25-09-2014 дата публикации
Номер: US20140287910A1
Принадлежит:
The present invention provides a hollow IM-5 molecular sieve sphere and the preparation process thereof. The process according to the present invention adds a relatively great amount of the surfactant of a cationic quaternary ammonium salt in the IM-5 molecular sieve system, to form a hollow IM-5 molecular sieve sphere via the micelle action by the surfactant, which structure benefits the mass transfer of the reaction process. 1. An IM-5 molecular sieve , characterized in that the IM-5 molecular sieve is in the form of a hollow sphere , the hollow sphere having an outer diameter of about 2-about 15 μm , preferably about 2-about 10 μm , more preferably about 4-about 8 μm.2. The IM-5 molecular sieve according to claim 1 , characterized in that the wall of the hollow sphere consists of IM-5 crystal grains having a particle size of about 10-about 500 nm claim 1 , preferably about 10-about 200 nm.3. The IM-5 molecular sieve according to claim 1 , characterized in that the wall thickness of the hollow sphere is about 10%-about 40% claim 1 , preferably about 15%-about 30% claim 1 , of the outer diameter of the hollow sphere.4. A process of preparing the IM-5 molecular sieve according to claim 1 , characterized in comprising the steps of:(1) mixing an alkali source, a templet agent, an aluminum source, water, a silicon source and a cationic surfactant, and stirring the mixture at a suitable temperature to generate a sol; and(2) elevating the temperature of the mixture of step (1) in a hydrothermal reactor to about 140-about 200 degrees C., after hydrothermal crystallization of about 2-about 15 days, taking out and separating the solid product, drying and calcinating to obtain a hollow IM-5 molecular sieve sphere.5. The process according to claim 4 , characterized in that in step (1) claim 4 , the temperature for stirring is about 20-about 70 degrees C. claim 4 , preferably about 55-about 65 degrees C.; and the duration of stirring is about 1-about 24 hours claim 4 , ...
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