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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3034. Отображено 100.
14-06-2012 дата публикации

Separating agent for optical isomers

Номер: US20120149851A1
Автор: Eiji Yashima, Kazumi Tamura, Toshitaka Miyabe
Принадлежит: Daicel Corp, Nagoya University NUC

To provide a novel separating agent for optical isomers based on a polymer having an optically active moiety, provided is a separating agent for optical isomers formed of: a helical polymer obtained by using an aromatic isonitrile as a monomer having an amide group in which an optically active amino acid is amide-bonded to an aromatic ring; and a carrier for carrying the helical polymer by being chemically bonded to an end of the helical polymer.

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Номер записи: 1
12-07-2012 дата публикации

Multi-layered macromolecules and methods for their use

Номер: US20120175307A1
Автор: Charles E. Skinner, William Henry Campbell, Yung K. Kim
Принадлежит: Individual

Multi-layered macromolecules wherein the layers are covalently bonded together and wherein the macromolecules are covalently bonded to solid particulate substrates, methods for the preparation of such compositions, and methods for their uses in a multitude of end use applications ranging from the purification of waste chemical and metal process streams to the separation and identification of proteins, peptides, and oligionucleotides.

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Номер записи: 2
12-09-2013 дата публикации

Adsorbent for carbon dioxide, method of preparing the same, and capture module for carbon dioxide

Номер: US20130236726A1
Автор: Hyuk Jae Kwon, Hyun Chul Lee, Jeong Gil SEO, Soonchul Kwon
Принадлежит: SAMSUNG ELECTRONICS CO LTD

An adsorbent for carbon dioxide may include an inorganic oxide porous structure having a plurality of mesopores and an active compound bound to the surface of the mesopores. The active compound may be selected from an alkali metal-containing compound, an alkaline-earth metal-containing compound, and a combination thereof. Various example embodiments also relate to a method of preparing the adsorbent for carbon dioxide and a capture module for carbon dioxide including the adsorbent for carbon dioxide.

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Номер записи: 3
05-12-2013 дата публикации

High purity chromatographic materials comprising an ionizable modifier

Номер: US20130319086A1
Автор: Kevin Daniel WYNDHAM, Pamela C. Iraneta, Thomas H. Walter
Принадлежит: Waters Technologies Corp

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are high purity chromatographic materials comprising a chromatographic surface wherein the chromatographic surface comprises a hydrophobic surface group and one or more ionizable modifier.

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Номер записи: 4
13-03-2014 дата публикации

Closed-circuit device and methods for isolation, modification, and re-administration of specific constituents from a biological fluid source

Номер: US20140074007A1
Автор: Gary L. Mcneil
Принадлежит: Individual

The present invention relates to a method and apparatus for the isolation, modification and re-administration of a molecule or biomolecule, or a class of biomolecules, from the body fluid of a mammal via an extracorporeal closed circuit device. The device is able to capture and modify the biomolecule by the covalent or non-covalent attachment of a secondary molecule or protein, by cross-linking the captured molecule, or by altering the structure of the molecule (for example, by deglycosylation, peptide cleavage, or aggregation). The apparatus can be used to return the modified molecule or biomolecule to the mammalian subject. The device and methods may be utilized for the patient-specific diagnosis and/or treatment of a disease state which presents an associated molecule or protein in plasma or any other fluidized physiological system. The methods and apparatus may also be employed as a closed system allowing the on-line purification and/or modification of a target molecule or biomolecule from a fluid source such as a bioreactor or perfusion bioreactor.

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Номер записи: 5
07-01-2021 дата публикации

COMPOSITE MATERIAL FOR BIOSEPARATIONS

Номер: US20210001306A1
Автор: FRANCO Pilar, GOTTSCHALL Klaus, MORISHITA Yasuto, Zhang Tong
Принадлежит: CHIRAL TECHNOLOGIES EUROPE SAS

The present invention relates to composite materials useful for purifying proteins obtained from biological feedstocks. The composite materials of the invention comprise a porous support having an average pore size of 5 to 500 nm, said porous support being filled with a polymer which is cross-linked, wherein the polymer is selected from polyvinylamines or polyallylamines having a weight average molecular weight (Mw) of 2,000 to 500,000 Da and a hydrolysis degree of the formamide groups of at least 66%, with the proviso that a polyvinylamine having a weight average molecular weight (Mw) of 27,200 Da and a hydrolysis degree of 70% and a polyvinylamine having a weight average molecular weight (Mw) of 50,000 Da and a hydrolysis degree of 95% are excluded. 1. A composite material comprising:a porous support having an average pore size of 5 to 500 nm, said porous support being filled with a polymer which is cross-linked,wherein the polymer is selected from polyvinylamines or polyallylamines having a weight average molecular weight (Mw) of 2,000 to 500,000 Da and a hydrolysis degree of the formamide groups of at least 66%,with the proviso that a polyvinylamine having a weight average molecular weight (Mw) of 27,200 Da and a hydrolysis degree of the formamide groups of 70% and a polyvinylamine having a weight average molecular weight (Mw) of 50,000 Da and a hydrolysis degree of the formamide groups of 95% are excluded.2. The composite material according to claim 1 , wherein the porous support is a particulate material with an average particle size of 1 μm and 500 μm.3. The composite material according to claim 1 , wherein the porous support material is porous silica gel.4. The composite material according to claim 1 , wherein the polyvinylamine is a linear or branched homopolymer of vinylamine or a copolymer of vinylamine and vinylformamide.5. The composite material according to claim 1 , wherein the concentration of cross-linked polymer is at least 3% w/w based on the ...

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Номер записи: 6
07-01-2016 дата публикации

Flue Gas Sorbents, Methods For Their Manufacture, and Their Use in Removal of Mercury From Gaseous Streams

Номер: US20160001261A1
Автор: Ghorishi Seyed Behrooz, Nalepa Christopher J., Parks John C., Pickrell William S., Zhou Qunhui
Принадлежит:

Disclosed are sorbents having superior water leachability performance characteristics especially when used as sorbents in semi-dry (CDS), high moisture (SDA), and fully wet SOscrubbers. Also disclosed are methods for the production of such performance-enhanced sorbents, and methods for the use of such sorbents in the removal of mercury and possibly one or more other heavy metals or other contaminants from various gaseous streams. The sorbents are carbonaceous substrates treated with a bromine-containing compound, especially gaseous bromine, and with at least one organic compound that contains at least one olefinic double bond. 1. A method for increasing the resistance of a brominated carbonaceous sorbent to water leaching of bromine species , which method comprises contacting a carbonaceous substrate with at least one organic compound that contains at least one olefinic double bond in an amount sufficient to increase the resistance of the brominated sorbent to water leaching of bromine species , wherein bromination of the carbonaceous substrate is conducted prior to , during , and/or after said treatment with the organic compound.2. A method as in wherein said bromination is conducted with gaseous elemental bromine.3. A method as in wherein the bromination is conducted only prior to treatment with said organic compound; only during treatment with said organic compound; or only after treatment with said organic compound.45-. (canceled)6. A method as in claim 1 , wherein the bromination is with a bromine-containing compound in gas or liquid form in a sufficient amount to increase the ability of the carbonaceous substrate to adsorb mercury and/or mercury-containing compounds and/or species.7. A method as in wherein said contacting of said carbonaceous substrate with organic compound is conducted only prior to bromination of said carbonaceous substrate; only during bromination of said carbonaceous substrate; or only after bromination of said carbonaceous substrate.89-. ...

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Номер записи: 7
04-01-2018 дата публикации

DEVICE FOR SOLID PHASE EXTRACTION AND METHOD FOR USE THEREOF

Номер: US20180001229A1
Автор: Iraneta Pamela C., JR. Frank John, Marszalkowski, Zhang Xin
Принадлежит:

Disclosed is a device for a solid phase extraction comprising two or more of the sorbents to remove phospholipids and salts from a sample, to thereby eliminate matrix effects during mass spectrometry analysis. In particular, the sorbents includes at least one sorbent which is water-wettable and contains at least one hydrophobic component and at least one hydrophilic component and at least one of sorbent having a specific affinity for a matrix interference like phospholipids. Further disclosed is a method using the device of the present invention. 1. A separation device comprising two or more sorbents wherein:the matrix interferences retained on one of the sorbents is substantially removed by the other sorbents as compared to a separation device comprising only one sorbent;the flowrate of the sorbents is substantially improved as compared to a separation device comprising only one sorbent; orthe backpres sure of the sorbents is substantially reduced as compared to a separation device comprising only one sorbent.2. The separation device of claim 1 , wherein at least one sorbent contains at least one hydrophobic component and at least one hydrophilic component.3. The separation device of claim 2 , wherein the sorbent that contains at least one hydrophobic component and at least one hydrophilic component is water-wettable.4. The separation device of claim 1 , wherein at least one of the sorbents has retention for analytes having a log P of 0.05 or greater in aqueous solutions.5. The separation device of claim 4 , wherein the remainder of the sorbents claim 4 , in total claim 4 , have a specific affinity for matrix interferences in greater than 40% organic solvent solutions.6. The separation device of claim 1 , wherein at least one sorbent has a specific affinity to phospholipids.7. The separation device of claim 1 , wherein the sorbents are selected from the group consisting of a silica claim 1 , a modified silica claim 1 , an alumina claim 1 , an modified alumina claim ...

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Номер записи: 8
05-01-2017 дата публикации

Egg-shell type hybrid structure of highly dispersed nanoparticle-metal oxide support, preparation method thereof, and use thereof

Номер: US20170001168A1
Автор: Dong Hyun Chun, Heon Jung, Ho Tae Lee, Jae In Kwon, Ji Chan Park, Jung Il Yang, Sung Jun Hong
Принадлежит: Korea Institute of Energy Research KIER

The present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, a preparation method thereof, and a use thereof. Specifically, the present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, providing an excellent platform in a size of nanometers or micrometers which can support nanoparticles selectively in the porous shell portion by employing a metal oxide support with an average diameter of nanometers or micrometers including a core of nonporous metal oxide and a shell of porous metal oxides, a preparation method thereof, and a use thereof.

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Номер записи: 9
04-01-2018 дата публикации

ADSORBENT HAVING MICROWAVE ABSORPTION PROPERTY

Номер: US20180001302A1
Автор: Cho Sung Jong, Huh Tae Kyung, Kim Jeong Yeon, Lee Dong Che, PARK Sang Jun, Yoon Seong Jin
Принадлежит: ECOPRO CO., LTD.

An adsorbent having a microwave absorption property is provided. The adsorbent having an improved microwave absorption property, which has a core-shell structure including a silicon carbide bead disposed therein, and an adsorbing material disposed outside the silicon carbide bead, can be provided. Also, the adsorbent may further include a plurality of silicon carbide particles dispersed and disposed therein and having a diameter of 1 μm to 10 μm, and the adsorbing material may be ion-exchanged with a cation. Therefore, the adsorbent can be useful in improving desorption efficiency since the adsorbent may be rapidly heated by microwaves to reach the desorption temperature due to high reactivity to microwaves. Also, the adsorbent can be useful in maintaining full adsorption capacity without having an influence on adsorption quantity since the silicon carbide bead is disposed in the inner core of the adsorbent. Further, when the adsorbent is applied to conventional systems for removing organic compounds using microwaves or dehumidification systems, the adsorbent can be semi-permanently used, and may also have an effect of enhancing the energy efficiency by 30% or more, compared to adsorbents used in the conventional systems. 1. An adsorbent having a microwave absorption property , which adsorbent has a core-shell structure comprising:a silicon carbide bead disposed therein; andan adsorbing material disposed outside the silicon carbide bead.2. The adsorbent of claim 1 , wherein the adsorbing material is selected from the group consisting of zeolite claim 1 , activated alumina claim 1 , and a mixture thereof.3. The adsorbent of claim 1 , wherein the silicon carbide bead has a diameter of approximately 0.5 mm 1.5 mm.4. The adsorbent of claim 1 , wherein an increase in temperature of the adsorbent is in a range of 30° C. to 50° C. when the adsorbent is irradiated with 1 kW microwaves for 60 seconds to 90 seconds.5. The adsorbent of claim 1 , further comprising a plurality ...

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Номер записи: 10
11-01-2018 дата публикации

FERRITE PARTICLES HAVING OUTER SHELL STRUCTURE USED FOR FILTERING MEDIUM

Номер: US20180008921A1
Автор: AGA Koji, Sugiura Takao
Принадлежит: POWDERTECH CO., LTD.

An object of the present invention is to provide ferrite particles for a filtering medium excellent in filtration ability having a small apparent density, capable of various properties maintained in the controllable state and filling a specified volume with a small amount, and a filtering medium made from the ferrite particles. In order to achieve the object, ferrite particles provided an outer shell structure containing Ti oxide for a filtering medium, and a filtering medium made from the ferrite particles are employed. 1. Ferrite particles for a filtering medium provided an outer shell structure containing Ti oxide.2. The ferrite particles for a filtering medium according to claim 1 , wherein the thickness of the outer shell structure is 0.5 to 10 μm.3. The ferrite particles for a filtering medium according to claim 1 , density of the internal part is smaller than that of the outer shell structure.4. The ferrite particles for a filtering medium according to claim 1 , volume average particle diameter is 10 to 100 μm.5. A filtering medium made from the ferrite particles according to .6. The ferrite particles for a filtering medium according to claim 2 , density of the internal part is smaller than that of the outer shell structure.7. The ferrite particles for a filtering medium according to claim 2 , volume average particle diameter is 10 to 100 μm.8. The ferrite particles for a filtering medium according to claim 3 , volume average particle diameter is 10 to 100 μm.9. The ferrite particles for a filtering medium according to claim 6 , volume average particle diameter is 10 to 100 μm.10. A filtering medium made from the ferrite particles according to .11. A filtering medium made from the ferrite particles according to .12. A filtering medium made from the ferrite particles according to .13. A filtering medium made from the ferrite particles according to .14. A filtering medium made from the ferrite particles according to .15. A filtering medium made from the ferrite ...

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Номер записи: 11
14-01-2021 дата публикации

MODIFIED POLYAMINES GRAFTED TO A PARTICULATE, SOLID SUPPORT AS SORBENT MATERIALS FOR REMOVAL OF TARGET SUBSTANCES FROM FLUIDS

Номер: US20210008522A1
Автор: HAGEMANN Henrik, Li Wen, REEH Katharina, REEVE Benjamin David, YOU Amanda Yi Fen
Принадлежит: Puraffinity Ltd.

Provided are compositions for removal of a target substance from a fluid stream, the composition comprising a polyamine; and a covalently linked hydrophobic group, wherein the polyamine is covalently linked to a support material. Also provided are processes for removal of a target substance from a fluid stream comprising contacting the fluid stream with a composition comprising a polyamine; and a covalently linked hydrophobic group, wherein the polyamine is covalently linked to a support material. 1. A composition for removal of a target substance from a fluid stream , the composition comprising a polyamine; and a covalently linked hydrophobic group , wherein the polyamine is covalently linked to a support material.2. The composition of claim 1 , wherein the support material is comprised of a material selected from one or more of the group consisting of: lignocellulose; bacterial cellulose; microcrystalline cellulose; microfibrillated cellulose and a cellulose derivative.3. The composition of claim 2 , wherein the support material comprises a cellulose or lignocellulose powder or pulp.4. The composition of claim 3 , wherein the cellulose or lignocellulose powder or pulp is incorporated into a membrane or membrane-like filter.5. The composition of claim 1 , wherein the support material is selected from one or more of the group consisting of: silica; silica gel; and a silica derivative.6. The composition of any one of claim 1 , or claim 1 , wherein the support material is porous claim 1 , solid claim 1 , and particulate claim 1 , preferably wherein the average diameter size of the particles is greater than about 0.01 mm claim 1 , and less than about 1 mm.7. The composition of claim 6 , wherein the particulate form comprises one or more of the group consisting of a plurality of: granules; flakes; beads; pellets; and pastilles.8. The composition of any one of to claim 6 , wherein the polyamine is selected from a linear or branched polyamine.9. The composition of claim 8 ...

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Номер записи: 12
15-01-2015 дата публикации

Methods and Systems for Capturing Carbon Dioxide and Producing a Fuel Using a Solvent Including a Nanoparticle Organic Hybrid Material and a Secondary Fluid

Номер: US20150014182A1
Автор: Ah-Hyung Alissa Park, Camille PETIT, Kun-yi Andrew LIN, Youngjune Park
Принадлежит: Columbia University of New York

Methods and systems for capturing carbon dioxide and producing fuels such as alcohol using a solvent including a nanoparticle organic hybrid material and a secondary fluid are disclosed. In some embodiments, the methods include the following: providing a solvent including a nanoparticle organic hybrid material and a secondary fluid, the material being configured to capture carbon dioxide; introducing a gas including carbon dioxide to the solvent until the material is loaded with carbon dioxide; introducing at least one of catalysts for carbon dioxide reduction and a proton source to the solvent; heating the solvent including the material loaded with carbon dioxide until carbon dioxide loaded on the material is electrochemically converted to a fuel.

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Номер записи: 13
03-02-2022 дата публикации

DEVICE FOR SOLID PHASE EXTRACTION AND METHOD FOR USE THEREOF

Номер: US20220032210A1
Автор: Iraneta Pamela C., JR. Frank John, Marszalkowski, Zhang Xin
Принадлежит:

Disclosed is a device for a solid phase extraction comprising two or more of the sorbents to remove phospholipids and salts from a sample, to thereby eliminate matrix effects during mass spectrometry analysis. In particular, the sorbents includes at least one sorbent which is water-wettable and contains at least one hydrophobic component and at least one hydrophilic component and at least one of sorbent having a specific affinity for a matrix interference like phospholipids. Further disclosed is a method using the device of the present invention. 173-. (canceled)74. A solid phase extraction method , comprising:using a device, wherein the device comprises a sorbent bed including a sorbent containing at least one hydrophobic component and at least one hydrophilic component and a sorbent having a specific affinity to phospholipids.75. The method of claim 75 , wherein the sorbent that contains at least one hydrophobic component and at least one hydrophilic component is water-wettable.76. The method of claim 75 , wherein the sorbent bed is layered.77. The method of claim 76 , wherein a top layer is the sorbent containing at least one hydrophobic component and at least one hydrophilic component.78. The method of claim 75 , wherein the sorbent containing at least one hydrophobic component and at least one hydrophilic component and the sorbent having a specific affinity to phospholipids are mixed in a single layer of the sorbent bed.79. The method of or claim 75 , wherein the sorbent containing at least one hydrophobic component and at least one hydrophilic component and the sorbent having a specific affinity to phospholipid are mixed at a weight ratio of about 1:2.80. (canceled)81. The method of claim 76 , wherein the sorbent having a specific affinity to phospholipids includes a silica containing a modified or unmodified octadecyl (C) or octyl Cto Calkyl component.82. The method of claim 76 , wherein the device is a syringe claim 76 , a cartridge claim 76 , a column claim ...

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Номер записи: 14
03-02-2022 дата публикации

COLORED ZEOLITE ADSORBENT

Номер: US20220032263A1
Автор: Serge Nicolas
Принадлежит: Arkema France

The present invention concerns a zeolitic adsorbent comprising a zeolitic agglomerate comprising at least one zeolite and at least one agglomeration binder, said agglomerate being coated with a coating comprising at least one pigment. 1. A zeolitic adsorbent material comprising:a zeolitic agglomerate comprising at least one zeolite and at least one agglomeration binder,the agglomerate being coated with a coating comprising at least one pigment.2. The material as claimed in claim 1 , having a color whose component L* is between 0 and 80.3. The material as claimed in claim 1 , wherein the coating has a thickness of between 10 μm and 1000 μm.4. The material as claimed in claim 1 , wherein the one zeolitic agglomerate comprises a zeolite selected from LTA-type zeolites and FAU-type zeolites.5. The material as claimed in claim 1 , wherein the amount of zeolite(s) is more than 65% relative to the total weight of the adsorbent material claim 1 , and is less than 99% by weight relative to the total weight of the material.6. The material as claimed in claim 1 , wherein the agglomeration binder is selected from clays and inorganic binders.7. The material as claimed in claim 1 , wherein the pigment is selected from peach black claim 1 , lamp black claim 1 , wine black claim 1 , vine black claim 1 , mineral black claim 1 , Dead Sea black clay claim 1 , and organic dyes from the lignosulfonate class.8. The material as claimed in claim 1 , wherein the amount of pigment is between 0.01% and 10% by weight relative to the total weight of the material.9. A process for preparing a zeolitic adsorbent material as claimed in claim 1 , comprising:a) mixing an agglomeration binder and at least one zeolite, and agglomerating and shaping the mixture to give a zeolitic agglomerate;b) coating the agglomerate prepared and shaped in step a) using a coating composition comprising at least one pigment;c) drying the coated agglomerate obtained in step b) at a temperature generally of between 80° C. ...

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Номер записи: 15
03-02-2022 дата публикации

SOLID SUPPORT COMPRISING CARBON NANOTUBES, SYSTEMS AND METHODS TO PRODUCE IT AND TO ADSORBE ORGANIC SUBSTANCES ON IT

Номер: US20220032264A1
Автор: VUONO Danilo
Принадлежит:

Method for manufacturing an inert solid support with optionally functionalised carbon nanotubes (CNTs), comprising the steps of: i) providing an inert solid support and at least one catalytic metal associated with, or absorbed in, or adsorbed/deposited on, said support, said metal being optionally selected from among the group consisting of iron, cobalt, nickel, molybdenum and combinations thereof; ii) supplying a source of gaseous, liquid or solid carbon to the catalytic metal; iii) through chemical vapor deposition (CVD), depositing at least part of the carbon source at the catalytic metal as CNTs, stably connected to the inert solid support. The present invention further regards an inert solid support and a separation method. 1. Method for manufacturing inert solid supports with optionally functionalised carbon nanotubes (CNTs) , comprising steps of:i) providing inert solid supports and at least one catalytic metal absorbed in, or adsorbed or deposited on, said supports, said metal being optionally selected from among the group consisting of iron, cobalt, nickel, molybdenum and combinations thereof;ii) supplying a gaseous, liquid or solid carbon source to the catalytic metal;iii) through chemical vapor deposition (CVD), depositing at the catalytic metal at least part of the carbon source as CNTs, stably connected to the inert solid supports;wherein the inert solid supports are in the form of particulate, granule or pellet with an over-nanometric particle size distribution, that is inert solid supports having an average size distribution comprised from 0.1 mm to 5 mm, and wherein the CNTs are in the form of scattered bundles or tangle, grouped at the catalytic metal.2. The method according to claim 1 , wherein the inert solid supports are selected from among the group consisting of aluminium silicate (for example: mullite) claim 1 , silico-aluminates claim 1 , quartz sand claim 1 , quartz claim 1 , alumina or aluminium oxide (for example: corundum) claim 1 , ...

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Номер записи: 16
18-01-2018 дата публикации

POLYFUNCTIONAL SORBENT MATERIALS

Номер: US20180015442A1
Автор: Addleman Raymond Shane, Chouyyok Wilaiwan, Johnson Darren W., Nell Kara, Pittman Jonathan, Warner Marvin G.
Принадлежит:

Disclosed herein is a material comprising a functionalized solid support surface, wherein the functionalization comprises a thioalkylene linker bound to the support surface and the thioalkylene linker is coupled to a moiety derived from a ligand, wherein the ligand includes a terminal alkenyl and at least one first functional group configured to bind to at least one predetermined target species. 2. The material of claim 1 , wherein X is selected from —CH(P(═O)(OH)) claim 1 , or —N(—CH—COOH).3. The material of claim 1 , further comprising a hydroxy or a thioalkyl directly bound to A.4. The material of claim 1 , wherein X comprises a phosphonic acid moiety or an iminodiacetic acid moiety.5. The material of claim 1 , wherein X is a urea claim 1 , thiourea claim 1 , phosphinimine claim 1 , hydroxypyridinoate (HOPO) claim 1 , sulfocatecholamide (CAMS) claim 1 , terephthalimide claim 1 , carbamoylmethylphosphine oxide (CMPO) claim 1 , phosphine derivative claim 1 , phosphine oxide derivative claim 1 , sulfonamide derivative claim 1 , ethylenediaminetetraacetic acid (EDTA) derivative claim 1 , dihydroxybenzene claim 1 , or N-phenyliminodiacetic acid.6. The material of claim 1 , wherein n is 3.7. The material of claim 1 , wherein Ris (—CH—)and m is 3.8. The material of claim 1 , wherein Ris (—CH—)Ph(—CH—).9. The material of claim 1 , wherein Ris (—CH—)Ph(—CH—)and a is 2 and b is 1.10. The material of claim 6 , wherein X comprises a phosphonic acid moiety or an iminodiacetic acid moiety.11. The material of claim 1 , wherein A comprises a silica substrate.12. A material comprising a functionalized solid support surface claim 1 , wherein the functionalization comprises a thioalkylene linker bound to the support surface and the thioalkylene linker is coupled to a moiety derived from a ligand claim 1 , wherein the ligand includes a terminal alkenyl and at least one first functional group configured to bind to at least one predetermined target species claim 1 , and wherein the ...

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Номер записи: 17
21-01-2016 дата публикации

ABSORBENT MEDIUM FOR ISOLATION OF BIOLOGICAL MOLECULES AND METHOD FOR SYNTHESIZING SAME

Номер: US20160016147A1
Автор: Fatemi Kamal, Tavoosidana Gholamreza
Принадлежит:

An absorbent medium for biological molecules separation is provided. The absorbent medium includes a scaffold made of polymeric nanofiber. The polymeric nanofiber is decorated with silica nanoparticles. 1. An absorbent medium comprising a scaffold made of polymeric nanofiber , wherein , the polymeric nanofiber is decorated with silica nanoparticles.2. The absorbent medium of claim 1 , wherein the polymeric nanofiber is made of a polymer selected from a group consisting of polymethyl methacrylate (PMMA) claim 1 , polyvinyl alcohol (PVA) claim 1 , nylon claim 1 , polystyrene (PS) claim 1 , polyamide claim 1 , polyethylene terephthalate (PET) claim 1 , polybutylene terephthalate (PBT) claim 1 , polyethylene (PE) claim 1 , polypropylene (PP) claim 1 , polyolefin claim 1 , polyethylene oxide (PEO) claim 1 , polyphenol formaldehyde (PPF) claim 1 , polyvinyl chloride (PVC) claim 1 , aromatic polyamide claim 1 , polyacrylonitrile (PAN) claim 1 , polyurethane (PU) claim 1 , or combinations thereof.3. The absorbent medium of claim 1 , wherein the silica nanoparticles have a mesoporous structure.4. The absorbent medium of claim 1 , wherein the silica nanoparticles are made using a silica source selected from a group consisting of tetraethyl orthosilicate (TEOS) claim 1 , 2-[methoxy(polyethyleneoxy)propyl]trimethoxysilane (PEGTMS) claim 1 , (3-glycidoxypropyl)trimethoxysilane (GPTES) claim 1 , triethoxysilane (APTES) claim 1 , trimethoxysilyl-propyl diethylene triamine (DETA) claim 1 , or combinations thereof.5. The absorbent medium of claim 1 , wherein the polymeric nanofiber has a diameter of less than 100 nanometer.6. The absorbent medium of claim 1 , wherein the silica nanoparticles have a diameter less than 100 nanometer.7. The absorbent medium of claim 1 , wherein the absorbent medium is in the form of a membrane.8. A solid bed for isolating a biological molecule claim 7 , the solid bed comprising a plurality of the absorbent mediums according to claim 7 , stacked in a ...

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Номер записи: 18
21-01-2016 дата публикации

ORGANIC-INORGANIC HYBRID MATERIAL OF USE FOR EXTRACTING URANIUM (VI) FROM AQUEOUS MEDIA CONTAINING PHOSPHORIC ACID, PROCESSES FOR PREPARING SAME AND USES THEREOF

Номер: US20160016150A1
Автор: Arrachart Guilhem, El Mourabit Sabah, Goettmann Frédéric, Grandjean Agnès, Pellet-Rostaing Stephane, Turgis Raphaël
Принадлежит:

The invention relates to an organic-inorganic hybrid material which comprises an inorganic solid support on which are grafted organic molecules of the general formula (I) hereafter:

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Номер записи: 19
17-01-2019 дата публикации

SUPERFICIALLY POROUS MATERIALS COMPRISING A COATED CORE HAVING NARROW PARTICLE SIZE DISTRIBUTION; PROCESS FOR THE PREPARATION THEREOF; AND USE THEREOF FOR CHROMATOGRAPHIC SEPARATIONS

Номер: US20190015815A1
Автор: Fairchild Jacob Nathan, Lawrence Nicole L., Walsh Daniel P., Wyndham Kevin Daniel
Принадлежит:

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are chromatographic materials comprising having a narrow particle size distribution. 1. A superficially porous material comprising a coated core and one or more layers of a porous shell material surrounding the coated core , wherein said coated core comprises a substantially nonporous core material coated with a core-coating material.2. The superficially porous material of claim 1 , wherein the material is comprised of superficially porous particles.3. The superficially porous material of claim 1 , wherein the material is a superficially porous monolith.4. The superficially porous material of claim 2 , wherein the material has a substantially narrow particle size distribution.5. The superficially porous material of claim 2 , wherein the substantially nonporous core material has a substantially narrow particle size distribution.6. The superficially porous material of claim 2 , wherein the 90/10 ratio of particle sizes is from 1.00-1.55.7. The superficially porous material of claim 6 , wherein the 90/10 ratio of particle sizes is from 1.00-1.10.8. The superficially porous material of claim 7 , wherein the 90/10 ratio of particle sizes is from 1.05-1.10.9. The superficially porous material of claim 6 , wherein the 90/10 ratio of particle sizes is from 1.10-1.55.10. The superficially porous material of claim 9 , wherein the 90/10 ratio of particle sizes is from 1.10-1.50.11. The superficially porous material of claim 10 , wherein the 90/10 ratio of particle sizes is from 1.30-1.45.12. The superficially porous material of claim 1 , wherein the material has chromatographically enhancing pore geometry.13. The ...

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Номер записи: 20
17-01-2019 дата публикации

Low Cost Immobilized Amine Regenerable Solid Sorbents

Номер: US20190015816A1
Автор: Chuang Steven S.C.
Принадлежит: THE UNIVERSITY OF AKRON

A method of modifying a chemical interaction between a functional group of an immobilized amine in a solid sorbent composition and a compound that chemically interacts with the functional group to reduce the heat required to desorb the compound from the solid sorbent. A method of inhibiting degradation of an immobilized amine in an immobilized amine solid sorbent. Compositions and methods of use of a low-cost regenerable immobilized amine solid sorbent resistant to degradation. 1. A method of removing a compound from a gas stream comprising: i. an immobilized amine susceptible to chemosorbing the compound,', 'ii. an alcohol species capable of lowering the threshold temperature for dissociation of the bond between the compound and the amine, and', 'iii. an inorganic base,, 'a. employing a regenerable solid sorbent in the gas stream, wherein the regenerable solid sorbent comprises,'}b. allowing the regenerable solid sorbent to adsorb the compound from the gas stream, and;c. heating the solid sorbent to a temperature above the threshold temperature for dissociation of the bond between the adsorbed compound and the immobilized amine, but below the threshold temperature for dissociation of the immobilized amine.2. The method of wherein the gas stream is flue gas claim 1 , the compound is CO claim 1 , the solid support is SiO claim 1 , the amine is an aliphatic amine claim 1 , the adhesive is an epoxy claim 1 , the alcohol species is a polyethylene glycol and the inorganic base is NaCO.3. The method of wherein the gas stream is flue gas and the compound is SO claim 1 , the solid support is SiO claim 1 , the amine is an aromatic amine claim 1 , the adhesive is an epoxy claim 1 , the alcohol species is a polyethylene glycol and the inorganic base is NaCO.4. A regenerable immobilized amine solid sorbent composition comprising:a. a solid support particle, 'i. wherein the immobilized amine comprises an adhesive and an amine susceptible to adsorbing a compound,', 'b. an ...

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Номер записи: 21
21-01-2021 дата публикации

MEMBRANES COMPRISING A LAYER OF METAL ORGANIC FRAMEWORK PARTICLES

Номер: US20210016232A1
Автор: Liu Kangsheng
Принадлежит:

A filtration membrane that includes a porous substrate layer and an active layer arranged over at least a part of the substrate layer. The active layer comprises a metal-organic framework (MOF). Also disclosed are methods for of producing a filtration membrane and uses of the filtration membrane for water treatment. 1. A filtration membrane , the membrane comprising a porous substrate layer and an active layer arranged over at least a part of the substrate layer , wherein the active layer comprises a metal-organic framework (MOF).2. A method of producing the filtration membrane claim 1 , according to claim 1 , wherein the membrane comprises a porous substrate layer and an active layer arranged over at least a part of the substrate layer claim 1 , wherein the active layer comprises a metal-organic framework (MOF) claim 1 , the method comprising the steps of:a. optionally preparing the substrateb. contacting the substrate with a coating composition comprising the MOF;c. optionally, drying the membrane.3. A filtration membrane wherein the membrane comprises a porous substrate layer and an active layer arranged over at least a part of the substrate layer claim 2 , wherein the active layer comprises a metal-organic framework (MOF) claim 2 , wherein the filtration membrane is formed by the method of .4. A coating composition for use in the manufacture of filtration membranes for use in gravity claim 2 , pressure claim 2 , or vacuum deposition claim 2 , or printing of filtration membranes claim 2 , the composition comprising at least one metal-organic framework material or precursor thereof.5. The membrane of claim 1 , wherein the substrate is a polymeric substrate claim 1 , a ceramic substrate claim 1 , a composite substrate claim 1 , an inorganic-organic substrate and/or a metal substrate.6. The membrane according to claim 5 , wherein the ceramic porous substrate is formed one or more of zeolite claim 5 , silicon claim 5 , silica claim 5 , alumina claim 5 , zirconia ...

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Номер записи: 22
21-01-2021 дата публикации

METHOD FOR IN-SITU SYNTHESIS OF METAL ORGANIC FRAMEWORKS (MOFs), COVALENT ORGANIC FRAMEWORKS (COFs) AND ZEOLITE IMIDAZOLATE FRAMEWORKS (ZIFs), AND APPLICATIONS THEREOF

Номер: US20210016245A1
Автор: . Sonia, Chauhan Anjali, Choudhary Anil Kumar, Jha Vivek Kumar, Pahwa Deepak, Pahwa Varun, Yadav Annu
Принадлежит:

The present invention relates to method for the synthesis in-situ of the class of compounds known generally as MOFs (metal organic frameworks or organometallic compounds), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), within and onto different types of substrates, and to the applications of such substrates having in-situ synthesized MOFs, COFs and ZIFs. 1. A method for the in situ synthesis of MOFs , COFs , or ZIFs , onto and within a porous substrate by contacting the porous substrate with a first solution and a second solution , wherein the first and second solutions are capable of forming the said MOFs , COFs , or ZIFs.2. A method as claimed in wherein the porous substrate is contacted with the first solution and the second solution claim 1 , sequentially in any order or simultaneously as a mixture of the two solutions.3. A method as claimed in or wherein the first solution and/or the second solution comprise a mixture of two or more solutions claim 1 , wherein the resulting adsorbent synthesized in situ is either one or more MOFs claim 1 , COFs claim 1 , or ZIFs or a combination of one or more of MOFs claim 1 , COFs or ZIFs with an inorganic adsorbent.4. A method as claimed in to wherein the contacting is done by dipping or soaking.5. A method as claimed in any preceding claim wherein dipping/soaking time claim 1 , temperature claim 1 , pressure claim 1 , concentration claim 1 , and viscosity for both the first solution and the second solution are optimized with or without use of enhancers or retarders.6. A method as claimed in any preceding claim wherein the ratio of the in situ synthesized adsorbent to substrate is in the range of 0.1 to 6 times by weight of the adsorbent to the bare substrate claim 1 , preferably in the range of 0.5 to 4 times by weight of the bare substrate claim 1 , and more preferably in the range of 1.5 to 3 times by weight of the bare substrate.7. A method as claimed in any preceding claim wherein the ...

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Номер записи: 23
21-01-2021 дата публикации

Multi-Functionalized Basic Immobilized Amine Sorbents for Removal of Metal Contaminants from Wastewater

Номер: US20210016246A1
Автор: Gray McMahan L., Kail Brian W., Shi Fan, Wang Qiuming, Wilfong Walter Christopher
Принадлежит:

This disclosure provides polyamine sorbent compositions for the separation of metals from aqueous solutions. The polyamine sorbent compositions comprise a silica support, an aminosilane bound to the silica support, an epoxysilane bound to the silica support, and a polyamine where the polyamine is chemically tethered onto a solid silica support through via the epoxysilane. The polyamine may be further stabilized within the bulk sorbent through hydrogen bonding interactions with the aminosilane. The sorbent compositions resist leaching by HO in an aqueous stream containing heavy oxyanion-based (and other) metals and demonstrate stability over a pH range of 2-14. The sorbent compositions are useful for the separation of metals from aqueous solutions. The cationic heavy metals are captured by the co-existing amine groups (—NH, —NH, —N) from the polymeric network while additional metal capture capacity is derived from the introduction of a secondary silane linker. 1. An immobilized amine solid sorbent composition , the composition comprising:a. a silica support;b. an aminosilane bound to the silica support;c. an epoxysilane bound to the silica support; and,d. a polyamine bound to the epoxysilane.2. The composition of claim 1 , where the polyamine is further bound to the aminosilane.3. The composition of claim 2 , where the polyamine is further bound to the aminosilane by hydrogen bonding.4. The composition of claim 1 , where the aminosilane is N-(3-trimethoxysilyl) propyl)ethylenediamine5. The composition of claim 1 , where the aminosilane is N-(3-trimethoxysilylpropyl)diethylenetriamine.6. The composition of claim 1 , where the epoxysilane is 2-(3 claim 1 ,4-epoxycyclohexyl)ethyltrimethoxysilane.7. The composition of claim 1 , where the epoxysilane is 2-(3 claim 1 ,4-epoxycyclohexyl)ethyltriethoxysilane.8. The composition of claim 1 , where the polyamine has a molecular weight ranging from 200 g/mol to 20 claim 1 ,000 g/mol claim 1 ,9. The composition of claim 1 , where ...

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Номер записи: 24
28-01-2016 дата публикации

Method of preparing adsorbent for phosphorus adsorption and adsorbent prepared by the same

Номер: US20160023184A1
Автор: Kim Jahyun, Lee Jeakeun, Lee Taeyoon, Lim Junheok
Принадлежит:

The present invention relates to a method for preparing an adsorbent for phosphorus adsorption and an adsorbent prepared by the method. More specifically, the present invention is based on the fact that phosphorus has a strong affinity for the surface of metal oxides or hydroxides, and relates to a method for preparing an adsorbent for phosphorus adsorption, which comprises absorbing and coating expanded vermiculite with aluminum and heating the coated vermiculite at high temperature to produce aluminum oxide on the surface of the expanded vermiculite so that the adsorption of phosphorus at the coordination of the oxide can be achieved with very high efficiency by a strong attraction between phosphorus ions and aluminum ions, and to an adsorbent prepared by the method. 1. A method for preparing an adsorbent for phosphorus adsorption , the method comprising absorbing and coating expanded vermiculite with a solution of aluminum nitrate (Al(NO)9H2O) and heating the coated vermiculite.2. The method according to claim 1 , comprising the steps of:{'b': '100', '(S) adding sodium hydroxide (NaOH) to an aluminum nitrate solution to adjust the pH of the solution;'}{'b': 200', '100, '(S) adding expanded vermiculite to the aluminum nitrate solution whose pH has been adjusted in step S;'}{'b': 300', '200, '(S) primarily heating the expanded vermiculite on which has been absorbed and coated with the aluminum nitrate solution in S; and'}{'b': 400', '300, '(S) washing the expanded vermiculite primarily heated in step S, and secondarily heating the washed vermiculite, followed by cooling.'}3100. The method according to claim 1 , wherein step S is performed by adding sodium hydroxide to adjust the pH of the aluminum nitrate solution to 12.0±0.5.4200100. The method according to claim 1 , wherein step S is performed by adding 40-60 g of the expanded vermiculite per 100 mL of the aluminum nitrate solution whose pH has been adjusted in step S.5300200. The method according to claim 1 , ...

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Номер записи: 25
10-02-2022 дата публикации

CARBON DIOXIDE ADSORBENT AND CARBON DIOXIDE PROCESSING SYSTEM

Номер: US20220040667A1
Автор: Iwasaki Hidekazu, KAWANO Akihito, NEGAMI Masahiro, NISHIBE Shohei, NOMURA Yoshimichi, Okumura Takeshi, YOSHIZAWA Katsuhiro
Принадлежит: KAWASAKI JUKOGYO KABUSHIKI KAISHA

A carbon dioxide adsorbent including silica gel and an amine compound carried by the silica gel. The silica gel has a spherical shape, a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, a pore volume ranging from 0.1 cm/g to 1.3 cm/g inclusive, and a waterproof property N that is defined by an expression (1) and that is not lower than 45%, 1. A carbon dioxide adsorbent comprisingsilica gel andan amine compound that is carried by the silica gel,{'sup': 3', '3, 'claim-text': {'br': None, 'i': N', 'W/W, 'sub': '0', '=()×100\u2003\u2003(1)'}, 'wherein the silica gel has: (i) a spherical shape, (ii) a particle size ranging from 1 mm to 5 mm inclusive, (iii) an average pore diameter ranging from 10 nm to 100 nm inclusive, (iv) a pore volume ranging from 0.1 cm/g to 1.3 cm/g inclusive, and (v) a waterproof property N that is defined by an expression (1) and that is not lower than 45%,'}whereN is the waterproof property in percentage (%) of the silica gel,{'sub': '0', 'Wis a total number of particles of the silica gel immersed in water,'}{'sub': '0', 'W is a number of particles of the silica gel not subjected to breakage out of W.'}2. The carbon dioxide adsorbent according to claim 1 , wherein the amine compound is at least one compound selected from a group of amines having at least one hydroxyl group and polyamines.3. The carbon dioxide adsorbent according to claim 1 , whereinthe silica gel has an average pore diameter in a range of from 10 nm to less than 100 nm, andthe amine compound is an amine compound that reversibly desorbs carbon dioxide.4. The carbon dioxide adsorbent according to claim 1 , wherein the silica gel has an average pore diameter in a range of from 10 nm to 80 nm.5. A carbon dioxide processing system comprising an adsorption vessel including a moving bed claim 1 , the moving bed being formed in an interior of the adsorption vessel by the carbon dioxide adsorbent according to claim 1 , ...

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Номер записи: 26
10-02-2022 дата публикации

SUPPORTED POLY(ALLYL)AMINE AND DERIVATIVES FOR CO2 CAPTURE FROM FLUE GAS OR ULTRA-DILUTE GAS STREAMS SUCH AS AMBIENT AIR OR ADMIXTURES THEREOF

Номер: US20220040669A1
Автор: Bali Sumit, Jones Christopher W., Khunsupat Ratayakorn
Принадлежит:

Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO.sub.2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-.gamma.-alumina, as well on mesoporous-.gamma.-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials. 1. A supported CO.sub.2 adsorbent comprising a porous substrate on and in which is infused an active adsorbent for CO.sub.2 selected from the group consisting of poly(allylamine) , cross-linked poly(allylamine) with epichlorhydrin and guanidylated poly(allylamine).2. The supported CO.sub.2 adsorbent of claim 1 , wherein the CO2 adsorbent has an average molecular weight of not greater than about 5000 Daltons.3. The supported CO.sub.2 adsorbent of claim 1 , wherein the adsorbent is poly(allylamine) claim 1 , having an average molecular weight of not greater than about 3000 Daltons.4. The supported CO.sub.2 adsorbent of claim 2 , wherein the adsorbent is a cross-linked poly(allylamine) cross-linked with epichlorhydrin.5. The supported CO.sub.2 adsorbent of claim 1 , wherein the average molecular weight of the poly(allylamine) material claim 1 , is in the range of from about 500 to about 2200 Daltons.6. The supported CO.sub.2 adsorbent of claim ...

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Номер записи: 27
28-01-2021 дата публикации

SURFACE FUNCTIONALISED MATERIALS FOR SAMPLING BIOLOGICAL MOLECULES

Номер: US20210023534A1
Автор: JONES Paul Antonio
Принадлежит:

The invention relates to materials, methods and devices useful for sampling biological molecules, including biomarkers and/or metabolites. In particular, the invention relates to surface functionalised xerogels and surface functionalised poly(dimethyl) siloxane (PDMS), devices comprising those materials, and methods of using the materials and devices for sampling, analysing or detecting biological molecules. 1. A surface-functionalised xerogel comprising a functional group capable of selectively binding to a biological molecule from a subject.2. A surface-functionalised xerogel according to claim 1 , wherein the biological molecule is from a mucous membrane or biological fluid.3. A surface-functionalised xerogel according to or claim 1 , for insertion into: a body orifice claim 1 , typically a nostril claim 1 , ear canal claim 1 , mouth claim 1 , anus/rectum claim 1 , vagina claim 1 , or urethra; or a body cavity; or a bodily tube claim 1 , typically a fallopian tube.4. A surface-functionalised xerogel according to any of to claim 1 , wherein the functional group is capable of selectively binding to a cell claim 1 , protein claim 1 , lipid or nucleic acid biomarker claim 1 , or metabolite.5. A surface-functionalised xerogel according to any preceding claim claim 1 , wherein the surface-functionalised xerogel is a silica xerogel.6. A surface-functionalised xerogel according to any preceding claim claim 1 , wherein the functional group is selected from an antigen-binding protein claim 1 , a nucleic acid claim 1 , a lipid-binding moiety claim 1 , a sugar or glycoprotein; or a block group-presenting co-polymer.7. A surface-functionalised xerogel according to claim 6 , wherein:{'sub': 4', '20, 'a. the lipid-binding moiety comprises a C-Calkyl silicate functionalised silica xerogel, optionally an octadecylsilyl (ODS) group; or'}b. the sugar is mannose; orc. the antigen-binding protein is an antibody or an antigen-binding fragment thereof.8. A surface functionalised ...

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Номер записи: 28
02-02-2017 дата публикации

Methods, compositions and devices for maintaining chemical balance of chlorinated water

Номер: US20170029304A1
Автор: Vivian I. Teichberg
Принадлежит: Mia Levite, Nof Lyle Teichberg, Yaar Teichberg

A composition-of-matter for use in water treatment, composed of a water-insoluble matrix and one or more amidohydrolase, such as cyanuric acid amidohydrolase, incorporated in or on the matrix, is disclosed. Also disclosed are devices containing same and methods utilizing same for water treatment. The water treatment is effected by an enzymatically-catalyzed reduction of the concentration of an amide-containing compound, such as cyanuric acid, found in chlorinated water of swimming polls, spas and other similar structures.

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Номер записи: 29
01-05-2014 дата публикации

Sorbent article for co2 capture

Номер: US20140116250A1
Автор: Dayue Jiang, Jianguo Wang, Zhen Song
Принадлежит: Corning Inc

A sorbent article having a substrate having porous channel walls defining open channels, and an organic-inorganic hybrid sorbent material distributed on a surface of the porous channel walls, wherein the sorbent material is derived from an amino-functionalized alkoxysilane and a polyamine, wherein the sorbent material is present in an amount equal to or greater than 10 g/l, wherein at least some of the sorbent material resides in the porous channel walls and forms CO 2 adsorption sites within the interior of the porous channel walls. The article may be useful, for example, for removing CO 2 from a gas.

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Номер записи: 30
04-02-2021 дата публикации

MOISTURE AND HYDROGEN ADSORPTION GETTER AND METHOD OF FABRICATING THE SAME

Номер: US20210031167A1
Автор: CHOA YONGHO, EOM Nusia, LIM Hyoryoung
Принадлежит: Industry-University Cooperation Foundation Hanyang University ERICA Campus

A moisture and hydrogen adsorption getter is provided. The moisture and hydrogen adsorption getter includes a silicon substrate including a concave portion and a convex portion, a silicon oxide layer conformally provided along a surface of the concave portion and a surface of the convex portion and configured to adsorb moisture, and a hydrogen adsorption pattern disposed on the silicon oxide layer. A portion of the silicon oxide layer is exposed between portions of the hydrogen adsorption pattern. 1. A method of fabricating a moisture and hydrogen adsorption getter , the method comprising:preparing a silicon substrate including a concave portion and a convex portion;forming a silicon oxide layer for adsorbing moisture by immersing the silicon substrate in an acid solution; andforming a hydrogen adsorption pattern on the silicon oxide layer.2. The method of claim 1 , further comprising:forming a plurality of holes extending downward from surfaces of the concave portion and the convex portion before the forming of the silicon oxide layer.3. The method of claim 2 , wherein the forming of the holes comprises:forming a metal thin layer on the concave portion and the convex portion;thermally treating the metal thin layer formed on the concave portion and the convex portion to form metal particles; andforming the holes extending downward from the surfaces corresponding to the metal particles by a method of etching the silicon substrate including the concave portion and the convex portion by using the metal particles as a catalyst.4. The method of claim 1 , wherein the preparing of the silicon substrate comprises:forming a mask film that covers a first region of the silicon substrate and exposes a second region of the silicon substrate; andimmersing the silicon substrate in a basic solution to form the concave portion and the convex portion on the second region of the silicon substrate.5. The method of claim 1 , wherein the forming of the hydrogen adsorption pattern ...

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Номер записи: 31
04-02-2021 дата публикации

SUPERIOR CORE-IN-SHELL COMPONENT COMPOSITE ADSORBENTS FOR VSA/VPSA/PSA SYSTEMS

Номер: US20210031171A1
Автор: Barrett Philip A., Pontonio Steven J., Stephenson Neil A., Stuckert Nicholas R.
Принадлежит:

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. 2. The composite of having an attrition loss of less than or equal to 5 wt %.3. The composite of wherein said adsorbent shell comprises one or more of zeolites claim 1 , aluminas claim 1 , silicas claim 1 , carbons claim 1 , activated carbons claim 1 , molecular organic frameworks (MOFs) claim 1 , transition metal substituted silicas claim 1 , zincosilicates claim 1 , titanosilicates and mixtures thereof.4. The composite of wherein said adsorbent shell comprises one or more zeolites.5. The composite of wherein said zeolite is selected from LSX claim 4 , Y claim 4 , A claim 4 , L claim 4 , ZSM-5 claim 4 , Mordenite claim 4 , Clinoptilolite claim 4 , Chabazite and mixtures thereof.6. The composite of wherein said zeolite has a SiO2/AlOratio of from about 1.9 to 10 claim 5 , and wherein the zeolite contains cations selected from H claim 5 , Li claim 5 , Na claim 5 , K claim 5 , Mg claim 5 , Ca claim 5 , Sr claim 5 , Ba claim 5 , Ag claim 5 , Cu and mixtures thereof.7. The composite of wherein the adsorbent is LiX wherein the extent of Li exchange is greater than or equal to 90% on an equivalents basis.8. The composite of wherein said adsorbent shell comprises from about 1-20 wt % binder.9. The composite of wherein said adsorbent shell comprises from about 2-12 wt % binder.10. The composite of wherein said adsorbent shell comprises 0-5 wt % of at least one coating aid.11. The composite of wherein the binder is selected from clays claim 8 , aluminas claim 8 , silicas claim 8 , alumina-silica reagents and hydroxides that claim 8 , upon calcination become alumina-silica.12. The composite of ...

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Номер записи: 32
30-01-2020 дата публикации

Sorbent and Devices for Capturing, Stabilizing and Recovering Volatile and Semi-volatile Compounds

Номер: US20200033236A1
Автор: APBLETT Allen W., MATERER Nicholas F., SHAIKH Shoaib F.
Принадлежит: XPLOSAFE, LLC

The present invention provides an improved sorbent and corresponding device(s) and uses thereof for the capture and stabilization of volatile organic compounds (VOC) or semi-volatile organic compounds (SVOC) from a gaseous atmosphere. The sorbent is capable of rapid and high uptake of one or more compounds and provides quantitative release (recovery) of the compound(s) when exposed to elevated temperature and/or organic solvent. Uses of particular improved grades of mesoporous silica are disclosed. 3. A device for passive sampling of volatile organic compound or semi-volatile organic compound in air or gaseous environment , the device comprising:a sorbent holder comprising two or more separate and independently unsealable and independently resealable chambers, wherein a first one of said chambers comprises a first portion of sorbent, and a second one of said chambers comprises a second portion of sorbent.4. The device of further comprising a diffuser comprising plural ports claim 3 , pores or perforations through which said VOC or SVOC must pass to contact said portions of sorbent.5. A method of providing plural samples of sorbent differing in exposure time limit claim 3 , the method comprising:providing a device comprising plural separate sections of sorbent, each section in a respective sealed receptacle;unsealing a first receptacle comprising a first section of sorbent, exposing said first section to VOC or SVOC for a first period of time, and then sealing the first receptacle;unsealing a second receptacle comprising a second section of sorbent, exposing said second section to VOC or SVOC for a second period of time, and then sealing the second receptacle; whereinthe first and second receptacles can be unsealed at the same or different times.6. The method of claim 5 , wherein: a) the first and second receptacles are separately (independently) sealable; b) the first and second receptacles are separately (independently) unsealable; c) the first period of time is ...

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Номер записи: 33
07-02-2019 дата публикации

Carbon dioxide sorbents for air quality control

Номер: US20190039047A1
Автор: David WEINBERGER, Jeffrey Alan Levine, John KAUFFMAN, Mark Buelow, Pascaline Tran, Riichiro Kimura, Sai Ping Shum, Wolfgang Ruettinger
Принадлежит: BASF Corp

Disclosed in certain embodiments are carbon dioxide and VOC sorbents that include a porous support impregnated with an amine compound.

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Номер записи: 34
18-02-2021 дата публикации

CHROMATOGRAPHIC COMPOSITIONS

Номер: US20210046450A1
Автор: Lauber Matthew A., Walsh Daniel P.
Принадлежит: WATERS TECHNOLOGIES CORPORATION

Provided herein are stationary phase compositions comprising a chromatographic surface of porous or non-porous core material comprising a surface modifier for use in chromatographic separations. 5. The stationary phase composition of claim 4 , wherein Ris trimethylsilyl.11. The stationary phase composition of claim 10 , wherein Ris trimethylsilyl.12. The stationary phase composition of claim 1 , wherein each b is 0 to 3.13. The stationary phase composition of claim 1 , wherein each b is 0.14. The stationary phase composition of claim 1 , wherein each a is 0 to 3.15. The stationary phase composition of claim 1 , wherein each a is 0.16. The stationary phase composition of claim 1 , wherein each x is 0 to 4.17. The stationary phase composition of claim 1 , wherein each x is 0.18. The stationary phase composition of claim 1 , wherein each y is 0 to 4.19. The stationary phase composition of claim 1 , wherein each y is 0.20. The stationary phase composition of claim 1 , wherein each Rand Rare independently aryl or (C-C)alkyl optionally substituted with cyano. This application is a continuation of U.S. application Ser. No. 15/921,811 entitled “Chromatographic Compositions” filed Mar. 15, 2018, which claims benefit of and priority to U.S. Provisional Application Nos. 62/472,342 entitled “Chromatographic Compositions” filed Mar. 16, 2017, and 62/543,654 entitled “Chromatographic Compositions” filed Aug. 10, 2017, the contents of each of which are incorporated herein by reference in their entirety.The technology relates generally to chromatographic compositions. The invention relates more particularly, in various embodiments, to stationary phase compositions comprising a chromatographic surface of porous or non-porous core material comprising a surface modifier for use in chromatographic separations.Liquid chromatography (LC) combined with mass spectrometry (MS) is one of the most powerful analytical tools for the characterization of proteins. Indeed, for the analysis of ...

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Номер записи: 35
15-02-2018 дата публикации

MATERIAL SUCH AS FILM, FIBER, WOVEN AND NONWOVEN FABRIC WITH ADSORBANCY

Номер: US20180043331A1
Автор: Wood Willard E.
Принадлежит:

Compositions that can be used to adsorb low concentration, of unwanted or target substances from a dynamic fluid stream or from an enclosed static vapor phase. Such adsorbency can be obtained with thermoplastic materials used in the form of bulk polymer or a film, fiber, web, woven fabric, non-woven fabric, sheet, packaging and other such structures including or surrounding the enclosed volume. The concentration should be reduced to non-offensive sensed limits or a limit that does not produce a biological response. 1. A method of making an adsorbent , the method comprising , in order:combining an aqueous floc of ferric hydroxide with an aqueous solution of a polyethylenimine to form a coating composition;applying the coating composition to a substrate; anddrying the coating composition on the substrate to form the adsorbent.2. The method of claim 1 , the method further comprising combining potassium ferrate with water to form the aqueous floc of the ferric hydroxide.3. The method of claim 2 , further comprising adding glycerol and ethanol to the aqueous floc of the ferric hydroxide.4. The method of claim 2 , comprising combining the potassium ferrate with the water and a pH buffer to form the aqueous floc of the ferric hydroxide.5. The method of claim 1 , the method further comprising combining a ferric salt and an alkaline hydroxide in water to form the aqueous floc of the ferric hydroxide.6. The method of claim 5 , wherein the ferric salt is selected from ferric chloride claim 5 , ferric nitrate claim 5 , ferric sulfate claim 5 , ferric citrate claim 5 , ferric ammonium citrate claim 5 , and ferric ammonium sulfate.7. The method of claim 5 , further comprising adjusting a pH of the coating composition to about 12.5 before the applying the coating composition to the substrate.8. The method of claim 1 , wherein the substrate is selected from a bulk polymer claim 1 , a polymer film claim 1 , a woven fabric claim 1 , a nonwoven fabric claim 1 , and a cellulosic paper. ...

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Номер записи: 36
08-05-2014 дата публикации

Temperature-responsive monolithic porous body, method for producing same, and temperature-responsive chromatography method using same

Номер: US20140124445A1
Автор: Akihiko Kikuchi, Hideko Kanazawa, Jun Kobayashi, Kenichi Nagase, Teruo Okano, Yoshikatsu Akiyama
Принадлежит: Cellseed Inc, Hideko Kanazawa, TOKYO WOMENS MEDICAL UNIVERSITY

A temperature responsive monolithic porous material is obtained that comprises a polymer having a hydration ability that changes in a temperature range of 0 to 80° C. and being immobilized to a surface of the porous material at a high density by binding an atom transfer radical polymerization initiator to a surface of the porous material, and inducing a growth reaction of a polymer, having a hydration ability that changes in a temperature range of 0 to 80° C., from the initiator using an atom transfer radical process under a presence of a catalyst.

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Номер записи: 37
13-02-2020 дата публикации

MESOPOROUS ALUMINA/HEMATITE COMPOSITE NANOFIBERS FOR HEAVY METAL REMOVAL

Номер: US20200047150A1
Автор: CWIERTNY David Michael, MYUNG Nosang V., NALBANDIAN Michael J.
Принадлежит: The Regents of the University of California

A method is disclosed of synthesizing θ-alumina/hematite (θ-AlO/FeO) composite nanofibers for removing heavy metals from a water source. The method includes preparing a polymer solution, the polymer solution comprising an iron precursor, acetic acid and a polymer; adding a select amount of an aluminum precursor to the polymer solution; and electrospinning the polymer solution and the select amount of the aluminum precursor to form the θ-AlO/FeOcomposite nanofibers. 1. A method of synthesizing θ-alumina/hematite (θ-AlO/FeO) composite nanofibers , the method comprising:preparing a polymer solution, the polymer solution comprising an iron precursor, acetic acid and a polymer;adding a select amount of an aluminum precursor to the polymer solution; and{'sub': 2', '3', '2', '3, 'electrospinning the polymer solution and the select amount of the aluminum precursor to form the θ-AlO/FeOcomposite nanofibers.'}2. The method of claim 1 , wherein the iron precursor is iron(III) 2-ethylhexano-isopropoxide and the polymer is polyvinylpyrrolidone (PVP).3. The method of claim 1 , wherein the aluminum precursor is an aluminum oxide hydroxide (AlOOH) nanopowder.4. The method of claim 3 , wherein the aluminum hydroxide (AlOOH) nanopowder is synthesized using aluminum isopropoxide (AIIP) claim 3 , acetic acid claim 3 , DI water and isopropanol.5. The method of claim 1 , comprising:maintaining a total amount of a metal precursor of Al and Fe to the polymer solution at 9 wt. %.6. The method of claim 1 , further comprising:{'sub': 2', '3', '2', '3, 'annealing the θ-AlO/FeOcomposite nanofibers.'}7. The method of claim 1 , further comprising:{'sub': 2', '3', '2', '3, 'synthesizing the θ-AlO/FeOcomposite nanofibers to an average diameter of 17 nm to 33 nm.'}8. The method of claim 1 , further comprising:{'sub': 2', '3', '2', '3, 'removing heavy metals from water with the θ-AlO/FeOcomposite nanofibers.'}9. The method of claim 8 , wherein the heavy metals include arsenic (As) claim 8 , chromium ...

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Номер записи: 38
22-02-2018 дата публикации

CARBON DIOXIDE SORBENTS FOR INDOOR AIR QUALITY CONTROL

Номер: US20180050322A1
Автор: Buelow Mark T., Kauffman John, KIMURA Riichiro, Tran Pascaline, Wosylus Aron
Принадлежит:

Disclosed in certain embodiments are carbon dioxide sorbents that include porous particles impregnated with an amine compound. 1. A sorbent comprising:a gas-adsorbing material comprising an amine compound;a hydroxyl-containing additive comprising at least one of glycerol, glycerin, pentaerythritol, sorbitol, sucrose, polyether, polyester, ethylene glycol, or a silicon-based compound; anda porous support impregnated with the gas-adsorbing material.2. The sorbent of claim 1 , wherein the gas-adsorbing material comprises diethanolamine or pentaethylenehexamine claim 1 , and wherein the hydroxyl-containing additive comprises glycerol claim 1 , wherein the gas-adsorbing material and the hydroxyl-containing additive are mixed together forming a coating on the porous support.3. (canceled)4. The sorbent of claim 1 , wherein the hydroxyl-containing additive comprises the silicon-based compound claim 1 , wherein the silicon-based compound forms a silicon-based coating on the porous support claim 1 , and wherein the gas-adsorbing material is coated onto the silicon-based coating.5. The sorbent of claim 4 , wherein silicon-based coating is present in an amount ranging from greater than 0% to 20% of a total weight of the porous support and the silicon-based coating claim 4 , and wherein the amine compound is present in an amount ranging from 20% to 40% of a total weight of the sorbent.69-. (canceled)10. The sorbent of claim 1 , wherein a weight loss of the sorbent after performing an attrition test is less than 3% claim 1 , and a COadsorption capacity of the sorbent is greater than 6 g/L when the sorbent is maintained at a temperature greater than 20° C. and less than 40° C.1113-. (canceled)14. The sorbent of claim 4 , wherein the silicon-based coating was formed by treating the porous support with one or more of tetraethylorthosilicate claim 4 , colloidal silica claim 4 , or sodium silicate.15. (canceled)16. The sorbent of claim 1 , wherein a COadsorption capacity of the ...

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Номер записи: 39
01-03-2018 дата публикации

Manganese dioxide nanowire @ multidimensional mesoporous metal-organic framework adsorbent and preparation therefor

Номер: US20180056269A1
Автор: JIAN Meipeng, Liu Bao, LIU Huijuan, Liu Ruiping, QU Jiuhui, Wang Huan
Принадлежит:

A manganese dioxide nanowire @ multidimensional mesoporous metal-organic framework adsorbent and application method thereof for removing heavy metals from water. A multidimensional mesoporous metal-organic framework material is prepared from metal ions and organic ligands by means of a self-assembly reaction; a manganese dioxide nanowire is prepared from manganese salt and thiosulfate by means of reaction in a reaction kettle. The adsorbent possesses not only the characteristics of a multidimensional mesoporous metal-organic framework material, such as reticulated pore adaptation, a large specific surface area, and abundant reaction sites, but also the oxidative and catalytic properties of manganese dioxide nanowire. 1. A manganese dioxide nanowire @ multi-dimensional mesoporous metal organic framework adsorbent , wherein the adsorbent is prepared by loading multi-dimensional mesoporous metal organic frameworks on the surface of manganese dioxide nanowires , the preparation method comprises the following steps:(1) respectively preparing a manganese salt solution and a thiosulfate solution to prepare a manganese dioxide nanowire;(2) respectively preparing a methanol solution of imidazole, a methanol solution of acetate and a methanol solution of zinc salt; wherein, the molar ratio of the zinc salt to the acetate is 1:4˜4:1; the molar ratio of the zinc salt to the imidazole is 1:5˜1:40;(3) putting the manganese dioxide nanowires into methanol, and carrying out ultrasonic treatment for 30˜120 min, in which the mass ratio of the manganese dioxide nanowires to the methanol is 1:100˜1:500;(4) sequentially adding the methanol solution of imidazole, the methanol solution of zinc salt and the methanol solution of acetate with the same volume as the volume of methanol used in step (3), then reacting for 120˜240 min under an ultrasonic condition;(5) separating a solid from the solution by adopting a solid-liquid separation method, then obtaining the manganese dioxide nanowire ...

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Номер записи: 40
02-03-2017 дата публикации

Process For Extracting A Surfactant Using A Boronic Acid Modified Material

Номер: US20170057840A1
Автор: Kevin L. BICKER, Robert William Tilford
Принадлежит: Individual

A process for extracting a surfactant from a mixture using a boronic acid modified material.

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Номер записи: 41
04-03-2021 дата публикации

Water Deodorizer and Method for Making It

Номер: US20210061692A1
Автор: Chih-Chieh Lin, Wen-Lung Chin
Принадлежит: Individual

A method includes preparing a natural seashell, calcining the seashell at a high temperature to clear organic substances from the seashell, processing and reacting the seashell at a high temperature, grinding and screening the seashell, and mixing the ground seashell with microorganism strains to form a water deodorizer. The water deodorizer includes a powder having a porous structure, and multiple microorganism strains mixed with the powder. The powder has an interior provided with a plurality of pores. The powder is made of a natural seashell which is processed at a high temperature, and is ground and screened to form the porous structure. The microorganism strains are filled in the pores of the powder and cover outer surfaces of the pores of the powder. The powder has a diameter of 0.4-10 μm.

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Номер записи: 42
20-02-2020 дата публикации

Surfactant product, manufacturing method and use thereof in oil and gas well operations

Номер: US20200056088A1
Автор: Raynard Veldman
Принадлежит: Veldman Consulting Corp

The application is directed to treating wells and subterranean formations in oil and gas well operations using surfactants. Solid treatment particles may be produced comprising one or more solid adsorbent materials and one or more surfactants adsorbed on the one or more solid adsorbent materials. The solid treatment particles are operationally configured to be introduced into wells and/or subterranean formations to carry out one or more treatments in various aspects of a life cycle of oil wells and gas wells.

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Номер записи: 43
28-02-2019 дата публикации

MOISTURE AND HYDROGEN-ABSORBING GETTER AND METHOD FOR MANUFACTURING SAME

Номер: US20190060863A1
Автор: CHOA YONGHO, EOM Nusia, LIM Hyoryoung
Принадлежит: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY ERICA CAMPUS

A moisture and hydrogen adsorption getter is provided. The moisture and hydrogen adsorption getter includes a silicon substrate including a concave portion and a convex portion, a silicon oxide layer conformally provided along a surface of the concave portion and a surface of the convex portion and configured to adsorb moisture, and a hydrogen adsorption pattern disposed on the silicon oxide layer. A portion of the silicon oxide layer is exposed between portions of the hydrogen adsorption pattern. 1. A moisture and hydrogen adsorption getter comprising:a silicon substrate including a concave portion and a convex portion;a silicon oxide layer conformally provided along a surface of the concave portion and a surface of the convex portion and configured to adsorb moisture; anda hydrogen adsorption pattern disposed on the silicon oxide layer,wherein a portion of the silicon oxide layer is exposed between portions of the hydrogen adsorption pattern.2. The moisture and hydrogen adsorption getter of claim 1 , wherein the silicon substrate further includes a plurality of holes extending downward from the surfaces of the concave portion and the convex portion.3. The moisture and hydrogen adsorption getter of claim 2 , wherein the silicon oxide layer is conformally provided along inner surfaces of the holes.4. The moisture and hydrogen adsorption getter of claim 2 , further comprising:a plurality of metal particles provided in the plurality of holes, respectively.5. The moisture and hydrogen adsorption getter of claim 4 , wherein the metal particles provided in the holes includes at least one of Pt claim 4 , Ag claim 4 , or Pd.6. The moisture and hydrogen adsorption getter of claim 1 , further comprising:passivation metal catalyst particles provided on the hydrogen adsorption pattern.7. The moisture and hydrogen adsorption getter of claim 6 , wherein the passivation metal catalyst particles include at least one of Ag claim 6 , Pd claim 6 , or Pt.8. The moisture and hydrogen ...

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Номер записи: 44
28-02-2019 дата публикации

CORROSION-RESISTANT, REACTIVE ADSORBENT FOR TREATMENT OF CONTAMINATED WATER, METHODS FOR PRODUCING SAME AND USE THEREOF

Номер: US20190060872A1
Автор: BLEYL Steffen, GEORGI Anett, KOPINKE Frank-Dieter, MACKENZIE Katrin, VOGEL Maria
Принадлежит: Helmholtz-Zentrum für Umweltforschung GmbH - UFZ

The invention relates to a corrosion-resistant, reactive adsorbent which is made up of element iron on a carbon carrier plus sulfur and additional phosphorus as well as a method for producing this reactive adsorbent and use thereof for removal of reductively degradable pollutants in contaminated groundwater and wastewater. 1. A corrosion-resistant , reactive adsorbent containing sulfur and phosphorus in addition to zero-valent iron in nanoparticulate form on a carbon carrier.2. The reactive adsorbent according to claim 1 , characterized in that it contains 10 to 40 wt % zero-valent iron claim 1 , 40 to 70 wt % carbon claim 1 , 0.01 to 5 wt % P and 0.01 to 5 wt % S.3. The reactive adsorbent according to claim 2 , characterized in that it contains 0.1 to 2 wt % P and 0.1 to 2 wt % S.4. A method for producing a reactive adsorbent according to claim 1 , characterized in that a basic composite material of zero-valent iron in nanoparticulate form is created on a carbon carrier and is converted to a form that is reactive and corrosion-resistant at the same time by means of a combined treatment with phosphorus and sulfur compounds in aqueous suspension.5. The method according to claim 4 , characterized in that to create the basic composite material claim 4 , the carbon carrier is loaded with an iron compound by wet impregnation claim 4 , and then the iron is reduced to zero-valent iron in a nanoparticulate form by means of a thermal treatment after drying.6. The method according to claim 5 , characterized in that a water-soluble iron(III) compound is used as the iron compound for impregnation.7. The method according to claim 4 , characterized in that the thermal treatment is carried out as a carbo-thermal treatment in a stream of nitrogen at temperatures up to 800° C. or in a stream of nitrogen up to 600° C. or by a combination of the two reduction methods.8. The method according to claim 4 , characterized in that the basic composite material is transferred to an oxygen- ...

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Номер записи: 45
27-02-2020 дата публикации

ALDEHYDE SCAVENGER AND METHOD FOR REMOVING ALDEHYDES

Номер: US20200061225A1
Автор: HIRAI Kenji, KOBAYASHI Osamu, Masuda Takahiro, OZAKI Takuri, Sudo Yukinori
Принадлежит:

To provide an aldehyde scavenger and a method for removing aldehydes by using the same, for quickly and continuously capturing aldehydes. An aldehyde scavenger comprising at least one O-substituted hydroxylamine or at least one chemically acceptable salt thereof, is used against an aldehyde generation source. 1: An aldehyde scavenger characterized by comprising at least one O-substituted hydroxylamine , or at least one chemically acceptable salt thereof.2: The aldehyde scavenger according to claim 1 , wherein the O-substituted hydroxylamine is an O-substituted mono hydroxylamine.4: The aldehyde scavenger according to claim 3 , wherein in the formula (1) claim 3 , Ris either a methyl group claim 3 , an ethyl group claim 3 , a propyl group claim 3 , an isopropyl group claim 3 , a butyl group claim 3 , an isobutyl group claim 3 , a sec-butyl group claim 3 , a tert-butyl group claim 3 , a benzyl group claim 3 , a 2-pyridylmethyl group claim 3 , a 3-pyridylmethyl claim 3 , a 4-pyridylmethyl group claim 3 , a carboxymethyl group claim 3 , a 1-carboxyethyl group claim 3 , a 2-carboxyethyl group claim 3 , a 1-carboxypropyl group claim 3 , a 2-carboxypropyl group claim 3 , a 3-carboxypropyl group claim 3 , an α-carboxy benzyl group claim 3 , an α-carboxy-phenethyl group claim 3 , a β-carboxy-phenethyl group claim 3 , a 2-hydroxyethyl group claim 3 , a 2-hydroxypropyl group claim 3 , a 3-hydroxypropyl group claim 3 , a 1-carboxy-2-hydroxyethyl group claim 3 , an α-(methoxycarbonyl) benzyl group claim 3 , an α-(methoxycarbonyl) phenethyl group claim 3 , a β-(methoxycarbonyl) phenethyl group claim 3 , a carbamoylmethyl group claim 3 , an N-phenylcarbamoyl methyl group claim 3 , an N-(2-carboxyphenyl) carbamoylmethyl group claim 3 , an N-(3-carboxyphenyl) carbamoylmethyl group claim 3 , an N-(4-carboxyphenyl) carbamoylmethyl group or an N-(2 claim 3 ,6-dimethylphenyl) carbamoylmethyl group.5: The aldehyde scavenger according to claim 1 , wherein the O-substituted hydroxylamine ...

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Номер записи: 46
27-02-2020 дата публикации

CESIUM ADSORBENT AND METHOD OF PREPARING THE SAME

Номер: US20200061577A1
Автор: CHUNG Yoon Suhn, Kang Sung Won, KIM Bok Seong, KIM Sol, KIM Young Sug, OH Dae Min
Принадлежит: KOREA INSTITUTE OF CIVIL ENGINEERING AND BUILDING TECHNOLOGY

Provided herein is a cesium adsorbent including: a support modified to have a carboxyl group on a surface thereof; and Prussian blue synthesized on the surface of the modified support, wherein the Prussian blue is at least partially chemically bound with the surface of the support. The cesium adsorbent may effectively adsorb cesium, which is a radioactive element released into the water and may be easily prepared using a simple solution process. 1. A cesium adsorbent comprising:a support modified to have a carboxyl group on a surface thereof; andPrussian blue synthesized on the surface of the modified support, wherein the Prussian blue is at least partially chemically bound with the surface of the support.2. The cesium adsorbent of claim 1 , wherein the support is a polymer material having a hydroxyl group claim 1 , and the carboxyl group is formed by treating the polymer material with acrylic acid.3. The cesium adsorbent of claim 2 , wherein the polymer material comprises a PVA sponge or cellulose.4. The cesium adsorbent of claim 1 , wherein the support comprises illite claim 1 , and the carboxyl group is formed by treating a surface of the illite with acrylic acid.5. The cesium adsorbent of claim 1 , wherein the support comprises powdered activated carbon.6. The cesium adsorbent of claim 5 , wherein the powdered activated carbon comprises a carboxyl group formed by oxidizing a surface thereof claim 5 , wherein a covalent organic polymer is bound to the surface.7. The cesium adsorbent of claim 6 , wherein the covalent organic polymer comprises melamine.8. A method of preparing a cesium adsorbent claim 6 , the method comprising:forming a carboxyl group on a surface of a support; anddirectly synthesizing Prussian blue on the surface of the support with the carboxyl group formed thereon.9. The method of claim 8 , wherein a polymer having a hydroxyl group is used as the support claim 8 , and the method comprises:modifying a surface of the polymer to have a carboxyl ...

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Номер записи: 47
27-02-2020 дата публикации

METHODS OF PRODUCING FERRIHYDRITE NANOPARTICLE SLURRIES, AND SYSTEMS AND PRODUCTS EMPLOYING THE SAME

Номер: US20200061600A1
Автор: Barton Jason Aaron, Cousins Megan Catherine, Gedvilas Tara S., Kosmoski Joe, Little Charles Deane, Michael Philip Henry, Parker Margarite Patricia
Принадлежит: SulfurCycle Intellectual Property Holding Company LLC

The present disclosure relates to methods of synthesizing slurries comprising ferrihydrite nanoparticles, and systems and methods employing the same. The method may include the steps of preparing an aqueous solution having ferric iron cations, halide anions, and a two-line iron promoter, and precipitating the ferrihydrite nanoparticles in the aqueous solution, thereby producing a ferrihydrite slurry. The ferrihydrite slurries may be useful in treating a polluted fluid having sulfur contaminants therein. 120.-. (canceled)21. A method for treating a HS-containing fluid stream , the method comprising:{'sub': '2', 'claim-text': [{'sub': 2', '2, '(i) a treated fluid stream comprising less HS than the HS-containing stream and'}, {'sub': '2', '(ii) a used slurry including ferrous sulfide, a 2LI promotor, and a first sulfur concentration of sulfur obtained from the HS-containing stream;'}], '(a) contacting a HS-containing fluid stream with a ferrihydrite slurry, wherein the ferrihydrite slurry includes ferrihydrite nanoparticles and a 2LI promotor wherein the contacting step results in'} (i) contacting the used slurry with an oxidizing agent thereby converting at least some of the sulfur in the used slurry into elemental sulfur and converting at least some of the ferrous sulfide in the used slurry into regenerated ferrihydrite thereby forming regenerated ferrihydrite slurry; and', '(ii) separating the elemental sulfur from the regenerated ferrihydrite slurry, wherein the regenerated ferrihydrite slurry includes ferrihydrite nanoparticles and a 2LI promotor and a second sulfur concentration less than the first sulfur concentration of the used slurry;, '(b) regenerating the used slurry to obtain elemental sulfur and a regenerated ferrihydrite slurry, wherein regenerating includeswherein the 2LI promotor is selected from the group consisting of alcohols, polyols, polysaccharides, alkali metasilicates and combinations thereof.22. The method of claim 21 , wherein steps (a) ...

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Номер записи: 48
09-03-2017 дата публикации

COATED MOLECULAR SIEVE

Номер: US20170065927A1
Автор: Kohl A., Sauer Jürgen
Принадлежит:

The invention relates to a hydrophobically coated molecular sieve which comprises particles having a particle size of 1000 nm or less, the surface of the particles being coated with a silane of the general formula SiRRRR, and also to a method of producing it and to a method of using it. In addition, the invention relates to use of the coated molecular sieve and also to compositions comprising the molecular sieve and to use in producing apparatus such as, for example, electronic components and devices. 1. An electronic device comprising: {'br': None, 'sup': 1', '2', '3', '4, 'SiRRRR,'}, 'molecular sieve as a getter material, wherein the molecular sieve is a hydrophobically coated molecular sieve comprising particles of a particle size of 1000 nm or less, the surface of the particles coated with a silane having the general formula{'sup': 1', '2', '3', '4', '1', '2', '3', '4, 'wherein two or three of the radicals R, R, Ror Rbeing, independently of the others, a hydrolysable alkoxyl radical, and the remaining radicals R, R, Rand Rbeing, independently of the others, selected from the group consisting of: non-hydrolysable unsubstituted alkyl radicals, alkenyl radicals, alkynyl radicals, cycloalkyl radicals, alkylcycloalkyl radicals, aryl radicals, arylalkyl radicals,'}wherein the particles comprise inorganic particles selected from particles which comprise porous aluminophosphates, porous silicoaluminophosphates or zeolites.2. The electronic device according to claim 1 , wherein each of the hydrolysable radicals of the silane is claim 1 , independently of the others claim 1 , a hydrolysable alkoxy radical claim 1 , and the remaining radicals are non-hydrolysable alkyl radicals.3. The electronic device according to claim 1 , wherein the alkyl radicals are branched alkyl radicals having from three to eight carbon atoms.4. The electronic device according to claim 1 , wherein the particles are selected from zeolite Na-P1 (GIS structure) claim 1 , zeolite F claim 1 , and ...

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Номер записи: 49
11-03-2021 дата публикации

Continuous Carbon Sequestration Material Production Methods and Systems for Practicing the Same

Номер: US20210069669A1
Автор: Bewernitz Mark A., Camire Chris L., Constantz Brent R., Kang Seung-Hee, Schneider Jacob
Принадлежит:

Methods of producing solid COsequestering carbonate materials are provided. Aspects of the methods include introducing a divalent cation source into a flowing aqueous liquid (e.g., a bicarbonate rich product containing liquid) under conditions sufficient such that a non-slurry solid phase COsequestering carbonate material is produced. Also provided are systems configured for carrying out the methods. 124-. (canceled)25. A continuous reactor configured to produce a solid COsequestering carbonate material , the reactor comprising:a flowing aqueous bicarbonate containing liquid;a divalent cation introducer configured to introduce divalent cations at an introduction location into the flowing aqueous bicarbonate liquid; and{'sub': '2', 'a non-slurry solid phase COsequestering carbonate material production location.'}26. The continuous reactor according to claim 25 , wherein the reactor comprises a flow modulator.27. The continuous reactor according to claim 25 , wherein the reactor comprises a pressure modulator.28. The continuous reactor according to claim 25 , wherein the reactor comprises a temperature modulator.29. The continuous reactor according to claim 25 , wherein the non-slurry solid phase COsequestering carbonate material production location comprises seed structures.30. The continuous reactor according to claim 29 , wherein the seed structures comprise granules.31. The continuous reactor according to claim 29 , wherein the seed structures comprise a carbonate material.32. The continuous reactor according to claim 29 , wherein the seed structures comprise a non-carbonate material.33. The continuous reactor according to claim 29 , wherein the reactor is configured to submerge the seed structures in the liquid.34. The continuous reactor according to claim 29 , wherein the reactor is not configured to submerge the seed structures in the liquid.35. The continuous reactor according to claim 25 , wherein the non-slurry solid phase COsequestering carbonate material ...

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Номер записи: 50
09-03-2017 дата публикации

TEMPERATURE-RESPONSIVE MONOLITHIC POROUS BODY, METHOD FOR PRODUCING SAME, AND TEMPERATURE-RESPONSIVE CHROMATOGRAPHY METHOD USING SAME

Номер: US20170067861A1
Автор: Akiyama Yoshikatsu, KANAZAWA Hideko, KIKUCHI Akihiko, Kobayashi Jun, Nagase Kenichi, OKANO Teruo
Принадлежит:

A temperature responsive monolithic porous material is obtained that comprises a polymer having a hydration ability that changes in a temperature range of 0 to 80° C. and being immobilized to a surface of the porous material at a high density by binding an atom transfer radical polymerization initiator to a surface of the porous material, and inducing a growth reaction of a polymer, having a hydration ability that changes in a temperature range of 0 to 80° C., from the initiator using an atom transfer radical process under a presence of a catalyst. 1. A temperature responsive monolithic porous material comprising a polymer having a hydration ability that changes in a temperature range of 0 to 80° C. and being bound to a surface of the porous material at a density of 0.01 molecular chain/nmor higher.2. The temperature responsive monolithic porous material of claim 1 , wherein the porous material consists of silica.3. The temperature responsive monolithic porous material according to claim 1 , wherein an amount of bound-polymer on the surface of the porous material is 0.2 to 10.0 mg/m.4. The temperature responsive monolithic porous material according to claim 1 , wherein a polymer molecular chain is non-crosslinked.5. The temperature responsive monolithic porous material according to claim 1 , wherein the polymer is one or a plurality of poly-N-substituted acrylamide derivative claim 1 , poly-N-substituted methacrylamide derivative claim 1 , their copolymer claim 1 , polyvinylmethyl ether claim 1 , a partially acetylated polyvinyl alcohol.6. The temperature responsive monolithic porous material according to claim 1 , wherein the polymer is poly-N-isopropylacrylamide.7. The temperature responsive monolithic porous material according to claim 5 , wherein the polymer is a copolymer containing a hydrophilic molecule claim 5 , a hydrophobic molecule and an ionic molecule in a polymer molecular chain claim 5 , at a range that retains a feature of the hydration ability to ...

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Номер записи: 51
12-03-2015 дата публикации

Metal Oxide Particles with Uniform Multilayer Polymer Coatings

Номер: US20150073134A1
Автор: Alexander S. Katz, James C. Bohling, John A. Roper, III, Joseph Jankolovits, Oz M. Gazit
Принадлежит: Dow Global Technologies LLC, Rohm and Haas Co, UNIVERSITY OF CALIFORNIA

The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

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Номер записи: 52
15-03-2018 дата публикации

SORBENTS FOR CARBON DIOXIDE REDUCTION FROM INDOOR AIR

Номер: US20180071672A1
Автор: Biran Israel, Meirav Udi
Принадлежит:

A sorbent for COreduction from indoor air from an enclosed space. In some embodiments, the sorbent comprises a solid support and an amine-based compound being supported by the support. The sorbent captures at least a portion of the COwithin the indoor air. The sorbent may be regenerated by streaming outdoor air through the sorbent to release at least a portion of the captured CO2. The sorbent is structured to allow indoor air to flow therein with relatively low flow resistance and relatively rapid reaction kinetics. Regeneration may be performed at relatively low outdoor air temperatures, thereby minimizing the thermal energy required for regenerating the sorbent. 143-. (canceled)45. A sorbent according to claim 44 , wherein the support is selected from the group consisting of gels claim 44 , molecular sieves claim 44 , nanotube-containing materials claim 44 , porous materials claim 44 , sponge and sponge-like materials claim 44 , electro-magnetically charged objects claim 44 , porous organic polymers claim 44 , ion exchange resins claim 44 , polymeric absorbent resins claim 44 , acrylic ester polymers claim 44 , polystyrene divinyl benzene claim 44 , polymethyl methacrylate (PMMA) claim 44 , polystyrene claim 44 , styrene divinylbenzene (SDB) claim 44 , fly ash claim 44 , activated carbon claim 44 , carbon nanotubes claim 44 , alumina nanoparticles claim 44 , synthetic zeolite claim 44 , porous alumina claim 44 , porous minerals claim 44 , porous silica claim 44 , silica nanoparticle claim 44 , fumed silica claim 44 , activated charcoal claim 44 , aluminum phyllosilicates claim 44 , bentonite claim 44 , montmorillonite claim 44 , ball clay claim 44 , fuller's earth claim 44 , kaolinite claim 44 , attapulgite claim 44 , hectorite claim 44 , palygorskite claim 44 , saponite claim 44 , sepiolitemetal claim 44 , organic frameworks claim 44 , and any combination thereof.46. A sorbent according to claim 44 , wherein the support comprises a plurality of particles with an ...

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Номер записи: 53
15-03-2018 дата публикации

Method For Preparing A Sorbent

Номер: US20180071711A1
Автор: EVANS Matthew James, LUNN Matthew David Gwydion, Partridge Martin Graham, Young Christopher John
Принадлежит:

A method is described for preparing a sorbent comprising the steps of: 1. A method for preparing a sorbent comprising the steps of:(i) mixing an inert particulate support material and one or more binders to form a support mixture,(ii) shaping the support mixture in a granulator using a liquid to form agglomerates,(iii) without drying the agglomerates, coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and one or more binders to form a coated agglomerate by adding the coating mixture to the agglomerates in the granulator, and(iv) drying the coated agglomerate to form a dried sorbent.2. The method according to claim 1 , wherein the inert particulate support material is alumina claim 1 , a metal-aluminate claim 1 , silicon carbide claim 1 , silica claim 1 , titania claim 1 , zirconia claim 1 , zinc oxide claim 1 , an aluminosilicate claim 1 , zeolite claim 1 , a metal carbonate claim 1 , carbon claim 1 , or a mixture thereof.3. The method according to claim 1 , wherein the inert particulate support material is an alumina or hydrated alumina.4. The method according to claim 1 , wherein the inert particulate support material is in the form of a powder with a Dparticle size in the range of 1-100 μm.5. The method according to claim 1 , wherein the binder is a clay binder claim 1 , cement binder claim 1 , or organic polymer binder.6. The method according to claim 1 , wherein the binder is a combination of a cement binder and a clay binder.7. The method according to claim 6 , wherein the relative weights of the cement and clay binders is in the range 1:1 to 3:1 (first to second binder).8. The method according to claim 1 , wherein the total amount of the binder in the agglomerate is in the range of 5-30% by weight.9. The method according to claim 1 , wherein agglomerates have a diameter in the range of 1-15 mm.10. The method according to claim 1 , wherein the particulate copper sulphide material is manufactured by roasting copper ...

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Номер записи: 54
18-03-2021 дата публикации

RADIONUCLIDE ADSORBENT, METHOD OF PREPARING THE SAME AND METHOD OF REMOVING RADIONUCLIDE USING THE SAME

Номер: US20210077980A1
Автор: Kim Il Gook, Lee Kune Woo, PARK Chan Woo, Yang Hee Man, Yoon In Ho
Принадлежит:

The present invention relates to a radionuclide adsorbent, which includes a hollow space (specifically, an area which is entirely empty or in which transition metal oxide particles are present); and a transition metal-ferrocyanide shell (specifically, a transition metal-ferrocyanide shell having a structure in which a plurality of two-dimensional nano flakes overlap or a transition metal-ferrocyanide shell having a structure in which a plurality of three-dimensional nano polyhedrons agglomerate) formed on the space surface, a preparation method thereof, and a method of removing a radionuclide using the same. 1. A method of preparing a radionuclide adsorbent , comprising:(a) preparing a dispersion in which transition metal oxide particles and a ferrocyanide salt are dispersed in an acidic solution; and(b) forming transition metal-ferrocyanide on the surface of the transition metal oxide particle by reacting transition metal ions and the ferrocyanide salt in the dispersion.2. The method of claim 1 , wherein claim 1 , in Step (a) claim 1 , the transition metal oxide particles include one or more of TiO claim 1 , ZnO claim 1 , CuO claim 1 , CuO claim 1 , MnO claim 1 , MnO claim 1 , MnOand MnO.3. The method of claim 1 , wherein claim 1 , in Step (a) claim 1 , the acidic solution is a 0.1 M to 2.0 M HCl solution.4. The method of claim 1 , wherein claim 1 , in Step (a) claim 1 , the concentrations of the transition metal oxide particles and the ferrocyanide salt in the dispersion are 0.1 to 10.0 g/L and 0.001 to 1.0 M claim 1 , respectively.5. The method of claim 1 , wherein claim 1 , in Step (b) claim 1 , the reaction is performed at 10 to 80° C. for 10 minutes to 72 hours.6. A radionuclide adsorbent claim 1 , comprising:a hollow space; and a transition metal-ferrocyanide shell formed on the space surface.7. The adsorbent of claim 6 , further comprising transition metal oxide particles claim 6 , which are spaced apart from the transition metal-ferrocyanide shell claim 6 , ...

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Номер записи: 55
18-03-2021 дата публикации

QUANTUM DOT BEAD HAVING MULTIFUNCTIONAL LIGAND, AND TARGET ANTIGEN DETECTION METHOD AND BIO-DIAGNOSTIC APPARATUS USING SAME

Номер: US20210080454A1
Автор: JUNG Heung Su, KIM Hyun Soo, LEE Ji Young, PARK Sang Hyun, SHIN Sung Young
Принадлежит: ZEUS CO., LTD.

In one aspect, the present disclosure relates to a quantum dot bead comprising a multifunctional ligand having a first binding material and a second antibody, and an immunochromatographic detection method for a target antigen in a biological sample, comprising forming multiple bonds with a quantum dot having a second binding material. In addition, the present disclosure has the effect of remarkably amplifying the detection intensity and significantly improving the detection sensitivity without a separate washing step, and thus enables the detection and diagnosis of physiological materials in a biological sample even in an actual product, and may be used to provide a product with excellent competitiveness in price. 1. An immunochromatographic detection method for a target antigen in a biological sample , comprising:forming multiple bonds between a quantum dot bead including a multifunctional ligand having a first binding material and a second antibody, and a quantum dot having a second binding material,wherein the first binding material and the second binding material react to bind to each other, and the second antibody is specific for a target antigen.2. The method of claim 1 , comprising:(a) binding a target antigen in a biological sample with a quantum dot bead; and(b) forming multiple bonds between the quantum dot bead and quantum dots by bonding a first binding material and a second binding material.3. The method of claim 2 , further comprising:after Step (b), Step (c) measuring fluorescence by UV irradiation.4. The method of claim 1 , wherein the first binding material and the multifunctional ligand are covalently bonded.5. The method of claim 1 , wherein the multifunctional ligand is a polymer; a nucleotide chain; or a peptide chain.6. The method of claim 5 , wherein the multifunctional ligand has one or more substituents selected from the group consisting of a hydroxyl group claim 5 , an amine group claim 5 , a thiol group claim 5 , a carbonyl group claim 5 , ...

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Номер записи: 56
23-03-2017 дата публикации

GAS TREATMENT MONOLITH ARTICLE

Номер: US20170080376A1
Автор: Jakobsson Niklas Bengt, Thøgersen Joakim Reimer
Принадлежит: Haldor Topsoe A/S

The invention relates to a gas treatment monolith article, said gas treatment article comprising: a full body porous material comprising a porous substrate and an aluminium oxide coating homogeneously distributed throughout said porous substrate, wherein said porous substrate is a fibrous material; and at least one acid gas absorption active component or a precursor thereof impregnated into said porous aluminium oxide coated substrate. The invention further relates to uses of the gas treatment monolith article of the invention. 1. A gas treatment monolith article , said gas treatment article comprising:a full body porous material comprising a porous substrate and an aluminium oxide coating homogeneously distributed throughout said porous substrate, wherein said porous substrate is a fibrous material; andat least one acid gas absorption active component or a precursor thereof impregnated into said porous aluminium oxide coated substrate.2. A gas treatment monolith article according to claim 1 , wherein said monolith article comprises one or more sheets of said full body porous material claim 1 , where said one or more sheets is/are shaped so as to form a plurality of channels.3. A gas treatment monolith article according to claim 1 , wherein said monolith article comprises a corrugated sheet of said full body porous material and a substantially flat sheet of said full body porous material.4. A gas treatment monolith article according to claim 1 , wherein said fibrous material is ceramic paper claim 1 , ceramic cardboard or a paper of high silica content glass enforced with E-glass fibers.5. A gas treatment monolith article according to claim 1 , wherein said aluminium oxide coated full body porous material has porosity of about 45% or above.6. A gas treatment monolith article according to claim 1 , wherein said least one acid gas absorption active component or a precursor thereof is an amine.7. A gas treatment monolith article of claim 6 , wherein said amine is an ...

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Номер записи: 57
31-03-2022 дата публикации

Composite Materials Containing Alkyl-Aryl Amine Rich Molecules and Mesoporous Supports for Direct Air CO2 Capture

Номер: US20220096991A1
Автор: Jones Christopher W., Kumar Dharam Raj, Ping Eric W., Rosu Cornelia, Sakwa-Novak Miles A.
Принадлежит:

The present disclosure provides for alkyl-aryl amine rich molecules impregnated into various porous substrates were examined for potential use as sorbents for COcapture from dilute and ultra-dilute gas streams such as flue gas and ambient air, respectively. 13-. (canceled)4. A process the sorption of COfrom mixed gases ranging from 100 ppm-20% COconcentration using composites of the organic molecule denoted Ph-3-PD supported on a porous or nonporous support material.57-. (canceled)8. The process described in claim 4 , with the preferred concentration range of 100-1000 ppm CO.93. The process described in claim claim 4 , with the preferred concentration range of 100-1000 ppm CO.10. The process described in claim 4 , with the preferred concentration range of 100-1000 ppm CO.113. The process described in claim claim 4 , with the preferred concentration range of 100-1000 ppm CO.12. The process described in claim 4 , with the preferred concentration range of 500 ppm-6% CO.133. The process described in claim claim 4 , with the preferred concentration range of 500 ppm-6% CO.14. The process described in claim 4 , with the preferred Ph-3-PD loading on the support material ranging from 20-70% wt.153. The process described in claim claim 4 , with the preferred Ph-3-ED loading on the support material ranging from 20-70% wt.1624-. (canceled) This study describes the use of alkyl-aryl amine reach molecules (Ph-XX-YY) as sorbents for capturing COfrom dilute and ultra-dilute mixtures. These amines were impregnated into solid supports of various chemical compositions such as SBA-15, and y-alumina. The organic loading of the composite Ph-XX-YY-based supports was in the 20%-60% mass range. In the case of each substrate, the high amine-loading samples (50%-60%) adsorbed the largest amount of CO(using 400 ppm streams, at 35° C.). For example, the COadsorption capacity of 60% Ph-3-ED/SBA-15 was 1.9 mmol CO/g, those of 50% Ph-3-PD/SBA-15 and 50% Ph-6-ED/SBA-15 were 1.23 mmol CO/gand 0.8 ...

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Номер записи: 58
31-03-2022 дата публикации

MATERIALS INCLUDING ALKYL DIAMINE-SUBSTITUTED ARYL COMPOUNDS, METHODS OF MAKING, AND METHODS OF SEPARATING CO2

Номер: US20220096999A1
Автор: Jones Christopher W., Kumar Dharam Raj, Ping Eric W., Rosu Cornelia, Sakwa-Novak Miles A.
Принадлежит:

The present disclosure provides for materials comprising porous structures supporting (e.g., disposed therein and/or thereon) alkyl diamine-substituted aryl compounds, methods of making the materials and components thereof, methods of use thereof, and the like. In an aspect, the materials can be used to separate COand/or adsorb COin one or more COcapture or separation applications. In one aspect, the sorbent material can be used to separate and capture COin gas mixtures (e.g., ambient air, flue gas, exhaust, and mixtures of these) in a wide range of concentrations. As a result, embodiments of the present disclosure are advantageous in that they can be used in different types of COconcentration environments. 1. A material comprising:a porous structure comprising an alkyl diamine-substituted aryl compound supported by the porous structure.2. The material of claim 1 , wherein the organic loading of the alkyl diamine-substituted aryl compound on the porous structure is about 10% to 80% based on thermogravimetric analysis.3. The material of claim 1 , wherein the alkyl diamine-substituted aryl compound is physically impregnated in the porous structure.4. The material of claim 1 , wherein the alkyl diamine-substituted aryl compound is covalently bonded to the porous structure.5. The material of claim 1 , wherein the alkyl of the alkyl diamine-substituted aryl compound is an ethyl group claim 1 , propyl group or butyl group.6. The material of claim 1 , wherein the alkyl diamine-substituted aryl compound includes 3 to 6 alkyl diamine moieties.7. The material of claim 1 , wherein the alkyl diamine-substituted aryl compound includes 3 alkyl diamine moieties.8. The material of claim 7 , wherein the 3 alkyl diamine moieties are in the 1 claim 7 , 3 claim 7 , and 5 positions on the alkyl diamine-substituted aryl compound.9. The material of claim 8 , wherein the 2 position claim 8 , 4 position claim 8 , 6 position claim 8 , or any combination thereof of the aryl group each ...

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Номер записи: 59
31-03-2022 дата публикации

Method for preparing monolithic coated surfaces

Номер: US20220097024A1
Автор: Christopher A. Pohl, John M. Riviello
Принадлежит: Dionex Corp

A carrier for adsorption a compound, comprising a support; and a shrink-fitted monolithic body attached to and surrounding at least a portion of the support. The monolithic body can be porous and configured to bind compounds in a solution either for the isolation or depletion of the compounds from the solution.

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Номер записи: 60
25-03-2021 дата публикации

POROUS NANOCOMPOSITES

Номер: US20210087076A1
Автор: Abbas Abdennour, Ahmed Snober, Brockgreitens John, Heidari Fatemeh
Принадлежит:

The article includes a porous scaffold structure comprising a plurality of supports. The article further includes a plurality of metallic or non-metallic nanomaterials disposed on at least one of the supports. Each of the plurality of metallic or non-metallic nanomaterials is directly bound to at least one of the supports. 1. An article , comprising:a porous scaffold structure comprising a plurality of supports; anda plurality of metallic or non-metallic nanomaterials disposed on at least one of the supports,wherein each of the plurality of metallic or non-metallic nanomaterials is directly bound to at least one of the supports.2. The article of claim 1 , wherein each of the plurality of nanomaterials has a diameter between about 5 nm and about 500 nm.3. The article of claim 1 , wherein the porous scaffold structure is a sponge claim 1 , wherein the sponge comprises a plurality of fibers claim 1 , and wherein at least a portion of the plurality of nanomaterials is disposed on a surface of at least one of the fibers and at least a portion of the plurality of nanomaterials is disposed within at least one of the fibers.4. The article of claim 3 , wherein the plurality of fibers includes one or more polymers chosen from polyurethane claim 3 , polyamide claim 3 , polystyrene claim 3 , polyethylene terephthalate claim 3 , polypropylene or mixtures thereof.5. The article of claim 1 , wherein the porous scaffold structure is a porous ceramic.6. The article of claim 1 , wherein the plurality of nanomaterials comprises one or more metals claim 1 , non-metals claim 1 , or metal oxides between about 1 wt. % to about 100 wt. % of the metallic or non-metallic nanomaterial.7. The article of claim 6 , wherein at least one of the metals or non-metals is chosen from selenium claim 6 , copper claim 6 , aluminum claim 6 , zinc claim 6 , iron claim 6 , nickel claim 6 , calcium claim 6 , magnesium claim 6 , titanium claim 6 , silver claim 6 , manganese claim 6 , mixtures thereof claim 6 ...

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Номер записи: 61
29-03-2018 дата публикации

SEPARATING AGENT FOR OPTICAL ISOMERS

Номер: US20180085734A1
Автор: Hamasaki Ryota, UEDA Takunori
Принадлежит: Daicel Corporation

Provided is a separating agent for optical isomers, which is excellent in solvent resistance and has optical separating ability comparable to or higher than that of existing separating agents for optical isomers of chemical bonding type or physical adsorption type. In the separating agent for optical isomers, amylose (3-chloro-5-methylphenylcarbamate) is supported on a carrier through chemical bonding. 1. A separating agent for optical isomers , comprising amylose (3-chloro-5-methylphenylcarbamate) and a carrier wherein amylose (3-chloro-5-methylphenylcarbamate) is supported on the carrier through chemical bonding.2. The separating agent for optical isomers according to claim 1 , wherein the separating agent for optical isomers is obtained by a method comprising a step of physically adsorbing amylose tris(3-chloro-5-methylphenylcarbamate) onto a carrier claim 1 , and a step of crosslinking the amylose tris(3-chloro-5-methylphenylcarbamate) and the carrier through irradiation of light energy.3. The separating agent for optical isomers according to claim 1 , wherein the separating agent for optical isomers is obtained by a method comprising a step of chemically bonding a reducing terminal of amylose and a carrier claim 1 , and a step of claim 1 , thereafter claim 1 , causing hydroxyl groups of amylose and 3-chloro-5-methylphenylisocyanate to react.4. The separating agent for optical isomers according to claim 1 , wherein the separating agent for optical isomers is obtained by a method comprising a step of copolymerizing a carrier having a polymerizable functional group claim 1 , amylose (3-chloro-5-methylphenylcarbamate) having a polymerizable functional group claim 1 , and a polymerizable monomer.5. The separating agent for optical isomers according to claim 1 , wherein the separating agent for optical isomers is obtained by a method comprising a step of modifying hydroxyl groups of amylose with 3-chloro-5-methylphenylisocyanate claim 1 , and thereafter obtaining an ...

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Номер записи: 62
21-03-2019 дата публикации

PEPTOID AFFINITY LIGANDS

Номер: US20190085022A1
Автор: Bordelon Tee, Crapanzano Michael, MURPHY Andrew J.
Принадлежит:

Disclosed herein are peptoids and related compounds, including peptoid affinity ligands, and hybrid peptoids, for binding and/or purifying immunoglobulins, immunoglobulin fragments or immunoglobulin fusion proteins thereof. Methods of making peptoid affinity ligands and using the same to bind, purify and/or isolate immunoglobulins and related compounds are also disclosed. Such peptoid affinity ligands comprise a peptoid compound consisting of sequentially coupled peptoid residues forming a peptoid backbone, with one or more functional groups appended to a Nitrogen of the peptoid residues of the peptoid backbone configured to provide the desired binding affinity. The peptoids can further comprise a peptoid backbone with at least one functional group coupled to an alpha carbon (C) of a peptide bond in the peptoid backbone thereby forming a hybrid peptoid. 1. A peptoid affinity ligand , the peptoid affinity ligand comprising:a peptoid compound consisting of sequentially coupled peptoid residues forming a peptoid backbone, with one or more functional groups appended to a Nitrogen of the peptoid residues of the peptoid backbone;wherein the one or more functional groups comprise, in any order but coupled to sequential peptoid residues on the peptoid backbone: at least two aromatic functional groups and either a basic or acidic functional group;wherein the peptoid backbone comprises at least one functional group coupled to an alpha carbon (C) of a peptide bond within the peptoid backbone;subject to the proviso that excluded therefrom are peptoid affinity ligands containing a contiguous segment of three peptoid residues with the following functional groups: (i) a basic residue, (ii) an aromatic residue, and (iii) a basic residue or hydrophilic residue; andwherein the peptoid affinity ligand specifically binds an immunoglobulin, immunoglobulin fragment or immunoglobulin fusion protein thereof, wherein the immunoglobulin, immunoglobulin fragment or immunoglobulin fusion ...

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Номер записи: 63
30-03-2017 дата публикации

CYCLIC THERMAL SWING ADSORPTION WITH DIRECT HEAT TRANSFER

Номер: US20170087506A1
Автор: Afeworki Mobae, Caram Hugo S., CHAUDHURY Manoj K., GUPTA Ramesh, MINHAS Bhupender S., Nines Meghan, THOMANN Hans, Vroman Hilda B., Weston Simon C.
Принадлежит:

A heat transfer fluid can be used as part of a multi-phase adsorption environment to allow for improved separations of gas components using a solid adsorbent. The heat transfer fluid can reduce or minimize the temperature increase of the solid adsorbent that occurs during an adsorption cycle. Reducing or minimizing such a temperature increase can enhance the working capacity for an adsorbent and/or enable the use of adsorbents that are not practical for commercial scale adsorption using conventional adsorption methods. The multi-phase adsorption environment can correspond to a trickle bed environment, a slurry environment, or another convenient environment where at least a partial liquid phase of a heat transfer fluid is present during gas adsorption by a solid adsorbent. 1. A method for adsorbing a gas component , comprising:exposing an input fluid comprising a first gas component and a heat transfer liquid to adsorbent particles to produce an adsorbent effluent having a lower concentration of the first gas component than the input fluid, the input fluid comprising a first temperature prior to contacting the adsorbent particles, a loading of adsorbed first gas component in the adsorbent particles at the end of the exposing being at least about 0.01 mol/kg; anddesorbing at least a portion of the first gas component from the adsorbent particles at a desorption temperature greater than the first temperature.2. The method of claim 1 , wherein the first gas component comprises CO.3. The method of claim 1 , wherein the adsorbent particles comprise a Type V adsorbent.4. The method of claim 1 , wherein a loading of adsorbed first gas component in the adsorbent particles after the desorbing is less than 50% of the loading of first gas component in the adsorbent particles at the end of the exposing.5. The method of claim 1 , wherein the desorption temperature is greater than the first temperature by at least about 25° C.6. The method of claim 1 , wherein the adsorbent ...

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Номер записи: 64
19-03-2020 дата публикации

REMOVAL OF SELENOCYANATE FROM REFINERY SOUR WATER STRIPPER WASTEWATER

Номер: US20200087179A1
Автор: Huang Yongheng, Mason Samuel A., Wismer Michael W.
Принадлежит:

Systems and methods for removing heavy metals such as selenium from wastewater with zero valent iron media. Air may be introduced directly into a reaction zone of a fluidized bed reactor filled with the media to catalyze treatment. 1. A method of removing selenium species from wastewater , the method comprising:directing wastewater contaminated with selenium species into a fluidized bed reactor comprising zero-valent iron media and a mixer;mechanically mixing the wastewater in the fluidized bed reactor with the mixer to contact contaminants in the wastewater with the zero-valent iron media; andinjecting an oxygen-containing gas into a reaction zone defined about the mixer,wherein the selenium species comprise selenocyanate.2. The method of claim 1 , wherein injecting the oxygen-containing gas into the reaction zone includes injecting the oxygen-containing gas into a lower portion of the fluidized bed reactor.3. The method of claim 1 , wherein the oxygen-containing gas is air.4. The method of claim 1 , wherein the method includes removing approximately 75% or more of the selenium species from the wastewater in a single pass through a system comprising the fluidized bed reactor.5. The method of claim 1 , wherein the method includes removing approximately 99% or more of the selenium species from the wastewater in a single pass through a system comprising the fluidized bed reactor.6. The method of claim 1 , wherein the method includes reducing a concentration of selenium species in the wastewater to below 50 ppb in a single pass through a system comprising the fluidized bed reactor.7. The method of claim 1 , wherein the zero-valent iron media comprises zero-valent iron particles coated with an iron oxide.8. The method of claim 1 , wherein the zero-valent iron media comprises zero-valent iron particles coated with magnetite.9. The method of claim 1 , wherein the zero-valent iron media comprises particles comprising zero-valent iron and particles comprising magnetite.10. ...

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Номер записи: 65
12-05-2022 дата публикации

ANIMAL LITTERS WITH REDUCED DUSTING

Номер: US20220142115A1
Автор: Adamy Steven T.
Принадлежит: CHURCH & DWIGHT CO., INC.

An animal litter composition having enhanced dust reduction properties, and a related method, are disclosed. The animal litter can include a plurality of particles a liquid adsorbing material, such as diatomaceous earth. The animal litter can also include a dust reducing composition, which composition particularly can comprise polyvinyl alcohol and nanoparticulate silica. 1. An animal litter composition comprising:a plurality of particles of diatomaceous earth;polyvinyl alcohol (PVOH); anda nanoparticulate silica material.2. The animal litter composition of claim 1 , wherein the plurality of particles of the diatomaceous earth have an average particle size of about 0.2 mm to about 5 mm.3. The animal litter composition of claim 1 , wherein the PVOH has a degree of hydrolysis of about 87% to about 89%.4. The animal litter composition of claim 1 , wherein the PVOH has a weight average molecular weight of about 20 claim 1 ,000 g/mol or greater.5. The animal litter composition of claim 1 , wherein the PVOH has a weight average molecular weight of about 20 claim 1 ,000 g/mol to about 75 claim 1 ,000 g/mol.6. The animal litter composition of claim 1 , wherein the nanoparticulate silica has an average particle size of about 50 nm or less.7. The animal litter composition of claim 1 , wherein the nanoparticulate silica has an average particle size of about 5 nm to about 25 nm.8. The animal litter composition of claim 1 , wherein the nanoparticulate silica is cationic.9. The animal litter composition of claim 1 , wherein the nanoparticulate silica is a colloidal silica.10. The animal litter composition of claim 1 , wherein one or both of the PVOH and the nanoparticulate silica material is present as a coating on at least a portion of an outer surface of the plurality of particles of the diatomaceous earth.11. The animal litter composition of claim 1 , wherein the PVOH is present in an amount of about 0.5% to about 5% by weight based on the total weight of the animal litter ...

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Номер записи: 66
01-04-2021 дата публикации

MATERIALS AND METHODS FOR SELECTIVE NOBLE GAS ADSORPTION

Номер: US20210094015A1
Автор: Bhattacharya Sumit, Miao Yinbin, Yacout Abdellatif M.
Принадлежит:

An adsorptive material for adsorption of a noble gas can include a mesoporous support material having a plurality of pores and a pattern of metal atoms deposited onto the mesoporous support material. 1. An adsorptive material for adsorption of a noble gas , comprising:a mesoporous support material having a plurality of pores; anda pattern of metal atoms deposited onto the mesoporous support material such that the pattern of metal atoms infiltrates the plurality of pores of the mesoporous support.2. The adsorptive material of claim 1 , wherein the pattern of metal atoms an alternating set of at least two types of metal atoms.3. (canceled)4. The adsorption material of claim 1 , wherein the mesoporous support is doped with one or more of Cu claim 1 , Pt claim 1 , Au claim 1 , Ag claim 1 , and Pd.5. The adsorptive material of claim 1 , wherein the mesoporous support comprises one or more of saponite claim 1 , SiO claim 1 , TiO claim 1 , AlO claim 1 , and ZrO.6. (canceled)7. The adsorptive material of claim 1 , wherein the adsorptive material has a surface area for sorption of a noble gas of 500 m/g to 1000 m/g.8. The adsorptive material of claim 1 , wherein the pattern of metal atoms covers at least about 60% of a surface area of the mesoporous support.9. (canceled)10. (canceled)11. The adsorptive material of claim 1 , wherein the adsorptive material is heat stable to a temperature of up to about 600° C.12. (canceled)13. The adsorptive material of claim 1 , wherein the adsorptive material has an adsorption capacity for Xenon of about 1 mmol/g to about 3.5 mmol/g.14. (canceled)15. (canceled)16. The adsorptive material of claim 1 , wherein the pattern of metal atoms has an average thickness of about 2 nm to about 10 nm.17. The adsorptive material of claim 1 , wherein the metal atoms comprise one or more of Pt claim 1 , Pd claim 1 , Cu claim 1 , Au claim 1 , Ag and Al.18. The adsorptive material claim 1 , wherein the pattern of metal atoms comprises a plurality of pillar ...

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Номер записи: 67
28-03-2019 дата публикации

HIGH PURITY CHROMATOGRAPHIC MATERIALS COMPRISING AN IONIZABLE MODIFIER

Номер: US20190091606A1
Автор: Iraneta Pamela C., Walter Thomas H., Wyndham Kevin D.
Принадлежит: WATERS TECHNOLOGIES CORPORATION

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are high purity chromatographic materials comprising a chromatographic surface wherein the chromatographic surface comprises a hydrophobic surface group and one or more ionizable modifier. 117-. (canceled)19. The high purity chromatographic material of claim 18 , wherein the ratio of the hydrophobic surface group:ionizable modifier is from about 2.5:1 to about 12:1.20. The high purity chromatographic material of claim 18 , wherein m is 2 or 3.21. The high purity chromatographic material of claim 18 , wherein the ionizable modifying reagent is 2-(2-(trichlorosilyl)ethyl)pyridine claim 18 , 2-(2-(trimethoxy)ethyl)pyridine claim 18 , 2-(2-(triethoxy)ethyl)pyridine claim 18 , 2-(4-pyridylethyl)triethoxysilane claim 18 , 2-(4-pyridylethyl)trimethoxysilane claim 18 , 2-(4-pyridylethyl)trichlorosilane.22. The high purity chromatographic material of claim 18 , further comprising a chromatographic core material.23. The high purity chromatographic material of claim 22 , wherein the chromatographic core material is a silica material or a hybrid inorganic/organic material.24. The high purity chromatographic material of claim 23 , wherein the chromatographic core material is a superficially porous material.25. The high purity chromatographic material of claim 18 , wherein the hydrophobic surface group is a C4 to C30 bonded phase claim 18 , an aromatic claim 18 , a phenylalkyl claim 18 , a fluoro-aromatic claim 18 , a phenylhexyl claim 18 , a pentafluorophenylalkyl claim 18 , or a chiral bonded phase26. A method for preparing a high purity chromatographic material according to comprising the steps of:reacting a ...

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Номер записи: 68
28-03-2019 дата публикации

HYBRID MATERIAL FOR CHROMATOGRAPHIC SEPARATIONS COMPRISING A SUPERFICIALLY POROUS CORE AND A SURROUNDING MATERIAL

Номер: US20190091657A1
Автор: Lawrence Nicole L., Muriithi Beatrice W., Wyndham Kevin Daniel
Принадлежит:

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a superficially porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, chemical stability, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA. 1. An inorganic/organic hybrid material comprising an inorganic/organic hybrid surrounding material and a superficially porous core.2. The inorganic/organic hybrid material of claim 1 , wherein the inorganic/organic hybrid surrounding material and the superficially porous core are composed of different materials.3. The inorganic/organic hybrid material of claim 1 , wherein the inorganic/organic hybrid surrounding material and the superficially porous core are composed of the same materials.4. The inorganic/organic hybrid material of claim 1 , wherein the inorganic/organic hybrid surrounding material is composed of a material which enhances one or more of the characteristics selected from the group consisting of chromatographic selectivity claim 1 , particle chemical stability claim 1 , column efficiency claim 1 , and mechanical strength.5. The inorganic/organic hybrid material of claim 1 , wherein the superficially porous core is composed of a material which enhances one or more characteristics selected from the group consisting of chromatographic selectivity claim 1 , particle chemical stability claim 1 , column efficiency claim 1 , and mechanical strength.6. The inorganic/organic hybrid material of claim 4 , wherein the ...

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Номер записи: 69
06-04-2017 дата публикации

Ammonia adsorbent

Номер: US20170096348A1
Автор: Akira Takahashi, Hisashi Tanaka, Parajuli DURGA, Tohru Kawamoto, Yukiya Hakuta, Yutaka Sugiyama
Принадлежит: National Institute of Advanced Industrial Science and Technology AIST

The object of the invention is to provide an adsorbent that can adsorb ammonia with no large volume change between absorption and desorption, that has a high ammonia and/or ammonium ion adsorption capacity, and that can have an additional function by gaining proper control of composition, etc. The invention makes it possible to provide an adsorbent that absorbs ammonia and/or ammonium ions through the use of a metal cyanocomplex as an ammonia adsorbent, experiences no or little volume change, exhibits high enough capacity for adsorbing ammonia and/or ammonium ions, and has a function of decomposing ammonia as well as a function of varying optical responses before and after adsorption, etc.

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Номер записи: 70
06-04-2017 дата публикации

PROCESSES FOR PREPARING SILICA-CARBON ALLOTROPE COMPOSITE MATERIALS AND USING SAME

Номер: US20170096657A1
Автор: BERE Kossi E., BRAIDY Nadi, GAMYS Ce Guinto, GAUDREAULT Charles, GOSSELIN Mathilde, LEMAY Jean-Francois
Принадлежит:

The present document describes a carbon allotrope-silica composite material comprising a silica microcapsule comprising a silica shell having a thickness of from about 50 nm to about 500 μm, and a plurality of pores, said shell forming a capsule having a diameter from about 0.2 μm to about 1500 and having a density of about 0.001 g/cm3 to about 1.0 g/cm3, wherein said shell comprises from about 0% to about 70% Q3 configuration, and from about 30% to about 100% Q4 configuration, or wherein said shell comprises from about 0% to about 60% T2 configuration and from about 40% to about 100% T3 configuration, or wherein said shell comprises a combination of T and Q configurations thereof, and wherein an exterior surface of said capsule is covered by a functional group; a carbon allotrope attached to said silica microcapsule. Also described is a carbon allotrope-silica composite material comprising a carbon allotrope attached to a silica moiety comprising a silica nanoparticle having a diameter from about 5 nm to about 1000 nm, wherein an exterior surface of said silica nanoparticle is covered by a functional group. 1. A carbon allotrope-silica composite material comprising:a silica microcapsule comprising:a silica shell having a thickness of from about 50 nm to about 500 μm, and a plurality of pores,{'sup': 3', '3, 'said shell forming a capsule having a diameter from about 0.2 μm to about 1500 μm, and having a density of about 0.001 g/cmto about 1.0 g/cm,'}wherein said shell comprises from about 0% to about 70% Q3 configuration, and from about 30% to about 100% Q4 configuration, orwherein said shell comprises from about 0% to about 60% T2 configuration and from about 40% to about 100% T3 configuration, orwherein said shell comprises a combination of T and Q configurations thereof, andwherein an exterior surface of said capsule is covered by a functional group;a carbon allotrope attached to said silica microcapsule.2. A carbon allotrope-silica composite material comprising: ...

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Номер записи: 71
26-03-2020 дата публикации

A coalescing media product and method

Номер: US20200094166A1
Автор: Mundheim Atle
Принадлежит:

A coalizing product and a method for the coalescing of oil contaminants from a water flow is described, in which the product according to the invention is arranged in an apparatus for in depth coalescing of oil contaminated water. There are also disclosed uses of the method and the product for coalescing of oil contamination in water. 114- (canceled)15. An oil coalescing granulated media product , comprising a granulated substrate having a metal oxide-containing surface , fluorosiloxane permanently cross-linked to the metal oxide-containing surface , and wherein the product is wetted by a surfactant liquid , preferably an alcohol.16. Product according to claim 15 , wherein the granulated substrate comprises crushed recycled glass or quartz sand.17. A method for producing an oil-coalescing granulated media product claim 15 , comprising dissolving 1-10% of fluorosiloxane in an nonpolar claim 15 , de-aromatized volatile hydrocarbon solvent to a solution in which a granular substrate having a metal oxide surface is placed and completely wetted by solution claim 15 , after which solvent is evaporated at temperature above the evaporation temperature of solvent so that the substrate is dried and that the fluorosiloxane is adhered to the substrate claim 15 , after which the dry substrate with attached fluorosiloxane is heated to between 170 and 700 degrees Celsius for 15 minutes to 45 minutes claim 15 , whereby permanent crosslinking will occur place between the substrate metal oxides and siloxane and form a permanent chemical bond.18. A method according to claim 17 , wherein the substrate is crushed recycled glass or quartz sand.19. A method according to claim 17 , wherein the amount of the fluosiloxane is 3-5%.20. The method of claim 17 , wherein the hydrocarbon solvent is iso-alkanic claim 17 , with hydrocarbon chain lengths from C10 to C18.21. A method according to claim 17 , wherein evaporation temperature is between 170-220 degrees Celsius.22. A method according to ...

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Номер записи: 72
04-04-2019 дата публикации

Carbon Dioxide Sorbent and Method for Producing Carbon Dioxide Sorbent

Номер: US20190099710A1
Автор: KISHIMOTO Akira, Oshima Junji, Ueda Kentaro
Принадлежит:

A carbon dioxide sorbent characterized in that carbon dioxide sorbing material incorporated in pores of the porous inorganic particles is sealed in the pores with a resin. 1. A carbon dioxide sorbent , comprising a carbon dioxide sorbing material incorporated in pores of porous inorganic particles which is sealed in the pores with a resin.2. The carbon dioxide sorbent of claim 1 , wherein the carbon dioxide sorbing material is an ionic liquid.3. The carbon dioxide sorbent of claim 2 , wherein the ionic liquid is tetraethylphosphonium benzimidazolide or tetraethylammonium benzimidazolide.4. The carbon dioxide sorbent of claim 1 , wherein the resin is a cured product obtained by curing a vinyl monomer solution of a curable resin.5. The carbon dioxide sorbent of claim 4 , wherein the vinyl monomer solution is at least one selected from the group consisting of an unsaturated polyester resin claim 4 , an epoxy acrylate resin claim 4 , and a urethane acrylate resin.6. The carbon dioxide sorbent of claim 5 , wherein the vinyl monomer solution is an unsaturated polyester resin.7. The carbon dioxide sorbent of claim 4 , wherein the ratio of the volume of the resin to the oil sorptive capacity of the porous inorganic particle is 0.3 or more.8. The carbon dioxide sorbent of claim 4 , wherein the ratio of the total volume of the carbon dioxide sorbing material and the resin to the oil sorptive capacity of the porous inorganic particle is 0.7 or less.9. The carbon dioxide sorbent of claim 4 , wherein the ratio of the total volume of the carbon dioxide sorbing material and the resin to the oil sorptive capacity of the porous inorganic particles exceeds 0.5.10. The carbon dioxide sorbent of claim 4 , wherein the ratio of the total mass of the carbon dioxide sorbing material and the resin to the mass of the porous inorganic particle is 1.5 or more.11. The carbon dioxide sorbent of claim 4 , wherein the ratio of the mass of the carbon dioxide sorbing material to the mass of the ...

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Номер записи: 73
08-04-2021 дата публикации

Method for analyzing triglyceride, method for sorting oil and fat, and method for producing triglyceride

Номер: US20210102923A1
Автор: Koji Masuda, Kosuke Abe, Yoshihiro Murano
Принадлежит: Nisshin Oillio Group Ltd

An object of the present invention is to provide a method for analyzing an isomer of triglyceride, a method for sorting oils and fats having different contents of an isomer of triglyceride, and a method for producing triglyceride of which an isomer can be fractionated. The present invention is a method for analyzing triglyceride, including a step of analyzing an isomer of triglyceride by supercritical fluid chromatography, in which multiple types of stationary phases are used in the supercritical liquid chromatography, and at least two stationary phases among the stationary phases have different chiral selectors in each of which one or more chlorines are bound to a polysaccharide derivative.

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Номер записи: 74
02-06-2022 дата публикации

Alkyl-Aryl Amine-Rich Small Molecules and Their Composites with Solid Mesoporous Substrates

Номер: US20220169593A1
Автор: Jones Christopher W., Kumar Dharam Raj, Ping Eric W., Rosu Cornelia, Sakwa-Novak Miles A., Sujan Achintya
Принадлежит:

The present disclosure provides for alkyl-aryl amine-rich small molecules that are prepared by nucleophilic substitution from tri- and hexa-bromine-substituted aromatic cores with various aliphatic diamines. The resulting products can be subsequently subjected by solution impregnation into solid mesoporous supports. Various types of alkyl-aryl amine-rich small molecules can fill the support's pores up to ˜90% and displayed good thermal stability 1. (canceled)2. Composite materials of Ph-XX—YY amines impregnated into porous supports.3. The same as with the support being mesoporous silica.4. The same as with the silica being SBA15.5. The same as with the support being porous alumina.6. The same as with the support being porous carbon. (Original) The same as with the support being porous polymer.8. The same as with the support being porous metal organic frameworks.9. The same as with the Ph-XX—YY being Ph-3-ED (N1 claim 2 ,N1′ claim 2 ,N1″-(benzene-1 claim 2 ,3 claim 2 ,5-triyltris(methylene))tris(ethane-1 claim 2 ,2-diamine)).10. The same as with the Ph-XX—YY being Ph-3-PD (N1 claim 2 ,N1′ claim 2 ,N1″-(benzene-1 claim 2 ,3 claim 2 ,5-triyltris(methylene))tris(propane-1 claim 2 ,3-diamine)).11. The same as with the Ph-XX—YY being Ph-6-PD (N1 claim 2 ,N1′ claim 2 ,N1″ claim 2 ,N1′″ claim 2 ,N1″″ claim 2 ,N1′″″-(benzene-1 claim 2 ,2 claim 2 ,3 claim 2 ,4 claim 2 ,5 claim 2 ,6-hexaylhexakis(methylene))hexakis(propane-1 claim 2 ,3-diamine).12. The same as with the Ph-XX—YY being Ph-6-ED (N1 claim 2 ,N1′ claim 2 ,N1″ claim 2 ,N1′″ claim 2 ,N1″″ claim 2 ,N1′″″-(benzene-1 claim 2 ,2 claim 2 ,3 claim 2 ,4 claim 2 ,5 claim 2 ,6-hexaylhexakis(methylene))hexakis(ethane-1 claim 2 ,2-diamine)).13. The same as with the Ph-XX—YY being Ph-4-ED (N1 claim 2 ,N1′ claim 2 ,N1″ claim 2 ,N1′″-(benzene-1 claim 2 ,2 claim 2 ,4 claim 2 ,5-tetrayltetrakis(methylene))tetrakis(ethane-1 claim 2 ,2-diamine)).14. The same as with the Ph-XX—YY being Ph-4-PD (N1 claim 2 ,N1′ claim 2 ,N1″ claim 2 ,N1 ...

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Номер записи: 75
19-04-2018 дата публикации

Salt Coated With Nanoparticles

Номер: US20180106508A1
Автор: Bolin Goran, Glebov Dmitri
Принадлежит:

A particle comprises an inner part and an outer coating, wherein the inner part comprises MgO and the outer coating comprises hydrophobic nanoparticles, wherein the nanoparticles have an average size of from 1-50 nm and/or the nanoparticles are fused together and form aggregates of 100-1,000 nm of a size less than 1 μm, wherein the particle has an average size of from 1 to 1000 μm. A device adapted to perform an absorption process comprises at least one such particle. An absorption process comprises contacting such a particle with a liquid or gas. 1. A particle comprising an inner part and an outer coating , wherein said inner part comprises MgO and said outer coating comprises hydrophobic nanoparticles , wherein the nanoparticles have an average size of from 1-50 nm and/or the nanoparticles are fused together and form aggregates of 100-1 ,000 nm of a size less than 1 μm , wherein the particle has an average size of from 1 to 1000 μm.2. The particle according to claim 1 , wherein said nanoparticles comprise at least one material selected from the group consisting of hydrophobically-modified SiO2 particles and carbon materials.3. The particle according to claim 1 , wherein said hydrophobic nanoparticles comprise SiO2 nanoparticles claim 1 , and the SiO2 nanoparticles are modified by covalently bound hydrophobic compounds.4. The particle according to claim 1 , wherein said particle further comprises at least one liquid.5. The particle according to claim 1 , wherein said particle further comprises water.6. The particle according to claim 1 , wherein said particle has an average size of from 5 to 500 μm.7. The particle according to claim 1 , wherein said particle has an average size of from 20 to 100 μm.8. The particle according to claim 1 , wherein said nanoparticles have an average size of from 1 to 50 nm.9. A device adapted to perform an absorption process claim 1 , said device comprising at least one particle claim 1 , wherein said particle comprises an inner part ...

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Номер записи: 76
02-04-2020 дата публикации

ZIRCONIA-BASED COMPOSITIONS FOR USE IN PASSIVE NOx ADSORBER DEVICES

Номер: US20200101436A1
Автор: CROCKER Mark, DARAB John G., Harris Deborah Jayne, JI Yaying, SCAPENS David Alastair
Принадлежит:

A passive NOadsorbent includes: palladium, platinum or a mixture thereof and a mixed or composite oxide including the following elements in percentage by weight, expressed in terms of oxide: 10-90% by weight zirconium and 0.1-50% by weight of least one of the following: a transition metal or a lanthanide series element other than Ce. Although the passive NOadsorbent can include Ce in an amount ranging from 0.1 to 20% by weight expressed in terms of oxide, advantages are obtained particularly in the case of low-Ce or a substantially Ce-free passive NOx adsorbent. 120-. (canceled)21. A passive NOx adsorbent comprising: palladium , platinum or a mixture thereof and a mixed or composite oxide comprising the following elements in percentage by weight , expressed in terms of oxide: 10-90% by weight zirconium; and 0.1-50% by weight of least one of the following: a lanthanide series element other than Ce , comprising Pr; and a transition metal comprising at least one of the following metals selected from W , Mn , and Fe.22. A passive NOx adsorbent according to further comprising at least one of Y claim 21 , La and Nd as said lanthanide series element other than Ce.23. A passive NOx adsorbent according to claim 21 , comprising Mn as said transition metal in an amount of 0.1 to 20% by weight and Pr as said lanthanide series element other than Ce in an amount of 0.5 to 30% by weight claim 21 , wherein a total amount of Pr and Mn is not more than 50% by weight.24. A passive NOx adsorbent according to further comprising at least one of W and Fe as said transition metal.25. A passive NOx adsorbent according to further including at least one of Y claim 23 , La and Nd as said lanthanide series element other than Ce.26. A passive NOx adsorbent according to further comprising an element from Group 14 of the Periodic Table in an amount ranging from 0.1 to 20% by weight expressed in terms of oxide.27. A passive NOx adsorbent according to comprising Ce in an amount ranging from 0.1% to ...

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Номер записи: 77
02-04-2020 дата публикации

SORBENTS, DEVICES, KITS AND METHODS USEFUL FOR SAMPLE TREATMENT

Номер: US20200101437A1
Автор: Alden Bonnie A., Brousmiche Darryl W., Fairchild Jacob N., Lawrence Nicole L., Wyndham Kevin D.
Принадлежит:

Novel sorbents, devices, kits and methods useful for sample treatment are disclosed herein. 1. Inorganic/organic hybrid sorbent particles comprising (a) a core region that comprises a silica component and (b) a surface region that comprises an organic copolymer comprising at least one hydrophobic organic monomer and at least one hydrophilic organic monomer.2. The inorganic/organic hybrid sorbent particles of claim 1 , herein the core region consists of silica or comprises a material having the formula SiO/(RRSiO)or SiO/[R(RSiO)]wherein Rand Rare independently C1-C18 aliphatic or aromatic moieties claim 1 , Ris a substituted or unsubstituted C-Calkylene claim 1 , alkenylene claim 1 , alkynylene or arylene moiety bridging two or more silicon atoms claim 1 , p and q are 0 claim 1 , 1 or 2 claim 1 , provided that p+q=1 or 2 claim 1 , and that when p+q=1 claim 1 , t=1.5 claim 1 , and when p+q=2 claim 1 , t=1; r is 0 or 1 claim 1 , provided that when r=0 claim 1 , t=1.5 claim 1 , and when r=1 claim 1 , t=1; m is an integer greater than or equal to 2 claim 1 , and n is a number from 0.03 to 1.3. The inorganic/organic hybrid sorbent particles of claim 1 , further comprising a C4-C60 alkyl component.4. The inorganic/organic hybrid sorbent particles of claim 1 , wherein the core region is formed by hydrolytically condensing one or more silane compounds.5. The inorganic/organic hybrid sorbent particles of claim 4 , wherein the one or more silane compounds that are hydrolytically condensed comprise (a) one or more silane compounds of the formula SiZZZZ claim 4 , where Z claim 4 , Z claim 4 , Zand Zare independently selected from Cl claim 4 , Br claim 4 , I claim 4 , C1-C4 alkoxy claim 4 , C1-C4 alkylamino claim 4 , and C1-C4 alkyl claim 4 , although at most three of Z claim 4 , Z claim 4 , Zand Zcan be C1-C4 alkyl and/or (b) one or more compounds of the formula Si ZZZ—R—SiZZZ claim 4 , where Z claim 4 , Zand Zare independently selected from Cl claim 4 , Br claim 4 , I claim 4 , ...

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Номер записи: 78
09-06-2022 дата публикации

METHOD FOR PURIFYING DYE-CONTAINING WASTEWATER BASED ON POROUS-POLYMER-MODIFIED METAL CARBON NANOTUBE COMPOSITE MEMBRANE

Номер: US20220177333A1
Автор: Chen Dongyun, LU Jianmei
Принадлежит:

A method for purifying dye-containing wastewater based on a porous-polymer-modified metal carbon nanotube membrane includes: (1) preparing the porous-polymer-modified metal carbon nanotube membrane; and (2) passing the dye-containing wastewater through the porous-polymer-modified metal carbon nanotube membrane to remove dyes in the dye-containing wastewater. A device for purifying dye-containing wastewater is also disclosed. The device includes the porous-polymer-based metal carbon nanotube membrane. 1. A method for purifying dye-containing wastewater based on a porous-polymer- modified metal carbon nanotube membrane , comprising: immersing a carbon nanotube membrane in aqua regia for acidification to obtain an acidified carbon nanotube membrane;', 'preparing a modification solution that includes a zirconium salt, terephthalic acid, acetic acid, and a solvent;', 'heating the acidified carbon nanotube membrane in the modification solution and reacting to obtain a metal carbon nanotube membrane;', 'conducting a polymerization reaction of 2,3,5,6-tetrafluoroterephthalonitrile and 5,5′,6,6′-tetrahydroxy-3,3′,4,4′-tetramethyl-1,1′-spiralbisindan, under nitrogen atmosphere and in the presence of anhydrous potassium carbonate, to obtain a crude polymer product;', 'precipitating the crude polymer product in methanol, dissolving the crude product in chloroform, precipitating the crude polymer product in methanol, and heating the crude polymer product in water to obtain a porous polymer;', 'preparing a polyethylene glycol diglycidyl ether (PEGDEG) solution and coating the metal carbon nanotube membrane with the polyethylene glycol diglycidyl ether solution;', 'preparing a porous polymer solution and coating the metal carbon nanotube membrane with the porous polymer solution; and', 'heating the metal carbon nanotube membrane to obtain the porous-polymer- modified metal carbon nanotube membrane; and, '(1) preparing the porous-polymer-modified metal carbon nanotube membrane, ...

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Номер записи: 79
09-06-2022 дата публикации

METAL NANOPARTICLE-DECORATED NANOTUBES FOR GAS SENSING

Номер: US20220178859A1
Автор: Iftime Gabriel, Schwartz David Eric, Smith Clinton, Vedharathinam Vedasri, Zhang Yong
Принадлежит:

Disclosed herein are methods of producing metal nanoparticle-decorated carbon nanotubes. The methods include forming a reaction mixture by combining a first solution with a second solution, wherein the first solution comprises polymer-coated metal nanoparticles comprising metallic nanoparticles coated with a polymer, and wherein the second solution comprises carbon nanotubes. The methods also include heating the reaction mixture to a temperature greater than a glass transition temperature of the polymer for a time sufficient to cause the polymer-coated metal nanoparticles to bind to the carbon nanotubes forming the metal nanoparticle-decorated carbon nanotubes. 1. A method of producing metal nanoparticle-decorated carbon nanotubes , the method comprising:forming a reaction mixture by combining a first solution with a second solution, wherein the first solution comprises polymer-coated metal nanoparticles comprising metallic nanoparticles coated with a polymer, and wherein the second solution comprises carbon nanotubes; andheating the reaction mixture to a temperature greater than a glass transition temperature of the polymer for a time sufficient to cause the polymer-coated metal nanoparticles to bind to the carbon nanotubes forming the metal nanoparticle-decorated carbon nanotubes.2. The method of claim 1 , wherein the polymer-coated metal nanoparticles are fully-formed prior to forming the reaction mixture.3. The method of claim 2 , wherein the polymer-coated metal nanoparticles are non-covalently bound to the carbon nanotubes.4. The method of claim 1 , wherein an average degree of functionalization of the carbon nanotubes with carboxylic acid groups and/or hydroxyl groups is less than 3 wt % based on a total weight of the carbon nanotubes.5. The method of claim 1 , further comprising:dispersing the metal nanoparticle-decorated carbon nanotubes in a non-aqueous solvent-based ink.6. The method of claim 1 , wherein the polymer-coated-metal nanoparticles are coated ...

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Номер записи: 80
13-05-2021 дата публикации

ADSORBENT

Номер: US20210138430A1
Автор: Honda Kazunori, KOJIMA Chihiro, Okita Atsushi, SAKAI Shingo, TAKAHASHI Kaoru, YASHIMA Takahiro
Принадлежит: JGC CATALYSTS AND CHEMICALS LTD.

An adsorbent of the invention, which is an adsorbent for removing carbonyl sulfide in a stream containing an olefin, contains copper oxide and an aluminum compound, in which a content of the aluminum compound ranges from 10 mass % to 50 mass % in terms of Al, and an NHdesorption in a temperature region ranging from 100 degrees C. to 200 degrees C. as measured by NH-TPD measurement is more than 0.001 mmol/g and 1 mmol/g or less. 1. An adsorbent for removing carbonyl sulfide contained in a stream containing an olefin , the adsorbent comprising:copper oxide; andan aluminum compound, whereina content of the aluminum compound is in a range from 10 mass % to 50 mass % in terms of Al, and{'sub': '3', 'an NHdesorption as calculated based on a temperature-programmed desorption of ammonia in a temperature region ranging from 100 degrees C. to 200 degrees C. is in a range of more than 0.001 mmol/g and 1 mmol/g or less.'}2. The adsorbent according to claim 1 , wherein the aluminum compound exhibits the NHdesorption in a range from 0.01 mmol/g to 10 mmol/g as calculated based on a temperature-programmed desorption of ammonia in the temperature region ranging from 100 degrees C. to 200 degrees C.3. The adsorbent according to claim 2 , wherein the aluminum compound is at least one selected from the group consisting of aluminum hydroxide and aluminum oxide.4. The adsorbent according to claim 3 , wherein a crystal structure of the aluminum hydroxide is pseudo-boehmite.5. The adsorbent according to claim 3 , wherein a crystal structure of the aluminum oxide is at least one crystal structure selected from the group consisting of χ claim 3 , ρ claim 3 , and θ.6. The adsorbent according to claim 1 , wherein a specific surface area of the adsorbent is less than 200 m/g.7. The adsorbent according to claim 1 , wherein a content of the copper oxide is in a range from 5 mass % to 50 mass % in terms of Cu.8. The adsorbent according to claim 7 , wherein a Cu/Al molar ratio is in a range from 0 ...

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Номер записи: 81
04-05-2017 дата публикации

SYSTEMS AND METHODS OF PREPARING STABILIZED LIPID ASSEMBLIES

Номер: US20170120218A1
Автор: Aspinwall Craig A., Bright Leonard, Gallagher Elyssia S., Ratnayaka Saliya N., Saavedra Steven Scott
Принадлежит:

Direct polymerization of lipid monomers or polymer scaffolding of non-lipid monomers coupled with irradiation or redox polymerization performed at neutral pH resulted in stabilized lipid assemblies. An initiator-buffer component and NaHS03 redox mixture polymerizes reactive lipid monomers at near neutral pH conditions to preserve functionality of reconstituted membrane proteins. Improved stability of black lipid membranes (BLMs) is attained by chemical cross-linking of polymerizable, hydrophobic and commercially available non-lipid monomers partitioned into the suspended lipid membranes, and by suspending the BLMs across low surface energy apertures. Substrate apertures having low surface energy modifiers with amphiphobic properties facilitated a reproducible formation of BLMs by promoting interactions between the lipid tail and the substrate material. In addition, polymeric lipid bilayer membranes were prepared by photochemical or redox initiated polymerization of polymerizable lipid monomers, and disposed onto supporting substrates for use in chromatography columns. 1. A suspended lipid system comprising:a. a supporting substrate having a substrate surface and an aperture; andb. modified lipid membrane comprising a plurality of non-polymerizable lipid monomers and a plurality of polymerized, hydrophobic non-lipid monomers;wherein the modified lipid membrane is disposed on the substrate such that the lipid monomers form a lipid bilayer suspended across the aperture, wherein the non-lipid monomers are disposed in the lipid bilayer.2. The system of claim 1 , wherein the lipid bilayer is suspended across the aperture such that a first lipid leaflet and a second lipid leaflet of the lipid bilayer are both disposed above or below the aperture.3. The system of claim 1 , wherein the lipid bilayer is suspended across the aperture such that a first lipid leaflet of the lipid bilayer is disposed above the aperture and a second lipid leaflet of the lipid bilayer is disposed ...

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Номер записи: 82
25-04-2019 дата публикации

Gas Chromatography Columns with Integrated Ferrules

Номер: US20190120801A1
Автор: McCAULEY Edward B.
Принадлежит:

A capillary column includes a fused silica tubing and a polyimide coating over the fusing silica tubing. Additionally, the capillary column further includes a first plurality of integrated ferrules positioned along at least a first portion of the fused silica tubing and spaced apart from one another by a first fixed interval. 1. A capillary column comprising:a fused silica tubing;a polyimide coating over the fused silica tubing; anda first plurality of integrated ferrules positioned along at least a first portion of the fused silica tubing and spaced apart from one another by a first fixed interval, the first portion of the fused silica tubing is located at or near a first end of the capillary column.2. The capillary column of wherein the first fixed interval is not less than an insertion depth.3. The capillary column of further comprising an additional integrated ferrule positioned at or near a second end of the capillary column.4. The capillary column of further comprising a second plurality of integrated ferrules positioned along a second portion of the fused silica tubing and spaced apart from one another by a second fixed interval claim 1 , the second portion of the fused silica tubing located at or near a second end of the capillary column.5. The capillary column of wherein the first fixed interval is greater than the second fixed interval.6. The capillary column of wherein the plurality of integrated ferrules include graphite claim 1 , polyimide claim 1 , or a combination thereof.7. The capillary column of wherein the plurality of integrated ferrules are cemented to the polyimide coating.8. The capillary column of wherein the plurality of integrated ferrules include a metal.9. The capillary column of wherein the plurality of integrated ferrules are pre-swaged to the capillary column.10. A method of manufacturing a capillary column claim 7 , comprising:obtaining a polyimide coated fused silica tubing; andaffixing a plurality of ferrules to the polyimide coated ...

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Номер записи: 83
10-05-2018 дата публикации

CHILL-PROOFING COMPOSITE FILTER AIR AND RELATED METHODS

Номер: US20180126356A1
Автор: BIRMINGHAM Scot, DIAS Nathan, Fleming Robert
Принадлежит:

A chill-proofing composite filter aid may include a filtration component and an adsorption component including precipitated silica at least partially coating the filtration component. The composite filter aid may have a pore volume of at least about 0.15 cm/gram at an average pore size between 3 nanometers and 15 nanometers. A method for removing particles from a fluid may include providing a chill-proofing composite filter aid, pre-coating a filter element with the composite filter aid, and passing a fluid containing particles to be adsorbed through the coated filter element. A method of making a chill-proofing composite filter aid may include providing a filtration component, and at least partially coating the filtration component with an adsorption component including precipitated silica. The composite filter aid may have a pore volume of at least about 0.15 cm/gram at an average pore size between 3 nanometers and 15 nanometers. 1. A chill-proofing composite filter aid comprising:a filtration component; andan adsorption component comprising precipitated silica at least partially coating the filtration component,{'sup': '3', 'wherein the composite filter aid has a pore volume of at least about 0.15 cm/gram at an average pore size between 3 nanometers and 15 nanometers.'}2. The composite filter aid of claim 1 , wherein the filtration component comprises diatomaceous earth.3. The composite filter aid of claim 1 , wherein the composite filter aid has a pore volume of at least about 0.20 cm/gram at an average pore size between 3 nanometers and 15 nanometers.4. (canceled)5. (canceled)6. The composite filter aid of claim 1 , wherein the composite filter aid has a pore volume of ranging from at least about 0.15 cm/gram to about 0.35 cm/gram at an average pore size between 3 nanometers and 15 nanometers.7. The composite filter aid of claim 1 , wherein the composite filter aid has a pore volume of ranging from at least about 0.20 cm/gram to about 0.35 cm/gram at an average ...

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Номер записи: 84
02-05-2019 дата публикации

CARBON DIOXIDE ADSORBENT, METHOD FOR MANUFACTURING THE SAME, AND CARBON DIOXIDE PROCESSING SYSTEM

Номер: US20190126235A1
Автор: Iwasaki Hidekazu, KAWANO Akihito, NEGAMI Masahiro, NISHIBE Shohei, NOMURA Yoshimichi, Okumura Takeshi, YOSHIZAWA Katsuhiro
Принадлежит: KAWASAKI JUKOGYO KABUSHIKI KAISHA

A method for manufacturing a carbon dioxide adsorbent includes preparing an amine aqueous solution having an amine compound concentration ranging from 5% to 70% inclusive and a temperature ranging from 10° C. to 100° C. inclusive, impregnating silica gel with the amine aqueous solution, and aeration-drying the silica gel carrying the amine compound. The silica gel has a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, and a pore volume ranging from 0.1 cm/g to 1.3 cm/g inclusive. 1. A method for manufacturing a carbon dioxide adsorbent comprising:preparing an amine aqueous solution having an amine compound concentration ranging from 5% to 70% inclusive and a temperature ranging from 10° C. to 100° C. inclusive;impregnating silica gel with the amine aqueous solution; andaeration-drying the silica gel carrying the amine compound, wherein{'sup': 3', '3, 'the silica gel has a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, and a pore volume ranging from 0.1 cm/g to 1.3 cm/g inclusive.'}2. The method for manufacturing a carbon dioxide adsorbent according to claim 1 , wherein a water proof property N of the silica gel claim 1 , which is defined by an expression (1) claim 1 , is not lower than 45% claim 1 ,{'br': None, 'i': N', 'W/W, 'sub': '0', '=()×100\u2003\u2003(1)'}{'sub': 0', '0, 'where N is a waterproof property [%] of the silica gel, Wis a total number [pieces] of particles of the silica gel immersed in water, W is a number [pieces] of particles of the silica gel not subjected to breakage out of W.'}3. The method for manufacturing a carbon dioxide adsorbent according to claim 1 , wherein the amine compound is at least one compound selected from a group of amines having at least one hydroxyl group and polyamines.4. A carbon dioxide adsorbent including silica gel and an amine compound carried by the silica gel claim 1 , the silica gel ...

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Номер записи: 85
02-05-2019 дата публикации

NANOMETER-SIZE ZEOLITIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF

Номер: US20190126258A1
Автор: GONCHE FORTUNATUS MACHOKE Albert, SCHWIEGER Wilhelm
Принадлежит:

A particulate material and a process for the production thereof are provided, which particulate material comprises zeolitic particles having a crystalline structure, which contain as the main component a zeolite material having a zeolitic framework structure formed from Si, O and optionally Al, and/or a zeolite-like material having a zeolitic framework structure which is formed not only from Si, O and optionally Al, wherein the zeolitic particles are in the form of essentially spherical particles with nanometer dimensions. 1. A particulate material which comprises zeolitic particles having a crystalline structure , which contain as the main component a zeolite material having a zeolitic framework structure formed from Si , O and optionally Al , and/or a zeolite-like material having a zeolitic framework structure which is formed not only from Si , O and optionally Al , characterized in that the zeolitic particles are in the form of essentially spherical particles with nanometer dimensions.2. The particulate material as claimed in claim 1 , characterized in that it comprises zeolitic particles which contain one or more metal-containing components that are not involved in the structure of the zeolitic framework material.3. The particulate material as claimed in claim 1 , characterized in that at least 90% of all the zeolitic particles claim 1 , expressed in terms of the particle number claim 1 , have a particle size of from 50 to 200 nm.4. The particulate material as claimed in claim 1 , characterized in that the zeolitic framework structure is formed from tetrahedral SiOunits claim 1 , wherein up to 30% of all the silicon atoms in the framework structure may be replaced by one or more other network-forming elements selected from elements of main groups 3 claim 1 , 4 and 5 of the periodic table.5. The particulate material as claimed in claim 1 , characterized in that the zeolitic framework structure is a high-silica zeolite structure.6. The particulate material as ...

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Номер записи: 86
02-05-2019 дата публикации

COMPOSITIONS AND METHODS FOR PERFORMING MAGNETIBUOYANT SEPARATIONS

Номер: US20190127697A1
Автор: GOHEL Dhanesh, RANSOM John, ZHANG Hong
Принадлежит:

Processes and compositions are provided for performing magnetibuoyant separations of different biomolecules (e.g., cells, organelles, etc.) in a biological sample, as well as compositions and kits for performing such methods. Compositions containing the separated biomolecules, and methods for using the same for in-vitro and in-vivo biomedical applications, are also provided. The magnetibuoyant methods of the invention employ targeted magnetic particles, preferably targeted nanomagnetic particles, and targeted buoyant particles such as buoyant microparticles and microbubbles. Among the benefits of the invention is the ability to combine targeted magnetic particles with differentially targeted buoyant particles to achieve separation of two or more specifically cell targeted populations during the same work flow. 1. A method of separating at least one target biomolecule species from a biological sample , comprising:(a) in a reaction mixture, contacting a biological sample known or suspected to contain first and second biomolecule species of interest with a targeted magnetic particle species, optionally a targeted nanomagnetic particle species, that targets the first biomolecule species of interest to form first target biomolecule/magnetic particle complexes and a targeted buoyant particle species, optionally a targeted buoyant microparticle, optionally a microbubble, species that targets the second biomolecule species of interest to form second target biomolecule/buoyant particle complexes;(b) using a magnetic field to isolate the first biomolecule/magnetic particle complexes from the reaction mixture; and/or,(c) using buoyancy/floatation properties to separate the second target biomolecule/buoyant particle complexes from the reaction mixture.2. A method according to wherein the targeted magnetic particle species is a targeted nanomagnetic particle species that comprises:(i) a magnetic core particle;(ii) a glass layer encapsulating the magnetic core particle;(iii) a ...

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Номер записи: 87
17-05-2018 дата публикации

NOVEL CROSSLINKED POLYMERIC SUBSTRATES METHODS OF PREPARATION AND END USE APPLICATIONS OF THE SUBSTRATES

Номер: US20180134740A1
Автор: Adamson Douglas H., Collins Warde T., GRAHAM David E., Mininni Robert M.
Принадлежит:

A composition of matter wherein the composition comprises a siliceous substrate having silanols on the surface and a polymer selected from the group consisting essentially of a water soluble polymer, a water soluble copolymer, an alcohol soluble polymer, an alcohol soluble copolymer, and combinations of such polymers, wherein the polymer is chemically bonded to the siliceous substrate by a silane linking material having the general formula 133.-. (canceled)34. A process for preparing a crosslinked polymer that is chemically bonded to the surface of a siliceous substrate , said process consisting essentially of:(I) heating a predetermined amount of alcohol in a reaction vessel with stirring, wherein the alcohol has from 1 to 9 carbon atoms;(II) adding a predetermined amount of a hydrolysis catalyst selected from organic acids having from 1 to 7 carbon atoms:(III) adding a predetermined amount of a silanol condensation catalyst;(IV) adding a predetermined amount of siliceous substrate containing reactive silanols; [{'br': None, 'sub': '3', '(RO)SiQX'}, 'wherein R is a hydrocarbon group having from 1 to 6 carbon atoms, Q is a hydrocarbon group having from 0 to 6 carbon atoms, X is a functional group selected from the group consisting of epoxy, halogen, methacrylate, vinyl, amine, allyl, phosphonate, styrlamine, and sulfide;, '(V) adding a predetermined amount of silane coupling agent, said silane being an alkoxy-functional silane having the general formula'} (i) a water soluble polymer,', '(ii) a water soluble copolymer,', '(iii) an alcohol soluble polymer,', '(iv) an alcohol soluble copolymer, and', '(v) combinations of (i) to (iv),, '(VI) adding a predetermined amount of polymer, said polymer being selected from the group consisting of'}(VII) stirring the combination of (I) to (VI) for a period of time of 12 hours or less at a temperature of 75° C. or less; wherein the ratio of polymer to siliceous substrate is in the range of P:S wherein P is 0.1 to 50 and S is 99.9 ...

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Номер записи: 88
18-05-2017 дата публикации

SORBENTS FOR CARBON DIOXIDE REDUCTION FROM INDOOR AIR

Номер: US20170136399A1
Автор: Biran Israel, Meirav Udi
Принадлежит:

A sorbent for COreduction from indoor air from an enclosed space. In some embodiments, the sorbent comprises a solid support and an amine-based compound being supported by the support. The sorbent captures at least a portion of the COwithin the indoor air. The sorbent may be regenerated by streaming outdoor air through the sorbent to release at least a portion of the captured CO. The sorbent is structured to allow indoor air to flow therein with relatively low flow resistance and relatively rapid reaction kinetics. Regeneration may be performed at relatively low outdoor air temperatures, thereby minimizing the thermal energy required for regenerating the sorbent. 143.-. (canceled)44. A sorbent for reduction of COfrom indoor air of an enclosed space , comprising: a support material; and', 'an amine-based compound, wherein at least 25% of amine functional groups are secondary amines,, 'a plurality of solid particles having an average diameter dimension in the range of 0.1-10 millimeters, and wherein at least some of the particles comprise{'sub': 2', '2, 'wherein the amine-based compound further comprises water, wherein the support is combined with the amine-based compound; and wherein the amine-based compound is configured to capture at least some of the COwithin the indoor air of the enclosed space and release at least a portion of the captured CO.'}45. A sorbent according to claim 44 , wherein the support is selected from the group consisting of gels claim 44 , molecular sieves claim 44 , nanotube-containing materials claim 44 , porous materials claim 44 , sponge and sponge-like materials claim 44 , electro-magnetically charged objects claim 44 , porous organic polymers claim 44 , ion exchange resins claim 44 , polymeric absorbent resins claim 44 , acrylic ester polymers claim 44 , polystyrene divinyl benzene claim 44 , polymethyl methacrylate (PMMA) claim 44 , polystyrene claim 44 , styrene divinylbenzene (SDB) claim 44 , fly ash claim 44 , activated carbon claim ...

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Номер записи: 89
18-05-2017 дата публикации

MERCURY REMOVAL

Номер: US20170137914A1
Автор: STEVENS James George
Принадлежит: JOHNSON MATTHEY PUBLIC LIMITED COMPANY

Disclosed is selective removal of mercury from aqueous feeds also including precious metals. In particular, the present invention is useful for removal of mercury from processing waters produced during precious metal mining processes. The process includes contacting the aqueous feed solution with a solid sorbent material including thiol and/or thiolate functional groups, wherein (i) the aqueous feed solution includes at least 10 ppm of free cyanide ions; and/or (ii) the sorbent material is contacted with an aqueous cyanide solution after contact with the aqueous feed solution to selectively desorb precious metal from the sorbent material. 1. A process for selectively removing mercury from an aqueous feed solution , the aqueous feed solution comprising mercury in addition to one or more precious metals , wherein the process comprises contacting the aqueous feed solution with a solid sorbent material comprising thiol and/or thiolate functional groups , wherein(i) the aqueous feed solution comprises at least 10 ppm of free cyanide ions; and/or(ii) the sorbent material is contacted with an aqueous cyanide solution after contact with the aqueous feed solution to selectively desorb precious metal from the sorbent material.2. A process according to wherein the precious metal present in the aqueous feed solution is one or both of gold and silver.3. A process according to wherein the mercury is present as a mercury cyanide complex and each precious metal is present as a precious metal cyanide complex.4. A process according to wherein the aqueous feed solution comprises at least 30 ppm of free cyanide ions.5. A process according to wherein the aqueous cyanide solution comprises at least 30 ppm of cyanide ions.6. A process according to wherein the process further comprises the step of adding cyanide ions to the aqueous feed solution.7. A process according to wherein the aqueous feed solution has a pH in the range from 9 to 13.8. A process according to where in the sorbent ...

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Номер записи: 90
08-09-2022 дата публикации

SORBENT PARTICLES FOR SAMPLE TREATMENT

Номер: US20220280909A1
Автор: Alden Bonnie, Brousmiche Darryl W., Fairchild Jacob N., Lawrence Nicole L., Wyndham Kevin D.
Принадлежит: WATERS TECHNOLOGIES CORPORATION

Novel sorbents, devices, kits and methods useful for sample treatment are disclosed herein. 134-. (canceled)35. Inorganic/organic hybrid sorbent particles comprising an organic copolymer that comprises at least one hydrophilic organic monomer , at least one hydrophobic organic monomer , and at least one alkenyl-functionalized organosilane monomer , wherein the particles are modified by the addition of a C4-C60 alkyl component.36. The inorganic/organic hybrid sorbent particles of claim 35 , wherein the particles are modified by hydrolytic condensation of a C4-C60-alkyl-functionalized organosilane compound.37. The inorganic/organic hybrid sorbent particles of claim 36 , wherein the C4-C60-alkyl-functionalized organosilane compound is a compound of the formula RSiZZZ claim 36 , where R is C4-C60 alkyl and where Z claim 36 , Zand Zare independently selected from Cl claim 36 , Br claim 36 , I claim 36 , C1-C4 alkoxy claim 36 , C1-C4 alkylamino claim 36 , and C1-C4 alkyl claim 36 , although at most two of Z claim 36 , Zand Zcan be C1-C4 alkyl.38. inorganic/organic hybrid sorbent particles of claim 36 , wherein the C4-C60-alkylorganosilane is selected from octadecyltrimethoxysilane claim 36 , octadecyltriethoxysilane claim 36 , octadecyltrichlorosilane claim 36 , octadecyltri(dimethylamino)silane claim 36 , methyloctadecyldimethoxysilane claim 36 , methyloctadecyldiethoxysilane claim 36 , methyloctadecyldichlorosilane claim 36 , methyloctadecyldi(dimethylamino)silane claim 36 , dimethyloctadecylmethoxysilane claim 36 , dimethyloctadecylethoxysilane claim 36 , dimethyloctadecylchlorosilane claim 36 , dimethyloctadecyldimethylaminosilane claim 36 , diisopropyloctadecylmethoxysilane claim 36 , diisopropyloctadecylethoxysilane claim 36 , diisopropyloctadecylchlorosilane claim 36 , diisopropyloctadecyldimethylaminosilane claim 36 , octyltrimethoxysilane claim 36 , octyltriethoxysilane claim 36 , octyltrichlorosilane claim 36 , octyltri(dimethylamino)silane claim 36 , ...

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Номер записи: 91
18-05-2017 дата публикации

Fiber bragg grating optical sensor having a nanoporous coating

Номер: US20170138862A1
Автор: Arjen Boersma, Dennis Johannes Maria SNELDERS
Принадлежит: Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO

The invention relates to an optical waveguide having a Fibre Bragg Grating, which waveguide is provided with a coating having a nanoporous sensor material, the sensor unit further having an optical detection unit for detecting a change in an optical property of the waveguide, wherein the grating is present in the core of the waveguide and the coating at least substantially surrounds the grating. The coating is expandable or shrinkable under the influence of the chemical substance, thereby causing a change in axial strain in the grating when the sensor material is exposed to the chemical substance, which change is detectible by a optical detection unit. The invention further relates to an optical sensor system for measuring a chemical substance, the sensor system having a waveguide according to the invention

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Номер записи: 92
10-06-2021 дата публикации

CONDUCTIVE POLYMER GRAFTED REUSABLE 3D PLATFORM FOR WATER RESTORATION

Номер: US20210170360A1
Автор: FU Wenxin, Lu Jennifer
Принадлежит: The Regents of the University of California

A platform and system for concentration, reduction and regeneration of heavy metals and other contaminants from fluids is provided. The platform has a three-tiered hierarchical porous structure, composed of micropores formed by woven carbon cloth, nanopores formed after carbon nanotube growth on the cloth fibers and mesopores formed by a polymer outer layer. The material of the platform can be incorporated into cells with two electrodes with properly functionalized PDAN grafted 3D carbon as an anode and cathode respectively. Metal ions and toxic anions in water will be captured selectively by primary amine, secondary amine and quaternary amine groups in porous PDAN on the anode. Metals are captured and reduced by the cathode. 1. A heavy metal ion adsorber material , comprising:(a) a scaffold of multiple interwoven carbon strands, said strands having an outer surface;(b) a plurality of 1D conductive nanostructures mounted to the outer surface of each carbon strand; and(c) a coating of at least one polymer on outer surfaces of said nanostructures and said carbon strands.2. The adsorber of claim 1 , wherein said scaffold comprises a carbon cloth of interwoven carbon strands with a diameter of between 5 μm and 10 μm.3. The adsorber of claim 1 , wherein said 1D nanostructures are selected from the group of nanostructures consisting of multiwalled carbon nanotubes claim 1 , carbon nanofibers and carbon nanowires.4. The adsorber of claim 1 , wherein said polymer is a polymer selected from the group of polymers consisting of polyaniline claim 1 , PANI claim 1 , and polypyrrole.5. The adsorber of claim 1 , wherein said polymer is a polymer selected from the group of polymers consisting of poly(1 claim 1 ,5-diaminonaphthalene) and poly(1 claim 1 ,8-diaminonaphthalene).6. The adsorber of claim 1 , said polymer coating further comprising functionalized amine groups from exhaustive methylation.7. The adsorber of claim 1 , said scaffold further comprising an electrical contact ...

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Номер записи: 93
16-05-2019 дата публикации

AMINE-BASED CARBON DIOXIDE ADSORBENT RESISTENT TO OXYGEN AND SULFER DIOXIDE AND METHOD OF PREPARING THE SAME

Номер: US20190143299A1
Автор: CHOI Minkee, CHOI Woosung, KIM CHAEHOON
Принадлежит:

The core-shell type amine-based carbon dioxide adsorbent including a chelating agent resistant to oxygen and sulfur dioxide according to the present invention is an adsorbent which includes a chelating agent to inhibit oxidative decomposition of amine and has, as a core, a porous support on which an amine compound is immobilized and has, as a shell, an amine layer resistant to inactivity by sulfur dioxide, and a method of preparing the same. The amine-based carbon dioxide adsorbent including a chelating agent exhibits considerably high oxidation resistance because an added chelate compound functions to directly remove a variety of transition metal impurities catalytically acting on amine oxidation. In addition, the sulfur dioxide-resistant amine layer of the shell selectively adsorbs sulfur dioxide to protect the amine compound of the core and, at the same time, the amine compound of the core selectively adsorbs only carbon dioxide. In addition, sulfur dioxide adsorbed on the shell is readily desorbed therefrom at about 110° C. and thus remarkably improved regeneration stability is obtained during the temperature-swing adsorption (TSA) process containing sulfur dioxide. 1. An amine-based carbon dioxide adsorbent in which a chelating agent is supported on a porous support and an amine compound is bonded to the porous support.2. An amine-based carbon dioxide adsorbent having a core-shell structure comprising:a core containing an amine compound and a porous support; anda shell containing a sulfur dioxide-resistant amine compound and being coated with surrounding the core.3. The amine-based carbon dioxide adsorbent according to claim 1 , wherein the chelating agent is selected from the group consisting of phosphoric acid and salts in which some or all of the hydrogen cations (protons) thereof are substituted with alkali metal cations claim 1 , etidronic acid (1-hydroxyethane 1 claim 1 ,1-diphosphonic acid claim 1 , HEDP) and salts in which some or all of the hydrogen ...

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Номер записи: 94
07-05-2020 дата публикации

Magnetic Adsorbent for Removing Arsenic and Antimony by means of Adsorption-Superconducting Magnetic Separation and Preparation Method therefor

Номер: US20200139341A1
Автор: LAN Huachun, LIU Huijuan, Liu Ruiping, QI Zenglu, QU Jiuhui, ZHU Lijun
Принадлежит:

A magnetic adsorbent, preparation method therefor and application thereof. The magnetic adsorbent is made by loading a weakly material with high adsorption capacity, an iron-based gel, onto a strongly magnetic ferrite material with low adsorption capacity by means of in-situ reaction. The magnetic adsorbent is used for removing heavy metal pollutants and phosphate pollutants from water. 1. A method for preparing a magnetic adsorbent used for superconducting magnetic separation , comprising the following steps:preparing an iron-based gel by a ferric salt solution and an alkali solution, wherein, dropping the alkali solution slowly into the ferric salt solution and balancing the pH value between 4 to 7.5 under conditions of sufficient stirring, then continuing stirring for 5 to 30 min and standing for 60 min to 24 h to obtain the iron-based gel;loading the obtained iron-based gel on a surface of ferrite by reaction in situ.2. The method of claim 1 , wherein the concentration range of ferric salt is 0.5 to 10 mmol/L and the concentration range of OH in the alkali solution is 0.1 to 10 mol/L.3. The method of claim 1 , wherein the ferric salt is at least one of ferric chloride claim 1 , ferric sulfate claim 1 , ferric nitrate claim 1 , polyferric chloride claim 1 , polyferric sulfate and polyferric nitrate;the alkali solution is at least one of sodium hydroxide, potassium hydroxide and aqueous ammonia.4. The method of claim 1 , wherein claim 1 , the iron-based gel is loaded on the ferrite surface using the following method:(1) adding polyacrylamide solution slowly into ferrite solution under conditions of sufficient stirring, in which the mass ratio of polyacrylamide to ferrite is 1:100 to 1:50000, and reacting for 30 to 120 min to obtain a ferrite suspension;(2) adding an iron-based gel suspension slowly into the ferrite suspension obtained in (1) under conditions of sufficient stirring, in which the mass ratio of the iron-based gel and ferrite is 1:10 to 1:500, and ...

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Номер записи: 95
31-05-2018 дата публикации

PHOTOCATALYST COATING

Номер: US20180147572A1
Автор: Fukumura Takuya
Принадлежит:

The present invention provides a photocatalytic composition comprising: a photocatalyst; and an adsorbent material. 1. A photocatalytic composition comprising:a photocatalyst; andan adsorbent material.2. The photocatalytic composition according to claim 1 , wherein the adsorbent material comprises solid acid and/or solid base.3. The photocatalytic composition according to claim 1 , wherein the adsorbent material comprises at least one of ZrO claim 1 , activated carbon and AlO.4. The photocatalytic composition according to claim 1 , further comprising a co-catalyst.5. The photocatalytic composition according to claim 1 , wherein the photocatalyst comprises WO.6. The photocatalytic composition according to claim 4 , wherein the co-catalyst comprises ZrO claim 4 , or CeO.7. The photocatalytic composition according to claim 4 , wherein the co-catalyst comprises cerium.8. The photocatalytic composition according to claim 4 , wherein the co-catalyst comprises CeO.9. The photocatalytic composition according to claim 1 , where the photocatalyst is doped with at least one naturally occurring element.10. The photocatalytic composition according to claim 1 , where the photocatalyst is loaded with a transition metal claim 1 , a transition metal oxide claim 1 , or a transition metal hydroxide.11. The photocatalytic composition according to claim 10 , wherein the transition metal is Cu claim 10 , Fe claim 10 , or Ni.12. The photocatalytic composition according to claim 1 , wherein the photocatalyst is loaded with a noble metal claim 1 , a noble metal oxide claim 1 , or a noble metal hydroxide.13. The photocatalytic composition according to claim 12 , wherein the noble metal is Au claim 12 , Ag claim 12 , Pt claim 12 , Pd claim 12 , Ir claim 12 , Ru claim 12 , or Rh.14. The photocatalytic composition according to claim 4 , wherein the co-catalyst comprises a binder.15. The photocatalytic composition according to claim 1 , wherein the photocatalytic composition is capable of ...

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Номер записи: 96
17-06-2021 дата публикации

Method for Trapping Noble Gas Atoms and Molecules in Oxide Nanocages

Номер: US20210178323A1
Автор: Akter Nusnin, Boscoboinik Alejandro Miguel, Boscoboinik Jorge A., Lu Deyu, Stacchiola Dario J., Wang Mengen, Xu Yixin, Zhang Jianqiang
Принадлежит:

A method for trapping noble gas atoms and molecules in oxide nanocages that includes providing oxide nanocages on a metallic substrate, ionizing a noble gas to form noble gas cations, applying a voltage to the metallic substrate, contacting the oxide nanocages with the noble gas cations, and deionizing the cations to form noble gas atoms and molecules that are trapped within the oxide nanocages. In one embodiment of the present device, polygonal prism organosilicate cages on a ruthenium thin film can trap noble gases. 1. A method of trapping noble gas atoms or molecules comprising:providing a metallic substrate;forming one or more oxide nanocages on the metallic substrate to form a gas trapping assembly;contacting the gas trapping assembly with a noble gas comprising noble gas atoms or noble gas molecules;ionizing the noble gas to form noble gas cations that enter the one or more oxide nanocages; anddeionizing the noble gas cations,wherein, after the noble gas cations enter the one or more oxide nanocages of the gas trapping assembly, the deionization of the noble gas cations forms noble gas atoms or noble gas molecules that are trapped in the one or more oxide nanocages.2. The method of trapping noble gas atoms or molecules according to claim 1 , wherein the metallic substrate is selected from the group consisting of ruthenium (Ru) claim 1 , nickel (Ni) claim 1 , iron (Fe) claim 1 , copper (Cu) claim 1 , gold (Au) claim 1 , and cobalt (Co).3. The method of trapping noble gas atoms or molecules according to claim 1 , wherein the one or more oxide nanocages comprises silica or aluminosilicate.4. The method of trapping noble gas atoms or molecules according to claim 3 , wherein the one or more oxide nanocages further comprise an additional component selected from the group consisting of aluminum claim 3 , titanium claim 3 , iron claim 3 , boron claim 3 , and phosphorus.5. The method of trapping noble gas atoms or molecules according to claim 1 , wherein the noble gas ...

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Номер записи: 97
17-06-2021 дата публикации

ARSINE ADSORBENTS

Номер: US20210178358A1
Автор: Hratko Linda, Maglio Alfonse, VITYUK Artem D.
Принадлежит:

An adsorbent composition comprises a bismuth material, a promoter and optionally a support. The adsorbent composition is suitable for adsorbing an arsenic material, such as arsine, from a process stream. 1. An adsorbent composition comprising a bismuth material , a promoter , and a support , wherein the support comprises particles having a particle size of from about 1 μm to 10 mm.2. The adsorbent composition according to claim 1 , wherein the bismuth material and the promoter are in a bulk form or dispersed form.3. The adsorbent composition according to claim 1 , wherein the bismuth material is selected from a group consisting of elemental bismuth and bismuth compounds.4. (canceled)5. The adsorbent composition according to claim 1 , wherein the bismuth material comprises bismuth (III) oxide (BiO).6. The adsorbent composition according to claim 1 , wherein the composition comprises from about 0.1 wt % to about 50.0 wt % bismuth material on a bismuth metal basis claim 1 , based on the total weight of the composition.7. The adsorbent composition according to claim 1 , wherein the promoter comprises a tungsten material or a silicon material.8. (canceled)9. The adsorbent composition according to claim 1 , wherein the composition comprises from about 0.05 wt % to about 25.0 wt % promoter claim 1 , based on the total weight of the composition.10. The adsorbent composition according to claim 1 , wherein the support is selected from a group consisting of metal oxides claim 1 , metalloid oxides claim 1 , activated carbons claim 1 , high surface area metal oxides claim 1 , and molecular sieves.11. (canceled)12. The adsorbent composition according to claim 1 , wherein the support comprises titanium dioxide or anatase titanium dioxide.13. (canceled)14. The adsorbent composition according to claim 1 , wherein the support comprises aluminum oxide claim 1 , titanium oxide claim 1 , oxide claim 1 , or silica.15. (canceled)16. (canceled)17. The adsorbent composition according to ...

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Номер записи: 98
01-06-2017 дата публикации

Method of Preparing Adsorbent for Phosphorus Adsorption and Adsorbent Prepared by the Same

Номер: US20170151550A1
Автор: Lee Taeyoon
Принадлежит:

The present invention relates to a method for preparing an adsorbent for phosphorus adsorption and an adsorbent prepared by the method. Specifically, according to the present invention, the surface of conventional expanded vermiculite, which is effective for removal of cations but is not effective for removal of anions, is coated with sulfate to modify the surface, thereby preparing an adsorbent for phosphorus adsorption. Namely, the surface of expanded vermiculite is ionized by sulfate to thereby significantly increase the efficiency with which the anion phosphorus is removed by the expanded vermiculite. In addition, a floating-type adsorbent can be prepared using the expanded vermiculite as described above, and thus it can be quickly separated from water after adsorption without requiring a process for separating the absorbent from water. 1. A method for preparing an adsorbent for phosphorus adsorption , the method comprising soaking expanded vermiculite with a sulfate solution , followed by heat treatment.2. The method of claim 1 , comprising the steps of:{'b': '100', '(S) mixing the sulfate solution with the expanded vermiculite;'}{'b': 200', '100, '(S) heat-treating the expanded vermiculite absorbed and coated with the sulfate solution in step S; and'}{'b': 300', '200, '(S) cooling the expanded vermiculite heat-treated in step S, followed by washing and drying.'}3100. The method of claim 2 , wherein step S comprises mixing the sulfate solution with the expanded vermiculite at a ratio of 3:1 to 5:1.4100. The method of claim 3 , wherein the sulfate solution is obtained by mixing 3-5 parts by weight of sulfate with parts by weight of water.5200100. The method of claim 2 , wherein step S comprises heat-treating the expanded vermiculite claim 2 , absorbed and coated with the sulfate solution in step S claim 2 , by heating the expanded vermiculite to a temperature of 380 to 780° C. in an electric furnace.6300. The method of claim 2 , wherein step S comprises:{'b': ' ...

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Номер записи: 99
01-06-2017 дата публикации

PROCESS FOR MANUFACTURING A COMPOSITE SORBENT MATERIAL FOR CHROMATOGRAPHICAL SEPARATION OF BIOPOLYMERS

Номер: US20170152501A1
Автор: Balayan Hamlet, Brem Gottfried, Leiser Robert-Matthias, Plobner Lutz, Tkachenko Leonti E.
Принадлежит: NExtTec GmbH

The present invention relates to a sorbent material for separation and purification of biopolymers, particularly nucleic acids, having a solid support substantially modified with a copolymer coating comprising aromatic monomers and crosslinking compounds and unsaturated esters or ethers preferably attached to the support via a vinylchlorsilane. The use of these materials for separation of nucleic acids, particularly a one-step isolation of DNA from lysates of different biological sources, is an object of the invention as well as a chromatographic column or cartridge at least partially filled with the sorbent material of the invention, a membrane-like device comprising the sorbent material of the invention, and a kit comprising the sorbent material of the invention in bulk or packed in chromatographic devices as well as other devices necessary for performing sample preparations. 122-. (canceled)24. The process of wherein the support is a porous inorganic material comprising inorganic metal oxide.25. The process of wherein the porous inorganic metal oxides show a bidisperse distribution of pore sizes.26. The process of wherein the support has an average pore size of 2-200 nm.27. The process of wherein the polymer coating has a thickness of about 10 to 250 Angström.28. The process of wherein the inorganic metal oxide is selected from the group consisting of oxides of aluminum claim 24 , titanium claim 24 , zirconium claim 24 , silicon oxides claim 24 , iron oxides claim 24 , controlled pore glass (CPG) claim 24 , diatomaceous earth and combinations thereof.29. The process of wherein the porous inorganic metal oxide shows a bidisperse distribution with mean pore diameters in the range of 20-100 nm for the larger pore size.30. The process of wherein the porous inorganic metal oxide has a mean pore diameter in the range of 2-15 nm for the smaller pore size.31. The process of wherein the ratio of the mean diameter of the large pore size distribution and the lower pore size ...

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