КОМПОЗИЦИЯ ДЛЯ БОРЬБЫ С БОЛЕЗНЯМИ РАСТЕНИЙ И СПОСОБ БОРЬБЫ С БОЛЕЗНЯМИ РАСТЕНИЙ

Изобретение относится к сельскому хозяйству. Композиция для борьбы с болезнями растений содержит в качестве активных ингредиентов соединение, представленное формулой (1):где Xпредставляет собой метильную группу, дифторметильную группу или этильную группу; Xпредставляет собой метоксигруппу или метиламиногруппу; и Xпредставляет собой фенильную группу, 2-метилфенильную группу или 2,5-диметилфенильную группу; и по меньшей мере одно соединение азола, выбранное из группы, состоящей из бромуконазола, ципроконазола, дифеноконазола, фенбуконазола, флуквинконазола, гексаконазола, имибенконазола, ипконазола, миклобутанила, протиоконазола, симеконазола, тетраконазола, тритиконазола и метконазола. Массовое соотношение соединения, представленного формулой (1), и по меньшей мере одного соединения азола, находится в диапазоне от 0,0125:1 до 500:1. Средство для протравливания семян содержит указанную композицию. Осуществляют нанесение на растение или участок, где растение выращивают, эффективного количества ...

СПОСОБ ПОДАВЛЕНИЯ ФИТОПАТОГЕННЫХ ГРИБКОВ, ПРОИЗВОДНОЕ БЕНЗОФЕНОНА, СПОСОБ ЗАЩИТЫ РАСТЕНИЙ ОТ ПОВРЕЖДЕНИЯ, ВЫЗВАННОГО ФИТОПАТОГЕННЫМ ГРИБКОМ, ФУНГИЦИДНАЯ КОМПОЗИЦИЯ И СПОСОБЫ ПОЛУЧЕНИЯ БЕНЗОФЕНОНОВ

Описывается способ подавления фитопатогенных грибков или вызываемых ими заболеваний путем обработки их производным бензофенона общей формулы I, где значение заместителей обозначены в п. 1 формулы. Описывается способ защиты растений от повреждения, вызванного фитопатогенным грибком, с использованием соединения формулы I, а также фунгицидная композиция на основе соединения формулы I, описывается также способ получения соединения формулы I. Указанные бензофеноны обладают высокой фунгицидной активностью в широкой области концентраций и могут использоваться в сельском хозяйстве без вредного фитотоксического воздействия на полезные растения. 6 с. и 3 з.п. ф-лы, 12 табл.

ПРОИЗВОДНЫЕ БЕТА-ФЕНОКСИНИТРИЛОВ И СПОСОБ БОРЬБЫ С ГРИБКОВЫМИ ЗАБОЛЕВАНИЯМИ КУЛЬТУР

Использование: сельское хозяйство, в качестве вещества, обладающего фунгицидной активностью. Сущность изобретения: продукт формулы , где R - водород, метил, этил, изопропил, н-пропил, аллил; n = 1 или 2; x - атом кислорода или серы; y - хлор, бром, фтор; m = 1, 2, 3. Реагент I: . Реагент II: (Hal)2CH2. Реагент III: . Способ борьбы с грибковыми заболеваниями культур обработки листвы продуктом в количестве 0,03 - 1,0 кг/га. 2 с.п. ф-лы, 4 табл.

ПРОИЗВОДНЫЕ N-ФЕНИЛПИРАЗОЛА

Использование: в сельском хозяйстве в качестве инсектицида. Сущность изобретения: производные N-фенилпиразола. Получают известными методами. Реагент 1: 2, 4-дихлор-4-трифторметилфенилгидразина. Реагент II: 2-хлор-1, 1-ди-циано-2-трифторметилэтилена. Условия реакции: в растворе сухого диэтилового эфира при 0oC. 3 з. п. ф-лы, 4 табл.

ИНСЕКТОАКАРИЦИДНАЯ КОМПОЗИЦИЯ

Использование: в сельском хозяйстве для защиты растений. Сущность изобретения: инсектоакарицидная композиция содержит 0,1 - 40,25 мас.% соединения общей формулы: где R - н.пропил, трет-бутил, R′ - Н - трифторметил, циано, AX-гексинил, бутинилоксилметил, 3-3-диметилбутил, 4-этинилциклогексил, Y′ и Y -одинаковые кислород или сера, Z - CH2O, CH2S, остальное - целевые добавки. 3 з. п. ф-лы, 5 табл.

КРЕМНИЙСОДЕРЖАЩИЕ СОЕДИНЕНИЯ ИЛИ ИХ СОЛИ, ОБЛАДАЮЩИЕ ФУНГИЦИДНОЙ АКТИВНОСТЬЮ, И СПОСОБ ИХ ПОЛУЧЕНИЯ

Соединения формулы I в которой А представляет собой 1,2,4-триазол-1-ил или имидазол-1-ил, n равно 0, 1, 2 или 3, Х представляет собой галоген, фенил, алкил, галоидалкил, алкокси или галоидалкокси, или (Х)n представляет собой алкилендиокси, R1 представляет собой алкил или фенил, R1 и R2 каждый представляет собой алкил, и соли этих соединений проявляют полезную противогрибковую активность. Описываются также некоторые промежуточные продукты, получаемые при приготовлении данных соединений. 7 табл., 4 ил.

N-(4-ПИРИДИЛ- ИЛИ 4-ХИНОЛИНИЛ)АРИЛАЦЕТАМИДНЫЕ ПРОИЗВОДНЫЕ

Использование: в химии гетероциклических веществ, в частности в способе получения N-(4-пиридил-или 4-хинолинил)арилацетамидных производных. Сущность изобретения: продукт N-(4-пиридил- или 4-хинолил)арилацетамидные производные ф-лы 1: (CR2 двойная связь CR1 - N двойная связь CR3 - CR4 двойная связь C (вторая связь с CR2) - NR - C(O) - Y'Z), где R - водород и R1, R2, R3 и R4 имеют одно из следующих значений: а) R3 и R4 - водород, а R1 и R2 - независимы, галоген или C1 - C4-алкил; б) один из R1, R2, R3 и R4 - C1 - C4-алкил, а другие - водород; в) R1, R2, R3 и R4 независимы, водород или галоген; г) R1 и R2 - вместе образуют цепь: (-СН двойная связь СН-СН двойная связь СН-), которая может быть замещена атомом фтора, а R3 и R4 - водородом; Y'Z - вместе образуют неразветвленную или разветвленную насыщенную углеводородную C4 - C1-цепь или Y - метиленовая группа, а Z - фенил, моно- или дизамещенный C1 - C6-алкилом, галогеном, трифторметилом, C1 - C4 -алкокси группа, которая м. б. замещена фтором ...

КАРБОКСАНИЛИДЫ, АРТРОПОЦИДНАЯ КОМПОЗИЦИЯ И СПОСОБ БОРЬБЫ С АРТРОПОДАМИ

Изобретение относится к артроиодидным карбоксанилидам, композициям на их основе и способу борьбы с артроиодами и может быть использовано в сельском хозяйстве. Сущность изобретения: карбоксанилиды ф-лы I, приведенной в описании, где Q - соединение ф-лы Q-1, X-O, Y - выбрано из группы, содержащей H, C1-C6-алкил, C2-C6-алкенил, C2-C6-алкинил, C2- C6-алкилкарбонил, C2 -C6-алкоксикарбонил, или C1-C3-алкил, замещенный заместителем, выбранным из группы, содержащей SR32, C1-C3-алкокси, CO2 R32 и фенил; G-фенил, замещенный одним или двумя заместителями R1, который выбирают из группы, содержащей H, галоген, C1-C6-алкил, C1-C6-галоидалкил, NO2, CN, OR17, SR17. 3 с. и 10 з.п.ф-лы, 12 табл.

СРЕДСТВО ДЛЯ ПРЕДПОСЕВНОЙ ОБРАБОТКИ СЕМЯН

Назначение: изобретение относится к сельскому хозяйству, в частности, к средствам для предпосевной обработки семян. Сущность: средство по изобретению содержит, масс. % (по микроэлементам): источник цинка - 0,1-10, источник бора - 0,1-10, источник марганца - 0,1-10, источник меди - 0,1-10, высокодисперсный гидрофобный кремнезем - остальное. Средство комплексно влияет на растения, повышая всхожесть, урожайность, устойчивость к болезням и т. п. в дозе меньшей, чем обычно рекомендуемые для микроэлементов. 4 табл.

РЕПЕЛЛЕНТНОЕ СРЕДСТВО

... 1. Применение пиретроида или пиретрина в комбинации с никотиновым агонистом для отпугивания членистоногих. 2. Применение по п.1, в соответствии с которым пиретроид выбирают из группы I. пиретроиды типа I, II. пиретроиды типа II, III. пиретроиды без сложноэфирных групп, IV. натуральные пиретрины. 3. Применение по п.1, в соответствии с которым никотиновый агонист выбирают из группы V. неоникотиноиды, VI. нитиазин, VII. спинозины. 4. Применение по п.1 на теплокровных животных для отпугивания клещей, блох, комаров и/или мух. 5. Способ отпугивания членистоногих от теплокровных животных, в соответствии с которым на теплокровное наружно наносят пиретроид или пиретрин в композиции с никотиновым агонистом. 6. Способ удерживания членистоногих на расстоянии от мест и материалов, на которых их присутствие нежелательно, в соответствии с которым на место или на материал, на расстоянии от которых должны удерживаться членистоногие, наносят пиретрин или пиретроид в комбинации с никотиновым агонистом.

МАТЕРИАЛЫ С АНТИМИКРОБНОЙ ОБРАБОТКОЙ

... 1. Способ получения материала с антимикробной обработкой, включающий: получение раствора из жидкости и антимикробного агента; соединение целлюлозного волокнистого материала с указанным раствором с образованием жидкой суспензии, при этом после соединения указанный антимикробный агент связывается с указанным целлюлозным волокнистым материалом; и формирование полотна из указанной жидкой суспензии указанного целлюлозного волокнистого материала с антимикробной обработкой таким образом, что практически весь целлюлозный волокнистый материал, содержащийся в указанном полотне, получен из указанного целлюлозного волокнистого материала с антимикробной обработкой. 2. Способ по п.1, в котором, по крайней мере, часть указанной жидкости из указанной жидкой суспензии удаляется в процессе формирования указанного полотна, причем эта удаляемая часть жидкости по существу не содержит указанного антимикробного агента. 3. Способ по п.1, в котором указанным антимикробным агентом является кремнийорганическое соединение ...

СОЕДИНЕНИЕ МАЛОНОНИТРИЛА В КАЧЕСТВЕ ПЕСТИЦИДОВ

... 1. Соединение малононитрила, представленное формулой(I) где любой из X1, X2, X3 и X4 представляет собой CR100, (где R100 представляет собой группу, представленную формулой где R1 представляет собой C1-C5 алкил, необязательно замещенный одним или несколькими галогенами, C2-C5 алкенил, необязательно замещенный одним или несколькими галогенами, C2-C5 алкинил, необязательно замещенный одним или несколькими галогенами, или водород, R2 представляет собой C1-C5 алкил, необязательно замещенный одним или несколькими галогенами, C1-C5 алкокси, необязательно замещенный одним или несколькими галогенами, C2-C5 алкенил, необязательно замещенный одним или несколькими галогенами, C2-C5 алкинил, необязательно замещенный одним или несколькими галогенами, циано или водород, каждый из R3 и R4 представляет собой C1-C5 алкил, необязательно замещенный одним или несколькими галогенами, C2-C5 алкенил, необязательно замещенный одним или несколькими галогенами, C2-C5 алкинил, необязательно замещенный одним или несколькими ...

СПОСОБ ДЕФОЛИАЦИИ РАСТЕНИЙ ХЛОПЧАТНИКА

Способ дефолиации растений хлопчатника, включающий обработку посевов смесью химических веществ с последующей уборкой хлопка - сырца, отличающийся тем, что при созревании 20-30% коробочек посевы опрыскивают ПАБК, а спустя 10-15 дней в период созревания 50-60% коробочек проводят обработку посевов смесью дефолиантов басты и реглона в количестве 1,5-2 кг/га каждого.

СМЕСИ ФУНГИЦИДНЫХ АКТИВНЫХ ВЕЩЕСТВ

... 1. Смеси активных веществ, содержащие, как минимум, одно соединение по формуле и (1) производную триазола по формуле в которой Х обозначает хлор или фенил; Y обозначает или и/или (2) производную триазола по формуле и/или (3) производную анилина по формуле в которой R1 обозначает водород или метил, и/или (4) N-[1(4-хлор-фенил)-этил]-2, 2-дихлор-1-этил-3-метил-циклопропан-амид карбоновой кислоты по формуле и/или (5) цинк-пропилен-1,2-бис-(дитиокарбамидата) по формуле и/или (6) как минимум, один тиокарбамат по формуле где Me обозначает Zn или Mn, или смесь Zn и Mn, и/или (7) производную анилина по формуле и/или (8) соединения по формуле и/или (9) производную бензотиадиазола по формуле и/или (10) 8t-бутил-2-(N-этил-N-n-пропил-амино)-метил-1,4-диоксаспиро[5,4]-декана по формуле и/или (11) соединения по формуле и/или (12) соединения по формуле и/или (13) соединения по формуле и/или (14) производную цианоксима по формуле и/или (15) производную пиримидина по формуле в которой R2 обозначает метил ...

ПРОТИВОМИКРОБНОЕ ПОКРЫТИЕ И СПОСОБ ЕГО ФОРМИРОВАНИЯ

Изобретение относится к композициям противомикробного покрытия. Описан состав противомикробного покрытия, содержащий:(i) силан со структурой (1),(ii) пероксотитановую кислоту и золь пероксо-модифицированного анатаза, а также(iii) триэтаноламин,при этом R1, R2 и R3 выбраны из группы, состоящей из -ОН и -O-алкила, a R4 выбран из группы, состоящей из -O-алкила и замещенного -алкила, в том числе γ-хлор-пропила, γ-амино-пропила и замещенного солью четвертичного аммония алкила. Также описан способ формирования противомикробного покрытия на поверхности. Технический результат: предложена покрывающая композиция противомикробного действия. 2 н. и 18 з.п. ф-лы, 15 ил.

Средство для повышения зимостойкости и морозостойкости растений

Изобретение относится к химическим средствам, воздействующим на рост и развитие растений, в частности повышающим их зимо- и морозостойкость, и может найти применение в сельском хозяйстве. Цель изобретения - повышение эффективности воздействия на зимо- и морозостойкость растений. Согласно изобретению в качестве средства, повышающего зимо- и морозостойкость растений используют полиоксиалкиленорганосилокса- новый блок-сополимер с вязкостью 350-5000 сСт. Указанные сополимеры ранее использовались в качестве стабилизаторов пенсуретанов. Применение указанного полиоксиалкиленорганосилоксанового блок-сополимера обеспечивает защиту растений при температуре до -40°С и хорошую перезимовку озимых. Криопротектор может быть включен в составы для обработки семян или использован как таковой для обработки растений перед зимовкой. 4 табл.

Производные арилпропилморфолина, обладающие фунгицидной активностью

Использование: в качестве вещества, обладающего фунгицидной активностью. Сущность изобретения: продукт-производные эрилпропил- морфолина ф-лы 1, R-C -С или 1, Y-C -С дихлорлиридил , нитропиридиа пиримидинил - 2, Si(CHJ D, D-Ct-C Реагент 1:4 - 3 - (4 - гидро- ксифенил) - 2 - метилпропил -2.6- диметилмор- фопии Реагент 2: G-(CH ) -у. где G-галоген Условия реакции: нагревание. 3 табл. Структурная формула1 сн 3Ьл О N-CH - CH(R)- CH Ь 2 сн (X ...

CПOCOБ PEГУЛИPOBAHИЯ POCTA PACTEHИЙ

Способ сплошного уничтожения растительности

Средство,проявляющее гербицидные свойства и влияющие на рост растений

Antimikrobielle und fungizide Zusammensetzungen enthaltend Siliziumverbindungen, und ihre Verwendung in der Landwirtschaft und in Gartenbau

N-Phenylpyrazolderivate

Neue Pflanzenschutzmittel-Formulierungen

Organosilicium quaternäre antimicrobische Ammonium-Verbindungen.

13-SUBSTITUIERTE DERIVATE VON AVERMECTIN-AGLYCONEN.

Wasser-Fäulnis verhütende Zusammensetzung.

Fungizide Verfahren, Verbindungen und Zusammensetzungen die Benzophenone enthalten

Glutarimide.

SCHAEDLINGSBEKAEMPFUNGSMITTEL

Ortho-substituierte Benzylester von Cyclopropancarbonsäuren.

VERFAHREN ZUR BEKÄMPFUNG VON SCHÄDLINGEN DURCH ANWENDUNG CYCLISCHER POLYSILOXANE

Substituted diphenyl ethers

Novel substituted diphenyl ethers of the formula in which R<1>, R<2>, R<3>, R<4>, R<5>, Y, m and n have the meaning given in the description, a plurality of processes for the preparation of the novel substances, and their use as herbicides. Novel intermediates and processes for their preparation.

PESTIZIDE MITTEL

Novel acrylic acid amides

The invention relates to novel acrylic acid amides of the formula in which A, B, R<1> and Q are as defined in the text, to processes for their preparation, and to fungicidal compositions which are characterised in that they contain compounds of the formula (I).

Plant fungicidal compositions

There is provided a fungicidal composition particularly for cereal crops, which comprises as active ingredient a compound of general formula: in which: X is N, CH or CCH3; Q1 and Q2 represent hydrogen atoms or methyl groups; and R1, R2 and R3 represent alkyl, naphthyl or optionally substituted phenyl, or R2 and R3 are OH or alkoxy; and an aliphatic alcohol alkoxylate, for example an ethoxylate, with an average of 5-9 ethylene oxide units per molecule, of a C9-15 aliphatic alcohol, as an activity enhancing adjuvant. ...

Chemical compounds

Formulation

N-substituted-tetrahydrothiazines and their use as pesticides

N-substituted 2- (nitromethylene)-tetrahydro-2H-1,3- thiazines of the following formula have pesticidal, especially insecticidal, activity: in which R represents an alkyl or alkenyl group of up to 26 carbon atoms; or an alkyl group substituted by one or more halogen atoms, or by an alkoxy, alkoxycarbonyl, alkanoyloxy, oxobicycloalkyl, cycloimido, optionally substituted phenyl or phenoxy, or trialkylsilyl group, or by a quaternary ammonium group of formula: Q<->R3<1>N<+>- in which each group R<1> is an alkyl group and Q<-> is a monovalent anion; and n is 0 or 1.

N-SUBSTITUTED-TETRAHYDROTHIAZINES AND THEIR USE AS PESTICIDES

MORPHOLINYL SILANES & USE FOR CONTROL OF PLANT DISEASES CAUSED BY FUNGI

SUBSTITUTED CARBAMATES PREPARATION THEREOF AND USE THEREOF AS INSECTICIDES

Pesticidal compositions containing silicon compounds.

Pest cidal compo ition

Novel insecticidal 2,4 diaminoquina-zolines

Pyrimidine derivatives.

There are described ...

Insecticidal 5-substituted-2,4-diaminopyrimidine derivatives.

An insecticidal composition comprising, in admixture with an agriculturally acceptable carrier, an insecticidally effective amount of compound of the formula: whereinr is (a)hydrogen, straight or branched chain alkyl, cycloalkyl,polycycloalkyl, cyano, morpholinly, alkylsilane, arylsilane, phenyl, or substituted-phenyl-phenyl of the formula: ...

Fungicides.

Compounds of formula ...

Fluorobenzyl esters.

This invention ...

Pestcidal compounds.

Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2]-octanes and bicyclo-[2,2,3]-nonanes, having 2 or 3 ring hetero atoms selected from 0, s and n substituted at the 1-position by a carbocyclic group other than an alkynylphenyl group, and substituted at the 4 position and optionally substituted at the 3 and/or 5 position, are valuable pesticides, particularly insecticides and acaracides. Various cyclisation processes are disclosed to form the various bicyclo ring systems.

PESTICIDAL COMPOUNDS

Carboxymethlcyclopropane derivatives.

Novel 2-(2-chloro-2-fluorocyclopropyl)-acetic acid derivatives of formula i wherein x is oxygen or -nr-, y is hydrogen, or is c1-c20alkyl, c-c7cycloalkyl, c3-c20alkenyl, c3-c20alkynyl, benzyl or aryl, each of which is unsubstituted or substituted, and r is hydrogen or c1-c6alkyl, can be used as pesticides. Especially insects and arachnids can be controlled.

Novel insecticidal 2,4-diaminoquinazolines.

Novel quinazolines having the structure ...

Pesticidal compounds.

The present invention provides a class of novel substituted ...

New methoxyacrylic ester-and methyloxim glyoxylic acid ester derivatives, their preparation and their use as pesticides.

Compounds of formula (i)and the isomers, and isomer mixtures thereof, which are possible, in which either a)x is an n atom and y is or11 or n(r12)r13, or b)x is ch and y is or11, and in which furthermore: r11 is c1-c4alkyl; r12 and r13, independently, are hydrogen or c1-c4alkyl; a is an o atom or the group nr4; r1 is hydrogen, c1-c4alkyl, halo-c1-c4alkyl, cyclopropyl, cyano or methylthio; r2 is hydrogen, c1-c6alkyl, c3-c6cycloalkyl, a group (i), a group (ii), or thienyl; r3 is hydrogen, c1-c6alkyl, c1-c6haloalkyl having 1 to 5 halogen atoms, c1-c4alkoxy-c1-c2alkyl, c2-c4alkeny-c1-c2alkyl, which is unsubstituted or substituted by 1 to 3 halogen atoms, c2-c4alkynyl-c1-c2-alkyl, c3-c6cycloalkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, c3-c6-cycloalkyl-c1-c4alkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, cyano-c1-c4alkyl; c1-c4alkoxycarbonyl-c1-c2alkyl, c1-c4alkoxycarbamoyl-c1-c2alkyl, phenyl-c1-c3alkyl which is unsubstituted or substituted by halogen ...

Pestcidal compounds.

Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2]-octanes and bicyclo-[2,2,3]-nonanes having 2 or 3 ring hetero atoms selected from o, s and n, substituted at the 1-position by a 4-alkynylphenyl group and at the 4-position and optionally at the 3 and/or 5-position are valuable pesticides, particularly insecticides and acaracides. The compounds may be prepared by reacting an alkyne with the corresponding 4-iodophenyl substituted compound or by debromination of the corresponding 4-dibromomethylphenyl substituted compound.

Insecticidal substituted-2,4-diaminoquinazolines.

There is provided an insecticidal composition comprising, in admixture with an agriculturally acceptable carrier, an insecticidally effective amount of a diaminoquinazole compopund of the formula: ...

Pesticidal compositions containing oxadiazine derivatives

Fungicides for the control of take-all disease of plants.

This invention relates to a method for the control of Take-All disease (Gaeumannomyces species) in plant by applying a fungicidal compound, 4,5-dimethyl-N-2-propenyl-2(trimethylsilyl)-3-thiophene carboxamide in an agronomically acceptable carrier.

Synergistic Insecticide and acaricide compositions containing insect-pathogenic fungus.

Novel synergistic compositions for controlling insects and Acarina The invention relates to insecticidal and acaricidal compositions of silafluofen and at least one entomopatho-genic fungus, such as, for example, Beauveria bassiana. ' ...

Pesticidal compositions containing silicon compounds

The present invention deals with pesticidal compositions comprising as the active component a silicon ester of formula (I) , a method for controlling insects, mites nematodes and fungi, by the application of such a composition. The invention is further directed to a method for the preparation silicon esters of formual(I) and some such novel compounds.

Fungicides for the control of take-all disease of plants

PYRIMIDINE DERIVATIVES

Novel synergistic compositions for controlling insects and acarina

PESTICIDAL COMPOUNDS

Pesticidal compounds.

... 3-substituted 2,6,7-trioxabicyclo[2,2,2]-octanes, also substituted in the 1 and 4 position and optionally substituted in the 5 position are valuable pesticides, particularly insecticides and acaracides. Various methods of preparation are disclosed including condensation of an ortho-carboxylate with an appropriately substituted 2-hyrdoxymethyl-propane-1,3-diol.

PESTICIDAL COMPOUNDS

Pesticides

Insecticidal substituted-2,4-diaminoquinaz olines

Pest cidal compo ition

CARBOXYMETHYLCYCLOPROPANE DERIVATIVES

Novel insecticidal 2,4 diaminoquina-zolines

FUNGICIDES

Nitrogen-containing heterocyclic compound and agricultural fungicide

PESTICIDAL COMPOUNDS

Intecticidal 5-substituted-2, 4-diaminopyrimidine derivatives

Insecticidal n-(substituted phenyl) methyl) piperidines

Compounds of the following structure,the corresponding n-oxides and agriculturally acceptable salts, are disclosed as effective insecticides:.....In which q is selected from hydrogen,hydroxy, and fluorine; r is selected from a heteroaryl having5 or 6 ring atoms, and .....In which v is hydrogen,halogen.ALkyl,haloalkyl,or alkoxy; w and x are independently selected from a wide variety of substituents, y and z are independently selected form hydrogen and alkoxy; w and x are taken together may be -och2ch2o-,-ch2c[ch3]20-,or -oc[ch3]20-;r1 and r2 are independently selected from phenyl substituted with halogen,alkyl, haloakyl, haloalkoxy, alkysulfonyloxy, and haloalkysulfonyloxy; and n is 1,2,or 3;with the proviso that each aliphatic moiety contains not more than 6 carbon atoms, halogen means chlorine ofr fluorine, and each alkyl substituent on an amino nitrogen contains 1 to 3 carbon atoms. The manner of preparing these compounds is also disclosed.

Nitrogen-containing heterocyclic compound and agricultural fungicide.

Fungicidal compositions containing derivatives nicotinic, new derivatives nicotinic and their preparation.

Pesticides compositions.

Insecticidal 5-substituted-2, 4-diaminopyrimidine derivatives

Pyrimidine derivatives.

Use of acyl urea compounds for controlling endoparasites and ectoparasites of warm-blooded animals.

Esters of fluorobenzyle their method of insecticidal composition preparation the container and their application to the insecticidal fight

Pesticidal compositions containing silicon compounds.

New pentagonal heterocycles containing of nitrogen, their processes of production like their use as pesticides.

Plant microbiocidal compound and method.

Insecticidal n-(substituted arylmethyl)-4-Äbis(substituted phenyl)methylÜpiperidines

Pesticidal method using N-phenylpyrazoles.

New esters of related acids cyclopropanecarboxylic to the acid pyrethric, their method of preparation and their application to the fight against the parasites.

New derivatives of the 2,2-dimethyl acid bearing carboxylic cyclopropane in 3 a saturated halogenous chain, their method and intermediaries of preparation, their application like pesticides and compositions containing them.

Novel formulations of agricultural pesticides

phytopharmacological Halogéno-éthyl-silanes and products which contain some.

New synergistic agents for the fight against the insects and the acarina

N-substitued-tetrahydrothiazines, process for their preparation, and their use as pesticides.

Heterocyclic pentalene derivatives for use in combating microorganisms.

Weedkillers of the type sulfonylurée, their preparation, compositions the container and their use.

Derivatives of N-phenylpyrazoles.

Pesticides

Nitrogen-containing heterocyclic compound and agricultural fungicide.

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di- tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

Host materials for phosphorescent oleds

Novel aryl silicon and aryl germanium host materials are described. These compounds improve OLED device performance when used as hosts in the emissive layer of the OLED.

PLANT DISEASE CONTROLLING COMPOSITION AND USE THEREOF

A plant disease controlling composition is provided containing a pyridazine compound represented by formula (I): 2. The plant disease controlling composition according to claim 1 , wherein a weight ratio of the pyridazine compound to the azole compound is in a range of 0.1/1 to 10/1.4. The method for controlling plant diseases according to claim 3 , wherein a weight ratio of the pyridazine compound to the azole compound is in a range of 0.1/1 to 10/1.5. The method for controlling plant diseases according to claim 3 , wherein the plant or soil for growing a plant is wheat or soil for growing wheat.6. The method for controlling plant diseases according to claim 4 , wherein the plant or soil for growing a plant is wheat or soil for growing wheat. The present invention relates to a plant disease controlling composition and use thereof.Conventionally, many compounds for controlling plant diseases have been developed and put into practical use (see, for example, Patent Literature 1, Patent Literature 2).An object of the present invention is to provide a composition having an excellent efficacy in controlling plant diseases.The present invention primarily provides a plant disease controlling composition containing a pyridazine compound represented by the following formula (I) and at least one azole compound selected from the following group (A). The composition has an excellent efficacy in controlling plant diseases.More specifically, the present invention is as follows.[1] A plant disease controlling composition, containing a pyridazine compound represented by formula (I):wherein Rrepresents a chlorine atom, a bromine atom, a cyano group or a methyl group, and Rrepresents a hydrogen atom or a fluorine atom, and at least one azole compound selected from Group (A).Group consisting of propiconazole, prothioconazole, triadimenol, prochloraz, penconazole, tebuconazole, flusilazole, diniconazole, bromuconazole, epoxiconazole, difenoconazole, cyproconazole, metconazole, ...

EPOXYSILICONE CONDENSATE, CURABLE COMPOSITION COMPRISING CONDENSATE, AND CURED PRODUCT THEREOF

There is provided an epoxy group-containing silicone condensate that yields cured products with excellent transparency, thermal resistance and gas barrier properties. An epoxysilicone condensate which is the product of hydrolytic condensation of an epoxy group-containing alkoxysilane compound represented by formula (1): 2. The epoxysilicone condensate according to claim 1 , wherein Rto Rin formula (1) are all hydrogen.3. A curable composition comprising the epoxysilicone condensate according to .4. A cured product of the curable composition according to .5. An optical element comprising the cured product according to as an encapsulant.6. An electronic component comprising the cured product according to as an encapsulant.7. A curable composition comprising the epoxysilicone condensate according to .8. A cured product of the curable composition according to .9. An optical element comprising the cured product according to as an encapsulant.10. An electronic component comprising the cured product according to as an encapsulant. The present invention relates to an epoxysilicone condensate with an alicyclic epoxy group in the molecule, a curable composition comprising the condensate, and a cured product thereof.Epoxy resins have been commonly used in the past as encapsulants for light emitting diode (LED) elements and semiconductor chips, from the viewpoint of adhesion with the substrates on which such parts are mounted, as well as toughness and gas barrier properties.When epoxy resins are used as encapsulants, however, the thermal resistance and light resistance of such resins being inadequate, coloration of the encapsulant is observed with blue and white LEDs that have high heat release and light energy, and thus the performance of such LED elements is significantly reduced.Much research is therefore being conducted on the use of silicone resins with excellent thermal resistance and light resistance, as LED encapsulants (see Patent Documents 1 and 2, for example). ...

SELENIUM-BASED BIOCIDAL FORMULATIONS AND METHODS OF USE THEREOF

Biocidal compositions containing organoselenium compounds are disclosed, as well as methods of producing and using same. 2. The composition of claim 1 , wherein the biocidal composition is permanently attached to the substrate claim 1 , whereby the biocidal composition is substantially unable to leach from the substrate.3. The composition of claim 1 , wherein the biocidal composition is effective against at least one of a gram positive bacterial strain claim 1 , a gram negative strain claim 1 , a virus claim 1 , a fungus claim 1 , an algae claim 1 , and a mold.4Staphylococcus aureusPseudomonas aeruginosa.. The composition of claim 2 , wherein the biocidal composition is effective against at least one gram positive bacterial strain and at least one gram negative strain claim 2 , wherein the gram positive strain is and the gram negative strain is5. The composition of claim 1 , wherein the biocidal composition is effective against at least one gram positive bacterial strain claim 1 , at least one gram negative strain claim 1 , at least one virus claim 1 , at least one fungus claim 1 , at least one algae claim 1 , and at least one mold.6. The composition of claim 2 , wherein the biocidal composition inhibits formation of bacterial biofilms on the substrate.7. The composition of claim 1 , wherein the selenium compound of the biocidal composition is present in a range of from about 0.01 micrograms to about 100 micrograms of elemental selenium per square centimeter of surface area.8. The composition of claim 1 , wherein the grafting agent is a methacrylate compound.9. The composition of claim 8 , wherein the biocidal composition is diselanediylbis(2-hydroxypropane-3 claim 8 ,1-diyl)bis(2-methylacrylate).10. The composition of claim 1 , wherein the biocidal composition is 3 claim 1 ,3′-diselanediylbis(propane-1 claim 1 ,2-diol).11. The composition of claim 1 , wherein the grafting agent is an acrylate polymer claim 1 , and wherein the biocidal composition is non-covalently ...

ANTIMICROBIAL POLYMERIC COMPOSITIONS

A compound having the formula: 3. A polymer , comprising a polymerization product of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(A) the compound of ;'}(B) one or more of an isocyanate, diisocyanate, or combination thereof;(C) optionally, a diol or diamine chain extender; and(D) optionally, a diol selected from the group polydimethylsiloxane diol, polytetramethylene oxide diol, polypropylene oxide diol, polyethylene oxide diol, polybutadiene diol, polyisobutylene diol, perfluorinated diol or a combination of two or more thereof.10. The composition of claim 9 , which is a blend of (a) and (b).19. A method claim 9 , comprising: (a) at least one selected from the group consisting of polyurethane polymer, polyurethane copolymer, or a combination thereof; and', '(b) at least one selected from the group consisting of non-polar solvent, pentane, cyclopentane, hexane, cyclohexane, benzene, toluene, 1,4-dioxane, chloroform, diethyl ether, polar aprotic solvent, tetrahydrofuran, dichloromethane, ethyl acetate, acetone, dimethylformamide, acetonitrile, dimethyl sulfoxide, propylene carbonate, or a combination thereof; and', '(c) at least one selected from the group consisting of polar protic solvent, water, methanol, ethanol, propanol, isopropanol, n-butanol, formic acid, or a combination thereof;, 'contactingand thereafter separating, to produce a purified polyurethane polymer, polyurethane copolymer, or a combination thereof.20. A method for making a polymer claim 19 , comprising the method of .21. A polymer claim 19 , produced by the method of .22. An article or device claim 3 , comprising the polymer of on a surface thereof.23. An article or device claim 7 , comprising the composition of on a surface thereof.24. An article or device claim 9 , comprising the composition of on a surface thereof.25. An article or device claim 15 , comprising the polymer of on a surface thereof.26. A method for killing a microbe claim 17 , comprising contacting said microbe with the ...

Antibacterial Agent, Substrate Surface Treatment Method Using The Same, Antibacterial Agent Composition, And Substrate Surface Treatment Method Using The Same

[Problem] To provide an antibacterial agent which can be limited to the required location on the surface of a material without mixing and has excellent antibacterial, antifungal and antiviral effects even at low concentrations of the active component without elution or volatilization. 8. A curable antibacterial agent as claimed in claim 7 , containing a cross-linking agent claim 7 , characterized in that the resin is cross-linked by a cross-linking agent having one or more kinds of groups selected from isocyanate group claim 7 , hydroxyl group claim 7 , mercapto group claim 7 , carboxyl group claim 7 , amino group claim 7 , epoxy group claim 7 , alkenyl group claim 7 , alkynyl group claim 7 , acryloyl group claim 7 , methacryloyl group claim 7 , chlorosilyl group claim 7 , alkoxysilyl group and hydrosilyl group.9. A substrate surface treatment method characterized by applying or attaching an antibacterial agent as claimed in to a substrate surface thereby forming a film.12. A substrate surface treatment method as claimed in claim 1 , characterized in that the film of an antibacterial agent as discussed in is formed after further adding a cross-linking agent.13. A substrate surface treatment method as claimed in claim 12 , characterized by heating the film to cause polymerization or cross-linking thereby curing the film.14. A substrate surface treatment method as claimed in claim 12 , characterized by irradiating the film with light to cause polymerization or cross-linking thereby curing the film.15. A method for producing an antibacterial member claim 9 , characterized by conducting a surface treatment according to a surface treatment method as claimed in .22. An antibacterial agent composition as claimed in claim 20 , further containing a cross-linking agent having one or more kinds of groups selected from isocyanate group claim 20 , hydroxyl group claim 20 , mercapto group claim 20 , carboxyl group claim 20 , amino group claim 20 , epoxy group claim 20 , alkenyl ...

PEST CONTROLLING COMPOSITION AND METHOD FOR CONTROLLING PEST

The present invention provides a composition having an excellent controlling activity on a pest. The composition comprising a compound represented by Formula (1) and one or more pyrethroid compound(s) selected from Group (A) shows an excellent controlling activity on a pest. Group (A): a group consisting of acrinathrin, bifenthrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lamda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, etofenprox, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, halfenprox, permethrin, protrifenbute, silafluofen, tefluthrin and tralomethrin 2. The pest controlling composition according to claim 1 , wherein the weight ratio of the compound represented by Formula (1) to the pyrethroid compound(s) is from 0.0125/1 to 500/1.3. The pest controlling composition according to or claim 1 , wherein the compound represented by Formula (1) has R-absolute configuration.5. The method according to claim 4 , wherein the compound of Formula (1) and the pyrethroid compound(s) are applied to a seed.6. The method according to or claim 4 , wherein the weight ratio of the compound represented by Formula (1) to the'pyrethroid compound(s) is from 0.0125/1 to 500/1.7. The method according to claim 4 , wherein the compound represented by Formula (1) has R-absolute configuration. The present invention relates to a pest controlling composition and a method for controlling a pest.Hitherto, there has been provided compounds as an active ingredient for a composition for controlling a pest (see e.g., The Pesticide Manual—15th edition (BCPC published) ISBN 1901396188; and SHIBUYA INDEX (Index of Pesticides) 13th Edition 2008 (SHIBUYA INDEX RESEARCH GROUP published) ISBN 9784881371435).Also there has been provided a compound of Formula (1):(see e.g., WO 95/27693 pamphlet and WO 02/10101 pamphlet).An object of the present invention is ...

BIOCIDAL COMPOSITION AND METHOD

An aqueous biocidal composition comprising: (a) a compound of formula (II): or a derivative salt thereof wherein L is a linking group; each of R, Rand Ris independently selected from an optionally substituted alkyl, alkenyl, aryl or alkoxy group; Ris oxygen or an optionally substituted alkyl, alkenyl or aryl group; each of Rand Ris an optionally substituted alkyl, alkenyl or aryl group; and n is 0 or 1; (b) a hydrocarbyl saccharide compound; and (c) at least one cationic biocide; wherein the molar ratio of component (b) to component (a) is at least 0.5:1. 2. An aqueous biocidal composition according to wherein each of R claim 1 , Rand Ris a Cto Calkoxy group.3. An aqueous biocidal composition according to wherein L is a group of formula (CH)wherein n is from 2 to 5.4. An aqueous biocidal composition according to wherein Ris a Cto Calkyl group.5. An aqueous biocidal composition according to wherein each of Rand Ris a fluoroalkyl group having 6 to 16 carbon atoms.6. An aqueous biocidal composition according to wherein Ris a Cto Calkyl group and Ris a Cto Calkyl group.8. An aqueous biocidal composition according to wherein component (c) comprises a quaternary ammonium salt.9. An aqueous biocidal composition according to wherein component (c) comprises guanidine based compound.10. An aqueous biocidal composition according to which comprises at least 90 wt % water.11. An aqueous biocidal composition according to which comprises one or more non-ionic surfactants.12. A method of combating a pathogen at a locus claim 1 , the method comprising applying to the locus a composition as claimed in .13. A method according to wherein the pathogen is selected from bacteria claim 12 , viruses claim 12 , fungi claim 12 , prions claim 12 , algae and mixtures thereof.14. A packaged biocidal composition comprising a composition according to and means for applying the composition to a locus. The present invention relates to biocidal compositions and to methods and uses relating thereto. ...

ANTIMICROBIAL PARYLENE COATINGS AND METHODS OF DEPOSITING SAME

Antimicrobial parylene coatings and methods for their vapor-phase deposition. 1. A method of forming an antimicrobial parylene coating , comprising:immobilizing an antimicrobial agent on a parylene film through molecular attachment, interaction or covalent bonding.4. The method of claim 1 , wherein the antimicrobial agent comprises octadecyldimethyl(3-trimethoxysilylpropyl) ammonium chloride claim 1 , N claim 1 ,N-didecyl-N-methyl(3-trimethoxysilylpropyl) ammonium chloride claim 1 , or a similar compound.5. The method of claim 4 , wherein the antimicrobial agent comprises N claim 4 ,N-didecyl-N-methyl(3-trimethoxysilylpropyl)ammonium chloride.6. The method of claim 1 , wherein the parylene film and the antimicrobial agent are deposited simultaneously on a substrate.7. The method of claim 1 , wherein the parylene film is deposited on a substrate prior to introduction of the antimicrobial agent.8. The method of claim 1 , further comprising depositing parylene on the immobilized antimicrobial agent.9. The method of claim 1 , further comprising dissolving the antimicrobial agent in a carrier solvent prior to immobilization.10. The method of claim 1 , wherein the substrate comprises a medical device.11. The method of claim 10 , further comprising pretreating the substrate prior to deposition.12. A coating claim 10 , comprising:a parylene material; andan antimicrobial agent immobilized on the parylene material.15. The coating of claim 12 , wherein the antimicrobial agent comprises octadecyldimethyl(3-trimethoxysilylpropyl)ammonium chloride claim 12 , N claim 12 ,N-didecyl-N-methyl(3-trimethoxysilylpropyl)ammonium chloride claim 12 , or a similar compound.16. The coating of claim 15 , wherein the antimicrobial agent comprises N claim 15 ,N-didecyl-N-methyl(3-trimethoxysilylpropyl)ammonium chloride.17. The coating of claim 12 , wherein the coating includes a first layer comprising the parylene material claim 12 , and a second layer deposited on the first layer claim 12 , ...

ETHYNYLPHENYLAMIDINE COMPOUND OR SALT THEREOF, METHOD FOR PRODUCING SAME, AND FUNGICIDE FOR AGRICULTURAL AND HORTICULTURAL USE

An object of the present invention is to provide a novel fungicide having an excellent fungicidal activity. The compound used as the fungicide of the present invention is an ethynylphenylamidine compound or a salt thereof, the compound being represented by Formula (1): 2. The ethynylphenylamidine compound or a salt thereof according to claim 1 , wherein the ethynylphenylamidine compound is represented by Formula (1) wherein Ris hydrogen.3. The ethynylphenylamidine compound or a salt thereof according to claim 1 , wherein the ethynylphenylamidine compound is represented by Formula (1) wherein Rand Rare each Calkyl.4. The ethynylphenylamidine compound or a salt thereof according to claim 1 , wherein the ethynylphenylamidine compound is represented by Formula (1) wherein Ror Ris halogen or Calkyl.5. The ethynylphenylamidine compound according to claim 1 , wherein the ethynylphenylamidine compound is represented by Formula (1) wherein Ris hydrogen; Calkyl optionally substituted on the alkyl group with one or more substituents independently selected from the group consisting of Calkoxy claim 1 , hydroxy claim 1 , cyano claim 1 , and phenyl; Ccycloalkyl; phenyl optionally substituted on the phenyl ring with one to five substituents independently selected from the group consisting of halogen claim 1 , Calkyl claim 1 , Chaloalkyl claim 1 , Calkoxy claim 1 , and phenoxy; a heterocyclic group; or —(CH)n-Si(R)(R)(R) wherein R claim 1 , R claim 1 , and R claim 1 , and n are as defined in .10. An agricultural and horticultural fungicide comprising the ethynylphenylamidine compound or a salt thereof according to as an active ingredient. The present invention relates to an ethynylphenylamidine compound or a salt thereof, a method for producing the same, and an agricultural and horticultural fungicide.Various compounds with a fungicidal activity for agricultural and horticultural use are known as compounds having an amidino group on the phenyl ring. Many of these compounds have a ...

5-HALOGENOPYRAZOLE(THIO)CARBOXAMIDES

The present invention relates to novel 5-halogenopyrazole(thio)carboxamides, their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein T represents an oxygen atom.3. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methylsulfonyl claim 1 , ethylsulfonyl claim 1 , n- or isopropylsulfonyl claim 1 , n- claim 1 , iso- claim 1 , sec- or tert-butylsulfonyl claim 1 , methoxymethyl claim 1 , methoxyethyl claim 1 , ethoxymethyl claim 1 , ethoxyethyl claim 1 , trifluoromethylsulfonyl claim 1 , trifluoromethoxymethyl or formyl.4. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methoxymethyl claim 1 , or formyl.5. A compound according to claim 1 , wherein Rrepresents hydrogen or chlorine.6. A compound according to claim 1 , wherein s or u represents 1.7. A compound according to claim 1 , wherein Rand Rindependently of one another represents hydrogen claim 1 , fluorine claim 1 , chlorine claim 1 , methyl claim 1 , ethyl claim 1 , trifluoromethyl claim 1 , difluoromethyl claim 1 , fluoromethyl claim 1 , trichloromethyl claim 1 , dichloromethyl claim 1 , chloromethyl claim 1 , chlorofluoromethyl claim 1 , fluorodichloromethyl claim 1 , difluorochloromethyl claim 1 , pentafluoroethyl claim 1 , 1-fluoroethyl claim 1 , 2-fluoroethyl claim 1 , 2 claim 1 ,2-difluoroethyl claim 1 , 2 claim 1 ,2 claim 1 ,2-trifluoroethyl claim 1 , 2-chloro-2-fluoroethyl claim 1 , 2-chloro-2 claim 1 ,2-difluoroethyl claim 1 , 2-chloro-2 claim 1 ,2-difluoroethyl claim 1 , 2-dichloro-2-fluoroethyl claim 1 , 2 claim 1 ,2 claim 1 ,2-trichloroethyl claim 1 , 1-chlorobutyl claim 1 , heptafluoro-n-propyl or heptafluoroisopropyl.8. A compound according to claim 1 , wherein Rrepresents represents hydrogen claim 1 , fluorine claim 1 , chlorine claim ...

Beds and bed accessories having an antimicrobial treatment

A hospital bed is provided that may include a support structure having a plurality of surfaces coated with an antimicrobial treatment, which may include a silane quaternary ammonium salt and isopropyl alcohol. The silane quaternary ammonium salt may include an unreacted organofunctional silane to promote bonding to the surfaces of the bed, such as 3-(trimethoxysilyl) propyldimethyloctadecyl ammonium chloride. Bed accessories, such as tables and IV stands, may also include the antimicrobial treatment. A method is also provided for coating these articles with the antimicrobial treatment.

5-Halogenopyrazolecarboxamides

The present invention relates to novel 5-halogenopyrazole(thio)carboxamides, their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein T represents an oxygen atom.3. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methylsulfonyl claim 1 , ethylsulfonyl claim 1 , n- or isopropylsulfonyl claim 1 , n- claim 1 , iso- claim 1 , sec- or tert-butylsulfonyl claim 1 , methoxymethyl claim 1 , methoxyethyl claim 1 , ethoxymethyl claim 1 , ethoxyethyl claim 1 , trifluoromethyl-sulfonyl claim 1 , trifluoromethoxymethyl or formyl.4. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methoxymethyl claim 1 , or formyl.6. A compound according to claim 1 ,{'sup': '1', 'wherein Rrepresents hydrogen, fluorine, chlorine, methyl or trifluoromethyl.'}7. A compound according to claim 1 ,{'sup': 1', '1, 'wherein Q and Rtogether with the carbon atoms to which said Q and Rare attached represent a 5- or 6-membered carbocyclic ring which is optionally mono-, di- or trisubstituted by methyl or a 5- or 6-membered saturated heterocyclic ring containing one oxygen atom and which is optionally mono-, di- or trisubstituted by methyl.'}14. A compound according to claim 1 , wherein X represents a single bond.15. A compound according to claim 1 , wherein Y represents oxygen claim 1 , sulfur claim 1 , N(R) claim 1 , CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , C(CH) claim 1 , CH(CH) claim 1 , CH(CH) claim 1 , C(CH)(CH) claim 1 , CH(OCH) or C(OCH).16. A compound according to claim 1 , wherein n represents 0.17. A compound according to claim 1 , wherein m represents 0.19. A fungicide composition comprising claim 1 , as an active ingredient claim 1 , an effective amount of a compound of formula (I) according to claim 1 , and an agriculturally ...

HETEROARYLPIPERIDINE AND -PIPERAZINE DERIVATIVES AS FUNGICIDES

Heteroarylpiperidine and -piperazine derivatives of the formula (I) 2. A compound according to claim 1 , in which {'sup': 3', '4', '3', '4, 'sub': 1', '6', '2', '6', '2', '6', '3', '8', '1', '6', '2', '6', '2', '6', '3', '6', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '6', '1', '4', '1', '6', '1', '6', '1', '6, 'halogen, cyano, hydroxyl, —NRR, —C(═O)NRR, nitro, C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-cycloalkyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-halocycloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C-alkenyloxy, C-C-alkynyloxy, C-C-alkylthio, C-C-alkylsulphonyl, C-C-haloalkylthio, C-C-haloalkylsulphonyl, C-C-alkoxy-C-C-alkyl, hydroxyl-C-C-alkyl, C-C-alkylcarbonyl, C-C-alkoxycarbonyl, C-C-alkylcarbonyloxy or —C(═O)H, or'}, 'A is phenyl which may contain up to two substituents, where the substituents are each independently selected from the following list substituents on carbon:', {'sup': 3', '4, 'sub': 1', '6', '2', '6', '2', '6', '3', '6', '1', '6', '2', '6', '2', '6', '3', '6', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '6', '1', '6', '1', '6, 'halogen, cyano, hydroxyl, nitro, —NRR, C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-cycloalkyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-halocycloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C-alkylthio, C-C-alkylsulphonyl, C-C-haloalkylthio, C-C-haloalkylsulphonyl, C-C-alkoxy-C-C-alkyl, hydroxy-C-C-alkyl, C-C-alkylcarbonyl, C-C-alkoxycarbonyl, C-C-alkylcarbonyloxy or phenyl,'}, 'substituents on nitrogen:', {'sub': 1', '6', '2', '6', '2', '6', '1', '6', '2', '6', '2', '6', '3', '10', '1', '6', '1', '6', '1', '4', '1', '4', '1', '6, 'C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-cycloalkyl-C-C-alkyl, C-C-haloalkylcarbonyl, phenyl, benzyl, C-C-alkylsulphonyl, C-C-haloalkylsulphonyl, phenylsulphonyl, —C(═O)H, or C-C-alkylcarbonyl.'}], 'A is a heteroaromatic radical ...

Fungicidal Composition

Synergistic fungicidal compositions are provided for use in the treatment or control of plant diseases caused by or associated with phytopathogenic fungi. The compositions comprise at least one conazole fungicide and at least one fungicidal compound which is a fungicidal volatile oil. The conazole fungicides are selected from imazalil, prochloraz, propiconazole, tebuconazole, epoxiconazole, flusilazole and metal complexes thereof. The fungicidal volatile oils are selected from fungicidal C 6 -C 12 aldehydes, fungicidal C 6 -C 12 alcohols, fungicidal C 6 -C 12 carboxylic acids and fungicidal C 6 -C 12 esters. The preferred conazole fungicides are imazalil, prochloraz and the preferred fungicidal volatile oil is n-hexanal.

ANTIMICROBIAL COMPOSITIONS AND METHODS

Methods and compositions to reduce the rate of infections in a hospital wherein a long-acting surface disinfectant is applied to pre-cleaned hard surfaces in the hospital and wherein health care workers apply a persistent hand sanitizer to their hands. The long-acting surface disinfectant contains an antimicrobial organosilane compound and an additive. The persistent hand sanitizer contains an antimicrobial agent and a treated particle. 1. An antimicrobial composition which contains:a. an antimicrobial organosilane compound 0.01-5.0 percent by weight; andb. an additive chosen from the class of additives consisting of phenol 0.01-1.5 percent by weight, o-phenylphenol 0.01-1.5 percent by weight, p-tert-Amylphenol 0.01-1.5 percent by weight, and 2-Benzyl-4-chlorophenol 0.01-1.5 percent by weight, the composition having antimicrobial activity for at least 30 days after application to a pre-cleaned hard surface.2. The composition of claim 1 , which also contains alcohol 50-80 percent by weight claim 1 , chosen from the class of alcohols consisting of ethanol claim 1 , methanol claim 1 , and propanol.3. The composition of claim 1 , in which the antimicrobial organosilane compound is selected from the group consisting of a 3-(Trimethoxysilyl)propyl dimethyl octadecyl ammonium chloride claim 1 , 3-(trihydroxysilyl)propyl dimethyl octadecyl ammonium chloride claim 1 , 1-Tetradecanaminium claim 1 ,N claim 1 ,N-dimethyl-N-(3-(trimethoxysilyl)propyl)-chloride claim 1 , and N claim 1 ,N-Didecyl-N-methyl-3-(trimethoxysilyl)propanaminium chloride.4. The composition of claim 3 , in which the organosilane compound is 0.01-1.5 percent by weight 3-(trihydroxysilyl)propyl dimethyl octadecyl ammonium chloride.5. The composition of claim 1 , in which o-phenylphenol is the only ingredient chosen from the class of additives consisting of phenol 0.01-1.5 percent by weight claim 1 , o-phenylphenol 0.01-1.5 percent by weight claim 1 , p-tert-Amylphenol 0.01-1.5 percent by weight claim 1 , and ...

POLYMER SURFACES CONTAINING HEAT LABILE COMPONENTS ADSORBED ON POLYMERIC CARRIERS AND METHODS FOR THEIR PREPARATION

Surfaces and members having one or more surfaces derived from compositions containing polymers and one or more heat labile and/or incompatible components adsorbed on carrier materials are provided. The heat labile components include materials that, unless adsorbed on a carrier, are transformed at the polymer's processing temperatures (such as for example, heat labile biocides). Incompatible components are materials that generally react or form gels, slimes or precipitates upon mixing. The carrier materials typically include inorganic and/or organic porous materials capable of remaining solid during processing temperatures. Methods for preparing the polymer surfaces and members having polymer surfaces are provided. Members include, but are not limited to, structures, articles, containers, devices, woven/nonwoven articles, remediation materials, and the like. 1. A surface comprising a polymer having a continuous solid phase , and a heat labile component/carrier combination therein , wherein:(a) the polymer has a melting temperature;(b) the heat labile component has a transformation temperature;(c) the polymer's melting temperature is greater than the heat labile component's transformation temperature;(d) the heat labile component/carrier combination is distributed throughout the polymer's continuous solid phase; and(e) the surface exhibits at least one property derived from the heat labile component.2. The surface of claim 1 , wherein said surface is included in a member selected from the group consisting of structures claim 1 , articles claim 1 , containers claim 1 , devices claim 1 , woven/nonwoven articles claim 1 , and remediation materials.3. The surface of claim 1 , wherein the heat labile component/carrier combination involves a carrier loaded with a heat labile component and the combination is encapsulated within the polymer's continuous phase.4. The surface of claim 1 , wherein the composition includes a plurality of heat labile component/carrier combinations ...

LIQUID INSECTICIDE COMPOSITION

A liquid insecticide composition is provided containing a neonicotinoid-based compound, a silicone-based surfactant, and a water-soluble organic solvent. Furthermore, a method is provided for enhancing an insecticidal effect which includes using a silicone-based surfactant in combination with a neonicotinoid-based compound as an insecticidal active ingredient. 1. A liquid insecticide composition containing a neonicotinoid-based compound , a silicone-based surfactant , and a water-soluble organic solvent.2. The liquid insecticide composition according to claim 1 ,wherein the neonicotinoid-based compound is acetamiprid.3. The liquid insecticide composition according to claim 1 ,wherein the silicone-based surfactant is polyether-modified polysiloxane.4. The liquid insecticide composition according to claim 1 ,wherein the silicone-based surfactant is polyoxyethylene-modified heptamethyltrisiloxane.6. The liquid insecticide composition according to claim 1 ,wherein the neonicotinoid-based compound is 0.1 parts by mass to 60 parts by mass; the water-soluble organic solvent is 35 parts by mass to 95 parts by mass; and the silicone-based surfactant is 1 part by mass to 15 parts by mass in the total 100 parts by mass of the neonicotinoid-based compound, the water-soluble organic solvent, and the silicone-based surfactant.7. The liquid insecticide composition according to claim 1 , further comprising a non-silicone-based nonionic surfactant.8. The liquid insecticide composition according to claim 7 ,wherein the non-silicone-based nonionic surfactant is a polyoxyalkylene block polymer.9. The liquid insecticide composition according to claim 7 ,wherein the neonicotinoid-based compound is 0.1 parts by mass to 60 parts by mass; the water-soluble organic solvent is 35 parts by mass to 95 parts by mass; and the total amount of the silicone-based surfactant and the non-silicone-based nonionic surfactant is 1 part by mass to 30 parts by mass in the total 100 parts by mass of the ...

SUBSTITUTED VINYL AND ALKINYL CYCLOHEXENOLS AS ACTIVE AGENTS AGAINST ABIOTIC STRESS IN PLANTS

The invention relates to substituted vinyl- and alkynylcyclohexenols of the general formula (I) and salts thereof 4. A compound of formula (I) and/or a salt thereof as claimed in capable of being used for increasing tolerance to abiotic stress in a plant.5. A method for treating a plant comprising applying a nontoxic amount claim 1 , effective for enhancing resistance of a plant to one or more abiotic stress factors claim 1 , of at least one compound of formula (I) and/or a salt thereof as claimed in .6. The method as claimed in claim 5 , wherein the abiotic stress factor corresponds to at least one condition selected from the group consisting of heat claim 5 , drought claim 5 , cold and drought stress claim 5 , osmotic stress claim 5 , waterlogging claim 5 , elevated soil salinity claim 5 , elevated exposure to minerals claim 5 , ozone conditions claim 5 , strong light conditions claim 5 , limited availability of nitrogen nutrients claim 5 , and limited availability of phosphorus nutrients.7. A compound of formula (I) and/or a salt thereof as claimed in capable of being used in spray application to a plant and/or a plant part in combination with at least one active ingredient selected from the group consisting of insecticides claim 1 , attractants claim 1 , acaricides claim 1 , fungicides claim 1 , nematicides claim 1 , herbicides claim 1 , growth regulators claim 1 , safeners claim 1 , substances which influence plant maturity and bactericides.8. The compound of formula (I) or a salt thereof as claimed in capable of being used in spray application to a plant and/or a plant part in combination with a fertilizer.9. The compound of formula (I) and/or a salt thereof as claimed in capable of being for applied to a genetically modified cultivar claim 1 , a seed thereof claim 1 , and/or to a cultivated area on which a cultivar grows.10. A spray solution for treatment of a plant claim 1 , comprising an amount claim 1 , effective for enhancing resistance of a plant to one ...

SUBSTITUTED 5-(CYCLOHEX-2-EN-1-YL)-PENTA-2,4-DIENES AND 5-(CYCLOHEX-2-EN-1-YL)-PENT-2-EN-4-INES AS ACTIVE AGENTS AGAINST ABIOTIC STRESS IN PLANTS

The invention relates to substituted 5-(cyclohex-2-en-1-yl)penta-2,4-dienes and 5-(cyclohex-2-en-1-yl)pent-2-en-4-ines of the formula (I) and their salts 4. A compound of formula (I) and/or a salt thereof as claimed in capable of being used for increasing tolerance to abiotic stress in a plant.5. A method for treating a plant comprising applying a nontoxic amount claim 1 , effective for enhancing resistance of a plant to one or more abiotic stress factors claim 1 , of at least one compound of formula (I) and/or a salt thereof as claimed in .6. The method as claimed in claim 5 , wherein the abiotic stress factor comprises at least one condition selected from the group consisting of heat claim 5 , drought claim 5 , cold and drought stress claim 5 , osmotic stress claim 5 , waterlogging claim 5 , elevated soil salinity claim 5 , elevated exposure to minerals claim 5 , ozone conditions claim 5 , strong light conditions claim 5 , limited availability of nitrogen nutrients claim 5 , and limited availability of phosphorus nutrients.7. A compound of formula (I) and/or a salt thereof as claimed in any of capable of being used in spray application to a plant and/or a plant part in combination with at least one active ingredient selected from the group consisting of insecticides claim 1 , attractants claim 1 , acaricides claim 1 , fungicides claim 1 , nematicides claim 1 , herbicides claim 1 , growth regulators claim 1 , safeners claim 1 , substances which influence plant maturity and bactericides.8. The compound of formula (I) and/or a salt thereof as claimed in capable of being used in spray application to a plant and/or a plant part in combination with a fertilizer.9. The compound of formula (I) and/or a salt thereof as claimed in capable of being used for application to a genetically modified cultivar claim 1 , a seed thereof claim 1 , and/or to a cultivated area on which a cultivar grows.10. A spray solution for treating a plant claim 1 , comprising an amount claim 1 , ...

TRANSITION-METAL-FREE SILYLATION OF AROMATIC COMPOUNDS

The present invention describes chemical systems and methods for silylating aromatic organic substrates, said system comprising a mixture of (a) at least one organosilane and (b) at least one strong base, said system being substantially free of a transition-metal compound, and said methods comprising contacting a quantity of the organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate; wherein said system is substantially free of a transition-metal compound. 1. A method comprising contacting an organic substrate comprising an aromatic moiety with a mixture of (a) at least one organosilane and (b) at least one strong base , under conditions sufficient to silylate the substrate; wherein said mixture and substrate are substantially free of transition-metal compounds.2. The method of claim 1 , wherein the transition-metal compound is present at less than 10 ppm claim 1 , relative to the weight of the total system.3. The method of claim 1 , wherein the mixture further comprises an optionally substituted tetraalkylethylenediamine (e.g. claim 1 , tetramethylethylenediamine) claim 1 , an optionally substituted 1 claim 1 ,10-phenanthroline derivative claim 1 , an optionally substituted 2 claim 1 ,2′-bipyridine derivatives claim 1 , or an optionally substituted 4-dimethylaminopyridine derivative.4. The method of claim 1 , that is substantially free of water claim 1 , oxygen claim 1 , or both water and oxygen.5. The method of claim 1 , wherein at least one organosilane comprises an organosilane of Formula (I) or Formula (II):{'br': None, 'sub': 4-m', 'm, '(R)Si(H)\u2003\u2003(I)'}{'br': None, 'sub': 'n', 'R—[—SiH(R)—O—]—R\u2003\u2003(II)'} n is 10 to 100; and', {'sub': 1-12', '5-20', '6-30', '6-30', '1-12', '5-20', '6-30', '6-30', '1', '20', '5', '20', '1', '20', '5', '20', '1', '20', '5', '20', '1', '20', '5', '20', '2', '20', '5', '20', '1', '20, 'each R is independently ...

Heteroarylpiperidine and -piperazine derivatives as fungicides

Heteroarylpiperidine and -piperazine derivatives of the formula (I) 115-. (canceled)18. The compound according to claim 16 , wherein{'sub': 1', '6', '1', '6, 'A is phenyl which may contain up to two substituents, where the substituents are each independently selected from the group consisting of halogen, C-C-alkyl and C-C-haloalkyl,'}or{'sub': 1', '6', '1', '6, 'A is pyrazol-1-yl which may contain up to two substituents, where the substituents are each independently selected from the group consisting of halogen, C-C-alkyl and C-C-haloalkyl.'}19. The compound according to claim 16 , wherein{'sup': '1-2', 'sub': 1', '6, 'Zis halogen or C-C-alkyl.'}20. The compound according to claim 16 , wherein{'sup': 4', '3', '4', '7', '8', '4', '3, 'sub': 2', '6', '3', '8', '1', '6', '1', '6', '1', '6', '1', '4', '1', '6', '1', '6', '1', '4', '1', '6', '1', '6', '1', '4', '2', '4', '1', '4', '2', '4, 'Zis —C(═O)OH, —C(═S)NRR, C-C-alkenylcarbonyloxy, C-C-halocycloalkylcarbonyloxy, C-C-alkylcarbonylamino, C-C-alkoxycarbonylamino, C-C-alkoxy-C-C-alkylcarbonyl, —NHC(═O)H, C-C-alkoxycarbonyl-C-C-alkoxy, —C(═NOR)R, tri(C-C-alkyl)silyloxy, C-C-haloalkylsulphonyloxy, C-C-alkylsulphonyloxy, tri(C-C-alkyl)silyl-C-C-alkynyloxy, tri(C-C-alkyl)silyl-C-C-alkynyl or -LZ, or'}{'sup': '4', 'sub': 1', '3, 'claim-text': {'sub': 2', '4', '2', '4', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3, 'C-C-alkenyloxy, C-C-alkynyloxy, C-C-alkoxy-C-C-alkylthio, C-C-alkoxy-C-C-alkylsulphinyl, C-C-alkoxy-C-C-alkylsulphonyl, C-C-alkylcarbonyloxy, or'}, 'Zis C-C-alkyl which contains 1 or 2 substituents, where the substituents are each independently selected from the following list{'sup': 4', '3', '4, 'sub': 3', '8, 'Zis a substituted hydroxyl, where the substituent is C-C-cycloalkylsulphonyl or C(═O)NRR,'}{'sup': 3', '4, 'sub': 1', '6, 'Rand Rare the same or different and are each independently hydrogen or C-C-alkyl,'}{'sup': '7', 'sub': 1', '6, 'Ris hydrogen or C-C-alkyl,'}{'sup': '8', 'sub': ...

INTERMEDIATE FOR ACENEDICHALCOGENOPHENE DERIVATIVE AND METHOD FOR SYNTHESIZING SAME

An intermediate for an acenedichalcogenophene derivative is expressed by formula (1) or formula (2). 4. The intermediate for the acenedichalcogenophene derivative according to claim 1 , wherein the boronate ester group is a pinacol boronate ester group.6. The method of synthesizing the intermediate for the acenedichalcogenophene derivative according to claim 5 , further comprisingadding a CH activation catalyst as a catalyst.7. The method for synthesizing the intermediate for the acenedichalcogenophene derivative according to claim 5 , wherein pinacol boronate ester is used for the boronate ester.9. The method for synthesizing the intermediate for the acenedichalcogenophene derivative according to claim 8 , further comprising adding an organometallic reagent. The present disclosure relates to an intermediate for an acenedichalcogenophene derivative and a method for synthesizing the same.Recently, attention has been drawn to compounds having acenedichalcogenophene as a basic skeleton such as naphthodithiophene, benzodithiophene, anthradithiophene, and the like especially as materials for organic semiconductors due to their high electron mobility, the high on/off current ratio, and the excellent storage stability (for example, Patent Literatures 1 and 2).Patent Literature 1: Unexamined Japanese Patent Application Kokai Publication No. 2009-267134Patent Literature 2: Unexamined Japanese Patent Application Kokai Publication No. 2009-267140Essentially, obtaining the organic semiconductor materials having acenedichalcogenophene as a basic skeleton relies on efficiency and selectivity of obtaining the acenedichalcogenophene derivatives. However, sufficient research has not been conducted for the compounds having the acenedichalcogenophene as the basic skeleton due to their difficulty in carrying out synthesis, and other such reasons.It is therefore an object of the present disclosure to provide intermediates for acenedichalcogenophene derivatives that are advantageous in ...

METALLOCENE COMPOUND, CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST FOR OLEFIN POLYMERIZATION CONTAINING THE SAME, AND METHOD FOR PRODUCING OLEFIN POLYMER USING CATALYST FOR OLEFIN POLYMERIZATION

The metallocene compound represented by the following general formula (I): 4. The metallocene compound according to any one of to , wherein Qis a silicon atom in the above general formula (1) , (2) , or (3).5. The metallocene compound according to any one of to , wherein Ris a hydrogen atom in the above general formula (1) , (2) , or (3).6. The metallocene compound according to any one of to , wherein Mis zirconium or hafnium in the above general formula (1) , (2) , or (3).7. The metallocene compound according to any one of to , wherein M′ is zirconium in the above general formula (1) , (2) , or (3).8. A catalyst component for olefin polymerization , comprising the metallocene compound according to any one of to .9. A catalyst for olefin polymerization , comprising the metallocene compound according to any one of to .10. A catalyst for olefin polymerization , comprising the following essential components (A) , (B) and (C):{'claim-ref': [{'@idref': 'CLM-00001', 'claims 1'}, {'@idref': 'CLM-00003', '3'}], 'Component (A): the metallocene compound according to any one of to ,'}Component (B): a compound reacting with the metallocene compound of the component (A) to form a cationic metallocene compound, andComponent (C): a fine particle carrier.11. The catalyst for olefin polymerization according to claim 10 , wherein the component (B) is an aluminoxane.12. The catalyst for olefin polymerization according to claim 10 , wherein the component (C) is silica.13. The catalyst for olefin polymerization according to claim 10 , which further comprises the following component (D):Component (D): an organoaluminum compound.14. A method for producing an olefin-based polymer claim 9 , comprising polymerizing an olefin using the catalyst for olefin polymerization according to .15. The method for producing an olefin-based polymer according to claim 14 , wherein the olefin contains at least ethylene.16. The method for producing an olefin-based polymer according to claim 15 , wherein the ...

SUBSTITUTED THIOPHENECARBOXAMIDES AND ANALOGUES AS ANTIBACTERIALS AGENTS

The present disclosure relates to substituted thiophene carboxamides and analogues thereof of formula (I) that may be used for protecting plants from bacterial diseases, in particular from bacterial diseases caused by bacteria belonging to the genus . 2. The compound of formula (I) according to wherein Ris selected from the group consisting of hydrogen atom claim 1 , C-C-alkyl claim 1 , benzyl claim 1 , benzyl substituted by hydroxyl claim 1 , C-C-alkyl substituted by a C-C-alkylsulfanyl and Ris a hydrogen atom; or Rand Rform claim 1 , together with the carbon atom to which they are linked claim 1 , a cyclopropyl.3. The compound of formula (I) according to wherein Ris selected from the group consisting of hydrogen atom claim 1 , C-C-alkyl claim 1 , C-C-haloalkyl claim 1 , C-C-cyanoalkyl claim 1 , C-C-alkenyl claim 1 , C-C-alkynyl claim 1 , C-C-cycloalkyl claim 1 , phenyl claim 1 , benzyl claim 1 , 4- claim 1 , 5- or 6-membered heterocyclyl claim 1 , —C-C-alkyl-Si(C-C-alkyl)and —C-C-alkyl-cyclopropyl.4. The compound of formula (I) according to claim 1 , wherein Ris selected from the group consisting of hydrogen atom claim 1 , C-C-alkyl claim 1 , C-C-haloalkyl claim 1 , C-C-cyanoalkyl claim 1 , C-C-alkenyl claim 1 , C-C-alkynyl claim 1 , C-C-cycloalkyl claim 1 , phenyl claim 1 , benzyl claim 1 , oxetanyl claim 1 , thietanyl claim 1 , dioxothietanyl claim 1 , oxolanyl claim 1 , oxanyl claim 1 , —C-C-alkyl-Si(C-C-alkyl)and —C-C-alkyl-cyclopropyl.5. A composition comprising at least one compound of formula (I) according to and at least one agriculturally suitable auxiliary.6. A method for controlling bacterial diseases comprising the step of applying (i) at least one compound of formula (I) according to claim 1 , or (ii) a composition comprising at least one compound of formula (I) according to and at least one agriculturally suitable auxiliary to plants claim 1 , plant parts claim 1 , seeds claim 1 , fruits or to the soil in which the plants grow. This application is a ...

METHODS FOR TREATING ARTHROPODS

Methods for treating arthropods comprising depositing at least one drop of a liquid formulation containing at least one surfactant on a solid surface of an arthropod at a contact angle sufficient to cause rapid and enhanced knockdown (KD) of the arthropod. The contact angle comprises an angle formed between a resting drop of the liquid formulation and the solid surface on which the drop rests measured, after a period of about 80 milliseconds (ms) or more from the time that a drop of the liquid formulation is deposited on the solid surface, at a contact point between a tangent line drawn on a liquid/vapor interface surface of the resting drop in contact with the solid surface and a tangent to the solid surface on which the drop rests. 1. A method for treating arthropods comprising depositing at least one drop of a liquid formulation containing at least one surfactant on a solid surface of an arthropod at a contact angle sufficient to cause rapid knockdown (KD) of the arthropod , the contact angle comprising an angle formed between a resting drop of the liquid formulation and the solid surface on which the drop rests measured , after a period of about 80 milliseconds (ms) or more from the time that a drop of the liquid formulation is deposited on the solid surface , at a contact point between a tangent line drawn on a liquid/vapor interface surface of the resting drop in contact with the solid surface and a tangent to the solid surface on which the drop rests.2. The method of wherein the contact angle is less than about 40° as measured with a Krüss DSA 100 tensiometer.3. The method of wherein knockdown (KD) of a treated arthropod occurs within about two minutes or less after the at least one drop of the formulation is deposited on the solid surface of the arthropod.4. The method of wherein the knockdown (KD) rate of treated arthropods is about 80% or greater within about two minutes or less after the at least one drop of the formulation is deposited on the solid ...

PLANT TREATMENT METHOD

A plant treatment method comprising contacting the plant with: (a) a compound of formula (I): or a derivative salt thereof wherein L is a linking group; each of R, Rand Ris independently selected from an optionally substituted alkyl, alkenyl, aryl or alkoxy group; Ris oxygen or an optionally substituted alkyl, alkenyl or aryl group; each of Rand Ris an optionally substituted alkyl, alkenyl or aryl group; (b) at least one cationic biocide; (c) a hydrocarbyl saccharide compound; and (d) a non-ionic surfactant. 2. A method according to which involves contacting the plant with a single composition comprising components (a) claim 1 , (b) claim 1 , (c) and (d).4. A method according to wherein component b) comprises a cationic biocide selected from a quaternary ammonium salt claim 1 , a guanidine based compound or a mixture thereof.5. A method according to wherein component (b) comprises a quaternary ammonium salt.7. A method according to which involves contacting the plant with an aqueous composition comprising:{'b': '2500 ppm of a compound of formula (I);', '10 to'}{'b': '2500 ppm of a hydrocarbyl saccharide compound;', '10 to'}{'b': '3000 ppm quaternary ammonium biocide;', '10 to'}{'b': '1000 ppm guanidine based cationic biocide; and', '5 to'}{'b': '1000 ppm non-ionic surfactants.', '5 to'}8. A method according to wherein the composition contacted with the plant is prepared by dilution of a concentrated composition in a ratio of from 1:1000 to 1:2.9. A method according to which involves contacting the plant with a composition which combats nematodes.10. A method according to which leads to a reduction of at least 50% in the number of nematodes present at or near to the surface after 24 hours.11. A method according to which involves contacting the plant with a composition which is effective against one or more types of bacteria and/or algae and/or fungi. The present invention relates to a method of treating plants. In particular the invention relates to methods of ...

PARAFFINIC OIL-IN-WATER EMULSIONS FOR CONTROLLING INFECTION OF CROP PLANTS BY FUNGAL PATHOGENS

This disclosure features fungicidal combinations that include a paraffinic oil and an emulsifier. The combinations can further include one or more of the following: pigments, silicone surfactants, anti-settling agents, conventional fungicides such as demethylation inhibitors (DMI) and quinone outside inhibitors (Qol) and water. The fungicidal combinations are used for controlling infection of a crop plant by a fungal pathogen. 153.-. (canceled)54. A method of controlling infection of a crop plant by a fungal pathogen , the method comprising applying a fungicidal composition to the plant , wherein the fungicidal composition comprises a paraffinic oil-in-water emulsion , the paraffinic oil-in-water emulsion including a paraffinic oil and an emulsifier.55. The method of claim 54 , wherein the crop plant is wheat claim 54 , barley claim 54 , soybean claim 54 , or corn.56. The method of claim 54 , wherein the plant is monocotyledonous.57. The method of claim 56 , wherein the plant is of the order Poaceae.58Triticum, Secale, Hordeum, Oryza, ZeaElymus.. The method of claim 57 , wherein the plant is of the genus claim 57 , or59. The method of claim 54 , wherein the fungal pathogen is of the order Pucciniales.60Puccinia.. The method of claim 59 , wherein the fungal pathogen is of the genus61Puccinia graminis, Puccinia triticinaPuccinia sriiformis.. The method of claim 60 , wherein the fungal pathogen is of the species claim 60 , or62. (canceled)63. (canceled)64Bipolaris sorokiniana, Fusarium graminearumPyrenophora triticirepentis.. The method of claim 54 , wherein the fungal pathogen is selected from the group consisting of claim 54 , and -65. (canceled)66. (canceled)67. The method of claim 54 , wherein the plant is dicotyledonous.68. The method of claim 67 , wherein the plant is of the order Fabaceae.69. The method of claim 68 , wherein the plant is of the species Glycine max.70Phakopsora.. The method of claim 67 , wherein the fungal pathogen is of the genus71Phakopsora ...

PERFORMANCE GEAR, TEXTILE TECHNOLOGY, AND CLEANING AND PROTECTING SYSTEMS AND METHODS

A cleaning system for laundry which includes a washing agent and a protective agent. The washing agent is configured to remove unwanted matter from the laundry. The protective agent is configured to create a bonded barrier comprising organosilane antimicrobial(s) on the laundry for protection against odors from bacteria, mold and mildew and/or the like. The washing agent and the protective agent are configured to be used in a two-step water-based treatment process in which the washing agent is provided in a given first step of the treatment process and the protective agent is provided in a given subsequent second step of the treatment process. 1. A cleaning system for natural and synthetic fabrics , high performance textiles , sports gear , towels and linens , the cleaning system comprising:a cleaning agent configured to remove unwanted matter from laundry, the cleaning agent comprising at least one chelator, a plurality of nonionic/cationic surfactants, at least one organosilane antimicrobial and a plurality of enzymes; anda protective agent configured to create a bonded barrier of protection against odors from at least one of bacteria, mold and mildew on the from laundry, the protective agent comprising at least one antistatic agent and at least one organosilane antimicrobial, and the bonded barrier comprising the at least one organosilane antimicrobial.2. The system of claim 1 , wherein the cleaning agent comprises claim 1 , by weight claim 1 , generally one percent chelator claim 1 , in a range of generally 20 to 72 percent nonionic/cationic surfactants claim 1 , generally 0.7 percent organosilane antimicrobial claim 1 , and generally 0.7 percent enzymes.3. The system of claim 1 , wherein the cleaning agent comprises claim 1 , by weight claim 1 , generally one percent chelator claim 1 , generally of 20 percent nonionic/cationic surfactants claim 1 , generally 0.7 percent organosilane antimicrobial claim 1 , and generally 0.7 percent enzymes.4. The system of ...

CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

A condensed cyclic compound represented by one of Formulae 1A to 1D, wherein the Formulae 1A to 1D are described in the specification. 2. The condensed cyclic compound of claim 1 , wherein{'sub': 1', '1, 'Xis C(R),'}{'sub': 2', '2, 'Xis C(R),'}{'sub': 3', '3, 'Xis C(R),'}{'sub': 4', '4, 'Xis C(R),'}{'sub': 5', '5, 'Xis C(R),'}{'sub': 6', '6, 'Xis C(R),'}{'sub': 7', '7, 'Xis C(R), and'}{'sub': 8', '8, 'Xis N or C(R).'}3. The condensed cyclic compound of claim 1 , wherein{'sub': '1', 'Lis selected from'}a phenylene group, a naphthylene group, a fluorenylene group, a phenanthrenylene group, an anthracenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, and a triazinylene group; and{'sub': 1', '20', '1', '20, 'a phenylene group, a naphthylene group, a fluorenylene group, a phenanthrenylene group, an anthracenylene group, a triphenylenylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, and a triazinylene group, each substituted with at least one selected from a deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C-Calkyl group, a C-Calkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, and a triazinyl group.'}4. The condensed cyclic compound of claim 1 , wherein{'sub': '1', 'Lis selected from'}a phenylene group, a naphthylene group, a pyridinylene group, a pyrimidinylene group, and a triazinylene group; and{'sub': 1', '10', '1', '10, 'a ...

PLANT TREATMENT METHOD

A plant treatment method comprising contacting the plant with: 2. A method according to which involves contacting the plant with a single composition comprising components (a) claim 1 , (b) claim 1 , (c) and (d).4. A method according to wherein component (b) comprises a cationic biocide selected from a quaternary ammonium salt claim 1 , a guanidine based compound or a mixture thereof.5. A method according to wherein component (b) comprises a quaternary ammonium salt.7. A method according to which involves contacting the plant with an aqueous composition comprising:10 to 2500, suitably 500 to 1500 ppm of a compound of formula (I);10 to 2500, suitably 500 to 1500 ppm of a hydrocarbyl saccharide compound;10 to 3000, suitably 500 to 2000 ppm quaternary ammonium biocide;5 to 1000, suitably 250 to 750 ppm guanidine based cationic biocide; and5 to 1000, suitably 250 to 750 ppm non-ionic surfactants.8. A method according wherein the composition contacted with the plant is prepared by dilution of a concentrated composition in a ratio of from 1:1000 to 1:2.9. A method according to which leads to a reduction of at least 50% in the number of nematodes present at or near to the surface after 24 hours.10. A method according to wherein the plant treatment composition is effective against one or more types of bacteria and/or algae and/or fungi. The present invention relates to a method of treating plants. In particular the invention relates to methods of treating plants with compositions having long lasting efficacy and which can be applied in aqueous solution.The method of the present invention may be used to treat any type of plant, for example trees, flowers, fruits and vegetables. All types of plants are susceptible to damage and disease from attack by microorganisms for example bacterial, fungi and algae. Plants may also be attacked by parasitic species.One particular problem that has increased in recent years is damage to plants by nematodes.Nematodes are microscopic ...

Host materials for oleds

Novel aryl silicon and aryl germanium host materials, and in particular host materials containing triphenylene and pyrene fragments, are described. These compounds improve OLED device performance when used as hosts in the emissive layer of the OLED.

Formula and Process for Crosslinking Antimicrobials to Textiles

A process is described herein for applying antimicrobials to substrates such as fabrics. An antimicrobial-binder mixture is provided that includes an antimicrobial and a binder that includes guar gum in an aqueous solution, which is applied to the substrate. Once the substrate is cured, spikes formed by the antimicrobial are disposed on the fabric and function to rupture membranes of infectious agents. 1. A method of applying an antimicrobial to a fabric comprisingapplying an antimicrobial-binder mixture to the fabric, wherein the binder of the antimicrobial-binder mixture comprises guar gum in an aqueous solution and the antimicrobial of the antimicrobial-binder mixture is characterized as an organo silane quaternary amine capable of forming spiked structures.2. The method of claim 1 , wherein the binder further comprises ammonium sulfate.3. The method of claim 2 , wherein the binder further comprises urea and methyl acryloid.4. The method of claim 1 , wherein the antimicrobial-binder mixture comprises at least 2% antimicrobial and at least 2% binder by weight.5. The method of claim 1 , wherein after applying the antimicrobial-binder mixture to the fabric claim 1 , the antimicrobial forms spiked structures on the fabric that function to rupture membranes of infectious agents.6. The method of claim 1 , wherein the antimicrobial includes a quaternary amine claim 1 , a carbon chain claim 1 , and a silane group claim 1 , and wherein the carbon chain is bound at one end to the quarternary amine and bound at the other end to the silane group.7. The method of claim 6 , wherein the antimicrobial is oriented such that the silane group is proximate to the fabric while the quarternary amine is distal to the fabric.8. The method of claim 6 , wherein the antimicrobial forms a spiked structure with the quaternary amine forming the peak of the spike.9. The method of claim 6 , wherein the antimicrobial is characterized by the formula NHCHR claim 6 , where R is a silane group.10. ...

MATERIAL FOR PACKAGING COMPRISING ANTIMICROBIAL COMPOSITION

Materials are provided that combine certain antimicrobial compositions with substrates to provide materials suitable for the packaging of food products, such as meat products. In one aspect, the present invention provides a material suitable for packaging that comprises (a) a substrate, and (b) an antimicrobial composition comprising: (i) an active antimicrobial agent and (ii) a carrier, wherein the antimicrobial composition has a viscosity of at least 50 centipoise at temperatures between 2° C. and 12° C. 1. A material suitable for food packaging , comprising:(a) a polymeric film; and(b) an antimicrobial composition comprising: (i) an active antimicrobial agent and (ii) a carrier, wherein the antimicrobial composition has a viscosity of at least 50 centipoise at temperatures between 2° C. and 12° C.2. The material of claim 1 , wherein the antimicrobial composition has a viscosity of up to 200 claim 1 ,000 centipoise at temperatures between 2° C. and 12° C.3. The material of claim 1 , wherein the carrier comprises water and at least one of a cellulose ether polymer claim 1 , gelatin claim 1 , pectin claim 1 , xantham gum claim 1 , guar gum claim 1 , and combinations thereof.4. The material of claim 1 , wherein the carrier comprises water and methylcellulose.5. The material of claim 1 , wherein the antimicrobial agent comprises at least one of an amino acid derivative claim 1 , an organic acid claim 1 , a peptide claim 1 , a quaternary ammonium salt claim 1 , an amino acid derivative claim 1 , and combinations thereof.6. The material of claim 1 , wherein the antimicrobial agent comprises at least one of cetylpyridinium chloride claim 1 , lauric arginate claim 1 , and dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride.7. The material of claim 1 , wherein the antimicrobial agent comprises at least one bacteriophage and at least one other antimicrobial agent.8. The material of claim 1 , wherein the antimicrobial agent is not a bacteriophage.9. The material of ...

TETRAZOLINONE COMPOUNDS AND ITS USE AS PESTICIDES

The present invention provides a compound having an excellent efficacy for controlling pests. A tetrazolinone compound of a formula (1): [wherein R1 represents an C6-C16 aryl group, an C1-C12 alkyl group, or a C3-C12 cycloalkyl group, etc., which each optionally be substituted; R2, R3, R4 and R5 represent independently of each other a hydrogen atom, a halogen atom or an C1-C3 alkyl group, etc.; R6 represents an C1-C6 alkyl group, a C3-C6 cycloalkyl group, a halogen atom, a C1-C6 haloalkyl group, an C2-C6 alkenyl group, an C1-C6 alkoxy group, or a C1-C6 haloalkoxy group, etc.; R7, R8 and R9 represent independently of each other a hydrogen atom, a halogen atom, or an C1-C4 alkyl group, etc.; X represents an oxygen atom or a sulfur atom; and R10 represents an C1-C6 alkyl group, etc.] shows an excellent controlling efficacy on pests. 2. The tetrazolinone compound according to wherein{'sup': 2', '3', '4', '5, 'R, R, Rand Rrepresent a hydrogen atom;'}{'sup': '10', 'Rrepresents a methyl group; and'}X represents an oxygen atom.3. The tetrazolinone compound according to wherein{'sup': '1', 'Rrepresents an C6-C16 aryl group optionally having one or more atoms or groups selected from Group P (with the proviso that when the C6-C16 aryl group has two or more atoms or groups selected from Group P, the substituents consisting of the atoms and the groups may be same or different to each other);'}{'sup': 2', '3', '4', '5, 'R, R, Rand Rrepresent a hydrogen atom;'}{'sup': '10', 'Rrepresents a methyl group; and'}X represents an oxygen atom.4. The tetrazolinone compound according to wherein{'sup': '1', 'Rrepresents an C1-C12 alkyl group optionally having one or more atoms or groups selected from Group P, a C3-C12 cycloalkyl group optionally having one or more atoms or groups selected from Group P, an C2-C12 alkenyl group optionally having one or more atoms or groups selected from Group P, a C3-C12 cycloalkenyl group optionally having one or more atoms or groups selected from Group P, an ...

METHODS OF CONTROLLING NEONICOTINOID RESISTANT PESTS

The invention relates to a method of controlling insects (in particular insects of the order Hemiptera, especially aphids and whitefly) that are resistant to neonicotinoid insecticides, to methods of controlling insects whereby undesired insects are affected but beneficial arthropods are not affected, using compounds of formula (I) (where A, R1 and R2 are as defined above), and, further, to novel compounds of formula I which are useful in the aforementioned methods and/or which possess enhanced insecticidal properties, and to compositions containing said compounds. 2. A method according to wherein Ris hydrogen claim 1 , C-Calkyl (optionally substituted by one or two substituents independently selected from phenyl claim 1 , or phenoxy claim 1 , which themselves can be optionally substituted by one or two substituents independently selected from halogen claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Chaloalkyl claim 1 , and C-Calkoxy) claim 1 , C-Calkoxy(C-C)alkyl claim 1 , C-Ccycloalkyl (optionally substituted by one to three substituents independently selected from halogen claim 1 , C-Calkyl claim 1 , cyano claim 1 , C-Calkoxy claim 1 , and C-Chaloalkyl) claim 1 , tri(C-C)alkylsilyl claim 1 , phenyl (optionally substituted by one or two substituents independently selected from halogen claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Chaloalkyl claim 1 , and C-Calkoxy) claim 1 , heteroaryl (wherein heteroaryl is pyridyl claim 1 , thiophenyl or thiazolyl claim 1 , and is optionally substituted by one or two substituents independently selected from halogen claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Chaloalkyl claim 1 , and C-Calkox).3. A method according to or wherein Ris hydrogen claim 1 , formyl claim 1 , C-Calkyl (optionally substituted by phenyl claim 1 , heteroaryl (wherein heteroaryl is pyridyl claim 1 , thiophenyl claim 1 , oxazolyl claim 1 , isoxazolyl claim 1 , oxadiazolyl claim 1 , thiazolyl claim 1 , isothiazolyl or thiadiazolyl) or heterocyclyl (wherein ...

ANTIMICROBIAL POLYMERIC COMPOSITIONS

A compound having the formula: 14-. (canceled)10. The composition of claim 9 , which is a blend of (a) and (b).1122-. (canceled)23. An article or device claim 7 , comprising the composition of on a surface thereof.24. An article or device claim 9 , comprising the composition of on a surface thereof.2527-. (canceled)28. A method for killing a microbe claim 7 , comprising contacting said microbe with the composition of .29. A method for killing a microbe claim 9 , comprising contacting said microbe with the composition of .3031-. (canceled)33. The compound of claim 5 , wherein Rand Rare not identical and at least one is —OCHCFH claim 5 , —OCHCFCFH claim 5 , —OCHCFCFCFH claim 5 , —Br claim 5 , —(OCH)—O—CH claim 5 , wherein x is 0-11 claim 5 , or —CFH-terminated-fluoroalkoxy.34. The compound of claim 5 , wherein Rand Rare not identical and at least one is —OCHCFH claim 5 , —OCHCFCFH claim 5 , —OCHCFCFCFH claim 5 , —(OCH)—O—CH claim 5 , wherein x is 0-11 claim 5 , or —CFH-terminated-fluoroalkoxy. This application claims priority to U.S. Provisional Application Ser. No. 61/552,452, filed Oct. 27, 2011, and 61/552,454, filed Oct. 27, 2011.This invention was made with government support under DMR grants DMR-0207560 DMR-0802452, and DMR-1206259 awarded by the National Science Foundation and Office of Naval Research Grant #000140-81-09-2-2 awarded by the Office of Naval Research. The government has certain rights in the invention. National Science Foundation (DMR-grants DMR-0207560, DMR-0802452, and DMR-1206259), the Office of Naval Research (Grant #000140-81-09-2-2) and the VCU School of Engineering Foundation supported this research.The present application relates to polymer compositions which impart microbial resistance.Infection acquired from health care environments is one of the leading major medical complications in the present world. Studies have shown that almost 6% of patients admitted to hospitals acquire infections and the number of such cases is increasing. ...

DURABLE POLYMER-AEROGEL BASED SUPERHYDROPHOBIC COATINGS: A COMPOSITE MATERIAL

Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140° and a contact angle hysteresis of less than about 1°. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized a silylating agent and a plurality of pores. 1. An article comprising:a surface, wherein the surface comprises at least one region; anda polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating comprises one or more polymers and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel comprising a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores,wherein the polymer-aerogel composite coating has a water contact angle of at least about 140° and a contact angle hysteresis of less than about 1°.2. The article of claim 1 , wherein the silylating agent comprises one or more of trimethylchlorosilane claim 1 , trichloromethylsilane claim 1 , trichlorooctylsilane claim 1 , hexamethyldisilazane claim 1 , and any reactive silane including at least one hydrophobic ligand.3. The article of claim 1 , wherein the polymer comprises one or more of poly(methyl methacrylate) claim 1 , polystyrene claim 1 , poly(butyl methacrylate) claim 1 , poly(tert-butyl methacrylate) claim 1 , poly(methyl acrylate) claim 1 , poly(butyl acrylate) claim 1 , poly(tert-butyl acrylate) claim 1 ...

STRIGOLACTAM DERIVATIVES AS PLANT GROWTH REGULATING COMPOUNDS

The present invention relates to novel strigolactam derivatives, to processes and intermediates for preparing them, to plant growth regulator compositions comprising them and to methods of using them for controlling the growth of plants and/or promoting the germination of seeds. 1. A compound of Formula (II).whereinW is O or S;{'sub': 1', '3, 'R2 and R3 are independently hydrogen, or C-Calkyl;'}{'sub': 1', '3', '1', '3', '1', '3', '1', '3', '1', '3, 'R4 and R5 are independently hydrogen, halogen, nitro, cyano, C-Calkyl, C-Chaloalkyl, C-Calkoxy, hydroxyl, —OC(O)R9, amine, N—C-Calkyl amine, or N,N-di-C-Calkyl amine;'}{'sub': 1', '6', '1', '6', '1', '6, 'R9 is hydrogen, C-Calkyl, C-Calkoxy, or C-Chaloalkyl;'}{'sub': 1', '6', '1', '6', '1', '8', '1', '8', '1', '8', '1', '6', '1', '6', '1', '8', '1', '8', '1', '8, 'R8 is hydrogen, nitro, cyano, C-Calkyl, C-Chaloalkyl, halogen, C-Calkylthio, C-Chaloalkylthio, C-Calkylsulfinyl, N—C-Calkyl amine, N,N-di-C-Calkyl amine, C-Chaloalkylsulfinyl, C-Calkylsulfonyl, or C-Chaloalkylsulfonyl;'}{'sub': 1', '6', '1', '6', '1', '6', '1', '6', '1', '8', '1', '8, 'R1 is hydrogen, C-Calkoxy, hydroxyl, amine, N—C-Calkyl amine, N,N-di-C-Calkyl amine, C-Calkyl optionally substituted by one to five R10, C-Calkylcarbonyl, C-Calkoxycarbonyl, aryl optionally substituted by one to five R10, heteroaryl optionally substituted by one to five R10, or benzyl optionally substituted by one to five R10;'}{'sub': 1', '6', '1', '6', '1', '6', '2', '6', '2', '6, 'R10 is hydrogen, cyano, nitro, halogen, C-Calkyl, C-Calkoxy, C-Chaloalkyl, C-Calkenyl, or C-Calkynyl;'}{'sub': 1', '2', '3', '4', '1', '2', '3', '4', '1', '2', '3', '4, 'A, A, Aand Aare each independently C—X, C—Y or nitrogen, wherein each X or Y may be the same or different, and provided that no more than two of A, A, Aand Aare nitrogen and that at least one of A, A, Aand Ais C—X;'}{'sub': 1', '6', '1', '6', '1', '6', '1', '3', '1', '6', '1', '6, 'Y is hydrogen, halogen, cyano, hydroxyl, —OC(O)R9, ...

Process for Preparing a Triazine-Based Precursor, the Precursor Prepared Thereby, a Method for Producing a Micro-Particulate Complex Using the Precursor, and the Micro-Particulate Complex Produced Thereby

A process for preparing a triazine-based precursor for producing a micro-particulate complex containing a far infrared-emissive silica particle comprises steps of: a) subjecting 2-4-6-trichloro-1,3,5-triazine and a first nucleophilic compound to a displacement reaction in the presence of a first solvent at a first temperature range to form an intermediate; and b) subjecting the intermediate and a second nucleophilic compound to a further displacement reaction in the presence of a second solvent at a second temperature range higher than the first temperature range. 2. The process according to claim 1 , wherein in step a) claim 1 , the first temperature range is up to 40° C.3. The process according to claim 1 , wherein in step b) claim 1 , the second temperature range is from 35° C. to 70° C.5. The process according to claim 4 , wherein the first nucleophilic compound used in sub-step a1) is different from that used in sub-step a2) claim 4 , and the first solvent used in sub-step a1) is different from that used in sub-step a2).6. A triazine-based precursor prepared by the process according to .7. A method for producing a micro-particulate complex containing a far infrared-emissive silica particle claim 6 , comprising a step of subjecting the triazine-based precursor according to and tetra-alkyl orthosilicate to hydrolysis and polycondensation.8. The method according to claim 7 , wherein the tetra-alkyl orthosilicate is tetraethyl orthosilicate.9. A micro-particulate complex containing a far infrared-emissive silica particle produced by the method according to . This application claims priority of Taiwanese Application No. 106127601, filed on Aug. 15, 2017.The disclosure relates to a process for preparing a triazine-based precursor, and more particularly to a process for preparing a triazine-based precursor for producing a micro-particulate complex containing a far infrared-emissive silica particle. The disclosure also relates to the triazine-based precursor prepared ...

Use Of Polyether Modified Short-Chain Siloxanes In Agriculture In Order To Increase Harvest Yield

The invention relates to the use of polyether modified short-chain siloxanes in agiculture in order to increase agronomic yield, a method for irrigation, and a kit containing at least one polyether modified short-chain siloxane, and an irrigation system. 1. A method of increasing agronomic yield comprising the steps of adding polyether-modified short-chain siloxanes of the formula (I) to the irrigation system in a periodic manner wherein the polyether-modified short-chain siloxanes of formula (I){'br': None, 'sub': a', 'b', 'c, 'MDD′\u2003\u2003Formula (I)'}{'sup': 1', '1', '1', '2, 'sub': 3', '1/2', '2', '2/2', '2/2, 'b': '32', 'with M=RSiO, D=RSiO, D′ RRSiO,'}wherea is 2,b is 0 to 0.5,c is 1 to 3,{'sup': '1', 'Ris independently hydrocarbyl having 1 to 8 carbon atoms,'}{'sup': '2', 'claim-text': {'br': None, 'sup': 3', '5, 'sub': 2', '2', 'm', '2', '3', 'n, 'RO[CHCHO][CHCH(CH)O]R\u2003\u2003Formula (II)'}, 'Ris independently a polyether radical of the formula (II)'}wherem=2 to 30,n=0 to 10,but with the provisos that:{'sup': '3', 'Rare independently divalent hydrocarbyl radicals having 2 to 8 carbon atoms,'}{'sup': '5', 'Ris independently a hydrocarbyl radical having 1 to 16 carbon atoms or hydrogen,'}and, if n is greater than 0,m/n=is 1 to 30 andfor all values of n claimed, if c is greater than or equal to 1.2,c*(m+n)=12 to 50,in the root region for increasing agronomic yield.2. The method of polyether-modified short-chain siloxanes of the formula (I) according to in irrigation in agriculture.3. The method of polyether-modified short-chain siloxanes of the formula (I) according to for reducing the variability of harvest outcomes and stabilization at a higher level compared to identical irrigation without use of polyether-modified short-chain siloxanes of the formula (I).4. The method of polyether-modified short-chain siloxanes of the formula (I) according to claim 1 , wherein an amount of 0.25 to 100 l/ha is used with the irrigation claim 1 , preferably 0.75 to 20 ...

USE OF SILTHIOFAM FOR THE TREATMENT OF SOYBEAN RUST

The present invention relates to the use of silthiofam for the treatment of soybean rust and agricultural compositions thereof. The invention further relates to a method of controlling, preventing and/or treating of phytopathogenic fungi causing soybean rust. 1. A method for controlling , preventing and/or treating phytopathogenic fungi causing soybean rust infections , wherein the method comprises spraying or dusting seeds , soil , or plants in need thereof with a fungicidally effective amount of silthiofam.2Phakopsora pachyrhiziP. meibomiae.. The method according to claim 1 , wherein the phytopathogenic fungi is selected from the group consisting of and3. The method according to claim 1 , wherein the plant is a legume plant.4. The method according to claim 3 , wherein the legume plant is selected from the group consisting of soybean claim 3 , bean claim 3 , kudzu and pea.5. The method according to claim 1 , wherein the silthiofam is applied as a foliar treatment.6. The method according to claim 1 , wherein the silthiofam is applied in an amount of about 10 g/ha to about 2000 g/ha.7. The method according to claim 1 , wherein the silthiofam is applied in an amount of about 100 g/ha to about 1000 g/ha.8. The method according to claim 1 , wherein the silthiofam is applied in an amount of about 100 g/ha to about 500 g/ha.9. The method according to claim 1 , wherein the silthiofam is applied in an amount of about 125 g/ha claim 1 , about 250 g/ha and/or about 500 g/ha.10. The method according to claim 1 , wherein the silthiofam is applied in combination with other ingredients and/or compounds and/or mixtures thereof.11. The method according to claim 10 , wherein the other ingredients or compounds are chosen from chitosan claim 10 , tagatose claim 10 , or one or more compounds chosen from:a) benzimidazoles chosen from benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate, or thiophanate-methyl;b) carboxamides chosen from bixafen, boscalid, carboxin, carpropamid, ...

A FABRIC IMPREGNATED WITH ORGANOSILANE FOR PURIFICATION OF LIQUIDS

The present invention relates to a fabric for purification of water. An object of the present invention is to provide a fabric for purification of liquids which achieves at least 2 log reductions of bacteria, and viruses. It is a further object of the present invention to provide a fabric for purification of liquids which provides high flow rates in gravity fed water purification systems. The present inventors have surprisingly found that a fabric having a matrix of polymer impregnated with organosilane superimposed on a surface of the fibre of a fibrous support not only provides reduction of viruses from a liquid to be purified at low pressure drops but also removes bacteria without using a separate microfiltration membrane and also retains high flow rates. 112-. (canceled)13. A fabric for purification of liquids comprising a non-woven fibrous support having a pore size in a range from 10 to 300 micrometers composed of fibres and a matrix of polymer with organosilane impregnated therein , and the matrix of polymer is superimposed on a surface of the fibres , wherein total organosilane to total polymer content ranges from 0.1:1 to 1:1 by weight; further wherein the polymer is selected from polyamides , polyacrylonitriles , polysulfones , polyethersulfone , polyvinylidenefluoride or a mixture thereof.14. A method of preparing a fabric according to comprising the steps of:i. preparing a solution of a polymer and pore forming agent in a solvent and adding organosilane into the solution to obtain a suspension;ii. contacting the suspension of step (i) with the fibrous support composed of fibres;iii. rinsing the fibrous support of step (ii) in an antisolvent, the solvent simultaneously precipitating the polymer to form a matrix of polymer with organosilane impregnated therein which matrix is superimposed on the fibres.15. The method according to wherein the pore forming agent is selected from polyvinylpyrrolidone (PVP) claim 14 , polyethylene glycol (PEG) claim 14 , ...

Fungicide pyrazole carboxamides derivatives

The present invention relates to pyrazole carboxamides derivatives of formula (1) wherein Y represents CR 5 or N, T represents S or O, X1 and X2 represent a chlorine or a fluorine atom, and Z1 represents a substituted or non-substituted cyclopropyl; Their process of preparation, their use as fungicide, and/or anti-mycotoxin active agents, and/or insecticide, and/or nematicide, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions.

Compositions and Methods for Treating Ectoparasite Infestation

Compositions suitable for topical use to treat ectoparasite infestations are described. The compositions are suitable for use on the hair of humans or animals, without the need for pharmaceuticals or medicaments. The compositions are essentially nonaqueous and non-Newtonian, such that the compositions can be controllably delivered either manually or through use of a dispensing means. One such exemplary dispenser/applicator is described. Although the compositions are otherwise substantially free of water, they exhibit good risibility characteristics and pseudoplastic rheology. Methods for the use of the nonaqueous compositions and kits containing the compositions are also presented. 1. A nonaqueous composition for the control and elimination of ectoparasites on a subject , comprising:a. at least one active ingredient;b. at least one emulsifier; andc. at least one nonaqueous solvent, or at least one thickener, or at least one nonaqueous solvent and at least one thickener;wherein the active ingredient comprises a polydimethylsiloxane and the composition is non-Newtonian.2. The nonaqueous composition of claim 1 , wherein the ectoparasite is selected from the group consisting essentially of lice claim 1 , nits claim 1 , ticks claim 1 , fleas and combinations of any of the foregoing claim 1 , and wherein the composition exhibits pseudoplastic rheology.3Pediculus capitis, Pediculus humanus capitisPediculus corporis, Pediculus humanus corporisPhthirus pubisRhipicephalus sanguineousCtenocephalides canis. The nonaqueous composition of claim 1 , wherein the ectoparasite is selected from among or head lice claim 1 , or body lice claim 1 , or pubic lice or crabs claim 1 , or brown dog ticks claim 1 , or canine fleas or fleas.4Pediculus humanus capitis.. The nonaqueous composition of claim 3 , wherein the ectoparasite is5. The nonaqueous composition of claim 1 , wherein the polydimethylsiloxane has a viscosity not greater than 100 claim 1 ,000 cps and wherein the composition is ...

Process for the Production of Partially Polymerized Antimicrobial Silanol Quaternary Ammonium Compounds

This invention is a process for the manufacture of water stable, partially polymerized antimicrobial alkoxysilyl quaternary ammonium compounds and their trisilanol, polysiloxanol and water soluble polysiloxane derivatives thereof (SQACs). Partial polymerization is accomplished by allowing the aqueous SQAC product solution to polymerize at conditions that will substantially convert all the chlorosilanol monomer to a copolymer of the SQAC, thus reducing the toxicity of the solution greatly. A stabilizing agent is added either before or after the partial polymerization. The stabilizing agent is selected from a list of antimicrobial, naturally occurring, renewable phytochemical essential oils and extracts that easily form crystal clear microemulsions when water is added to the concentrated SQAC/essential oil mixture. These non-foaming oil in water microemulsions have excellent long term storage stability, are freeze/thaw stable, remain very low in viscosity and do not phase separate or precipitate for many months. Many of the essential oils found to be useful in this process are non-toxic food additives and have pleasant scents, have low flammability yet are volatile enough to evaporate upon cure down of the SQAC, thereby resulting in a higher concentration of SQAC in the cured, antimicrobial film. Economically shippable concentrations of the low toxicity, partially polymerized, stabilized SQACs can be further diluted with water to application concentrations without loosing any of their stabilizing properties and remain storage stable at these lower concentrations indefinitely. In particular, the invention relates to the use of such aqueous dilutions cured as durable antimicrobial coatings on both manufactured and natural substrates and for human or animal skin that covalently bond to the skin, remain active through many washings and reduce or eliminate bacteria, viruses and fungi for days.

CLEANING COMPOSITION INCLUDING BOTH A DISINFECTANT AND A LONG-LASTING ANTIMICROBIAL COMPONENT

A cleaning composition comprising: a disinfectant; and an antimicrobial component including a silane quaternary ammonium ion or salt thereof. The disinfectant can include ortho-phthalaldehyde, peracetic acid, glutaraldehyde, a phenol, sodium hypochlorite, hydrogen peroxide, among other disinfectants. Such other disinfectants include two or more of octyldecyldimethyl ammonium chloride, dioctyldimethyl ammonium chloride, didecyldimethyl ammonium chloride, and n-alkyl (C14 to C16) dimethylbenzyl ammonium chloride. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. The silane quaternary ammonium ion or salt thereof can constitute 0.05% to 5% by weight of the cleaning composition. The phenol can constitute 0.10% to 2.0% by weight of the cleaning composition. The cleaning composition can further include a propellant, and the cleaning composition can be contained in an aerosol can. 1. A cleaning composition comprising:a disinfectant; andan antimicrobial component including a silane quaternary ammonium ion or salt thereof.2. The cleaning composition of claim 1 , the disinfectant including ortho-phthalaldehyde.3. The cleaning composition of claim 2 , the ortho-phthalaldehyde constituting 0.275 percent to 0.65 percent by weight of the cleaning composition.4. The cleaning composition of claim 1 , the disinfectant including peracetic acid.5. The cleaning composition of claim 4 , the peracetic acid constituting 0.04 to 0.35 percent by weight of the cleaning composition.6. The cleaning composition of claim 1 , the disinfectant including glutaraldehyde.7. The cleaning composition of claim 6 , the glutaraldehyde constituting 1.2 to 3.5 percent by weight of the cleaning composition.8. The cleaning composition of claim 1 , ...

DETECTING ANTIMICROBIAL SURFACES

A method includes depositing an antimicrobial material onto a surface of a substrate. The method includes binding a photochromic material to the antimicrobial material. Depositing the antimicrobial material and binding the photochromic material can include forming a mixture of the antimicrobial material and the photochromic material and depositing the mixture onto the surface of the substrate. It is also contemplated that depositing the antimicrobial material and binding the photochromic material can include first depositing the antimicrobial material onto the surface of the substrate and then depositing the photochromic material onto the antimicrobial material. 1. A method comprising:depositing an antimicrobial material onto a surface of a substrate; andbinding a photochromic material to the antimicrobial material.2. The method as recited in claim 1 , wherein depositing the antimicrobial material and binding the photochromic material includes:forming a mixture of the antimicrobial material and the photochromic material; anddepositing the mixture onto the surface of the substrate.3. The method as recited in claim 1 , wherein depositing the antimicrobial material and binding the photochromic material includes:first depositing the antimicrobial material onto the surface of the substrate; anddepositing the photochromic material onto the antimicrobial material.4. The method as recited in claim 1 , wherein the antimicrobial material includes Si-QAC (3-(trimethoxysilyl) Propyldimethyl Octadecyl Ammonium Chloride).5. The method as recited in claim 1 , wherein the photochromic material includes at least one of sulfonates claim 1 , sulfates claim 1 , carboxylates claim 1 , acrylates claim 1 , phosphates claim 1 , and/or phosphonates.6. The method as recited in claim 1 , wherein the antimicrobial material includes Si-QAC and the photochromic material includes anionic moiety claim 1 , wherein binding the photochromic material to the antimicrobial material includes the anionic ...

N-CYCLOALKYL-N-[(TRISUBSTITUTEDSILYLPHENYL)METHYLENE]-(THIO)CARBOXAMIDE DERIVATIVES

The present invention relates to fungicidal N-cycloalkyl-N-[(trisubstitutedsilylphenyl)methylene]carboxamide derivatives and their thiocarbonyl derivatives, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions. 3. A compound according to wherein A is selected in the list consisting of A; A; A; Aand A.4. A compound according to wherein A represents Awherein Rrepresents a substituted or non-substituted C-C-alkyl claim 3 , C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different; substituted or non-substituted C-C-alkoxy; Rrepresents a hydrogen atom or a halogen atom and Rrepresents a substituted or non-substituted C-C-alkyl.5. A compound according to wherein A represents Awherein Rrepresents C-C-alkyl claim 4 , C-C-halogenoalkyl comprising up to 3 halogen atoms that can be the same or different; Rrepresents a hydrogen atom; a chlorine atom; or a fluorine atom; and Rrepresents a methyl.6. A compound according to wherein T represents O.7. A compound according to wherein Zrepresents a substituted or non-substituted cyclopropyl.8. A compound according to wherein Zrepresents a non-substituted cyclopropyl or a 2-C-C-alkylcyclopropyl.9. A compound according to wherein Zand Zindependently represent a hydrogen atom or a methyl.10. A compound according to wherein n represents 0 claim 1 , 1 or 2.11. A compound according to wherein Zand Zindependently represent a non-substituted C-C-alkyl.12. A compound according to wherein B represents a substituted or non-substituted phenyl ring; a substituted or non-substituted naphthyl ring; a substituted or non-substituted thienyl ring; a substituted or non-substituted benzothienyl ring; a substituted or non-substituted furan ring; or a substituted or non-substituted benzofuran ring.13. A compound according ...

ANTIMICROBIAL COATING APPLIED TO PROTECTIVE BODY EQUIPMENT SUCH AS HELMETS, SHOULDER PADS, AND ELBOW PADS

A helmet including a head-facing portion with an exterior surface and an antimicrobial coating applied thereto. The antimicrobial coating includes a silane quaternary ammonium ion or salt thereof. Exemplary silane quaternary ammonium ions or salts thereof include: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. 1. A helmet comprising:a head-facing portion shaped to partially surround a head of a person, the head-facing portion including an exterior surface to contact the head of the person; andan antimicrobial coating applied to the exterior surface of the head-facing portion;wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof and isopropyl alcohol.2. The helmet of claim 1 ,wherein, the silane quaternary ammonium ion or salt thereof is one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride.3. The helmet of claim 1 ,wherein, the helmet is an equestrian riding helmet, the head-facing portion includes padding, and the antimicrobial coating is applied to the exterior surface of the padding.4. The helmet of claim 1 ,wherein, the helmet is a football helmet, the head-facing portion includes one or more of padding and liner, and the antimicrobial coating is applied to the exterior surface of the one or more included padding and liner.5. The helmet of claim 1 ,wherein, the helmet is a hockey helmet, the head-facing portion includes padding, and the antimicrobial coating is applied to the exterior surface of the padding.6. The helmet of claim 1 ,wherein, the helmet is a cricket helmet, the head-facing portion includes one or more of padding and ...

NOVEL MICROBIOCIDAL DIOXIME ETHER DERIVATIVES

The present invention provides compounds of formula (I) wherein G, G, G, G, G, G, Y, Y, Y, Y, Yand Yand p and q are as defined in the claims. The invention further relates to compositions which comprise these compounds and to their use in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi. 2. A compound according to claim 1 , wherein G claim 1 , G claim 1 , G claim 1 , G claim 1 , Gand Grepresent methylene.3. A compound according to claim 1 , wherein p and q are independently of one another 1 or 2.4. A compound according to claim 1 , wherein p and q are 1.5. A compound according to claim 1 , wherein X represents X-3 or X-5.6. A compound according to claim 1 , wherein X represents X-3.7. A compound according to claim 1 , whereinX represents X-3;{'sup': 3', '5, 'Zand Zrepresent methylene;'}{'sup': 4', '3', '4', '5', '6', '7', '8, 'Zrepresents C═CRR, CRRor SiRR;'}{'sup': 3', '4, 'Rand Rindependently of one another represent hydrogen, halogen, methyl or halomethyl;'}{'sup': 5', '6', '7', '8, 'sub': 1', '4', '1', '4, 'R, R, Rand Rindependently of one another represent hydrogen, halogen, OH, C-Calkyl, C-Chaloalkyl or phenyl, wherein the phenyl is optionally substituted by one or more groups independently selected from halogen, CN, methyl, halomethyl, methoxy and halomethoxy;'}{'sup': 5', '6, 'sub': 3', '6, 'or Rand Rtogether with the carbon atom to which they are attached may form a C-Ccycloalkyl group optionally substituted by halogen.'}8. A compound according to claim 1 , wherein{'sup': 1', '2', '3', '4', '5', '6', '11', '10, 'sub': 2', '2', '1', '8', '1', '6', '1', '4', '3', '8', '2', '6', '2', '6', '1', '8', '1', '8', '1', '8', '2', '2', '1', '4', '1', '4', '1', '4', '1', '4, 'Y, Y, Y, Y, Yand Yindependently of one another represent hydrogen, halogen, N(R), CN, NO, C-Calkyl, C-C-alkoxy-C-C-alkyl, C-Ccycloalkyl, C-Calkenyl, C-Calkynyl, phenyl, pyridyl, OR, SH, C-Calkylthio, C- ...

Amine compound and organic electroluminescence device including the same

Provided are an amine compound and an organic electroluminescence device including the same. The amine compound according to an embodiment is represented by the following Formula 1,

TRISUBSTITUTEDSILYLBENZYLBENZIMIDAZOLES AND ANALOGUES

The present disclosure relates to fungicidal active compounds, more specifically to trisubstitutedsilylbenzylbenzimidazoles and analogues thereof, processes and intermediates for their preparation as well as use thereof as fungicidal active compound, particularly in the form of fungicide compositions. The present disclosure also relates to methods for the control of phytopathogenic fungi of plants using these compounds or compositions comprising thereof. 2. The compound according to wherein Z is selected from the group consisting of hydrogen atom claim 1 , halogen atom claim 1 , hydroxyl claim 1 , C-C-alkyl claim 1 , C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different claim 1 , C-C-alkoxy claim 1 , C-C-halogenoalkoxy comprising up to 9 halogen atoms that can be the same or different and cyano3. The compound according to wherein X is independently a halogen atom or a C-C-alkyl group.4. The compound according to wherein Y is independently selected from the group consisting of halogen atom claim 1 , C-C-alkyl claim 1 , C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different claim 1 , C-C-alkoxy claim 1 , C-C-halogenoalkoxy comprising up to 9 halogen atoms that can be the same or different and cyano.5. The compound according to wherein A is a benzimidazolyl group claim 1 , an oxoquinazolinyl group or an imidazo[4 claim 1 ,5-b]pyridinyl group.6. The compound according to wherein Rand/or Ris a C-C-alkyl.7. The compound according to wherein Ris selected from the group consisting of aryl claim 1 , biaryl claim 1 , aryl-C-C-alkyl-aryl claim 1 , aryloxy-aryl aryl-C-C-alkyl claim 1 , heterocyclyl and heterocyclyl-C-C-alkyl claim 1 , wherein said aryl claim 1 , biaryl claim 1 , aryl-C-C-alkyl-aryl claim 1 , aryloxy-aryl claim 1 , aryl-C-C-alkyl claim 1 , heterocyclyl and heterocyclyl-C-C-alkyl may be substituted with one more Ras recited in .8. The compound according to wherein Ris selected from the group consisting ...

METHOD FOR IMPARTING AN ARTICLE OR A HYGIENE PRODUCT WITH ANTIMICROBIAL ACTIVITY AND THE ARTICLE AND THE HYGIENE PRODUCT IMPARTED WITH THE ANTIMICROBIAL ACTIVITY

A method for imparting an article or a hygiene product with antimicrobial activity includes a step of applying an antimicrobial agent including an antimicrobial polyaminosilane to the article or the hygiene product. The antimicrobial polyaminosilane is prepared by subjecting an aminosilane monomer to a hydrolysis and condensation reaction. The antimicrobial polyaminosilane thus prepared is free of halide ions. 1. A method for imparting an article or a hygiene product with antimicrobial activity , the method comprising a step of:applying an antimicrobial agent including an antimicrobial polyaminosilane to the article or the hygiene product,wherein the antimicrobial polyaminosilane is prepared by subjecting an aminosilane monomer to a hydrolysis and condensation reaction and is free of halide ions.2. The method according to claim 1 , wherein the aminosilane monomer is selected from the group consisting of 3-aminopropyltrimethoxysilane claim 1 , 3-aminopropyltriethoxysilane claim 1 , triamino-functional propyltrimethoxysilane claim 1 , 2-aminoethyl-3-aminopropyltrimethoxysilane claim 1 , bis(3-triethoxysilylpropyl)amine claim 1 , diamino/alkyl-functional siloxane claim 1 , cationic benzylamino-functional silane claim 1 , cationic vinylbenzylamino-functional silane claim 1 , 2-aminoethyl-3-aminopropylmethyldimethoxysilane claim 1 , 3-aminopropylmethyldiethoxysilane claim 1 , 3-ureidopropyltriethoxysilane claim 1 , and combinations thereof.3. The method according to claim 1 , wherein the aminosilane monomer contains an amino group selected from the group consisting of dioctylamino claim 1 , octylamino claim 1 , dodecylamino claim 1 , hexylamino claim 1 , pyridyl claim 1 , oleylamino claim 1 , and combinations thereof.4. The method according to claim 1 , wherein the antimicrobial polyaminosilane is in form of polymeric particulates.5. The method according to claim 4 , wherein the polymeric particulates have a size ranging from 1 nm to 10 nm.6. The method according to ...

SURFACE TREATMENT METHOD

A method of treating a grass-carrying surface, the method comprising applying to the g carrying surface: (a) a compound of formula (I): or a derivative salt thereof wherein L is a linking group; each of R, Rand Ris independently selected from an optionally substituted alkyl, alkenyl, aryl or alkoxy group; Ris oxygen or an optionally substituted alkyl, alkenyl or aryl group; each of Rand Ris an optionally substituted alkyl, alkenyl or aryl group; and n is 0 or 1; (b) at least one cationic biocide; (c) a hydrocarbyl saccharide compound; and (d) a nonionic surfactant. 2. A method according to which involves applying to the grass-carrying surface a single composition comprising components (a) claim 1 , (b) claim 1 , (c) and (d).4. A method according to wherein component (b) comprises a cationic biocide selected from a quaternary ammonium salt claim 1 , a guanidine based compound or a mixture thereof.5. A method according to wherein component (b) comprises a quaternary ammonium salt.7. A method according to which involves applying to a grass-carrying surface an aqueous composition comprising:10 to 2500 ppm of a compound of formula (I);10 to 2500 ppm of a hydrocarbyl saccharide compound;10 to 3000 ppm quaternary ammonium biocide;5 to 1000 ppm guanidine based cationic biocide; and5 to 1000 ppm non-ionic surfactants.8. A method according to wherein the composition applied to the surface is prepared by dilution of a concentrated composition in a ratio of from 1:1000 to 1:2.9. A method according to which involves applying to the grass-carrying surface a composition which combats nematodes.10. A method according to which leads to a reduction of at least 50% in the number of nematodes present at or near to the surface after 24 hours.11. A method according to which involves applying to the grass-carrying surface a composition which is effective against one or more types of bacteria and/or algae and/or fungi. The present invention relates to a method of treating a grass-carrying ...

HETEROCYCLIC COMPOUND, LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND ELECTRONIC APPARATUS INCLUDING THE LIGHT-EMITTING DEVICE

Provided is a heterocyclic compound represented by Formula 1, a light-emitting device including the same, and an electronic apparatus including the light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and the heterocyclic compound represented by Formula 1.

LECITHIN-BASED SPRAY ADJUVANT CONTAINING ORGANOSILICON WETTING AGENTS

An adjuvant composition contains lecithin and an organosilicon surfactant as defined herein. 1. An adjuvant composition comprising:a) lecithin; and, {'br': None, 'sup': '1', 'sub': 3', '2, 'R—Si(CH)—Z'}, 'b) an organosilicon surfactant of general formula (I)wherein:{'sup': '1', 'Ris a branched monovalent hydrocarbon group of from 5 to 8 carbon atoms containing at least two methyl groups;'}{'sup': 2', '3, 'Z is Ror R;'}{'sup': 2', '4', '4, 'sub': 2', '2', '2', '2', '4', 'a', '3', '6', 'b', '4', '8', 'c, 'Ris CHCHCH—O—(CH—O)(CHO)(CHO)—Rin which Ris hydrogen, a linear or branched monovalent hydrocarbon group of from 1 to about 4 carbon atoms or an acyl group, subscript a is from 1 to about 20, subscript b is from 0 to about 19, subscript c is from 0 to about 19 and the sum of subscripts a, b and c is from 1 to about 20; and,'}{'sup': 3', '+', '5', '−', '5', '−, 'sub': 2', '2', '2', '2', '3', '2, 'Ris —CHCHCH—O—CH(OH)CH—N(CH)—R[X] in which Ris a linear or branched hydrocarbon group of from 1 to about 4 carbon atoms or an acetyl group and X is a saturated or unsaturated carboxylate anion of from 2 to about 22 carbon atoms containing 0 to 2 hydroxyl groups.'}2. The adjuvant composition of wherein the lecithin component (a) contains from 10 to 70 weight percent lecithin as phosphalidylcholine with the balance being selected from phosphatidylethanolamine claim 1 , phosphalidylinositol claim 1 , phosphatidic acid claim 1 , glycolipids claim 1 , complexed sugars and triglycerides claim 1 , having a hydrophilic-lipophilic balance between 2 and 15.3. The adjuvant composition of wherein the lecithin component (a) has an average acetone insoluble (AI) content of more than 60 weight percent.4. The adjuvant composition of wherein the lecithin component (a) has an average acetone insoluble (AI) content of more than 60 weight percent.6. The adjuvant composition of wherein Rcontains from 2 to 4 methyl groups claim 5 , CRRRis selected from the group consisting of HC— claim 5 , (HC)CH— ...

Peptide-Silica Hybrid Materials

The invention relates to novel peptide-silane “hybrid block” molecules, to the synthesis thereof and to the use of same for producing novel peptide-silica hybrid materials that can be used in various applications. 117.-. (canceled)19. The method according to claim 18 , wherein X is represented by a divalent radical derived from a saturated or unsaturated aliphatic hydrocarbon chain comprising from 1 to 10 carbon atoms claim 18 , optionally intercalated with one or more structural linkers selected from arylene or fragments —O— claim 18 , —S— claim 18 , —C(═O)— claim 18 , SOor —N(R) claim 18 , wherein Rrepresents a hydrogen atom claim 18 , an aliphatic hydrocarbon radical comprising from 1 to 6 carbon atoms claim 18 , a benzyl radical or a phenethyl radical claim 18 , wherein said chain is unsubstituted or is substituted by one or more radicals selected from halogen atoms claim 18 , a hydroxyl group claim 18 , alkyl radicals comprising from 1 to 4 carbon atoms or benzyl or phenethyl radicals.20. The method according to claim 18 , wherein peptide fragment A is a linear natural peptide strand claim 18 , a linear synthetic peptide strand claim 18 , a linear protected natural peptide strand claim 18 , a linear protected synthetic peptide strand claim 18 , a linear natural pseudopeptide strand claim 18 , a linear synthetic pseudopeptide strand claim 18 , a linear protected natural pseudopeptide strand or a linear protected synthetic pseudopeptide strand claim 18 , or peptide fragment A comprises or consists of a cyclic natural peptide fragment claim 18 , a cyclic synthetic peptide fragment claim 18 , a cyclic protected natural peptide fragment claim 18 , a cyclic protected synthetic peptide fragment claim 18 , a cyclic natural pseudopeptide fragment claim 18 , a cyclic synthetic pseudopeptide fragment claim 18 , a cyclic protected natural pseudopeptide fragment or a cyclic protected synthetic pseudopeptide fragment.21. The method according to claim 18 , wherein the peptide ...

ANTIMICROBIAL SANITIZER COMPOSITIONS AND THEIR USE

The present invention relates to antimicrobial sanitizing compositions for use as skin sanitizers, especially sanitizers for the hands and feet, and air sanitizers and deodorisers. The sanitizing compositions comprise a combination of three ammonium compounds (ie. an alkoxy silyl ammonium compound, a benzalknonium chloride or benzethonium chloride and a polymeric biguanide) in a non-ionic surfactant carrier. The non-ionic surfactant system comprises an alcohol ethoxylate and an alkylglucoside or alkylpolyglycoside. Methods of use of the compositions are also described. 1. A sanitizing composition comprising:i) an alkoxy silyl ammonium film-forming compound;ii) a benzalkonium or benzethonium chloride;v) a polymeric biguanide; and a. an alcohol ethoxylate; and', 'b. an alkylglucoside or alkylpolyglycoside., 'vi) a surfactant system comprising2. The sanitizing composition according to wherein the alkoxy silyl ammonium film-forming compound is selected from 3-trimethoxysilylpropyl-N claim 1 ,N-dimethyl-N-octadecyl ammonium chloride claim 1 , 3-triethoxysilylpropyl-N claim 1 ,N-dimethyl-N-octadecyl ammonium chloride claim 1 , 3-triethoxysilylpropyl-N claim 1 ,N-dimethyl-N-isodecyl ammonium chloride and 3-trimethoxysilylpropyl-N claim 1 ,N-dimethyl-N-isodecyl ammonium chloride.3. The sanitizing composition according to wherein the concentration of alkoxy silyl ammonium film-forming compound is 0.1% to 1.5% w/w of the composition.4. The sanitizing composition according to wherein the benzalkonium or benzethonium chloride is present in an amount of 0.1% to 1.0% w/w of the composition.5. The sanitizing composition according to wherein the polymeric biguanide is a polyaminopropyl biguanide or polyhexamethylene biguanide.6. The sanitizing composition according wherein the polymeric biguanide is present in an amount of 0.1% to 1.5% w/w of the composition.7. The sanitizing composition according to wherein the alcohol ethoxylate surfactant is a Calcohol ethoxylate comprising 6 to ...

HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

A heterocyclic compound represented by Formula 1 and an organic light-emitting device including the same are provided, wherein the substituents in Formula 1 are the same as defined in the detailed descriptions. 2. The organic light-emitting device of claim 1 , wherein the emission layer comprises the one or more heterocyclic compounds.3. The organic light-emitting device of claim 2 , wherein:the one or more heterocyclic compounds comprised in the emission layer serve as a host, andthe emission layer further comprises at least one selected from a phosphorescent dopant and a fluorescent dopant.4. The organic light-emitting device of claim 2 , wherein:the one or more heterocyclic compounds comprised in the emission layer serve as a host, andthe emission layer further comprises at least one of an electron transport host and a hole transport host.5. The organic light-emitting device of claim 2 , wherein:the one or more heterocyclic compounds comprised in the emission layer serve as a host, andthe emission layer further comprises an electron transport host comprising at least one 7 electron-depleted nitrogen-containing ring.6. The organic light-emitting device of claim 2 , wherein:the organic layer further comprises at least one layer selected from an electron blocking layer between the first electrode and the emission layer and a hole blocking layer between the emission layer and the second electrode,the electron blocking layer comprises the one or more heterocyclic compounds represented by Formula 1 when the organic layer comprises the electron blocking layer, andthe hole blocking layer comprises the one or more heterocyclic compounds represented by Formula 1 when the organic layer comprises the hole blocking layer.7. The organic light-emitting device of claim 1 , wherein:the first electrode is an anode,the second electrode is a cathode,the organic layer comprises the one or more heterocyclic compounds represented by Formula 1,the organic layer comprises a hole ...

EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF

Disclosed are an epoxy compound having an alkoxysilyl group, a composite of which exhibits good heat resistant properties and/or a cured product of which exhibits good flame retardant properties, a method of preparing the same, a composition comprising the same, and a cured product and a use of the composition. An alkoxysilylated epoxy compound comprising at least one of Chemical Formula S1 substituent and at least two epoxy groups in a core, a method of preparing the epoxy compound by an allylation, a claisen rearrangement, an epoxidation and an alkoxysilylation, an epoxy composition comprising the epoxy compound, and a cured product and a use of the composition are provided. The composite of the disclosed exhibits improved chemical bonding, good heat resistant properties, a low CTE, a high glass transition temperature or Tg-less The cured product of the composition exhibits good flame retardant properties. 4. The epoxy compound having an alkoxysilyl group of claim 3 , wherein at least one of the plurality of Q is Chemical Formula S3 above.9. The epoxy composition of claim 8 , further comprising at least one epoxy compound selected from the group consisting of a glycidyl ether-based epoxy compound claim 8 , a glycidyl-based epoxy compound claim 8 , a glycidyl amine-based epoxy compound claim 8 , a glycidyl ester-based epoxy compound claim 8 , a rubber modified epoxy compound claim 8 , an aliphatic polyglycidyl-based epoxy compound and an aliphatic glycidyl amine-based epoxy compound.10. The epoxy composition of wherein the epoxy compound comprises bisphenol A claim 9 , bisphenol F claim 9 , bisphenol claim 9 , biphenyl claim 9 , naphthalene claim 9 , benzene claim 9 , thiodiphenol claim 9 , fluorene claim 9 , anthracene claim 9 , isocyanurate claim 9 , triphenylmethane claim 9 , 1 claim 9 ,1 claim 9 ,2 claim 9 ,2-tetraphenylethane claim 9 , tetraphenylmethane claim 9 , 4 claim 9 ,4′-diaminodiphenylmethane claim 9 , aminophenol cyclo aliphatic unit or a novolak unit ...

NITROGENOUS CYCLIC COMPOUND AND COLOR CHANGING FILM COMPRISING SAME

The present specification relates to a compound containing nitrogen, and a color conversion film, a backlight unit, and a display device, including the same. 3. The compound of claim 1 , wherein L1 and L2 are the same or different from each other claim 1 , and are each independently a direct bond; —SiRR—; —SO—; —NR—; —C(═O)O—; a substituted or unsubstituted methylene group; a substituted or unsubstituted ethylene group; a substituted or unsubstituted propylene group; a substituted or unsubstituted butylene group; a substituted or unsubstituted pentylene group; a substituted or unsubstituted cyclohexylene group; a substituted or unsubstituted phenylene group; a substituted or unsubstituted biphenylene group; a substituted or unsubstituted naphthylene group; a substituted or unsubstituted anthracenylene group; a substituted or unsubstituted phenanthrenylene group; a substituted or unsubstituted pyrenylene group; a substituted or unsubstituted fluorenylene group; a substituted or unsubstituted spirobifluorenylene group; a substituted or unsubstituted pyridinylene group; a substituted or unsubstituted pyrimidinylene group; a substituted or unsubstituted pyrrolylene group; a substituted or unsubstituted furanylene group; a substituted or unsubstituted thiophenylene group; a substituted or unsubstituted oxazolylene group; a substituted or unsubstituted triazolylene group; a substituted or unsubstituted indolene group; a substituted or unsubstituted benzoxadiazolene group; a substituted or unsubstituted triazolene group; a substituted or unsubstituted dibenzofuranylene group; a substituted or unsubstituted carbazolylene group; a substituted or unsubstituted xanthenylene group; a substituted or unsubstituted dihydroanthracenylene group; a substituted or unsubstituted dihydroacridinylene group; or a substituted or unsubstituted phenoxathinylene group claim 1 , and{'sub': 101', '103, 'Rto Rare the same or different, and are each independently hydrogen; deuterium; a methyl ...

ANTIMICROBIAL TREATMENT FOR A HEALTHCARE FACILITY HEADWALL

A headwall for a healthcare facility comprising: one or more cover panels having an exterior surface; and an antimicrobial coating applied to the exterior surface of the one or more cover panels; wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof. The headwall can further include one or more electrical outlets, one or more gas outlets, one or more accessory rails, a nurse call button, at least one end cap, at least one bed bumper, a bed locator, at least one lighting assembly, and a light switch, each having an exterior surface and an antimicrobial coating applied to the exterior surface. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. 1. A headwall for a healthcare facility comprising:one or more cover panels having an exterior surface; andan antimicrobial coating applied to the exterior surface of the one or more cover panels;wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof.2. The headwall of further comprising:one or more electrical outlets having an exterior surface; andan antimicrobial coating applied to the exterior surface of the one or more electrical outlets;wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof.3. The headwall of further comprising:one or more gas outlets having an exterior surface; andan antimicrobial coating applied to the exterior surface of the one or more gas outlets;wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof.4. The headwall of further comprising:one or more accessory rails having an exterior surface; andan antimicrobial coating applied to the exterior surface of the one or more accessory rails;wherein ...

Composition for Killing Arthropods and Uses Thereof

The present invention relates to a composition for killing arthropods and their eggs, such as lice or ticks and nits. More in particular, the invention provides a composition for killing arthropods, said composition comprising at least 65% by weight of a mixture of saturated linear or branched hydrocarbons, wherein said hydrocarbons comprise a mixture of saturated linear or branched C-Chydrocarbons and saturated linear or branched C-Chydrocarbons, wherein the ratio of saturated linear or branched C-Chydrocarbons to saturated linear or branched C-Chydrocarbons by weight is lower than 15:85. The invention further relates to the use of such composition for killing arthropods and to a method for killing arthropods comprising the application of the present composition. 1. A composition for killing arthropods , said composition comprising at least 65% by weight of a mixture of saturated linear or branched hydrocarbons , wherein said hydrocarbons comprise a mixture of saturated linear or branched C-Chydrocarbons and saturated linear or branched C-Chydrocarbons , wherein the ratio of saturated linear or branched C-Chydrocarbons to saturated linear or branched C-Chydrocarbons by weight is lower than 15:85 , the composition comprises between 6.9% and 21.9% of Cby weight.2. The composition according to claim 1 , said composition further comprising between 0.01 and 10% by weight of dimethicone having a viscosity of at least 20000 centistokes at 25° C.3. The composition according to claim 1 , wherein the ratio of saturated linear or branched C-Chydrocarbons to saturated linear or branched C-Chydrocarbons by weight is lower than 10:90.4. The composition according to claim 1 , wherein the ratio of saturated linear or branched C-Chydrocarbons to saturated linear or branched C-Chydrocarbons by weight is lower than 5:95.5. The composition according to claim 1 , wherein said hydrocarbons comprise a mixture of saturated linear or branched C-Chydrocarbons and saturated linear or ...

ANTIMICROBIAL TREATMENT FOR VENDING MACHINES AND GAMBLING GAMING MACHINES

A vending machine comprising: a payment interface that accepts payment from a user of the vending machine, the payment interface having an exterior surface; an object dispensary that dispenses an object after the user makes payment via the payment interface, the object dispensary having an exterior surface; and an antimicrobial coating applied to the exterior surface of one or more of the payment interface and object dispensary; wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. The vending machine can further include a user interface where the user commands which object the vending machine will dispense at the object dispensary, the user interface having the antimicrobial coating applied to an exterior surface of the user interface. 1. A vending machine comprising:a payment interface that accepts payment from a user of the vending machine, the payment interface having an exterior surface;an object dispensary that dispenses an object after the user makes payment via the payment interface, the object dispensary having an exterior surface; andan antimicrobial coating applied to the exterior surface of one or more of the payment interface and object dispensary;wherein, the antimicrobial coating includes a silane quaternary ammonium ion or salt thereof.2. The vending machine of claim 1 ,wherein, the vending machine is a change machine, the payment interface accepts payment from the user in the form of paper currency, and the object dispensary dispenses one or more of coin currency or paper currency.3. The vending machine of further comprising:a user interface where the user commands via physical contact with the user ...

METHOD OF LIMITING THE SPREAD OF NOROVIRUS WITHIN A CRUISE SHIP

A method of limiting the spread of the norovirus within a cruise ship comprising: identifying a surface within a common area of a cruise ship that passengers are likely to touch; and applying a silane quaternary ammonium ion or salt thereof to the surface. The common area can be an elevator and the surface an elevator button. The common area can be a stairway and the surface a handrail. The common area can be a casino. The common area can be a dining room. The common area can be a walkway and the surface a handrail. The silane quaternary ammonium ion or salt thereof can be 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. Applying the silane quaternary ammonium ion or salt thereof to the surface comprises applying a solution including the silane quaternary ammonium ion or salt thereof and a solvent. 1. A method of limiting spread of a virus within a cruise ship comprising:applying, to a surface of a common area of a cruise ship, a solution comprising a silane quaternary ammonium ion or salt thereof and 55 percent and 65 percent by weight isopropyl alcohol;wherein, the silane quaternary ammonium ion or salt comprises one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride.2. The method of further comprising:wiping the surface with a microfiber cloth.3. The method of further comprising:testing the surface for presence of a virus, after applying the solution, to confirm that the solution has effectively eliminated the virus from the surface.4. The method of claim 1 , wherein the common area is an elevator and the surface is an elevator button.5. The method of claim 1 , wherein the ...

SANITIZING AND ANTIMICROBIAL SOLUTION WITH SILANE QUATERNARY AMMONIUM WITH HYPOCHLOROUS ACID

A disinfecting and antimicrobial solution comprises: hypochlorous acid; silane quaternary ammonium ion or salt thereof; and water. The hypochlorous acid can exist in the solution at a concentration of 0.1 to 1000 ppm. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. The silane quaternary ammonium ion or salt thereof can be 0.1 to 10 percent by weight of the solution. The disinfecting and antimicrobial solution can further comprise isopropyl alcohol. The disinfecting and antimicrobial solution can further comprise an anolyte product of electrolysis of an aqueous solution of sodium chloride, and the anolyte product comprises the hypochlorous acid of the disinfecting and antimicrobial solution. 1. A disinfecting and antimicrobial solution comprising:hypochlorous acid;silane quaternary ammonium ion or salt thereof; andwater.2. The disinfecting and antimicrobial solution of claim 1 ,the hypochlorous acid exists in the solution at a concentration of 0.1 to 1000 ppm.3. The disinfecting and antimicrobial solution of claim 1 ,the hypochlorous acid exists in the solution at a concentration of 0.1 to 200 ppm.4. The disinfecting and antimicrobial solution of claim 1 ,the hypochlorous acid exists in the solution at a concentration of 200 to 1000 ppm.5. The disinfecting and antimicrobial solution of claim 1 , 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion,', '3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride,', '3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and', '3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride., 'the silane quaternary ammonium ion or salt thereof is one or more of6. The disinfecting and antimicrobial solution of claim 1 ,the silane quaternary ammonium ion ...

ANTIMICROBIAL FOAMS AND METHODS OF MAKING SAME

Antimicrobial foams and methods of making same. The antimicrobial foams can include a polymeric foam having a wet-out time of at least 250 sec; and a coating comprising an antimicrobial material. The antimicrobial material can include a quaternary ammonium compound, and the antimicrobial material can be covalently bound to the foam. The antimicrobial foam can include at least 0.25 parts by weight of quarternary ammonium compound per 100 parts by dry weight of the foam. The method can include providing the polymeric foam and an antimicrobial material comprising a quaternary ammonium precursor. The method can further include combining the foam and the quaternary ammonium precursor to form a combination; and heating the combination to a temperature of at least 40° C. to form an antimicrobial foam comprising a quaternary ammonium compound covalently bound to the foam. 1. An antimicrobial foam comprising:a polymeric foam, the foam having a wet-out time of at least 250 sec; anda coating comprising an antimicrobial material comprising a quaternary ammonium compound, the antimicrobial material covalently bound to the foam;wherein the antimicrobial foam comprises at least 0.25 parts by weight of quarternary ammonium compound per 100 parts by dry weight of the foam.2. The antimicrobial foam of claim 1 , wherein the antimicrobial foam comprises at least 0.5 parts by weight of quarternary ammonium compound per 100 parts by dry weight of the foam.3. The antimicrobial foam of claim 1 , wherein the antimicrobial foam comprises at least 1 part by weight of quarternary ammonium compound per 100 parts by dry weight of the foam.4. The antimicrobial foam of claim 1 , wherein the quaternary ammonium compound includes a silane-based quaternary ammonium compound.5. The antimicrobial foam of claim 4 , wherein the silane-based quaternary ammonium compound is covalently bonded to the foam via a silyl ether bond.6. The antimicrobial foam of claim 4 , wherein the silane-based quaternary ...

BROAD SPECTRUM PRO-QUORUM-SENSING MOLECULES AS INHIBITORS OF VIRULENCE IN VIBRIOS

Using a whole-cell high-throughput screen, eleven molecules were identified that activate quorum sensing (QS). Eight molecules are receptor agonists and three molecules are antagonists of LuxO, the central NtrC-type response regulator that controls the global QS cascade. Pro-QS molecules are used for the development of novel anti-infectives. 2. A broad spectrum anti-virulence composition comprising the compound of .3. A method for inhibiting virulence of gram negative quorum sensing bacteria that comprise the quorum sensing response regulator LuxO claim 1 , wherein the method comprises contacting the bacteria with the compound of .4Vibrio choleraeVibrio parahaemolyticus.. The method of wherein the bacteria are or5. A method for prophylactic treatment of a host to inhibit bacterial pathogenicity of bacteria that comprise the quorum sensing response regulator LuxO claim 1 , wherein the method comprises administering to the host the compound of .6. A method for inhibiting biofilm formation by gram negative quorum sensing bacteria that comprise the quorum sensing response regulator LuxO claim 1 , wherein the method comprises contacting the bacteria with the compound of . This application claims benefit of U.S. Provisional Application No. 61/603,590, filed Feb. 27, 2012, which is hereby incorporated in its entirety by reference.This invention was made with government support from NIH#5R01GM0-65859, NIH#5R01AI054442, and NSF# MCB-0343821. The government has certain rights in this invention.The invention relates to compounds that activate quorum sensing in bacteria.Quorum sensing (QS) is a process of bacterial cell-cell communication that relies on the production, release, detection, and response to extracellular signaling molecules called autoinducers. QS allows groups of bacteria to synchronously alter behavior in response to changes in the population density and species composition of the vicinal community. QS controls collective behaviors including bioluminescence, ...

MACROMOLECULES COMPRISING TRIAZOLES

Macromolecules comprising triazoles and related compositions and methods are provided. In some embodiments, a macromolecule may comprise one or more repeat units including a triazole and a functionalizable pendant group. The macromolecule may also comprise one or more orthogonally addressable end groups. In some embodiments, one or more repeat units may be formed by a synthetic process that allows for precise control over stereochemistry, pendant functionality, and/or the spatial relationship (e.g., distance) between groups in the repeat unit(s). Such precise control over pendant group and repeat unit structure allows for the macromolecule functionality, stereochemistry, and spacing between groups (e.g., pendant groups) to be precisely controlled. Macromolecules described herein may be used for a wide variety of applications, including the delivery of active agents. 2. The compound of claim 1 , wherein is independently a single bond.3. The compound of claim 1 , wherein each Ris independently S claim 1 , SR claim 1 , C(R) claim 1 , C(R) claim 1 , C(═O)R claim 1 , C(═NR)R claim 1 , or C(═S)R.48-. (canceled)9. The compound of claim 1 , wherein at least one Ris C(R)and wherein the at least one C(R)has the structure:{'br': None, 'sup': 6', 'a', 'b', 'c, 'sub': 2', 't, 'C(R)—(R)—(R)—R'} [{'sup': 'a', 'each Ris independently optionally substituted alkylene, optionally substituted alkenylene, or optionally substituted alkynylene;'}, {'sup': 'b', 'Ris O, N(R), or S;'}, {'sup': 'c', 'Ris hydrogen, optionally substituted acyl, optionally substituted alkyl, optionally substituted carbocyclyl, optionally substituted heteroalkyl, optionally substituted alkenyl, optionally substituted heteroalkenyl, optionally substituted alkynyl, optionally substituted heteroalkynyl, optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted silyl, or optionally substituted sulfonyl;'}, 'R is hydrogen or optionally substituted alkyl ...

Heteroarylpiperidine and -piperazine derivatives as fungicides

Heteroarylpiperidine and -piperazine derivatives of the formula (I) 2. A compound according to claim 1 , in which {'sup': 3', '4', '3', '4, 'sub': 1', '6', '2', '6', '2', '6', '3', '8', '1', '6', '2', '6', '2', '6', '3', '6', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '6', '1', '4', '1', '6', '1', '6', '1', '6, 'halogen, cyano, hydroxyl, —NRR, —C(═O)NRR, nitro, C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-cycloalkyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-halocycloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C-alkenyloxy, C-C-alkynyloxy, C-C-alkylthio, C-C-alkylsulphonyl, C-C-haloalkylthio, C-C-haloalkylsulphonyl, C-C-alkoxy-C-C-alkyl, hydroxyl-C-C-alkyl, C-C-alkylcarbonyl, C-C-alkoxycarbonyl, C-C-alkylcarbonyloxy or —C(═O)H, or'}, 'A is phenyl which may contain up to two substituents, where the substituents are each independently selected from the following list substituents on carbon:', {'sup': 3', '4, 'sub': 1', '6', '2', '6', '2', '6', '3', '6', '1', '6', '2', '6', '2', '6', '3', '6', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '6', '1', '6', '1', '6, 'halogen, cyano, hydroxyl, nitro, —NRR, C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-cycloalkyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-halocycloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C-alkylthio, C-C-alkylsulphonyl, C-C-haloalkylthio, C-C-haloalkylsulphonyl, C-C-alkoxy-C-C-alkyl, hydroxy-C-C-alkyl, C-C-alkylcarbonyl, C-C-alkoxycarbonyl, C-C-alkylcarbonyloxy or phenyl,'}, 'substituents on nitrogen:', {'sub': 1', '6', '2', '6', '2', '6', '1', '6', '2', '6', '2', '6', '3', '10', '1', '6', '1', '6', '1', '4', '1', '4', '1', '6, 'C-C-alkyl, C-C-alkenyl, C-C-alkynyl, C-C-haloalkyl, C-C-haloalkenyl, C-C-haloalkynyl, C-C-cycloalkyl-C-C-alkyl, C-C-haloalkylcarbonyl, phenyl, benzyl, C-C-alkylsulphonyl, C-C-haloalkylsulphonyl, phenylsulphonyl, —C(═O)H, or C-C-alkylcarbonyl.'}], 'A is a heteroaromatic radical ...

ANTIMICROBIAL QUATERNARY AMMONIUM ORGANOSILANE COATINGS

The present invention provides novel solid phase carriers coated with a quaternary ammonium organosilane coating for use in reducing or eliminating the viable number of microorganisms in a liquid. The invention is useful in a wide variety applications, such as water purification and reduction of harmful microorganisms in liquid foodstuffs. 2. A method in accordance with in which{'sup': '4', 'sub': 1', '10', '5', '7, 'claim-text': {'sup': '4', 'sub': 1', '10', '5', '7, 'wherein Ris a member selected from the group consisting of hydrogen, substituted or unsubstituted (C-C)alkyl, substituted or unsubstituted 2 to 10 membered heteroalkyl, substituted or unsubstituted (C-C)cycloalkyl, substituted or unsubstituted 5 to 7 membered heterocycloalkyl, substituted or unsubstituted aryl, and substituted or unsubstituted heteroaryl;'}, 'A is a member independently selected from the group consisting of —OR, substituted or unsubstituted (C-C)alkyl, substituted or unsubstituted 2 to 10 membered heteroalkyl, substituted or unsubstituted (C-C)cycloalkyl, substituted or unsubstituted 5 to 7 membered heterocycloalkyl, substituted or unsubstituted aryl, and substituted or unsubstituted heteroaryl;'}{'sub': 1', '10, 'R is substituted or unsubstituted (C-C) alkylene; and'}{'sup': 1', '2', '3, 'sub': 1', '20', '5', '7, 'R, R, and Rare members independently selected from the group consisting of hydrogen, substituted or unsubstituted (C-C)alkyl, substituted or unsubstituted 2 to 20 membered heteroalkyl, substituted or unsubstituted (C-C)cycloalkyl, substituted or unsubstituted 5 to 7 membered heterocycloalkyl, substituted or unsubstituted aryl, and substituted or unsubstituted heteroaryl.'}3. A method in accordance with in which{'sup': '4', 'sub': 1', '10', '5', '7, 'claim-text': {'sup': '4', 'sub': 1', '10', '5', '7, 'wherein Ris a member selected from the group consisting of hydrogen, unsubstituted (C-C)alkyl, unsubstituted 2 to 12 membered heteroalkyl, unsubstituted (C-C)cycloalkyl, ...

Process Using Grignard Reagents

The present invention relates to a process using Grignard reagents for providing thio-triazolo group-containing compounds. 24-. (canceled)5. The process of claim 1 , wherein LiCl is either added to the reaction mixture of step (i) or the Grignard reagent (V) is brought together with LiCl before contacting the same with a compound of formula (IV) claim 1 , thereby forming an addition product RMgX.LiCl((V).LiCl) claim 1 , which is then used in step (i).10. The process of claim 1 , wherein the reaction is carried out as a one-pot reaction.1719-. (canceled) The present invention relates to a process using Grignard reagents for providing thio-triazolo group-containing compounds, in particular pesticidal compounds of the triazole class having phytopathogenic activity, and for the synthesis of precursors therefor. The invention furthermore relates to intermediates and to their preparation.Important pesticidal compounds carry a thio-triazolo group. Specific thio-triazole compounds that are known as active ingredients having pesticidal, in particular fungicidal activity, are known, for example, from WO 96/38440. Also WO 2009/077471 (PCT/EP2008/067483), WO 2009/077443 (PCT/EP2008/067394) WO 2009/077500 (PCT/EP2008/067545), WO 2009/077497 (PCT/EP2008/067539), EP 09178224 (PCT/EP2010/068848), EP 09178291 (PCT/EP2010/068853), EP09178288 (PCT/EP2010/068790) describe further specific thio-triazolo compounds. Therein, preparation routes for the disclosed compounds are explained.In particular, it is known from the literature, for example, to introduce the thio-group into the respective triazole compounds using a strong base such as n-BuLi and sulfur powder. Alternatively, the triazole compounds are reacted with sulfur in the presence of an aprotic polar solvent, such as, for example, an amide (such as dimethylformamide (DMF)) or N-alkylpyrrolidone (such as N-octylpyrrolidone, N-dodecylpyrrolidone or N-methylpyrrolidone (NMP)). See also WO 99/19307, WO 97/06151, WO 97/05119 and WO 96 ...

3-ALKOXY, THIOALKYL AND AMINO-4-AMINO-6-(SUBSTITUTED)PICOLINATES AND THEIR USE AS HERBICIDES

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di-tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control. 2. The compound of claim 1 , wherein Q is C-Calkoxy or C-Chaloalkoxy.3. The compound of claim 1 , wherein Q is SRor NRR4. The compound of claim 1 , wherein Q is C-Calkoxy.5. The compound of claim 1 , wherein Q is methoxy.6. The compound of claim 1 , wherein X is H or F.7. The compound of claim 1 , wherein Y is Ar.8. The compound of claim 1 , wherein Ar is para-substituted phenyl with or without other substituents.9. The compound of claim 8 , wherein the para-substituted phenyl has no other substitutents.10. The compound of claim 8 , wherein the para-substituted phenyl has one or two other substitutents.11. The compound of claim 8 , wherein the para-substituted phenyl has three or four other substitutents.12. The compound of claim 8 , wherein the other substituents is each independently halogen or Calkoxy.13. The compound of claim 1 , wherein:a. Q is methoxy,b. X is H or F,c. Y is para-substituted phenyl with or without other substituents, and{'sup': 1', '2, 'd. Rand Rindependently represent H.'}14. The compound of claim 1 , wherein the compound is the compound of formula A or claim 1 , with respect to the carboxylic acid moiety of Formula A claim 1 , a C-Calkyl ester or benzyl ester thereof.16. A herbicidal composition comprising an herbicidally effective amount of a compound of and an agriculturally acceptable adjuvant or carrier.17. A method of controlling undesirable vegetation comprising contacting the vegetation or the locus thereof with claim 1 , or applying to soil or water to prevent the emergence of vegetation claim 1 , an herbicidally effective amount of a compound of .20. The compound of claim 18 , wherein the compound is a compound of Formula II or a C-Calkyl ester or benzyl ester thereof. This ...

Silicon-based compound and organic light-emitting diode comprising the same

A silicon-based compound represented by Formula 1 below and an organic light-emitting device including the silicon-based compound are provided.

Highly dispersible antimicrobial and adhesion agents

Compositions of matter that have antimicrobial properties and adhesion properties and are highly dispersible in aqueous solutions. The presence of a large number of silanols on the molecules of this invention creates a solubility or disperseability of these molecules in aqueous solutions that is not obtainable from prior art antimicrobial monomers.

ORGANIC LIGHT-EMITTING MATERIALS AND DEVICES

A novel compound containing two silicon centers with carbazole, dibenzothiophene, or triphenylene building blocks connected to the silicon is disclosed. The disclosed compound is useful as a host material in the emissive layers in phosphorescent OLEDs. 2. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Aare each independently selected from the group consisting of carbazole claim 1 , N-phenyl carbazole claim 1 , dibenzofuran claim 1 , dibenzothiophene claim 1 , triphenylene claim 1 , and fluorene.3. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Acontain at least one group selected from the group consisting of aza-carbazole claim 1 , aza-(N-phenyl carbazole) claim 1 , aza-dibenzofuran claim 1 , aza-dibenzothiophene claim 1 , aza-triphenylene claim 1 , and aza-fluorene.4. The compound of claim 1 , wherein each of m claim 1 , n claim 1 , and q is 1.5. The compound of claim 1 , wherein no more than one of A claim 1 , A claim 1 , and Ais aza-carbazole claim 1 , aza-(N-phenyl carbazole) claim 1 , aza-dibenzofuran claim 1 , aza-dibenzothiophene claim 1 , aza-triphenylene claim 1 , or aza-fluorene.6. The compound of claim 1 , wherein each of L claim 1 , L claim 1 , L claim 1 , and Lhas 1 to 24 carbon atoms.7. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Aare different from each other.8. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Acontain at least one carbazole or N-phenyl carbazole.9. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Acontain at least one triphenylene.10. The compound of claim 1 , wherein A claim 1 , A claim 1 , and Acontain at least one dibenzofuran or dibenzothiophene.11. The compound of claim 1 , wherein the aza-(N-phenyl carbazole) is selected from the group consisting of N-pyridyl carbazole claim 1 , N-pyrazinyl carbazole claim 1 , and N-triazinyl carbazole.1526-. (canceled)27. The device of claim 14 , wherein the organic layer is an emissive layer and the compound of Formula ...

SYNTHESIS OF NEW SMALL MOLECULES/OLIGOMERS WITH HIGH CONDUCTIVITY AND ABSORPTION FOR OPTOELECTRONIC APPLICATION

Disclosed are semiconducting or conducting organic small molecules and oligomers that contain a central, electron rich, functionalized dihydrodicyclopentylanthracene core (or electron donor core) that is connected to at least one or two comparatively electron deficient monomeric unit or units (or electron acceptor units) that feature group 16 heteroatoms sulfur, selenium or tellurium or combinations thereof. Multiple electron rich cores can be linked together through one or more alkynyl linkages. The small molecules and oligomers can have the following generic structure and can be used in areas such as organic photovoltaic materials: 6. The compound of claim 1 , wherein L claim 1 , L claim 1 , and Lare each individually Cl claim 1 , Br claim 1 , I claim 1 , a linear claim 1 , branched or cyclic aliphatic claim 1 , aryl or heteroaryl group of up to 20 carbon atoms.7. The compound of claim 1 , wherein Mis S and Mis S claim 1 , Mis S and Mis Se claim 1 , or Mis S and Mis Te.8. The compound of claim 1 , wherein Mis Se and Mis Se or Mis Se and Mis Te.9. The compound of claim 1 , wherein Mis Te and Mis Te.10. The compound of claim 1 , wherein Zand Zor Zand Zor Zand Zare each N and are connected by a metal bridge atom to form claim 1 , together with the carbon atoms to which they are attached claim 1 , a 5 member ring system.11. The compound of claim 10 , wherein Zand Zare each N and are connected by a metal bridge atom to form claim 10 , together with the carbon atoms to which they are attached claim 10 , a 5 member ring system.15. An electronic device comprising an organic or hybrid semiconducting or conducting layer or both comprising a compound of .16. The electronic device of claim 15 , wherein the semiconducting layer is photoactive.17. The electronic device of claim 15 , wherein the conducting layer is photoactive.18. The electronic device of claim 15 , wherein said device is a polymeric organic light-emitting diodes (PLED) claim 15 , a small-molecule organic light- ...

NEMATOCIDAL SULFONAMIDES

Disclosed are compounds of Formula 1, N-oxides, and salts thereof, 2. A compound of wherein:Z is O; and{'sup': 4', '5', '6', '7', '8', '11', '12', '9', '11', '12', '7a', '10', '7a, 'sub': 1', '4', '2', '4', '2', '4', '1', '4', '2', '4', '2', '6', 'm', '2, 'Q is phenyl or a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, OR, NRR, C-Calkyl, C-Calkenyl, C-Calkynyl, C-Chaloalkyl, C-Chaloalkenyl, C-Calkoxyalkyl, C(X)R, C(O)OR, C(X)NRR, S(O)R, S(O)NRR, OC(O)Rand N(R)C(O)R.'}3. A compound of wherein:{'sup': 4', '5', '6', '7', '8', '11', '12', '9', '11', '12', '7a', '10', '7a, 'sub': 1', '4', '2', '4', '2', '4', '1', '4', '2', '4', '2', '6', 'm', '2, 'Q is phenyl, pyridyl, pyrazolyl, oxazolyl, thiazolyl, isoxazolyl, isothiazolyl, furanyl or thienyl, each optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, OR, NRR, C-Calkyl, C-Calkenyl, C-Calkynyl, C-Chaloalkyl, C-Chaloalkenyl, C-Calkoxyalkyl, C(X)R, C(O)OR, C(X)NRR, S(O)R, S(O)NRR, OC(O)Rand N(R)C(O)R.'}4. A compound of or wherein:{'sup': 1', '4, 'sub': 1', '6', '1', '6, 'each Ris independently halogen, cyano, nitro, OR, C-Calkyl or C-Chaloalkyl;'}{'sup': '2', 'sub': 1', '6, 'Ris H, halogen or C-Calkyl;'}{'sup': 3', '7', '8', '9', '4, 'sub': 1', '6', '1', '6', 'm', '1', '6, 'Ris H, C-Calkyl, C-Chaloalkyl, C(X)R, C(O)ORor S(O)R; or C-Calkyl substituted with 1 or 2 OR; and'}n is 1 or 2.5. A compound of that is selected from the group consisting of:8-chloro-N-[(2-chloro-5-methoxyphenyl)sulfonyl]-6-(trifluoromethyl)-imidazo[1,2-a]pyridine-2-carboxamide,8-chloro-N-[(4-cyano-2,5-dimethylphenyl)sulfonyl]-6-(trifluoromethyl)-imidazo[1,2-a]pyridine-2-carboxamide,N-[(5-acetyl-2-chlorophenyl)sulfonyl]-8-chloro-6-(trifluoromethyl)-imidazo[1,2-a]pyridine-2-carboxamide,8-chloro-N-[(3-methyl-2-thienyl)sulfonyl]-6-(trifluoromethyl)-imidazo[1,2-a]pyridine ...

METHOD OF LIMITING THE SPREAD OF NOROVIRUS WITHIN A CRUISE SHIP

A method of limiting the spread of the norovirus within a cruise ship comprising: identifying a surface within a common area of a cruise ship that passengers are likely to touch; and applying a silane quaternary ammonium ion or salt thereof to the surface. The common area can be an elevator and the surface an elevator button. The common area can be a stairway and the surface a handrail. The common area can be a casino. The common area can be a dining room. The common area can be a walkway and the surface a handrail. The silane quaternary ammonium ion or salt thereof can be 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, or 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride. Applying the silane quaternary ammonium ion or salt thereof to the surface comprises applying a solution including the silane quaternary ammonium ion or salt thereof and a solvent. 1. A method of limiting the spread of norovirus within a cruise ship comprising:identifying a surface within a common area of a cruise ship that passengers are likely to touch; andapplying a silane quaternary ammonium ion or salt thereof to the surface.2. The method of further comprising:identifying presence of norovirus within the cruise ship.3. The method of further comprising:wiping the surface with a microfiber cloth.4. The method of further comprising:testing the surface for presence of the norovirus.5. The method of claim 1 , wherein the common area is an elevator and the surface is an elevator button.6. The method of claim 1 , wherein the common area is a stairway and the surface is a handrail.7. The method of claim 1 , wherein the common area is a casino.8. The method of claim 1 , wherein the common area is a dining room.9. The method of claim 1 , wherein the common area is a walkway and the surface is a handrail.10. The method of claim 1 , wherein the silane quaternary ...

NON-STICKY ANTIMICROBIAL MEDICAL ARTICLES

The present invention relates to broad spectrum antiseptic or antimicrobial compositions that may be coated or impregnated on medical articles. 1. An antimicrobial composition comprising:a. a chlorhexidine salt at a concentration of about 1% to about 19%;b. a silicone and/or its derivative at a concentration of about 1% to about 15%; andc. one or more medically acceptable excipients.2. The antimicrobial composition according to claim 1 , wherein the chlorhexidine salt is selected from the group consisting of chlorhexidine gluconate claim 1 , chlorhexidine acetate claim 1 , chlorhexidine palmitate claim 1 , chlorhexidine succinate claim 1 , chlorhexidine diisobutyrate claim 1 , chlorhexidine diphosphanilate claim 1 , and chlorhexidine dihydrochloride.3. The antimicrobial composition according to claim 1 , wherein the silicone and its derivative are selected from the group consisting of dimethicone claim 1 , cyclomethicone claim 1 , and dimethiconol.4. The antimicrobial composition according to claim 1 , wherein the medically acceptable excipient is glycerin.5. The antimicrobial composition according to claim 1 , wherein the composition is applied as a coating on a medical article.6. The antimicrobial composition according to claim 5 , wherein the composition claim 5 , when applied as a coating to a medical article claim 5 , reduces or prevents sticking of the medical article to other surfaces.7. An antimicrobial medical article comprising a medical article coated with an antimicrobial composition according to .8. A method for preparing an antimicrobial medical article comprising applying the antimicrobial composition according to to a medical article.9. The method according to claim 8 , wherein the antimicrobial composition is applied to an external surface of the medical article.10. The method according to claim 8 , wherein the antimicrobial composition is applied to the medical article by spraying or dipping.11. The antimicrobial medical article according to claim ...

(S)-5-ETHYNYL-ANABASINE, DERIVATIVES THEREOF, AND RELATED COMPOSITIONS AND METHODS OF MAKING AND USING

(S)-5-ethynyl-anabasine and derivatives thereof; composition comprising same and a carrier; methods of treating an animal; method of protecting a plant from a pest; and methods of making compound and derivatives. 1. The compound (S)-5-ethynyl-anabasine.2. The compound of claim 1 , which comprises a substitution of one or more ring hydrogens claim 1 , wherein each substitution is a moiety independently selected from the group consisting of:{'sub': 2', '2', '2, 'alkyl, cycloalkyl, hydroxyalkyl, alkenyl, alkynyl, aryl, alkylaryl, arylalkyl, aryloxyalkyl, heterocyclic, trifluoromethyl, halo, cyano, cyanomethyl, nitro, —S(O)R′, —S(O)R′, —S(O)NHR′, —NR′, —C(O)R″, —OR′, —OR′″, —NR′″, —SR′, SR″″, and SiR′″″,'}wherein R′ is hydrogen, alkyl, cycloalkyl, alkenyl, alkynyl, aryl, alkylaryl, arylalkyl, heterocyclic, trifluoromethyl, halo, cyano, or nitro,wherein R″ is hydrogen, alkyl, alkoxy, alkylamino, alkenyl, alkynyl, aryl, aryloxy, arylamino, alkylaryl, arylalkyl, heterocyclic, or trifluoromethyl,wherein R′″ is hydrogen, alkyl, cycloalkyl, alkenyl, alkynyl, aryl, alkylaryl, arylalkyl, aroyl, heterocyclic, acyl, trifluoromethyl, alkylsulfonyl, or arylsulfonyl,wherein, when the moiety is NR′″, R′″ and the N to which it is attached can form a 4-, 5-, 6-, or 7-membered ring,wherein R″″ is hydrogen, alkyl, alkenyl, alkynyl, aryl, alkylaryl, arylakyl, heterocyclic, or trifluoromethyl,wherein any of the aforementioned moieties can be substituted, andwherein the compound has acetylcholine receptor-modulating activity.3. A composition comprising (i) the compound of and (ii) a carrier.4. The composition of claim 3 , further comprising one or more other compounds having acetylcholine receptor-modulating activity.5. The composition of claim 3 , further comprising one or more other compounds having ascaricidal and/or nematicidal activity.6. A method of prophylactically or therapeutically treating an animal for infection with a pest claim 3 , which method comprises administering to the ...

TRIARYLMETHYL RADICALS

New radical compounds, useful in the field of MRI imaging of formula (I). The radical compounds are in particular new triarylmethyl (“trityl”) radicals which can be used as polarizing agents for polarizing a molecule in the DNP process. 2. The radical of wherein when A and/or B in the above formula represent a group —CO—O— claim 1 , then R′″ is not hydrogen.3. The radical according to wherein one or more of the hydrogen atoms of the groups R′ and/or R″ are deuterium.4. The radical according to wherein each R′-R′independently represents a straight or branched C-Calkyl group claim 1 , optionally substituted with an aromatic group or a group —(CH)-A-R′″ claim 1 , where n and A are as above defined and R′″ is a straight or branched C-Calkyl.5. The radical according to wherein each R″-R″independently represents a straight or branched C-Calkyl group or a group —(CH)—B—R′″ claim 1 , where n and B are as above defined and R′″ is a straight or branched C-Calkyl.7. A DNP preparation which comprises a C-labelled compound in admixture with a radical of .8. The DNP preparation of wherein said C-labelled compound is an ester precursor of an MR agent.9. A DNP preparation which comprises a C-labelled compound in admixture with a radical of .10. A DNP preparation which comprises a C-labelled compound in admixture with a radical of .11. A method for preparing a polarized sample for MR imaging which comprises:{'sup': '13', 'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'submitting a mixture comprising a C-labelled compound and a radical according to to DNP, to obtain a polarized sample;'}dissolving said mixture in an aqueous carrier; andremoving the radical of formula (I) from the polarized sample.12. A method for preparing a polarized sample for MR imaging which comprises:{'sup': '13', 'claim-ref': {'@idref': 'CLM-00006', 'claim 6'}, 'submitting a mixture comprising a C-labelled compound and a radical according to to DNP, to obtain a polarized sample;'}dissolving said mixture in an ...

ANTI-MICROBIAL COMPOSITIONS COMPRISING QUATERNARY ORGANOSILANE COMPOUNDS

An antimicrobial composition comprising at least two quaternary ammonium compounds selected from: (i) a quaternary ammonium compound having the formula: ASi(R—NHRZ)n and (ii) a quaternary ammonium compound having the formula: NHcRdZ wherein in each of the at least two quaternary ammonium compounds A, R, R, a, Z and n are independently selected, and: A is a member selected from the group consisting of alkoxy radicals, alkylether alkoxy radicals, and alkyl radicals; R is a divalent hydrocarbon radical; each Ris independently a member selected from the group consisting of benzyl, alkyl radicals, alkyl ether hydrocarbon radicals, hydroxyl-containing alkyl radicals, and nitrogen-containing hydrocarbon radicals; Z is a member selected from the group consisting of chloride, bromide, iodide, tosylate, hydroxide, sulfate and phosphate; a is 0, 1 or 2, b is 1, 2 or 3, and the sum of a and b is 3; c is 0, 1, 2 or 3, d is 1, 2, 3 or 4, and the sum of c and d is 4; and n is 1, 2 or 3; and wherein the composition comprises at least two quaternary ammonium compounds of formula (i). A method of making an anti-microbial composition, and a method of reducing the number of micro-organisms on a surface, are disclosed. 1. An antimicrobial composition comprising at least two quaternary ammonium compounds selected from: {'br': None, 'sub': 4-n', 'a', 'b', 'n, 'sup': '1', 'ASi(R—NHRZ)'}, '(i) a quaternary ammonium compound having the formulaand {'br': None, 'sub': c', 'd, 'sup': '1', 'NHRZ'}, '(ii) a quaternary ammonium compound having the formula{'sup': '1', 'wherein in each of the at least two quaternary ammonium compounds A, R, R, a, Z and n are independently selected, andA is a member selected from the group consisting of alkoxy radicals, alkylether alkoxy radicals, and alkyl radicals;R is a divalent hydrocarbon radical;{'sup': '1', 'each Ris independently a member selected from the group consisting of benzyl, alkyl radicals, alkyl ether hydrocarbon radicals, hydroxyl-containing alkyl ...

Ready-to-use storable methanolic solution of a biocompatible and biocidal polymer

An alcoholic solution of a partially quaternarized polyvinylpyridine polymer is provided. The alcoholic solution has iocidal and biocompatibility properties. The alcoholic solution is ready-to-graft in order to confer biocidal properties on various surfaces and to prevent biofilm formation on such surfaces.

ANTIBACTERIAL AGENT COMPOSITION AND ANTIVIRAL AGENT COMPOSITION COMPRISING SILICON-CONTAINING COMPOUND; ANTIBACTERIALIZING METHOD, CLEANING/MOUTH RINSING METHOD; METHOD FOR FIXING ANTIBACTERIAL AGENT AND ANTIVIRAL AGENT

Disclosed is an antibacterial agent composition which is highly safe and has excellent antibacterial abilities, by using a silicon-containing compound that is obtained by a specific manufacturing method. The antibacterial agent composition has a more stable antibacterial component, and is capable of imparting antibacterial abilities to teeth, while being also capable of cleaning an article or the mouth. Also disclosed are: an antiviral agent composition which is highly safe and has excellent virus deactivation abilities; an antibacterializing method, a cleaning/mouth rinsing method, each using the antibacterial agent composition or the antiviral agent composition; and a method for fixing an antibacterial agent or an antiviral agent. The antibacterial agent composition may contain a silicon-containing compound which is represented by general formula (1) and obtained by reacting a specific triethoxysilyl compound in an ethanol solvent. The present invention generally relates to an antibacterial agent composition and an antiviral agent composition, containing a silicon-containing compound; antibacterializing method, cleaning/mouth rinsing method, using the antibacterial agent composition and a method for fixing an antibacterial agent using the antibacterial agent composition or a method for fixing an antiviral agent using the antiviral agent composition.As a concern over hygiene of daily-life environment increases, there is increasingly a demand for higher hygiene and antibacterial standards for various articles, such as tableware, eyeglasses, sinks, kitchen fixtures, toilet, toilet fixtures, bathtubs, bath-room fixtures, wash bowls, washroom fixtures, textile products and clothes. In addition, as population of our society is aging, and largely to a global pandemic of atypical influenza, there has been a strong demand for reducing the risks of infection or secondary infection significantly by simply inactivating not only eumycetes, such as bacteria or molds, but also ...

CHEMICAL COMPOUNDS

The invention relates to pyrrolone compounds of the formula (I) wherein X, R, R, Rand A are as defined in the specification. Furthermore, the present invention relates to processes and intermediates for making compounds of formula (I), to herbicidal compositions comprising these compounds and to methods of using these compounds to control plant growth. 2. The compound of claim 1 , wherein X is O.4. (canceled)5. The compound of claim 1 ,{'sup': 'a', 'wherein Ris selected from hydrogen and fluorine.'}6. (canceled)7. The compound of claim 1 , wherein Ris selected from hydrogen claim 1 , halogen claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Chaloalkyl claim 1 , C-Calkylthio claim 1 , C-Ccyanoalkenyl claim 1 , C-Calkoxy claim 1 , C-Chaloalkoxy claim 1 , C-Calkoxy C-Calkoxy claim 1 , C-Calkenyl claim 1 , C-Calkynyl claim 1 , C-Calkoxy C-Calkenyl claim 1 , C-Calkylsulfinyl claim 1 , C-Calkylsulfonyl claim 1 , C-Calkylcarbonyl claim 1 , a group RO(O)C— claim 1 , a group RRNC(O)— claim 1 , a group RC(O)N(R)— claim 1 , a group RRNSO— claim 1 , tri C-Calkylsilyl C-Calkynyl claim 1 , a C-Caryl group optionally substituted by from 1 to 3 groups independently selected from halogen claim 1 , nitro claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Calkoxy claim 1 , C-Chaloalkyl claim 1 , and C-Chaloalkoxy claim 1 , a C-Caryloxy group optionally substituted by from 1 to 3 groups independently selected from halogen claim 1 , nitro claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Calkoxy claim 1 , C-Chaloalkyl claim 1 , and C-Chaloalkoxy; a C-Cheteroaryl group optionally substituted by from 1 to 3 groups independently selected from halogen claim 1 , nitro claim 1 , cyano claim 1 , C-Calkyl claim 1 , C-Calkoxy claim 1 , C-Chaloalkyl claim 1 , and C-Chaloalkoxy; a C-Cheterocyclyl group optionally substituted by from 1 to 3 groups independently selected from C-Calkyl; and a heterocyclyl C-Calkoxy group optionally substituted by from 1 to 3 groups independently selected from halogen claim 1 , ...

ORGANIC/INORGANIC HYBRID COMPOUND FOR FOULING RESISTANCE, MEMBRANE FOR FOULING RESISTANCE, AND METHOD OF PREPARING FOULING RESISTANT MEMBRANE

An organic/inorganic composite compound is disclosed, which includes a core of a polyhedron of polyhedral oligomeric silsesquioxane and at least one arm connected to a silicon atom of the polyhedral oligomeric silsesquioxane. The at least one arm includes a vinyl-based first structural unit including at least one ethylene oxide group at a side chain thereof and a vinyl-based second structural unit including at least one anti-biotic functional group at a side chain thereof. 1. An organic/inorganic composite compound , comprising:a core of a polyhedron of a polyhedral oligomeric silsesquioxane; andat least one arm connected to a silicon (Si) atom of the polyhedral oligomeric silsesquioxane,wherein the at least one arm includes a vinyl-based first structural unit and a vinyl-based second structural unit,the vinyl-based first structural unit includes at least one ethylene oxide group at a side chain thereof, andthe vinyl-based second structural unit includes at least one anti-biotic functional group at a side chain thereof.3. The organic/inorganic composite compound of claim 1 , wherein an atomic ratio of the silicon (Si) to oxygen (O) in the polyhedron of the polyhedral oligomeric silsesquioxane is about 1:1 to 1:1.5.5. The organic/inorganic composite compound of claim 1 , wherein the core is connected by 1 to 16 arms.8. The organic/inorganic composite compound of claim 1 , wherein the vinyl-based first structural unit and the vinyl-based second structural unit in the at least one arm ranges from about 95 mol %:about 5 mol % to about 60 mol %:about 40 mol %.9. The organic/inorganic composite compound of claim 4 ,{'sup': '1', 'sub': 2', '1', '30', '5', '30', '3', '30', '1', '30', '1', '30', '2', '30', '2', '30', '2', '30', '2', '30, 'wherein the Lis one of a single bond, —O—, —OOC—, —COO—, —OCOO—, —NX—, wherein X is one of hydrogen and a C1-C10 alkyl group), —CO—, —SO—, a substituted or unsubstituted C-Calkylene group, a substituted or unsubstituted Cto Carylene group, ...

THIENO-CONTAINING COMPOUNDS AND PROCESSES AND USES THEREOF

Disclosed herein are embodiments of thieno-containing compounds suitable for use in electrical devices and/or electrooptical device. Also disclosed herein are methods of making the disclosed compounds, with particular embodiments of the method concerning a novel dione intermediate that may be used to make particular embodiments of the thieno-containing compounds. 2. The compound of wherein one or more Z is carbon.3. The compound of claim 1 , wherein Ris aryl.4. The compound of wherein Ris substituted alkynyl.6. The compound of wherein Ris methyl claim 5 , ethyl claim 5 , or isopropyl.7. The compound of wherein each Rindependently is selected from Calkyl or Calkoxy.8. The compound of wherein Ris substituted aryl.9. The compound of wherein Ris substituted aryl comprising from 1 to 5 substituents selected from hydrogen claim 8 , halogen claim 8 , alkyl claim 8 , alkenyl claim 8 , alkynyl claim 8 , aryl claim 8 , heteroaryl claim 8 , cycloalkyl claim 8 , heteroalkyl claim 8 , cycloheteroalkyl claim 8 , amino claim 8 , haloalkyl claim 8 , alkoxy claim 8 , hydroxy claim 8 , amide claim 8 , nitro claim 8 , azide claim 8 , carboxyl claim 8 , ester claim 8 , ether claim 8 , thiol claim 8 , thioether claim 8 , or cyano.10. The compound of wherein the substituent is fluoro claim 9 , bromo claim 9 , iodo claim 9 , chloro claim 9 , trifluoromethyl claim 9 , methyl claim 9 , or combinations thereof.12. An apparatus comprising an electronic or electrooptical device selected from an organic light-emitting diode (OLED) claim 1 , an organic field-effect transistor (OFET) claim 1 , or an organic photovoltaic cell (OPV) and further comprising a compound of . This application claims priority to U.S. Provisional Application No. 61/859,133, filed on Jul. 26, 2013, and U.S. Provisional Application No. 62/023,803, filed on Jul. 11, 2014, each of which is herein incorporated by reference in its entirety.This invention was made with government support under grant numbers NSF CHE-1013032, NSF ...

COATING COMPOSITIONS COMPRISING POLYMERS HAVING TITANIUM/OXYGEN OR SILICON/OXYGEN BACKBONES

A method to prepare a self-decontaminating surface, where that method includes disposing a first coating on a surface, where that first coating comprises an organosilane, and disposing a second coating over the first coating, where the second coating comprises TiO. 4. The composition of claim 1 , wherein Rcomprises a Calkyl chain.6. The composition of claim 5 , wherein Ris alkyl; Ris isopropyl; Ris selected from the group consisting of alkyl and oxyalkyl; R claim 5 , R claim 5 , and Rare selected from the group consisting of alkyl claim 5 , alkenyl claim 5 , phenyl claim 5 , and benzyl; and X is selected from the group consisting of chlorine claim 5 , bromine claim 5 , and iodine; m is 1; n is between about 5 and 500; and p is 1.7. The composition of claim 5 , wherein Ris alkyl; Ris isopropyl; Ris selected from the group consisting of alkyl and oxyalkyl; R claim 5 , R claim 5 , and Rare selected from the group consisting of alkyl claim 5 , alkenyl claim 5 , phenyl claim 5 , and benzyl; and X is selected from the group consisting of chlorine claim 5 , bromine claim 5 , and iodine; m is 2; n is between about 5 and 500; and p is 1 claim 5 , such that polymer (6) comprises a titanium/oxygen backbone with silyl ester end groups.8. The composition of claim 5 , wherein Ris alkyl; Ris isopropyl; Ris selected from the group consisting of alkyl and oxyalkyl; R claim 5 , R claim 5 , and Rare selected from the group consisting of alkyl claim 5 , alkenyl claim 5 , phenyl claim 5 , and benzyl; and X is selected from the group consisting of chlorine claim 5 , bromine claim 5 , and iodine; m is between about 5 and 500; n is 2; and p is 1 claim 5 , such that polymer (6) comprises a titanium/oxygen backbone with silyl ester end groups claim 5 , and wherein polymer (6) is substantially linear.9. The composition of claim 5 , wherein Ris alkyl; Ris isopropyl; Ris selected from the group consisting of alkyl and oxyalkyl; R claim 5 , R claim 5 , and Rare selected from the group consisting ...

ORGANIC THIN-FILM TRANSISTOR AND METHOD FOR MANUFACTURING THE SAME, MATERIAL FOR ORGANIC THIN-FILM TRANSISTOR, COMPOSITION FOR ORGANIC THIN-FILM TRANSISTOR, COMPOUND, AND ORGANIC SEMICONDUCTOR FILM

An object of the present invention is to provide an organic thin-film transistor which has an organic semiconductor film produced using a compound having an excellent solubility in organic solvents and has an excellent carrier mobility, a compound, a material for an organic thin-film transistor for which the compound is used, a composition for an organic thin-film transistor, a method for manufacturing an organic thin-film transistor, and an organic semiconductor film. 2. The organic thin-film transistor according to claim 1 ,{'sup': 1', '12, 'wherein, in General Formula (1) and General Formula (2), the number of carbon atoms included in each of Rto Ris independently 30 or less.'}3. The organic thin-film transistor according to claim 1 ,{'sup': 1', '12', 'w, 'wherein, in General Formula (1) and General Formula (2), at least one of R, . . . , or Rhas, as R, a substituted or unsubstituted alkyl group having 20 or less carbon atoms, a substituted or unsubstituted alkenyl group having 20 or less carbon atoms, a substituted or unsubstituted alkynyl group having 20 or less carbon atoms, a substituted or unsubstituted aryl group having 20 or less carbon atoms, or a substituted or unsubstituted heteroaryl group having 20 or less carbon atoms.'}4. The organic thin-film transistor according to claim 1 ,{'sup': 1', '12', '2', '11', '3', '10', '4', '9', '5', '8', '6', '7, 'wherein, in General Formula (1) and General Formula (2), Rand Rare the same group, Rand Rare the same group, Rand Rare the same group, Rand Rare the same group, Rand Rare the same group, and Rand Rare the same group.'}8. The compound according to claim 7 ,{'sup': 1', '12, 'wherein, in General Formula (1) and General Formula (2), the number of carbon atoms included in each of Rto Ris independently 30 or less.'}9. The compound according to claim 7 ,{'sup': 1', '12', 'w, 'wherein, in General Formula (1) and General Formula (2), at least one of R, . . . , or Rhas, as R, a substituted or unsubstituted alkyl group ...

COATING COMPOSITION WITH SELENIUM-BASED BIOCIDAL FORMULATIONS

Coating compositions including and incorporating biocidal compositions containing organoselenium and/or selenium-based compounds are disclosed, as well as methods of producing and using same. For instance, a coating composition comprises covalent linkage of an anchor group to the surface of a substrate, wherein the active group comprises an organic selenium compound acting as a biocidal composition attached to the anchor group. 1. A coating composition , comprising: '(1) diselanediylbis(2-hydroxypropane-3,1-diyl)bis(2-methylacrylate); and', 'a covalent linkage of an anchor group to the surface of a substrate, wherein the active group comprises an organic selenium compound acting as a biocidal composition attached to the anchor group, the organic selenium compound comprising at least one of(2) 3,3′-diselanediylbis(propane-1,2-diol).2. The composition of claim 1 , wherein the substrate comprises a metallic composition.3. The composition of claim 2 , wherein the metallic composition of the substrate comprises a titanium coating.4. A method of making a coating composition comprising the steps of:etching a surface;linking of an anchor group to the surface through a covalent linkage the anchor group to the surface;attaching the active group of an organic selenium compound to the anchor group, the organic selenium compound comprising at least one of(1) diselanediylbis(2-hydroxypropane-3,1-diyl)bis(2-methylacrylate); and(2) 3,3′-diselanediylbis(propane-1,2-diol).5. The method of making the coating composition of claim 4 , further comprising the step of applying a metallic coating.6. The method of making the coating composition of wherein the metallic coating comprises a titanium coating. This application claims the benefit of U.S. Provisional Application No. 62/884,756, filed on Aug. 9, 2019.The present application discloses and describes composition(s), system(s), and/or method(s) of forming and/or utilizing coatings having coatings composition(s) incorporating selenium- ...

Silane Modified Diatomaceous Earth Mechanical Insecticide

A mechanical insecticide is made by mixing water with at least one type of silane to make a silane solution which is then mixed with diatomaceous earth until there is substantial deposition of the silane material on the diatomaceous earth material, to make a silanized diatomaceous earth. The silanized diatomaceous earth can be diluted with water and applied to vertical and overhead surfaces using a sprayer, for the control of insects. The silanized diatomaceous earth can also be dried into a powder for broadcast application, or mixed as a paste for brush/roller/caulk application. 1. A mechanical insecticide comprising:a natural uncalcined diatomaceous earth material;a silane material, wherein there is a substantial deposition of the silane on the diatomaceous earth; andwherein there are no pest control agents in the mechanical insecticide.2. The mechanical insecticide of further comprising water to provide a fluid suspension.3. The mechanical insecticide of further comprising a sprayer for spraying the fluid suspension.4. The mechanical insecticide of further comprising an alcohol mixed into the mechanical insecticide.5. The mechanical insecticide of wherein the mechanical insecticide is a dry powder.6. The mechanical insecticide of further comprising a broadcaster for broadcasting the dry powder.7. The mechanical insecticide of wherein the ratio of silane material to diatomaceous earth is in the range of 1:1 and 1:2000 by weight.8. The mechanical insecticide of wherein the pH level of the fluid suspension is between 4.0 and 5.5.9. The mechanical insecticide of further comprising acetic acid.10. The mechanical insecticide of wherein the type of silane is of the formula RSiX claim 1 , wherein n is equal to 0-3 claim 1 , R is an organic functional group claim 1 , and X is a hydrolyzable group.11. The mechanical insecticide of wherein the type of silane is of the formula XSi—(CH)—R—(CH)—SiX claim 1 , wherein R is an organic functional group covalently bonded to both ...

PHYSICAL ANTIMICROBIAL METHOD

The present invention relates to a physical antimicrobial method, which has the action of combating or inhibiting microorganisms when applied to the surface of human or animal body or an object. The method is safe for human body, and can prevent drug resistance caused by an antibacterial drug. 1. An antimicrobial method , the method comprising: applying an antimicrobial film or particle with positive charges to the surface of human or animal body or an object in need of antimicrobial treatment.2. The antimicrobial method of claim 1 , the method comprising: applying a silicone diquaternary ammonium salt of formula (I) or an antimicrobial composition comprising a silicone diquaternary ammonium salt of formula (I) and at least one excipient to the surface of human or animal body or an object in need of antimicrobial treatment claim 1 ,{'br': None, 'sup': 1', '2', '3', '+', '−', '5', '1', '2', '3', '+', '−, ':(RRRNX)—R—(RRRNX)\u2003\u2003(I)'}{'sup': 1', '2', '3', '5', '−, 'sub': 8-18', '8-18', '8-18', '3-10', '1-3', '1-3', '1-6, 'wherein, Reach is independently a Calkyl group, a Calkenyl group or a Calkynyl group; Rand Reach are independently methyl or ethyl; Ris Calkylene, which is substituted in β-site or farther site by tri (Calkoxy) silyloxy or tri (Calkoxy) silyl-Calkoxy; and Xeach is independently a pharmaceutically acceptable counter anion;'}to form an antimicrobial film with quaternary cation, the antimicrobial film being composed of polymer particles of the silicone diquaternary ammonium salt of formula (I).3. The antimicrobial method of claim 2 , wherein the silicone diquaternary ammonium salt has at least one of the following features:{'sup': '1', 'sub': '8-18', 'each Ris independently a Clinear chain alkyl group;'}{'sup': −', '−', '−, 'each Xis independently Clor Br; and'}{'sup': '5', 'Ris a group of the formula{'sub': 2', 'n', '6', '2', '3', '3', '2', 'n', '1-3, 'sup': '6', '(CH)CH(ORSi(OCHCH)) (CH)— wherein 1≦n≦3; Ris a single bond or a Calkylene group.'} ...

HETEROARYLPIPERIDINE AND -PIPERAZINE DERIVATIVES AS FUNGICIDES

Heteroarylpiperidine and -piperazine derivatives of the formula (I) in which the symbols A, X, Y, L, L, G, Q, p, R, Rand Rare each as defined in the description, and salts, metal complexes and N-oxides of the compounds of the formula (I), and the use thereof for controlling phytopathogenic harmful fungi and processes for preparing compounds of the formula (I). This application is a divisional of U.S. Ser. No. 13/993,262, filed Jul. 16, 2013, which is a 371 National Stage of PCT/EP2011/064527, filed Aug. 24, 2011, which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/377,229, filed Aug. 29, 2010 and U.S. Provisional Patent Application Ser. No. 61/442,967, filed Feb. 15, 2011, which claims priority to EP 10174012.4, filed Aug. 25, 2010 and EP 11154453.2, filed Feb. 15, 2011, the contents of which are incorporated herein by reference in their entireties. These applications are related to U.S. Ser. No. 13/216,033, filed Aug. 23, 2011.1. Field of the InventionThe invention relates to heteroarylpiperidine and -piperazine derivatives, to agrochemically active salts thereof, to use thereof and to methods and compositions for controlling phytopathogenic harmful fungi in and/or on plants or in and/or on seed of plants, to processes for producing such compositions and treated seed, and to use thereof for controlling phytopathogenic harmful fungi in agriculture, horticulture and forestry, in animal health, in the protection of materials and in the domestic and hygiene sector. The present invention further relates to a process for preparing heteroarylpiperidine and -piperazine derivatives.2. Description of Related ArtIt is already known that particular heterocyclically substituted thiazoles can be used as fungicidal crop protection compositions (see WO 07/014290, WO 08/013925, WO 08/013622, WO 08/091594, WO 08/091580, WO 09/055514, WO 09/094407, WO 09/094445, WO 09/132785, WO 10/037479, WO 10/065579, WO 11/076510, WO 11/018415, WO 11/018401, WO 11/076699). ...

CELLULAR TELEPHONES AND TOUCH SCREEN DISPLAYS HAVING ANTI-MICROBIAL COATINGS

A touch screen and a cellular telephone are provided that may include one or more surfaces coated with an antimicrobial treatment, which may include a silane quaternary ammonium salt and isopropyl alcohol. The silane quaternary ammonium salt may initially include an unreacted organofunctional silane that subsequently reacts with and covalently bonds to the surfaces of the touch screen, such as 3-(trimethoxysilyl) propyldimethyloctadecyl ammonium chloride. Methods are also provided for coating, or otherwise integrating the antimicrobial treatment on or within a touch screen and a cellular telephone.

HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

Provided are a heterocyclic compound represented by Formula 1 and an organic light-emitting device including the heterocyclic compound: 3. The heterocyclic compound of claim 1 , wherein Ato Aare each independently a benzene group claim 1 , a naphthalene group claim 1 , an anthracene group claim 1 , a phenanthrene group claim 1 , a triphenylene group claim 1 , a pyrene group claim 1 , a 1 claim 1 ,2 claim 1 ,3 claim 1 ,4-tetrahydronaphthalene group claim 1 , a fluorene group claim 1 , a carbazole group claim 1 , a benzofuran group claim 1 , a dibenzofuran group claim 1 , a benzothiophene group claim 1 , a dibenzothiophene group claim 1 , a benzosilole group claim 1 , a dibenzosilole group claim 1 , an azafluorene group claim 1 , an azacarbazole group claim 1 , an azadibenzofuran group claim 1 , an azadibenzothiophene group claim 1 , an azadibenzosilole group claim 1 , a pyridine group claim 1 , a pyrimidine group claim 1 , a pyrazine group claim 1 , a pyridazine group claim 1 , a triazine group claim 1 , a quinoline group claim 1 , an isoquinoline group claim 1 , a quinoxaline group claim 1 , a quinazoline group claim 1 , or a phenanthroline group.4. The heterocyclic compound of claim 1 , wherein Aand Aare each independently a benzene group claim 1 , a naphthalene group claim 1 , a pyridine group claim 1 , a pyrimidine group claim 1 , a pyrazine group claim 1 , a pyridazine group claim 1 , a triazine group claim 1 , a quinoline group claim 1 , or an isoquinoline group.6. The heterocyclic compound of claim 1 , wherein when any one of Yand Yis single bond claim 1 , and the other one of Yand Yis not a single bond.7. The heterocyclic compound of claim 1 , wherein Arto Arare each independently a substituted or unsubstituted C-Carylene group claim 1 , a substituted or unsubstituted C-Cheteroarylene group claim 1 , a substituted or unsubstituted divalent non-aromatic condensed polycyclic group claim 1 , or a substituted or unsubstituted divalent non-aromatic condensed ...

SYNTHESIS OF ANTIMICROBIAL SILSESQUIOXANE-SILICA HYBRIDS

One-pot synthetic methods are disclosed for synthesizing curable, antimicrobial silsesquioxane-silica hybrids by hydrolytically co-condensing a tetraalkoxysilane with two different trialkoxysilanes. Particles are also disclosed that are substantially spherical and have an ordered lamellar internal structure. In addition, polymers prepared from the curable, antimicrobial silsesquioxane-silica hybrids and co-monomers are disclosed. 2. A method of claim 1 ,{'sup': 'y', 'wherein each Ris, independently, H, methyl, ethyl, or propyl.'}3. A method of claim 1 ,{'sup': 'y', 'wherein each Ris H.'}4. A method of claim 1 ,{'sup': 'y', 'wherein each Ris methyl.'}5. A method of claim 1 ,{'sub': 1', '6, 'wherein said siloxane of formula I is tetra(C-C)alkoxysilane.'}6. A method of claim 1 ,wherein said siloxane of formula I is tetramethoxysilane (TMOS), tetraethoxysilane (TEOS), tetrapropoxysilane (TPOS), or a mixture thereof.7. A method of claim 1 ,wherein said siloxane of formula I is tetraethoxysilane (TEOS).8. A method of claim 1 ,{'sup': 'a', 'wherein Ris methacrylate.'}9. A method of claim 1 ,{'sup': 'a', 'wherein Ris methacryloxypropyl.'}10. A method of claim 1 ,wherein said trialkoxysilane of formula II is 3-methacryloxypropyltrimethoxysilane (3-MPTS).12. A method of claim 1 ,{'sup': 'c', 'wherein Ris methyl.'}13. A method of claim 1 ,{'sup': 'd', 'wherein Ris methyl.'}14. A method of claim 1 ,{'sup': 'e', 'wherein Ris octadecyl.'}15. A method of claim 1 ,{'sup': ⊖', '−, 'wherein X is Cl.'}16. A method of claim 1 ,wherein said trialkoxysilane of formula III is 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride (SiQAC).17. A method of claim 1 ,{'sub': 1', '3, 'wherein said (C-C)alcohol is methanol, ethanol, propanol, or a mixture thereof.'}18. A method of claim 1 ,{'sub': 1', '3, 'wherein said (C-C)alcohol is ethanol.'}19. A method of claim 1 ,{'sub': '4', 'sup': '+', 'wherein said ammonium cation (NH) is derived from ammonium hydroxide, ammonium carbonate, ...

METHODS OF USE AND PROCESSES FOR PREPARING ALCOHOLIC SOLUTIONS OF POLYVINYLPYRIDINE POLYMERS

Provided is a process for preparing an alcoholic solution of a polyvinylpyridine polymer having biocidal and biocompatibility properties. The alcoholic solution is ready-to-graft in order to confer biocidal properties to various surfaces and to prevent biofilm formation on such surfaces. Also provided are methods of using the alcoholic solution, such as for controlling the growth of bacteria, fungi and/or viruses, and/or for preventing digestion of wood cellulose by wood-boring insects. 1. A one-step reaction process to prepare an alcoholic solution , the process comprising:reacting polyvinylpyridine, monomer A and monomer B in an alcoholic solvent for a period of two days.2. The process of claim 1 , wherein the monomer A is selected from the group consisting of iodopropyltrimethoxysilane and chloromethylcatechol.3. The process of claim 1 , wherein the monomer B is bromobutane.4. The process of claim 1 , wherein the alcoholic solvent is selected from the group consisting of methanol and ethanol.5. The process of claim 2 , wherein the monomer A is iodopropyltrimethoxysilane.6. The process of claim 2 , wherein the monomer A is chloromethylcatechol.7. The process of claim 1 , wherein the monomer A is used in 5% fixed proportion to prevent reticulation in volume.9. The process of claim 8 , being a process for preparing an alcoholic solution comprising the polymer of formula I claim 8 , the process comprising reacting polyvinylpyridine claim 8 , chloromethylcatechol claim 8 , and bromobutane.10. The process of claim 9 , wherein X in the formula I is 44±2%.11. The process of claim 9 , wherein the chloromethylcatechol is used in 5% fixed proportion to prevent reticulation in volume.12. The process of claim 8 , being a process for preparing an alcoholic solution comprising the polymer of formula II claim 8 , the process comprising reacting polyvinylpyridine claim 8 , iodopropyltrimethoxysilane claim 8 , and bromobutane.13. The process of claim 12 , wherein X in the formula ...