Pesticidal compositions.
Patents Granted (Contd.) FORM 25 (22)PATENT {29} ΑΡ (U) patent No ; ΑΡ 3534 (73) Applicant^) Dew AgraScsgfices U.C, 9330 Zittesviiie Road, Indianapolis;, 4626S- iOS4. (21) Apphcatfon No ; AP/P/2CH2/00SM? Indiana, United States of America (22) filing Date ; 05,08.2010 (24) Pate of Grant & (45) Publication j »/0D20i& (30) Priority Data (72) Inventors (33) Countiy (31) Number {32} Date US 61/231,Μ2 0 LAMBERT WiSwro, United States at America etst (84) Designated States: (74) Representative BW GH GH KB U IS MW FESHEK CQBMACK HZ ΝΑ SD SL SZ ΤΖ UG 2Μ ZW (51) International Classification: ΑΜΝ 43/64 (2006.01) (54) Title Pesddidal compositions (57) Abstract The present invention concerns in iinsporetion of die pesticide compositions cunmining the compounds, and methods of controlling insects using the compounds. (56) Documents Cited ; US 6,417,18? 8? US 20Q8/0Z62GS? At US 2067)06661? Α1 WO 00/24735 Μ Pesticidal compositions and their uses are disclosed. A molecule of the following formula:
wherein:
(a) Ar1 is a substituted phenyl wherein said substituted phenyl has one or more substituents independently selected from C1-C6 haloalkyl and C1-C6 haloalkoxy; (b) Het is a 1,3-disubstituted 1,2,4-triazole where Ar1 and Ar2 are not ortho to each other but are 1,3; (c) Ar2 is a phenyl, (d) X1 is O or S; (e) X2 is O or S; and (f) R4 is H or C1-C6 alkyl; (g) R1, R2, and R3 are independently selected from H, F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), (C1-C6 alkyl)O(C1-C6 alkyl)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), C(=O)phenyl, phenyl, C1-C6 alkylphenyl, C(=O)phenoxy, phenoxy, C1-C6 alkylphenoxy, C(=O)Het-1, Het-1, or C1-C6 alkylHet-1,
wherein Het-1 is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, and
wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, phenoxy, and Het-1 are optionally substituted with one or more substituents independently selected from F, Cl, Br, I, CN, NO2, oxo, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, (C1-C6 alkenyl)NRxRy, (C1-C6 alkynyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1,
wherein n = 0, 1, or 2;
wherein Rx and Ry are independently selected from H, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, and phenoxy;
wherein R1 and R2 together can optionally form a 3- to 12-membered saturated or unsaturated cyclic group which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen with the proviso that there is not a C1- O- bond in such cyclic group wherein said cyclic group may have one or more substituents independently selected from F, Cl, Br, I, CN, NO2, oxo, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1. A molecule according to claim 1 wherein R1, R2, and R3 are independently selected from H, CN, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C(=O)O(C1-C6 alkyl), phenyl, and Het-1. A molecule according to claim 1 having one of the following structures
A molecule according to claim 1 having one of the following structures
A process to apply a molecule according to claim 1 said process comprising applying a molecule according to claim 1, to an area to control a pest, in an amount sufficient to control such pest. A process according to claim 5 wherein said pest is beet armyworm (BAW), corn earworm (CEW), or green peach aphid (GPA). A molecule that is a pesticidally acceptable acid addition salt, a salt derivative, a solvate, or an ester derivative of a molecule according to claim 1. A molecule according to claim 1 wherein at least one H is2H or at least one C is14C. A composition comprising a molecule according to claim 1 and at least one other compound having insecticidal, herbicidal, acaricidal, nematicidal, or fungicidal activity. A composition comprising a molecule according to claim 1 and a seed. A process comprising applying a molecule according to claim 1 to a genetically modified plant, or genetically-modified seed, which has been genetically modified to express one or more specialized traits. A molecule according to claim 1 for use in controlling endoparasites, ectoparasites, or both in a non-human animal, preferably by oral, dermal or parenteral administration.1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136