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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 6271. Отображено 100.
03-01-2013 дата публикации

Radiation-curable coating compositions, composite and plastic materials coated with said compositions and methods for their preparation

Номер: US20130005850A1
Принадлежит: Finishes Unlimited Inc

Disclosed is a curable coating composition suitable for use on composite substrates such as plastic composites, cementitious composites, ceramic composites, and engineered wood, or on plastic materials. The curable coating composition comprises a multifunctional oligomer, a monomer selected from the group consisting of monofunctional monomers, difunctional monomers and mixtures thereof, a photoinitiator, a polyester resin and a polycarboxylic acid. Also disclosed is a method of coating the substrates with the curable coating composition and a coated substrate wherein the cured coating resides on the surface of the substrate.

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14-03-2013 дата публикации

FUNCTIONAL LAMINATED PLATE, AND TRANSPARENT ELECTRICALLY CONDUCTIVE LAMINATED PLATE FOR TOUCH PANEL AND TOUCH PANEL PRODUCED USING SAME

Номер: US20130063393A1
Принадлежит:

Disclosed is a functional laminated sheet having flexibility, high body and good die cutting workability. The functional laminated sheet comprises a laminated sheet composed of at least two plastic films bound to each other through an adhesive layer and a functional layer formed on one surface or both surfaces of at least one of the plastic films, wherein the adhesive layer has a Martens hardness of 260 N/mmor less. The functional layer is, for example, a layer having an electromagnetic wave shielding function, a heat ray reflection function, a gas barrier function or a planar heat generation function, and can be arranged in the inside of the laminated sheet. Alternatively, the functional layer is a layer having a light reflection function, a light permeation control function or an antifogging function, and can be arranged on the outermost surface of the laminated sheet. Also disclosed is a transparent electrically conductive laminated sheet for a touch panel, which comprises a transparent laminated sheet having a transparent plastic film bonded thereto through the adhesive layer and a transparent electrically conductive layer formed on the transparent laminated sheet. 1. A functional laminated plate comprising at least two plastic films adhered to each other through an adhesive layer , at least one of the plastic films having a functional layer provided on one surface or both surfaces of the plastic film ,{'sup': '2', 'characterized in that the adhesive layer has a Martens hardness of 260 N/mmor less.'}2. A functional laminated plate comprising at least two plastic films adhered to each other through an adhesive layer ,{'sup': '2', 'characterized in that at least one functional layer is provided between the plastic films, and the adhesive layer has a Martens hardness of 260 N/mmor less.'}3. The functional laminated plate according to claim 2 ,characterized in that the functional layer has a function selected from an electromagnetic wave shielding function, a heat ...

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04-04-2013 дата публикации

Waterborne base coat compositions having a light metallic color

Номер: US20130084403A1
Принадлежит: EI Du Pont de Nemours and Co

A waterborne base coat having a light metallic color and containing 0.5 to 2 wt.-% of poly(meth)acrylic acid thickener and 2 to 7 wt.-% of non-ionically emulsified EVA copolymer wax with a drop point of the wax portion of 80 to 110° C., the wt.-% in each case calculated as solids and relative to the solids content of the waterborne base coat.

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23-05-2013 дата публикации

Polymer Latex Blends and Applications Thereof

Номер: US20130130025A1
Принадлежит: Celanese International Corp

Disclosed are blended latex dispersions which can be used as binders in paper coating compositions. Such latex dispersions comprise a first copolymer of a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms and ethylene; and a second copolymer of (i) styrene and butadiene, (ii) styrene, butadiene and acrylonitrile, or (iii) styrene and an acrylic monomer, wherein the first and second copolymers are colloidally dispersed in an aqueous medium comprising a surfactant. The paper coating compositions containing latex dispersion binders of this type preferably exhibit especially desirable coating strength as quantified by the Dry Pick Values which such compositions provide.

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23-05-2013 дата публикации

AQUEOUS POLYMER DISPERSIONS AND PRODUCTS FROM THOSE DISPERSIONS

Номер: US20130131260A1
Принадлежит: Dow Global Technologies LLC

A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer. 1. An aqueous dispersion comprising: the melt-kneading product of ethylene-vinyl acetate copolymer and at least one or more dispersing agents-in the presence of water and, optionally, one or more neutralizing agents; wherein the aqueous dispersion has a pH in the range of 8 to 11, and an average particle size in the range of 0.05 to 4.5 μm, and wherein said aqueous dispersion comprises from 10 to 70 percent by weight solid, based on the weight of the aqueous dispersion, and wherein said aqueous dispersion comprises at least 30 percent by weight of water, based on the weight of the aqueous dispersion. This patent application is a continuation of U.S. patent application Ser. No. 13/416,453, filed on May 29, 2012, entitled, “AQUEOUS POLYMER DISPERSIONS AND PRODUCTS FROM THOSE DISPERSIONS,” which is a continuation of U.S. patent application Ser. No. 13/048,626, filed on Mar. 15, 2011, which is a continuation application of U.S. patent application Ser. No. 12/815,918, filed on Jun. 15, 2010, which is a divisional application of U.S. patent application Ser. No. 11/068,573, which claims the benefit, pursuant to 35 U.S.C. §120 as a continuation in part application of U.S. patent application Ser. No. 10/925,693, which claims priority to U.S. Provisional Application Ser. No. 60/497,527, filed on Aug. 25, 2003, and U.S. Provisional Application Ser. No. 60/548,493, filed on Feb. 27, 2004, the teachings of which are incorporated by reference herein, as if reproduced in full hereinbelow.Aqueous dispersions of a thermoplastic resin of ...

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27-06-2013 дата публикации

Decorative and Protective Covering

Номер: US20130164482A1
Автор: Tornetta Anthony
Принадлежит:

The present invention generally relates to covering for a window sill, a fireplace mantel or ledge. The covering can be used for the purpose of decoration. The covering can be used for the purpose of protection. The covering can be used for the purpose of energy savings. The present invention relates to a covering comprising a core material, enclosed by a cover having a first portion which encloses the core and a second portion which extends downward from first portion. 1. A covering comprising a core material , enclosed by a cover having a first portion which encloses the core material and a second portion which extends from first portion.2. The covering of claim 1 , wherein the core material comprises rubber.3. The covering of claim 1 , wherein the core material comprises plastic.4. The covering of claim 1 , wherein the cover comprises fabric.5. The covering of claim 1 , wherein the cover is removable.6. The covering of claim 1 , wherein the second portion extends downward from first portion.7. The covering of claim 1 , wherein the cover contains an opening.8. The covering of claim 1 , wherein the core material contains an opening.9. The covering of claim 1 , wherein the cover contains an opening and the core material contains an opening.10. A covering comprising a first portion and a second portion which extends downward from first portion. This application claims priority to U.S. Provisional Application No. 61/547,173 filed Oct. 14, 2011, which is hereby incorporated by reference.The present invention relates to a decorative and protective covering for a window sill, a fireplace mantel or other ledge.The present invention generally relates to a covering for a window sill, a fireplace mantel or other ledge that provides decoration, protection and energy savings.The present invention relates to a covering for a window sill, fireplace mantel or ledge comprising a cover which spans a portion or the entire length of a window sill, fireplace mantel or ledge.The ...

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04-07-2013 дата публикации

POROUS MATERIAL AND METHOD FOR FABRICATING SAME

Номер: US20130171443A1
Принадлежит: PPD MEDITECH

A composite structure comprising a first porous portion comprising a plurality of interconnected pores and a second solid portion having a first surface, said first surface secured to said first portion wherein said first and second portions are fabricated from a polymer material. The material may be suitable for implant, illustratively vertebral or spinal implants, comprising a rigid biocompatible polymer such as PEEK comprising a plurality of interconnected pores. The polymer illustratively has a porosity of between 50% and 85% by volume and in a particular embodiment is able to withstand pressures of up to 20 MPa. The porous PEEK material may also have a minimum thickness in any dimension of one (1) inch. 1. A composite structure comprising:a first porous portion comprising a plurality of interconnected pores;a second solid portion having a first surface, said first surface secured to said first portion;wherein said first and second portions are fabricated from a polymer material.2. The structure of claim 1 , wherein said composite material is suitable for implantation and said first portion is fabricated from a first biocompatible polymer and said second portion is fabricated from a second biocompatible polymer.3. The structure of claim 2 , wherein said first biocompatible polymer is PEEK.4. The structure of claim 2 , wherein said second biocompatible polymer is PEEK Carbon Prepreg.5. The structure of claim 1 , wherein said composite material is suitable for implantation and said first portion and said second portion are both fabricated from a biocompatible polymer.6. The structure of claim 1 , wherein said second solid portion has a second surface and further comprising a second porous portion secured to said second surface.7. The structure of claim 1 , wherein said second solid portion is fabricated from a material the same as said first and second portions.8. The structure of claim 1 , wherein said first porous portion has a porosity of between 50% and 85% by ...

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18-07-2013 дата публикации

RESIN COMPOSITION FOR PAVEMENT, AND ASPHALT COMPOSITION FOR PAVEMENT AND PROCESS FOR PRODUCING THE SAME

Номер: US20130184389A1
Автор: Hakata Toshiyuki
Принадлежит: TODA KOGYO CORPORATION

The present invention relates to a resin composition for pavement which comprises at least an ethylene-vinyl acetate copolymer having a vinyl acetate content of 25 to 45% by weight, a melting temperature of 40 to 100° C. and a melt flow rate of not less than 400 g/10 min, a petroleum-based process oil having an aromatic ring-derived carbon content (CA) of 20 to 40%, and a teleblock polymer. The resin composition for pavement according to the present invention can be melted for a short period of time, and is excellent in wettability and adhesion to an aggregate, and can provide a paved surface having an excellent durability which is free from problems such as deformation in the summer season and occurrence of cracks in the winter season. 1. A resin composition for pavement comprising:an ethylene-vinyl acetate copolymer which has a vinyl acetate content of 25 to 45% by weight, a melting temperature of 40 to 100° C. and a melt flow rate of not less than 400 g/10 min,a petroleum-based process oil having an aromatic ring-derived carbon content (CA) of 20 to 40%, anda teleblock polymer.2. A resin composition for pavement according to claim 1 , wherein contents of the ethylene-vinyl acetate copolymer claim 1 , the petroleum-based process oil and the teleblock polymer are 2 to 30% by weight claim 1 , 20 to 80% by weight and 2 to 20% by weight claim 1 , respectively.3. A resin composition for pavement according to claim 1 , wherein the teleblock polymer is a styrene-butadiene-styrene block polymer (SBS) and/or a styrene-isobutylene-styrene block polymer (SIS).4. A resin composition for pavement according to claim 1 , further comprising an aromatic petroleum resin having a softening point of 80 to 110° C. and an acid value of not more than 0.5 mg KOH/g in an amount of less than 20%.5. A resin composition for pavement according to claim 1 , further comprising a polyolefin-based wax having an acid value of 1.0 to 70 mg KOH/g in an amount of 0 to 10%.6. A resin composition for ...

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18-07-2013 дата публикации

Coating of substrates with curable fluorinated copolymers

Номер: US20130184400A1
Принадлежит:

A process for coating flexible substrates applying a curable fluorinated copolymer A which is the reaction product of FC and 1. A curable fluorinated copolymer A2 which is the reaction product of FC andM1) at least trimellitic anhydride and optionally other polycarboxylic anhydrides and optionallyM2) at least a monofunctional isocyanate,wherein FC is a curable fluorinated copolymer on the basis ofFC1) at least one fluorinated olefin having 2 to 10 carbon atoms,FC2) at least one non-fluorinated olefin having OH-groups and optionally carboxyl groups andFC3) at least one non-fluorinated, hydroxyl group free olefin having optionally carboxyl groups.2. A curable fluorinated copolymer A2 according to claim 1 , wherein FC is a curable fluorinated copolymer on the basis ofFC1) tetrafluoroethene,FC2) 2-hydroxyethyl vinyl ether, 3-hydroxypropyl vinyl ether, 4-hydroxybutyl vinyl ether, 2-hydroxyethyl allyl ether, 3-hydroxypropyl allyl ether, 4-hydroxybutyl allyl ether or mixtures thereofandFC3) maleic acid, maleic anhydride, fumaric acid, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, vinylacetic acid, norbornene carboxylic acid, norbornene dicarboxylic acid, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl hexanoate, vinyl octanoate, vinyl decanoate, vinyl dodecanoate, vinyl tetradecanoate, vinyl hexadecanoate, vinyl octadecanoate, vinyl lactate, vinyl pivalate, vinyl benzoate, vinyl para-tert-butyl benzoate, vinyl versatate, ethyl vinyl ether, cyclohexyl vinyl ether, isobutene, 2-methyl-1-pentene, dimethyl maleate, diethyl maleate, dibutyl maleate, diethyl fumarate, dibutyl fumarate or mixtures thereof.3. A process for the manufacturing of the copolymer A2 according to comprising the steps1) reaction of a polymer solution comprising of solvent X and polymer FC, with trimellitic anhydride and optionally one or more polycarboxylic anhydrides, and optionally at least one monofunctional isocyanate, optionally in the presence of a solvent Y2) neutralization ...

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01-08-2013 дата публикации

AQUEOUS SEALANT SYSTEM, WOOD PRODUCT AND METHOD FOR SEALING WOOD-BASED SUBSTRATE

Номер: US20130196162A1
Принадлежит: Valspar Sourcing, Inc.

An aqueous sealant system, a wood product sealed by the aqueous sealant system, and a method for sealing a wood-based substrate. The aqueous sealant system includes: a) a film-forming resin composition including an aqueous latex of an active hydrogen-containing polymer, a filler, and optional additional additives; and b) a multi-isocyanate hardener, wherein the ratio by weight of the component a) to the component b) is 100:3 to 100:10. 2. The aqueous sealant system according to claim 1 , wherein component a) comprises claim 1 , based on the total weight of component a) claim 1 ,20 to 55% by weight of the aqueous latex of the active hydrogen-containing polymer;20 to 70% by weight of the filler; and0 to 25% by weight of an additional additive, wherein the additive comprises one or more of wetting and dispersing agents, defoamers, thickeners, and pigments.3. The aqueous sealant system according to claim 2 , wherein component a) comprises claim 2 , based on the total weight of the component a) claim 2 ,35 to 55% by weight of the aqueous latex of active hydrogen-containing polymer;40 to 65% by weight of the filler; and0.3 to 15% by weight of the additional additives.4. The aqueous sealant system according to claim 2 , wherein component a) comprises claim 2 , based on the total weight of component a) claim 2 ,20 to 50% by weight of the aqueous latex of the active hydrogen-containing polymer;40 to 65% by weight of the filler;0.3 to 0.5% by weight of the wetting and dispersing agent;0.3 to 0.6% by weight of the defoamer;0.5 to 1.5% by weight of the thickener; and0 to 15% by weight of the pigment.5. The aqueous sealant system according to claim 4 , further comprising claim 4 , based on the total weight of component a) claim 4 ,1 to 3% by weight of an antifreeze agent;0.1 to 0.3% by weight of a bactericide;0.1 to 0.3% by weight of a biocide; and0.1 to 0.3% by weight of pH adjuster.67-. (canceled)8. The aqueous sealant system according to claim 1 , wherein the active hydrogen- ...

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08-08-2013 дата публикации

SEALANT LAMINATED COMPOSITE, SEALED SEMICONDUCTOR DEVICES MOUNTING SUBSTRATE, SEALED SEMICONDUCTOR DEVICES FORMING WAFER, SEMICONDUCTOR APPARATUS, AND METHOD FOR MANUFACTURING SEMICONDUCTOR APPARATUS

Номер: US20130200534A1
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

Described herein is a sealant laminated composite for collectively sealing a semiconductor device's mounting surface of a substrate on which semiconductor devices are mounted or a semiconductor device's forming surface of a wafer on which semiconductor devices are formed. The composite can include a support wafer and an uncured resin layer constituted of an uncured thermosetting resin formed on one side of the support wafer. In certain aspects, the sealant laminated composite is very versatile, even when a large diameter or thin substrate or wafer is sealed. In certain aspects, this can prevent the substrate or wafer from warping and the semiconductor devices from peeling; can collectively seal a semiconductor device's mounting surface of a substrate on which semiconductor devices are mounted or a semiconductor device's forming surface of a wafer on which semiconductor devices are formed on a wafer level; and can provide a sealant laminated composite that is excellent in the heat resistance and humidity resistance after sealing. 1. A sealant laminated composite for collectively sealing a semiconductor devices mounting surface of a substrate on which semiconductor devices are mounted or a semiconductor devices forming surface of a wafer on which semiconductor devices are formed , comprising:a support wafer; andan uncured resin layer constituted of an uncured thermosetting resin formed on one side of the support wafer.2. The sealant laminated composite according to claim 1 , wherein difference between an expansion coefficient of the support wafer and that of the substrate on which the semiconductor devices are mounted or the wafer on which the semiconductor devices are formed is 3 ppm or less.3. The sealant laminated composite according to claim 1 , wherein a thickness of the uncured resin layer is 20 μm or more and 2000 μm or less.4. The sealant laminated composite according to claim 2 , wherein a thickness of the uncured resin layer is 20 μm or more and 2000 μm or ...

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22-08-2013 дата публикации

Hydrophobic self-etch dental adhesive compositions

Номер: US20130217800A1
Автор: Byoung I. Suh, LIANG Chen
Принадлежит: Bisco Inc

A hydrophobic self-etch dental adhesive composition including a hydrophobic, surfactant-type acidic monomer. The composition may further include hydrophilic and hydrophobic monomers, preferably in a ratio of less than 1:1, and may include a solvent that is an azeotrope.

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29-08-2013 дата публикации

INSERT FOR PIPE ASSEMBLY AND METHOD FOR FORMING PIPE ASSEMBLY

Номер: US20130220474A1
Принадлежит: Ticona LLC

An insert, a pipe assembly, and a method for forming a pipe assembly are disclosed. The pipe assembly includes a hollow body and an insert bonded to the hollow body. The insert spans a knit line defined in the hollow body. The insert is formed from a fiber reinforced polymer material. The fibers are generally anisotropic, and preferably unidirectional, and the insert is oriented such that the fibers extend at an angle to the knit line and thus span the knit line. Preferably, the fibers extend perpendicularly to the knit line. The use of an insert having such an orientation reinforces the hollow body, particularly at the knit line. Thus, the use of such an insert bonded to a hollow body according to the present disclosure produces a pipe assembly having increased pressure ratings. 1. A fiber reinforced polymer insert for a pipe assembly , comprising:an insert having a front side and an opposing back side, the front side and opposing back side defining a thickness therebetween,the insert formed from a polymer material having a plurality of fibers dispersed therein, the fibers having an anisotropic orientation,the insert configured for bonding in the pipe assembly such that the fibers of the insert span a knit line of the pipe assembly.2. The fiber reinforced polymer insert of claim 1 , wherein the polymer material is a thermoplastic.3. The fiber reinforced polymer insert of claim 1 , wherein the polymer material is a polyolefin.4. The fiber reinforced polymer insert of claim 1 , wherein the plurality of fibers are long fibers.5. The fiber reinforced polymer insert of claim 1 , wherein the plurality of fibers are generally unidirectional.6. The fiber reinforced polymer insert of claim 1 , further comprising a plurality of surface features included on the front side of the insert.7. The fiber reinforced polymer insert of claim 6 , wherein the surface features are ribs.8. The fiber reinforced polymer insert of claim 7 , wherein each of the plurality of ribs has a height ...

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26-09-2013 дата публикации

AQUEOUS BINDER SYSTEMS AND THEIR USE IN PRODUCING COATING COMPOSITIONS

Номер: US20130253101A1
Принадлежит: CELANESE EMULSIONS GMBH

A binder mixture is described comprising: an aqueous copolymer dispersion which has a glass transition temperature, T, of less than 10° C. and which is prepared by emulsion polymerization of a monomer mixture comprising: (i) at least 60% by weight, based on the total amount of monomers, of at least one vinyl ester; (ii) from 15 to 30% by weight, based on the total amount of monomers, of ethylene; (iii) from 0.05 to 5% by weight, based on the total amount of monomers, of an ethylenically unsaturated carboxylic acid having at least 4 carbon atoms; and (iv) from 0.05 to 5% by weight, based on the total amount of monomers, of an ethylenically unsaturated sulfonic acid or salt thereof. 1. An aqueous binder mixture comprising:{'sub': 'g', '(A) an aqueous copolymer dispersion which has a glass transition temperature, T, of less than 10° C. and which is prepared by emulsion polymerization of a monomer mixture comprising(i) at least 60% by weight, based on the total amount of monomers, of at least one vinyl ester;(ii) from 15 to 30% by weight, based on the total amount of monomers, of ethylene;(iii) from 0.05 to 5% by weight, based on the total amount of monomers, of an ethylenically unsaturated carboxylic acid having at least 4 carbon atoms; and(iv) from 0.05 to 5% by weight, based on the total amount of monomers, of an ethylenically unsaturated sulfonic acid or salt thereof.2. The binder mixture of claim 1 , wherein the at least one vinyl ester comprises vinyl acetate.3. The binder mixture of and comprising from 18 to 30% by weight claim 1 , based on the total amount of monomers claim 1 , of ethylene.4. The binder mixture of and comprising from 20 to 25% by weight claim 1 , based on the total amount of monomers claim 1 , of ethylene.5. The binder mixture of and comprising from 0.2 to 1.5% by weight claim 1 , based on the total amount of monomers claim 1 , of said ethylenically unsaturated carboxylic acid having at least 4 carbon atoms.6. The binder mixture of and ...

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03-10-2013 дата публикации

Paper coating slips comprising a combination of styrene-butadiene copolymer and/or styrene-acrylic ester copolymer and vinyl acetate-ethylene copolymer

Номер: US20130260162A1
Принадлежит: Wacker Chernie AG

The invention provides paper coating slips comprising, as a binder, an aqueous dispersion of a styrene-butadiene copolymer or of a styrene-acrylic ester copolymer, or a mixture of these aqueous dispersions, characterized in that an aqueous dispersion of a polyvinyl alcohol-stabilized vinyl acetate-ethylene copolymer is additionally present in each case. 1. A paper coating slip comprising as binder an aqueous dispersion of a styrene-butadiene copolymer or of a styrene-acrylic ester copolymer , or a mixture of these aqueous dispersions , wherein in each case additionally an aqueous dispersion of a vinyl acetate-ethylene copolymer stabilized with polyvinyl alcohol is included.2. The paper coating slip of claim 1 , wherein the aqueous dispersion or the vinyl acetate-ethylene copolymer is stabilized with a partially hydrolyzed polyvinyl alcohol.3. The paper coating slips of claim 1 , wherein the aqueous dispersion of the vinyl acetate-ethylene copolymer is stabilized with a partially hydrolyzed polyvinyl alcohol having a degree of hydrolysis of 80 to 95 mol % and a Höppler viscosity in 4% strength aqueous solution of 4 to 30 mPas (Höppler method at 20° C. DIN 53015).4. The paper coating slip of claim 1 , wherein the vinyl acetate-ethylene copolymer comprises one or more copolymers selected from the group consisting of copolymers of vinyl acetate with 1% to 40% by weight of ethylene claim 1 , copolymers of vinyl acetate with 1% to 40% by weight of ethylene and with 1% to 50% by weight of one or more further comonomers selected from the group consisting of vinyl esters having 3 to 12 C atoms in the carboxylic acid residue claim 1 , and copolymers of vinyl acetate with 1% to 40% by weight of ethylene and with 1% to 50% by weight of (meth)acrylic esters of unbranched or branched alcohols having 1 to 18 C atoms claim 1 , the figures in % by weight adding up to 100% by weight in each case.5. The paper coating slip of claim 1 , wherein the vinyl acetate-ethylene copolymer ...

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24-10-2013 дата публикации

METHOD OF FORMING A REINFORCED FOAM-FILLED COMPOSITE STRINGER

Номер: US20130280491A1
Принадлежит:

A method and apparatus for manufacturing a composite stringer. A composite material and foam are laid up onto a tool in the form of a stringer. The foam has a plurality of structural members within the foam. The plurality of structural members has a number of orientations to resist a number of loads. The composite material, the foam in the form of the stringer, and the plurality of structural members are cured to form the composite stringer. 124-. (canceled)25. An apparatus comprising:a composite material defining a channel;a foam disposed in the channel; anda plurality of structural members in the foam supporting the composite material.26. The apparatus of claim 25 , wherein the plurality of structural members contact the composite material.27. The apparatus of claim 25 , wherein the composite material is cured.28. The apparatus of further comprising a skin ply connected to the composite material.29. The apparatus of claim 25 , wherein the plurality of structural members comprise a structure selected from the group consisting of rods claim 25 , pins claim 25 , and tubes.30. The apparatus of claim 25 , wherein the plurality of structural members comprise a material selected from the group consisting of aluminum claim 25 , steel claim 25 , carbon claim 25 , titanium claim 25 , metal alloy claim 25 , and ceramic material.31. The apparatus of claim 25 , wherein the foam comprises a material selected from the group consisting of polyisocyanurate claim 25 , aromatic polyester claim 25 , polyimide styrene acrylo-nitrile claim 25 , polymethacrylimide claim 25 , polyetherimide claim 25 , polyphenylene claim 25 , polyetherether-ketone claim 25 , polyvinylidene fluoride claim 25 , polyisocyanurate claim 25 , and poly vinyl chloride32. The apparatus of claim 25 , wherein the foam comprises a cellular polymer foam.33. The apparatus of claim 25 , wherein a member in the plurality of structural members is one of hollow or solid.34. The apparatus of claim 25 , wherein a member in ...

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07-11-2013 дата публикации

BINDER FOR MAT OF FIBERS, ESPECIALLY MINERAL FIBERS, AND PRODUCTS OBTAINED

Номер: US20130295361A1
Принадлежит: Saint-Gobain Adfors

The present invention concerns a binder for a mat of fibers, especially mineral fibers, which comprises: 1. A binder comprising:a monosaccharide, a polysaccharide, or a mixture thereof;a polycarboxylic organic acid having a molar mass of 1000 or less; anda vinyl acetate homopolymer or copolymer.2. The binder of claim 1 , wherein the monosaccharide is present and is a monosaccharide comprising 3 to 8 carbon atoms.3. The binder of claim 2 , wherein the monosaccharide is present and is a hexose.4. The binder of claim 1 , wherein the polysaccharide is present and wherein more than 50% of the polysaccharide comprises glucose units.5. The binder of claim 4 , wherein the polysaccharide comprises a dextrin and a starch.6. The binder of claim 1 , comprising a dextrin claim 1 , molasses claim 1 , or a mixture comprising 20% to 80% by weight of a starch.7. The binder of claim 6 , wherein the dextrin has a dextrose equivalent in the range 5 to 100.8. The binder of claim 1 , wherein the polycarboxylic organic acid comprises at least two carboxylic functions.9. The binder of claim 8 , wherein the polycarboxylic organic acid has a molar mass of 750 or less.10. The binder of claim 1 , wherein the polycarboxylic organic acid is malonic acid claim 1 , tartaric acid claim 1 , or citric acid.11. The binder of claim 1 , wherein the vinyl acetate copolymer is a copolymer of vinyl acetate and at least one hydrophobic monomer selected from the group consisting of ethylene claim 1 , propylene claim 1 , butylene claim 1 , styrene claim 1 , and vinyl chloride.12. The binder of claim 1 , wherein the monosaccharide claim 1 , the polysaccharide claim 1 , or the mixture thereof is 10% to 90% of the weight of the mixture comprising the monosaccharide claim 1 , the polysaccharide claim 1 , or the mixture thereof and the polycarboxylic organic acid.13. The binder of claim 1 , wherein the vinyl acetate polymer is present in an amount of 1 to 15 parts per 100 parts by weight of the mixture constituted ...

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09-01-2014 дата публикации

SOUND ABSORBING AND INSULATION COMPOSITION MATERIAL COMPOSITION

Номер: US20140008145A1
Автор: Lin Mingyang, Pan Kuoliang
Принадлежит: SAN SHANG TECHNOLOGY CO., LTD.

The present invention discloses a sound absorbing and insulating composite material composition formed by attaching at least one non-woven fiber layer and at least one polyethylene film closely with each other, and the non-woven fiber layer is a stacked fiber layer made of a renewable green fiber material and manufactured by the non-woven fabric manufacturing method, and the non-woven fiber layer has a thickness equal to or greater than 1 mm, and the polyethylene film has a thickness from 0.009 mm to 0.1 mm. 1. A sound absorbing and insulating composite material composition , formed by attaching at least one non-woven fiber layer and at least one polyethylene film closely , and the non-woven fiber layer being a stacked fiber layer manufactured by a non-woven fabric manufacturing method and having a thickness equal to or greater than 1 mm , and the polyethylene film having a thickness from 0.009 mm to 0.1 mm.2. The sound absorbing and insulating composite material composition of claim 1 , formed by attaching a non-woven fiber layer and a polyethylene film closely claim 1 , wherein the non-woven fiber layer is a stacked fiber layer manufactured by a non-woven fabric manufacturing method and has a thickness equal to or greater than 1 mm claim 1 , and the polyethylene film has a thickness from 0.009 mm to 0.1 mm.3. The sound absorbing and insulating composite material composition of claim 2 , further comprising a second polyethylene film attached closely onto a surface of the non-woven fiber layer claim 2 , and the second polyethylene film having a thickness from 0.009 mm to 0.1 mm.4. The sound absorbing and insulating composite material composition of claim 3 , further comprising a second non-woven fiber layer attached flatly and closely onto a surface of the second polyethylene film claim 3 , and the second non-woven fiber layer being a stacked fiber layer manufactured by a non-woven fabric manufacturing method and having a thickness equal to or greater than 1 mm.5. ...

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16-01-2014 дата публикации

AQUEOUS LATEX COATING COMPOSITIONS

Номер: US20140018473A1
Принадлежит: Celanese International Corporation

Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions. These paint products provide paint coatings that exhibit desirable dry and wet adhesion characteristics and desirable resistance to blocking. 1. An aqueous latex-based coating composition , said composition comprising a blend of an ethylene-vinyl acetate copolymer and an acrylic copolymer wherein:(a) the ethylene-vinyl acetate copolymer comprises the emulsion polymerization product of from about 5 wt % to about 20 wt % of ethylene, from about 70 wt % to about 95 wt % of vinyl acetate, and from about 0 wt % to about 10 wt % of auxiliary co-monomers; said ethylene-vinyl acetate copolymer being present in the blend in an amount from about 50 wt % to about 95 wt %, based on total weight of ethylene-vinyl acetate and acrylic emulsion copolymers; and{'sub': 1', '12', '1', '12, '(b) the acrylic copolymer comprises the emulsion polymerization product of from about 70 wt % to about 99 wt % of one or more C-Cesters of (meth)acrylic acid or one or more of said C-Cesters of (meth)acrylic acid in combination with one or more vinyl aromatic co-monomers, from about 0.1 wt % to about 10 wt % of one or ...

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16-01-2014 дата публикации

SOLVENT-BASED PAINT COMPOSITION AND FLUORINE-CONTAINING COPOLYMER

Номер: US20140018492A1
Принадлежит: DAIKIN INDUSTRIES, LTD.

Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH═CH—O—(CH)—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): RRC═CR—(CH)—COOH wherein R, R, and Rare the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more. 1. A solvent-based paint composition , comprising:a fluorocopolymer (I), andan organic solvent (II),the fluorocopolymer (I) including:a perhaloolefin structural unit (a) that contains two carbon atoms,a vinyl acetate structural unit (b), {'br': None, 'sub': 2', '2', 'n, 'CH═CH—O—(CH)—OH'}, 'a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1)wherein n is an integer of 2 or more, and {'br': None, 'sup': 1', '2', '3, 'sub': 2', 'm, 'RRC═CR—(CH)—COOH'}, 'a carboxyl group-containing monomer structural unit (d) represented by the following formula (2){'sup': 1', '2', '3, 'wherein R, R, and Rare the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.'}2. The solvent-based paint composition according to claim 1 ,wherein, in the formula (1), n is 2 or 4.3. The solvent-based paint composition according to claim 1 ,wherein, in the formula (2), m is 2 to 20.4. The solvent-based paint composition according to claims 1 ,wherein the fluorocopolymer includes 40 mol % or more and 50 mol % or less of the structural unit (a), 20 mol % ...

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23-01-2014 дата публикации

CARPET BACKING COMPOSITIONS PREPARED FROM RECYCLED PAINT

Номер: US20140024740A1
Принадлежит: ARROWSTAR, LLC

Described herein are carpet backing compositions prepared with paint. These compositions have (a) one or more first polymers, (b) one or more second polymers derived from a latex paint, (c) a filler, (d) a froth aid, and (e) a thickener. The compositions described herein solve several technical problems which have heretofore been inadequately addressed. The compositions described herein accept the required filler loading, can be applied easily without interference by paint components, have high solids contents, and dry or cure quickly. Methods for making the compositions and articles comprising the compositions are also described herein. 1. A composition comprising:(a) one or more first polymers comprising polyvinyl acetate, polyvinyl chloride, a polyacrylate, an acrylic copolymer, a polyethylene-vinyl acetate copolymer, a styrene-butadiene copolymers (SBR), a polyurethane dispersions, a carboxylated styrene-butadiene copolymer, an ethylene vinyl acetate copolymer, or any combination thereof:(b) one or more second polymers derived from a latex paint;(c) a filler;(d) a froth aid; and(e) a thickener,wherein (i) the ratio of filler/sum of the first and second polymers in dry parts is from 1:1 to 8:1;(ii) the amount of froth aid is from 1% to 10% of the sum of the first and second polymer in dry parts;(iii) the composition has a solids content of from at least 50% to 85%; and(iv) the composition has a viscosity of from at least 4,000 cps to 25,000 cps.2. The composition of claim 1 , wherein the carboxylated styrene-butadiene copolymer comprises a copolymerizable unsaturated acid.3. The composition of claim 2 , wherein the copolymerizable unsaturated acid comprises acrylic acid claim 2 , methacrylic acid claim 2 , maleic acid claim 2 , maleic anhydride claim 2 , fumaric acid claim 2 , itaconic acid claim 2 , vinyl benzoic acid claim 2 , α-chloro acrylic acid claim 2 , crotonic acid claim 2 , and mixtures thereof.4. The composition of claim 2 , wherein the carboxylated ...

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20-02-2014 дата публикации

RESIN COMPOSITION, TWO-PACK TYPE ADHESIVE FOR LAMINATES, MULTILAYER FILM, AND BACK SHEET FOR SOLAR CELLS

Номер: US20140050919A1
Принадлежит: DIC CORPORATION

Provided are a resin composition with high adhesion to substrates under hot and humid conditions, a two-part laminate adhesive containing the resin composition, and a laminated film and backsheet for solar cells including a layer of the adhesive. The resin composition contains, as essential components, a polyester polyurethane polyol (A) having a branched structure in a molecule thereof and having a weight average molecular weight (Mw) of 25,000 to 200,000 and a molecular weight distribution (Mw/Mn) of 2.5 to 25; a hydroxyl-containing epoxy resin (B) having a number average molecular weight (Mn) of 300 to 5,000; a hydroxyl-containing polycarbonate resin (C) having a number average molecular weight (Mn) of 300 to 3,000; and a polyisocyanate (D). 1. A resin composition containing , as essential components , a polyester polyurethane polyol (A) prepared by reacting a polybasic acid (E) , a polyalcohol (F) , and a polyisocyanate (G) as essential components , the polybasic acid (E) being a combination of an aliphatic polybasic acid and an aromatic polybasic acid , the polyisocyanate (G) being a nurate-type polyisocyanate compound having a functionality of 3 or more , the polyester polyurethane polyol (A) having a hydroxyl value of 5 to 30 mg KOH/g , having a branched structure in a molecule thereof , and having a weight average molecular weight (Mw) of 25 ,000 to 200 ,000 and a molecular weight distribution (Mw/Mn) of 2.5 or more; a hydroxyl-containing epoxy resin (B) having a number average molecular weight (Mn) of 300 to 5 ,000; a hydroxyl-containing polycarbonate resin (C) having a number average molecular weight (Mn) of 300 to 3 ,000; and a polyisocyanate (D).2. (canceled)3. (canceled)4. The resin composition according to claim 1 , wherein the polyester polyurethane polyol (A) is a polyester polyurethane polyol prepared by reacting claim 1 , as an essential component claim 1 , a polyisocyanate (G) containing a diisocyanate compound (G1) and a nurate-type ...

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27-03-2014 дата публикации

PROCESS FOR PRODUCING FOAMED WALLPAPERS

Номер: US20140087088A1
Принадлежит:

The invention relates to a method for manufacturing a foamed coating on a web-shaped substrate, the substrate being coated entirely or partly with a coating agent, the applied coating being dried at a temperature above 70° C., and the coating agent being applied as a foam, an aqueous coating agent containing polymers selected from poly(meth)acrylates, maleinate polymers, or ethylene vinyl acetate polymers being used, and the coating agent being foamed by means of an introduced inert gas. 1. A method for manufacturing a foamed coating on a web-shaped substrate , the substrate being coated entirely or partly with a coating agent , the applied coating agent being dried at a temperature above 70° C. , wherein the coating agent is applied as a foam , the coating agent being aqueous and containing polymers selected from poly(meth)acrylates , maleinate polymers , or ethylene-vinyl acetate polymers being used , and the coating agent being foamed by means of an introduced inert gas.2. The method according to claim 1 , wherein the foam is formed by the introduction of air claim 1 , nitrogen claim 1 , or COand mixtures thereof claim 1 , as a gas claim 1 , into the coating agent.3. The method according to claim 1 , wherein the coating agent achieves claim 1 , by being foamed claim 1 , a density of less than 0.80 g/cm.4. The method according to claim 1 , wherein the coating has claim 1 , after drying claim 1 , a layer thickness from 0.1 to 3 mm.5. The method according to claim 1 , wherein drying is carried out by means of an IR radiator and/or with heated air claim 1 , at a temperature above 80° C. for a time period of less than one minute.6. The method according to claim 1 , wherein after drying the coating is imprinted and/or embossed.7. The method according to claim 1 , wherein the substrate is constructed from hydrophilic polymers selected from polyester fibers and/or natural fibers.8. An aqueous coating agent for use in a method according to claim 1 , containing at least ...

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04-01-2018 дата публикации

PIGMENT COMPLEXES FOR WATER BORNE COATING COMPOSITIONS

Номер: US20180002557A1
Принадлежит: THE SHERWIN-WILLIAMS COMPANY

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of titanium dioxide are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone. 1. A heat-age stable latex paint composition comprisingan acrylic, styrene acrylic or vinyl acrylic polymer or copolymer thereof including as polymerizable units at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer;a titanium dioxide particle associated with the acrylic, styrene acrylic or vinyl acrylic polymer or copolymer forming a pigment-polymer complex;water; andwherein the latex paint composition exhibits a contrast ratio of about 0.9 to about 0.99 and a y-reflectance of about 90 to about 100 when the heat-age stable latex paint composition has a particle loading factor based on a weight ratio of titanium dioxide particle to the acrylic, styrene acrylic or vinyl acrylic polymer or copolymer of greater than 1:2.2. The heat-age stable latex paint composition of claim 1 , further comprising a KU viscosity increase after 4 weeks of aging at about 140° F. of no more than about 10 units.3. The heat-age stable latex paint composition of claim 1 , wherein the heat-age stable latex paint composition includes about 30 to about 50 weight percent of the acrylic claim 1 , styrene acrylic or vinyl acrylic polymer or copolymer and about 10 to about 25 weight percent of the titanium dioxide particle.4. The heat-age stable latex paint composition of claim 1 , wherein the polymer or copolymer further includes ureido monomers claim 1 , amino monomers ...

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04-01-2018 дата публикации

WATER BORNE COATING COMPOSITONS AND POLYMERS THEREFOR

Номер: US20180002558A1
Принадлежит: THE SHERWIN-WILLIAMS COMPANY

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone. 1. A heat-age stable latex paint composition comprising:a polymer including as polymerized units vinyl acetate; a phosphate surfactant selected from a propoxylated or ethoxylated phosphate acrylate surfactant, a propoxylated or ethoxylated phosphate methacrylate surfactant, or mixtures thereof; and at least one vinyl ester with a C4 to C30 linear or branched carbon chain;titanium dioxide;water; andwherein the heat-age stable latex paint composition has a KU viscosity increase as measured by ASTM D562 of no more than about 10 units after 4 weeks of aging at about 140° F.2. The heat-age stable latex paint composition of claim 1 , wherein the heat-age stable latex paint composition claim 1 , when dried as a film claim 1 , exhibits a contrast ratio as tested by ASTM D2805-11 of about 0.9 to about 0.99 when the heat-age stable latex paint composition has a particle loading factor based on a weight ratio of the titanium dioxide to the polymer of greater than 1:2.3. The heat-age stable latex paint composition of claim 1 , wherein the heat-age stable latex paint composition claim 1 , when dried as a film claim 1 , has an increased contrast ratio relative to a dried film of a comparative latex paint composition that does not include the polymer but instead includes a vinyl acrylic latex polymer without the phosphate surfactant and includes about 13 to about 20 weight percent more titanium dioxide.4. The heat ...

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14-01-2016 дата публикации

Composite Filler

Номер: US20160009045A1
Принадлежит:

A method and apparatus is presented. The composite filler comprises a number of layers of composite material and a core comprising a material which is non-bondable with the composite material. 1. A composite filler comprising:a number of layers of composite material; anda core comprising a material which is non-bondable with the composite material.2. The composite filler of claim 1 , wherein the core has a substantially circular cross-section.3. The composite filler of claim 1 , wherein the number of layers of composite material comprises:a number of wraps surrounding the core to form a wrapped core;a number of buildups adjacent to the wrapped core;a number of charges adjacent to the number of buildups; anda base, wherein the wrapped core is adjacent to the base.4. The composite filler of claim 3 , wherein the core comprises:a polymer which is non-bondable with the number of wraps.5. The composite filler of claim 3 , wherein the core has a substantially circular cross-section.6. The composite filler of claim 3 , wherein the number of buildups comprises:a unidirectional composite material.7. The composite filler of claim 3 , wherein the base comprises:a composite laminate stack.8. The composite filler of claim 3 , wherein the number of charges comprises a number of stacks of composite material.9. The composite filler of claim 3 , wherein the number of wraps comprises:a −45 degree wrap of composite fabric and a +45 degree wrap of composite fabric.10. The composite filler of further comprising:a buildup positioned over at least a portion of the number of charges.11. The composite filler of claim 1 , wherein the number of layers of composite material comprises:a number of wraps surrounding the core to form a wrapped core, the number of wraps comprising a number of layers of composite fabric;a number of buildups adjacent to the wrapped core, the number of buildups comprising unidirectional composite material in which fibers of the unidirectional composite material are ...

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12-01-2017 дата публикации

Surfactant Compositions and Methods of Forming and Using Same

Номер: US20170009025A1
Принадлежит:

Disclosed are surfactant compositions comprising: 120.-. (canceled)22. The method of wherein at least 3 of said Rin each of said x groups is H.23. The method of wherein x is 7.24. The method of wherein the at least one compound in accordance with Formula VII has a weight average molecular weight (Mw) of from about 3000 to about 650025. The method of wherein said at least one compound in accordance with Formula (VII) is present in the surfactant composition in an amount of from about 10% to about 30% by weight based on the total of the (a) components and (b) component in the surfactant composition.26. The method of claim 21 , wherein the surfactant composition has a solidification point below 15° C.27. The method of claim 21 , wherein the surfactant composition decreases the amount of coagulum formed during an emulsion polymerization.28. The method of claim 21 , wherein the surfactant composition stabilizes a latex after polymerization.30. The method according to wherein x is from about 2 to about 2.5.31. A surfactant composition prepared according to the method of .32. The surfactant composition of wherein compound (VII) is present in an amount of about 1% to about 30% claim 31 , by weight claim 31 , of the surfactant concentrate. The present application is related to and claims the priority benefit of pending U.S. patent application Ser. No. 11/869,185, filed on Oct. 9, 2007, which in turn claims the priority benefit of U.S. Provisional Application No. 60/853,344, filed on Oct. 20, 2006, and from U.S. Provisional Application No. 60/856,638, filed on Nov. 3, 2006, each of which is incorporated herein by reference in its entirety.The invention relates generally to surfactants, and more particularly to surfactants and methods for forming and using the surfactants. In one particular aspect, the invention is in the field involving emulsion polymerization reactions and polymer dispersions, and for stabilizing emulsion polymers, polymer dispersions, and polymer coatings. ...

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12-01-2017 дата публикации

CROSSLINKABLE POLYMERIC COMPOSITIONS WITH N,N,N',N',N",N"-HEXAALLYL-1,3,5-TRIAZINE-2,4,6-TRIAMINE CROSSLINKING COAGENT, METHODS FOR MAKING THE SAME, AND ARTICLES MADE THEREFROM

Номер: US20170009060A1
Принадлежит:

Crosslinkable polymeric compositions comprising a thermoplastic, non-elastomer ethylene-based polymer, an organic peroxide, and a crosslinking coagent comprising N,N,N′,N′,N″,N″-hexaallyl-1,3,5-triazine-2,4,6-triamine. Such crosslinkable polymeric compositions and their crosslinked forms can be employed as polymeric layers in wire and cable applications, such as insulation in power cables. 1. A crosslinkable polymeric composition , comprising:(a) a thermoplastic, non-elastomer ethylene-based polymer;(b) an organic peroxide; and(c) a crosslinking coagent comprising N,N,N′,N′,N″,N″-hexaallyl-1,3,5-triazine-2,4,6-triamine2. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer is non-polar.3. The crosslinkable polymeric composition of claim 2 , wherein said ethylene-based polymer has no fluoromonomers incorporated therein.4. The crosslinkable polymeric composition of claim 1 , wherein said N claim 1 ,N claim 1 ,N′ claim 1 ,N′ claim 1 ,N″ claim 1 ,N″-hexaallyl-1 claim 1 ,3 claim 1 ,5-triazine-2 claim 1 ,4 claim 1 ,6-triamine and said organic peroxide are present in a coagent-to-peroxide weight ratio of greater than 1:1.5. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer comprises a high-pressure low-density polyethylene; wherein said organic peroxide comprises dicumyl peroxide; wherein said crosslinkable polymeric composition further comprises one or more antioxidants.6. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer is present in an amount ranging from 50 to 99 weight percent claim 1 , based on the entire crosslinkable polymeric composition weight; wherein said organic peroxide is present in an amount of less than 1.2 weight percent claim 1 , based on the entire crosslinkable polymeric composition weight; wherein said crosslinking coagent is present in an amount ranging from 0.01 to 15 weight percent claim 1 , based on the entire crosslinkable polymeric ...

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12-01-2017 дата публикации

Coating compositions for improved block resistance

Номер: US20170009095A1
Принадлежит: Arkema Inc

The aqueous, substantially volatile organic compound (VOC)-free coating compositions of the invention include an acrylic latex and a vinyl acetate-ethylene latex including from about 10 to about 90 weight percent of a vinyl acetate-ethylene polymer, based on total weight of acrylic polymer and vinyl acetate-ethylene polymer, having a T g from about −20 to about 20 degrees Celsius; and from about 10 to about 90 weight percent of an acrylic polymer, based on the total weight of acrylic polymer and vinyl acetate-ethylene polymer, the acrylic polymer comprising, in polymerized form, at least one ethylenically unsaturated (meth)acrylic monomer and from about 0.01 to about 10 weight percent, based on total weight of the acrylic polymer, of an acetoacetate moiety containing monomer, where the acrylic polymer has a T g of from about −20 to about 20 degrees Celsius.

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10-01-2019 дата публикации

ELECTRICALLY ACTIVE HYDROPHILIC BIO-POLYMERS

Номер: US20190008999A1
Автор: HIGHGATE DONALD JAMES
Принадлежит:

A process of forming a cross-linked electronically active hydrophilic co-polymer comprising the steps of: providing a co-monomer solution comprising at least one hydrophobic monomer, at least one hydrophilic monomer, water, at least one amino acid and at least one cross-linker; and polymerising the co-monomer solution. 1. A process of forming a cross-linked electronically active hydrophilic co-polymer comprising the steps of:providing a co-monomer solution comprising at least one hydrophobic monomer, at least one hydrophilic monomer, water, at least one amino acid and at least one cross-linker; andpolymerising the co-monomer solution.2. The process according to claim 1 , wherein the at least one amino acid is selected from phenylalanine claim 1 , tryptophan claim 1 , histidine claim 1 , ethylenediaminetetraacetic acid (EDTA) and tyrosine claim 1 , or a combination thereof.3. The process according to claim 2 , wherein the at least one amino acid is selected from phenylalanine and tryptophan claim 2 , or a combination thereof.4. The process according to claim 1 , wherein the at least one hydrophilic monomer is selected from methacrylic acid claim 1 , 2-hydroxyethyl methacrylate claim 1 , ethyl acrylate claim 1 , vinyl pyrrolidone claim 1 , propenoic acid methyl ester claim 1 , monomethacryloyloxyethyl phthalate claim 1 , ammonium sulphatoethyl methacrylate claim 1 , poly vinyl alcohol or a combination thereof.5. The process according to claim 4 , wherein the at least one hydrophilic monomer is selected from vinyl pyrrolidone and hydroxyethyl methacrylate claim 4 , or a combination thereof.6. The process according to claim 1 , wherein the at least one hydrophobic monomer is selected from methyl methacrylate claim 1 , allyl methacrylate claim 1 , acrylonitrile claim 1 , methacryloxypropyltris(trimethylsiloxy)silane claim 1 , 2 claim 1 ,2 claim 1 ,2-trifluoroethyl methacrylate claim 1 , or a combination thereof.7. The process according to claim 6 , wherein the at least ...

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08-01-2015 дата публикации

METHOD FOR MANUFACTURING ELECTROPHORESIS GEL AND APPARATUS FOR MANUFACTURING ELECTROPHORESIS GEL

Номер: US20150010867A1
Принадлежит: SHARP KABUSHIKI KAISHA

An electrophoresis gel, in which a good pH gradient or concentration gradient of a gel-forming monomer is formed, is produced. In addition, the production efficiency of an electrophoresis reaction tool is improved and the production processes are simplified. At least one of a first process to add a gel-forming monomer to a first solution containing an initiator to initiate polymerization of the gel-forming monomer by external energy in such a way that a pH gradient or concentration gradient of the gel-forming monomer is formed and a second process to initiate the polymerization of the above-described gel-forming monomer in the first solution, to which the above-described gel-forming monomer has been added, by using the above-described external energy is included. 1. A method for manufacturing an electrophoresis gel , characterized by including at least one of:adding a gel-forming monomer to a first solution containing an initiator to initiate polymerization of the gel-forming monomer by external energy in such a way that a pH gradient or concentration gradient of the gel-forming monomer is formed, as a first process; andinitiating the polymerization of the gel-forming monomer in the first solution, to which the gel-forming monomer has been added, by using the external energy, as a second process.2. The method for manufacturing an electrophoresis gel claim 1 , according to claim 1 , characterized in that the first process is performed on a base material to support an electrophoresis gel.3. The method for manufacturing an electrophoresis gel claim 1 , according to claim 1 , characterized in that the gel-forming monomer is added by using an ink-jet device in the first process.4. The method for manufacturing an electrophoresis gel claim 1 , according to claim 1 , characterized in that the external energy is light or heat.5. The method for manufacturing an electrophoresis gel claim 2 , according to claim 2 , characterized by further including claim 2 , before the first ...

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10-01-2019 дата публикации

PATTERNING MATERIAL, PATTERNING METHOD, AND PATTERNING APPARATUS

Номер: US20190009457A1
Автор: WATANABE Koji
Принадлежит:

Provided is a patterning material for three-dimensional stereolithography, with which it is possible to improve the curing speed and suppress a shrinkage of the three-dimensionally shaped article. The patterning material for three-dimensional stereolithography contains a diallyl phthalate prepolymer, a photocurable monomer and a photopolymerization initiator, and is liquid at room temperature. The patterning material is suitable for use in patterning performed by surface exposure. The proportion of the diallyl phthalate prepolymer is, for example, 5 to 40 mass % in the total amount of the diallyl phthalate prepolymer and the photocurable monomer. 1. A patterning material for three-dimensional stereolithography comprising:a diallyl phthalate prepolymer;a photocurable monomer; anda photopolymerization initiator,wherein the patterning material is liquid at room temperature.2. The patterning material in accordance with claim 1 ,wherein the patterning material is patterned by using a surface exposure technique.3. The patterning material in accordance with claim 1 ,wherein a proportion of the diallyl phthalate prepolymer in a total amount of the diallyl phthalate prepolymer and the photocurable monomer is 5 to 40 mass %.4. The patterning material in accordance with claim 1 , further comprising a thiol compound.5. The patterning material in accordance with claim 1 ,wherein the photopolymerization initiator is a radical polymerization initiator.6. The patterning material in accordance with claim 1 ,wherein the photocurable monomer contains a radically polymerizable monomer.7. The patterning material in accordance with claim 1 ,wherein the patterning material has a viscosity at 25° C. of 100 mPa to 15,000 mPa.8. The patterning material in accordance with claim 1 ,wherein an amount of the photopolymerization initiator is 1 to 10 parts by mass relative to 100 parts by mass of a total amount of the diallyl phthalate prepolymer and the photocurable monomer.9. A patterning method ...

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11-01-2018 дата публикации

AEROGEL-CONTAINING COMPOSITION AND INSULATION BLANKET PREPARED USING THE SAME

Номер: US20180009969A1
Принадлежит:

The present disclosure provides an aerogel-containing composition including an aerogel, a water-soluble binder, a foaming agent, and a mixture of water and a polar organic solvent as a solvent, and an insulation blanket prepared using the same. In the aerogel-containing composition, the aerogel is uniformly dispersed in the composition, and when preparing a blanket, an insulation blanket having low thermal conductivity and flexibility of low density is prepared without concern of shrinkage of the substrate for a blanket and detachment of the aerogel during a drying process. 1. An aerogel-containing composition comprising:an aerogel;a water-soluble binder;a foaming agent; anda solvent,wherein the solvent includes water and a polar organic solvent.2. The aerogel-containing composition of claim 1 , wherein the aerogel has porosity of 90% by volume or greater claim 1 , and tap density of 0.04 g/cmto 0.2 g/cm.3. The aerogel-containing composition of claim 1 , wherein the aerogel has a specific surface area of 700 m/g or greater claim 1 , and an average particle diameter of 5 μm to 80 μm.4. The aerogel-containing composition of claim 1 , wherein the aerogel has thermal conductivity of 0.02 W/mK or less.5. The aerogel-containing composition of claim 1 , wherein the aerogel includes a silica aerogel.6. The aerogel-containing composition of claim 1 , wherein the water-soluble binder includes any one or a mixture of two or more selected from the group consisting of polyvinyl acetate claim 1 , polyacrylic acid claim 1 , polyacrylic ester claim 1 , polyethylene vinyl acetate claim 1 , styrene acrylic ester resins claim 1 , styrene butadiene resins claim 1 , polyvinyl alcohol claim 1 , polyurethane claim 1 , cellulose-based resins claim 1 , starch or copolymers thereof.7. The aerogel-containing composition of claim 1 , wherein the foaming agent includes any one or a mixture of two or more selected from the group consisting of saturated hydrocarbon-based compounds having 1 to 8 ...

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10-01-2019 дата публикации

Materials, Treatment Compositions, & Material Laminates, with Carbon Nanotubes

Номер: US20190010350A9
Автор: Brogan Paul H.
Принадлежит: C-Bond Systems, LLC

Improved materials and compositions for improving materials to enhance their properties; the compositions, in certain aspects, strengthening materials, enhancing bonding between materials, and/or improving properties such as strength, impact resistance, sustainability, protection level, and structural integrity; the material in certain aspects being glass; the compositions including alcohol, glycerol, a silane, acetate adhesive, a surfactant, and carbon nanotubes; and, optionally in certain aspects, no nanotubes and/or no surfactants but with a vinyl acetate monomer. This abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure and is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims, 37 C.F.R. 1.72(b). 1. A composition for treating material , the composition comprisinga silane,an alcohol,a glycerol,a surfactant,an acetate adhesive, andcarbon nanotubes dispersed in the composition.2. The composition of wherein the nanotubes are one of single-walled nanotubes and multi-walled nanotubes.3. The composition of wherein the acetate adhesive is one of vinyl acetate adhesive claim 1 , polyvinyl acetate adhesive claim 1 , and vinyl acetate ethylene emulsion.4. The composition of wherein the material strengthened is at least one layer or multiple layers of glass claim 1 , LEXAN (trademark) material claim 1 , polycarbonate material claim 1 , polyester film or films claim 1 , and/or acrylic material.5. The composition of further comprising an essential oil claim 1 , essential oils claim 1 , and/or an essential oil blend or blends.6. The composition of wherein the essential oil claim 6 , etc. is present in the range of 40 to 250 ml of gallon of composition.7. The composition of wherein the carbon nanotubes are present as 0.1 to 90 weight percent of the composition; 4 to 15 weight percent of the ...

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19-01-2017 дата публикации

Water Repellent Spray Applied Fire Resistive Materials

Номер: US20170015844A1
Автор: Li Qinghua
Принадлежит: United States Mineral Products Company

The present disclosure relates to water repellent coating compositions, kits and methods of applying the same, for use as fireproofing materials. The water repellent spray applied fire resistant material contains an latex polymer(s), such as a vinyl acetate/ethylene copolymer, a silicone, such as methoxy-functional polysiloxane, or both to reduce or eliminate the effect of water damage to the SFRM and underlying substrate. 1. A fireproofing composition comprising:(i) a binder; and(ii) at least one latex polymer2. The fireproofing composition of wherein the binder is selected from the group consisting of portland cement claim 1 , pozzolanas claim 1 , pozzolanic cement claim 1 , quicklime claim 1 , plaster and calcium aluminate cement.3. The fireproofing composition of wherein the latex polymer is selected from the group consisting of a polyvinyl acetate claim 1 , a vinyl acetate copolymer claim 1 , a polyacrylate claim 1 , a polyacrylate copolymer claim 1 , a polyvinyl acrylate claim 1 , a vinyl acrylate copolymer claim 1 , a polyethylene claim 1 , a polyethylene copolymer claim 1 , a polystyrene claim 1 , a polystyrene copolymer claim 1 , a polyvinyl chloride claim 1 , a polyvinyl chloride copolymer claim 1 , a polyvinyl ester claim 1 , a polyvinyl ester copolymer claim 1 , a poly(ethylene-vinyl acetate) (PEVA) claim 1 , a PEVA copolymer claim 1 , a styrene butadiene rubbers (SBR) claim 1 , a styrene/acrylate copolymer claim 1 , and combinations thereof.4. The fireproofing composition of comprising about 0.1 wt % and about 20 wt % of latex polymer in the composition.5. The fireproofing composition of wherein the composition has a density of less than about 90 pounds per cubic foot.6. The fireproofing composition of further comprising at least one silicone.7. The fireproofing composition of wherein the silicone is selected from the group consisting of silicone resins claim 6 , siloxanes and silanes.8. The fireproofing composition of comprising about 0.1 wt % and ...

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15-01-2015 дата публикации

ORGANOCATALYZED PHOTOREDOX MEDIATED POLYMERIZATION USING VISIBLE LIGHT

Номер: US20150018446A1
Автор: MIYAKE Garret M.
Принадлежит:

The present invention is directed to method of forming a polymer comprising exposing a mixture comprising an organic pre-polymer, an organic photoredox catalyst, and an organic initiator to a source of visible or near-infrared light under conditions and for a time sufficient to polymerize the organic pre-polymer, and polymers and articles derived therefrom. 1. A method of forming a polymer comprising exposing a mixture comprising an organic pre-polymer , an organic photoredox catalyst , and an organic initiator to a source of visible light under conditions and for a time sufficient to polymerize the organic pre-polymer.2. The method claim 1 , wherein the mixture is substantially free of photoredox catalysts comprising metals or metalloids.3. The method of claim 1 , wherein the organic pre-polymer is a monomer or oligomer having polymerizable functional groups.4. The method of claim 1 , wherein the organic pre-polymer comprises an alpha olefin claim 1 , diolefin claim 1 , internal olefin claim 1 , or cyclic olefin5. The method of claim 1 , wherein the organic pre-polymer comprises an acrylate claim 1 , methacrylate claim 1 , acrylamide claim 1 , methacrylamide claim 1 , acrylonitrile claim 1 , vinyl acetate claim 1 , vinyl ketone claim 1 , vinyl aldehyde claim 1 , vinyl chloride claim 1 , vinyl ether claim 1 , vinyl amine claim 1 , vinyl silsesquioxane claim 1 , vinyl phosphonate claim 1 , or vinyl sulfonate claim 1 , or a mixture thereof.6. The method of claim 5 , wherein the organic pre-polymer comprises an acrylate or methacrylate.7. The method of claim 1 , wherein the photoredox catalyst is an organic molecule capable of reaching an excited electronic state when exposed to the visible light claim 1 , and having at least one absorption or emission wavelength in a range of from about 200 nm to about 800 nm.8. The method of claim 1 , wherein a source of visible light delivers a wavelength of light coincident with at least one absorption wavelength of the photoredox ...

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10-02-2022 дата публикации

SELF-HEALING LAMINATE COMPOSITION, RELATED ARTICLES AND RELATED METHODS

Номер: US20220040730A1
Принадлежит:

The disclosure relates to a self-healing laminate composition. The composition includes a first, self-healing layer with a self-healing polymer and a second, mechanical layer adjacent to the first layer. The second layer includes any desired polymer, for example a crosslinked polymer, a thermoplastic polymer, or a functional thermoset polymer. Self-healing polymers with dynamic covalent bonds are suitable, for example those with dynamic urea bonds and/or dynamic urethane bonds. A self-healing polymer that is damaged can undergo autonomous repair when separated surfaces re-contact each other due to the soft nature of the self-healing polymer, whereupon reversible bonds can reform to rejoin and repair the damaged self-healing polymer. When the self-healing laminate according to the disclosure is damaged, the self-healing mechanism of the first layer can cause the repair of both layers. The self-healing laminate composition can be used as a coating on any of a variety of substrates to provide self-healing properties to a surface 1. A self-healing laminate composition comprising:a first layer comprising a self-healing polymer; anda second layer adjacent to the first layer and comprising a polymer selected from the group consisting of a crosslinked polymer, a thermoplastic polymer, a functional thermoset polymer, and combinations thereof:,wherein the self-healing polymer comprises backbone segments comprising reversible linking groups selected from the group consisting of non-covalent interactions, coatings with trapped unreacted reagents, dynamic covalent bonds, thermoreversible bonds, mechanically reversible bonds, UV-triggerable reversible bonds, and combinations thereof.2. (canceled)3. A self-healing laminate composition comprising:a first layer comprising a self-healing polymer; anda second layer adjacent to the first layer and comprising a polymer selected from the group consisting of a crosslinked polymer, a thermoplastic polymer, a functional thermoset polymer, ...

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10-02-2022 дата публикации

RADIATION CURABLE PRIMER ADHESIVE

Номер: US20220041892A1
Принадлежит:

The present invention involves a 100% solids, radiation curable adhesive formulation for adhesion to EVA. This formulation may have varying compositions, as discussed in detail herein. However primarily the composition may comprise at least a monomer, and a chlorinated additive. Photo initiators may be used to allow for low temperature UV or other radiation curing. Other additives may be used to enhance functional features in various ways. In use, the present invention may be coated on a surface of EVA and then cured, and may be adhered to a substrate using only a layer of adhesive on the substrate, in contrast to the structures of the prior art, which require at least two sided adhesive application, among other complexities. 1. A 100% solids composition operable at room temperature and capable of radiation curing comprising:a monomer, selected to be at least one of a (meth)acrylate monomer and (meth)acrylate functional urethane oligomer;a chlorinated compound selected to be at least one of a chlorinated polyester, chlorinated rubber, and chlorinated polyolefin; anda photo initiator making up to 5% of the composition.2. The 100% solids composition of consisting of:10-50% hexanediol diacrylate as the monomer;10-40% chlorinated polyester as the chlorinated compound;10-30% cyclic aliphatic diacrylate;1-5% acidic methacrylate; and1-5% photoinitiator.3. The 100% solids composition of consisting of:10-50% hexanediol diacrylate as the monomer;10-40% chlorinated polyester as the chlorinated compound;10-30% cyclic aliphatic diacrylate;1-5% acidic methacrylate;5-35% modified epoxy diacrylate; and1-5% photoinitiator.4. The 100% solids composition of consisting of:60-99% methyl methacrylate as the monomer;0-20% hexanediol diacrylate;10-20% chlorinated polyolefin as the chlorinated compound;1-20% acidic methacrylate;1-5% NVC; and1-5% photoinitiator.5. The 100% solids composition of consisting of:10-30% hexanediol diacrylate as the monomer;10-70% acrylic polymer;10-20% ...

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24-01-2019 дата публикации

COMPOSITION INCLUDING COMPOUND HAVING MESOGENIC GROUP, POLYMER AND OPTICALLY ANISOTROPIC BODY OBTAINED BY POLYMERIZING POLYMERIZABLE COMPOSITION, AND PHASE DIFFERENCE FILM

Номер: US20190025490A1
Принадлежит: DIC CORPORATION

A polymerizable composition of the present invention has favorable solubility, and an optically anisotropic body using the polymerizable composition is unlikely to discolor and is excellent in heat resistance and light resistance. The problem to be solved by the present invention is to provide a polymer obtained by polymerizing the polymerizable composition and an optically anisotropic body using the polymer. The present invention relates to a polymerizable composition which includes a compound having at least one mesogenic group and satisfying an expression represented by Expression (1), and which satisfies an expression represented by Expression (2). 1. A polymerizable composition comprising: {'br': None, 'Re(450 nm)/Re(550 nm)<1.05\u2003\u2003Expression (1)'}, 'a compound that has at least one mesogenic group and satisfies an expression represented by Expression (1)(wherein Re (450 nm) represents an in-plane phase difference at a wavelength of 450 nm obtained in the case where the molecules of the compound are aligned on a substrate such that a major axis direction of each molecule is aligned substantially horizontally with respect to the substrate, and Re (550 nm) represents an in-plane phase difference at a wavelength of 550 nm obtained in the case where the molecules of the compound are aligned on a substrate such that a major axis direction of each molecule is aligned substantially horizontally with respect to the substrate), {'br': None, 'i': 'n≤', '0.5≤YI/Δ500\u2003\u2003Expression (2)'}, 'the composition satisfying an expression represented by Expression (2)(wherein YI represents a yellowness index of a material consisting only of the above-defined compound present in the polymerizable composition, Δn represents a refractive index anisotropy of a material consisting only of the above-defined compound present in the polymerizable composition, provided that a chiral compound having a mesogenic group is excluded from a material consisting only of the above- ...

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28-01-2021 дата публикации

Ethylene-Vinyl Acetate Copolymer And Preparation Method Thereof

Номер: US20210024667A1
Принадлежит: LG CHEM, LTD.

Provided are an ethylene-vinyl acetate copolymer having a high degree of crosslinking by controlling a temperature difference in an autoclave reactor and an input ratio of an initiator during polymerization, even though a reduced amount of a crosslinking agent is used, and a preparation method thereof. 1. An ethylene-vinyl acetate copolymer satisfying the following conditions of (1) to (4):(1) a degree of crosslinking: 89% or more,(2) a content of vinyl acetate: 25% by weight to 35% by weight with respect to the total weight of the ethylene-vinyl acetate copolymer,(3) a melt index (190° C., 2.16 kg): 10 g/10 min to 20 g/10 min, and(4) a ratio of η*/[η]: 7500 to 9500,where η* represents a complex viscosity at zero shear, as measured at 160° C., and [η] represents an intrinsic viscosity, as measured at 25° C.2. The ethylene-vinyl acetate copolymer of claim 1 , wherein the ethylene-vinyl acetate copolymer has a number average molecular weight of 18 claim 1 ,000 g/mol to 23 claim 1 ,000 g/mol.3. The ethylene-vinyl acetate copolymer of claim 1 , wherein the ethylene-vinyl acetate copolymer has a molecular weight distribution of 3.0 to 4.0.4. The ethylene-vinyl acetate copolymer of claim 1 , wherein the ethylene-vinyl acetate copolymer has a degree of crosslinking of 89% to 93%.5. A method of preparing an ethylene-vinyl acetate copolymer claim 1 , the method comprising the step ofpolymerizing an ethylene monomer and a vinyl acetate monomer in an autoclave reactor in the presence of an initiator,wherein the autoclave reactor includes three or more reaction zones,the initiator is introduced into an upper end and a lower end of the autoclave reactor, in which an amount of the initiator introduced into the lower end of the autoclave reactor is 12% by weight to 22% by weight of the total amount of the initiator,the reactor satisfies a relationship of a temperature (T1) of one or more reaction zones from the lowermost end>a temperature (T2) of one or more reaction zones from ...

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04-02-2016 дата публикации

Coating for a Surface

Номер: US20160032145A1
Принадлежит:

Coatings for a surface, especially a priming coating, of the present invention have been found to be durable, resistant to oxidative degradation, erosion and depolymerisation, stable to sterilization and low particulating, and are easily applied to the required surface of a substrate in a surface-independent manner. Such coatings, when used as priming coatings to be coated with a subsequent coating, in at least some embodiments, form exterior coatings which are also highly durable and are stable to sterilisation and aging. 1. A method of coating a surface , comprising the steps of: component A is a molecule capable of self-polymerisation comprising catechol functionality and amine and/or amide and/or hydroxyl functionality; and', 'component B is', '(i) a cross-linking molecule comprising two or more photosensitive or thermosensitive moieties capable of forming covalent bonds with component A; or', '(ii) a polymer comprising photosensitive or thermosensitive moieties capable of forming covalent bonds with component A,', 'or a mixture thereof;', 'such that component A self-polymerises in the presence of component B and in the case of (ii) forms an interpenetrating network with component B; and, '(a) contacting the surface with a mixture comprising components A and B, wherein'}(b) activating the photosensitive or thermosensitive moieties of component B such that at least some of said moieties form covalent bonds with component A.2. A method of coating a surface , comprising the steps of: component A is a molecule capable of self-polymerisation comprising catechol functionality and amine and/or amide and/or hydroxyl functionality; and', 'component B is a molecule comprising one or more groups capable of participating in the polymerisation of component A, wherein said molecule comprises one or more photosensitive or thermosensitive moieties capable of forming covalent bonds with component A such that a copolymer of components A and B is formed; and, '(a) contacting the ...

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09-02-2017 дата публикации

ELECTROCONDUCTIVE PASTE

Номер: US20170037271A1
Принадлежит: Sekisui Chemical Co., Ltd.

The present invention provides a conductive paste that has excellent printability, that can provide a printed electrode with a smooth surface, and that is excellent in storage stability. The present invention relates to a conductive paste used for formation of an electrode of a multilayer ceramic capacitor, the conductive paste including: a polyvinyl acetal resin that contains a carboxylic acid-modified polyvinyl acetal resin; an organic solvent; and a conductive powder, the polyvinyl acetal resin having an average degree of polymerization of 200 to 800, an carboxyl group content of 0.05 to 1 mol %, a hydroxy group content of 16 to 24 mol %, an acetyl group content of 0.1 to 3 mol %, and an acetoacetal group content of not more than 25 mol %, the carboxylic acid-modified polyvinyl acetal resin having at least one of a structural unit that has a carboxyl group represented by the formula (1-1) and a structural unit that has a carboxyl group represented by the formula (1-2): 2. The conductive paste according to claim 1 ,wherein the polyvinyl acetal resin has a ratio of the acetyl group content to the hydroxy group content of 0.01 to 0.15.3. The conductive paste according to claim 1 ,wherein the conductive powder comprises nickel.4. The conductive paste according to claim 1 , further comprising a ceramic powder.5. The conductive paste according to claim 1 ,{'sup': 3', '0.5, 'wherein the organic solvent has a solubility parameter of 8.0 to 11.0 (cal/cm).'}6. The conductive paste according to claim 1 ,wherein the polyvinyl acetal resin has a sodium ion content of less than 50 ppm.7. A multilayer ceramic capacitor produced using the conductive paste according to . The present invention relates to a conductive paste excellent in surface smoothness after printing.Electronic components used in various electronic devices have recently been down-sized and multilayered, leading to a wide use of multilayer-type electronic components such as multilayer circuit boards, multilayer ...

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08-02-2018 дата публикации

Fire Retardant-Treated Wood Products with Durable Coating Protection

Номер: US20180037751A1
Автор: LU ZIQIANG
Принадлежит:

A novel method of improving the water and leaching resistances and durability of a fire retardant-treated wood product by using a chemical fire retardant composition in which crosslinking polyvinyl acetate (XPAVc or X-PVAc) is applied as a protective coating on wood over the fire retardant layer. An additional crosslinking polyvinyl acetate coating layer or one or more layers of acrylic, alkyd, epoxy, lacquer, polyester, polyurethane, silicone coatings, vinyl ester, or the like may further cover the cured crosslinking polyvinyl acetate primer and then dried or cured. 1. A chemical fire retardant composition for wood comprising:a fire retardant;said composition further including a crosslinking polyvinyl acetate protective coating which is applied to exteriorly bond and seal wood surfaces;wherein the crosslinking polyvinyl acetate protective coating at least consists of a polyvinyl acetate-based adhesive resin, a crosslinking agent, and a catalyst before being cured; andwherein the protective coating has a minimum Fruehauf wet shear strength of 275 psi when applied to wood and cured.2. The chemical fire retardant composition of claim 1 , wherein the fire retardant includes a zinc- claim 1 , magnesium- claim 1 , or aluminum-based compound or complex claim 1 , a boron- claim 1 , phosphorus- claim 1 , bromine- claim 1 , sulfur- claim 1 , nitrogen- claim 1 , chlorine- claim 1 , fluorine- claim 1 , or silicon-based compound or complex claim 1 , or the combination thereof.3. The chemical fire retardant composition of having a minimum fire retardant retention of 0.005 lbs. per cubic foot for a fire retardant-treated wood member.4. The chemical fire retardant composition of claim 1 , wherein the concentration of an active fire retardant is at least 0.1% of a fire retardant formula by weight.5. The chemical fire retardant composition of claim 1 , wherein said crosslinking polyvinyl acetate adhesive has a solid content of at least 20% by weight.6. The chemical fire retardant ...

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07-02-2019 дата публикации

VINYL CHLORIDE-VINYL ACETATE COPOLYMER PARTICLES AND AUTOMOBILE UNDERBODY COATING AGENT

Номер: US20190040170A1
Автор: Watanabe Kazunori
Принадлежит: TOSOH CORPORATION

To provide vinyl chloride-vinyl acetate copolymer particles, which have a small change with time in sol viscosity when kneaded together with a plasticizer and are excellent in the mechanical strength during low temperature processing, and applications represented by a coating agent, particularly an automobile underbody coating or an automotive sealant. 1. Vinyl chloride-vinyl acetate copolymer particles comprising:vinyl chloride-vinyl acetate copolymers in which a vinyl acetate residue unit content is continuously distributed in a range of 0 to 30% by weight and the distribution has one local maximum, and which have an average degree of polymerization of 1,500 to 3,000 and an average vinyl acetate residue unit content of 5 to 15% by weight, wherein an average diameter of a primary particle of the vinyl chloride-vinyl acetate copolymers is from 1 to 2 μm.2. The vinyl chloride-vinyl acetate copolymer particles as claimed in comprising:a composition containing from 0.5 to 2 parts by weight of an alkyl sulfate ester salt with respect to 100 parts by weight of vinyl chloride-vinyl acetate copolymers in which a vinyl acetate residue unit content is continuously distributed in a range of 0 to 30% by weight and the distribution has one local maximum, and which have an average degree of polymerization of 1,500 to 3,000 and an average vinyl acetate residue unit content of 5 to 15% by weight,wherein an average diameter of a primary particle of the vinyl chloride-vinyl acetate copolymers is from 1 to 2 μm.3. The vinyl chloride-vinyl acetate copolymer particles as claimed in claim 2 ,wherein the alkyl sulfate ester salt is one selected from the group consisting of lithium lauryl sulfate, sodium lauryl sulfate, ammonium lauryl sulfate and triethanol ammonium lauryl sulfate.4. The vinyl chloride-vinyl acetate copolymer particles as claimed in claim 1 ,wherein the vinyl acetate residue unit content is continuously distributed in a range of 0 to 25% by weight and the distribution ...

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18-02-2021 дата публикации

COATING COMPOSITION

Номер: US20210047524A1
Принадлежит:

Described herein is a building panel comprising a body having a first major surface opposite a second major surface and a side surface extending therebetween, a coating applied to at least one of the first major surface, the second major surface, or the side surface, the coating comprising a binder, and a pigment composition comprising titanium dioxide, an alkali metal silicate, and a clay; wherein the titanium dioxide is present in an amount ranging from about 3.0 wt. % to about 15.0 wt. % based on the total weight of the pigment composition. 1. A building panel comprising:a body having a first major surface opposite a second major surface and a side surface extending therebetween; a binder; and', titanium dioxide;', 'an alkali metal silicate; and', 'a clay;, 'a pigment composition comprising'}], 'a coating applied to at least one of the first major surface, the second major surface, or the side surface, the coating comprisingwherein the titanium dioxide is present in an amount ranging from about 3.0 wt. % to about 15.0 wt. % based on the total weight of the pigment composition.2. The building panel according to claim 1 , wherein the pigment composition further comprises calcium carbonate claim 1 , optionally present in an amount ranging from about 40.0 wt. % to about 70.0 wt. % claim 1 , based on the total weight of the pigment composition.3. (canceled)4. The building panel according to claim 1 , wherein the alkali metal silicate is an alkali aluminum silicate claim 1 , optionally present in an amount ranging from about 0.3 wt. % to about 3.0 wt. % based on the total weight of the pigment composition.5. The building panel according to claim 4 , wherein the alkali metal silicate is sodium aluminum silicate.6. (canceled)7. The building panel according to claim 1 , wherein the pigment composition further comprises magnesium carbonate claim 1 , optionally present in an amount ranging from about 5.0 wt. % to about 20.0 wt. % based on the total weight of the pigment ...

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08-05-2014 дата публикации

Two Part Primer Composition

Номер: US20140127499A1

Two part compositions comprising Part A having vinyl acetate ethylene copolymer, acrylic tackifying resin and polyethylene imine, and Part B having an epoxy material curing agent. The two part compositions can be applied to make coated substrates and laminated structures. 1. A two component composition comprising a Part A comprising vinyl acetate ethylene copolymer , acrylic tackifying resin and polyethylene imine and a Part B comprising an epoxy material.2. The two component composition of wherein the Part A comprises 0.1% to about 25% polyethylene imine claim 1 , about 0.1% to about 15% claim 1 , acrylic tackifying resin and about 30% to about 90% vinyl acetate ethylene copolymer.3. The two component composition of wherein the Part A further comprises about 5% to about 50% water.4. The two component composition of wherein the Part A further comprises additives selected from the group consisting of solvents claim 1 , UV fluorescing agents claim 1 , antimicrobial compounds claim 1 , defoaming agents claim 1 , wetting agents claim 1 , waxes claim 1 , silica and combinations thereof.5. The two component composition of wherein the acrylic tackifying resin is selected from the group consisting of ethylacrylate acrylic acid claim 1 , styrene acrylic acid claim 1 , ethylene acrylic acid claim 1 , ethylene methacrylic acid claim 1 , styrene methacrylic acid claim 1 , vinyl toluene acrylic acid claim 1 , vinyl toluene methacrylic acid claim 1 , alpha methyl styrene acrylic acid claim 1 , alpha methyl styrene methacrylic acid claim 1 , indene acrylic acid claim 1 , indene methacrylic acid and combinations thereof.6. The two component composition of wherein the epoxy material is selected from the group consisting of epoxidized sorbitol claim 1 , epoxidized soybean oil claim 1 , epoxidized castor oil claim 1 , epoxidized novalac claim 1 , epoxidized linseed oil claim 1 , epoxidized meta-xylenediamine claim 1 , epoxidized Bisphenol A claim 1 , epoxidized menhaden oil claim 1 , ...

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22-02-2018 дата публикации

PHASE CHANGE COMPOSITE BIMORPHS

Номер: US20180050505A1
Автор: Blonder Greg E.
Принадлежит:

A bilayer composite thin-film beam structure is described. The structure incorporates a bulk phase change material as small inclusions in one layer of a bimorph. The structure, also referred to as a “phase change composite bimorph” or “PCBM”, curls abruptly, and reversibly, at a phase transition temperature. Large curling and effective expansion coefficients are demonstrated. The PCBMs may be employed in various self-assembly mechanisms and actuators. 1. An apparatus comprising:a first layer comprising a first material; anda second layer comprising a matrix incorporating a plurality of inclusions of a phase-change component.2. The apparatus of claim 1 , wherein the phase-change component transitions from a solid state to a liquid state at a transition temperature.3. The apparatus of claim 1 , wherein a curvature of the apparatus changes in response to reaching a transition temperature corresponding to the phase-change component.4. The apparatus of claim 3 , where the phase-change component produces a curvature shift in the apparatus due to a change in volume of the phase-change component.5. The apparatus of claim 1 , wherein at least a portion of the phase-change component is encapsulated prior to incorporation into the matrix of the second layer.6. The apparatus of claim 5 , wherein at least a portion of the phase-change component is encapsulated by one or more microsphere shells.7. The apparatus of claim 1 , wherein the matrix comprises a polymer.8. The apparatus of claim 1 , wherein the plurality of inclusions of the phase-change component transition from a solid state to a liquid state in response to reaching a transition temperature.9. The apparatus of claim 8 , wherein a curvature of the apparatus changes in response to the plurality of inclusions of the phase-change component transitioning from the solid state to the liquid state.10. The apparatus of claim 1 , wherein the phase-change component comprises gallium.11. The apparatus of claim 1 , wherein the ...

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10-03-2022 дата публикации

HIGH SOLIDS COATINGS FOR BUILDING PANELS

Номер: US20220073778A1
Принадлежит:

Described herein is a coating composition suitable for application to a building panel. The coating composition comprises inorganic pigment, liquid carrier, and a humectant comprising a first ester-containing compound. The liquid carrier may be present in an amount ranging from about 10 wt. % to about 30 wt. % based on the total weight of the coating composition. Described herein are also building panels coated with the coating composition and methods of their production. 1. A building system comprisinga first building panel positioned adjacent to a second building panel, and a seam formed between the first and second building panels;a seam-filling material applied to the seam;{'claim-text': ['a binder having a pH of at least about 7.0 and a Tg of at least 20° C.;', 'a pigment; and', 'a viscosity modifier;'], '#text': 'a coating applied to the first and second building panels and the seam-filing material, the coating comprising:'}wherein the pigment and binder are present in a weight ratio of at least about 5:1.2. The building system according to claim 1 , wherein the Tg of the binder is at least 30° C.3. The building system according to claim 1 , wherein the binder is a styrene acrylic copolymer.4. The building system according to claim 1 , wherein the styrene acrylic copolymer has a pH ranging from about 7.5 to about 9.5. The building system according to claim 1 , wherein the binder is polyvinyl acetate.6. The building system according to claim 5 , wherein the polyvinyl acetate has a pH of about 7.0.7. The building system according to claim 1 , wherein the viscosity modifier comprises a humectant and a dispersant.8. The building system according to claim 7 , wherein humectant and the dispersant are present in a weight ratio ranging from about 1:1 to about 4:1.9. The building system according to claim 7 , wherein the humectant is selected from the group consisting of ester-containing humectants including sugar-based esters and glycol-based esters.10. The building ...

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10-03-2022 дата публикации

Universal Printable Topcoat for Graphics

Номер: US20220073780A1
Автор: Patil Dhananjay
Принадлежит:

Coated substrates comprising a topcoat are disclosed. The coated substrate may be substantially free of PVC while having performance comparable to a coated substrate comprising PVC. The topcoat may comprise a base polymer comprising a polyvinylpyrrolidone copolymer, such as polyvinylpyrrolidone/vinyl acetate. The base polymer may also comprise a cationic acrylic resin. The topcoat may also comprise a pigment system and optionally, a crosslinking system. 1. A topcoat comprising a base polymer and a pigment system , wherein the base polymer comprises a polyvinylpyrrolidone copolymer and a cationic acrylic resin.2. The topcoat of claim 1 , wherein the topcoat further comprises a pigment system.3. The topcoat of claim 1 , wherein the topcoat is substantially free of polyvinyl chloride.4. The topcoat of claim 1 , wherein the topcoat comprises from 25 to 80 wt. % base polymer claim 1 , based on the total weight of the topcoat.5. The topcoat of claim 1 , wherein the topcoat comprises from 1 to 20 wt. % polyvinylpyrrolidone copolymer claim 1 , based on the total weight of the topcoat.6. The topcoat of claim 1 , wherein the polyvinylpyrrolidone copolymer comprises polyvinylpyrrolidone and vinyl acetate.7. The topcoat of claim 1 , wherein the cationic acrylic resin does not have hydroxyl functionality and further wherein the topcoat does not comprise a crosslinker.8. The topcoat of claim 1 , wherein the cationic acrylic resin is a high molecular weight cationic stabilized polymer with hydroxyl functionality.9. The topcoat of claim 1 , wherein the base polymer comprises from 20 to 60 wt. % cationic acrylic resin claim 1 , based on the total weight of the topcoat.10. The topcoat of claim 1 , wherein the pigment system comprises a pigment claim 1 , a filler claim 1 , and a binding agent.11. The topcoat of claim 9 , wherein the filler is a silica.12. The topcoat of claim 1 , wherein the binding agent is a metal oxide.13. The topcoat of claim 1 , wherein the pigment system ...

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20-02-2020 дата публикации

MACROPOROUS BEADS

Номер: US20200055965A1
Принадлежит:

A continuous process for manufacturing macroporous beads, the process comprising: providing an aqueous carrier phase flowing through a pipe at a carrier phase flow velocity; providing an emulsion of a UV-polymerisable or thermally polymerisable continuous phase in an aqueous dispersed phase; injecting the emulsion into the carrier phase at an injection speed to create polymerisable droplets flowing in the carrier phase; forming macroporous beads by irradiating the droplets with UV light, or by heating the droplets to a temperature sufficient to decompose a thermal initiator in the continuous phase, to polymerise the droplets; and removing the macroporous beads from the carrier phase; wherein the ratio of carrier phase flow velocity/injection speed is at least 1. 1. A continuous process for manufacturing macroporous beads , the process comprising:providing an aqueous carrier phase flowing through a pipe at a carrier phase flow velocity;providing an emulsion of a UV-polymerisable or thermally polymerisable continuous phase in an aqueous dispersed phase;injecting the emulsion into the carrier phase at an injection speed to create polymerisable droplets flowing in the carrier phase;forming macroporous beads by irradiating the droplets with UV light, or by heating the droplets to a temperature sufficient to decompose a thermal initiator in the continuous phase, to polymerise the droplets; andremoving the macroporous beads from the carrier phase; whereinthe ratio of carrier phase flow velocity/injection speed is at least 1.2. The process according to claim 1 , wherein the ratio of carrier phase flow velocity/injection speed is in the range 1-5.3. The process according to claim 1 , wherein the carrier phase contains an initiator for initiating or promoting polymerisation of the continuous phase in the emulsion.4. The process according to claim 1 , wherein the carrier phase contains a material to be encapsulated within the macroporous beads.5. The process according to claim ...

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28-02-2019 дата публикации

HIGH SOLIDS EDGE COATINGS FOR BUILDING PANELS

Номер: US20190062574A1
Автор: Hughes John E.
Принадлежит:

Described herein is a coating composition suitable for application to a building panel. The coating composition comprises inorganic pigment, liquid carrier, and a humectant comprising a first ester-containing compound. The liquid carrier may be present in an amount ranging from about 10 wt. % to about 30 wt. % based on the total weight of the coating composition. Described herein are also building panels coated with the coating composition and methods of their production. 1. A coated building panel comprising:a body comprising a first major surface and a side surface that intersects the first major surface; inorganic pigment; and', 'a humectant comprising a first ester-containing compound;, 'a coating applied to at least one of the first major surface or the side surface, the coating comprisingwherein the surface coating comprises a liquid carrier in an amount less than about 1 wt. % based on the total weight of the coating.2. The coated building panel according to claim 1 , wherein the humectant is present in an amount ranging from about 0.5 wt. % to about 3.0 wt. % based on the total weight of the coating.3. The coated building panel according to claim 1 , wherein the first ester-containing compound is non-ionic.4. The coated building panel according to claim 1 , wherein the humectant is hydrophobic.5. (canceled)6. The coated building panel according to claim 1 , wherein the humectant is a blend of the first ester-containing compound and a second ester-containing compound that is different from the first ester-containing compound.7. The coated building panel according to claim 6 , wherein first ester-containing compound is a carbohydrate based ester.8. The coated building panel according to claim 6 , wherein the second ester containing compound is a keto-acid based ester claim 6 , wherein the second ester is the reaction product of acetoacetic acid and a mono-functional alcohol having a C1-C12 carbon chain.910.-. (canceled)11. The coated building panel according ...

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28-02-2019 дата публикации

HIGH SOLIDS COATINGS FOR BUILDING PANELS

Номер: US20190062585A1
Принадлежит:

Described herein is a coating composition suitable for application to a building panel. The coating composition comprises inorganic pigment, liquid carrier, and a humectant comprising a first ester-containing compound. The liquid carrier may be present in an amount ranging from about 10 wt. % to about 30 wt. % based on the total weight of the coating composition. Described herein are also building panels coated with the coating composition and methods of their production. 1. A coated building panel comprising:a body comprising a first major surface and a side surface that intersects the first major surface; a binder having a pH of at least about 7.0 and a Tg of at least 20° C.;', 'a pigment; and', 'a viscosity modifier;, 'a coating applied to at least one of the first major surface or the side surface, the coating comprisingwherein the pigment and binder are present in a weight ratio of at least about 5:1.2. The coated building panel according to claim 1 , wherein the Tg of the binder is at least 30° C.3. The coated building panel according to claim 1 , wherein the binder is a styrene acrylic copolymer having a pH ranging from about 7.5 to about 9.4. (canceled)5. The coated building panel according to claim 1 , wherein the binder is polyvinyl acetate having a pH of about 7.0.6. (canceled)7. The coated building panel according to claim 1 , wherein the viscosity modifier comprises a humectant and a dispersant present in a weight ratio ranging from about 1:1 to about 4:1.811.-. (canceled)12. The coated building panel according to claim 1 , wherein the pigment is selected from one or more of titanium dioxide claim 1 , calcium carbonate claim 1 , alumina trihydrate claim 1 , and diatomaceous earth.1332.-. (canceled)33. A coated building panel comprising:a body comprising a first major surface and a side surface that intersects the first major surface; a binder;', 'a pigment; and', 'a viscosity modifier comprising a humectant and a dispersant present in a weight ratio ...

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12-03-2015 дата публикации

Method for producing laminated body

Номер: US20150070764A1
Принадлежит: Sumitomo Chemical Co Ltd

Method for producing a thin optical laminated body. This method is a method for producing a laminated body including a polarization layer, a λ/2 layer, a λ/4 layer, a positive C layer, and a transfer adhesive layer, the laminated body including the polarization layer, the λ/2 layer and the λ/4 layer in this member-described order; including the positive C layer between the polarization layer and the λ/4 layer, or at the side of the λ/4 layer that is opposite to the λ/2-layer-arranged side of the λ/4 layer; and including the transfer adhesive layer between the polarization layer and the λ/4 layer or positive C layer, the method including the step of bonding a bonding body including a substrate and the transfer adhesive layer to an adherend through the transfer adhesive layer, and peeling the substrate from the resultant.

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29-05-2014 дата публикации

HIGH TEMPERATURE RESISTANT SOUND ABSORBING MATERIALS FOR VEHICLE

Номер: US20140144723A1
Принадлежит:

Disclosed is a highly heat resistant sound absorbing material for a vehicle capable of maintaining a shape even at high temperatures of about 200° C. or above and which satisfies UL 94V-0 flame retardancy. More particularly, the a highly heat resistant sound absorbing material includes a fiber material having a limiting oxygen index (LOI) of at least about 25% and capable of maintaining a shape at a temperature of about 200° C. or above, and a thermosetting binder resin capable of maintaining a shape at a temperature of about 200° C., wherein the fiber material and thermosetting binder resin are provided at a specific proportion. 1. A highly heat resistant sound absorbing material for a vehicle that maintains a shape at temperatures of about 200° C. or above and satisfies UL 94V-0 flame retardancy.2. The highly heat resistant sound absorbing material for a vehicle according to claim 1 , comprising about 20-80 parts by weight of a fiber material and about 20-80 parts by weight of a thermosetting binder resin.3. The highly heat resistant sound absorbing material for a vehicle according to claim 2 , wherein the fiber material has a limiting oxygen index (LOI) of at least about 25% and maintains a shape at a temperature of about 200° C. or above claim 2 , and the thermosetting binder resin maintains a shape at a temperature of about 200° C. or above.4. The highly heat resistant sound absorbing material for a vehicle according to claim 2 , wherein the fiber material comprises one or more selected from the group consisting of m-aramid fiber claim 2 , p-aramid fiber claim 2 , polyphenylene sulfide (PPS) fiber claim 2 , preoxidized polyacrylonitrile (PAN) fiber claim 2 , polyimide (PI) fiber claim 2 , polybenzimidazole (PBI) fiber claim 2 , polybenzoxazole (PBO) fiber claim 2 , polytetrafluoroethylene (PTFE) fiber claim 2 , metallic fiber claim 2 , carbon fiber claim 2 , glass fiber claim 2 , basalt fiber claim 2 , silica fiber and ceramic fiber.5. The highly heat resistant ...

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10-03-2016 дата публикации

FLAME RETARDANT POLY(TRIMETHYLENE) TEREPHTHALATE COMPOSITIONS AND ARTICLES MADE THEREFROM

Номер: US20160069018A1
Принадлежит:

Poly(trimethylene terephthalate) compositions, and articles made therefrom, having improved flame retardancy are provided. The compositions can be used to make carpets that are suitable for installation where flame retardancy is desired. 116-. (canceled)17. A carpet comprising face fibers and a precoat , wherein: the face fibers comprise (a) from about 75 to about 99.9 weight percent of a resin component , based on the total composition weight , wherein the resin component comprises at least about 70 weight percent of a poly(trimethylene terephthalate) homopolymer , based on the weight of the resin component; and (b) from about 0.1 to about 25 weight percent of an additive package , based on the total composition weight , comprising from about 0.1 to about 15 weight percent of melamine cyanurate , melamine pyrophosphate , a zinc salt of diethyl phosphinic acid , or blends thereof , based on the total composition weight and the precoat contains a flame retardant additive selected from aluminum trihydrate and magnesium hydroxide.18. The carpet of claim 17 , wherein the precoat is latex-derived and contains the flame retardant in a quantity of 400 phr or less claim 17 , based on the total weight of the resin component in the precoat.19. The carpet of wherein the flame retardant is aluminum trihydrate.20. The carpet of wherein the precoat comprises a hot melt adhesive and contains the flame retardant in a quantity of 25 weight % or less claim 17 , based on the total weight of the resin component in the precoat.21. The carpet of claim 17 , wherein the precoat is latex-derived and contains the flame retardant aluminum trihydrate in a quantity of 300 phr or less claim 17 , based on the total weight of resin component in the precoat claim 17 , and wherein the carpet contains 2 weight % or less zinc salt of diethyl phosphinic acid in the fiber claim 17 , at a carpet basis weight of 28 oz/ydor less.22. The carpet of claim 21 , wherein the carpet exhibits a radiant panel ...

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11-03-2021 дата публикации

ULTRAVIOLET CURABLE ORGANOPOLYSILOXANE COMPOSITION, SILICONE GEL CURED PRODUCT AND METHOD FOR PRODUCING SAME, AND PRESSURE SENSOR

Номер: US20210070912A1
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

An ultraviolet curable organopolysiloxane composition which contains: 2. The UV-curable organopolysiloxane composition of wherein component (A) is a linear or branched organopolysiloxane having one or two groups of the general formula (1) and/or (2) on each of the silicon atoms at the ends of the molecular chain independently claim 1 , the total number of said groups being at least three per molecule claim 1 , andcomponent (B) is a linear or branched organopolysiloxane blocked at the end of the molecular chain with a group of the general formula (3).4. A method for preparing a silicone gel cured product claim 1 , comprising the step of irradiating UV radiation to the UV-curable organopolysiloxane composition of claim 1 , the cured product having a penetration of 10 to 130 according to JIS K2220.5. A silicone gel cured product obtained by curing the UV-curable organopolysiloxane composition of claim 1 , the cured product having a penetration of 10 to 130 according to JIS K2220 and a volume resistivity of at least 1 TΩ·m according to JIS K6271 at an applied voltage of 500 V.6. A pressure sensor comprising the silicone gel cured product of . This invention relates to an ultraviolet-curable organopolysiloxane composition which is effectively curable with a wide range of UV illuminance and good in surface cure and depth cure and facilitates to adjust the hardness of a cured product, and more particularly, to a UV-curable organopolysiloxane composition which upon UV irradiation, is improved in reducing oxygen inhibition and consistently cures even in the presence of oxygen into a silicone gel (gel-like cured product) having a substantially constant crosslinking density (substantially constant penetration), independently of the UV dose (irradiation energy amount); a silicone gel cured product obtained by curing the composition, a method for producing the cured product, and a pressure sensor comprising the cured product.The efforts to enable simplification and cost ...

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15-03-2018 дата публикации

Low Emission, High Scrub VAE Latex Paints

Номер: US20180072910A1
Принадлежит:

A water-based, low-emission latex paint formulation includes a vinyl acetate/ethylene (VAE) latex including a VAE resin with from 80 to 95 weight % vinyl acetate residue and from 5 to 20 weight % ethylene residue, optionally including additional monomers as well as a pigment composition including inorganic solids selected from inorganic pigments, inorganic fillers and mixtures thereof present in an amount such that the paint formulation has a pigment volume concentration (PVC) of from 25% to 85%. The formulations are suitable for eggshell and flat latex paints and exhibit surprising durability. 1. A water-based , low-emission latex paint formulation comprising:(a) a vinyl acetate/ethylene (VAE) latex including a VAE resin consisting of (i) from 80 to 95 weight % vinyl acetate residue and (ii) from 5 to 20 weight % ethylene residue;(b) a pigment composition including solids selected from the group consisting of inorganic pigments, inorganic fillers and mixtures thereof present in an amount such that the paint formulation has a pigment volume concentration (PVC) of from 25% to 85%; and(c) one or more auxiliary components selected from the group consisting of wetting agents, dispersants, emulsifiers, protective colloids, thickeners, antifoams, dyes and preservatives;wherein (i) the resin has a K-value of greater than 60, (ii) the paint formulation exhibits a relative scrub index of greater than 200% and up to 300%, and (iii) the ratio of the relative scrub index of the latex to the K-value of the resin is at least 2.25/1; and wherein the resin and the paint formulation are alkylphenol ethoxylate (APE)-free.2. The water-based claim 1 , low-emission paint formulation according to claim 1 , wherein the ethylene residue in the resin is from 10 to 15 weight %.3. The water-based claim 1 , low-emission paint formulation according to claim 1 , wherein the paint formulation has a volatile organic content less than 5 g/L.4. The water-based claim 1 , low emission paint ...

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16-03-2017 дата публикации

HYDROPHOBING AGENT FOR COATINGS

Номер: US20170073527A1
Принадлежит:

Weathering-resistance and hydrophobicity of paints and coatings are enhanced by addition of a composition comprising an organopolysiloxanes bearing pendent aminoalkyl groups and fatty acid ester-based epoxy group-containing compounds. 1. A weather-resistant paint or coating which is an aqueous emulsion , comprising:a) at least one organic polymer binder;b) optionally, one or more pigments;c) optionally, one or more surfactants; andd) from 0.1 weight percent to 10 weight percent based on the total weight of the aqueous emulsion, of a composition comprising: {'br': None, 'sub': m', 'n', 'o', 'p, 'MDTQ\u2003\u2003(I),'}, 'at least one organosiloxane of the formula (I)'}in which {'br': None, 'sup': 1', '2', '3, 'sub': '1/2', 'RRRSiO\u2003\u2003(Ia),'}, 'M is a terminal group of the formula (Ia)'} {'br': None, 'sup': 4', '5, 'sub': '2/2', 'RRSiO\u2003\u2003(Ib),'}, 'D is a difunctional group of the formula (Ib)'} {'br': None, 'sup': '6', 'sub': '3/2', 'RSiO\u2003\u2003(Ic),'}, 'T is a trifunctional group of the formula (Ic)'}{'sub': '4/2', 'Q is a unit of the formula SiO,'}{'sup': 1', '2', '3', '4', '5', '6', '6, 'where R, R, R, R, Rand Rindependently of one another are hydrocarbon radicals having 1 to 20 C atoms, optionally containing heteroatoms, or are hydroxyl radicals, or alkoxy radicals having 1 to 10 C atoms, where at least one hydrocarbon radical Rcontains at least one amine function, and not more than 25% of all of the radicals are hydroxyl or alkoxy radicals,'}m is an integer 0-20,n is an integer 0-1000,o is an integer 1-30,p is an integer 0-20, and {'br': None, 'sub': 'q', '(A-B)C \u2003\u2003(II)'}, 'm+n+o+p is an integer which is at least 2, and epoxides of the formula (II)'}in whichA independently at each occurrence is a monovalent linear or branched hydrocarbon radical having 1 to 30 C atoms, optionally substituted by heteroatoms or which is optionally interrupted by heteroatoms, and which optionally contains one or more epoxy functions,B independently at ...

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19-03-2015 дата публикации

POLYMER ENCAPSULATED TITANIUM DIOXIDE PARTICLES

Номер: US20150079397A1
Принадлежит:

A process for encapsulating TiOparticles by polymerizing sodium styrene sulfonate with a redox initiator system; then polymerizing a first monomer mixture comprising at least 60 wt % acrylic monomers; then polymerizing a second monomer mixture comprising at least 40 wt % vinyl ester monomers. 1. A process comprising steps of:{'sub': '2', '(a) contacting a mixture of i) an aqueous dispersion of TiOparticles and a sulfur-acid containing polymer; ii) an anionic surfactant; and iii) an aqueous solution of sodium styrene sulfonate with a redox initiator system; then'}(b) adding to the mixture of step (a) an aqueous dispersion of a first monomer mixture comprising monomers selected from the group consisting of acrylic monomers, ethylene monomers, styrene monomers, vinyl ester monomers, and combinations thereof; wherein said first monomer mixture comprises at least 60 wt % acrylic monomers, based on total weight of monomers in the first monomer mixture;{'sub': '2', '(c) polymerizing the first monomer mixture to form an aqueous dispersion of a first polymer that at least partially encapsulates the TiOparticles;'}(d) adding to the aqueous dispersion of step (c) an aqueous dispersion of a second monomer mixture comprising monomers selected from the group consisting of acrylic monomers, ethylene monomers, styrene monomers, vinyl ester monomers, and combinations thereof;wherein said second monomer mixture comprises at least 50 wt % vinyl ester monomers, based on total weight of monomers in the second monomer mixture; and(e) polymerizing the second monomer mixture.2. The process of wherein a ratio of the total weight of monomers in the first monomer mixture to weight of TiOparticles is from 0.1:1 to 0.6:1 and a ratio of the total weight of monomers in the second monomer mixture to weight of TiOparticles is from 0.4:1 to 1.4:1.3. The process of wherein a ratio of weight of sodium styrene sulfonate to weight of TiOparticles is from 0.001:1 to 0.015:1.4. The process of wherein said ...

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05-03-2020 дата публикации

PROCESSING TECHNOLOGY OF BUSBAR FOR NEW ENERGY AUTOMOBILE

Номер: US20200071545A1
Автор: GE Yangbo
Принадлежит:

A processing technology of a busbar for a new energy automobile comprises the following steps: first step: punching a raw material blank of a busbar to obtain a busbar base material; second step: spraying high-temperature-resistant insulating paint on part or whole of an outer surface of the busbar base material obtained in the first step; and third step: drying to obtain a busbar. The busbar of the present invention has simple processing technology. 2. The processing technology of the busbar for the new energy automobile according to claim 1 , characterized in that: the thickness of the busbar base material is less than or equal to 12.5 mm; the cross-sectional area of the busbar base material is less than or equal to 38 cm; the tensile strength claim 1 , σb of the busbar base material is greater than or equal to 200 Mpa; the yield strength claim 1 , σp0.2 of the busbar base material is greater than or equal to 150 Mpa; and the elongation claim 1 , δ5 of the busbar base material is greater than or equal to 15%.3. The processing technology of the busbar for the new energy automobile according to claim 2 , characterized in that: the density of the busbar base material is 2.7 g/cm.4. The processing technology of the busbar for the new energy automobile according to claim 2 , characterized in that: the thermal conductivity of the busbar base material at 25° C. is 218 W/(m·K).5. The processing technology of the busbar for the new energy automobile according to claim 2 , characterized in that: the conductivity of the busbar is greater than or equal to 57% IACS.6. The processing technology of the busbar for the new energy automobile according to claim 6 , characterized in that: the solid content in the raw material formula of the high-temperature-resistant insulating paint is less than or equal to 60%. The present invention relates to a processing technology of a busbar for a new energy automobile, and belongs to the technical field of new energy automobiles.The automobile ...

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19-03-2015 дата публикации

PROTECTIVE OVERCOAT FOR PRINTED IMAGES

Номер: US20150080514A1
Принадлежит: XEROX CORPORATION

A method includes forming a film over a printed image on a substrate, the film includes a print overcoat composition having a binder that includes an aqueous vinylacetate-ethylene copolymer emulsion, (1) a particulate additive as a dispersion or emulsion, (2) a co-binder, or (3) both, and a surfactant, the film provides wear and scratch resistance to the printed image. 1. A method comprising: a binder comprising an aqueous vinylacetate-ethylene copolymer emulsion;', '(1) a particulate additive as a dispersion or emulsion, (2) a co-binder, or (3) both; and', 'a surfactant;', 'wherein the film provides wear and scratch resistance to the printed image., 'forming a film over a printed image on a substrate, the film comprising a print overcoat composition comprising2. The method of claim 1 , wherein the printed image is ink or toner image.3. The method of claim 1 , wherein the substrate is one selected from the group consisting of uncoated paper claim 1 , coated paper claim 1 , synthetic paper and polymer film.4. The method of claim 1 , wherein the co-binder is an acrylic copolymer latex.5. The method of claim 1 , wherein the particulate additive comprises one selected from the group consisting of alumina nanoparticles claim 1 , a silicone powder claim 1 , colloidal silica claim 1 , a micronized wax claim 1 , and combinations thereof.6. A print overcoat composition comprising:a binder comprising aqueous vinylacetate-ethylene copolymer emulsion;a particulate additive comprising an aqueous dispersion of alumina oxide nanoparticles;an optional micronized wax emulsion; anda surfactant.7. The print overcoat of claim 6 , wherein the vinylacetate-ethylene copolymer emulsion is present in an amount from about 5 percent to about 97% by weight of the composition.8. The print overcoat of claim 6 , wherein the vinylacetate-ethylene copolymer is present in the emulsion in an amount from about 15 percent to about 60 percent by weight of the emulsion.9. The print overcoat of claim 6 , ...

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18-03-2021 дата публикации

PROCESS TO MAKE A COMPOSITE AUTOMOTIVE TRIM PART

Номер: US20210078218A1
Принадлежит:

The present invention relates to a method for producing a composite part comprising a textured skin and a rigid or foam substrate layer, in particular a composite automotive trim part. The method comprises the steps of spraying or casting an aqueous thermoplastic dispersion onto a rigid or foam substrate composite followed by forming the composite into a composite part comprising a textured skin and a rigid or foam substrate layer. Preferably, the dispersion is derived from the extrusion melt blending of thermoplastic polymer, a dispersing agent, and water. 1. A process for making a composite part having a shape and a thickness comprising a textured skin and a rigid or foam substrate layer comprising the steps of: a) a thermoplastic composition in the presence of', 'b) at least one dispersing agent,', 'and', 'c) water;, 'A) applying an aqueous thermoplastic dispersion onto a first surface of a rigid or foam substrate forming a composite structure with a skin layer wherein the aqueous thermoplastic dispersion is derived from the extrusion melt blending of'}B) providing a molding apparatus comprising a mold having a first mold half having a textured surface and a second mold half having a second surface opposite the first surface and being engageable with said first mold half such that when the mold halves are engaged a mold cavity there between is defined corresponding to the shape and the thickness of a part;C) heating the composite structure;D) placing the heated composite structure between the open mold halves in the molding apparatus such that the skin layer will be contacted by the textured surface of the first mold half;E) closing the mold halves and contacting the composite structure;F) forming a rigid or foam substrate composite part having a textured skin layer;H) cooling the composite part;I) opening the mold;andJ) removing the composite part.2. The process of wherein the dispersion applied in step A) is allowed to dry prior to step C).3. The process of ...

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12-06-2014 дата публикации

Laminate Structure To Stabilize A Dimensionally Unstable Layer

Номер: US20140158691A1
Принадлежит:

A seal laminate for closing a mouth of a container is provided. The seal laminate includes a heat seal layer, a structural base support layer and upper and lower dimensional stable layers. The heat seal layer bonds the laminate to a rim surrounding the container's mouth. The structural base support layer may be comprised of a pulp, paper, cardboard, chipboard, paperboard, or cellulose based material having a moisture content of about 3 to about 6 percent and is positioned above the heat seal layer. The upper and lower dimensionally stable layers are disposed above and below the structural base support layer and are sized to balance the vertical forces on the structural base support layer upon exposure to about 60 percent or greater relative humidity. The upper and lower dimensionally stable layers have a water vapor transmission rate of about 1.5 g/100 in/24 hours or below. 115-. (canceled)16. A seal laminate having dimensional stability in high humidity and for closing a mouth of a container , the dimensionally stable seal laminate comprising:a heat seal layer having an upper surface thereof, the heat seal layer for bonding the seal laminate to a rim surrounding the container's mouth;a structural support layer having upper and lower surfaces thereof and positioned above and extending across the entire upper surface of the heat seal layer, the structural support layer including materials selected from the group consisting of pulp, paper, cardboard, chipboard, paperboard, cellulose based material, and mixtures thereof and including one of softwood fibers, hardwood fibers, and blends thereof with a moisture content of about 3 to about 6 percent at about 50 to about 55 percent relative humidity;{'sup': '2', 'upper and lower dimensionally stable layers directly bonded to the structural support layer on the upper and lower surfaces thereof, the upper and lower dimensionally stable layers each having a water vapor transmission rate of no more than about 1.5 g/100 in/24 ...

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22-03-2018 дата публикации

GYPSUM BOARDS WITH POLYMER COATING AND METHODS FOR MAKING SAME

Номер: US20180080226A1
Автор: Lu Runhai, ROHLF Evan V.
Принадлежит:

A gypsum board provided with a foamed gypsum core layer, a facing sheet over the foamed gypsum core, and a latex polymer coating layer on an outer surface of the facing sheet. The latex polymer having a glass transition temperature (Tg) of 0 to 35° F. Methods for making the board are also disclosed. 1. A gypsum board comprising:a face paper sheet having an inner bond surface and an outer surface, the face paper sheet inner bond surface opposed to the face paper sheet outer surface, the face paper sheet treated with a polymer coating composition disposed on the entire outer surface of the face paper sheet to have a polymer coating, 0.05 to 0.25 wt. % 2-amino-2-methyl-1-propanol,', '0 to 0.5 wt. % dispersant selected from at least one member of the group consisting of polycarboxylate dispersant, polyphosphate dispersant, and naphthalene dispersant,', 'preferably the polycarboxylate dispersant comprises a polycarboxylic ether dispersant,', 'preferably the naphthalene dispersant is selected from at least one of beta-naphthalene sulfonate, naphthalene sulfonate formaldehyde condensate and sodium naphthalene sulfate formaldehyde condensate,', 'preferably the polyphosphate dispersant is selected from at least one member of the group consisting of sodium trimetaphosphate (STMP), sodium tripolyphosphate (STPP), potassium tripolyphosphate (KTPP), tetrasodium pyrophosphate tetrapotassium pyrophosphate, and tetrapotassium pyrophosphate (TKPP), more preferably the polyphosphate is tetrapotassium pyrophosphate (TKPP),', '0.02 to 0.5 wt. % thickener selected from at least one member of the group consisting of a cellulose thickener and an acrylate thickener,', '0.01 to 0.5 wt. % silicon based defoamer,', '4.5 to 15 wt. %, preferably 4.8 to 6.5 wt. %, more preferably 4.8 to 5.2 wt. %, latex comprising latex polymer having a glass transition temperature (Tg) of 0 to 35° F., preferably 25 to 32° F., the latex polymer having a weight average molecular weight of 40,000 to 500,000, the ...

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26-03-2015 дата публикации

VINYL ESTER/ETHYLENE COPOLYMER DISPERSIONS PREPARED BY CONTINUOUS TUBULAR EMULSION POLYMERIZATION FOR COATING CARPET PRODUCTS

Номер: US20150086746A1
Принадлежит: CELANESE EMULSIONS GMBH

Disclosed are aqueous compositions suitable for use as binders or adhesives in carpet products. Such compositions, prior to being applied to carpet substrates and cured, comprise vinyl ester/ethylene copolymer dispersions, along with other optional comonomers. The compositions are made by a continuous emulsion polymerisation that utilises a continuous loop reactor with a secondary line section. Carpet products which utilise such coating compositions to provide binder and/or adhesive layer within the carpet are also disclosed. 1. A carpet coating composition comprising:an aqueous dispersion of a copolymer comprising polymerized co-monomers vinyl acetate and ethylene, where the dispersion is prepared by a continuous emulsion polymerization in a reactor comprising a closed loop section and a secondary line section.2. A carpet coating composition comprising:an aqueous dispersion of a copolymer comprising polymerized monomers vinyl acetate and ethylene, where the dispersion is prepared by a continuous emulsion polymerization in a polymerization reactor comprising a first section with a circulation loop with one or more inlets for raw material, a pump for circulating a reactor charge within the circulation loop, and a secondary line section not forming a closed loop connected to a discharge of the first section.3. The composition of claim 2 , wherein the volume of the secondary section is less than twice the volume of the circulation loop.4. The composition of claim 2 , wherein the mean residence time in the circulation loop is less than 12 minutes.5. The composition of claim 1 , wherein the aqueous dispersion further comprises an emulsifier.6. The composition of claim 5 , wherein the emulsifier is nonionic.7. The composition of claim 1 , wherein the aqueous dispersion further comprises a protective colloid.8. The composition of claim 1 , wherein the copolymer is substantially free of functional monomer.9. The composition of claim 1 , wherein the aqueous dispersion has a ...

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12-03-2020 дата публикации

INSULATION LAYER COMPOSITION AND INSULATION LAYER FOR PLANT TISSUE CULTURE

Номер: US20200079928A1
Автор: LIU Jun-Nan
Принадлежит:

The present disclosure provides an insulation layer composition and an insulation layer for a plant tissue culture. The insulation layer composition includes polyvinyl acetate emulsion resin, water, a gel forming agent and a hyaluronic acid diluent, in which the gel forming agent is a mixture of glycerin and polyglycerol acrylate. The insulation layer for the plant tissue culture includes the insulation layer composition. 1. An insulation layer composition comprising a polyvinyl acetate emulsion resin , water , a gel forming agent and a hyaluronic acid diluent , wherein the gel forming agent is a mixture of glycerin and polyglycerol acrylate.2. The insulation layer composition of claim 1 , wherein a volume percent concentration (V/V) of the hyaluronic acid diluent is 1%.3. The insulation layer composition of claim 2 , wherein the polyvinyl acetate emulsion resin claim 2 , the water claim 2 , the gel forming agent and the hyaluronic acid diluent are mixed in a weight ratio of 2:1:0.5:0.5 to 2:2:1:1.4. The insulation layer composition of claim 3 , wherein the polyvinyl acetate emulsion resin claim 3 , the water claim 3 , the gel forming agent and the hyaluronic acid diluent are mixed in a weight ratio of 2:1:0.5:1.5. The insulation layer composition of claim 3 , wherein the polyvinyl acetate emulsion resin claim 3 , the water claim 3 , the gel forming agent and the hyaluronic acid diluent are mixed in a weight ratio of 2:1:0.5:0.5.6. The insulation layer composition of claim 3 , wherein the polyvinyl acetate emulsion resin claim 3 , the water claim 3 , the gel forming agent and the hyaluronic acid diluent are mixed in a weight ratio of 2:1.5:0.7:0.6.7. An insulation layer for a plant tissue culture claim 3 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the insulation layer composition of .'}8. The insulation layer for the plant tissue culture of claim 7 , wherein the insulation layer is used to isolate a medium from contact with a source of ...

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21-03-2019 дата публикации

Water Borne Coating Composition, Use of Such Composition, Method for Coating a Substrate Using Such Composition and Coated Substrates

Номер: US20190085180A1
Принадлежит:

The present invention is directed to a water borne coating composition. The composition according to the present invention comprises an emulsified binder, wherein the binder is a polymer selected from the group consisting of polymers prepared by emulsion polymerization of unsaturated vinyl, acrylate and/or methacrylate monomers, alkyd, polyurethane, and epoxy, 0.3% to 10% by weight of a second polymer selected from one or more of the group consisting of poly(vinyl alcohol) and water-soluble copolymers having repeat units of vinyl alcohol, wherein, if the second polymer is poly(vinyl alcohol), at least 85 wt % of the second polymer has a number of repeat units not less than 2,000, and 0% to 15% by weight of a cellulose-based filler, based on the total weight of the composition, wherein the weight ratio of second polymer to binder is in the range of from 1:100 to 1:1. The composition maybe used in various applications to form a decorative coating which has special visual and tactile effect. 2. The water borne coating composition according to claim 1 , wherein the weight percentage of the second polymer is within the range from 0.3% to 6% by weight based on the total weight of the composition.3. The water borne coating composition according to claim 1 , wherein the second polymer is a poly(vinyl alcohol) which has a number of repeat units of not less than 2 claim 1 ,000.4. The water borne coating composition according to claim 1 , wherein the second polymer is a poly(vinyl acetate-co-vinyl alcohol) with a mole percentage of vinyl alcohol of less than 70% claim 1 , and a number of repeat units of vinyl acetate and vinyl alcohol of at least 2 claim 1 ,000.5. The water borne coating composition according to claim 1 , wherein the cellulose-based filler is selected from the group consisting of microcrystalline cellulose claim 1 , regenerated cellulose claim 1 , and lignocellulose.6. The water borne coating composition according to claim 1 , wherein the cellulose-based ...

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02-04-2015 дата публикации

HASE RHEOLOGY MODIFIER VAE EMULSION COPOLYMER COMPOSITION

Номер: US20150094398A1
Принадлежит:

The present invention relates to a composition comprising a vinyl acetate copolymer and a HASE thickener comprising structural units of ethyl acrylate, methacrylic acid, acrylic acid, and a hydrophobic macromonomer. The composition of the present invention shows an improvement in heat aged stability over a vinyl acetate copolymer based paint thickened with a HASE that does not include structural units of acrylic acid. 1. A composition comprising an aqueous dispersion of a) a vinyl acetate copolymer having a Tin the range of −10° C. to 50° C. and b) a hydrophobically modified alkali soluble emulsion (HASE) comprising , based on the weight of the HASE: i) from 45 to 60 weight percent structural units of ethyl acrylate; ii) from 30 to 45 weight percent structural units of methacrylic acid; iii) from 2.0 to 20 weight percent structural units of acrylic acid; and iv) from 0.1 to 10 weight percent hydrophobic macromolecular groups.2. The composition of wherein the vinyl acetate copolymer is a VAE copolymer claim 1 , and wherein the HASE comprises from 2 to 15 weight percent structural units of acrylic acid and a total acid content of 40 to 48 weight percent claim 1 , based on the weight of the HASE.3. The composition of wherein the HASE comprises claim 2 , based on the weight of the HASE claim 2 , from 45 to 56 weight percent structural units of ethyl acrylate and from 4 to 11 weight percent structural units of acrylic acid.4. The composition of wherein the HASE comprises from 50 to 55 weight percent structural units of ethyl acrylate and from 8 to 11 weight percent structural units of acrylic acid claim 3 , each based on the weight of the HASE; and further comprises from 0.2 to 2 weight percent structural units of a sulfonic acid monomer or a salt thereof claim 3 , based on the weight of the HASE.5. The composition of wherein the sulfonic acid monomer is 2—(meth)acrylamido-2-methyl propanesulfonic acid or a salt thereof.6. The composition of wherein the total acid ...

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21-03-2019 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, TRANSFER FILM, MANUFACTURING METHOD OF PATTERN, DECORATIVE PATTERN, AND TOUCH PANEL

Номер: US20190086801A1
Принадлежит: FUJIFILM Corporation

Provided are a photosensitive resin composition including: a binder having an I/O value equal to or greater than 0.5 and a weight-average molecular weight equal to or smaller than 25,000; a pigment; a polymerizable monomer; and a polymerization initiator, in which a content of the pigment is equal to or greater than 20% by mass with respect to a total amount of solid contents of the photosensitive resin composition, a transfer film including a photosensitive resin layer including the solid contents of the photosensitive resin composition, a manufacturing method of a pattern using the photosensitive resin composition or the transfer film, a decorative pattern using the photosensitive resin composition or the transfer film, and a touch panel including the decorative pattern. 1. A photosensitive resin composition comprising:a binder having an I/O value equal to or greater than 0.5 and a weight-average molecular weight equal to or smaller than 25,000;a pigment;a polymerizable monomer; anda polymerization initiator,wherein a content of the pigment is equal to or greater than 20% by mass with respect to a total amount of solid contents of the photosensitive resin composition.2. The photosensitive resin composition according to claim 1 , wherein the pigment is a black pigment.3. The photosensitive resin composition according to claim 1 , wherein the polymerizable monomer includes a difunctional monomer.4. The photosensitive resin composition according to claim 3 , wherein a content of the difunctional monomer is equal to or greater than 50% by mass with respect to a total amount of the polymerizable monomer.5. The photosensitive resin composition according to claim 1 , wherein:the pigment is a black pigment, the polymerizable monomer includes a difunctional monomer; anda content of the difunctional monomer is equal to or greater than 50% by mass with respect to a total amount of the polymerizable monomer.6. The photosensitive resin composition according to claim 1 , ...

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21-03-2019 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, TRANSFER FILM, DECORATIVE PATTERN, AND TOUCH PANEL

Номер: US20190086802A1
Принадлежит: FUJIFILM Corporation

Provided are a photosensitive resin composition including: a binder; a polymerizable monomer; a polymerization initiator; a pigment; and a solvent, in which the polymerizable monomer includes a difunctional polymerizable monomer having a molecular weight equal to or smaller than 500, and a content of the difunctional polymerizable monomer having a molecular weight equal to or smaller than 500 is equal to or greater than 50% by mass with respect to a total mass of the polymerizable monomer, a transfer film, a decorative pattern, and a touch panel. 1. A photosensitive resin composition comprising:a binder;a polymerizable monomer;a polymerization initiator;a pigment; anda solvent,wherein the polymerizable monomer includes a difunctional polymerizable monomer having a molecular weight equal to or smaller than 500, anda content of the difunctional polymerizable monomer having a molecular weight equal to or smaller than 500 is equal to or greater than 50% by mass with respect to a total mass of the polymerizable monomer.2. The photosensitive resin composition according to claim 1 ,wherein the pigment is a black pigment.3. The photosensitive resin composition according to claim 2 ,wherein the black pigment is carbon black.4. The photosensitive resin composition according to claim 1 ,wherein a ratio of a content mass of the polymerizable monomer with respect to a content mass of the binder is 0.10 to 0.50.5. The photosensitive resin composition according to claim 1 ,wherein a ratio of a content mass of the polymerizable monomer with respect to a content mass of the binder is 0.32 to 0.36.6. The photosensitive resin composition according to claim 1 ,wherein a weight-average molecular weight of the binder is 5,000 to 15,000.7. The photosensitive resin composition according to claim 1 ,wherein the binder is at least one selected from the group consisting of a random copolymer of benzyl (meth)acrylate/(meth)acrylic acid, a random copolymer of styrene/(meth)acrylic acid, a ...

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30-03-2017 дата публикации

POLARIZER, POLARIZING PLATE, AND IMAGE DISPLAY APPARATUS

Номер: US20170090085A1
Принадлежит: NITTO DENKO CORPORATION

There is provided a polarizer that can realize multi-functionalization and high-functionalization of an electronic device, such as an image display apparatus. A polarizer according to an embodiment of the present invention includes a resin film containing iodine, wherein the polarizer has formed therein a transparent portion having a transmittance higher than that of another portion, and the transparent portion has a single hue (a+b)of less than 1.0, where the a represents an a value of an Lab colorimetric system and the b represents a b value of the Lab colorimetric system. 1. A polarizer , comprising a resin film containing iodine , wherein the polarizer has formed therein a transparent portion having a transmittance higher than that of another portion , and the transparent portion has a single hue (a+b)of less than 1.0 , where the a represents an a value of an Lab colorimetric system and the b represents a b value of the Lab colorimetric system.2. The polarizer according to claim 1 , wherein the transparent portion has an iodine content of 1.0 wt % or less.3. The polarizer according to claim 1 , wherein the transparent portion has a content of at least one of an alkali metal and an alkaline earth metal of 0.5 wt % or less.4. The polarizer according to claim 1 , wherein the resin film has a thickness of 8 μm or less.5. The polarizer according to claim 1 , wherein optical characteristics in the another portion satisfy relationships of P>-(10−1)×100 claim 1 , provided that T<42.3 claim 1 , and P≧99.9 claim 1 , provided that T≧42.3 claim 1 , where P represents a polarization degree (%) and T represents a single axis transmittance (%).6. The polarizer according to claim 1 , wherein the transparent portion corresponds to a camera portion of an image display apparatus on which the polarizer is mounted.7. A method of producing the polarizer of claim 1 , the method comprising decolorizing a desired portion of a resin film containing a dichromatic substance.8. The ...

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29-03-2018 дата публикации

BACK SHEET OF SOLAR CELL MODULE, AND SOLAR CELL MODULE

Номер: US20180090632A1
Принадлежит: DAIKIN INDUSTRIES, LTD.

The invention provides a back sheet including a water-impermeable sheet and a film firmly bonded to each other and exhibiting excellent adhesiveness to an EVA encapsulant layer of a solar cell module even without corona discharge treatment on the film surface. The back sheet of the invention is a back sheet for solar cell module, including a water-impermeable sheet and a film. The film is disposed on at least one side of the water-impermeable sheet and is formed from a coating containing a fluorine-containing copolymer. The fluorine-containing copolymer contains a C2-C3 perhaloolefin structural unit, a vinyl acetate structural unit, a hydroxy-containing vinyl monomer structural unit, and a carboxy-containing monomer structural unit. 2. The back sheet according to claim 1 ,wherein in the formula (1), 1 is 0 and m is 2 or 4.3. The back sheet according to claim 1 ,wherein in the formula (2), n is 0 to 20.4. The back sheet according to claim 1 ,wherein the fluorine-containing copolymer contains:15 to 50 mol % of the structural unit (a);20 to 75 mol % of the structural unit (b);5 to 22 mol % of the structural unit (c); and0.1 to 5 mol % of the structural unit (d).5. The back sheet according to claim 1 ,wherein the fluorine-containing copolymer further contains, as a monomer structural unit (e), a non-aromatic vinyl ester structural unit other than the vinyl acetate structural unit.6. The back sheet according to claim 1 ,wherein the fluorine-containing copolymer has a number average molecular weight of 3,000 to 100,000.7. The back sheet according to claim 1 ,wherein the proportion of the structural unit (a) to the sum of the moles of the structural unit (a) and the structural unit (b) is 0.16 to 0.51 in the fluorine-containing copolymer.8. The back sheet according to claim 1 ,wherein the coating further contains an organic solvent.9. The back sheet according to claim 1 ,wherein the coating further contains a curing agent.10. A solar cell module comprising:a solar cell;an ...

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19-03-2020 дата публикации

CURABLE COMPOSITION, FILM, NEAR INFRARED CUT FILTER, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, AND INFRARED SENSOR

Номер: US20200087424A1
Автор: MIYATA Tetsushi
Принадлежит: FUJIFILM Corporation

A curable composition includes: a near infrared absorbing colorant; a polymerizable monomer that has a group including an ethylenically unsaturated bond; a resin; and a radical polymerization initiator, in which a content of the near infrared absorbing colorant is 10 mass % or higher with respect to a total solid content of the curable composition and a content of the polymerizable monomer that has at least one group selected from an acid group or a hydroxyl group and a group having an ethylenically unsaturated bond is higher than 50 mass % with respect to a total mass of all the polymerizable monomers. A near infrared cut filter, a solid image pickup element, an image display device, and an infrared sensor include a film which is formed using the curable composition. 1. A curable composition comprising:a near infrared absorbing colorant;a polymerizable monomer that has a group including an ethylenically unsaturated bond;a resin; anda radical polymerization initiator,wherein the near infrared absorbing colorant is a compound that includes a π-conjugated plane having a monocyclic or fused aromatic ring,the polymerizable monomer includes a polymerizable monomer MA that has a group including an ethylenically unsaturated bond and at least one group selected from the group consisting of an acid group and a hydroxyl group,a content of the near infrared absorbing colorant is 10 mass % or higher with respect to a total solid content of the curable composition,a content of the polymerizable monomer MA is higher than 50 mass % with respect to a total mass of all the polymerizable monomers, and{'sub': 1', '2', '1', '2, 'the curable composition has a maximum absorption in a wavelength range of 700 to 1300 nm and a ratio A/Aof a maximum value Aof an absorbance in a wavelength range of 400 to 600 nm to an absorbance Aat the maximum absorption is 0.3 or lower.'}2. The curable composition according to claim 1 ,wherein the polymerizable monomer includes a compound that has three or ...

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12-05-2022 дата публикации

Powder paint composition which can be redispersed in water

Номер: US20220145093A1
Принадлежит: Wacker Chemie AG

A powder paint composition. The powder paint composition contains (a) at least one polymer powder which can be re-dispersed in water, (b) pigment and filler, and optionally (c) which may be one or more adjuvants and/or may be one or more hydraulic binders. The at least one polymer powder which can be re-dispersed in water contains a polyvinyl alcohol-stabilized copolymer that is based on (a1) a wt % of a vinyl acetate, (a2) a wt % of ethylene and optionally (a3) and/or (a4) wherein (a3) is vinyl esters of long-chain, optionally branched Cto Ccarboxylic acids and (a4) is further ethylenically unsaturated comonomers that are co-polymerizable therewith. 110-. (canceled)11. A powder paint composition , comprising:wherein the powder paint composition comprises a) at least one water-redispersable polymer powder, b) a pigment and a filler, and c) optionally one or more adjuvants and/or optionally one or more hydraulic binders;{'sub': 3', '12, 'wherein the water-redispersable polymer powder comprises a) a polyvinyl alcohol-stabilized copolymer based on a1) approximately 50 to approximately 95 wt % of vinyl acetate, a2) approximately 1 to approximately 30 wt % of ethylene, a3) 0 to approximately 20 wt % of vinyl esters of long-chain, optionally branched Cto Ccarboxylic acids, a4) 0 to approximately 10 wt % of further ethylenically unsaturated comonomers co-polymerizable therewith, wherein the amounts in wt % adding up in each case to 100 wt %;'}wherein the polyvinyl alcohol comprises a mixture of at least one polyvinyl alcohol having a degree of hydrolysis of approximately 80 to approximately 95 mol % and a Höppler viscosity (4% aqueous solution, Höppler method at 20° C., DIN 53015) of approximately 1 to approximately 5 mPas and at least one polyvinyl alcohol having a degree of hydrolysis of approximately 80 to approximately 95 mol % and a Höppler viscosity of 6 to 40 mPas; andwherein a powder paint composition having one or more hydraulic binders therein comprises ...

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26-06-2014 дата публикации

POLYOXYALKYLENE MODIFIED VINYL ALCOHOL-BASED POLYMER AND USE THEREOF

Номер: US20140178609A1
Принадлежит: KURARAY CO., LTD.

Provided is a polyoxyalkylene modified vinyl alcohol-based polymer comprising a polyoxyalkylene group in a side chain, wherein the polymer has a viscosity average degree of polymerization of not less than 150 and not more than 5000, a degree of saponification of not less than 40 mol % and not more than 99.99 mol %, and a polyoxyalkylene group modification rate of not less than 0.05 mol % and not more than 10 mol %; and the polyoxyalkylene group is composed of a polyoxypropylene block and a (poly)oxyethylene block and is represented by the following general formula (I). Such polymer is excellent in temperature-sensitive thickening properties. 2. The polyoxyalkylene modified vinyl alcohol-based polymer according to claim 1 , wherein claim 1 , when measuring viscosity of a 4 mass % aqueous solution of the polyoxyalkylene modified vinyl alcohol-based polymer with a BL type viscometer at a rotor rotation speed of 6 rpm claim 1 , a viscosity ratio η/η claim 1 , where ηis a viscosity at 60° C. and ηis a viscosity at 20° C. claim 1 , is 2.0 or more.3. An aqueous solution comprising the polyoxyalkylene modified vinyl alcohol-based polymer according to .5. A coating agent comprising the polyoxyalkylene modified vinyl alcohol-based polymer according to .6. A coated article claim 5 , wherein the coating agent according to is coated on a surface of a substrate.7. A method of producing the coated article according to claim 6 , the method comprising:coating the coating agent on the surface of the substrate having a previously adjusted temperature of not less than 50° C. and not more than 100° C.8. An ink jet recording material claim 5 , wherein the coating agent according to is coated on a surface of a substrate.9. A thermal paper claim 1 , comprising the polyoxyalkylene modified vinyl alcohol-based polymer according to .10. A release paper base paper comprising the polyoxyalkylene modified vinyl alcohol-based polymer according to .11. The release paper base paper according to ...

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28-03-2019 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, TRANSFER FILM, DECORATIVE PATTERN, TOUCH PANEL, AND MANUFACTURING METHOD OF PATTERN

Номер: US20190094693A1
Принадлежит: FUJIFILM Corporation

Provided are a photosensitive resin composition including a binder having a weight-average molecular weight of 4,000 to 25,000, a polymerization initiator having a content greater than 0% by mass and smaller than 9% by mass with respect to a total amount of solid contents of the composition, a polymerizable monomer, and a pigment, a transfer film, a decorative pattern, a touch panel, and a manufacturing method of a pattern. 1. A photosensitive resin composition comprising:a binder having a weight-average molecular weight of 4,000 to 25,000;a polymerization initiator having a content greater than 0% by mass and smaller than 9% by mass with respect to a total amount of solid contents of the composition;a polymerizable monomer; anda pigment.2. The photosensitive resin composition according to claim 1 ,wherein the pigment is a black pigment.3. The photosensitive resin composition according to claim 1 ,wherein a ratio of a content mass of the polymerizable monomer with respect to a content mass of the binder is 0.10 to 0.50.4. The photosensitive resin composition according to claim 1 ,wherein a ratio of a content mass of the polymerizable monomer with respect to a content mass of the binder is 0.32 to 0.40.5. The photosensitive resin composition according to claim 1 ,wherein the polymerizable monomer includes a difunctional polymerizable monomer.6. The photosensitive resin composition according to claim 5 ,wherein a percentage of a mass of the difunctional polymerizable monomer with respect to a total mass of the polymerizable monomer is equal to or greater than 50% by mass.7. The photosensitive resin composition according to claim 1 ,wherein the pigment is a black pigment, a ratio of a content mass of the polymerizable monomer with respect to a content mass of the binder is 0.10 to 0.50, the polymerizable monomer includes a difunctional polymerizable monomer, and a percentage of a mass of the difunctional polymerizable monomer with respect to a total mass of the ...

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13-04-2017 дата публикации

WOOD PRESERVATION PRODUCTS PROTECTED WITH A DURABLE COATING SYSTEM

Номер: US20170101542A1
Автор: LU ZIQIANG
Принадлежит:

A crosslinking polyvinyl acetate (XPVAc or X-PVAc) adhesive is applied as a primer (i.e., a basecoat) or an exterior coat (i.e., a top coat) on a wood preservation product which is mainly treated with a water-based preservative. By sealing the exterior wood surfaces, the new coating system not only effectively prevents the leaching of the preservative by bonding and chelating with the unfixed preservative compounds or complexes at the surface layer, but it also significantly reduces surface aging of wood, maintains effective preservation functions, and provides a longer service life to the wood preservation product. 1. A chemical preservative composition for wood comprising:a water-based biocide, selected from the group consisting of a waterborne biocide, a water-dispersible biocide, or the combination thereof;said composition further including a crosslinking polyvinyl acetate protective coating which may be applied to bond and seal wood surfaces;said crosslinking polyvinyl acetate protective coating chelating with the active water-based biocide;wherein the crosslinking polyvinyl acetate protective coating at least consists of a polyvinyl acetate-based adhesive resin, a crosslinking agent, and a catalyst before being cured; andwherein the protective coating has a minimum Fruehauf wet shear strength of 325 psi when applied to wood and cured.2. The chemical preservative composition of claim 1 , wherein the biocide is a copper- claim 1 , chromium- claim 1 , arsenic- claim 1 , zinc- claim 1 , tin- claim 1 , or titanium-based compound or complex claim 1 , a boron- claim 1 , nitrogen- claim 1 , sulfur- claim 1 , chloride- claim 1 , phosphate- claim 1 , or silicate-based compound or complex claim 1 , or the combination thereof;3. The chemical preservative composition having a minimum biocide retention of 0.005 lb. per cubic foot.4. The chemical preservative composition of claim 1 , wherein said crosslinking polyvinyl acetate adhesive has a solid content of at least 20% by ...

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23-04-2015 дата публикации

ADSORBING VINYL ACETATE BINDERS

Номер: US20150112016A1
Принадлежит:

The present invention relates to a composition comprising and a method for preparing a stable aqueous dispersion of polymer particles comprising structural units of vinyl acetate and a phosphorous acid monomer. The composition of the present invention provides vinyl acetate/phosphorus acid based polymer particles that improve hiding efficiency in pigmented coatings formulations. 1. A composition comprising a stable aqueous dispersion of polymer particles comprising , based on the weight of the polymer , from 35 to 99.8 weight percent structural units of vinyl acetate and from 0.2 to 4 weight percent structural units of a phosphorus acid monomer or a salt thereof.2. The composition of which is further characterized by having less than 5.0 percent by weight acetic acid or a salt thereof based on the weight of structural units of vinyl acetate.3. The composition of wherein the polymer particles further comprise from 0.1 to 2.0 weight percent claim 2 , based on the weight of the polymer particles claim 2 , structural units of a sulfur acid monomer and wherein the stable aqueous dispersion is further characterized by having less than 1.0 percent by weight acetic acid or a salt thereof based on the weight of structural units of vinyl acetate.4. The composition of wherein the polymer particles further comprise claim 3 , based on the weight of the polymer claim 3 , from 10 to 64.8 weight percent structural units of an acrylate monomer and wherein the structural units of the sulfur acid monomer are structural units 2-acrylamido-2-methylpropane sulfonic acid or sodium vinyl sulfonate or a salt thereof or a combination thereof.5. The composition of wherein the acrylate monomer is ethyl acrylate claim 4 , butyl acrylate claim 4 , or 2-ethylhexyl acrylate claim 4 , or a combination thereof.6. The composition of wherein the polymer particles comprise from 30 to 40 weight percent structural units of butyl acrylate claim 1 , based on the weight of the polymer.7. The composition of ...

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20-04-2017 дата публикации

Aqueous vinyl acetate ethylene copolymer dispersion for paper coating

Номер: US20170107394A1
Принадлежит: Wacker Chemie AG

The invention relates to a polymer dispersion for paper coating compositions obtainable by means of a radically initiated, aqueous emulsion polymerization of a) 60 to 97% by weight of vinyl acetate, b) 2 to 30% by weight of ethylene, c) 0.5 to 5% by weight of at least one ethylenically unsaturated silane monomer, d) 0.5 to 5% by weight of at least one ethylenically unsaturated carboxylic acid, based in each case on the total weight of the monomers used for the polymerization, and the data in % by weight summing in each case to 100% by weight, in the presence of one or more polymeric emulsifiers.

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20-04-2017 дата публикации

POROUS COATINGS

Номер: US20170108148A1
Принадлежит:

A porous metallic coating is provided. The coating is characterized by a combination of optimized properties that improve coating performance, as measured by heat transfer efficiency. The porous coating has optimal ranges for properties such as porosity, particle size and thickness, and has particular applicability in boiling heat transfer applications as part of an air separations unit. The porous coatings are derived from slurry-based formulations that include a mixture of metallic particles, a binder and a solvent. 1. A porous coating applied onto a substrate , comprising:metallic particles comprising aluminum, magnesium and tin, wherein the aggregate amount of magnesium and tin is not greater than 15 wt %, based on the weight of the porous coating, and the balance is aluminum;wherein the porous coating has an average particle diameter ranging from about 35 to about 55 μm;a thickness ranging from about 300 to about 400 μm;a median pore diameter ranging from about 7 to about 12 μm; andan overall porosity ranging from about 40% to about 60% based on the overall volume of the coating.2. The porous coating of claim 1 , characterized by the absence of a fugitive.3. The porous coating of claim 1 , further comprising:said average particle diameter ranges from about 38 to about 43 μm;said median pore diameter ranging from about 7 to about 10 μm; andan overall porosity ranging from about 40% to about 55% based on the overall volume of the coating.4. The porous coating of claim 1 , wherein the Mg ranges from about 0.1 wt % to about 10 wt % claim 1 , the Sn ranges from about 0.1 wt % to about 5 wt %.5. The porous coating of claim 1 , wherein the substrate is a surface of an inner diameter of a heat exchanger tube.6. The porous of coating of claim 5 , wherein said heat exchanger tube is utilized for boiling surfaces.7. The porous coating of claim 6 , wherein said heat exchanger tube is part of a main condenser of an air separations system.8. The porous coating of claim 1 , ...

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28-04-2016 дата публикации

DURABLE, WATER RESISTANT WOOD AND WOOD COMPOSITES

Номер: US20160115337A1
Автор: LU ZIQIANG
Принадлежит:

The invention provides a novel product and method to coat wood and wood composite products and improves their durability and service life in outdoor conditions. The method comprises coating a Type I waterborne adhesive, crosslinking polyvinyl acetate (XPVAc or x-PVAc), on wood and applying sufficient heat to dry and cure the coating to form a durable bond on wood or wood composites. The above paint system consists of at least two coating layers, in which both layers are crosslinking polyvinyl acetate coating. Alternatively, crosslinking polyvinyl acetate can be used as a primer, while the second or the third layer uses an acrylic, alkyd, or other water resistant coating. This coating approach results in a durable wood or wood composite product due to the excellent bonding with the wood substrate and the excellent water blocking by crosslinking polyvinyl acetate. 1. A crosslinked waterproofing composition for application to an exterior surface of a wood member comprising:a) a crosslinking polyvinyl acetate adhesive;b) a catalyst selected from the group consisting of chromium nitrate, aluminum nitrate, aluminum chloride, iron trichloride, zirconium nitrate and potassium bichromate;c) a crosslinking agent; andd) a colorant;wherein the composition has a minimum Fruehauf wet shear strength of 325 psi when applied to wood and cured.2. The waterproofing composition of wherein said catalyst is less than or equal to 10% by weight of catalyst.3. The waterproofing composition of wherein said catalyst is between about 4% to about 6% by weight of catalyst.4. The waterproofing composition of further including a stabilizer or a surfactant.5. The waterproofing composition of wherein said colorant is carbon black.6. The waterproofing composition of wherein said crosslinking polyvinyl acetate adhesive has a solid content of about 40% to about 60% by weight.7. The waterproofing composition of wherein said crosslinking polyvinyl acetate adhesive has a minimum Fruehauf wet shear ...

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27-04-2017 дата публикации

INSECTICIDE-CONTAINING COATING COMPOSITION AND METHOD FOR PROTECTING PALM TREES FROM PESTS

Номер: US20170112126A1
Принадлежит: Sabic Global Technologies B.V.

A palm plant treatment method, palm plant treatment layer, palm plant treatment composition and method of making the palm plant treatment composition that relates to a layer comprising an insecticide and a polymeric adhesive present on a palm plant surface that is effective for treating or preventing infestation of the palm plant by a pest without the insecticide entering the vascular system of the palm plant. 1. A palm plant treatment method , comprising:applying a composition comprising an insecticide and a polymeric adhesive to an exterior surface of a palm plant to form an insecticide-containing layer comprising a homogenous mixture of the insecticide and the polymeric adhesive which is in direct contact with the surface of the palm plant,wherein the insecticide-containing layer is effective for treating or preventing infestation of the palm plant by a pest without the insecticide entering the vascular system of the palm plant.2. The method of claim 1 , wherein the composition further comprises a repellant and the applying forms an insecticide-containing layer further comprising the repellant.3. The method of claim 1 , wherein the insecticide-containing layer remains on the surface of the palm plant for at least 3 months during which there is no infestation of the palm tree by the pest.4. The method of claim 1 , wherein the insecticide is selected from the group consisting of tefluthrin and chlorpyrifos.5. The method of claim 1 , wherein the pest is a red palm weevil and the palm plant is a palm tree.6. The method of claim 1 , wherein the polymeric adhesive is selected from the group consisting of polyvinyl acetate and raw linseed oil.7Phoenix dactyliferaPhoenix canariensis.. The method of claim 1 , wherein the palm plant is selected from the group consisting of and8. The method of claim 1 , wherein the insecticide-containing layer continuously covers the severed and live leaf bases and petiole bases of the palm plant.9. The method of claim 1 , wherein the ...

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26-04-2018 дата публикации

COMPOSITE SYSTEM COMPRISING A MATRIX AND SCATTERING ELEMENTS, PROCESS FOR PREPARING IT AND USE THEREOF

Номер: US20180112111A1
Принадлежит:

A composite system for light diffusion comprises a matrix of a material that is transparent to light; the matrix contains a dispersion of scattering elements having a core that is a nanocluster of inorganic nanoparticles, and a shell comprising silane compounds and dispersing agents; the nanocluster having average dimensions in the range of 20 nm to 300 nm. 1. A composite system , comprising a matrix wherein a plurality of scattering elements is dispersed , wherein said matrix is of a material that per se is transparent and does not absorb light , said scattering elements have a core , said core having a refractive index that is different from the refractive index of the matrix to provide a scattering of at least a portion of the light transmitted through said system , characterized in that said core comprises a nanocluster of inorganic nanoparticles , said nanocluster having average dimensions in the range of 20 nm to 300 nm , and wherein said scattering elements further comprise at least a silane compound and at least a dispersing agent that provide at least part of a shell for said nanocluster core.2. A composite system according to claim 1 , wherein said matrix is a polymer matrix.3. A composite system according to claim 2 , wherein said scattering elements are free from a shell made of the same polymer of the polymer matrix.4. A composite system according to or claim 2 , wherein said inorganic material is selected from TiO claim 2 , SiO claim 2 , ZnO claim 2 , ZrO claim 2 , FeO claim 2 , AlO claim 2 , SbSnO claim 2 , BiO claim 2 , CeO claim 2 , preferably from ZnO and TiO5. A composite system according to any to claim 2 , wherein the average dimension of said nanoclusters is comprised in the range of 20 nm to 300 nm claim 2 , preferably in the range of 50 nm to 200 nm claim 2 , more preferably in the range of 80 nm to 130 nm.6. A composite system according to claim 5 , comprising scattering elements having a core comprising a single nanoparticle and having a ...

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09-06-2022 дата публикации

BUILDING PANEL COATINGS

Номер: US20220177710A1
Принадлежит:

Described herein are panel coating compositions, building panel and a ceiling panel assembly having such coating compositions. The coating compositions are useful in obtaining stable and splotch-free finished paint on large panels. 1. A building panel coating composition comprising calcium carbonate , aluminum hydroxide , zinc borate , a rheology modifier , a defoamer , a dispersing agent , a whitening pigment , and an anionic wax emulsion.2. The building panel coating composition of wherein the rheology modifier is non-ionic claim 1 , water-soluble hydroxyethylcellulose surface-treated with glyoxal.3. The building panel coating composition of wherein the rheology modifier is present in an amount of about 0.002% to about 0.08% claim 1 , about 0.002% to about 0.04% claim 1 , about 0.002% to about 0.01% claim 1 , or about 0.002% to about 0.008% claim 1 , by weight of the composition.4. The building panel coating composition of wherein the defoamer is a polyether siloxane copolymer.5. The building panel coating composition of wherein the polyether siloxane copolymer comprises fumed silica.6. The building panel coating composition of wherein the defoamer is present in an amount of about 0.08% to about 0.3% claim 1 , about 0.1% to about 0.25% claim 1 , or about 0.1% to about 0.2% claim 1 , by weight of the composition.7. The building panel coating according to claim 1 , wherein the dispersing agent is a nonionic dispersant copolymer.8. The building panel coating according to claim 1 , wherein the dispersing agent is present in an amount of about 1.0% to about 3.0% claim 1 , about 1.0% to about 2.0% claim 1 , or about 1.0% to about 1.5% claim 1 , by weight of the composition.9. The building panel coating composition according to claim 1 , wherein the whitening pigment is titanium dioxide.10. (canceled)11. The building panel coating composition according to claim 1 , wherein the anionic wax emulsion comprises paraffin claim 1 , polyethylene claim 1 , or a combination ...

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09-06-2022 дата публикации

INTUMESCENT FIRE-RETARDANT COATING WITH ULTRA-HIGH CORROSION RESISTANCE AND PREPARATION METHOD THEREOF

Номер: US20220177713A1
Принадлежит:

Disclosed are an intumescent fire-retardant coating with ultra-high corrosion resistance and a preparation method thereof. The fire-retardant coating is composed by water, wetting and dispersing agent, defoaming agent, composite carbon-forming catalyst, composite blowing agent, pentaerythritol, titanium dioxide, Mg(OH), mica powder, kaolin, anti-rust pigment, aluminum tripolyphosphate, VAE emulsion, freeze-thaw agent, film-forming aid, and thickener. On the basis of the existing fire-retardant coatings, the present disclosure adds a series of anti-corrosion, heat insulation fillers and salt spray resistance additives to achieve a certain salt spray resistance effect. The fire-retardant coating of the present disclosure has both fire-retardant and anticorrosive functions, does not contain organic solvents, is low in price, has high construction tolerance, and has broad application prospects in the field of intumescent fire-retardant coatings. 1. An intumescent fire-retardant coating with ultra-high corrosion resistance , wherein comprising the following components and mass ratios:water 13-20;wetting and dispersing agent 0.3-0.6;defoaming agent 0.2-0.5;composite carbon-forming catalyst 12-20;composite blowing agent 6-10;pentaerythritol 6-10;titanium dioxide 3-6;{'sub': '2', 'Mg(OH)4-8;'}mica powder 3-6;kaolin 3-7;anti-rust pigment 3-7;aluminum tripolyphosphate 4-7;vinyl acetate-ethylene (VAE) emulsion 11-21;freeze-thaw agent 0.6-0.8;film-forming aid 1.0-1.8; 'the composite carbon-forming catalyst is a mixture of ammonium polyphosphate and calcium phytate, and the mass ratio of the ammonium polyphosphate and calcium phytate is 2:1; and the composite blowing agent is a mixture of melamine and chlorinated paraffin, and the mass ratio of melamine and chlorinated paraffin is 2:1.', 'thickener 0.2-0.5;'}2. The intumescent fire-retardant coating with ultra-high corrosion resistance according to claim 1 , wherein claim 1 ,the wetting and dispersing agent is an ammonium ...

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07-05-2015 дата публикации

CARPET COATING COMPOSITIONS OF VINYL ACETATE HAVING IMPROVED WET AND/OR DRY STRENGTH

Номер: US20150125649A1
Принадлежит:

A latex coating composition for a carpet product comprising a first polymer formed from one or more monomers selected from the group consisting of vinyl esters of a C-Calkanoic acid, ethylenically unsaturated carboxylic acids, esters of ethylenically unsaturated carboxylic acids, vinylaromatics, and vinyl halides and a second polymer formed from an α-olefin and an ethylenically unsaturated carboxylic acid. External crosslinker may also be used in the latex coating composition. The second polymer, preferably ethylene/acrylic acid, may be present in an amount from 1 to 10 parts of the second polymer per 100 parts of the total polymer. 1. A carpet product comprising at least one substrate and at least one adhesive layer adhered to the at least one substrate , the adhesive layer being formed from a latex coating composition comprising:{'sub': 1', '18, 'a first polymer formed from one or more monomers selected from the group consisting of vinyl esters of a C-Calkanoic acid, ethylenically unsaturated carboxylic acids, esters of ethylenically unsaturated carboxylic acids, vinylaromatics, and vinyl halides;'}a second polymer formed from an α-olefin and ethylenically unsaturated carboxylic acids; andat least one external crosslinker.2. The carpet product of claim 1 , wherein the composition comprises from 50 to 500 parts filler per 100 parts of the total polymer.4. The carpet product of claim 1 , wherein the first polymer comprises at least one vinyl monomer of a vinyl ester of a C-Calkanoic acid or vinylaromatic.5. The carpet product of claim 1 , wherein the first polymer comprises a vinyl ester of a C-Calkanoic acid claim 1 , and an α-olefin.6. The carpet product of claim 5 , wherein the α-olefin is ethylene and the first polymer comprises from 2 to 30 parts per hundred of ethylene based on total monomers in the first polymer.7. The carpet product of claim 1 , wherein the second polymer comprises an ethylene acrylic acid polymer claim 1 , and wherein the ethylene acrylic ...

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07-05-2015 дата публикации

Polymer Latex Blends and Applications Thereof

Номер: US20150125711A1
Принадлежит:

Disclosed are blended latex dispersions which can be used as binders in paper coating compositions. Such latex dispersions comprise a first copolymer of a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms and ethylene; and a second copolymer of (i) styrene and butadiene, (ii) styrene, butadiene and acrylonitrile, or (iii) styrene and an acrylic monomer, wherein the first and second copolymers are colloidally dispersed in an aqueous medium comprising a surfactant. The paper coating compositions containing latex dispersion binders of this type preferably exhibit especially desirable coating strength as quantified by the Dry Pick Values which such compositions provide. 1. A latex dispersion , comprising:(a) a first copolymer of a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms and ethylene; and(b) a second copolymer of (i) styrene and butadiene, (ii) styrene, butadiene and acrylonitrile, or (iii) styrene and an acrylic monomer, wherein the first and second copolymers are colloidally dispersed in an aqueous medium comprising a surfactant, wherein the first copolymer has an average particle size from 100 to 300 nm, as determined by Laser Aerosol Spectroscopy.2. The dispersion of claim 1 , comprising less than 1.0 pphm polyvinyl alcohol.3. The dispersion of claim 1 , comprising less than 0.5 pphm polyvinyl alcohol.4. The dispersion of claim 1 , comprising less than 1.0 wt. percent polyvinyl alcohol claim 1 , based on the total weight of all monomers.5. (canceled)6. The dispersion of claim 1 , wherein the second copolymer is a copolymer of styrene and butadiene claim 1 , the first copolymer is present in an amount from 70 to 95 wt. % claim 1 , and the second copolymer is present in an amount from 5 to 30 wt. %.7. The dispersion of claim 1 , wherein the first copolymer is present in an amount from 40 to 99 wt. % and the second copolymer is present in an amount from 1 to 60 wt. %.8. The dispersion of claim 1 , wherein the first copolymer is ...

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25-04-2019 дата публикации

POLYVINYL ALCOHOL AND METHOD FOR PRODUCING SAME

Номер: US20190119414A1
Принадлежит:

A polyvinyl alcohol is produced in a method comprising: a polymerization step comprising polymerizing vinyl ester monomers by controlled radical polymerization in the presence of a radical initiator and an organic cobalt complex to obtain a polymer solution containing a polyvinyl ester; an extraction step comprising extracting a cobalt complex from the polymer solution by contacting an aqueous solution containing a water-soluble ligand with the polymer solution; and a saponification step comprising saponifying the polyvinyl ester after the extraction step to obtain a polyvinyl alcohol. A method for producing a polyvinyl alcohol is thus provided that has a narrow molecular weight distribution and a high number-average molecular weight with good hue and further good solubility in water. 1. A method for producing a polyvinyl alcohol , the method comprising:polymerizing vinyl ester monomers by controlled radical polymerization in the presence of a radical initiator and an organic cobalt complex to obtain a polymer solution comprising a polyvinyl ester;extracting a cobalt complex from the polymer solution by contacting an aqueous solution comprising a water-soluble ligand with the polymer solution; andsaponifying the polyvinyl ester after the extracting to obtain the polyvinyl alcohol.2. The method of claim 1 , wherein the polyvinyl ester after the extracting has a cobalt element content from 0.01 to 100 ppm.3. The method of claim 1 , wherein the polyvinyl alcohol after the saponifying has a cobalt element content from 0.01 to 50 ppm.4. The method of claim 1 , wherein the water-soluble ligand is an acid having a pKa at 25° C. from 0 to 12.5. The method of claim 1 , wherein the water-soluble ligand is carboxylic acid.6. A polyvinyl alcohol having a number-average molecular weight (Mn) from 4 claim 1 ,400 to 440 claim 1 ,000 claim 1 , a molecular weight distribution (Mw/Mn) from 1.05 to 1.70 claim 1 , a degree of saponification from 80 to 99.99 mol % claim 1 , and a cobalt ...

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16-04-2020 дата публикации

METHOD FOR PRODUCING ORGANIC-INORGANIC HYBRID HYDROGEL

Номер: US20200115474A1
Автор: TAKEHISA Toru
Принадлежит:

A method for producing an organic-inorganic hybrid hydrogel includes mixing an aqueous solution (A) containing a water-soluble organic monomer (a1) and a phosphonic acid-modified hectorite (a2), a polymerization initiator (B), and a polymerization promotor (C) with each other. The aqueous solution (A) has a viscosity of 1,000 mPa·s or less when stored at 50° C. for one week after preparation. The polymerization initiator (B) has a solubility of 50 g/100 ml or more in water at 20° C. The molar ratio [(B)/(a1)] of the polymerization initiator (B) to the water-soluble organic monomer (a1) is in the range of 0.01 to 0.1. The aqueous solution in the state immediately before being subjected to polymerization can be stored for a long term, and thus has excellent operation properties and has no restriction on the place where a hydrogel is produced, and therefore can be applied to various industrial uses. 1a step of mixing an aqueous solution (A) containing a water-soluble organic monomer (a1) and a phosphonic acid-modified hectorite (a2), a polymerization initiator (B), and a polymerization promotor (C) with each other, whereinthe aqueous solution (A) has a viscosity of 1,000 mPa·s or less when stored at 50° C. for one week after preparation,the polymerization initiator (B) has a solubility of 50 g/100 ml or more in water at 20° C., anda molar ratio [(B)/(a1)] of the polymerization initiator (B) to the water-soluble organic monomer (a1) is in a range of 0.01 to 0.1.. A method for producing an organic-inorganic hybrid hydrogel, comprising: The present invention relates to a method for producing an organic-inorganic hybrid hydrogel.A gel has intermediate properties between the properties of liquids and those of solids, and is in a stable state such that it has a material, such as an organic polymer, constituting a three-dimensional network in a solvent, such as water. Particularly, a gel having water as a solvent is called a hydrogel, and the development of the use of a ...

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27-05-2021 дата публикации

THERMAL TRANSFER SHEET AND COMBINATION OF TRANSFER FOIL AND THERMAL TRANSFER SHEET

Номер: US20210154983A1
Автор: Iwasaki Yuki, Yoda Shinya
Принадлежит: Dai Nippon Printing Co., Ltd.

The present invention provides a thermal transfer sheet that can accurately remove a transfer layer, and a combination of a transfer foil and the thermal transfer sheet. A thermal transfer sheet comprising a peel-off layer on a substrate , wherein the peel-off layer (i) contains at least a vinyl chloride-type resin and an acrylic-type resin, and a mass of the vinyl chloride-type resin based on a total mass of the peel-off layer is more than 50% by mass and not more than 95% by mass, or the peel-off layer (ii) contains a polyester-type resin having a number average molecular weight (Mn) of not more than 17000, and having a glass transition temperature (Tg) of not less than 50° C. and not more than 120° C. 1. A thermal transfer sheet comprising:a substrate; anda peel-off layer affixed to the substrate,wherein a surface of the substrate is subjected to an adhesive treatment, or a primer layer is provided between the substrate and the peel-off layer,wherein the peel-off layer is not removed from the substrate, andwherein the peel-off layer contains a polyester-type resin having a number average molecular weight (Mn) of not more than 17000 and having a glass transition temperature (Tg) of not less than 50° C. and not more than 120° C.2. The thermal transfer sheet according to claim 1 , wherein the polyester-type resin has a number average molecular weight (Mn) of not less than 3500 and less than 9000.3. The thermal transfer sheet according to claim 1 , wherein the polyester-type resin has a glass transition temperature (Tg) of not less than 50° C. and not more than 100° C.4. The thermal transfer sheet according to claim 2 , wherein the polyester-type resin has a glass transition temperature (Tg) of not less than 50° C. and not more than 100° C. This application is a continuation of U.S. application Ser. No. 16/082,366, filed Sep. 5, 2018, which in turn is the National Stage entry of International Application No. PCT/JP2017/009043, filed Mar. 7, 2017, the entireties of ...

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10-05-2018 дата публикации

FOOD PACKAGING CONTAINER, PACKAGING METHOD AND APPLICATION THEREOF

Номер: US20180127190A1
Автор: KANG Kui
Принадлежит:

The present disclosure discloses a food packaging container and a packaging method and an application thereof. The packaging container is applied for food storing and microwave heating. The packaging container includes a container main body an outlet part connected to the container main body and a protecting cap sheathed on the outlet An opening is provided on the outlet part and a sealing film is provided on the opening. The packaging container is rational and simple in structure, which can be heated directly in the microwave. The food would not block an air vent and the food is ready to serve after microwave heating, exhibiting an excellent practical application value. 1. A food packaging container for storing food to be heated in microwave , comprising:a container main body,an outlet part connected through to the container main body, anda protecting cap sheathed on the outlet part;wherein an opening is provided on the outlet part;a sealing film is provided on the opening; the sealing film is configured to automatically unseal the opening to form an air outlet;an air ventilation structure is further provided coordinated with the air outlet for air exhaust between the outlet part and the protecting cap, and/or between the outlet part, the protecting cap and the container main body; andfood is stored below a horizontal level of the outlet part when the food stored in the food packaging container is heated.2. The food packaging container according to claim 1 , whereinthe container main body is screwed with the protecting cap; anda globoidal bulge is provided on a top of the protecting cap.3. The food packaging container according to claim 1 , whereinthe sealing film has four layers;the four layers are a food-wax layer, a starch film layer, a thin polypropylene film layer, and a food-wax layer at sequence from inside to outside; andthe polypropylene film layer is provided with a plurality of first air vents.4. The food packaging container according to claim 1 , ...

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01-09-2022 дата публикации

Blend of polyacrylic and polyvinyl acetate latexes

Номер: US20220275238A1

The present invention is a composition comprising a blend of a PVA based latex and an EA/MMA based polyacrylic latex. The composition of the present invention is useful in a paint formulation for providing a coating with superior scrub resistance over a formulation comprising a blend of a PVA based latex and a BA/MMA based polyacrylic latex.

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23-04-2020 дата публикации

Super Absorbent Polymer And Method For Preparing Same

Номер: US20200123281A1
Принадлежит: LG CHEM, LTD.

The present invention relates to a super absorbent polymer and a method for preparing the same. According to the super absorbent polymer and the method for preparing a super absorbent polymer of the present invention, a laponite is contained in a colloidal solution state during polymerization of the monomer composition, and thus achieves an appropriate crosslinking density, thereby contributing to improvement of various physical properties such as a gel strength and a centrifuge retention capacity of the super absorbent polymer. 1. A method for preparing a super absorbent polymer comprising:preparing a monomer composition containing a water soluble ethylenically unsaturated monomer, an internal crosslinking agent, and a polymerization initiator;mixing the monomer composition with a laponite colloidal solution containing 0.02 to 0.09 part by weight of a positively charged laponite based on 100 parts by weight of the monomer composition to form a mixture of the monomer composition and the lapnotie colloidal solution; andthermally polymerizing or photo-polymerizing the mixture of the monomer composition and the laponite colloidal solution to form a crosslinked polymer.2. The method for preparing a super absorbent polymer according to claim 1 , wherein the laponite colloidal solution includes laponite in the concentration of 0.5% to 10% by weight.3. The method for preparing a super absorbent polymer according to claim 1 , wherein the laponite colloidal solution has a viscosity of 1.2 to 10 cps at 25° C.4. The method for preparing a super absorbent polymer according to claim 1 , wherein a charge amount of the laponite is 1 to 10 mmol/100 g.5. The method for preparing a super absorbent polymer according to claim 1 , wherein the positively charged laponite includes at least one of Laponite XLG claim 1 , Laponite RD claim 1 , Laponite EP claim 1 , Laponite XL21 claim 1 ,or Laponite D.6. The method for preparing a super absorbent polymer according to claim 1 , wherein the ...

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23-04-2020 дата публикации

Low Dust Additives Comprising Emulsified Powder For Joint Compounds And Joint Compounds Thereof

Номер: US20200123407A1
Автор: Ayambem Amba
Принадлежит:

The present invention relates generally to wall repair compounds such as joint compounds, spackling compounds, and the like used to repair imperfections in walls or fill joints between adjacent wallboard panels. Particularly, the present invention relates to such a wall repair compound comprising a dust reduction additive that reduces the quantity of airborne dust generated when the hardened compound is sanded and also exhibits improved adhesive properties. The dust reduction additive also imparts adhesion to the wall repair compounds to which it is added, for example to a joint compound. The dust reduction additive is a powder prepared from colloidally-protected, wax-based microstructure dispersions. 1. A method of using a first low-dust , wall-repair compound composition that has low-dust property and optionally improved adhesive property and/or improved water resistance property , said method comprising:(I) applying said composition to a wallboard panel;(II) allowing said composition to dry; and(III) sanding said dried composition;wherein said wall repair composition comprises a dust reduction additive emulsified powder made from an emulsion comprising colloidally-protected-wax-based (CPWB) microstructure, comprising:{'sub': n', '2n+2, '(A) a wax core, wherein said wax core comprises a micro-crystalline wax component and/or a non-micro-crystalline wax component, wherein said micro-crystalline wax component comprises at least one linear alkane wax defined by the general formula CH, where n ranges from 13-80, wherein said non-micro-crystalline wax component comprises at least one wax selected from the group consisting of animal-based wax, plant-based wax, mineral wax, synthetic wax, a wax containing organic acids and/or esters, anhydrides, an emulsifier containing a mixture of organic acids and/or esters, and combinations thereof and'}(B) a polymeric shell, wherein said polymeric shell comprises at least one polymer selected from polyvinyl alcohol, polyvinyl ...

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01-09-2022 дата публикации

Devices for inspecting adequate exposure of a tissue sample to a treatment medium and methods and uses therefor

Номер: US20220276175A1
Принадлежит: Pathcore Inc

Provided are devices for measuring the exposure of a tissue sample to a treatment medium, wherein the device provides for inspection without direct inspection of the tissue sample. The inspection may comprise visual inspection of the device. Treatment containers comprising these devices and methods of use of the devices and treatment containers are also provided.

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17-05-2018 дата публикации

CARPET COATING COMPOSITIONS

Номер: US20180135242A1
Принадлежит: Wacker Chemie AG

The invention relates to the use of mixtures that contain an aqueous dispersion of a vinyl acetate polymer and an aqueous dispersion of a vinyl acetate-ethylene copolymer for carpet coating compositions, and corresponding carpet coating compositions, as well as carpets which are coated with such carpet coating compositions. 1. The method of using mixtures comprising an aqueous dispersion of a vinyl acetate polymer and an aqueous dispersion of a vinyl acetate-ethylene copolymer for carpet coating compositions.2. The method as claimed in claim 1 , characterized in that the vinyl acetate polymer is obtained via free-radically initiated emulsion polymerization of 99 to 100 wt % of vinyl acetate and optionally up to 1 wt % of further comonomers claim 1 , all based on the total weight of the monomers claim 1 , while the particulars in weight % add up to 100 wt % in each case claim 1 , in an aqueous medium.3. The method as claimed in or claim 1 , characterized in that the vinyl acetate-ethylene copolymer is obtained via free-radically initiated emulsion polymerization of 65 to 98 wt % of vinyl acetate and 2 to 30 wt % of ethylene and optionally up to 10 wt % of further comonomers claim 1 , all based on the total weight of the monomers claim 1 , while the particulars in weight % add up to 100 wt % in each case claim 1 , in an aqueous medium.4. The method as claimed in or claim 1 , characterized in that the polymerization of the vinyl acetate polymer is effected in the presence of protective colloid claim 1 , optionally in combination with emulsifier.5. The method as claimed in or claim 1 , characterized in that the polymerization of the vinyl acetate-ethylene copolymer is effected in the presence of protective colloid or in the presence of emulsifier or in the presence of a combination of emulsifier and protective colloid.6. The method as claimed in or claim 1 , characterized in that not only the polymerization of the vinyl acetate polymer but also the polymerization of the ...

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18-05-2017 дата публикации

COMPOSITION FOR FORMING LASER DIRECT STRUCTURING LAYER, KIT, AND METHOD FOR MANUFACTURING RESIN MOLDED ARTICLE WITH PLATED LAYER

Номер: US20170137660A1

Making formation of a plated layer on a surface of a resin molded article possible, without adding the LDS additive to the thermoplastic resin composition. Provided is a composition for forming a laser direct structuring layer, the composition comprising a water-compatible organic substance, water, and a laser direct structuring additive. Further provided is a kit having the composition for forming a laser direct structuring layer and a method for manufacturing a resin molded article with a plated layer, which uses the composition for forming a laser direct structuring layer. 122-. (canceled)23. A composition for forming a laser direct structuring layer , the composition comprising a water-compatible organic substance , water , and a laser direct structuring additive.24. The composition for forming a laser direct structuring layer of claim 23 , wherein the water-compatible organic substance is a paste.25. The composition for forming a laser direct structuring layer of claim 23 , containing 0.05 to 45 parts by weight of the laser direct structuring additive claim 23 , per 100 parts by weight in total of the water-compatible organic substance and water.26. The composition for forming a laser direct structuring layer of claim 23 , wherein the composition for forming a laser direct structuring layer contains 0.5 to 30% by weight of the water-compatible organic substance.27. The composition for forming a laser direct structuring layer of claim 23 , wherein the water-compatible organic substance is selected from polyvinyl alcohol paste claim 23 , hydroxyethyl cellulose claim 23 , gelatin claim 23 , emulsion-type vinyl acetate resin-based adhesive claim 23 , and claim 23 , water-soluble polyurethane.28. A kit comprising the composition for forming a laser direct structuring layer described in claim 23 , and a thermoplastic resin composition containing a thermoplastic resin.29. The kit of claim 28 , wherein the thermoplastic resin composition contains substantially no laser ...

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28-05-2015 дата публикации

QUICK-DRYING, TACKY POLYMER FILM COMPOSITIONS AND METHODS OF USE

Номер: US20150147468A1
Принадлежит:

A formulation for coating surfaces, for example gloves, with a tacky film comprises a hydrophobically modified biopolymer, where the hydrophobic modifications of the biopolymer correspond to between 1 and 90% of available functional groups, a plasticizer, and a volatile solvent. The formulation quickly dries into a tacky film that provides an enhanced friction of the surface. 1. A formulation , comprising:a hydrophobically modified biopolymer, where between 1 and 90% of available functional groups of the biopolymer are covalently attached to a hydrophobic moiety, a plasticizer, and a volatile solvent; wherein the formulation quickly dries into a tacky film.2. The formulation of claim 1 , further comprising a weak acid claim 1 , selected from the group consisting of acetic acid claim 1 , lactic acid claim 1 , formic acid claim 1 , nitrous acid claim 1 , gluconic acid claim 1 , citric acid claim 1 , malic acid claim 1 , succinic acid.3. The formulation of claim 1 , wherein the hydrophobically modified biopolymer is selected from the group consisting of chitosans claim 1 , alginates claim 1 , and cellulosics.4. The formulation of claim 1 , wherein the plasticizer is selected from the group consisting of ethylene glycol claim 1 , glycerol claim 1 , include erythritol claim 1 , threitol claim 1 , arabitol claim 1 , xylitol claim 1 , ribitol claim 1 , sorbitol claim 1 , mannitol claim 1 , or other small claim 1 , non-volatile hydroxyl-containing molecule.5. The formulation of claim 1 , further comprising an enhancer selected from the group consisting of polyvinyl acetate claim 1 , celluloses claim 1 , alkyl celluloses claim 1 , hydroxyalkyl celluloses claim 1 , zein claim 1 , polylactic acid claim 1 , alkyl acrylates claim 1 , hydroxyalkyl acrylates claim 1 , polyvinyl alcohol claim 1 , and partially hydrolyzed polyvinyl acetate.6. The formulation of claim 1 , wherein the solvent comprises a small molecule alcohol and water claim 1 , in a concentration of between 60 and ...

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28-05-2015 дата публикации

DECORATIVE SHEET

Номер: US20150147526A1
Принадлежит:

To provide a decorative sheet which has anti-skid properties, is resistant to abrasion, exhibits high abrasion resistance even when bonded to a floor or road surface over which pedestrians or vehicles traverse, does not cause pedestrians or vehicles to skid, and does not suffer from damage or peeling. [Resolution Means] A decorative sheet having a first bead coat layer comprising a resin and particles having a median diameter of from 20 μm to 60 μm, a second bead coat layer which is coated on the first bead coat layer and which includes a resin and particles having a median diameter of from 20 μm to 60 μm, a design layer and an adhesive layer. 1. A decorative sheet comprising a first bead coat layer including a resin and particles having a median diameter of from 20 μm to 60 μm , a second bead coat layer which is coated on the first bead coat layer and which includes a resin and particles having a median diameter of from 20 μm to 60 μm , a design layer , and an adhesive layer.2. The decorative sheet according to claim 1 , wherein the median diameter of the particles contained in the second bead coat layer is greater than the median diameter of the particles contained in the first bead coat layer.3. The decorative sheet according to claim 1 , wherein the median diameter of the particles contained in the second bead coat layer is less than the median diameter of the particles contained in the first bead coat layer.4. The decorative sheet according to claim 1 , which contains an adhesive layer claim 1 , a metal layer claim 1 , a bonding layer claim 1 , a design layer claim 1 , a transparent film layer claim 1 , a first bead coat layer and a second bead coat layer in that order.5. The decorative sheet according to claim 4 , wherein the bonding layer contains a colored adhesive.6. The decorative sheet according to claim 5 , wherein the colored adhesive contains titanium oxide.7. The decorative sheet according to claim 1 , wherein the adhesive layer contains an adhesive ...

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09-05-2019 дата публикации

PHOTOCURABLE RESIN COMPOSITION, INK AND COATING MATERIAL

Номер: US20190135955A1
Принадлежит:

Provided is a photocurable resin composition containing an allylic polymer (A) which has excellent adhesion to plastic substrates. The present invention relates to a photocurable resin composition containing an allylic polymer (A), the allylic polymer (A) being produced by polymerization of an allylic compound represented by the following formula (I): 17-. (canceled)10. The method according to claim 8 , wherein the photocurable resin composition further comprises an ethylenically unsaturated compound (B).11. The method according to claim 8 , wherein the photocurable resin composition further comprises a photopolymerization initiator. The present invention relates to a photocurable resin composition containing an allylic polymer (A) and also relates to an ink and a coating material including the resin composition. Specifically, the present invention relates to a photocurable resin composition having excellent adhesion to plastic substrates.Various resin compositions that can be cured by light (e.g. ultraviolet rays) have been used in inks, coating materials, adhesives, photoresists, and other applications. For example, UV curable printing inks are highly valued because, e.g., they have a high cure rate so that they can be cured in a short time;they are environmentally friendly due to no use of solvents; and they can save resources and energy. Therefore, they are increasingly widely used in practice.Among such resin compositions, those containing diallyl phthalate resins derived from diallyl phthalate (diallyl orthophthalate, diallyl isophthalate, or diallyl terephthalate) are used as UV offset inks for paper.However, in offset ink applications, the incorporation of diallyl phthalate resins is known to result in insufficient adhesion to plastic substrates (see, for example, Patent Literature 1). Moreover, Patent Literature 2 describes an active energy ray-curable resin composition that contains a diallyl hydrogenated phthalate prepolymer with an alkyl group on the ...

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