19-11-1958 дата публикации
Номер: GB0000804504A
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A paper-maker's size, which in use is added to aqueous cellulosic paper-pulp, comprises activated clay, e.g. bentonite, and a sizing substance which reacts chemically with the hydroxyl groups of cellulose. The sizing substance may be a ketene dimer having the general formula [R , CH : C : O]2, wherein R may be an alkyl group having at least eight carbon atoms, a cycloalkyl group having at least six carbon atoms, an aryl, aralkyl or alkaryl group. Octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl, tetracosyl, phenyl, benzyl, beta-naphthyl and cyclohexyl ketene dimers are suitable and so are ketene dimers prepared from montanic, naphthenic, D 9, 10 decylenic, D 9, 10 dodecylenic, palmitoleic, oleic, ricinoleic, petroselenic, vaccenic, linoleic, linolenic, eleostearic, licanic, parinaric, tariric, gadoleic, arachidonic, cetoleic, erucic and selacholeic acids and from mixed fatty acids derived from coconut, babassu, palm kernel, palm olive, peanut and rape oils, beef ...
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