01-11-2012 дата публикации
Номер: US20120277330A1
Автор:
Duane A. Goetsch,
Kym B. Arcuri,
Steven J. Schmit,
Jacqueline R. Hitchingham,
Lloyd R. White,
GOETSCH DUANE A,
ARCURI KYM B,
SCHMIT STEVEN J,
HITCHINGHAM JACQUELINE R,
WHITE LLOYD R,
GOETSCH DUANE A.,
ARCURI KYM B.,
SCHMIT STEVEN J.,
HITCHINGHAM JACQUELINE R.,
WHITE LLOYD R.
A process for producing transportation fuels, such as gasoline and diesel fuel, from syngas with a low H/CO ratio. The syngas is first converted to dimethyl ether which is then converted to gasoline by way of a dimethyl ether to gasoline process and to diesel fuel by way of a Fischer-Tropsch process. 1. A process for producing at least one transportation fuel boiling range stream from syngas , which syngas is comprised predominantly of hydrogen and carbon monoxide , up to about 20 volume percent of other moieties , substantially no sulfur , and has a hydrogen to carbon monoxide ratio of about 1 to about 1.5 , which process comprising:a) reacting said syngas in a first reaction zone in the presence of a bifunctional catalyst, at pressures from about 400 psi to about 1,000 psi and at a temperature from about 150° C. to 400° C. for an effective residence time, thereby resulting in product stream comprised of dimethyl ether, methanol, unreacted syngas at a higher hydrogen to carbon monoxide ratio than the feed ratio, water, and carbon dioxide;b) conducting said product stream to a first separation zone wherein the stream is cooled and condensed, thereby resulting in a gaseous product stream comprised of unreacted syngas and a first separated liquid product stream comprised substantially of dimethyl ether, methanol, water and dissolved carbon dioxide;c) conducting said first separated liquid product stream to a second separation zone wherein at least a portion of said carbon dioxide is removed thereby resulting in a second separated liquid product stream comprised of dimethyl ether, methanol, and water;d) conducting said second separated liquid reaction product stream to a third separation zone wherein at least a fraction of the methanol and water are removed, thereby resulting in a third separated liquid product stream comprised of predominantly dimethyl ether;e) conducting at least a portion of said third liquid product stream to a second reaction zone wherein it is ...
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