23-05-2013 дата публикации
Номер: US20130130151A1
A metal alloy catalyst for the oxygen reduction reaction in fuel cells is disclosed. The catalyst contains the metals Pd, M1 and M2. M1 and M2 are different metals selected from Co, Fe, Au, Cr and W, excluding the combination PdCoAu. 1. A metal alloy catalyst for the oxygen reduction reaction in fuel cells , the alloy comprising the metals Pd , M1 and M2 , where M1 and M2 are different metals selected from Co , Fe , Au , Cr , or W; but excluding the combination PdCoAu.2. The catalyst of claim 1 , wherein M1 is Fe.3. The catalyst of claim 1 , wherein M1 is Co and M2 is Cr or W.4. The catalyst of claim 1 , wherein a ternary alloy consisting essentially of Pd claim 1 , M1 claim 1 , and M2.5. The catalyst of claim 4 , consisting essentially of Pd claim 4 , Fe claim 4 , and Au.6. The catalyst of claim 4 , consisting essentially of Pd claim 4 , Co claim 4 , and Cr.7. The catalyst of claim 6 , consisting essentially of 40 to 60 atomic percentage (at %) Pd claim 6 , 40 to 60 at % Co claim 6 , and up to 30 at % Cr.8. The catalyst of claim 6 , consisting essentially of 30 to 60 at % Pd claim 6 , 30 to 70 at % Co claim 6 , and less than 20 at % Cr.9. The catalyst of claim 4 , consisting essentially of Pd claim 4 , Co and W.10. The catalyst of claim 9 , consisting essentially of 60 at % or more Pd claim 9 , 40 at % or less Co claim 9 , and up to 20 at % W.11. The catalyst of claim 4 , consisting essentially of Pd claim 4 , Fe claim 4 , and Cr.12. The catalyst of claim 11 , consisting essentially of 40 to 80 at % Pd claim 11 , 20 to 60 at % Fe claim 11 , and up to 20 at % Cr.13. The catalyst of claim 11 , consisting essentially of 30 to 80 at % Pd claim 11 , 20 to 70 at % Fe claim 11 , and up to 40 at % Cr.14. The catalyst of selected from the group consisting of PdCoCr claim 4 , PdCoW claim 4 , PdFeCr claim 4 , PdFeW claim 4 , PdCrW claim 4 , PdWAu claim 4 , PdCrAu claim 4 , PdCoFe claim 4 , and PdFeAu.15. A cathode for a fuel cell claim 1 , the cathode comprising a cathode ...
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