochar, the composition comprising an amount of lipids to provide a carboxyl group content in the hydrochar of not less than 0.3 millimoles (mmol) carboxyl groups per gram of hydrochar; andcontacting the gas with the hydrochar, whereby the ammonia is adsorbed onto the hydrochar.2. The method according to claim 1 , wherein the stover composition comprises plant material from: corn claim 1 , sorghum claim 1 , soybean claim 1 , rice claim 1 , wheat claim 1 , or any combination thereof.3. The method according to claim 1 , wherein the composition comprises corn stover claim 1 , condensed distillers solubles (CDS) claim 1 , spent brewers grains claim 1 , or any combination thereof.4. The method according to claim 1 , wherein the composition comprises one or more stover compositions and one or more added lipids.5. The method according to claim 4 , wherein the one or more added lipids comprise corn oil.6. The method according to claim 1 , wherein the carboxyl group content is not less than 0.4 millimoles (mmol) carboxyl groups per gram of composition.7. The method according to claim 1 , wherein the carboxyl group content can be determined using a Boehm titration.8. The method according to further comprising adding lipids to a stover composition to form the composition subjected to hydrothermal carbonization.9. The method according to further ...
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