04-07-2023 дата публикации
Номер: CN116387541A
Принадлежит:
The invention belongs to the field of electrocatalysts, and discloses an electrocatalytic oxygen reduction catalyst and a preparation method thereof. According to the catalyst, metal rhenium exists in a nitrogen-doped carbon skeleton in a monatomic form. The preparation method comprises the following steps: (1) adding 0.1-0.5 part by mass of ammonium perrhenate solid powder into 30-50 parts by volume of methanol, and adding 0.2-16 parts by mass of zinc nitrate hexahydrate to obtain a solution A; (2) adding 1-18 parts by mass of 2-methylimidazole solid powder into 50-80 parts by volume of methanol to obtain a solution B; (3) pouring the solution A into the solution B; (4) standing for layering, discarding supernate, washing, and drying in vacuum to obtain a precursor; (5) roasting the precursor for 2 to 5 hours under the condition of 600 to 1100 DEG C; (6) etching with an acid solution, washing to be neutral, filtering, and freeze-drying; and (7) roasting at 700-1100 DEG C for 2-4 hours ...
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