11-10-2018 дата публикации
Номер: US20180291125A1
Автор:
Anderson Emily Baird,
Baker,
Carvagno Terri Roxanne,
CHAPELET Judicael Jacques,
Cheng Wei Min,
De Hullu Jacobus Gillis,
Deng Liu,
Finger Sebastian,
Hirschlag Hubert,
JR. John Dayton,
Lester Christopher Lee,
Li Wentao,
Muvundamina Mutombo Joseph,
Pavlin Mark Stanley,
Peters Fabian,
Recker Carla,
Scilla Christopher Thomas
Принадлежит:
Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance. 1. A composition , comprising:about 10 to about 90 weight percent of at least one polymer,about 4 to about 70 weight percent of at least one functionalized resin,about 0 to about 70 weight percent of at least one thermoplastic tackifying resin,about 0 to about 50 weight percent of at least one wax,about 0 to about 60 weight percent of at least one oil or plasticizer,about 0.5 to about 3 weight percent of at least one stabilizer, andabout 0 to about 70 weight percent of at least one filler,wherein the composition is non-vulcanized, {'br': None, 'sub': k', 'n', '2', 'm', 'p', 'q, 'sup': 1', '2, 'resin-[Z—X—R—(CH)—Si(R)]\u2003\u2003(I)'}, 'wherein the functionalized resin comprises Formula Iwherein Z is an aromatic group or an aliphatic group, optionally comprising a heteroatom;wherein X is a linker comprising a heteroatom selected from sulfur, oxygen, nitrogen, a carbonyl group, or a combination thereof;{'sup': '1', 'sub': 1', '18, 'wherein Rcomprises one or more of an aliphatic Cto Cand/or a linkage group comprising a heteroatom;'}{'sup': 2', '2, 'sub': 1', '18', '1', '18, 'wherein each Ris the same or different and is independently selected from a Cto Calkoxy, aryloxy, alkyl, ...
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