05-04-2018 дата публикации
Номер: US20180096847A1
Принадлежит:
Processing methods comprising selectively orthogonally growing a first material through a mask to provide an expanded first material are described. The mask can be removed leaving the expanded first material extending orthogonally from the surface of the first material. Further processing can create a self-aligned via. 1. A processing method comprising:providing a substrate with a substrate surface comprising a first surface of a first material and a second surface of a second material different from the first material;forming a mask on the substrate, the mask having an opening exposing at least a portion of the first surface and the second surface;expanding the first material to orthogonally grow an expanded first material to a height greater than the second surface; andremoving the mask from the substrate to leave the first material extending orthogonally from the substrate surface.2. The method of claim 1 , wherein expanding the first material causes the expanded first material to expand straight up from the first surface through the opening in the mask to a height greater than the mask.3. The method of claim 1 , wherein expanding the first material comprises one or more of oxidizing or nitriding the first material.4. The method of claim 3 , wherein the first material comprises one or more of Co claim 3 , Mo claim 3 , W claim 3 , Ta claim 3 , Ti claim 3 , Ru claim 3 , Rh claim 3 , Cu claim 3 , Fe claim 3 , Mn claim 3 , V claim 3 , Nb claim 3 , Hf claim 3 , Zr claim 3 , Y claim 3 , Al claim 3 , Sn claim 3 , Cr or La.5. The method of claim 4 , wherein oxidizing or nitriding the first material comprises exposing the first material to an oxidizing agent or nitriding agent comprising one or more of O claim 4 , O claim 4 , NO claim 4 , HO claim 4 , HO claim 4 , CO claim 4 , CO claim 4 , NH claim 4 , NH claim 4 , NO claim 4 , N claim 4 , N/Ar claim 4 , N/He or N/Ar/He.6. The method of claim 1 , wherein the first material comprises a metal and the second material ...
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