25-06-2020 дата публикации
Номер: US20200199346A1
Принадлежит:
The present invention relates to a polymerizable composition, which comprises (a) at least one radically polymerizable oligomer, (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization, characterized in that the radically polymerizable oligomer (a) is selected from the group consisting of aliphatic urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers and polyether urethane (meth)acrylate oligomers, and the radically polymerizable monomer (b) is polyfunctional. 11. Polymerizable composition according to further comprisinga monofunctional monomer or a monofunctional monomer selected from the group consisting of dicyclopentanyl methacrylate, p-cumylphenoxyethylene glycol methacrylate and mixtures thereof.12. Polymerizable composition according to further comprisinga UV absorber, wherein the UV absorber is selected from the group consisting of 2,2′-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], 2,2′,4,4′-tetrahydroxybenzophenone, 2-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)-4-methylphenol (bumetrizole), 2,2′-benzene-1,4-diylbis(4h-3,1-benzoxazin-4-one), 2-(4,6-bis-(2,4-dimethylphenyl)-1,3,5-triazin-2-yl)-5-(octyloxy)phenol, 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxyphenyl)benzotriazole, 2-(2H-benzotriazol-2-yl)-6-dodecyl-4-methylphenol, 2-(2′-hydroxy-3′,5′-di-t-butylphenyl)-5-chlorobenzotriazole, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone and mixtures thereof, or wherein the UV absorber is bumetrizole or 2,2′,4,4′-tetrahydroxybenzophenone.13. Polymerizable composition according to further comprisingup to 15 vol.-% of a filler.14. Polymerizable composition according to comprising in each case relative to the total weight of the composition claim 1 ,(a) 25 to 60 wt.-% oligomer,(b) 30 to 65 wt.-% polyfunctional monomer,(c) 0.1 to 3.0 wt.-% photoinitiator,(d) 0 to 15 wt.-% monofunctional monomer,(e) 0 to 2.0 wt.-% UV absorber,(f ...
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