THERMAL HEAD AND THERMAL PRINTER
The present disclosure relates to a thermal head and a thermal printer. Conventionally, as a printing device of facsimiles, video printers, etc., various thermal heads have been proposed. For example, known in the art is a thermal head provided with a substrate, heat-generating portions positioned on the substrate, electrodes which are positioned on the substrate and are connected to the heat-generating portions, and a protective layer covering the heat-generating portions and parts of electrodes (see Patent Literature 1). Patent Literature 1: Japanese Patent Publication No. 2000-141729 A thermal head of the present disclosure includes a substrate, a heat-generating portion, an electrode, and a protective layer. The heat-generating portion is located on the substrate. The electrode is located on the substrate and is connected to the heat-generating portion. The protective layer covers the heat-generating portion and a part of the electrode. Further, a skewness Rsk of the protective layer is larger than 0. A thermal printer of the present disclosure includes a thermal head described above, a conveyance mechanism which conveys a recording medium onto the protective layer which is located on the heat-generating portion, and a platen roller pressing against the recording medium. In a conventional thermal head, in order to improve slip of the protective layer, use is made of a protective layer having recesses formed in its surface. Due to that, the recording medium becomes harder to stick to the protective layer, so it becomes harder to cause so-called “sticking”. However, in a conventional thermal head, sometimes the recording medium ends up stuck to a part of the protective layer which does not have recesses formed at it. For this reason, there are still cases of sticking occurring. Therefore further improvement of slip has been demanded. The thermal head in the present disclosure improves the slip of the protective layer and thereby makes sticking harder to occur. Below, the thermal head in the present disclosure and a thermal printer using the same will be explained in detail. Below, a thermal head X1 will be explained with reference to The thermal head X1 is provided with a head base body 3, connector 31, sealing member 12, heat-radiating plate 1, and bonding member 14. Note that, the connector 31, sealing member 12, heat-radiating plate 1, and bonding member 14 need not necessarily be provided. The heat-radiating plate 1 radiates excessive heat of the head base body 3. The head base body 3 is placed on the heat-radiating plate 1 through the bonding member 14. The head base body 3 performs printing on a recording medium P (see The heat radiating plate 1 is cuboid shaped. The heat radiating plate 1 is for example formed by copper, iron, aluminum, or another metal material and has the function of radiating heat which does not contribute to the printing in the heat generated in the heat-generating portions 9 in the head base body 3. The head base body 3 is rectangle shaped when viewed on a plane and has members configuring the thermal head X1 arranged on a substrate 7. The head base body 3 has a function of printing on the recording medium P according to an electrical signal supplied from the external portion. Using The head base body 3 has the substrate 7, heat storage layer 13, electrical resistance layer 15, common electrode 17, individual electrodes 19, first connection electrodes 21, connection terminals 2, conductive member 23, driving ICs (integrated circuits) 11, coating member 29, protective layer 25, and coating layer 27. Note that, all of these members need not be provided. Further, the head base body 3 may be provided with members other than them as well. The substrate 7 is arranged on the heat radiating plate 1 and is rectangle shaped when viewed on a plane. The substrate 7 has a first surface 7 The substrate 7 is for example formed by an alumina ceramic or other electrical insulating material or single crystal silicon or other semiconductor material or the like. The heat storage layer 13 is positioned on the first surface 7 The heat storage layer 13 is arranged so as to be adjacent to the first long side 7 The heat storage layer 13 is formed by a glass having a low thermal conductivity and temporarily stores a part of the heat generated in the heat-generating portions 9. For this reason, the time required for raising the temperature of the heat-generating portions 9 can be made shorter, therefore the thermal response characteristic of the thermal head X1 can be raised. The heat storage layer 13 is for example formed by coating a predetermined glass paste, obtained by mixing a suitable organic solvent with glass powder, on the first surface 7 The electrical resistance layer 15 is positioned on the upper surface of the heat storage layer 13. On the electrical resistance layer 15, the common electrode 17, individual electrodes 19, first connection electrodes 21, and second connection electrodes 26 are formed. Between the common electrode 17 and the individual electrodes 19, exposed regions where the electrical resistance layer 15 is exposed are formed. The exposed regions of the electrical resistance layer 15 are arranged in a row on the heat storage layer as shown in Note that, the electrical resistance layer 15 need not be positioned between various electrodes and the heat storage layer 13. For example, it may be positioned only between the common electrode 17 and the individual electrodes 19 so as to electrically connect the common electrode 17 and the individual electrodes 19 as well. The plurality of heat-generating portions 9 are described simplified in The common electrode 17 is provided with main wiring portions 17 The plurality of individual electrodes 19 electrically connect the heat-generating portions 9 and the driving ICs 11. Further, the plurality of heat-generating portions 9 are divided into a plurality of groups. The groups of heat-generating portions 9 and the driving ICs 11 which are arranged corresponding to the groups are electrically connected by the individual electrodes 19. The plurality of first connection electrodes 21 electrically connect the driving ICs 11 and the connector 31 to each other. A plurality of the first connection electrodes 21 connected to each of the driving ICs 11 are configured by a plurality of wirings having different functions. The plurality of second connection electrodes 26 electrically connect the adjoining driving ICs 11. The plurality of second connection electrodes 26 are configured by pluralities of wirings having different functions. These common electrode 17, individual electrodes 19, first connection electrodes 21, and second connection electrodes 26 are formed by materials having conductivity. For example, they are formed by one type of metal of any of aluminum, gold, silver, and copper or an alloy of the same. The plurality of connection electrodes 2 are arranged on the second long side 7 A conductive member 23 is provided on each connection terminal 2. As the conductive member 23, for example, solder or ACP (anisotropic conductive paste) or the like can be illustrated. Note that, between the conductive member 23 and the connection terminal 2, a plating layer of Ni, Au, or Pd may be arranged as well. The various electrodes configuring the head base body 3 described above can be formed by successively stacking material layers made of Al, Au, Ni, or another metal configuring each on the heat storage layer 13 by a sputtering process or other thin film forming technique, then processing the stack into predetermined patterns by using photoetching or the like. Note that, the various electrodes configuring the head base body 3 can be simultaneously formed by using the same manufacturing process. The driving ICs 11, as shown in The protective layer 25 coats the heat-generating portions 9 and parts of the common electrode 17 and individual electrodes 19. The protective layer 25 is one for protecting the coated regions from corrosion due to deposition of moisture etc. contained in the atmosphere or abrasion due to contact with the recording medium P for printing. The coating layer 27 is arranged on the substrate 7 so as to partially coat the common electrode 17, individual electrodes 19, first connection electrodes 21, and second connection electrodes 26. The coating layer 27 is one for protecting the coated regions from oxidation due to contact with the atmosphere or corrosion due to deposition of moisture etc. contained in the atmosphere. The coating layer 27 can be formed by a resin material such as an epoxy resin, polyimide resin, or silicone resin. The driving ICs 11 are sealed by the coating member 29 made of an epoxy resin or silicone resin or another resin in a state where they are connected to the individual electrodes 19, first connection electrodes 21, and second connection electrodes 26. The coating member 29 is arranged so as to extend in the main scanning direction and integrally seals the plurality of driving ICs 11. The connector 31 has the plurality of connector pins 8 and the housing 10 accommodating the plurality of connector pins 8. The plurality of connector pins 8 have first ends and second ends. The first ends are exposed to the external portion of the housing 10, while the second ends are accommodated inside the housing 10 and are led out to the external portion. The first ends of the connector pins 8 are electrically connected to the connection terminals 2 of the head base body 3. Due to that, the connector 31 is electrically connected with the various electrodes in the head base body 3. The sealing member 12 has a first sealing member 12 The sealing member 12 is arranged so that the connection terminals 2 and the first ends of the connector pins 8 are not exposed to the external portion. For example, the sealing member 12 can be formed by an epoxy-based thermosetting resin, ultraviolet curing resin, or visible light-curable resin. Note that, the first sealing member 12 The bonding member 14 is arranged on the heat radiating plate 1 and bonds the second surface 7 The protective layer 25 will be explained in detail by using The protective layer 25 is provided with a first layer 25 As the first layer 25 The thickness of the first layer 25 As the second layer 25 The thickness of the second layer 25 The arithmetic average roughness Ra of the second layer 25 The skewness Rsk of the second layer 25 The kurtosis Rku of the second layer 25 Here, it is known to form recesses in the surface of the protective layer in order to make the contact area with the recording medium smaller. However, the contact area ends up becoming larger between the parts without formation of recesses (flat surface) in the protective layer and the recording medium, therefore sometimes the recording medium ends up stuck to the parts without formation of recesses. Contrary to this, the thermal head X1 in the present disclosure has a configuration where the skewness Rsk of the second layer 25 The recording medium P becomes harder to stick to the second layer 25 Further, in the thermal head X1 in the present disclosure, the skewness Rsk of the second layer 25 According to the above configuration, the abrasion resistance of the second layer 25 Further, in the thermal head X1 in the present disclosure, the skewness Rsk of the second layer 25 According to the above configuration, the second layer 25 Further, the above configuration may also be said to be a configuration where the second layer 25 Note that, the protective layer 25 positioned on the upstream side in the conveyance direction of the recording medium P is part of the protective layer 25 positioned on the upstream side in the conveyance direction from the protective layer 25 positioned on the heat-generating portions 9. The protective layer 25 positioned on the downstream side in the conveyance direction of the recording medium P is part of the protective layer 25 which is positioned on the downstream side in the conveyance direction from the protective layer 25 positioned on the heat-generating portions 9. The thermal head X1 in the present disclosure has a configuration where the kurtosis Rku of the second layer 25 The recording medium P becomes harder to stick to the second layer 25 Further, in the thermal head X1 in the present disclosure, the kurtosis Rku of the second layer 25 According to the above configuration, the sharpness of the crests of the second layer 25 Further, the thermal head X1 in the present disclosure may have a configuration where the skewness Rsk of the second layer 25 According to the above configuration, the crest parts are reduced on the surface of the second layer 25 The arithmetic average roughness Ra, skewness Rsk, and kurtosis Rku can be measured according to for example JIS B 0601 (2013). Note that, for measurement, use can be made of a contact type surface roughness meter or contactless surface roughness meter. For example, use can be made of LEXT OLS4000 made by Olympus. As the measurement conditions, for example, a measurement length may be set to 0.4 mm, a cutoff value may be set to 0.08 mm, a spot diameter may be set to 0.4 μm, and a scanning speed may be set to 1 mm/sec. Further, the skewness Rsk and kurtosis Rku of the protective layer 25 may be measured at the position of the protective layer 25 positioned on the heat-generating portions 9. In this case, the measurement may be carried out by moving the spot in the sub-scanning direction so as to pass through the protective layer 25 on the heat-generating portions 9. At this time, the skewness Rsk and kurtosis Rku may be measured multiple times and mean values of them may be used as the measurement results. Note that, the arithmetic average roughness Ra may be measured by using an atomic force microscope (AFM) as well. The protective layer 25 can be formed by arc plasma type ion plating or hollow cathode type ion plating. The surface state of the second layer 25 Next, the thermal printer Z1 having the thermal head X1 will be explained with reference to The thermal printer Z1 in the present embodiment is provided with the thermal head X1 explained above, conveyance mechanism 40, platen roller 50, power supply device 60, and control device 70. The thermal head X1 is attached to an attachment surface 80 The conveyance mechanism 40 has a driving part (not shown) and conveyance rollers 43, 45, 47, and 49. The conveyance mechanism 40 is one for conveying the recording medium P such as thermal paper, image receiving paper to which ink is transferred, or the like in a direction indicated by an arrow S in The platen roller 50 has a function of pressing the recording medium P against the top of the protective layer 25 positioned on the heat-generating portions 9 in the thermal head X1. The platen roller 50 is arranged so as to extend along a direction perpendicular to the conveyance direction S and is supported fixed at the two end parts so that it becomes able to rotate in a state pressing the recording medium P against the tops of the heat-generating portions 9. The platen roller 50, for example, can be configured as a columnar shaft body 50 The power supply device 60 has a function of supplying current for making the heat-generating portions 9 in the thermal head X1 generate heat as described above and current for making the driving ICs 11 operate. The control device 70 has a function of supplying a control signal controlling the operation of the driving ICs 11 to the driving ICs 11 in order to selectively make the heat-generating portions 9 in the thermal head X1 generate heat as described above. The thermal printer Z1 presses the recording medium P against the tops of the heat-generating portions 9 in the thermal head X1 by the platen roller 50 while conveying the recording medium P onto the heat-generating portions 9 by the conveyance mechanism 40 and also selectively makes the heat-generating portions 9 generate heat by the power supply device 60 and control device 70 to thereby perform predetermined printing on the recording medium P. Note that, when the recording medium P is image receiving paper or the like, ink of the ink film (not shown) which is conveyed together with the recording medium P is thermally transferred to the recording medium P to thereby perform printing on the recording medium P. The thermal printer Z1 in the present disclosure may use cut paper (not shown) as the recording medium P as well. By that, conveyance of the cut paper can be made smooth. That is, the cut paper is conveyed one sheet by one, so a new contact with the protective layer 25 repeatedly occurs each time a new cut paper is conveyed. The cut paper contacting the protective layer 25 is pressed by the platen roller 50, therefore the configuration becomes one in which the cut pater easily sticks to the thermal head X1. Contrary to this, the thermal head X1 is larger in the skewness Rsk of the protective layer 25 than 0, therefore the crest parts on the protective layer 25 can be reduced, so the contact area between the cut paper and the protective layer 25 can be reduced. Due to that, the cut paper becomes harder to stick to the protective layer 25, so sticking hardly occurs. Note that, as the cut paper, sheet paper or cards or other media other than rolled paper are shown. Using The thermal head X1 is arranged on pressing members 55 provided on the attachment surface 80 As the pressing members 55, use may be made of for example coil springs, plate springs, disc springs, or other springs. Further, member having a low elastic modulus may be used as the pressing members 55 as well. The recording medium P is pressed against the thermal head X1 by the pressing members 55. The protective layer 25, as shown in Note that, the arithmetic average roughness Ra, kurtosis Rku, and skewness Rsk of the protective layer 25 indicate the arithmetic average roughness Ra, kurtosis Rku, and skewness Rsk of the area E contacting the recording medium P in the surface of the protective layer 25. As described above, the thermal head in the present disclosure is not limited to the above embodiment. Various changes are possible so long as not departing from the gist. For example, an example in which the protective layer 25 was formed by the first layer 25 Further, a thin film head in which the electrical resistance layer 15 is formed by a thin film and the heat-generating portions 9 is thin was exemplified, but the present disclosure is not limited to this. A thick film head in which the electrical resistance layer 15 is formed by a thick film after patterning various electrodes and the heat-generating portions 9 is thick may be employed as well. Further, an explanation was given illustrating a flat head in which the heat-generating portions 9 were formed on the first surface 7 Further, the heat-generating portions 9 may also be formed by forming the common electrode 17 and individual electrodes 19 on the heat storage layer 13 and forming the electrical resistance layer 15 only in regions between the common electrode 17 and the individual electrodes 19. Further, the sealing member 12 may be formed by the same material as that for the coating member 29 coating the driving ICs 11 as well. In that case, when printing the coating member 29, printing may be carried out also in the region for forming the sealing member 12 to simultaneously form the coating member 29 and the sealing member 12. Further, an example in which the connector 31 was directly connected to the substrate 7 was shown. However, a flexible printed circuit (FPC) may be connected to the substrate 7 as well. The following experiments were carried out for the purpose of checking the relationships between the surface state of the protective layer and the abrasion resistance of the protective layer, sticking resistance, scratch resistance, and printing noise. A plurality of substrates for use as specimens in each of which the common electrode 17, individual electrodes 19, first connection electrodes 21, second connection electrodes 26, and other various electrode wirings were formed were prepared. The protective layers 25 were formed as films to a thickness of 5 μm using an arc plasma type ion plating apparatus. At the time of formation of the films of the protective layers 25, the ionization currents and substrate bias voltages shown in Table 1 were supplied. The driving ICs 11 were mounted on the substrates 7 having the protective layers 25 formed thereon and the coating members 29 were coated and hardened to thereby prepare thermal heads. Note that, three thermal heads were prepared for each of Specimen Nos. 1 to 3. Further, the prepared thermal heads were assembled together with platen rollers 50 into housings to prepare thermal printers, and the following scanning test was carried out. Use was made of thermal paper as the recording media. The scanning test was carried out under conditions of a conveyance velocity of 300 mm/s, a printing period of 0.7 ms/line, an applied voltage of 0.3 W/dot, and a pressing force of 10 kgF/head. The case where dots were dropped during the printing was judged as breakage of the protective layer 25. The running distance up to there was recorded as the scanning distance, and a mean value of three specimens was described in Table 1. In all of the thermal printers in which the thermal heads of Specimen Nos. 1 to 3 were mounted, the scanning distance exceeded 150 km, therefore improvement of the abrasion resistance of the protective layers 25 could be confirmed. In other words, the protective layers 25 in the thermal heads of Specimen Nos. 1 to 3 in which the skewness of the protective layer 25 was larger than 0 had excellent abrasion resistance. Further, the protective layers 25 in the thermal heads of Specimen Nos. 1 to 3 in which the kurtosis of the protective layer 25 was larger than 3 had excellent abrasion resistance. Further, in all of the thermal printers mounting the thermal heads of Specimen Nos. 1 and 2 thereon, the scanning distance exceeded 200 km. Further improvement of the abrasion resistance of the protective layers 25 could be confirmed. Using the remaining two thermal heads, presence or absence of sticking was confirmed. The thermal printers mounting the thermal heads of Specimen Nos. 1 to 3 were used. Printing of 1000 mm was carried out by using thermal paper as the recording media under the condition of a conveyance velocity of 300 mm/s in a state where all of the heat-generating portions were ON. The thermal papers after printing were checked. As a result, in both of the specimens, dropping of printing did not occur in any of the two thermal heads. Using the thermal printers mounting the thermal heads of Specimen Nos. 1 to 3 and using thermal paper as the recording media, a scanning test was carried out under conditions of a conveyance speed of 300=/s, a printing period of 0.7 ms/line, an applied voltage of 0.3 W/dot, and a pressing force of 10 kgF/head. As a result, in each of the thermal heads, a scratch damage was not caused even if 10,000 sheets were run. Further, the printing noise caused during the above scanning test was measured by using a sound gathering microphone. As a result, the printing noise was 100 dB or less. A thermal head of the present disclosure includes a substrate, a heat-generating portion, electrodes, and a protective layer. The heat-generating portion is located on the substrate. The electrodes are located on the substrate and are connected to the heat-generating portion. The protective layer covers the heat-generating portion and parts of the electrodes. A skewness Rsk of the protective layer is larger than 0. Further, A thermal head of the present disclosure includes a substrate, a heat-generating portion, electrodes, and a protective layer. The heat-generating portion is located on the substrate. The electrodes are located on the substrate and are connected to the heat-generating portion. The protective layer covers the heat-generating portion and parts of the electrodes. A kurtosis Rku of the protective layer is larger than 3. 1. A thermal head comprising:
a substrate; a heat-generating portion on the substrate; an electrode which is located on the substrate and is connected to the heat-generating portion; and a protective layer which coats the heat-generating portion and a part of the electrode, wherein a skewness Rsk of the protective layer is larger than 0. 2. The thermal head according to 3. The thermal head according to 4. A thermal head comprising:
a substrate; a heat-generating portion on the substrate; an electrode which is located on the substrate and is connected to the heat-generating portion; and a protective layer which coats the heat-generating portion and a part of the electrode, wherein a kurtosis Rku of the protective layer is larger than 3. 5. The thermal head according to 6. A thermal printer comprising:
a thermal head according to a conveyance mechanism conveying a recording medium onto the heat-generating portion, and a platen roller pressing against the recording medium. 7. The thermal printer according to 8. A thermal printer comprising:
a thermal head according to a conveyance mechanism conveying a recording medium onto the heat-generating portion, and a platen roller pressing against the recording medium.TECHNICAL FIELD
BACKGROUND ART
CITATION LIST
Patent Literature
SUMMARY OF INVENTION
BRIEF DESCRIPTION OF DRAWINGS
DESCRIPTION OF EMBODIMENTS
First Embodiment
Examples
Ionization current (A) 27 26 26 Upper-base bias voltage (−V) 500 550 600 Lower-base bias voltage (−V) 600 600 600 Arithmetic average roughness 29.4 29.6 32.3 Skewness 0.835 1.504 0.312 Kurtosis 3.74 3.34 3.33 Hardness (Gpa) 28 25 25 Young's modulus (Gpa) 380 340 340 Scanning distance (km) 200 200 150 REFERENCE SIGNS LIST