30-03-2017 дата публикации
Номер: US20170088489A1
Принадлежит:
Systems and methods are provided for converting alkane while generating improved yields of desirable aromatics and/or improved selectivity for forming desired aromatics, such as para-xylene (p-xylene). Aromatics generated during the aromatic formation process can be alkylated to form xylenes with improved yield and/or improved selectivity. 1. A method for forming aromatic compounds , comprising:providing a feed comprising non-aromatic hydrocarbon;{'sub': 7', '8, "producing an aromatic formation effluent comprising benzene, Caromatic hydrocarbon, and ≦20 wt. % of Caromatic hydrocarbon from at least a portion of the feed's non-aromatic hydrocarbon in an aromatic formation process carried out under effective aromatic formation conditions;"}{'sub': 8', '8', '8', '7', '6', '7, 'separating from the aromatic formation effluent a first Cintermediate stream and a first lower boiling intermediate stream, the first Cintermediate stream having a Caromatic hydrocarbon concentration (weight percent) greater than that of the aromatic formation effluent, the first lower boiling intermediate stream having a benzene concentration (weight percent), a Caromatic hydrocarbon concentration (weight percent), or a combined C-Caromatic hydrocarbon concentration (weight percent) greater than those of the aromatic formation effluent;'}{'sub': '8', 'reacting at least a portion of the first lower boiling intermediate stream with a methylating agent in the presence of a zeolite catalyst to form a methylated intermediate stream, the methylated intermediate stream having a Caromatic hydrocarbon concentration (weight percent) greater than that of the portion of the first lower boiling intermediate stream which reacts to form the methylated intermediate stream;'}{'sub': 8', '8', '8, 'separating from the methylated intermediate stream a second Cintermediate stream and a second lower boiling intermediate stream, the second Cintermediate stream having a Caromatic hydrocarbon concentration (weight ...
Подробнее