26-07-2023 дата публикации
Номер: EP4216317A1
The present application relates to the technical field of secondary batteries, and in particular to a negative electrode active material and a preparation method, a secondary battery, a battery module, a battery pack and an electrical apparatus. The negative electrode active material of the present application comprises an inner core, an interlayer and an outer shell layer, wherein the interlayer is cladded on the surface of the inner core, and the outer shell layer is cladded on the surface of the interlayer; the inner core comprises silicon, an oxide of silicon and lithium silicate; the interlayer comprises silicon, or silicon and lithium silicate; and the outer shell layer comprises amorphous carbon. In the present application, an inner core comprising silicon, an oxide of silicon and lithium silicate is used as a nucleus, and an interlayer containing silicon as well as an outer shell layer comprising amorphous carbon are cladded outwards in sequence to form a uniformly cladded and structurally stable negative electrode active material with a core-shell structure, so that not only the content of silicon element in the negative electrode active material can be significantly increased, but also the side reactions between the silicon components and the active lithium in the electrolyte solution can be effectively suppressed, thereby simultaneously increasing the first reversible specific capacity and the first charge efficiency of the secondary battery.
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