10-10-2013 дата публикации
Номер: US20130266865A1
A negative active material having controlled particle size distribution of silicon nanoparticles in a silicon-based alloy, a lithium battery including the negative active material, and a method of manufacturing the negative active material are disclosed. The negative active material may improve capacity and lifespan characteristics by inhibiting (or reducing) volumetric expansion of the silicon-based alloy. The negative active material may include a silicon-based alloy including: a silicon alloy-based matrix; and silicon nanoparticles distributed in the silicon alloy-based matrix, wherein a particle size distribution of the silicon nanoparticles satisfies D10≧10 nm and D90≦75 nm. 1. A negative active material for a lithium battery comprising: a silicon alloy-based matrix; and', 'silicon nanoparticles distributed in the silicon alloy-based matrix,', 'wherein a particle size distribution of the silicon nanoparticles satisfies D10≧10 nm and D90≦75 nm., 'a silicon-based alloy comprising2. The negative active material of claim 1 , wherein the silicon-based alloy comprises silicon (Si) and at least one metal selected from the group consisting of Ca claim 1 , Sc claim 1 , Ti claim 1 , V claim 1 , Cr claim 1 , Mn claim 1 , Fe claim 1 , Co claim 1 , Ni claim 1 , Cu claim 1 , Zn claim 1 , Sr claim 1 , Y claim 1 , Zr claim 1 , Nb claim 1 , Ba claim 1 , Lu claim 1 , Hf claim 1 , Ta claim 1 , and Lanthanum group elements.3. The negative active material of claim 2 , wherein the content of Si in the silicon-based alloy is 40 at % or greater based on 100 at % of the silicon-based alloy.4. The negative active material of claim 1 , wherein the silicon-based alloy comprises Si claim 1 , M′ claim 1 , and M″ claim 1 , and wherein M′ is Al claim 1 , Ti claim 1 , or Fe claim 1 , and M″ is Ni claim 1 , Fe claim 1 , or Mn.5. The negative active material of claim 4 , wherein the content of Si in the silicon-based alloy is in a range of 40 to 80 at % claim 4 , the content of M′ in the silicon ...
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