03-12-2020 дата публикации
Номер: US20200376471A1
Автор:
Matthew S. Ide,
Brett T. Loveless,
Doron Levin,
William W. Lonergan,
Matthew J. Vincent,
Wei-Ping Tai,
Federico Barrai,
IDE MATTHEW S,
LOVELESS BRETT T,
LEVIN DORON,
LONERGAN WILLIAM W,
VINCENT MATTHEW J,
TAI WEI-PING,
BARRAI FEDERICO,
Ide, Matthew S.,
Loveless, Brett T.,
Levin, Doron,
Lonergan, William W.,
Vincent, Matthew J.,
Tai, Wei-Ping,
Barrai, Federico
Принадлежит:
Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d50). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or cumene) which exhibit improved yield of the mono-alkylated aromatic compound using alkylation catalysts comprising one or more of these catalyst compositions. 124-. (canceled)25. A catalyst composition comprising a zeolite and a mesoporous binder , said mesoporous binder is a mesporous metal oxide which has a particle diameter of greater than or equal to 20 μm at a median value of the particle size distribution in a sample where the value of the particle diameter is at 50% of the cumulative distribution and a pore volume of less than 1 cc/g , said mesoporous metal oxide has an alumina content of greater than or equal to 75% , by weight , wherein said catalyst composition has a surface area of less than or equal to 300 m/g as measured by ASTM D4284.26. The catalyst composition of claim 25 , wherein said zeolite has a framework structure which includes one or more of BEA* claim 25 , FAU claim 25 , MOR claim 25 , and MWW.27. The catalyst composition of claim 26 , wherein said framework structure which includes BEA* is zeolite beta claim 26 , said framework structure which includes FAU includes one or more of faujasite claim 26 , zeolite Y claim 26 , USY claim 26 , Deal-Y claim 26 , UHP-Y claim 26 , and REY claim 26 , said framework structure which includes MOR includes one or more of mordenite claim 26 , TEA-mordenite claim 26 , EMM-34 claim 26 , and UZM 14 claim 26 , said framework structure which comprises MWW is a MCM-22 family material selected from the group consisting of MCM-22 claim 26 , PSH-3 claim 26 , SSZ-25 claim 26 , MCM-36 claim 26 , MCM-49 claim 26 , MCM-56 claim 26 , ERB-1 claim 26 , ...
Подробнее