Pesticidal compositions.

30-04-2012 дата публикации
Номер:
AP0201206147D0
Принадлежит:
Контакты:
Номер заявки: 14-06-20127
Дата заявки: 05-08-2010

[1]

Patents Granted (Contd.)

[2]

FORM 25 (22)PATENT {29} ΑΡ

[3]

(U) patent No ; ΑΡ 3534 (73) Applicant^)

[4]

Dew AgraScsgfices U.C, 9330 Zittesviiie Road, Indianapolis;, 4626S- iOS4. (21) Apphcatfon No ; AP/P/2CH2/00SM? Indiana, United States of America

[5]

(22) filing Date ; 05,08.2010

[6]

(24) Pate of Grant & (45) Publication j »/0D20i&

[7]

(30) Priority Data (72) Inventors

[8]

(33) Countiy (31) Number {32} Date SfWfS Thomas, United States of America

[9]

US 61/231,Μ2 0 ?M2W$ CUDWOfttM Oamsa, Umted States of America

[10]

LAMBERT WiSwro, United States at America

[11]

etst

[12]

(84) Designated States: (74) Representative

[13]

BW GH GH KB U IS MW FESHEK CQBMACK & BOTHA) Mafcw

[14]

HZ ΝΑ SD SL SZ ΤΖ UG

[15]

2Μ ZW

[16]

(51) International Classification: ΑΜΝ 43/64 (2006.01)

[17]

(54) Title

[18]

Pesddidal compositions

[19]

(57) Abstract

[20]

The present invention concerns tmt& betenoaryhN'iKyt carbamates and telr use

[21]

in ξχη,Χ costnsi. as insecticides ace acefiades. This invention also includes

[22]

iinsporetion of die pesticide compositions cunmining the compounds, and

[23]

methods of controlling insects using the compounds.

[24]

(56) Documents Cited ; US 6,417,18? 8? US 20Q8/0Z62GS? At US 2067)06661? Α1 WO 00/24735 Μ



[25]

Pesticidal compositions and their uses are disclosed.



A molecule of the following formula: wherein:

(a) Ar1 is a substituted phenyl wherein said substituted phenyl has one or more substituents independently selected from C1-C6 haloalkyl and C1-C6 haloalkoxy;

(b) Het is a 1,3-disubstituted 1,2,4-triazole where Ar1 and Ar2 are not ortho to each other but are 1,3;

(c) Ar2 is a phenyl,

(d) X1 is O or S;

(e) X2 is O or S; and

(f) R4 is H or C1-C6 alkyl;

(g) R1, R2, and R3 are independently selected from H, F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), (C1-C6 alkyl)O(C1-C6 alkyl)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), C(=O)phenyl, phenyl, C1-C6 alkylphenyl, C(=O)phenoxy, phenoxy, C1-C6 alkylphenoxy, C(=O)Het-1, Het-1, or C1-C6 alkylHet-1, wherein Het-1 is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, and wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, phenoxy, and Het-1 are optionally substituted with one or more substituents independently selected from F, Cl, Br, I, CN, NO2, oxo, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, (C1-C6 alkenyl)NRxRy, (C1-C6 alkynyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1, wherein n = 0, 1, or 2; wherein Rx and Ry are independently selected from H, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, and phenoxy; wherein R1 and R2 together can optionally form a 3- to 12-membered saturated or unsaturated cyclic group which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen with the proviso that there is not a C1- O- bond in such cyclic group wherein said cyclic group may have one or more substituents independently selected from F, Cl, Br, I, CN, NO2, oxo, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C2-C6 alkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1.

A molecule according to claim 1 wherein R1, R2, and R3 are independently selected from H, CN, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C(=O)O(C1-C6 alkyl), phenyl, and Het-1.

A molecule according to claim 1 having one of the following structures

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A molecule according to claim 1 having one of the following structures

A process to apply a molecule according to claim 1 said process comprising applying a molecule according to claim 1, to an area to control a pest, in an amount sufficient to control such pest.

A process according to claim 5 wherein said pest is beet armyworm (BAW), corn earworm (CEW), or green peach aphid (GPA).

A molecule that is a pesticidally acceptable acid addition salt, a salt derivative, a solvate, or an ester derivative of a molecule according to claim 1.

A molecule according to claim 1 wherein at least one H is2H or at least one C is14C.

A composition comprising a molecule according to claim 1 and at least one other compound having insecticidal, herbicidal, acaricidal, nematicidal, or fungicidal activity.

A composition comprising a molecule according to claim 1 and a seed.

A process comprising applying a molecule according to claim 1 to a genetically modified plant, or genetically-modified seed, which has been genetically modified to express one or more specialized traits.

A molecule according to claim 1 for use in controlling endoparasites, ectoparasites, or both in a non-human animal, preferably by oral, dermal or parenteral administration.