06-02-2020 дата публикации
Номер: US20200040465A1
Принадлежит:
The present disclosure is directed to the methods for identifying a combined corrosion inhibitor formulation comprising at least a first and second corrosion inhibitor formulation for inhibiting corrosion in various substrates, for example in metal substrates. The present disclosure is also directed to compositions for inhibiting corrosion comprising a combined corrosion inhibitor formulation each independently selected from organic heterocyclic compounds and metal salts, metal anions, metal complexes, or any combinations thereof selected from rare earth, alkali earth and transition metals. 2. The method of claim 1 , wherein the combined corrosion inhibitor formulation is according to (i) claim 1 , and the at least two metal cations are selected from the group consisting of Pr claim 1 , Gd claim 1 , Tb claim 1 , Ce claim 1 , Dy claim 1 , Sm claim 1 , Er claim 1 , Lu claim 1 , Tm claim 1 , Zn claim 1 , Co claim 1 , Cu claim 1 , and the at least one organic heterocyclic compound of Formula 1 is selected from the group consisting of 3-amino-1 claim 1 ,2 claim 1 ,4-triazole claim 1 , benzimidazole claim 1 , 1H-benzotriazole claim 1 , 5-amino-2-mercapto-1 claim 1 ,3 claim 1 ,4-thiadiazole claim 1 , 9H-purine-8-thiol claim 1 , 1 claim 1 ,2 claim 1 ,4-triazole claim 1 , 1 claim 1 ,2 claim 1 ,4-triazole-3-thiol claim 1 , and 5-methyl-2-mercapto-1 claim 1 ,3 claim 1 ,4-thiadiazole.3. The method of claim 1 , wherein the combined corrosion inhibitor formulation is according to (ii) claim 1 , and the at least one metal cation is selected from the group consisting of Pr claim 1 , Gd claim 1 , Tb claim 1 , Ce claim 1 , Dy claim 1 , Sm claim 1 , Er claim 1 , Lu claim 1 , Tm claim 1 , Zn claim 1 , Co claim 1 , Cu claim 1 , the at least one metal anion is selected from the group consisting of MoO claim 1 , VO claim 1 , ZrO claim 1 , WO claim 1 , and the at least one organic heterocyclic compound of Formula 1 is selected from the group consisting of 3-amino-1 claim 1 ,2 claim 1 ,4- ...
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