Kohlenmonoxid/Wasserentfernung aus einem Einsatzgas für eine Brennstoffzelle

PROCEDURE FOR THE EXAMINATION OF THE VALVE ENTERPRISE IN CHANGE IN PRESSURE ADSORPTION SYSTEMS

CHANGE IN PRESSURE ADSORPTION PROCESS WITH SEVERAL ADSORPTION BEDS

EXECUTION AND OPTIMIZATION OF A CHANGE IN PRESSURE ADSORPTION PROCESS

SEPARATION PROCESS AND APPARATUS FOR LIGHT NOBLE GAS

Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit having minimal dead end volumes. A second separation unit receives a stream enriched in helium, neon, or argon, and a stream is recycled from the second separation unit back to the adsorption separation unit in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit within a targeted range.

SEPARATION PROCESS AND APPARATUS FOR LIGHT NOBLE GAS

Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit having minimal dead end volumes. A second separation unit receives a stream enriched in helium, neon, or argon, and a stream is recycled from the second separation unit back to the adsorption separation unit in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit within a targeted range.

Herstellung von Wasserstoff mittels Druckwechseladsorption durch Verwendung von einem Mehrschichtigen Adsorptionsbett

Ozone production by pressure swing adsorption using a protective adsorbed component

Rückgewinnung von Olefinen

Verfahren zur Überprüfung des Ventilbetriebs in Druckwechseladsorptionssystemen

Herstellung von Wasserstoff mittels Druckwechseladsorption durch Verwendung von einem mehrschichtigen Adsorptionsbett

Rückgewinnung von Olefinen

Herstellung von Wasserstoff mittels Druckwechseladsorption durch Verwendung von einem mehrschichtigen Adsorptionsbett

Valve operation diagnostic method for pressure swing absorption systems

Kohlenmonoxid/Wasserentfernung aus einem Einsatzgas für eine Brennstoffzelle

Adsorption cycle for ozone production

The invention relates to an adsorption cycle for ozone production. A gas mixture is separated by an adsorption cycle using at least three adsorber vessels (C1, C2, C3) in which the sweep stage recovering adsorbed product from one adsorber vessel overlaps with that of another of the adsorber vessels and/or effluent from one adsorber vessel in a feed rinse stage is routed to another adsorber vessel that is in an air sweep stage. Also provided is a PSA ozone separation cycle in which the product ozone concentration is maintained within a range of 10 mg/l.

Activated carbon as sole adsorbent in rapid cycle hydrogen PSA

A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and the apparatus are substantially free of zeolite adsorbents; feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.

Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration

The invention relates to a adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration. The process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality off adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressureequalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration

The invention relates to a adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration. The process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality off adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

Radial adsorber, adsorption system, and adsorption methods

A radial adsorber can be configured to facilitate utilization of different layers of material. The radial adsorber, system using at least one radial adsorber, and methods of utilizing embodiments of the radial adsorber can help permit improved efficient operation of fluid purification processing while also being configured to minimize, if not fully avoid, being susceptible to the effect of fluidization.

Sour Pressure Swing Adsorption Process

Methods and apparatuses for separating CO 2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

Mixed Bead Layering Arrangement For Thermal Swing Adsorption Application

An adsorbent vessel for removing contaminants from a feed gas upstream from a cryogenic distillation process using pressure swing adsorption, temperature swing adsorption, or thermal-pressure swing adsorption. The adsorbent vessel having an adsorbent bed comprised of multiple layers of adsorbent material, including two layers of adsorbent material that selective adsorbs carbon dioxide. Each of the two layers is formed from an adsorbent material having a different capacity for adsorbing carbon dioxide.

Separation Process and Apparatus for Light Noble Gas

Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit having minimal dead end volumes. A second separation unit receives a stream enriched in helium, neon, or argon, and a stream is recycled from the second separation unit back to the adsorption separation unit in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit within a targeted range.

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas

A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60° F. to about 105° F. into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.

Recovery of olefin monomers

In a process for the production of a polyolefin, an olefin monomer is polymerised said polyolefin and residual monomer is recovered. A gas stream comprising the monomer and nitrogen is subjected to a PSA process in which said monomer is adsorbed on a periodically regenerated silica gel or alumina adsorbent to recover a purified gas stream containing said olefin and a nitrogen rich stream containing no less than 99% nitrogen and containing no less than 50% of the nitrogen content of the gas feed to the PSA process.

Recovery of olefin monomers

In a process for the production of a polyolefin, an olefin monomer is polymerised said polyolefin and residual monomer is recovered. A gas stream comprising the monomer and nitrogen is subjected to a PSA process in which said monomer is adsorbed on a periodically regenerated silica gel or alumina adsorbent to recover a purified gas stream containing said olefin and a nitrogen rich stream containing no less than 99% nitrogen and containing no less than 50% of the nitrogen content of the gas feed to the PSA process.

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas

A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60°F to about 105°F into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.

Recovery of olefin monomers

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas

A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60°F to about 105°F into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.

Pressure swing adsorption process

A process for separating a primary gas component from a feed gas mixture comprising the primary gas component and secondary gas components in four or more adsorption beds. The process comprises subjecting each of the four or more adsorption beds to a repetitive cycle. The repetitive cycle comprises, in sequence, a feed step, a pressure decreasing equalization step, a provide purge step, a blowdown step, a purge step, a pressure increasing equalization step, and a repressurization step. During the pressure decreasing equalization step and/or provide purge step, rinse gas is co-currently introduced simultaneous with the withdrawal of pressure equalization gas. Rinse gas is formed by compressing blowdown gas from the adsorption bed undergoing the blowdown step and/or purge gas effluent from the adsorption bed undergoing the purge step. The process is particularly suited for separating H 2 from a reformate stream.

Radial adsorber, adsorption system, and adsorption methods

A radial adsorber can be configured to facilitate utilization of different layers of material. The radial adsorber, system using at least one radial adsorber, and methods of utilizing embodiments of the radial adsorber can help permit improved efficient operation of fluid purification processing while also being configured to minimize, if not fully avoid, being susceptible to the effect of fluidization.

Ozone production by pressure swing adsorption using a noble gas additive

Helium is introduced as an additive to any of the oxygen streams introduced into an ozone generator, such as a dielectric discharge (cold plasma) ozone generator, where the effluent of the generator is directed to an adsorption process for separating the ozone from the oxygen. Also disclosed is an improved PSA cycle, which is designed to reduce the amount of make-up helium and oxygen required to sustain the ozone generation and recovery process.

Perforated adsorbent particles

An adsorption vessel comprising a packed bed region of adsorbent particles contiguously arranged, comprising a perforated adsorbent particles, a gas separation process using the perforated adsorbent particles, and methods for making the perforated adsorbent particles. The perforated adsorbent particles each comprise an adsorbent material where the perforated adsorbent particles each have at least 10 channels extending through the particle. The equivalent diameter of the channels may range from 0.05 mm to 1.5 mm, and the void fraction of the channels may range from 0.05 to 0.5.

Ozone recovery by zeolite adsorbents

Ozone is recovered from an ozone-oxygen mixture adsorption using an absorbent which comprises a zeolite selected from the group consisting of L type zeolite, Y type zeolite, ZSM-5, and mordenite in which at least 90% of the exchangeable cation content in the ammonium form and the molar ratio potassium to aluminum is less than about 0.25. Alternatively, a proton-exchanged L type zeolite can be used in which at least 90% of the exchangeable cation content is in the proton form and the molar ratio of potassium to aluminum is less than about 0.25.

Optimum adsorbents for h2 recovery by pressure and vacuum swing adsorption

An improved adsorption process is provided for purifying hydrogen from a feed gas mixture including hydrogen and at least one impurity selected from the group consisting of carbon monoxide and nitrogen. The process includes providing an adsorption apparatus having a discharge end adsorption layer containing an adsorbent with a Henry's law constant (K H) at 70°F for the impurity from about 0.5 to about 2.4 mmole/g/atm. The product gas collected from the adsorption apparatus is high purity (99.99+%) hydrogen.

Perforated adsorbent particles

An adsorption vessel comprising a packed bed region of adsorbent particles contiguously arranged, comprising a perforated adsorbent particles, a gas separation process using the perforated adsorbent particles, and methods for making the perforated adsorbent particles. The perforated adsorbent particles each comprise an adsorbent material where the perforated adsorbent particles each have at least 10 channels extending through the particle. The equivalent diameter of the channels may range from 0.05 mm to 1.5 mm, and the void fraction of the channels may range from 0.05 to 0.5.

Design and operation methods for pressure swing adsorption systems

Method for the separation of a gas mixture comprising providing a pressure swing adsorption system having a plurality of adsorber vessels, wherein each vessel has an inlet, an outlet, and a bed of particulate adsorbent material disposed therein. The adsorbent material is selective for the adsorption of one or more components from the gas mixture, and each bed of adsorbent material is characterized by a bed depth and by an average particle diameter less than about 1.3 mm. A feed step is carried out during a feed time period wherein the gas mixture is introduced into the adsorber vessel, one or more components are selectively adsorbed from the gas mixture, and a product gas is withdrawn from the adsorber vessel. The bed depth in feet times the dimensionless ratio of the empty bed residence time to the feed time period is less than about 4.

Activated carbon as sole adsorbent in rapid cycle hydrogen psa

A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and said apparatus are substantially free of zeolite adsorbents; feed ing a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.

Design and operation methods for pressure swing adsorption systems

Method for the separation of a gas mixture comprising providing a pressure swing adsorption system having a plurality of adsorber vessels, wherein each vessel has an inlet, an outlet, and a bed of particulate adsorbent material disposed therein. The adsorbent material is selective for the adsorption of one or more components from the gas mixture, and each bed of adsorbent material is characterized by a bed depth and by an average particle diameter less than about 1.3 mm. A feed step is carried out during a feed time period wherein the gas mixture is introduced into the adsorber vessel, one or more components are selectively adsorbed from the gas mixture, and a product gas is withdrawn from the adsorber vessel. The bed depth in feet times the dimensionless ratio of the empty bed residence time to the feed time period is less than about 4.

Pressure swing adsorption process with multiple beds on purge and/or with ten beds and four pressure equalization steps

A pressure swing adsorption process includes providing an adsorption apparat us having a plurality of beds and counter-currently purging at least two of the beds simultaneously throughout the process. The number of beds and number of pressure equalization steps are not particularly limited, but a ten-bed, four pressur e equalization step process is advantageous. In addition, other ten-bed, four pressure equalization step processes are disclosed which do not counter-currently purge at least t wo of the beds simultaneously, but which have an average of at least two of the ten be ds being simultaneously regenerated by simultaneously providing off-gas from a feed e nd of each of the two beds to an off-gas lines.

Pressure swing adsorption process operation and optimization

A pressure swing adsorption process which comprises introducing a feed gas mixture into an inlet of an adsorber vessel during a feed period, wherein the feed gas mixture contains a more strongly adsorbable component and a less strongly adsorbable component and the adsorber vessel contains a bed of adsorbent material which selectively adsorbs the more strongly adsorbable component, and withdrawing a product gas enriched in the less strongly adsorbable component from an outlet of the adsorber vessel during at least a portion of the feed period, wherein a dimensionless cycle-compensated mass transfer coefficient defined as K t feed V ads /V feed is maintained in the range of about 23 to about 250.

Adsorption cycle for ozone production

A gas mixture is separated by an adsorption cycle using at least three adsorber vessels in which the sweep stage recovering adsorbed product from one adsorber vessel overlaps with that of another of the adsorber vessels and/or effluent from one adsorber vessel in a feed rinse stage is routed to another adsorber vessel that is in an air sweep stage. Also provided is a PSA ozone separation cycle in which the product ozone concentration is maintained within a range of 10 mg/l.

method, and apparatus

MéTODO, E APARELHO Hélio é introduzido como um aditivo a qualquer um dos fluxos de oxigênio introduzidos num gerador de ozónio, como um gerador de ozânio com descarga dielétrica (plasma frio), onde o efluente do gerador é dirigido a um processo de adsorçào para separar o ozânio do oxigênio. Também é divulgado um ciclo melhorado de PSA, que visa reduzir a quantidade de reposição de hélio e oxigênio necessária para sustentar a geração de ozónio e o processo de recuperação. METHOD, AND APPARATUS Helium is introduced as an additive to any of the oxygen flows introduced in an ozone generator, as an ozone generator with dielectric discharge (cold plasma), where the effluent from the generator is directed to an adsorption process to separate ozone from oxygen. An improved PSA cycle is also released, which aims to reduce the amount of helium and oxygen replacement needed to sustain ozone generation and the recovery process.

Layered adsorption zone for hydrogen production swing adsorption

The present invention describes a pressure swing adsorption (PSA) apparatus and process for the production of purified hydrogen from a feed gas stream containing heavy hydrocarbons (i.e., hydrocarbons having at least six carbons). The apparatus comprises at least one bed containing at least three layers. The layered adsorption zone contains a feed end with a low surface area adsorbent (20 to 400 m 2 /g) which comprises 2 to 20% of the total bed length followed by a layer of an intermediate surface area adsorbent (425 to 800 m 2 /g) which comprises 25 to 40% of the total bed length and a final layer of high surface area adsorbent (825 to 2000 m 2 /g) which comprises 40 to 78% of the total bed length.

Rapid cycle PSA with activated carbon as adsorbent

A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and said apparatus are substantially free of zeolite adsorbents; feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.

Ozone production by pressure swing adsorption using a noble gas additive

Helium is introduced as an additive to any of the oxygen streams introduced into an ozone generator, such as a dielectric discharge (cold plasma) ozone generator, where the effluent of the generator is directed to an adsorption process for separating the ozone from the oxygen. Also disclosed is an improved PSA cycle, which is designed to reduce the amount of make-up helium and oxygen required to sustain the ozone generation and recovery process.

Hydrogen production by pressure swing adsorption using a layered adsorbent bed

Gas purification by adsorption of hydrogen sulfide

Hydrogen sulfide is removed from a hydrogen rich gas stream using adsorbents having a low loss of carbon dioxide adsorption capacity upon sulfur loading including high purity silica gels, titania or highly cross-linked, non-chemically reactive resins. The adsorbents may be used to adsorb both carbon dioxide and hydrogen sulfide, or may be used as a guard bed upstream of a separate carbon dioxide adsorbent.

Adsorption process

A process for separating a first gas, for example CO 2 , from a feed gas mixture comprising the first gas and a second gas, for example H 2 , in five or more adsorption beds each containing an adsorbent selective for the first gas. The process comprises subjecting each of the adsorption beds to a repetitive cycle comprising, in sequence, (a) a feed step, (b) a rinse step, (c) a pressure decreasing equalization step, (d) a blowdown step, (e) an evacuation step, (f) a pressure increasing equalization step, and (g) a repressurization step. The feed gas mixture may be a reformate from a steam-hydrocarbon reforming process.

Carbon monoxide/water removal from fuel cell feed gas

The present invention is a method for production of a hydrogen-rich fuel gas compatible for a fuel cell, comprising; reforming a hydrocarbon-containing fuel to a CO-containing, hydrogen-rich reformate, converting CO in the reformate to CO2 and hydrogen by a catalyzed water-shift reaction, removing residual CO in the reformate by adsorption on a copper halide adsorbent, and passing the essentially CO-free reformate as a hydrogen-rich fuel gas to a fuel cell.

Adsorbents for rapid cycle pressure swing adsorption processes

Method for the separation of a gas mixture comprising providing a PSA syst em with at least one adsorber vessel containing adsorbent material that is selective for the adsorption of carbon monoxide and nitrogen, passing a feed gas mixture containing at least hydrogen and carbon monoxide and optionally containing nitrogen throug h the adsorbent material in a feed step and withdrawing a purified hydrogen produc t from the adsorber vessel, wherein the feed step has a duration or feed time period of about 30 seconds or less. The adsorbent material is characterized by any of (1) a Henry's law constant for carbon monoxide between about 2.5 and about 5.5 (mmole/g)/atm; (2) a carbon monoxide heat of adsorption between about 6.0 and about 7.5 kcal/gmol e; (3) a Henry's law constant for nitrogen greater than about 1.5 (mmole/g)/atm; and (4) a selectivity of carbon monoxide to nitrogen between about 5.0 and about 8.0.< /SDOAB>

Gas purification by adsorption of hydrogen sulfide

FAST CYCLE PSA WITH CARBON ACTIVATED AS ADSORBENT.

Un proceso de adsorción de oscilación de presión para recuperar un gas producto que comprende hidrógeno a partir de un gas de alimentación que comprende una mezcla de hidrógeno y al menos otro componente seleccionado del grupo constituido por dióxido de carbono, monóxido de carbono, hidrocarburos, oxígeno, metano, argón y nitrógeno, comprendiendo dicho proceso: suministrar un aparato de adsorción de oscilación de presión que comprende una composición adsorbente que consiste esencialmente en carbono activado en forma de gránulos, un monolito, un lecho sinterizado o una tela, en el que dicha composición adsorbente y dicho aparato estén sustancialmente libres de adsorbentes de zeolita; suministrar el gas de alimentación a dicho aparato de adsorción de oscilación de presión a una velocidad G que supere los 781,9 kg/mol/h/m 2 (160 lbmol/h/pie); y recuperar dicho gas producto de dicho aparato de adsorción de oscilación de presión. A pressure swing adsorption process for recovering a product gas comprising hydrogen from a feed gas comprising a mixture of hydrogen and at least one other component selected from the group consisting of carbon dioxide, carbon monoxide, hydrocarbons, oxygen , methane, argon and nitrogen, said process comprising: supplying a pressure swing adsorption apparatus comprising an adsorbent composition consisting essentially of activated carbon in the form of granules, a monolith, a sintered bed or a fabric, wherein said adsorbent composition and said apparatus are substantially free of zeolite adsorbents; supplying the feed gas to said pressure swing adsorption apparatus at a speed G exceeding 781.9 kg / mol / h / m 2 (160 lbmol / h / ft); and recovering said gas product from said pressure swing adsorption apparatus.

Adsorbents for rapid cycle pressure swing adsorption processes

Method for the separation of a gas mixture comprising providing a PSA system with at least one adsorber vessel containing adsorbent material that is selective for the adsorption of carbon monoxide and nitrogen, passing a feed gas mixture containing at least hydrogen and carbon monoxide and optionally containing nitrogen through the adsorbent material in a feed step and withdrawing a purified hydrogen product from the adsorber vessel, wherein the feed step has a duration or feed time period of about 30 seconds or less. The adsorbent material is characterized by any of (1) a Henry's law constant for carbon monoxide between about 2.5 and about 5.5 (mmole/g)/atm; (2) a carbon monoxide heat of adsorption between about 6.0 and about 7.5 kcal/gmole; (3) a Henry's law constant for nitrogen greater than about 1.5 (mmole/g)/atm; and (4) a selectivity of carbon monoxide to nitrogen between about 5.0 and about 8Ø

Pressure swing adsorption process

Activated carbon as sole adsorbent in rapid cycle hydrogen psa

A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and said apparatus are substantially free of zeolite adsorbents; feed ing a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.

Valve operation diagnostic method for pressure swing adsorption systems

Method of operating a pressure swing adsorption system having a plurality of parallel adsorber vessels and a plurality of valves and gas manifolds adapted to introduce gas into each adsorber vessel and withdraw gas from each adsorber vessel in a cyclic series of sequential process steps. A leaking valve may be identified by (1) determining a value of an operating parameter that is a function of the mass of gas provided to a receiving adsorber vessel or withdrawn from an adsorber vessel during a selected process step, portion of a process step, or series of process steps; (2) determining the deviation of the value of the operating parameter from a predetermined reference value; and (3) using the magnitude and direction of the deviation to determine whether any valves are leaking.

Perforated adsorbent particles

Gas purification by adsorption of hydrogen sulfide

Hydrogen sulfide is removed from a hydrogen rich gas stream using adsorbents having a low loss of carbon dioxide adsorption capacity upon sulfur loading including high purity silica gels, titania or highly cross-linked, non-chemically reactive resins. The adsorbents may be used to adsorb both carbon dioxide and hydrogen sulfide, or may be used as a guard bed upstream of a separate carbon dioxide adsorbent.

Ammonia cracking for green hydrogen

Residual ammonia is removed effectively from ammonia cracked gas in a hydrogen PSA system using a non-zeolitic adsorbent such as activated carbon, activated alumina or silica gel.

Druckwechseladsorptionsverfahren mit mehreren adsorptionsbetten

Ammonia cracking for green hydrogen

Residual ammonia is removed effectively from ammonia cracked gas in a hydrogen PSA system using a non-zeolitic adsorbent such as activated carbon, activated alumina or silica gel.

Rückgewinnung von olefinen

Recovery of a renewable hydrogen product from an ammonia cracking process

Recovery of a renewable hydrogen product from an ammonia cracking process, in which the cracked gas is purified in a first PSA device and at least a portion of the first PSA tail gas is recycled as fuel to reduce the carbon intensity of the renewable hydrogen product.

Separation process and apparatus for light noble gas

Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit (10) having minimal dead end volumes (109). A second separation unit (20) receives a stream enriched in helium, neon, or argon, and a stream is recycled from the second separation unit (20) back to the adsorption separation unit (10) in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit (10) within a targeted range.

Recovery of a renewable hydrogen product from an ammonia cracking process

Recovery of a renewable hydrogen product from an ammonia cracking process, in which the cracked gas is purified in a first PSA device and at least a portion of the first PSA tail gas is recycled as fuel to reduce the carbon intensity of the renewable hydrogen product.

Recovery of a renewable hydrogen product from an ammonia cracking process

Recovery of a renewable hydrogen product from an ammonia cracking process, in which the cracked gas is purified in a first PSA device and at least a portion of the first PSA tail gas is recycled as fuel to reduce the carbon intensity of the renewable hydrogen product.

Verfahren zur überprüfung des ventilbetriebs in druckwechseladsorptionssystemen

Schnell-zyklus druckwechseladsorptionsverfahren mit aktivkohle adsorptionsmittel

Kohlenmonoxid/wasserentfernung aus einem einsatzgas für eine brennstoffzelle

Ammonia cracking for green hydrogen

Residual ammonia is removed effectively from ammonia cracked gas in a hydrogen PSA system using a non-zeolitic adsorbent such as activated carbon, activated alumina or silica gel.

Pressure swing adsorption process with multiple beds on purge and/or with ten beds and four pressure equalization steps

A pressure swing adsorption process for separation of gas mixtures that contain components with different adsorbing characteristics is disclosed which process includes providing an adsorption apparatus having a plurality of beds and counter- currently purging at least two of the beds simultaneously throughout the process. The number of beds and number of pressure equalization steps are not particularly limited, but a ten-bed, four pressure equalization step process is advantageous. In addition, other ten-bed, four pressure equalization step processes are disclosed which do not counter-currently purge at least two of the beds simultaneously, but which have an average of at least two of the ten beds being simultaneously regenerated by simultaneously providing off-gas from a feed end of each of the two beds to an off-gas line.

Recovery of a renewable hydrogen product from an ammonia cracking process

Recovery of a renewable hydrogen product from an ammonia cracking process, in which the cracked gas is purified in a first PSA device and at least a portion of the first PSA tail gas is recycled as fuel to reduce the carbon intensity of the renewable hydrogen product.

Durchführung und optimierung eines druckwechseladsorptionsverfahrens

Hydrogen separation from natural gas

Methods and systems for measuring the concentration of a light gas in a main flow stream are disclosed herein. The methods include calculating a control parameter as a function of the concentration of the light gas in the main flow stream; dividing a portion of the main flow stream to produce a feed stream; and separating the feed stream by selective permeation across a semi-permeable membrane to produce a permeate stream enriched in the light gas and a retentate depleted in the light gas. A ratio of the flow rate of the feed stream to the flow rate of the main flow stream may be increased or decreased according to the control parameter. In addition, an area of the semi-permeable membrane may be increased or decreased according to the control parameter.

Hydrogen separation from natural gas

Methods and systems for measuring the concentration of a light gas in a main flow stream are disclosed herein. The methods include calculating a control parameter as a function of the concentration of the light gas in the main flow stream; dividing a portion of the main flow stream to produce a feed stream; and separating the feed stream by selective permeation across a semi-permeable membrane to produce a permeate stream enriched in the light gas and a retentate depleted in the light gas. A ratio of the flow rate of the feed stream to the flow rate of the main flow stream may be increased or decreased according to the control parameter. In addition, an area of the semi-permeable membrane may be increased or decreased according to the control parameter.

Recovery of a renewable hydrogen product from an ammonia cracking process

Recovery of a renewable hydrogen product from an ammonia cracking process, in which the cracked gas is purified in a first PSA device and at least a portion of the first PSA tail gas is recycled as fuel to reduce the carbon intensity of the renewable hydrogen product.

Adsorption Process To Recover Hydrogen From Feed Gas Mixtures Having Low Hydrogen Concentration

A process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality of adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

Sour pressure swing adsorption process

Methods and apparatuses for separating CO 2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

Perforated adsorbent particles

An adsorption vessel comprising a packed bed region of adsorbent particles contiguously arranged, comprising a perforated adsorbent particles, a gas separation process using the perforated adsorbent particles, and methods for making the perforated adsorbent particles. The perforated adsorbent particles each comprise an adsorbent material where the perforated adsorbent particles each have at least 10 channels extending through the particle. The equivalent diameter of the channels may range from 0.05 mm to 1.5 mm, and the void fraction of the channels may range from 0.05 to 0.5.