03-12-2015 дата публикации
Номер: US20150344748A1
Принадлежит:
Epoxy resin compositions prepared using amino terminated fluoro alkyl ethers. The epoxy resin compositions exhibit low surface adhesion properties making them useful as coatings, paints, moldings, adhesives, and fiber reinforced composites. 1. An epoxy composition comprising a reaction product of:(i) at least one epoxy resin including at least one glycidyl, alicyclic epoxy, oxirane, or ethoxyline group; and(ii) at least one amino terminated fluorinated alkyl ether oligomer or polymer including at least one amine which reacts with the epoxy resin and at least one fluorinated pendant group which migrates to the surface of the epoxy composition.2. The composition of claim 1 , wherein the at least one amino terminated fluorinated alkyl ether oligomer or polymer is represented by formula (I):{'br': None, 'sub': y', '2', '2', 'm', 'y, 'sup': 1', '2', '3', '1, '(E)R—C(O)—O—[CHCRR—CH—O]—C(O)—R(E)\u2003\u2003(I)'} [{'sub': '2', 'E comprises —NH;'}, 'y is 1;', {'sup': '1', 'Ris an aliphatic or aromatic hydrocarbon moiety of 1 to 10 carbon atoms;'}, {'sup': '2', 'Ris —H, —F, or an alkyl of 1 to 6 carbon atoms;'}, {'sup': 3', '4', '5', '4', '4', '4', '5, 'sub': (n-a)', 'a', '(n-a)', 'a', '(n-a)', 'a, 'Ris —F, —RHF, —R—O—RHF, or —O—RHF, wherein Ris an alkyl or ether moiety of 1 to 30 carbons, Ris an alkyl moiety of 1 to 30 carbons, a is an integer of 3 to n, and n is twice the number of carbon atoms in the alkyl moiety plus 1; and'}, 'm is from 4 to 500., 'wherein3. The composition of claim 2 , wherein Ris a divalent phenyl group; Ris alkyl of 1 to 3 carbon atoms; Ris —R—O—RHF claim 2 , the omega carbon of Rhas three fluoride substituents; Ris —Cl—O—C(X)—CF claim 2 , wherein X is —H or —F; and m is between about 6 and 100.4. The composition of claim 1 , wherein the at least one amino terminated fluorinated alkyl ether oligomer or polymer is an oligomer represented by formula (II):{'br': None, 'sub': y', 'm', 'y, 'sup': 1', '1, '(E)R—C(O)—O-[Q]-C(O)—R(E)\u2003\u2003(II)'} [{'sub ...
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