CHEMICAL CONVERSION COATED PLATED STEEL SHEET AND METHOD FOR PRODUCING SAME

The present disclosure relates to a chemically treated zinc-based plated steel sheet that is superior in weather resistance, water resistance, blackening resistance and film adhesion. A chemical conversion film having a thickness 0.5-10 μm is formed by coating and drying a chemical treatment solution on a surface of an aluminum-containing zinc-based alloy plated steel sheet. The chemical treatment solution contains a fluororesin containing 0.05-5% by weight of a hydrophilic functional group selected from the group consisting of a carboxyl group and a sulfonic acid group and 7-20% by weight of a fluorine atom, the fluororesin in which a number-average molecular weight is 1,000-2,000,000, and an oxoate, a fluoride, a hydroxide, an organic salt, a carbonate or a peroxygenated salt of a group 4A metal. 1. A chemically treated zinc-based plated steel sheet , comprising:an aluminum-containing zinc-based alloy plated steel sheet, the aluminum-containing zinc-based alloy containing 0.05-60% by weight of aluminum; anda chemical conversion film having a film thickness of 0.5-10 μm formed on a surface of the aluminum-containing zinc-based alloy plated steel sheet,wherein the chemical conversion film contains a fluororesin containing 0.05-5% by weight of a hydrophilic functional group selected from the group consisting of a carboxyl group and a sulfonic acid group and 7-20% by weight of a fluorine atom, and 0.1-5% by weight in terms of a metal with respect to the fluororesin of a group 4A metal compound.2. The chemically treated zinc-based plated steel sheet according to claim 1 , wherein a ratio between the carboxyl group and the sulfonic acid group included in the fluororesin in terms of a carboxyl group/sulfonic acid group molar ratio is 5-60.3. The chemically treated zinc-based plated steel sheet according to claim 1 , wherein the chemical conversion film further contains a phosphate claim 1 , and an amount of the phosphate with respect to the fluororesin is within a range ...

TREATMENT AGENT FOR CHROMIUM-FREE INSULATING COATING FORMATION, INSULATION-COATED GRAIN-ORIENTED ELECTRICAL STEEL SHEET, AND METHOD FOR MANUFACTURING THE SAME

A treatment agent for chromium-free insulating coating formation suitable for forming an insulating coating on a surface of a grain-oriented electrical steel sheet. The treatment agent includes components (A), (B), (C), and (D). The component (B) is contained in an amount of 50 to 150 parts by mass on a SiOsolid basis, and the component (C) is contained in an amount of 5.0 parts by mass or more on an elemental metal basis, the amounts being based on 100 parts by mass, on a solid basis, of the component (A). The component (D) is contained in an amount that a molar ratio of M and M, each being a metal element in the treatment agent for chromium-free insulating coating formation, to a phosphorus element P satisfies a specified relationship, and the treatment agent for chromium-free insulating coating formation has a pH of less than 4.5. 1. A treatment agent for chromium-free insulating coating formation suitable for forming an insulating coating on a surface of a grain-oriented electrical steel sheet , the treatment agent comprising:a component (A): at least one selected from the group consisting of phosphates of Mg, Ca, Ba, Sr, Zn, Al, and Mn;a component (B): colloidal silica;a component (C): at least one selected from the group consisting of organic acid salts of Mg, Ca, Ba, Sr, Zn, Al, Mn, Fe, Ni, Cu, and Co; anda component (D): phosphoric acid,{'sub': '2', '#text': 'wherein the component (B) is contained in an amount in a range of 50 to 150 parts by mass on a SiOsolid basis, and the component (C) is contained in an amount of 5.0 parts by mass or more on an elemental metal basis, the amounts being based on 100 parts by mass, on a solid basis, of the component (A),'}{'sup': ['2+', '3+'], 'claim-text': {'br': None, 'sup': ['2+', '3+'], '#text': '0.50<(M+1.5×M)/P≤1.20'}, '#text': 'the component (D) is contained in an amount that a molar ratio of M and M, each being a metal element in the treatment agent for chromium-free insulating coating formation, to a phosphorus ...

SHEET STEEL WITH A CONVERSION COATING, METHOD OF PRODUCING CONVERSION-COATED SHEET STEEL AND TREATMENT AGENT FOR APPLICATION OF A CONVERSION COATING ON SHEET STEEL

A sheet steel, in particular strip-shaped blackplate, with a conversion coating which is prepared from components dissolved in water. The components are selected from the group of i) hexafluorotitanate, ii) zinc phosphate, iii) phosphoric acid, iv) a mixture of any of i) to iii), provided that the components i), ii) and iii) do not contain any organic ingredients. 1. A sheet steel with a conversion coating on at least one surface of the sheet steel , wherein the conversion coating contains at least one of the following components:i) hexafluorotitanate,ii) zinc phosphate and/or iron phosphate,iii) phosphoric acid,provided that the components i), ii) and iii) do not contain any organic ingredients.2. The sheet steel of claim 1 , wherein the conversion coating consists of one of the following components or a mixture of these components:i) hexafluorotitanate,ii) zinc phosphate and/or iron phosphate,iii) phosphoric acid,provided that the components i), ii) and iii) do not contain any organic ingredients.3. The sheet steel of claim 1 , wherein an organic lacquer and/or a plastic coating is applied to the conversion coating.4. The sheet steel of claim 1 , wherein the conversion coating contains phosphate ions.5. The sheet steel of claim 1 , wherein the coating weight of the hexafluorotitanate in the conversion coating claim 1 , relative to titanium claim 1 , is in the range of 1 mg/mto 50 mg/m.6. The sheet steel of claim 1 , wherein the coating weight of the phosphate in the conversion coating claim 1 , relative to phosphate ions claim 1 , is in the range of 10 mg/mto 1000 mg/m.7. A method of producing a conversion-coated sheet steel claim 1 , comprising the following steps:a) having available a sheet steel, in particular in the form of a steel strip;b) cathodic degreasing of at least one surface of the sheet steel; i) hexafluorotitanate,', 'ii) zinc phosphate and/or iron phosphate,', 'iii) phosphoric acid, and', 'iv) a mixture of any one of i) to iii),, 'c) application of ...

ELECTRIC RESISTANCE WELDED STEEL PIPE HAVING IDENTIFIABLE SEAM PORTION AND METHOD FOR MANUFACTURING THE SAME

An electric resistance welded steel pipe having an identifiable seam portion and a method for manufacturing the same. The electric resistance welded steel pipe includes a steel pipe portion with a seam portion, which is formed by electric resistance welding, and a coating portion of zinc phosphate. The coating portion covers at least an outer surface side of the steel pipe portion. A part of the coating portion that is immediately above the seam portion forms a color difference portion that has a width W along a pipe circumferential direction of greater than or equal to 0.1 times a wall thickness of the pipe and less than or equal to the wall thickness of the pipe. The color difference portion has a visually identifiable color difference from the other parts of the coating portion. 1. An electric resistance welded steel pipe comprising:a steel pipe portion that includes a seam portion formed by electric resistance welding; anda coating portion of zinc phosphate that covers at least an outer surface side of the steel pipe portion,wherein a part of the coating portion that is immediately above the seam portion forms a color difference portion, the color difference portion having a width W along a pipe circumferential direction of greater than or equal to 0.1 times a wall thickness of the steel pipe and less than or equal to the wall thickness of the steel pipe, the color difference portion having a visually identifiable color difference from the other parts of the coating portion.2. A method for manufacturing the electric resistance welded steel pipe according to claim 1 , the method comprising:rounding a steel strip in a width direction by roll forming while continuously feeding the steel strip;joining both ends of the rounded steel strip in the width direction by electric resistance welding to make a steel pipe having a seam portion formed by the joining;cutting an inner surface bead and an outer surface bead of the steel pipe;applying coating of zinc phosphate to ...

METHOD FOR COATING THIN FILM IN ROLLING MANNER AND APPARATUS FOR COATING THIN FILM BY USING THE SAME

A method for coating a thin film in a rolling manner and a thin film coating apparatus are provided. The method includes: floating a thin film material on a liquefied material; rolling a cylindrical substrate after contacting the cylindrical substrate with the thin film material; and coating the thin film material on a surface of the cylindrical substrate by using an attraction force between the surface of the cylindrical substrate and the thin film material. 1. A method for coating a thin film in a rolling manner , the method comprising:floating a thin film material on a liquefied material;rolling a cylindrical substrate after contacting the cylindrical substrate with the thin film material; andcoating the thin film material on a surface of the cylindrical substrate by using an attraction force between the surface of the cylindrical substrate and the thin film material.2. The method of claim 1 , further comprising claim 1 , before the floating claim 1 , removing a sacrificial layer after depositing the thin film material on the sacrificial layer.3. The method of claim 2 , wherein the sacrificial layer comprises at least one of Cu and Ni.4. The method of claim 3 , wherein claim 3 , in the removing claim 3 , the sacrificial layer is removed by using an etchant.5. The method of claim 1 , wherein the attraction force is greater than an adhesive force between the liquefied material and the thin film material.6. The method of claim 1 , wherein the thin film material comprises a plurality of layers.7. The method of claim 6 , wherein the thin film material comprises a first thin film material and a second thin film material claim 6 , and wherein the first thin film material and the second thin film material are different from each other.8. A method for coating a thin film in a rolling manner claim 6 , the method comprising:forming a sacrificial layer on a planar substrate;depositing a thin film material on the sacrificial layer;removing the planar substrate and the ...

AQUEOUS DISPERSION FOR ACTIVATING A METAL SURFACE AND METHOD FOR THE PHOSPHATING THEREOF

The present invention relates to an aqueous dispersion as a concentrate for the activation stage of phosphating of metal surfaces, containing a dispersed particulate constituent and a thickener, the particulate constituent containing, in addition to dispersed inorganic compounds of polyvalent metal cations, polymeric organic compounds as dispersing agents which are composed at least partially of styrene and/or an α-olefin having no more than 5 carbon atoms and maleic acid, its anhydride and/or its imide, and which additionally comprise polyoxyalkylene units. The aqueous dispersion is further characterized by a D50 value above 10 μm. The present invention also relates to a method for anti-corrosion pretreatment of the surfaces of a metal material, in particular for zinc phosphating. 1. An aqueous dispersion having a D50 value of more than 10 μm , containing: (a1) at least one particulate inorganic compound of a polyvalent metal cation; and', '(a2) at least one polymeric organic compound composed at least partially of styrene and/or an α-olefin having no more than 5 carbon atoms and maleic acid, its anhydride and/or its imide and which additionally comprises polyoxyalkylene units;, '(a) at least 5 wt. % of a dispersed particulate constituent comprising'}and(b) at least one thickener.2. The dispersion according to claim 1 , wherein the at least one particulate inorganic compound (a1) of the dispersed particulate constituent (a) is composed at least partially of phosphates claim 1 , present in an amount of at least 25 wt. % based on the dispersed inorganic particulate constituent calculated as PO.3. The dispersion according to claim 2 , wherein the phosphates present in the at least one particulate inorganic compound (a1) are composed at least partially of one or more of hopeite claim 2 , phosphophyllite claim 2 , scholzite and hureaulite.4. The dispersion according to claim 1 , wherein the aqueous dispersion has a D90 value of less than 150 μm.5. The dispersion ...

SURFACE-TREATED METAL MATERIAL

A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100. 1. A surface-treated metal material , comprising:a metal sheet;a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc; anda composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound,wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.2. The surface-treated metal material according to claim 1 , wherein claim 1 , in the composite coating claim 1 , when analyzed with the micro-fluorescent X-rays at a spot size of φ30 μm claim 1 , an area ratio of a region in which the V/Zn is 0.010 to 0.100 to an entire measurement range is 1% to 50%.3. The surface-treated metal material according to claim 1 , wherein claim 1 , in the composite coating claim 1 , when analyzed with the micro-fluorescent X-rays at a spot size of φ30 μm claim 1 , a maximum value of V/Si claim 1 , which is a ratio of a solid content mass of V to a solid content mass of Si claim 1 , is 1.0 to 100.4. The surface-treated metal material according to wherein claim 1 , in the composite coating claim 1 , when analyzed ...

COMPOSITION, ITS USE FOR ACID PICKLING OF MAGNESIUM ALLOYS AND METHOD FOR ACID PICKLING OF MAGNESIUM ALLOYS

Composition, characterized in that: —it comprises, in a solution of demineralized water: between 10 and 80, preferably between 15 and 20, more preferably 17, g/l of a composition of phosphoric acid HPO, and between 2 and 15, preferably between 4 and 8, more preferably 6, g/l of a composition of potassium permanganate KMnO, —the weight ratio HPO/KMnOis between 1.5 and 10, preferably between 1.8 and 5, mote preferably equal to 2.8, —said composition has a pH between 2.4 and 3, preferably 2.5. 1. A composition , characterised in that:it comprises, in a solution of water:{'sub': 3', '4, 'between 10 and 80 g/l of a composition of phosphoric acid HPO, and'}{'sub': '4', 'between 2 and 15 g/l of a composition of potassium permanganate KMnO,'}{'sub': 3', '4', '4, 'the weight ratio HPO/KMnOis between 1.5 and 10, preferably between 1.8 and 5, most preferably equal to 2.8,'}said composition has a pH between 2.4 and 3, preferably 2.5.2. The composition according to claim 1 , wherein:it comprises:{'sub': 3', '4, 'between 10 and 30 g/l, preferably between 15 and 20 g/l of a composition of phosphoric acid HPO, and'}{'sub': '4', 'between 4 and 8 g/l of a composition of potassium permanganate KMnO.'}3. The composition according to claim 1 , whereinit comprises:{'sub': 3', '4, '17 g/l of a composition of phosphoric acid HPO, and'}{'sub': '4', '6 g/l of a composition of potassium permanganate KMnO,'}said composition has a pH of 2.5.4. The composition according to claim 1 , wherein:it comprises:{'sub': 3', '4, 'between 20 and 80 g/l of a composition of phosphoric acid HPO, and'}{'sub': 3', '4', '4, 'the weight ratio HPO/KMnOis between 2.5 and 10, preferably between 2.5 and 5, most preferably equal to 2.8.'}5. The composition according to claim 1 , wherein it further comprises an agent for adjusting the pH different from nitric acid HNO claim 1 , preferably selected from acetic acid CHCOOH claim 1 , sulfuric acid HSO claim 1 , phosphoric acid HPO claim 1 , sodium hydroxide NaOH and ...

RESOURCE-SAVING METHOD FOR ACTIVATING A METAL SURFACE PRIOR TO PHOSPHATING

The present invention relates to a method for phosphating metal surfaces in a layer-forming manner using a colloidal aqueous solution as an activation stage, containing a dispersed particulate constituent, the particulate constituent containing, in addition to dispersed inorganic compounds of phosphates of polyvalent metal cations, polymeric organic compounds as dispersing agents which are composed at least partially of styrene and/or an α-olefin having no more than 5 carbon atoms and are composed at least partially of maleic acid, its anhydride and/or its imide, the polymeric organic compounds additionally comprising polyoxyalkylene units. The cleaning and rinsing stages preceding the activation stage as well as the activation stage itself can be carried out using service water in a resource-saving manner without any loss of activation performance, the colloidal aqueous solution containing at least 0.5 mmol/L of alkaline-earth metal ions dissolved in water. 2. The method according to claim 1 , wherein the colloidal aqueous solution contains at least 1.0 mmol/L and no more than 10 mmol/L of the alkaline-earth metal ions dissolved in water.3. The method according to claim 2 , wherein claim 2 , in the colloidal aqueous solution claim 2 , amount of condensed phosphates dissolved in water is less than 0.25 claim 2 , based on phosphate content of the at least one particulate inorganic compound claim 2 , in each case based on the element P.4. The method according to claim 2 , wherein the colloidal aqueous solution contains at least 1.5 mmol/L claim 2 , but no more than 10 mmol/L claim 2 , of the alkaline-earth metal ions dissolved in water.5. The method according to claim 1 , wherein the colloidal aqueous solution has an alkaline pH and contains at least one complexing agent selected from α-hydroxycarboxylic acids claim 1 , organophosphonic acids and combinations thereof.6. The method according to claim 5 , wherein the complexing agents in the colloidal aqueous solution ...

RESOURCE-SAVING METHOD FOR ACTIVATING A METAL SURFACE PRIOR TO PHOSPHATING

A method for phosphating metal surfaces in a layer-forming manner using a colloidal aqueous solution as an activation stage containing a dispersed particulate constituent, the particulate constituent containing dispersed inorganic compounds of phosphates of polyvalent metal cations; plus polymeric organic compounds as dispersing agents, which are composed at least partially of styrene and/or an α-olefin having no more than 5 carbon atoms and are composed at least partially of maleic acid, its anhydride and/or its imide, the polymeric organic compounds additionally comprising polyoxyalkylene units. In the activation stage of the method according to the invention, the addition of condensed phosphates can be dispensed with such that the content of dissolved condensed phosphates in the colloidal aqueous solution is less than 0.25, based on the phosphate content in the particulate constituent thereof, in each case based on the element P. 1. A method for anti-corrosion pretreatment of a metal material selected from zinc , iron or aluminum or of a component which is composed at least partially of such metal materials , comprising steps of:(i) activating the metal material or the component; and then(ii) phosphating, optionally zinc phosphating, the metal material or component of step (i), in consecutive method steps,wherein activation in activating step (i) is carried out by contacting the metal material or the component with a colloidal aqueous solution containing, in a dispersed particulate constituent (a) of the colloidal aqueous solution:(a1) at least one particulate inorganic compound composed of phosphates of polyvalent metal cations at least partially selected from hopeite, phosphophyllite, scholzite and/or hureaulite, and(a2) at least one polymeric organic compound composed at least partially of styrene and/or an α-olefin having no more than 5 carbon atoms; at least partially of maleic acid, its anhydride and/or its imide, wherein the at least one polymeric organic ...

Dyed Trivalent Chromium Conversion Coatings and Methods of Using Same

An aqueous conversion coating solution comprises a trivalent chromium compound, a zirconate compound, and a dye compound. The trivalent chromium compound can comprise trivalent chromium compounds such as trivalent chromium sulfate. The dye compound can comprise an azo dye, a chromium complex dye, an anthraquinoid dye, and/or a methine dye. The zirconate compound can comprise alkali metal hexafluorozirconate compounds. The conversion coating solution can comprise a phosphorous compound such as an organic amino-phosphonic acid compound. The conversion coating solution can be formed by mixing a dye additive containing the dye with a trivalent chromium conversion coating solution that does not contain a dye. The conversion coating solution can be used to treat metal substrates comprising aluminum, magnesium, and/or zinc. 1. A trivalent chromium conversion coating solution comprising:a trivalent chromium compound;a zirconate compound; anda dye compound including a chromium complex azo dye or a triphenylmethane dye;wherein the conversion coating solution is an aqueous solution having a pH of at least 2.5; andwherein the trivalent chromium conversion coating solution is capable of satisfying the corrosion resistance requirement of MIL-DTL-81706B Class 1A or Class 3.2. The trivalent chromium conversion coating solution of wherein the trivalent chromium compound comprises trivalent chromium sulfate.3. The trivalent chromium conversion coating solution of wherein the dye compound comprises the chromium complex azo dye.4. The trivalent chromium conversion coating solution of wherein the dye compound comprises the triphenylmethane dye.5. The trivalent chromium conversion coating solution of wherein the zirconate compound comprises an alkali metal hexafluorozirconate compound.6. The trivalent chromium conversion coating solution of comprising:approximately 0.1 g/liter to approximately 20 g/liter of the trivalent chromium compound;approximately 0.2 g/liter to approximately 20 g/ ...

COATING STRUCTURE, IMPELLER, COMPRESSOR, METAL PART MANUFACTURING METHOD, IMPELLER MANUFACTURING METHOD, AND COMPRESSOR MANUFACTURING METHOD

Said coating structure is provided with: a chemical conversion layer (), which is formed by chemical conversion coating so as to cover the surface of an impeller body () obtained from a magnesium alloy that contains magnesium as the main component and which has a film thickness within a previously determined range; and a plating layer () formed so as to cover the chemical conversion layer (). 18-. (canceled)9. A coating structure comprising:a chemical conversion layer that contains magnesium as a main component and is made of a phosphate-coated film and is formed in a manner of covering a surface of a base material which is made of a magnesium alloy containing at least one kind of element selected from a group consisting of gadolinium, terbium, thulium, and lutetium; anda plating layer that is made of a nickel-based alloy and is formed in a manner of covering the chemical conversion layer.10. The coating structure according to claim 9 ,wherein the plating layer is formed of a nickel-phosphorous alloy.11. The coating structure according to claim 9 ,wherein the base material contains a atom percent of zinc, contains b atom percent of at least one kind of element, in total, selected from a group consisting of gadolinium, terbium, thulium, and lutetium, has a remaining portion made of magnesium, and has the factors a and b satisfying the following expressions (1) to (3), and [{'br': None, 'i': 'a≤', '0.2≤5.0\u2003\u2003(1)'}, {'br': None, 'i': 'b≤', '0.5≤5.0\u2003\u2003(2)'}, {'br': None, 'i': a−', 'b, '0.50.5≤\u2003\u2003(3)'}], 'wherein the base material has at least one kind of precipitate selected from a precipitate group consisting of a compound of magnesium and a rare earth element, a compound of magnesium and zinc, a compound of zinc and a rare earth element, and a compound of magnesium, zinc, and a rare earth element.'}12. An impeller comprising:{'claim-ref': {'@idref': 'CLM-00009', 'claim 9'}, 'the coating structure according to .'}13. A compressor comprising ...

METHOD FOR TREATMENT OF A CHROMIUM FINISH SURFACE

A method for post-treatment of a chromium finish surface to improve corrosion resistance comprising a) providing a substrate having a chromium finish surface, and at least one intermediate layer between the chromium finish surface and the substrate, selected from the group consisting of nickel, nickel alloys, copper and copper alloys, wherein the chromium finish surface is a surface of a trivalent chromium plated layer, obtained by electroplating the substrate, having the at least one intermediate layer, in a plating bath, the plating bath comprising chromium (III) ions; b) contacting the chromium finish surface with an aqueous solution, comprising a permanganate, at least one compound which is selected from a phosphorus-oxygen compound, a hydroxide, a nitrate, a borate, boric acid, a silicate, or a mixture of two or more of these compounds; c) forming a transparent corrosion protection layer onto the chromium finish surface during step b. 1. A method for post-treatment of a chromium finish surface to improve corrosion resistance , comprisinga) providing a substrate having a chromium finish surface, and at least one intermediate layer between the chromium finish surface and the substrate, wherein the at least one intermediate layer is selected from the group consisting of nickel, nickel alloys, copper and copper alloys, wherein the chromium finish surface is a surface of a trivalent chromium plated layer, obtained by electroplating the substrate having the at least one intermediate layer, in a plating bath, the plating bath comprising chromium (III) ions as a main chromium source;b) contacting the chromium finish surface with an aqueous solution, comprisinga permanganate,at least one compound which is selected from a phosphorus-oxygen compound, a hydroxide, a nitrate, a borate, boric acid, a silicate, or a mixture of two or more of these compounds;c) forming a transparent corrosion protection layer onto the chromium finish surface during contacting the chromium ...

DYED TRIVALENT CHROMIUM CONVERSION COATINGS AND METHODS OF USING SAME

An aqueous conversion coating solution comprises a trivalent chromium compound, a zirconate compound, and a dye compound. The trivalent chromium compound can comprise trivalent chromium compounds such as trivalent chromium sulfate. The dye compound can comprise an azo dye, a chromium complex dye, an anthraquinoid dye, and/or a methine dye. The zirconate compound can comprise alkali metal hexafluorozirconate compounds. The conversion coating solution can comprise a phosphorous compound such as an organic amino-phosphonic acid compound. The conversion coating solution can be formed by mixing a dye additive containing the dye with a trivalent chromium conversion coating solution that does not contain a dye. The conversion coating solution can be used to treat metal substrates comprising aluminum, magnesium, and/or zinc. 1. A trivalent chromium conversion coating solution comprising:a trivalent chromium compound;a zirconate compound; anda dye compound;wherein the conversion coating solution is an aqueous solution; andwherein the dye compound comprises an azo dye, a chromium complex dye, an anthraquinoid dye, and/or a methine dye.2. The trivalent chromium conversion coating solution of wherein the trivalent chromium compound comprises trivalent chromium sulfate.3. The trivalent chromium conversion coating solution of comprising approximately 0.1 g/liter to approximately 20 g/liter of the trivalent chromium compound.4. The trivalent chromium conversion coating solution of wherein the zirconate compound comprises an alkali metal hexafluorozirconate compound.5. The trivalent chromium conversion coating solution of comprising approximately 0.2 g/liter to approximately 20 g/liter of the zirconate compound.6. The trivalent chromium conversion coating solution of wherein the dye compound comprises a metal complex azo dye.7. The trivalent chromium conversion coating solution of wherein the dye compound comprises a chromium complex azo dye.8. The trivalent chromium conversion ...

SURFACE TREATED STEEL STRIP AND MANUFACTURING METHOD OF SURFACE TREATED STEEL STRIP

A surface treated steel strip according to the present invention includes: a base steel sheet; a zinc phosphate coating film layer made of needle zinc phosphate crystals which are formed in an island shape on a surface of the base steel sheet; and a lubricating coating film layer covering the surface of the base steel sheet and a part of the zinc phosphate coating film layer, and containing at least a lubricating component, in which an area ratio of the zinc phosphate crystals exposed from a surface of the lubricating coating film layer is 25% to 90%. 18-. (canceled)9. A surface treated steel strip , comprising:a base steel sheet;a zinc phosphate coating film layer made of needle zinc phosphate crystals which are formed in an island shape on a surface of the base steel sheet; anda lubricating coating film layer covering the surface of the base steel sheet and a part of the zinc phosphate coating film layer, and containing at least a lubricating component, whereinan area ratio of the zinc phosphate crystals exposed from a surface of the lubricating coating film layer is 25% to 90%.10. The surface treated steel strip according to claim 9 , whereinthe zinc phosphate crystals have an average grain diameter in a major axis direction of 25 μm to 70 μm, and have an average grain diameter in a minor axis direction of 3 μm to 10 μm.11. The surface treated steel strip according to claim 9 , wherein{'sup': 2', '2, 'a coating weight of the zinc phosphate coating film layer is 1.5 g/mto 15.0 g/mper one side.'}12. The surface treated steel strip according to claim 10 , wherein{'sup': 2', '2, 'a coating weight of the zinc phosphate coating film layer is 1.5 g/mto 15.0 g/mper one side.'}13. The surface treated steel strip according to claim 9 , wherein{'sup': 2', '2, 'a coating weight of the lubricating coating film layer is 1.0 g/mto 12.0 g/mper one side.'}14. The surface treated steel strip according to claim 10 , wherein{'sup': 2', '2, 'a coating weight of the lubricating ...

ACTIVATING RINSE AND METHOD FOR TREATING A SUBSTRATE

Disclosed is an activating rinse for treating at least a portion of a substrate, comprising a dispersion of metal phosphate particles having a Dparticle size of no greater than 10 μm, wherein the metal phosphate comprises divalent or trivalent metals or combinations thereof; a dispersant; and a metal sulfate salt. Methods of treating a substrate with the activating rinse also are disclosed. Optionally, substrates treated with the activating rinse also are disclosed. 1. An activating rinse for treating a substrate comprising:{'sub': '90', 'a dispersion of metal phosphate particles having a Dparticle size of no greater than 10 μm, wherein the metal phosphate comprises divalent or trivalent metals or combinations thereof;'}a dispersant; anda metal sulfate salt.2. The activating rinse of claim 1 , wherein the Dparticle size is measured from a sample of the activating rinse that has been sonicated.3. The activating rinse of claim 1 , wherein the dispersant comprises a non-ionic dispersant.4. The activating rinse of claim 1 , wherein the activating rinse is substantially free of ionic dispersants.5. The activating rinse of claim 1 , wherein a sulfate ion of the metal sulfate salt is present in an amount of 5 ppm to 5 claim 1 ,000 ppm based on a total weight of the activating rinse.6. The activating rinse of claim 1 , wherein the metal of the metal sulfate salt comprises a divalent metal.7. The activating rinse of claim 6 , wherein the divalent metal comprises nickel claim 6 , cobalt claim 6 , zinc claim 6 , iron claim 6 , copper claim 6 , or combinations thereof.8. The activating rinse of claim 1 , wherein the metal phosphate particles have a Dparticle size of no more than 1 μm.9. The activating rinse of claim 1 , wherein the metal phosphate particles are substantially pulverized.10. The activating rinse of claim 1 , wherein the activating rinse comprises a multi-component system claim 1 , and wherein the dispersion of metal phosphate particles and the dispersant form a ...

PROCESS FOR COATING METALLIC SURFACES WITH A PASSIVATING AGENT, THE PASSIVATING AGENT AND ITS USE

The invention relates to a process for coating metal surfaces with an aqueous composition in the form of a solution or in the form of a dispersion, the composition comprising at least one phosphate, at least 3 g/l of at least one titanium or/and zirconium compound and at least one complexing agent, and also to corresponding aqueous compositions. The coatings prepared thereby have very good bare corrosion protection in the NSS salt spray test and in the condensation-water/constant-climate test 1. A process for coating and passivating metal surfaces with an aqueous composition in the form of a solution or in the form of a dispersion , wherein the composition comprises12 to 400 g/L of at least one phosphate,3 to 200 g/L of at least one titanium or zirconium compound,1 to 200 g/L of at least one complexing agent, selected from the group of compounds based on phosphonic acid, phytin and tannin, wherein content of compounds based on phosphonic acid amounts to 0 or 1 to 200 g/L, and wherein the content of compounds based on phytin or tannin amounts to 0 or 0.05 to 30 g/L, and also3 to 100 g/L of cations of aluminum, chromium(III) or zinc or at least one compound having a content of aluminum, chromium(III) or zinc in the range from 1 to 100 g/L, calculated as metal, wherein the content of zinc is at least 3 g/L,in that the composition has values of the free acid FA in the range from 2 to 25 points, values of total acid TA in the range from 20 to 45 points, and values of total acid Fischer TAF in the range from 12 to 20 points, andin that a wet film of the aqueous composition is dried on metal strips or sheets without the wet film or the dried film being rinsed with water.2. The process according to claim 1 , wherein the composition further comprises cations of iron or manganese or at least one compound having a content of iron or manganese.3. The process according to claim 1 , wherein the composition comprises a total content of cations of aluminum claim 1 , chromium(III) ...

PLANAR TRANSFORMER COMPONENTS COMPRISING ELECTROPHORETICALLY DEPOSITED COATING

Provided is an electrically insulated component for use in a planar transformer. The insulated component may include a planar transformer conductive component having a first surface, a second surface and a plurality of edges. The insulated component may also include a first layer including an oxidized metal coating, as well as a second layer including an electrophoretically deposited (EPD) insulating coating. The EDP coating may include a polymer and an inorganic material. The first layer and the second layer may cover at least the first surface and the plurality of edges of the conductive component and the first layer may be disposed between the conductive component and the second layer. Also provided is a method of manufacturing of the electrically insulated component. 150.-. (canceled)51. An electrically insulated component configured for use in a planar transformer , the insulated component comprising:a planar transformer conductive component having two opposed surfaces comprising a first surface and a second surface and a plurality of edges; andtwo distinct coating layers comprising a first layer and a second layer, the first layer being disposed between the conductive component and the second layer,wherein the first layer and the second layer cover at least the first surface and the plurality of edges of the conductive component,wherein the first layer comprises an oxidized metal coating, which facilitates adhesion of the second layer to the conductive component, and the second layer comprises an electrophoretically deposited (EPD) insulating coating, comprising a polymer and an inorganic material.52. The electrically insulated component according to claim 51 , wherein the thickness of the first layer ranges from about 0.1 μm to about 5 μm.53. The electrically insulated component according to claim 51 , wherein the conductive component is made of copper and wherein the oxidized metal coating is selected from the group consisting of cuprous oxide claim 51 , ...

PROCESS AND COMPOSITION FOR TREATING METAL SURFACES USING TRIVALENT CHROMIUM COMPOUNDS

Aqueous compositions useful as pretreatments prior to painting to reduce the formation of rust in the uncoated condition. The compositions consist essentially of water, a trivalent chromium compound with the formula Cr(HPO), where x can be 1.5 or 2, a silica compound, and optionally hydrogen peroxide. The composition may have a pH between about 1 and about 4. A process for treating a metal surface includes contacting the surface with such aqueous compositions. The compositions and the processes provide benefits in comparison to the zinc phosphate metal pretreatment thought to be the standard in the industry. 1. An aqueous pretreatment composition for treating a metal surface , the composition comprising:water;silica;{'sub': x', '4', '3, 'a trivalent chromium compound with the formula Cr(HPO), where x can be 1.5 or 2.'}2. The aqueous pretreatment composition of claim 1 , wherein the pretreatment composition is acidic.3. The aqueous pretreatment composition of claim 1 , wherein the pretreatment composition has a pH of between about 1 and about 4.4. The aqueous pretreatment composition of claim 1 , further comprising hydrogen peroxide.5. The aqueous pretreatment composition of claim 1 , wherein the trivalent chromium compound is present in an amount of between about 10% wt. % to about 0.5% wt. %.6. The aqueous pretreatment composition of claim 1 , wherein x is 1.5.7. The aqueous pretreatment composition of claim 1 , wherein x is 2.8. An aqueous pretreatment composition for treating a metal surface claim 1 , the composition consisting of:water;silica;{'sub': x', '4', '3, 'a trivalent chromium compound with the formula Cr(HPO), where x can be 1.5 or 2.'}9. The aqueous pretreatment composition of claim 8 , wherein the pretreatment composition is acidic.10. The aqueous pretreatment composition of claim 8 , wherein the pretreatment composition has a pH of between about 1 and about 4.11. The aqueous pretreatment composition of claim 8 , wherein the pretreatment composition ...

METHOD FOR MANUFACTURING COPPER COMPOSITE ELECTRODE WITH A FLAKE STRUCTURE ON THE SURFACE

A method for manufacturing a copper composite electrode, including contacting a conductive substrate including copper with a phosphate solution for oxidation to produce a copper phosphate structure on a surface of the conductive substrate, thus acquiring a copper phosphate composite electrode. 1. A method for manufacturing a copper composite electrode with a flake structure on the surface , the method comprising:a) preparing a conductive substrate comprising a copper surface;b) placing the conductive substrate comprising the copper surface in a phosphate solution having pH values of 4.0˜6.0 allows copper to contact with the phosphate solution for oxidation, wherein:the oxidation adopts electro-oxidation, chemical oxidation, or a combination thereof, when chemical oxidation is adopted, an oxidant is added and when electro-oxidation is adopted, voltages of −0.1 V˜0.1 V are applied; andc) forming a copper phosphate having a flake structure on the surface of the conductive substrate to acquire a copper phosphate composite electrode.2. The method of claim 1 , further comprising a1) before a): collecting a non-copper conductive substrate claim 1 , and depositing copper on a surface of the non-copper conductive substrate.3. The method of claim 2 , wherein in a1) claim 2 , the non-copper conductive substrate is placed in a solution comprising the copper ions to nucleate the copper ions on the surface of the non-copper conductive substrate.4. The method of claim 1 , wherein the conductive substrate is a screen-printed carbon electrode or carbon.5. The method of claim 1 , wherein the oxidant is selected from the group consisting of hydrogen peroxide claim 1 , potassium ferrite claim 1 , potassium permanganate claim 1 , and potassium dichromate.6. The method of claim 1 , wherein the oxidant is hydrogen peroxide claim 1 , and a molar concentration of hydrogen peroxide is between 0.001 and 10 M.7. The method of claim 1 , wherein a molar concentration of a phosphate of the ...

Procede de reduction de la formation de depots dans les solutions aqueuses de phosphatation de metaux

Process and aqueous solution for phosphatising metallic surfaces

Copper coating of printed circuit boards

A process for copper coating printed circuit boards is disclosed. The process includes a treating step in which a metal surface is contacted with an adhesion promotion composition material. The adhesion promotion material includes 0.1 to 20% by weight hydrogen peroxide, an inorganic acid, an organic corrosion inhibitor and a surfactant.

Method of phosphatizing surfaces of metals

Method for Applying a Phosphate Coating on a Steel or Iron Part, and Corresponding Steel or Iron Part

Method for applying a phosphate coating on an iron or steel part, and corresponding iron or steel part. The method according to the invention consists in a first coating step with a first phosphating, through which a first crystalline layer of iron and manganese phosphates is obtained, an intermediate step of partial pickling of said first crystalline layer of phosphates, leaving the base metal partially uncovered, and a second coating step comprising a second phosphating through which a second crystalline layer of iron and manganese phosphates is obtained, covering the partially pickled first layer of phosphates and the base metal. The method provides a coating with a lower thickness, a finer crystallisation and a lower rugosity Rk than the one that can be obtained by a simple phosphating.

Method for the Passivation of Metal Surfaces with Polymers Containing Acid Groups

Process for the passivation of metallic surfaces by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and Zn, Ca, Mg or Al ions, said process being in particular a continuous process for the passivation of strip metals.

Patent DE3004927C2

Metodo para la pasivacion de superficies metalicas con polimeros que contienen grupos acidos.

La invencion se refiere a un metodo para la pasivacion de superficies metalicas a traves del tratamiento de la superficie con una composicion acuosa acida, que comprende por lo menos un polimero que contiene grupo acido soluble en agua y iones Zn, Ca, Mg o Al, el metodo que es particularmente un metodo continuo para la pasivacion de metales en tira.

process for passivation of metallic surfaces, and passivation layer

PROCESSO PARA A PASSIVAçãO DE SUPERFìCIES METALICAS, E, CAMADA DE PASSIVAçãO. A invenção refere-se a um processo para passivação de superficies metálicas, em particular, de metais em tira pelo tratamento da superficie com uma composição aquosa ácida contendo pelo menos um polímero contendo grupo ácido, solúvel em água e pelo menos uma cera. PROCESS FOR PASSIVATION OF METAL SURFACES, AND LAYER OF PASSIVATION. The invention relates to a process for passivating metal surfaces, in particular, strip metals by treating the surface with an aqueous acidic composition containing at least one water-soluble acid-containing polymer and at least one wax.

一种羟胺改性磷化液及其制备方法

本发明公开了一种羟胺改性磷化液及其制备方法，由以下组分按重量份数配比制成：氧化锌22～46份、磷酸13～32份、硝酸12～25份、柠檬酸14～28份、硝酸锌12～25份、碳酸钙16～28份、硝酸铜14～26份、磷酸二氢锰18～33份、羟胺22～42份、氟锆酸14～28份、纳米氧化银12～25份、纳米氯化钡13～28份、水22～45份。与现有技术相比，本发明具有以下优点：(1)本发明所述羟胺改性磷化液耗能少，且能保证磷化膜的质量；(2)本发明所述羟胺改性磷化液低毒低污染；(3)本发明所述磷化液浓度低且成本较低。

Zinc phosphate-treated galvanized steel sheet excellent in corrosion resistance and color tone

본 발명은 밀봉 크로메이트 처리를 필요로 하지 않고 충분한 백녹 저항성 (white rust resistance)과 불균일한 결로 저항성(non-uniform dew condensation resistance)을 확보할 수 있고, 백색도가 높고 색조(color tone) 균일성이 우수한 아연 인산염 처리 아연 도금 강판을 제공한다. 본 발명에 따른 아연 도금 강판은 2% 이상의 Mg 및 Ni, Co와 Cu로 이루어진 그룹으로부터 선택된 하나 이상의 성분을 0.01% 내지 1% 함유하는 아연 인산염 피막을 가지며, 아연 인산염 피막의 부착 값은 0.7g/m 2 이상이다. The present invention can secure sufficient white rust resistance and non-uniform dew condensation resistance without requiring sealing chromate treatment, and has high whiteness and excellent color tone uniformity. Provide zinc phosphate treated galvanized steel sheet. The galvanized steel sheet according to the present invention has a zinc phosphate film containing 0.01% to 1% of at least 2% of Mg and at least one component selected from the group consisting of Ni, Co and Cu, and the adhesion value of the zinc phosphate film is 0.7g / m 2 or more.

Method of simultaneous degreasing, pickling and phosphatizing of metal surfaces

Изобретение относитс  к химической обработки металлов , в частности, к фосфатированию перед окраской электроосаждением, и может быть использовано в машино- и приборостроении. Цель изобретени  - сокращение времени обработки и уменьшение теплозатрат при одновременном повышении коррозионной стойкости фосфатного покрыти . Обработку провод т в растворе, содержащем, г/л: препарат "Мажеф" 30-40, азотнокислый цинк 50-70, моющее средство 3-6, триэтаноламмониева  соль 4 трифторметил-3,6-диоксаперфтороктансульфокислоты (хромаксамин "Т")-0,05-0,1, при 60-65°С в течение 8-10 мин. Сокращение времени обработки и уменьшение теплозатрат при одновременном повышении коррозионной стойкости фосфатного покрыти  достигаетс  введением хромаксамина "Т". 1 табл. The invention relates to the chemical treatment of metals, in particular, to phosphating before painting by electrodeposition, and can be used in machine building and instrument making. The purpose of the invention is to reduce the processing time and reduce heat consumption while increasing the corrosion resistance of the phosphate coating. The treatment is carried out in a solution containing, g / l: drug "Mazhef" 30-40, zinc nitrate 50-70, detergent 3-6, triethanol ammonium salt 4 trifluoromethyl-3,6-dioxaperfluorooctanesulfonic acid (chromaxamine T) - 0 , 05-0.1, at 60-65 ° C for 8-10 minutes. A reduction in processing time and a decrease in heat consumption, while simultaneously increasing the corrosion resistance of the phosphate coating, is achieved by introducing Chromaxamine T. 1 tab.

钴、锌、铁三元体系磷酸盐金属表面处理剂、制备方法及复合沉积物

本发明公开了一种钴、锌、铁三元体系磷酸盐金属表面处理剂，及其制备方法，以及该金属表面处理剂应用后形成的复合沉积物。专门针对热镀锌件表面氧化物问题的终极设计，同时解决热镀锌件出钢厂表面防腐处理(传统为油封、三价铬、耐指纹膜)和涂装前增强附着力表面处理(现时锌‑锰二元系或陶化硅烷工艺)合二为一，以彻底解决热镀锌件表面防护的世纪难题。

用含酸基团的聚合物钝化金属表面的方法

本发明涉及一种通过用含有至少一种水溶性的含酸基团的聚合物，以及Zn、Ca、Mg或Al离子的酸性含水组合物处理金属表面而钝化所述表面的方法，所述方法尤其为一种钝化金属带的连续方法。

用于有效磷化金属表面的替换组合物和替换方法

本发明涉及一种用于有效磷化金属表面的替换酸性含水组合物，所述组合物除了锌离子、锰离子、磷酸根离子和优选镍离子外还包含至少一种式R 1 R 2 R 3 C‑NO 2 的促进剂，其中碳原子上的取代基R 1 、R 2 和R 3 各自彼此独立地选自由如下组成的组：羟甲基、1‑羟乙基、2‑羟乙基、1‑羟丙基、2‑羟丙基、3‑羟丙基、1‑羟基‑1‑甲基乙基和2‑羟基‑1‑甲基乙基。本发明还涉及一种制备该组合物的方法、一种用于磷化金属表面的替换方法以及由其生产的磷酸盐涂层的用途。

Method of forming phosphate film on metal surface

Brightening/passivating metal surfaces without hazard from emissions of oxides of nitrogen

금속 표면, 특히 철 및 강철을 위한, 무(無)크롬 및 무(無)질소 브라이트닝화 및 부동화 처리물은 하기를 함유하는 것을 특징으로 한다: Chrome-free and nitrogen-free brightening and passivating treatments for metal surfaces, especially iron and steel, are characterized by containing: 하나 이상의 산; One or more acids; 퍼옥시 부분을 포함하는 하나 이상의 물질; 및 One or more materials including peroxy moieties; And 하기로 이루어진 군에서 선택되는 하나 이상의 유기 물질: 하나 이상의 에테르 부분 및 하나 이상의 히드록실 부분 모두를 각 분자 내에 포함하는 분자로 구성된 물질; 둘 이상의 에테르 부분을 각 분자 내에 포함하는 분자로 구성된 물질: 및 하나 이상의 에테르 부분, 및 셋 이상의 탄소 원자에 공유 결합된 하나의 질소 원자 모두를 각 분자 내에 포함하는 분자로 구성된 물질. At least one organic material selected from the group consisting of: a material consisting of a molecule comprising both at least one ether moiety and at least one hydroxyl moiety in each molecule; A material consisting of a molecule comprising two or more ether moieties in each molecule: and a material consisting of a molecule comprising all of one or more ether moieties and one nitrogen atom covalently bonded to three or more carbon atoms in each molecule. 바람직하게는, 상기 산의 일부는, 상기 유기 물질과 공동으로 작용하여, 특히 금속 이온의 존재 하에서 퍼옥시 화합물을 분해에 대하여 안정화시키는 것으로 발견된, 인을 함유한다. Preferably, part of the acid contains phosphorus, which has been found to work in concert with the organic material, in particular to stabilize the peroxy compound against degradation in the presence of metal ions.

無段変速機用無端金属ベルト

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Способ получения фосфатного покрытия

Изобретение относится к защите металлов от коррозии и может быть использовано в машиностроении, приборостроении и других отраслях промышленности. Способ включает обработку поверхность металла водным раствором фосфатирования при температуре от плюс 35 до плюс 50°С за время от 2 до 10 минут. При этом используют водный раствор фосфатирования, обладающий стабильностью при температуре до 50°С и содержащий следующие компоненты, г/л: Zn1,53-3,27, PO4,35-8,64, NO1,41-4,30, Na0,15-0,28, Ni0,02-0,11, F0,75-0,85, SiF0,20-0,25, вода – остальное. Причем перед применением водный раствор фосфатирования корректируют 20%-ным водным раствором гидроокиси натрия до отношения условно-общей кислотности к свободной кислотности от 5,2 до 5,4. Техническим результатом изобретения является получение мелкокристаллического фосфатного покрытия, обладающего высокой адгезией и высокой коррозионной стойкостью, а также низкая норма расхода используемого водного раствора фосфатирования при температуре применения от плюс 35 до 50°С и возможность его применения с помощью распыления и погружения. 4 пр. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 690 876 C1 (51) МПК C23C 22/07 (2006.01) C23C 22/13 (2006.01) C23C 22/36 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C23C 22/07 (2019.02); C23C 22/13 (2019.02); C23C 22/36 (2019.02) (21)(22) Заявка: 2018122003, 14.06.2018 (24) Дата начала отсчета срока действия патента: Дата регистрации: 06.06.2019 (45) Опубликовано: 06.06.2019 Бюл. № 16 2 6 9 0 8 7 6 (54) Способ получения фосфатного покрытия (57) Реферат: Изобретение относится к защите металлов от коррозии и может быть использовано в машиностроении, приборостроении и других отраслях промышленности. Способ включает обработку поверхность металла водным раствором фосфатирования при температуре от плюс 35 до плюс 50°С за время от 2 до 10 минут. При этом используют водный раствор фосфатирования, обладающий стабильностью при температуре до 50°С и содержащий ...

Acid aqueous compositions and concentration in order to make zinc phosphate coating on the meal plate

옥심 촉진제를 함유한 인산아연 피복제 조성물을 개시한다. 상기 옥심 촉진제는 환경적으로 친화성이 있고, 인산아연 피복제 조성물의 산성 환경에서 안정하여 단일 포장 시스템의 제조를 가능하게 한다. A zinc phosphate coating composition containing an oxime promoter is disclosed. The oxime promoter is environmentally friendly and stable in the acidic environment of the zinc phosphate coating composition to enable the manufacture of a single packaging system.

一种铜件表面的钝化处理液

本发明涉及一种铜件表面的钝化处理液，所述钝化处理液由苯并三氮唑3～7g/L、磷酸钠180～220mg/L、柠檬酸6～12g/L、胶体二氧化硅60～90mg/L和润湿剂5～7ml/L构成；其中，润湿剂是由聚乙二醇和聚乙烯醇混合而成的，且聚乙二醇和聚乙烯醇的质量比为1.7～2.3:1。本发明的优点在于：通过各组分的协同作用，大大提高了钝化处理液的抗湿热性能，且钝化处理也中，不含铬离子，大大增强了环保性能，同时，也不含有昂贵的原料，进而大大降低了钝化处理液的成本。

Conditioning of surface prior to chemical conversion treatment of steel part

FIELD: technological processes. SUBSTANCE: invention is related to processing of steel parts prior to phosphate chemical conversion treatment. Steel part for conditioning of its surface is treated with water solution that contains tetraborate of alkaline metal and does not contain phosphate ions. Further manganese phosphate is used to perform phosphate chemical conversion treatment of steel part. Steel part with processed surface has chemical conversion coating of manganese phosphate with average diameter of crystalline particles 10-110 micrometer. Invention allows to form phosphate chemical conversion coating that gives to thread connection made of high-chromium steel or of stainless steel with content of Cr of at least 10 weight % resistance to abrasion with no sublayer necessary. EFFECT: preparation of phosphate chemical conversion coating that gives abrasion resistance to threaded joint. 6 cl, 2 dwg, 7 tbl, 7 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 333 292 (13) C2 (51) ÌÏÊ C23C 22/78 C23C 22/07 C23C 22/18 (2006.01) (2006.01) (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2006119435/02, 06.12.2004 (72) Àâòîð(û): ÈÇÀÂÀ Ìàñàðó (JP), ÃÎÒÎ Êóíèî (JP), ÓÄÇÈÒÀ Åñèõèñà (JP), ÒÀÊÀÍÎ Òàêàõèðî (JP) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 06.12.2004 (73) Ïàòåíòîîáëàäàòåëü(è): ÑÓÌÈÒÎÌÎ ÌÅÒÀË ÈÍÄÀÑÒÐÈÇ, ËÒÄ. (JP) (43) Äàòà ïóáëèêàöèè çà âêè: 10.12.2007 R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 04.12.2003 JP 2003-406017 (45) Îïóáëèêîâàíî: 10.09.2008 Áþë. ¹ 25 2 3 3 3 2 9 2 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: Ðóêîâîä ùèé ìàòåðèàë ìèíèñòåðñòâà ÐÌÎ 1434-64. Ïîêðûòè ãàëüâàíè÷åñêèå è õèìè÷åñêèå. Òåõíîëîãè÷åñêèå ïðîöåññû. 1966, ñ.269-277. RU 2138439 C1, 27.09.1999. RU 2213803 Ñ2, 10.10.2003. JP 2003231974 À, 19.08.2003. (86) Çà âêà PCT: JP 2004/018123 (06.12.2004) C 2 C 2 (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 02.06.2006 R U 2 3 3 3 2 9 2 (87) Ïóáëèêàöè ...

Article having a chip-resistant electrodeposited coating and a process for forming an electrodeposited coating

An electrodeposition process is provided for applying an elastomeric thermosetting, film-forming polymer to a corrosion-resistant electrically conductive substrate that is free of an electrodeposited coating. The elastomeric polymer typically is a polyurethane, a polyurea or a poly(urethane urea). The film-forming coating applied by this process provides chip resistance to the substrate. A coated article that is prepared according to the process is also provided.

亜鉛の表面被覆改良方法

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

一种无酸洗磷化液及其配制方法

本发明涉及电化学技术领域，具体涉及金属表面处理技术，更进一步涉及一种无酸洗磷化液和无酸洗磷化液的配制方法。无酸洗磷化液主要成分为由下列反应物反应生成的产物：氧化锌10‑20％、硝酸铁5‑10％、硝酸镍1‑5％、磷酸35‑40％、硝酸20‑30％、水10‑15％。本发明在磷化工艺前的预处理采用盘元抛丸机进行抛丸清理基础上，对无酸洗磷化液的配制方法进行了改进，改进后的无酸洗磷化液，使加工件表面所形成的磷化膜结晶致密、均匀、细致、密实，磷化膜不易脱落，同时磷化膜表面无挂灰、反白现象产生，具有抑制加工件因酸洗后缝隙残留酸根而产生腐蚀出现裂痕问题的出现，具有抗腐蚀性。

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Phosphating method

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Copper coating

일반적으로 구리인 금속 표면을 과산화수소, 무기산, 트리아졸, 테트라졸 또는 이미다졸 등의 부식 억제제 및 사차 암모늄 표면활성제를 포함하는 접착성 증진 조성물을 사용함으로서 중합 물질의 접착력을 향상시키기 위해 미세하게 거칠게(micro-roughened)한다. The metal surface, which is generally copper, is finely roughened to improve adhesion of the polymeric material by using an adhesion promoting composition comprising a corrosion inhibitor such as hydrogen peroxide, an inorganic acid, triazole, tetrazole or imidazole and a quaternary ammonium surfactant. micro-roughened).

Composition for phosphatizing metallic surface

Изобретение относитс  к химической обработке поверхности металлов, в частности к составам дл  нанесени  фосфатного сло  под лакокрасочные покрыти , и может быть использовано в машиностроении, энергомашиностроении, электро- и радиотехнике. Целью изобретени   вл етс  повышение коррозионной стойкости фосфатного покрыти  в комплексе с лакокрасочным. Раствор содержит (г/л): О, 3-4,8ч; Ni 0,03-1,2; N0 0,2-10; 1,5-19; левулинова  кислота 0,001-0,2; С10, 0,01-1,5; изатин 0,0002-0,1; вода - остальное. Повышение коррозионной стойкости фосфатного покрыти  в комплексе с лакокрасочньм достигаетс  i введением в раствор ионов хлората и изатина. I табл. 1 (/) С The invention relates to the chemical treatment of the surface of metals, in particular to compositions for applying a phosphate layer under a paint and varnish coating, and can be used in mechanical engineering, power plant engineering, electrical and radio engineering. The aim of the invention is to increase the corrosion resistance of the phosphate coating in combination with the paint and varnish. The solution contains (g / l): O, 3-4,8 h; Ni 0.03-1.2; N0 0.2-10; 1.5-19; levulinic acid 0.001-0.2; C10, 0.01-1.5; isatin 0.0002-0.1; water - the rest. An increase in the corrosion resistance of the phosphate coating in combination with the paint-and-lacquer coating is achieved by the introduction of chlorate and isatin ions into the solution. Table I 1 (/) С

Patent JPS5811515B2

금속 표면의 인산염 처리방법 및 처리액

본 발명은 강 및/또는 아연도금강과 알루미늄 합금과의 조합에 의해 얻어지는 금속 표면을 하기 조건을 만족하는 인산염 용액으로 화성처리하는 방법을 제공한다 : 2.0 Na이온+K이온 15.0(g/ℓ), 1.0 Mn이온+Ni이온 5.0(g/ℓ), 1.6-0.02T Zn이온 2.5-0.02T(g/ℓ), 3.2T -1 유리 F이온 8.0T -1 (g/ℓ), 0.014R-0.02(유리 F이온) -1 유리 산도 0.027T-0.02(유리 F이온) -1 (g/ℓ)(이때, T는 처리액 온도(℃)를 의미한다.)

Method for improving surface coating of zinc

Cr-FREE SURFACE TREATMENT COMPOSITIONS AND SURFACE TREATED GALVANIZED STEEL SHEET USING THEREOF

본 발명은 유해물질인 크롬(Cr)을 배제한 크롬-프리(Cr-free) 표면처리 조성물 및 이를 피복한 용융아연도금강판에 관한 것이다. 본 발명에 따른 크롬-프리 표면처리 조성물을 이용하여 도금강판의 도금층 상부에 피막을 형성시킴으로써, 내식성, 내흑화성 및 내지문성을 우수하게 갖는 강판을 제공하는 효과가 있다. The present invention relates to a chrome-free surface treatment composition excluding chromium (Cr) which is a harmful substance, and a hot-dip galvanized steel sheet coated with the same. There is an effect of providing a steel sheet excellent in corrosion resistance, blackening resistance and transparency by forming a coating on the plating layer of the coated steel sheet using the chrome-free surface treatment composition according to the present invention.

Process for priming aluminum materials and primers

본 발명은 알루미늄, 지르코늄, 세륨, 크롬 및 철에서 선택된 금속질산염화합물을 함유하는 프라이머를 알루미늄 재료의 표면에 도포하여 금속부착량이 1.0mM/m 2 이상이 되게 하고 그 프라이머를 베이킹 처리 단계를 포함하는 알루미늄 재료의 프라이밍 방법에 관한 것이며, 또한 수용성 아크릴산계 중합체를 고형분 농도로써 3.5~22.5g/ℓ, 알루미늄, 지르코늄, 세륨, 크롬 및 철에서 선택된 금속질산염화합물을 30~500g/ℓ, 플루오르화수소산계화합물을 플루오르 원소로써 1.0~5.0g/ℓ, 및 유기 환원제를 5~30g/ℓ의 범위로 함유하는 알루미늄재의 프라이머에 관한 것이다. 본 발명은 알루미늄재의 표면에 프라이머를 도포하여 우수한 내식성을 갖게 해준다. The present invention is to apply a primer containing a metal nitrate compound selected from aluminum, zirconium, cerium, chromium and iron to the surface of the aluminum material so that the metal adhesion amount is 1.0mM / m 2 or more and the primer comprising a baking treatment step It relates to a priming method of aluminum material, and also water-soluble acrylic acid polymer as a solid content concentration of 3.5 ~ 22.5g / L, metal nitrate compounds selected from aluminum, zirconium, cerium, chromium and iron 30 ~ 500g / L, hydrofluoric acid compounds The present invention relates to a primer of an aluminum material containing 1.0 to 5.0 g / l as an fluorine element and an organic reducing agent in the range of 5 to 30 g / l. The present invention provides a good corrosion resistance by applying a primer on the surface of the aluminum material. 프라이머*금속질산염화합물*수용성 아크릴산계 중합체*유기 환원제*플루오르화수소산계화합물 Primer * Metal Nitrate Compound * Water Soluble Acrylic Acid Polymer * Organic Reducing Agent * Hydrofluoric Acid Compound

Phosphate chemical treatment liquid

Conversion layers for surfaces containing zinc

本发明涉及生产防止腐蚀的涂层的方法，其中需要处理的表面与水性处理溶液进行接触，该溶液含有至少一种铬(III)离子源以及在弱酸性或酸性溶液中作为锌的氧化剂的至少一种有机化合物。这里，表面的装饰效果和功能性能得以保留或改进。另外，与含铬(VI)的化合物的使用相关的已知问题得到避免。

Phosphate coatings for metal surfaces.

Process for phosphating steel strips galvanized on one side

A process is disclosed for phosphatizing the zinc-coated surface of a steel strip electrolytically zinc-coated on one side only by a short spraying or immersion treatment with acid phosphatizing solutions which contain 1.0 to 6.0 g/l Zn<2+> cations, 0.5 to 5.0 g/l Ni<2+> cations and 14 to 25 g/l PO4<3> anions. The "free acid" content amounts to 3.5 to 8.0 points; the total acid content amounts to 22 to 40 points.

Solution for phosphotizing aluminium and its alloys

Copper-containing solution for prewashing yttrium-containing electroplating composition to improve anticorrosion protection

FIELD: chemistry. SUBSTANCE: invention relates to a method of electroplating a substrate that has not undergone pretreatment. The method includes (a) contacting at least part of substrate material with a solution containing a copper source and water, where the solution is substantially free of a group IIIB metal source and a group IVB metal source, (b) bringing at least part of the substrate into contact with an electroplating composition containing (i) a film-forming resin and (ii) a yttrium source. Also described is a coated substrate and a method of electroplating a substrate, which includes (a) contacting at least part of substrate material with a solution containing a copper source, water and at least one substance selected from acids and surfactants, followed by contacting at least part of the substrate with an electroplating composition. EFFECT: corrosion resistance of the substrate material without a compulsory pretreatment step. 20 cl, 9 tbl, 10 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 548 972 C2 (51) МПК C09D 5/44 (2006.01) C09D 5/00 (2006.01) C09D 163/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013106266/05, 12.07.2011 (24) Дата начала отсчета срока действия патента: 12.07.2011 (72) Автор(ы): ЗИГЛЕР Терри Л. (US), МАКМИЛЛЕН Марк (US) (73) Патентообладатель(и): ППГ ИНДАСТРИЗ ОГАЙО, ИНК. (US) Приоритет(ы): (30) Конвенционный приоритет: (43) Дата публикации заявки: 20.08.2014 Бюл. № 23 R U 14.07.2010 US 12/835,788 (45) Опубликовано: 20.04.2015 Бюл. № 11 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 14.02.2013 C 2 C 2 2006/109862 A1, 19.10.2006. US 2009101512 A1, 23.04.2009. US2008145678 A1, 19.06.2008. WO 2009/045558 A2, 09.04.2009. WO 2008/127744 A2, 23.10.2008. WO 00/64991 A1, 02.11.2000. RU 2119830 C1, 10.10.1998. RU 2130010 C1, 10.05.1999 (86) Заявка PCT: US 2011/043702 (12.07.2011) 2 5 4 8 9 7 2 (87) Публикация заявки PCT: R U 2 5 4 8 9 7 2 (56) Список ...

COPPER-CONTAINING SOLUTION FOR PRELIMINARY RINSING OF ITTRY-CONTAINING ELECTRODEPENDABLE COATING COMPOSITION

1. Способ, включающий:(а) контактирование по меньшей мере части подложки с раствором, содержащим источник меди, где раствор по существу свободен от источника металла группы IIIB и источника металла группы IVB; ипосле стадии (а) стадию (b) - введение по меньшей мере части подложки в контакт с композицией электроосаждаемого покрытия, содержащей:(i) пленкообразующую смолу; и(ii) источник иттрия.2. Способ по п.1, в котором раствор, содержащий источник меди, содержит растворимое в воде соединение меди, растворенное в воде.3. Способ по п.2, в котором растворимое в воде соединение меди включает нитрат меди и/или сульфат меди.4. Способ по п.1, в котором раствор характеризуется значением рН, составляющим 6 и менее.5. Способ по п.1, в котором раствор, содержащий источник меди, дополнительно содержит кислоту.6. Способ по п.5, в котором кислота включает минеральную кислоту.7. Способ по п.6, в котором минеральная кислота включает фосфорную кислоту.8. Способ по п.1, в котором раствор, содержащий источник меди, дополнительно содержит поверхностно-активное вещество.9. Способ по п.8, в котором поверхностно-активное вещество содержит неионное поверхностно-активное вещество.10. Способ по п.9, в котором упомянутое неионное поверхностно-активное вещество содержит октилфенилэтоксилат.11. Способ по п.1, в котором раствор, содержащий источник меди, дополнительно содержит фосфорную кислоту и поверхностно-активное вещество.12. Способ по п.2, в котором медь в растворе содержится в количестве от приблизительно 5 до приблизительно 100 частей на миллион совокупного количества меди, согласно измерению содержания элементарной меди, в расчете на совокупную массу ингредиенто� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C09D 5/00 (13) 2013 106 266 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2013106266/05, 12.07.2011 (71) Заявитель(и): ППГ ИНДАСТРИЗ ОГАЙО, ИНК. (US) Приоритет(ы): (30) Конвенционный приоритет: 14.07.2010 US 12/835,788 (85) ...

Composition of concentrate for preparation of aqueous solution for deposition of coating, treatment of metal surfaces, aqueous solution for deposition of phosphate coating of crystalline structure to metal surface, method for phosphatization of metal surface and composition for replenishing of solution for deposition of coating

Использование: для покрытия различных металлических основ, включая холоднокатаную сталь, цинковые сплавы и алюминий. Сущность изобретения: состав концентрата включает фосфат ионы, ионы цинка, никеля, марганца, гидроксиламиновый ускоритель и воду. Наполняющий состав для добавления к раствору для нанесения покрытий, помимо указанных компонентов может дополнительно содержать карбонат или бикарбонат аммония или гидроксид аммония, в количестве, обеспечивающем сохранение уровня кислотности раствора. 4 с. и 14 з.п. ф-лы, 3 табл. сузео0тгс пы Го РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) ВИ "” 2109 845‘ (51) МПК 13) СЛ С 23С 22/36, 22/18, 22/12, 22/13 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 94012855/25, 22.07.1992 (30) Приоритет: 29.07.1991 Ш$ 07/736,835 (46) Дата публикации: 27.04.1998 (56) Ссылки: Ц5, патент, 4838957, кл. С 23 С 22/12, 1989. (86) Заявка РСТ: 1$ 9205861 (22.07.92) (71) Заявитель: Хенкель Корпорейшн (1$) (72) Изобретатель: Майкл Л.Синковски[Ц$], Джеральд Дж.Кормир[Ц$] (73) Патентообладатель: Хенкель Корпорейшн (1$) (54) СОСТАВ КОНЦЕНТРАТА ДЛЯ ПОЛУЧЕНИЯ ВОДНОГО РАСТВОРА ДЛЯ НАНЕСЕНИЯ ПОКРЫТИЯ ДЛЯ ОБРАБОТКИ МЕТАЛЛИЧЕСКИХ ПОВЕРХНОСТЕЙ, ВОДНЫЙ РАСТВОР ДЛЯ НАНЕСЕНИЯ ФОСФАТНОГО ПОКРЫТИЯ КРИСТАЛЛИЧЕСКОЙ СТРУКТУРЫ НА МЕТАЛЛИЧЕСКУЮ ПОВЕРХНОСТЬ, СПОСОБ ФОСФАТИРОВАНИЯ МЕТАЛЛИЧЕСКОЙ ПОВЕРХНОСТИ И ПОПОЛНЯЮЩИЙ СОСТАВ ДЛЯ ДОБАВЛЕНИЯ К РАСТВОРУ ДЛЯ НАНЕСЕНИЯ ПОКРЫТИЯ (57) Реферат: Использование: для покрытия различных металлических ОСНОВ, включая холоднокатаную сталь, цинковые сплавы и алюминий. Сущность изобретения: состав концентрата включает фосфат ионы, ионы цинка, никеля, марганца, гидроксиламиновый ускоритель и воду. Наполняющий состав для добавления к раствору для нанесения покрытий, помимо указанных компонентов может дополнительно содержать карбонат или бикарбонат аммония или гидроксид аммония, в количестве, обеспечивающем сохранение уровня кислотности раствора. 4 с. и 14 з.п. ф-лы, 3 табл. 2109845 С1 КО сузео0тгс пы ...

Method of producing protective composite coating on steel part

FIELD: technological processes. SUBSTANCE: invention relates to chemical surface treatment. Method involves successive application on surface of part of two layers of coating, each of which is formed by depositing aluminum powder in solution of inorganic binder by dyeing with subsequent thermo hardening of applied coating layer and machining of part with applied coating layer. Suspension of aluminum powder is used in solution of inorganic binder, prepared from following components, wt%: aluminum hydroxide 1.2-1.6, solution of 85% orthophosphoric acid 4.7-5.5, magnesium oxide 0.12-0.16, potassium permanganate 0.25-0.33, aluminum powder 45.0-55.0, sodium silicate or potassium silicate 0.25-0.37, distilled water - balance. Inorganic binder is distilled water to specific density of 1.20-1.30 g/cm 3 . Thermosetting is followed by additional treatment with corundum powder at pressure of 2 to 3 bar. EFFECT: high protective capacity of the obtained coating from corrosion with simultaneous reduction of the thickness of the coating, hardening temperature of up to 200°C, simple process of applying protective coating, as well as avoiding use of substances of 1st class of hazard. 1 cl, 2 dwg, 2 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (51) МПК C23C 22/07 C23C 22/18 C23C 22/82 C23C 24/00 C23C 28/00 (11) (13) 2 737 838 C1 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C23C 22/07 (2020.08); C23C 22/18 (2020.08); C23C 22/82 (2020.08); C23C 24/00 (2020.08); C23C 28/00 (2020.08) (21)(22) Заявка: 2020112655, 27.03.2020 27.03.2020 Дата регистрации: Приоритет(ы): (22) Дата подачи заявки: 27.03.2020 (56) Список документов, цитированных в отчете о поиске: US 6074464 A1, 13.06.2000. RU 2714007 C2, 11.02.2020. RU 2627823 C2, 11.08.2017. RU 2036978 C1, 09.06.1995. RU 2510716 C2, 10.04.2014. US 20100288158 A1, 18.11.2010. SU 1560621 A1, 30.04.1990. 2 7 3 7 8 3 8 R U Адрес для переписки: 105118, Москва, ...

Zinc phosphate coating compositions containing oxime accelerators

本发明公开了含有一种肟加速剂的磷酸锌涂料组合物。该肟加速剂不会损害环境并且在可以形成单包装系统的磷酸锌涂料组合物的酸性环境中是稳定的。

Steel plate for containers excellent in organic film performance and method for producing the same

Procedure for forming thin corrosion inhibiting coating on metal surface

Изобретение относится к нанесению покрытий на металлические поверхности из фосфорсодержащих растворов. Способ включает контактирование металлической поверхности при температуре не выше 45°С и при величине рН менее 3,5 с водным кислотным фосфатирующим раствором или дисперсией с ионами щелочных металлов, содержащими соединение фосфорсодержащей кислоты и/или ее производных, подобных сложным эфирам и солям, при общем содержании всех видов кислот и всех их производных, подобных сложным эфирам и солям, вместе менее 20 г/л из расчета на моль основания ортофосфата, при этом содержание фосфорсодержащих соединений/ионов составляет, по меньшей мере, 50% по массе от всех таких соединений/ионов, также ион, выбранный из группы, состоящей из, по меньшей мере, одного иона щелочного металла и иона аммония, и ускоритель на основе гуанидина в общем количестве 0,01-5 г/л, свободный фторид в количестве от 0,01 до 1 г/л или не содержащими свободный фторид, при этом не содержат других тяжелых металлов, отличных от тех, которые будут вытравляться из металлической поверхности, возможно, за исключением добавления ионов Fe 2+ . Получаемое покрытие имеет содержание фосфора не более 8 атомных %, а его вес составляет от 0,01 до 0,5 г/м 2 . Способ фосфатирования является стабильным, хорошо подходит для промышленного применения для фосфатирования рулонов, деталей и проводов, а также более легкий и дешевый по сравнению с используемыми способами. Фосфатное покрытие имеет превосходный внешний вид и хорошую коррозионную стойкость. 3 н. и 17 з.п. ф-лы, 7 ил., 10 табл. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 358 035 (13) C2 (51) МПК C23C 22/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21), (22) Заявка: 2005123323/02, 18.12.2003 (24) Дата начала отсчета срока действия патента: 18.12.2003 (72) Автор(ы): ДИМЕР Майкл (US), КУПЕР Ченард (US) (43) Дата публикации заявки: 10.02.2006 2 3 5 8 0 3 5 (45) Опубликовано: 10.06.2009 Бюл ...

Surface treatment composition for aluminum-containing metal material and surface treatment method

Composition for anticorrosive phosphate coatings formation on steel surface

FIELD: chemistry. SUBSTANCE: proposed composition for the anticorrosive phosphate coatings on the steel surface formation contains, %: zinc oxide 0.8-1.0, phosphoric acid 1.84-2.0, nitric acid 0.78-0.9, cerium sulfuric acid (in terms of metal) - 0.006-0.012; hydroxylamine sulfuric acid - 0.5-1.0 and water - the rest. Phosphating of steel products, using the composition, is performed at the solution temperature of 20-30°C for 6-12 minutes, followed by the drying at the temperature of 60-160°C. EFFECT: composition provides the phosphate coatings on the steel surface formation, with high corrosion resistance and protective ability, at that the presence of the cerium ions in the composition contributes to the formation of practically nonporous phosphate coatings on the steel surface, which prevent the water and chloride ions penetration. 1 tbl, 6 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 633 427 C1 (51) МПК C23C 22/13 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2016146765, 29.11.2016 (24) Дата начала отсчета срока действия патента: 29.11.2016 Дата регистрации: Приоритет(ы): (22) Дата подачи заявки: 29.11.2016 (45) Опубликовано: 12.10.2017 Бюл. № 29 (56) Список документов, цитированных в отчете о поиске: CN 100478495 C, 15.04.2009. SU 2 6 3 3 4 2 7 R U (54) КОМПОЗИЦИЯ ДЛЯ ФОРМИРОВАНИЯ ПРОТИВОКОРРОЗИОННЫХ ФОСФАТНЫХ ПОКРЫТИЙ НА СТАЛЬНОЙ ПОВЕРХНОСТИ (57) Реферат: Изобретение относится к области защиты от минут с последующей сушкой при температуре коррозии стальных изделий. Предложенная 60-160°С. Композиция обеспечивает композиция для формирования формирование на стальной поверхности противокоррозионных фосфатных покрытий на фосфатных покрытий, обладающих высокой стальной поверхности содержит, %: оксид цинка коррозионной стойкостью и защитной – 0,8-1,0, фосфорную кислоту – 1,84-2,0, азотную способностью, причем присутствие в составе кислоту – 0,78-0,9, церий сернокислый (в пересчете композиции ионов ...

Patent JPS506418B1

Steel plate surface phosphatization treatment agent

本发明涉及一种钢板表面的磷化处理剂，由以下组份组成：马来酸酐6-9份、磷酸铵5-8份、硫酸1-2份、氯化锌3-5份、五氟化砷0.1-0.2份、次氯酸钾1-2份、水55-60份，本发明的磷化处理剂中，成膜稳定性好，大大提高了磷化处理后磷化膜的致密性和均匀性，提高了钢板的耐腐蚀性和耐磨性，可以在较低的温度下处理，处理温度在33-40℃，时间缩短到1-3min，提高了磷化的效率。

METHOD FOR PRODUCING A THIN THIN INHIBITING CORROSION COATING ON A METAL SURFACE

ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß (19) RU (11) 2005 123 323 (13) A (51) ÌÏÊ C23C 22/08 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÇÀßÂÊÀ ÍÀ ÈÇÎÁÐÅÒÅÍÈÅ (21), (22) Çà âêà: 2005123323/02, 18.12.2003 (71) Çà âèòåëü(è): Øåìåòàëë ÃìáÕ (DE) (30) Ïðèîðèòåò: 24.12.2002 US 10/328,924 (43) Äàòà ïóáëèêàöèè çà âêè: 10.02.2006 Áþë. ¹ 4 (74) Ïàòåíòíûé ïîâåðåííûé: Êâàøíèí Âàëåðèé Ïàâëîâè÷ (86) Çà âêà PCT: EP 03/14577 (18.12.2003) Àäðåñ äë ïåðåïèñêè: 105064, Ìîñêâà, óë. Êàçàêîâà, 16, ÍÈÈÐ Êàíöåë ðè "Ïàòåíòíûå ïîâåðåííûå Êâàøíèí, Ñàïåëüíèêîâ è ïàðòíåðû", ïàò.ïîâ. Â.Ï.Êâàøíèíó R U ÌÅÒÀËËÈ×ÅÑÊÎÉ ÏÎÂÅÐÕÍÎÑÒÈ Ôîðìóëà èçîáðåòåíè 1. Ñïîñîá äë ïîêðûòè ìåòàëëè÷åñêèõ ïîâåðõíîñòåé ïîêðûòèåì ôîñôàòèðîâàíèåì ïóòåì êîíòàêòà ìåòàëëè÷åñêèõ ïîâåðõíîñòåé ïðè òåìïåðàòóðå íå âûøå 45°Ñ è ïðè âåëè÷èíå ðÍ ìåíåå 3,5 ñ âîäíûì êèñëîòíûì ôîñôàòèðóþùèì ðàñòâîðîì ñ èîíàìè ùåëî÷íûõ ìåòàëëîâ èëè äèñïåðñèåé, ñîäåðæàùèìè: ïî ìåíüøåé ìåðå, îäíî ñîåäèíåíèå èç, ïî ìåíüøåé ìåðå, îäíîé ñîäåðæàùåé ôîñôîð êèñëîòû è/èëè, ïî ìåíüøåé ìåðå, îäíîãî èç åå ïðîèçâîäíûõ, ïîäîáíûõ ñëîæíûì ýôèðàì è ñîë ì, ïðè îáùåì ñîäåðæàíèè âñåõ âèäîâ êèñëîò è âñåõ èõ ïðîèçâîäíûõ, ïîäîáíûõ ñëîæíûì ýôèðàì è ñîë ì, âìåñòå ìåíåå 20 ã/ë èç ðàñ÷åòà íà ìîëü îñíîâàíè îðòîôîñôàòà, ãäå ñîäåðæàíèå òàêèõ ñîäåðæàùèõ ôîñôîð ñîåäèíåíèé/èîíîâ ñîñòàâë åò, ïî ìåíüøåé ìåðå, 50% ïî ìàññå îò âñåõ òàêèõ ñîåäèíåíèé/èîíîâ è ïî ìåíüøåé ìåðå, îäèí èîí, âûáðàííûé èç ãðóïïû, ñîñòî ùåé èç, ïî ìåíüøåé ìåðå, îäíîãî èîíà ùåëî÷íîãî ìåòàëëà è èîíà àììîíè , ãäå ôîñôàòèðóþùèé ðàñòâîð èëè äèñïåðñè íå ñîäåðæèò õðîìàòîâ, ìîëèáäàòîâ, íèîáàòîâ, òàíòàëàòîâ è âîëüôðàìàòîâ, ãäå ïîêðûòèå ôîñôàòèðîâàíèåì èìååò ñîñòàâ ïîêðûòè ñ ñîäåðæàíèåì ôîñôîðà íå áîëåå 8 àò.%, êàê èçìåðåíî ìåòîäîì âòîðè÷íîé íåéòðàëüíîé ìàñññïåêòðîñêîïèè (ÂÍÌÑ) è ãäå ïîêðûòèå ôîñôàòèðîâàíèåì èìååò âåñ ïîêðûòè â èíòåðâàëå îò 0,01 äî 0,5 ã/ì 2. 2. Ñïîñîá ïî ï.1, ãäå ôîñôàòèðóþùèé ðàñòâîð èëè äèñïåðñè ñîäåðæàò, ïî ìåíüøåé ìåðå, îäèí óñêîðèòåëü, ïîäîáíûé òàêîâîìó íà îñíîâå õëîðàòà, ...

Composition for treatment of steel zinc aluminium and alloy thereof surfaces

The composition, according to this invention, is 57.3 wt.% phosphoric acid; 5.4 wt% urea; an inhibitor that is selected from tiourea, total 0.5 wt.% of chromium, nickel, cobalt, copper, zinc; and more than one species of transition metal salt, which is selected from manganese.

continuous painting method using eco-friendly surface treatment agent

친환경적이면서도 피막성능이 개선되도록, 본 발명은 철계, 알루미늄계 또는 도금강판 중 어느 하나로 선택되는 대상체의 도장전 표면처리를 위하여, 상기 대상체의 표면에 인산염 피막이 형성되도록 불소화합물이 0.1~20 중량% 사용된 피막제 조성원액을 용매에 희석시 pH가 1.0~5.0인 표면처리제로 조성되되, 상기 표면처리제의 전산도가 상기 표면처리제 시료 10ml에 대한 0.1N-NaOH 소비량으로 10~40ml이 되도록 조성됨을 특징으로 하는 저농도 불소를 이용한 친환경 표면처리제를 제공한다. In order to be eco-friendly and to improve the film performance, the present invention uses 0.1 to 20% by weight of a fluorine compound so that a phosphate film is formed on the surface of the object for surface treatment before painting of an object selected from any one of iron-based, aluminum-based, or plated steel sheet It is composed of a surface treatment agent having a pH of 1.0 to 5.0 when diluted in a solvent, and the total acidity of the surface treatment agent is 10 to 40 ml with 0.1N-NaOH consumption for 10 ml of the surface treatment agent sample. It provides an eco-friendly surface treatment agent using low-concentration fluorine.

Steel sheet for containers which exhibits excellent performance for organic layers and process for production thereof

제관 가공성이 우수한 동시에, 드로잉 아이어닝 가공성, 용접성, 내식성, 도료 밀착성, 필름 밀착성, 젖음성이 우수한 용기용 강판으로서, 강판 표면에, 금속 Zr량으로 1 내지 100 ㎎/㎡의 Zr 산화물을 포함하는 Zr 피막을 가진 것을 특징으로 한다.

Aqueous composition for preparing metal surface to subsequent cathode electrovarnishing by dipping

Process for the phosphating of metal surfaces, particularly iron and steel, with aqueous, acid phosphating solutions. Along with zinc and phosphate ions, the solutions contain an activator combination of alkali metal bromate and m-nitrobenzolsulphonate. This new process is particularly well suited for the pretreatment of metal surfaces prior to cathodic electrobath lacquering. The acid phosphating solutions meet the following conditions: a) zinc content 1,2 to 2 g/l; b) bromate content 0.5 to 1 g/l; c) m-nitrobenzolsulphonate 0.2 to 0.5 g/l; d) weight ratio phosphate: zinc = (7 to 20) : 1; e) weight ratio phosphate : bromate = (14 to 48) : 1; f) weight ratio zinc : bromate = (1.2 to 4) : 1; g) weight ratio bromate : m-nitrobenzolsulphonate = (1 to 5) : 1; h) number of points total acid 18 to 25; i) number of points free acid 0.5 to 1; g) temperature 35 to 40<o>C.

Solution of phosphatisation with hydrogen peroxide and chelate forming carbonic acids

FIELD: metallurgy. ^ SUBSTANCE: acid water solution for phosphatisation contains from 0.2 to 3 g/l of ions of bivalent zinc, from 3 to 50 g/l of ions of phosphate in terms of PO3-Çè4, from 15 to 50 mg/l of hydrogen peroxide or equivalent amount of substance removing hydrogen peroxide, from 0.5 to 1.0 g/l of one or several aliphatic chelate forming carbonic acids containing from 2 to 7 of carbon atoms with maximal one point of contents of free acid. ^ EFFECT: accelerated formation of closed fine-crystalline phosphate coating on treated metal surface at simultaneous termination of rust formation. ^ 9 cl, 6 dwg, 1 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 428 518 (13) C2 (51) МПК C23C 22/17 C23C 22/18 C23C 22/36 (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2008116542/02, 16.08.2006 (24) Дата начала отсчета срока действия патента: 16.08.2006 (73) Патентообладатель(и): ХЕНКЕЛЬ АГ УНД КО.КГаА (DE) R U Приоритет(ы): (30) Конвенционный приоритет: 30.09.2005 DE 102005047424.1 (72) Автор(ы): БРОУВЕР Ян-Виллем (DE), ВАВЖИНЯК Ежи-Тадеуш (DE), КРЕМЕР Йенс (DE), ШЕНХЕРР Максимилиан (DE) (43) Дата публикации заявки: 10.11.2009 Бюл. № 31 2 4 2 8 5 1 8 (45) Опубликовано: 10.09.2011 Бюл. № 25 (56) Список документов, цитированных в отчете о поиске: RU 2051988 C1, 10.01.1996. DE 2342558 A1, 20.03.1975. DE 2818426 A1, 09.11.1978. DE 10310680 A1, 23.09.2004. RU 97118146 A, 10.08.1999. RU 2109845 C1, 27.04.1998. 2 4 2 8 5 1 8 R U (86) Заявка PCT: EP 2006/008063 (16.08.2006) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 30.04.2008 (87) Публикация заявки РСТ: WO 2007/039015 (12.04.2007) Адрес для переписки: 105064, Москва, а/я 88, "Патентные поверенные Квашнин, Сапельников и партнеры", пат.пов. В.П.Квашнину, рег.№ 4 (54) РАСТВОР ФОСФАТИРОВАНИЯ С ПЕРЕКИСЬЮ ВОДОРОДА И ХЕЛАТООБРАЗУЮЩИМИ КАРБОНОВЫМИ КИСЛОТАМИ количество вещества, отщепляющего перекись ...

Phosphonating liquid for cold deformation of iron and steel and its phosphonation process

一种钢铁冷变形加工的磷化液锌离子、镁离子、钠离子、磷酸根离子、硝酸根离子、硫酸根离子等组成;钢铁冷变形加工的磷化工艺包括待处理工件酸洗和水洗,磷化,风干,皂化,自然干燥步骤;本发明通过添加镁离子、钠离子等形成磷酸盐结晶的阳离子使生成的磷化膜更适合冷变形加工,添加硫酸根离子使生成的磷化膜易于连续拔管;本发明的磷化工艺所形成的涂层相当于一个“润滑剂”,不易在成型加工中被除去。

Blackened steel stheet with high adhesion property of blackened layer and surface appearance, and method for manufacturing the same

본 발명은 흑화층 밀착성이 개선되고, 표면외관이 우수한 흑색강판을 제공하고, 이를 용이하고, 친환경적으로 제조하는 방법을 제공하고자 하는 것이다. 이를 위해, 본 발명은 아연 또는 아연계 합금도금강판; 상기 아연 또는 아연계 합금도금강판의 표면에 형성된 Ni층; 및 상기 Ni층 위에 형성된 흑화층을 포함하는 흑화층 밀착성이 우수한 흑색강판과 이를 제조하는 방법을 제공한다. The present invention is to provide a black steel sheet with improved blackening layer adhesion, excellent surface appearance, and to provide a method for easily and eco-friendly manufacturing. To this end, the present invention is a zinc or zinc-based alloy plated steel sheet; Ni layer formed on the surface of the zinc or zinc-based alloy plated steel sheet; And It provides a black steel sheet excellent in blackening layer adhesion including a blackening layer formed on the Ni layer and a method of manufacturing the same.

Method of producing compound for phosphatization

Изобретение относитс  к защите металла от коррозии и может быть использовано в металлообрабатывающей и машиностроительной промышленности. Цель изобретени  - снижение температуры и продолжительности фосфатировани . Способ включает предварительное смешение дигидрофосфата цинка и нитрата натри  и/или магни  в соотношении P205/N03 -0,43 - 1,62 и последующее растворение смеси в воде в количестве 12-150 г/л. Снижение температуры и продолжительности фосфатировани  достигаетс  за счет предварительного смешени  компонентов. 1 табл. The invention relates to the protection of metal against corrosion and can be used in the metalworking and engineering industries. The purpose of the invention is to reduce the temperature and duration of phosphating. The method includes preliminary mixing of zinc dihydrogen phosphate and sodium and / or magnesium nitrate in the ratio P205 / N03 -0.43 - 1.62 and the subsequent dissolution of the mixture in water in the amount of 12-150 g / l. A decrease in the temperature and duration of phosphating is achieved by pre-mixing the components. 1 tab.

Method and composition for coating aluminium

내용 없음 No content

Corrosion-resistant aluminum alloy coating material

一种耐腐蚀铝合金涂层材料，铝合金表面上依次涂覆为等离子喷涂的TiMnN层和所述TiMnN层表面的磷化膜，其中所述TiMnN层的厚度为不大于3.5微米，所述磷化膜中的成分包括而不限于钛掺杂的Mn 3 (PO 4 ) 2 . 4H 2 O、钛掺杂的Zn 3 (PO4) 2 . 4H 2 O、钛掺杂的(Mn,Zn) 3 (PO4) 2 . 4H 2 O，通过等离子喷涂和后续磷化处理获得高耐腐蚀、高结合力的涂层，尤其涂层厚度大于2.5‑3.5微米时，也能维持较高的耐腐蚀性。

Formation of phosphate film

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Composition for treating metallic surface

FIELD: chemical industry, more particularly treatment of metallic surface of preferably large-size and intricately shaped structures. SUBSTANCE: claimed composition comprises (wt %) 50-60 85% orthophosphoric acid; 2.5-3.0 zinc nitrate; 3.0-4.0 potassium ferricyanide; 0.3-0.6 fluoro-carbon compound of formula: R f ZQ wherein R f is C 6 F 13 ; C 6 F 17 ; C 2 F 3 -OC 3 F 6 OC 2 F 4 -; Z is -CO-; SO 2 Q is NHC 2 H 4 OH; ; 6У0сСсЬс ПЧ Го РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) (51) МПК ВИ” 2 120 495 ' 13) СЛ С 23С 22/43, 22/36 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 97104509/02, 17.03.1997 (46) Дата публикации: 20.10.1998 (56) Ссылки: КЦ 2070945 С1 271296. ЗИ 324315 А 240212. ЕР 0645473 АЛ 290395. 4$ 5203930 А 200493. ОЕ 3628303 АЛ 120387. (71) Заявитель: Закрытое акционерное общество "РЕНТЕХ" (72) Изобретатель: Алмазова Э.А., Фреймарк М.В., Чернов Г.М. (73) Патентообладатель: Закрытое акционерное общество "РЕНТЕХ" (54) КОМПОЗИЦИЯ ДЛЯ ОБРАБОТКИ МЕТАЛЛИЧЕСКОЙ ПОВЕРХНОСТИ (57) Реферат: Композиция предназначена для обработки поверхности металла, преимущественно крупногабаритных и — сложнопрофильных конструкций, содержит — ортофосфорную кислоту (85%) 50,0 - 60,0 мас.%, нитрат цинка 2,5 - 3,0 мас.%, калий железистосинеродистый (желтая кровяная соль) 3,0 - 4,0 мас.%, фторуглеродное соединение общей формулы КО 0,3 - 0,6 мас.%, где № = -СёЁЕ4з -СёРт С 2Е3-ОСЗЕ6ОС2Ё4-: Г = -СО-; -$02-, @ = МНС 2Н4ОН: _ННС Н 3 6 с + — ССН 2 СТ ; к ты ОН 2 4 + ‚ Композиция образует на МНС Нм сСН_> 36| к. ен соо. 2 поверхности металла высокопрочное антикоррозионное покрытие, служащее грунтом для лакокрасочных материалов. Применение КОМПОЗИЦИИ не требует предварительной ОЧИСТКИ поверхности металла от ржавчины. 2 табл. 2120495 С1 КО 6У0сСсЬс ПЧ Го КУЗЗАМ АСЕМСУ ГОК РАТЕМТ$ АМО ТКАОЕМАКК$ 12) АВЗТКАСТ ОЕ 1МУЕМТОМ (19) ВИ "” 2 120 495 ' (51) 1пё С1.6 С 23 С 22/13, 22/36 13) СЛ (21), (22) АррИсаНоп: 97104509/02, 17.03.1997 (46) Бае ог ричбИсаНоп: 20.10. ...

Zinc-series low-slag phosphating agent and preparation method thereof

本发明涉及一种锌系低渣磷化剂，以水为溶剂，包括成膜物质、酸度调节剂、第一促进剂、第二促进剂、第三促进剂、螯合剂和络合剂，其重量比为：成膜物质21‑40％、酸度调节剂10‑20％、第一促进剂0.1‑0.5％、第二促进剂0.001‑0.01％、第三促进剂0.3‑0.8％、螯合剂0.5‑1.5％、络合剂1‑5％和余量的水。本发明在使用过程中能耗低、沉渣少、维护方便，经产品处理后形成的磷化膜的质量稳定，进而提高金属的综合性能。

Chemical treating method for iron phosphate film

Phosphate solution for galvanized steel sheet and phosphate treated galvanized steel sheet and as its method

(57)【要約】 【課題】 本発明は、良好な塗装後耐食性と白色度の高 い皮膜を形成することができる亜鉛系めっき鋼板のりん 酸塩処理液および該処理液を使用した白色度（Ｌ値）７ ０以上のりん酸塩処理鋼板を提供すること。 【解決手段】 （１）亜鉛系めっき鋼板のりん酸塩処理 する方法において、りん酸塩処理液中のＮＯ 3 - ：４〜 １０ｇ／Ｌ、Ｎｉ 2+ ：０．０１〜０．１４ｇ／Ｌ、Ｚｎ 2+ ：４〜７ｇ／Ｌ及びリンゴ酸、クエン酸、グルコン酸 及びその塩またはリン酸エステルの少なくとも１種以上 を溶液１Ｌ当り０．１〜１０ｇ／Ｌ含有し、りん酸塩処 理した後の亜鉛系めっき鋼板の外観の白色度（Ｌ値）が ７０以上になることを特徴とする亜鉛系めっき鋼板のり ん酸塩処理液。（２）上記（１）記載のりん酸塩処理液 を使用し、Ｚｎめっき付着量が０．１〜２００ｇ／ ｍ 2 、リン酸塩付着量が０．１〜５ｇ／ｍ 2 でめっき外 観の白色度（Ｌ値）が７０以上、リン酸塩結晶の粒径が ４０μｍ以下であることを特徴とするりん酸塩処理亜鉛 系めっき鋼板である。

Process for the passivation of metallic surfaces with polymers having acid groups

하나 이상의 수용성 산성 기 함유 중합체 및 Zn, Ca, Mg 또는 Al 이온을 포함하는 산성, 수성 배합물에 의한 표면 처리에 의한 금속 표면의 부동화 방법으로서 특히 스트립 금속의 부동화를 위한 연속적 방법. A continuous method for immobilizing a metal strip, in particular as a method for immobilizing a metal surface by surface treatment with an acidic, aqueous compound comprising at least one water-soluble acid group-containing polymer and Zn, Ca, Mg or Al ions.

Chromium-free passivator and preparation method thereof

本发明公开了一种无铬钝化剂及其制备方法，该钝化剂包括以下原料：乙醇胺，乙二胺，磷酸盐，镍盐，硝酸盐，柠檬酸，陶瓷粉，酚醛环氧树脂、水。制备方法：按重量份数计称取原料；将乙醇胺，乙二胺，磷酸盐，镍盐，磷酸盐和水混合后，搅拌15-25分钟得第一混合物；将第一混合物加热到55-78℃下，加入柠檬酸和陶瓷粉，搅拌1-5分钟后，再加入酚醛环氧树脂，搅拌并升温到85-95℃，保温3-7分钟，得第二混合物；将第二混合物真空浓缩1-3分钟，得无铬钝化剂。本发明钝化剂耐高温，耐腐蚀性强，成本低。

Phosphate Compound Coating Composition for Improving Lubrication

본 발명은 증류수 100중량부 기준으로, 인산(H 3 PO 4 ) 3 내지 6중량부; 탄산망간(MnCO 3 ) 1 내지 3중량부; 질산니켈[Ni(NO 3 ) 2 ㅇ6H 2 O] 0.01 내지 0.1중량부; 황산암모늄[(NH 4 ) 2 SO 4 ] 0.2 내지 0.6중량부; 및 이황화몰리브덴(MoS 2 ) 3 내지 20중량부를 포함하는 피막제 조성물을 제공한다. 본 발명에 따른 윤활성 향상을 위한 인산염 복합피막제 조성물은 금속표면에 고착성과 안정성이 높은 인산염 또는 산화피막 화합물 층을 형성시켜, 피막이 형성된 표층의 물리화학적 성질을 이용하여 내마모성, 내식성 및 윤활성을 향상시킬 수 있을 뿐만 아니라, 별도의 윤활성 향상 작업 등이 불필요하게 됨으로써 화성처리 시간 단축으로 약품 소비량 등을 저감시킬 수 있어 가격 경쟁력 확보가 용이하다.

Method of zinc phosphating with internated additional passivation

FIELD: phosphating of surfaces of metals with acid solutions. SUBSTANCE: method of phosphating metallic surfaces from steel, from zinc plated steel or from steel coated with zinc alloys, from aluminium and/or aluminium-magnesium alloys comprises metal surfaces with zinc-containing phosphating solution for period of 3 sec to 8 min when sprayed with solution or immersed into solution containing from 0.2 to 3g/l of zinc ions, from 3 to 50 g/l of phosphate ions calculated for PO 4 from 0.001 to 4 g/l of manganese ions, from 0.001 to 0.5 g/l of one or more polymers selected from polycarboxylates, polymeric phosphonic acids, polymeric phosphinocarboxylic acids, nitrogen-containing organic polymers and poly-4- vinylphenol compounds of general formula II: wherein n is integer from 5 to 100, X is independently hydrogen atoms or -CRR 1 OH, wherein R and R 1 are hydrogen atom, aliphatic and/or aromatic residues having from 1 to 12 carbon atoms and one or several accelerators selected from m-nitrobenzoate ions with concentration of 0.05 to 2 g/l, n-nitrophenol with concentration of 0.005 to 2 g/l, hydroxyamine in free or bonded form with concentration of 0.1 to 10 g/l, reducing sugar with concentration of 0.1 to 10 g/l, phosphating solution containing not higher than 0.5 g/l of nitrate, and ratio of amounts of phosphate ions to amount of zinc ions varying from 3.7 to 30. Method makes it possible to improve corrosion resistance and increase strength of coatings and make corrosion resistance greater. EFFECT: more efficient phosphating method. 16 cl, 1 tbl зегедлдс ПЧ с» РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) (11) ВКО 2179 198 5) МК С23С 22/48, 22/36 (13) С2 (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 98123610/02, 20.05.1997 (24) Дата начала действия патента: 20.05.1997 (30) Приоритет: 28.05.1996 ОЕ 196 21 184.0 (43) Дата публикации заявки: 10.10.2000 (46) Дата публикации: 10.02.2002 (56) Ссылки: МО 9528509 А, 26.10.1995. Ц$ ...

Non-chromate corrosion inhibitors for aluminum alloys

금속표면에 대한 비크롬산염 부식억제 코팅 조성물은 포스페이트, 포스포실리케이트, 아연염 및 이의 혼합물로 이루어지는 군에서 선택된 최소한 하나의 억제제, 티타네이트, 아연염 및 이의 혼합물로 이루어지는 군에서 선택된 최소한 하나의 억제제, 및 이들 억제제에 대한 캐리어를 포함하고, 상기 캐리어는 억제제를 금속표면 근처에 위치시킬 수 있다. 선호되는 구체예에서, 코팅 조성물은 붕산과 같은 붕산염과 숙신산염을 더욱 포함한다. 선호되는 포스페이트는 칼슘 2수소 포스페이트이며, 나트륨 티타늄 산화물이 선호되는 티타네이트이다. 아연염은 아연 포스페이트 또는 아연 시안아미드를 포함한다. The non-chromate corrosion inhibiting coating composition for a metal surface comprises at least one inhibitor selected from the group consisting of a phosphate, a phosphosilicate, a zinc salt, and mixtures thereof, at least one inhibitor selected from the group consisting of titanates, zinc salts, , And a carrier for these inhibitors, which carrier can position the inhibitor near the metal surface. In a preferred embodiment, the coating composition further comprises a borate and a succinate such as boric acid. The preferred phosphate is calcium dihydrogen phosphate, and sodium titanium oxide is the preferred titanate. The zinc salts include zinc phosphate or zinc cyanamide.

Preparation method for composite coating on surface of protective guard

本发明公开了一种防护栏表面复合涂层的制备方法，属于防护设施领域。对防护栏进行脱脂、除锈处理；对经脱脂除锈处理的防护栏整体镀锌；对镀锌后的防护栏进行磷化处理，在防护栏表面形成磷化膜；所述磷化液体由质量浓度比为1：1：2：2的NaOH、NaNO 2 、H 3 PO 4 、ZnO组成；采用静电喷涂方法在处理后的防护栏上喷涂聚酯粉末层。本发明通过镀锌层、磷化层和聚酯粉末层结合，提升涂层与防护栏的附着力；采用静电喷涂聚酯粉末层的方式，有效地控制喷粉量的大小将喷粉量控制在相对低的范围内，提高沉积率高；通过喷涂距离的控制，减少喷粉的使用量，提高粉末涂料的利用率。

Low-sludging zinc phosphate treatment and treating liquid using the same

(57)【要約】 【課題】 金属材料表面にりん酸亜鉛化成皮膜を形成さ せ、その際発生するスラッジ量を低減する方法及びそれ に用いる処理液を提供する。 【解決手段】 りん酸塩処理される金属材料とりん酸亜 鉛処理組成液とを接触させることにより達成される亜硝 酸塩を促進剤とするりん酸亜鉛処理で生じるスラッジ量 を低減する方法において、生成するスラッジ量を予測す る式を用いてスラッジ量の低減を図ることを特徴とする 前記方法及びそれに用いる処理液。

Tension coating agent for forming insulating film with excellent drying property, electrical resistance and method for forming insulation film using that, and electrical steel sheet with insulating film by that method

본 발명은 건조속도 및 절연성이 우수한 비크롬계 방향성 전기강판용 장력코팅제 조성물 및 이를 이용한 절연피막 형성방법, 이 방법에 의해 형성된 절연피막을 갖는 방향성 전기강판에 관한 것으로, 방향성 전기강판의 절연피막 처리 공정에 있어 금속 인산염과 콜로이달 실리카를 주요성분으로 하는 비크롬계 방향성 전기강판 장력코팅제로서, 상기 금속 인산염은 제1인산 마그네슘(Mg(H 2 PO 4 ) 2 )과 제1인산 알루미늄(Al(H 2 PO 4 ) 3 )이 혼합된 혼합액이고; 상기 금속인산염 용액 100g에 대하여 콜로이달 실리카 30~60g, 산화촉진제 2~15g을 포함하여 구성되는 것을 특징으로 하는 절연성을 갖는 건조속도 및 절연성이 우수한 비크롬계 방향성 전기강판용 장력코팅제 조성물을 제공한다. 본 발명에 따르면, 비크롬계 장력코팅제의 주요 문제인 건조 속도 저하에 의한 절연성, 밀착성 저하 및 이로 인한 코팅에 의한 장력저하를 산화촉진제를 도입함으로써 해결할 수 있고, 또한 도입된 산화촉진제는 코팅제의 주요 성분인 인산염의 반응속도를 가속화시키기 때문에 미건조에 의한 절연 불량 및 밀착성 저하 문제도 해소할 수 있게 되므로 궁극적으로 전기 절연성과 피막에 의한 장력을 향상시키는 효과를 얻을 수 있다. The present invention relates to a tension coating composition for non-chromium-oriented oriented electrical steel sheet having excellent drying speed and insulation properties, and a method for forming an insulating film using the same, and an oriented electrical steel sheet having an insulating film formed by the method. In the non-chromium-oriented oriented electrical steel sheet tension coating agent mainly composed of metal phosphate and colloidal silica, the metal phosphate is the first magnesium phosphate (Mg (H 2 PO 4 ) 2 ) and the first aluminum phosphate (Al (H 2 PO 4 ) 3 ) is a mixed solution; It provides a tension coating agent composition for non-chromium-based oriented electrical steel sheet having excellent drying speed and insulation, characterized in that it comprises a colloidal silica 30 ~ 60g, the oxidation promoter 2 ~ 15g with respect to the metal phosphate solution 100g. According to the present invention, the main problem of the non-chromium-based tension coating agent can be solved by introducing an oxidation promoter to the insulation, the adhesion decrease and the decrease in tension due to the coating, which is a major problem of the drying rate. Since the reaction rate of phosphate is accelerated, the problem of poor insulation and deterioration of adhesion due to undrying can be solved, and ultimately, the effect of ...

Phosphate treatment of metal surface

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Eco-Friendly Phosphate-Manganese Type Surface Conditioner for Car Components and Chemical Conversion Treatment Methods Using Thereof

The present invention relates to an eco-friendly phosphate-manganese based surface conditioner composition for a car component and a chemical conversion treatment method using the same. With respect to 100 parts by weight of water, the composition of the present invention comprises: 0.3 to 0.5 parts by weight of manganese dihydrogen phosphate [Mn(H2PO4)2]; 0.5 to 1.5 parts by weight of sodium tripolyphosphate [Na5P3O10]; 0.5 to 1.5 parts by weight of sodium pyrophosphate [Na4P2O7]; 1 to 3 parts by weight of sodium hexametaphosphate. According to the invention, after the surface conditioning is performed with the phosphate-manganese surface conditioner composition, a phosphate-manganese film makes crystals thereof become more finely, minutely, and evenly formed, thereby reducing the time for chemical conversion treatment thereof.

Composition for correcting zinc-phosphate solutions for zinc-phosphatizing

Изобретение относитс  к области химической обработки поверхности металлов и может быть использовано в различных област х металлообрабатывающей промышленности, таких как машиностроение , судостроение, приборостроение , бытова  техника и др. Целью изобретени   вл етс  стабилизаци  и продление срока раствора фос- фатироваки . Композици  дл  корректировани  цинкофосфатных растворов фос- фатировани  цинка содержит, г/л: соединение цинка в пересчете на ионы Zn 29-33 , 5: соединение фосфатов в 3 пересчете на ионы РО 94-109; соединение Нитратов в пересчете на ионы N0} 6-i1; гликокол 0,75-2,25; сали- циловокислый аммоний 0,3-0,9, Стабилизаци  и продление срока службы раствора фосфатировани  достигаютс  введением в корректирующий раствор гликокола и салициловокислого аммони , 1 табл. О (Л The invention relates to the field of chemical surface treatment of metals and can be used in various areas of the metalworking industry, such as mechanical engineering, shipbuilding, instrument making, household appliances, etc. The aim of the invention is to stabilize and extend the life of a phosphate sieve solution. A composition for adjusting zinc phosphate solutions of phosphating zinc contains, g / l: a zinc compound in terms of Zn ions 29-33, 5: a compound of phosphates in 3 in terms of PO ions 94-109; compound of nitrates in terms of ions N0} 6-i1; glycine 0.75-2.25; ammonium salicylate 0.3-0.9, Stabilization and prolongation of the life of the phosphate solution is achieved by introducing glycocol and ammonium salicylate into the corrective solution of glycocol, 1 table. O (L

Composition for phosphate treatment of metal surface

Изобретение относитс  к области обработки металлической поверхности химическим путем, в частности к получению фосфатных покрытий, и может быть использовано при обработке проволоки , труб перед холодной деформацией и при обработке стали с последующим промасливанием. Цель изобретени  - сокращение расхода реагентов, уменьшение токсичности промывных и сточных вод и повышение эффективности раствора. Раствор дл  фосфатирова- ни  металлической поверхности содержит , мас.%: ионы цинка 10,6-11,6; ионы никел  0,068-0,1; ионы фосфата 24,1-27,5; ионы нитрата 10,5-12,4; ионы железа () 0,046-0,07; Вода- остальное. Раствор позвол ет получать фосфатные покрыти  скоростным и осадочным способами. Дл  фосфати- ровани  методом окунани  толстой проволоки перед холодной деформацией и листовой стали перед промасливанием состав используют в количестве 36- 73 г на 1 дм водного раствора; дл  фосфатировани  скоростным методом - 140-220 г на 1 дм водного раствора. Введение трехвалентного железа в цинкфосфатирующий раствор при определенном массовом соотношении приводит к снижению равновесных свободных кислотностей, повьппению равновесных значений рН, увеличению скорости образовани  фосфатного сло , снижению массы стравленного металла и уменьшению расхода химикатов. 5 табл. (Л со 00 The invention relates to the field of treating a metal surface by chemical means, in particular, to obtaining phosphate coatings, and can be used in the treatment of wire, pipes before cold deformation and in the processing of steel, followed by oiling. The purpose of the invention is to reduce the consumption of reagents, reduce the toxicity of wash and waste water and increase the efficiency of the solution. The solution for phosphating metal surface contains, in wt.%: Zinc ions 10.6-11.6; nickel ions 0,068-0,1; phosphate ions 24.1-27.5; nitrate ions 10.5-12.4; iron ions () 0,046-0,07; Water is the rest. The solution allows to obtain phosphate coatings by speed and sedimentary methods. For phosphating by dipping a ...

SOLUTION FOR PHOSPHATING METAL SURFACE

Slag-free accelerator suitable for zinc phosphating solution

本发明涉及工业磷化液领域，提供一种适用于锌系磷化液的无渣促进剂。该促进剂包含有机硝基化合物，具体包含对硝基苯酚、硝基胍、硝基甲烷、二硝基苯中的一种或多种。该促进剂适用于锌系磷化液的配制，其能够有效减少磷化沉渣的生成，从而保证磷化膜正常形成，进而保证了磷化膜的质量和稳定性。