07-03-2019 дата публикации
Номер: US20190071319A1
Принадлежит:
The present invention relates to vanadium oxide and methods of controlling reaction processes for making such materials (e.g., powders). In particular embodiments, the method includes control of oxygen partial pressure in order to kinetically control the oxidation species of the crystalline vanadium oxide material. Other methods, uses, systems, protocols, and coatings are also described. 1. A method of preparing crystalline vanadium oxide , the method comprising:(i) providing a vanadium oxide precursor;{'sub': '2', '(ii) annealing the precursor at a reduced Opartial pressure, thereby preparing the crystalline vanadium oxide in tetragonal form; and'}{'sub': 1', '2', '2, '(iii) determining a first temperature Tat which a metastable VOform and/or a tetragonal VOform is present.'}2. The method of claim 1 , further comprising (iv) adjusting to a further reduced Opartial pressure claim 1 , thereby further isolating the crystalline vanadium oxide in tetragonal form.3. The method of claim 1 , wherein the crystalline vanadium oxide is VO.4. The method of claim 1 , wherein the vanadium oxide precursor comprises vanadium oxide particles.5. The method of claim 4 , wherein the crystalline vanadium oxide has substantially the same morphology as the vanadium oxide particles.6. The method of claim 5 , wherein the vanadium oxide particles comprise vanadium pentoxide VO.7. A method of preparing crystalline vanadium oxide claim 5 , the method comprising:(i) providing a vanadium oxide precursor;{'sub': 2', '1, '(ii) annealing the precursor at a first Opartial pressure P, thereby forming one or more vanadium oxide form(s);'}(iii) obtaining one or more spectroscopy measurements of the vanadium oxide form(s);{'sub': 1', '2', '2, '(iv) determining a first temperature Tat which a metastable VOform and/or a tetragonal VOform is present; and'}{'sub': 2', '2', '1, '(v) adjusting to a second Opartial pressure Pwhile maintaining T, thereby preparing the crystalline vanadium oxide.'}8. The method ...
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