08-10-2015 дата публикации
Номер: US20150284615A1
Low-VOC compositions of dialkyl-functional siloxane oligomers, especially of methylalkylalkoxysiloxanes, and processes for producing them are provided. Additionally methods for hydrophobizing porous mineral substrates employing the low-VOC compositions, in the course of which few or no volatile organic compounds are released, are provided. 2. The composition according to claim 1 , whereinR′ is a linear or branched octyl group,R″ is a methyl group,each R is independently hydrogen or an alkyl group having 1 to 2 C atoms, andn is an integer from 0 to 10.3. The composition according to claim 1 , whereinR′ is an alkyl group selected from the group consisting of propyl, n-propyl, isopropyl, butyl, isobutyl, n-butyl, tert-butyl, n-octyl, 2-methylheptyl, 3-methylheptyl, 4-methylheptyl, 2,2-dimethylhexyl, 2,3-dimethylhexyl, 2,4-dimethylhexyl, 2,5-dimethylhexyl, 3,3-dimethylhexyl, 3,4-dimethylhexyl, 3-ethylhexyl, 2,2,3-trimethylpentyl, 2,2,4-trimethylpentyl(isooctyl), 2,3,3-trimethylpentyl, 2,3,4-trimethylpentyl, 3-ethyl-2-methylpentyl and 3-ethyl-3-methylpentyl, 2,2,3,3-tetramethylbutyl, cycloheptylethylene, methylcyclohexylmethylene, cycloheptylmethylene and methylcycloheptyl.4. The composition according to claim 3 , wherein R′ is n-octyl claim 3 , isobutyl claim 3 , n-propyl or 2 claim 3 ,2 claim 3 ,4-trimethylpentyl(isooctyl).5. The composition according to claim 1 , whereinn is an integer from 1 to 5.6. The composition according to claim 1 , further comprising one or more different dialkyl-functional linear siloxane oligomers of the general formula I.7. The composition according to claim 1 , comprising the dialkyl-functional cyclic siloxane oligomer of formula (II).8. The composition according to claim 7 , wherein a molar ratio of the dialkyl-siloxane oligomer of formula I to the dialkyl-functional cyclic siloxane oligomer of formula (II) is from 100:1 to 1:100.9. The composition according to claim 1 , wherein a wt % of the the dialkyl-siloxane oligomers of the formula I ...
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