Method for preparing activated charcoal

The invention provides a method for preparing activated charcoal from a precursor material comprising high mineral content plant or algal material by heating the precursor material under suitable conditions sufficient to produce activated charcoal therefrom. The precursor may be woody (e.g. Eucalyptus) or non-woody plant material. The heating can take place at 300 up to 900 degrees C. The invention also provides various applications of the activated charcoal per se.

BALL ACTIVATED CHARCOAL

REACTIVE-ADSORPTIVE PROTECTIVE MATERIALS AND METHODS FOR USE

Porous bodies and methods

Zeolite adsorbents having a high external surface area and uses thereof

The present invention concerns the use, for gas separation, of at least one zeolite adsorbent material comprising at least one FAU zeolite, said adsorbent having an external surface area greater than 20 m ...

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

La présente invention concerne l'utilisation, pour la séparation et/ ou le séchage de gaz, d'au moins un matériau adsorbant zéolithique comprenant au moins une zéolithe de type A, ledit adsorbant présentant une surface externe supérieure à 20 m2 · g-1, une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ = 30%, et de ratio atomique Si/AI compris entre 1,0 et 2,0. L'invention concerne également un matériau adsorbant zéolithique présentant un rapport Si/AI compris entre 1,0 et 2,0, un volume mésoporeux compris entre 0,07 cm3 · g-1 à 0,18 cm3 ·g-1, un rapport (Vmicro - Vméso) / Vmicro compris entre -0,3 et 1,0, bornes non incluses, et une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ = 30%.

POROUS BODY AND PRODUCTION METHOD THEREFOR

The present invention provides a porous material which has continuous pores and comprises a polymethyl methacrylate as a main component, wherein the continuous pores have a diameter of 0.001 µm to 500 µm and at least one surface of the porous material has a porosity of 10% to 80%; a separation membrane composed of the same; an adsorbent composed of the same; and a method production of the same. According to the present invention, a porous material whose surface porosity and pore diameter are each controlled in a specific range can be obtained. The porous material according to the present invention has a fine and uniform porous structure in which the pore diameter can be controlled in the order of nanometers to micrometers; therefore, it can be advantageously used as a separation membrane such as a blood component separation membrane of an artificial kidney or the like or as an adsorbent.

Flüssigkeitsbrücke

METHOD OF SEPARATING GAS-CONDENSATE LIQUIDS FROM NATURAL GAS USING WITH LEGUMES GRASSES BEING SOWN ON CONTAMINATED MEDIA, CONTAINING PARTIALLY PYROLYZED MACROPOROUS POLYMER

ZEOLITE ADSORBENTS WITH LARGE OUTER SURFACE AND THEIR USE

ZEOLITE ADSORBENTS HIGH OUTER SURFACE, PROCESS FOR THEIR PREPARATION AND USES THEREOF

ZEOLITE ADSORBENTS HIGH OUTER SURFACE, PROCESS FOR THEIR PREPARATION AND USES THEREOF

COLUMN FOR ION CHROMATOGRAPH, SUPPRESSOR AND ION CHROMATOGRAPH

A separation column for an ion chromatograph, which is packed with an organic porous ion exchanger having a three-dimensionally network structure which has an open cell cellular structure comprising macropores connected with each other and, being present in the wall between them, a mesopore having a radius of 0. 01 to 50 μm, has a total pore volume of 1 to 50 ml/g, exhibits a value obtained by dividing the half width of the main peak of the pore distribution curve thereof by the radius of the peak top of the main peak of 0.5 or less, and has ion exchange groups introduced so as for the exchanger to have an ion-exchange capacity of 0.1 to 5000 μg equivalent/g-dry organic porous ion exchanger. The separation column exhibits high performance capability especially for the separation and concentration of low molecular weight ions, and thus can be used for passing a sample solution through it with a reduced pressure while retaining a high capability for ion resolution. © KIPO & WIPO 2007 ...

CHROMATOGRAPHY MEDIA AND DEVICES

MULTU-FUNCTIONAL PROTECTIVE TEXTILES AND METHODS FOR DECONTAMINATION

A reactive and adsorptive (i.e., multi -functional protective) textile and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. In one aspect, a protective spatially-distributed biocidal interface is provided comprising a textile having interior structures, wherein protective nanoparticles bonded to said interior structures such that an article or portions of an article which are maintained in proximity to the textile are permitted to safely pass through a contaminated environment without dispersing the nanoparticles from ...

POROUS INORGANIC COMPOSITE AND METHOD FOR SEPARATING METAL ELEMENTS USING THE SAME

A porous inorganic composite comprising: an inorganic porous particle having an average diameter of 1 'mu'm to 1 mm, a porosity of 0.20 to 0.90, and an average pore diameter of 10 to 5000 nm; and an inorganic material supported on the particle.

REACTIVE-ADSORPTIVE PROTECTIVE MATERIALS AND METHODS FOR USE

A reactive-adsorptive protective material having an activated carbon adsorbent, including those manufactured from a gel-type ion exchange resin. The activated carbon adsorbent has adsorptive properties for adsorbing chemical impurities. The activated carbon is wettlerized to further impart reactive properties onto the activated carbon for providing protection against blood agents in the atmosphere. Advantageously, a superior reactive-adsorptive material is provided having the ability to neutralize chemical substances, in particular, blood agents, while at the same time not diminishing the effectiveness of the carbon's adsorption capabilities.

Use of a polymeric mesh for the purification of macromolecules

Method for recovering a target protein from a feedstock comprising said target protein and at least one impurity compound selected from host cell proteins (HCP), DNA, RNA or other nucleic acid, the target protein being characterized by a hydrodynamic radius Rh1 and the impurity compound being characterized by a hydrodynamic radius Rh2, wherein Rh1>Rh2, comprising the following steps (i) to (iv) and optionally step (v): (i) providing a polymeric mesh comprising at least one crosslinked polymer containing positively charged amino groups, wherein the polymer has a pore size exclusion limit Rhi which can be set variably; (ii) adapting the variable pore size exclusion limit Rhi of the polymeric mesh such that Rh2Rhi; (iii) contacting the polymeric mesh with the feedstock; (iv) separating the polymeric mesh containing the retained impurity compound from the feedstock containing the excluded target protein.

Disposable filters and manufacturing process

Disposable paper filters suitable for removal of contaminants from fluids such as water or air are disclosed. Specific embodiments include single-ply and multi-ply filters in which metal removal additives and/or halogen and organic contaminant removal additives have been distributed during the manufacturing process. Special manufacturing methods for producing such composite filters are also described.

Carbon nanotube-containing catalysts, methods of making, and reactions catalyzed over nanotube catalysts

Methods have been developed to form catalysts having active metals disposed on a carbon nanotube coated porous substrate. Catalysts and reactions over nanotube-containing catalysts are also disclosed. Results are presented showing enhanced performance resulting from use of the inventive catalyst. Mesoporous oxide layers can be utilized to improve catalyst properties.

Monolithic natural gas storage delivery system based on sorbents

The invention provides methods for producing a strong, light, sorbent-based storage/dispenser system for gases and fuels. The system comprises a porous monolithic material with an adherent strong impervious skin that is capable of storing a gas under pressure in a safe and usable manner.

ADSORBENT FOR SEPARATION-RECOVERY OF CO

PROCEDURE FOR THE PRODUCTION OF A COMPOUND SORPTION MATERIAL FOR THE CHROMATOGRAPHI SEPARATION FROM BIO POLYMERS

Precipitated silica sorbents

The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.

NANOPOROUS CARBIDE DERIVED CARBON WITH TUNABLE PORE SIZE

The present invention provides a method for producing a nanoporous carbide-derived carbon composition with a tunable pore structure and a narrow pore size. Also provided are compositions prepared by the method.

METHOD FOR EXTRACTING NATURAL GAS LIQUIDS FROM NATURAL GAS USING AN ADSORBENT MEDIA COMPRISING A PARTIALLY PYROLIZED MACROPOROUS POLYMER

A method is disclosed for the separation of ethane and heavier hydrocarbons or propane and heavier hydrocarbons from natural gas to provide a methane-rich natural gas stream and less volatile natural gas liquids (NGLs). This method provides for passing a natural gas feedstream though a regenerable adsorbent media which adsorbs the NGLs to provides the methane rich natural gas product. The regenerable adsorbent media of the present invention is a pyrolized macroporous polymer adsorbent media.

ZEOLITE ADSORBENTS WITH LARGE OUTER SURFACE AND THEIR USE

SELF-SUPPORTING STRUCTURES HAVING ADSORPTIVE PROPERTIES

The present invention relates to a self-supporting three-dimensional adsorptive structure, in particular a shaped adsorptive body, which comprises a plurality of individual adsorber particles, characterized in that the individual adsorber particles are joined by means of at least one hydrocolloid to form a self-supporting three-dimensional adsorptive structure, in particular a shaped adsorptive body, and in that the individual adsorber particles are joined to one another and/or fixed to one another and/or made to adhere to one another by means of at least one hydrocolloid.

GAS ABSORPTION GRANULAR MATERIAL

The invention relates to a granular material composed of a build-up agglomeration of porous granules for absorbing harmful gases, such as SOx, from exhaust gases of thermal processes, the granules of said granular material being designed for use in a solid matter - exhaust gas reactor in terms of their strength properties and their granular grain size distribution, and containing at least one calcium compound in the form of calcium hydroxide and/or limestone powder as an active substance.

CO-AGGLOMERATED COMPOSITE MATERIALS, METHODS FOR MAKING CO-AGGLOMERATED COMPOSITE MATERIALS, AND METHODS FOR USING CO-AGGLOMERATED COMPOSITE MATERIALS

A composite filter aid may include a first mineral selected from diatomaceous earth and natural glass. The filter aid may also include a second mineral having and aspect ratio greater than about 2:1, and a binder. The filter aid may have a permeability ranging from 0.2 to 20 darcys. A method for making a composite filter aid may include blending a first mineral, a second mineral, and a binder, wherein the first mineral comprises at least one of diatomaceous earth and natural glass, and the second mineral has an aspect ratio greater than about 2:1. The method may further include agglomerating the first mineral and second mineral in the presence of the binder to form the composite filter aid. A method for filtering a beverage may include using the composite filter aid.

POLYMERIC SORBENTS FOR ALDEHYDES AND METHODS OF MAKING

ADSORPTIONSMITTEL ZUR TRENNUNG - GEWINNUNG VON CO, HERSTELLUNGSVERFAHREN DAFUER UND VERFAHREN ZUR TRENNUNG - GEWINNUNG VON CO HOHER REINHEIT UNTER VERWENDUNG DIESES ADSORPTIONSMITTELS

Superficially porous hybrid monoliths with ordered pores and methods of making and using same

Activated charcoal

Zeolite adsorbents having a high external surface area and uses thereof

The present invention concerns the use, for gas separation, of at least one zeolite adsorbent material comprising at least one FAU zeolite, said adsorbent having an external surface area greater than 20 m ...

MULTI-FUNCTIONAL PROTECTIVE MATERIALS AND METHODS FOR USE

A reactive-adsorptive protective material having an activated carbon adsorbe nt for adsorbing chemical impurities, wherein nanoparticular entities are loade d into and onto a surface of said activated carbon adsorbent to further impart chemically reactive and biocidal properties onto the activated carbon for providing protection against chemical and biological agents in the atmospher e. Advantageously, a superior reactive-adsorptive material is provided having t he ability to kill microorganisms in addition to the ability to neutralize and decompose chemical substances, while at the same time not diminishing the adsorptive/reactive capabilities and effectiveness of either the substrate carbon or the loaded nanoparticular entities used.

POROUS WEBS

... 2127979 9314265 PCTABS00024 Porous materials having a range of pore sizes are given desired characteristics by selective deposition in the large pores of particulate treatment agents. Thus some characteristics are achievable by control variation of pore size distribution (e.g. sample uniformity, liquid filtration properties) while others depend on specific attributes of the treatment agents (e.g. response to calendering, catalysis, security marking, adhesion properties).

GRANULAR MATERIAL ZEOLITIC RELATED STRUCTURE

RETAINING LOCK-BASED ADSORBENTS ZEOLITE X HAS LOW BINDER CONTENT AND LOW EXTERNAL SURFACE, PREPARATION METHOD AND USES THEREOF

L'invention concerne un adsorbant comprenant une phase zéolithique et une phase non zéolithique, ledit adsorbant présentant : - une surface externe inférieure ou égale à 30 m2.g-1, de préférence inférieure ou égale à 20 m2.g-1, - une phase zéolithique comprenant au moins une zéolithe de structure FAU de type X, - et une distribution de diamètre de pores, déterminée par intrusion de mercure selon la norme ASTM D4284-83 et exprimée par la distribution en volume dV/dlogDHg, où DHg est le diamètre apparent des pores, et V, le volume poreux, dont le mode est compris entre 100 nm et 250 nm, bornes incluses. L'invention concerne également un procédé de préparation dudit adsorbant et leurs utilisations, notamment pour la séparation des isomères de xylènes. The invention relates to an adsorbent comprising a zeolite phase and a non-zeolite phase, said adsorbent having: - an external surface area less than or equal to 30 m2.g-1, preferably less than or equal to 20 m2.g-1, - a zeolite phase comprising at least one zeolite of type X FAU structure, - and a pore diameter distribution, determined by mercury intrusion according to the ASTM D4284-83 standard and expressed by the volume distribution dV/dlogDHg, where DHg is the apparent diameter of the pores, and V, the pore volume, whose mode is between 100 nm and 250 nm, limits included. The invention also relates to a process for preparing said adsorbent and their uses, in particular for the separation of xylene isomers.

CAPTURE MASS WITH IMPROVED PERFORMANCE AND ITS USE IN THE CAPTURE OF HEAVY METALS

낮은 바인더 함량과 낮은 외부 표면적을 갖는 X 제올라이트로 만들어진 제올라이트 흡착제, 상기 흡착제의 제조 방법 및 그것의 용도

... 본 발명은 제올라이트 상 및 비제올라이트 상을 포함하는 흡수제에 관한 것으로, 상기 흡수제는: 30 m2.g-1 이하, 바람직하게 20 m2.g-1 이하의 외부 표면적, FAU 구조를 갖는 적어도 하나의 X 제올라이트를 포함한 제올라이트 상, 및 표준 ASTM D 4284-83 에 따라 수은 압입에 의해 결정되고 부피 분포 dV/dlogDHg 에 의해 표현된 포어 직경 분포로서, DHg 는 포어들의 겉보기 직경이고 V 는 다공성 부피이고, 포어 직경 분포의 모드는, 종단값들 (terminals) 을 포함해 100 ㎚ ~ 250 ㎚ 인, 포어 직경 분포를 갖는다. 본 발명은 또한 상기 흡수제를 제조하기 위한 방법 및 특히 크실렌 이성질체들의 분리를 위한 흡수제의 용도에 관한 것이다.

ACTIVATED CHARCOAL

The invention provides a method for preparing activated charcoal from a precursor material comprising high mineral content plant or algal material by heating the precursor material under suitable conditions sufficient to produce activated charcoal therefrom. The invention also provides various applications of the activated charcoal per se.

ADSORBENT FOR ADSORBING VIRUS AND/OR BACTERIUM, CARBON/POLYMER COMPOSITE AND ADSORBENT SHEET

[Object] To provide an adsorbent, an adsorbent sheet, and a carbon/polymer composite for adsorbing a virus having further improved virus adsorption capability. 113-. (canceled)14. A method , comprising:{'sup': −9', '−7', '2', '3, 'providing a porous carbonaceous material comprising pores having diameters in a range from 1×10m to 5×10m, wherein the porous carbonaceous material has a specific surface area of 10 m/g or more as measured by a nitrogen BET method and a total pore volume of 0.1 cm/g or more as determined by Non Localized Density Functional Theory; and'}adsorbing a virus and/or a bacterium to the porous carbonaceous material.15. The method according to claim 14 , wherein the porous carbonaceous material has at least one peak in a pore diameter distribution in a range from 3 nm to 20 nm as determined by Non Localized Density Functional Theory claim 14 , and a ratio of the volume of pores with diameters in the range from 3 nm to 20 nm to the total pore volume of 0.2 or more.16. The method according to claim 15 , wherein the porous carbonaceous material comprises mesopores having a pore diameter in a range of about 2 nm to about 50 nm and macropores having a pore diameter greater than about 50 nm.17. The method according to claim 16 , wherein the porous carbonaceous material further comprises micropores having a pore diameter less than about 2 nm.18. The method according to claim 14 , wherein the porous carbonaceous material has a pore volume of 0.5 cm/g or more as measured by a BJH method.19. The method according to claim 14 , wherein the porous carbonaceous material has a pore volume of 4.12 cm/g or more as measured by a mercury intrusion method.20. The method according to claim 14 , wherein the porous carbonaceous material has a pore volume of 0.515 cm/g or more as measured by an MP method.21. The method according to claim 14 , wherein:the porous carbonaceous material is made from a plant-based material; andthe plant-based material comprises chaff, straws, ...

MULTI-FUNCTIONAL PROTECTIVE TEXTILES AND METHODS FOR DECONTAMINATION

A reactive and adsorptive (i.e., multi-functional protective) textile and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. In one aspect, a protective spatially-distributed biocidal interface is provided comprising a textile having interior structures, wherein protective nanoparticles bonded to said interior structures such that an article or portions of an article which are maintained in proximity to the textile are permitted to safely pass through a contaminated environment without dispersing the nanoparticles from ...

Metal-Organic Material Extrudates, Methods of Making, and Methods of Use

The present disclosure relates to compositions including metal-organic framework materials and a polymeric binder. The compositions may have a crush strength of about 2.5 lb-force or greater. The present disclosure also relates to processes for producing metal-organic framework extrudates. Processes may include mixing a metal-organic framework material, a polymeric binder, and optionally a solvent to form a mixture. The process may also include extruding the mixture to form a metal-organic framework extrudate.

Board materials provided with adsorbents for dry construction

Gegenstand der Erfindung ist ein Baumaterial für den Innenausbau auf Basis eines plattenförmigen Werkstoffs für den Trockenbau, insbesondere einer Bauplatte, wobei der plattenförmige Werkstoff Aktivkohle aufweist. Das Baumaterial eignet sich in hervorragender Weise zur Beseitigung von Emissionen von Schad- und/oder Geruchsstoffen mittels Adsorption, vorzugsweise in Gebäuden, insbesondere zu Zwecken der Entfernung von Schad- und/oder Geruchsstoffen in schad- und/oder geruchsstoffbelasteten Räume, zu Zwecken der Sanierung schad- und/oder Geruchsstoffbelasteter Räume und/oder zu Zwecken der Raumluftverbesserung.

Packing material and cartridge for solid phase extraction

... [SUMMARY] [PROBLEM TO BE SOLVED] To provide a packing material for solid phase extraction, which is adjusted in the pore size of packing material and ensures an excellent recovery; a column and a cartridge for solid phase extraction, using the packing material; and a process for treating a medical sample using the column or cartridge. [MEANS TO SOLVE THE PROBLEM] A packing material for solid phase extraction, which is a particle having an exclusion limit molecular weight of 1×103 to 1.5×104 in gel permeation chromatography using a standard polystyrene as the sample; a column for solid phase extraction and a cartridge for solid phase extraction, using the packing material; and a process for treating a sample using the column or cartridge.

СПОСОБ ПРИДАНИЯ ЗАДАННОГО СВОЙСТВА ПОЛОТНУ ИЗ ПОРИСТОГО МАТЕРИАЛА И ИЗДЕЛИЕ, ИЗГОТОВЛЕННОЕ С ИСПОЛЬЗОВАНИЕМ АГЕНТА ДЛЯ ПРИДАНИЯ МАТЕРИАЛУ ЗАДАННОГО СВОЙСТВА

Пористым материалам, имеющим интервал размеров пор, придают требуемые свойства посредством выборочного осаждения в большие поры порошкообразных обрабатывающих веществ. Таким образом, некоторые свойства могут быть получены посредством регулируемого изменения распределения размера поры (например, однородность образца, свойства фильтровать жидкость), тогда как другие свойства зависят от конкретного вклада обрабатывающих веществ (например, реакция на каландрование, способность к катализу, маркировки для защиты, адгезионные свойства).

ГРАНУЛИРОВАННЫЙ ЦЕОЛИТНЫЙ МАТЕРИАЛ СО СВЯЗНОЙ СТРУКТУРОЙ

Disposable filters and manufacturing process

GUARD LAYERS FOR RAPID CYCLE PRESSURE SWING ADSORPTION DEVICES

Guard layers are employed in the adsorbent beds of rapid cycle pressure swing adsorption (RCPSA) devices to protect the adsorbent therein from certain contaminants (e.g. water vapour). Conventional PSA devices typically pack the guard layer with as much guard material as is practical. In RCPSA devices however, the performance of the guard layer can be improved by using a reduced amount of guard material and increasing access to it. Such embodiments are characterized by guard layers with a channel fraction of greater than 50%.

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

La présente invention concerne l'utilisation, pour la séparation de gaz, d'au moins un matériau adsorbant zéolithique comprenant au moins une zéolithe de type FAU, ledit adsorbant présentant une surface externe supérieure à 20 m2 · g-1, une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ = 30%, et de ratio atomique Si/AI compris entre 1 et 2,5. L'invention concerne également un matériau adsorbant zéolithique présentant un rapport Si/AI tel que 1 = Si/AI < 2,5, un volume mésoporeux compris entre 0,08 cm3· g-1 à 0,25 cm3 · g-1, un rapport (Vmicro - Vméso) / Vmicro compris entre -0,5 et 1,0, bornes non incluses, et une teneur en phase non zéolithique (PNZ), telle que 0 < PNZ = 30%.

CHROMATOGRAPHY MEDIA AND DEVICES

Chromatography devices contain chromatography media and methods of making and methods of using chromatography devices. Chromatography devices enable a more efficient, productive and/or environmentally friendly chromatographic operation due to one or more of the following advantages over conventional chromatographic operations: elimination of a device packing step by the user; elimination of clean-in-place (CIP) steps; elimination of clean-in-place (CIP) steps utilizing sodium hydroxide solution; elimination of any validation steps by the user; and use of a chromatography device comprising biodegradable material. The chromatography media includes porous inorganic particles having a functionalized surface and having a median pore size of at least about 300 Angstroms (A), or at least about 300 A up to about 3000 A. The inorganic particles may have a BET surface area of at least about 20 m2/g, or at least about 25 m2/g, or about 30 m2/g, up to about 2000 m2/g.

CHROMATOGRAPHY MEDIA AND DEVICES

Chromatography devices contain chromatography media and methods of making and methods of using chromatography devices. Chromatography devices enable a more efficient, productive and/or environmentally friendly chromatographic operation due to one or more of the following advantages over conventional chromatographic operations: elimination of a device packing step by the user; elimination of clean-in-place (CIP) steps; elimination of clean-in-place (CIP) steps utilizing sodium hydroxide solution; elimination of any validation steps by the user; and use of a chromatography device comprising biodegradable material. The chromatography media includes porous inorganic particles having a functionalized surface and having a median pore size of at least about 300 Angstroms (A), or at least about 300 A up to about 3000 A. The inorganic particles may have a BET surface area of at least about 20 m2/g, or at least about 25 m2/g, or about 30 m2/g, up to about 2000 m2/g.

Loudspeaker system with improved sound

METHOD FOR PREPARING AN ADSORBENT FOR VOLATILE ORGANIC COMPOUNDS, METHOD FOR QUANTITATION OF VOLATILE ORGANIC COMPOUNDS

ZEOLITE ADSORBENTS HIGH OUTER SURFACE, PROCESS FOR THEIR PREPARATION AND USES THEREOF

La présente invention concerne l'utilisation, pour la séparation de gaz, d'au moins un matériau adsorbant zéolithique comprenant au moins une zéolithe de type FAU, ledit adsorbant présentant une surface externe supérieure à 20 m2.g-1, une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ ≤ 30%, et de ratio atomique Si/Al compris entre 1 et 2,5. L'invention concerne également un matériau adsorbant zéolithique présentant un rapport Si/Al tel que 1 ≤ Si/Al < 2,5, un volume mésoporeux compris entre 0,08 cm3.g-1 à 0,25 cm3.g-1, un rapport (Vmicro - Vméso)/Vmicro compris entre -0,5 et 1,0, bornes non incluses, et une teneur en phase non zéolithique (PNZ), telle que 0 < PNZ ≤ 30%. The present invention relates to the use, for gas separation, of at least one zeolitic adsorbent material comprising at least one FAU-type zeolite, said adsorbent having an external surface greater than 20 m 2 g -1, a phase content non-zeolitic (PNZ) such that 0 <PNZ ≤ 30%, and Si / Al atomic ratio between 1 and 2.5. The invention also relates to a zeolitic adsorbent material having an Si / Al ratio such that 1 ≤ Si / Al <2.5, a mesoporous volume of between 0.08 cm3g-1 to 0.25 cm3g-1, a ratio (Vmicro-Vmeso) / Vmicro between -0.5 and 1.0, terminals not included, and a non-zeolitic phase (PNZ) content, such that 0 <PNZ ≤ 30%.

CHROMATOGRAPHY MEDIA AND DEVICES

POROUS PARTICULATE MATERIAL FOR FLUID TREATMENT, CEMENTITIOUS COMPOSITION AND METHOD OF MANUFACTURE THEREOF

A porous particulate material for treating a fluid containing a contaminant is disclosed. The particulate material comprises a cementitious matrix or binder and treated bauxite refinery residue or red mud. At least a portion of the pores in the particulate material is open cell or interconnected pores. The invention also relates to the use of a reactive permeable barrier comprising porous material, for treating a contaminated fluid. Also disclosed is a method for producing porous particulate material for treating a contaminated fluid and a method for treating a contaminated fluid, in which the porous material is used. The invention furthermore relates to a cementitious composition comprising partially neutralised red mud and cement, wherein the partially neutralised red mud has been pre-treated by contacting it with water having a total hardness supplied by calcium, magnesium or a combination thereof, of at least 3.5 millimoles per litre calcium carbonate equivalent. The cementitious composition is useful as a building and construction material.

Use of porous glass separation medium for high performance liquid chromatography

СОРБЕНТЫ НА ОСНОВЕ ОСАЖДЕННОГО ДИОКСИДА КРЕМНИЯ

FIELD: chemistry. SUBSTANCE: invention relates to separation material containing precipitated silicon dioxide, which is dried in a rotary or spray dryer. The silicon dioxide has pore surface area P, where log10 P>2.2, and a BET surface area to CTAB surface area ratio measured prior to any surface modification of the silicon dioxide of at least 1.0. A method is disclosed for separating suspended or dissolved substances from a stream of fluid medium by contacting said stream with separation material described above. EFFECT: high efficiency of separation. 23 cl, 5 tbl, 4 ex

MULTU-FUNCTIONAL PROTECTIVE TEXTILES AND METHODS FOR DECONTAMINATION

Sampling for monitoring per- and polyfluoroalkyl substances (pfas) in surface water, groundwater and pore water

Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

PRECIPITATED SILICA SORBENTS

The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.

POROUS PARTICULATE MATERIAL FOR FLUID TREATMENT, CEMENTITIOUS COMPOSITION AND METHOD OF MANUFACTURE THEREOF

A porous particulate material for treating a fluid containing a contaminant is disclosed. The particulate material comprises a cementitious matrix or binder and treated bauxite refinery residue or red mud. At least a portion of the pores in the particulate material is open cell or interconnected pores. The invention also relates to the use of a reactive permeable barrier comprising porous material, for treating a contaminated fluid. Also disclosed is a method for producing porous particulate material for treating a contaminated fluid and a method for treating a contaminated fluid, in which the porous material is used. The invention furthermore relates to a cementitious composition comprising partially neutralised red mud and cement, wherein the partially neutralised red mud has been pre-treated by contacting it with water having a total hardness supplied by calcium, magnesium or a combination thereof, of at least 3.5 millimoles per litre calcium carbonate equivalent. The cementitious composition ...

ACTIVATED CHARCOAL

The invention provides a method for preparing activated charcoal from a precursor material comprising high mineral content plant or algal material by heating the precursor material under suitable conditions sufficient to produce activated charcoal therefrom. The invention also provides various applications of the activated charcoal per se.

PROCESS FOR REGENERATING THE ACTIVATED CARBON BY ELECTRO FENTON'S METHOD

METAL OXIDE COMPOSITIONS FOR SEQUESTERING CARBON DIOXIDE AND METHODS OF MAKING AND USING THE SAME

The present invention is directed to methods of sequestering carbon dioxide using metal oxide compositions, methods of making the metal oxide compositions, and articles comprising the metal oxide compositions.

SEQUESTRATION OF COMPOUNDS FROM MICROORGANISMS

The invention provides novel mesoporous particles and methods for the selective sequestration of organic compounds from microorganisms, such as from various genera and species of algae that produce important organic compounds. The organic compounds can be selectively sequestered, for example, in favor of biodiesel impurities such as sterols and chlorophyll, to provide substantially pure free fatty acids. The free fatty acids can then be esterified to provide pure biodiesel.

POROUS BODIES AND METHODS

Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Adsorbent for separating nitrogen from mixed gas of oxygen and nitrogen

An adsorbent for separating nitrogen from a mixed gas of oxygen and nitrogen is MSC wherein an oxygen and nitrogen separation ratio alpha and a ratio (t95/t50) of a time t50 required for adsorbing 50% of the oxygen equilibrium adsorption amount and a time t95 required for adsorbing 95% of the oxygen equilibrium adsorption amount satisfy the inequality (t95/t50)<0.4x(alpha-24)alpha>=35. The amount of adsorbent used with respect to a predetermined amount of nitrogen generated can be reduced since a method is carried out which uses this adsorbent to produce nitrogen by separating nitrogen from the mixed gas of oxygen and nitrogen by means of a PSA method. By this means, it is possible to reduce the cost of the apparatus and reduce and miniaturize the scale of the apparatus, and the power consumption amount can be reduced.

Porous Molded Article, and Method for Manufacturing the Same

There is provided a porous formed article which can remove hazardous substances at a high speed, has a high adsorption capacity and has high durability to cleaning chemicals and further which is scarcely broken even if being repeatedly used, and which contains an organic polymeric resin and an inorganic ion-adsorbing material, wherein the organic polymeric resin is a polyether sulfone resin and/or a polysulfone resin, and is an organic polymeric resin having a hydroxyl group.

Engine control sysstem configured to adjust present operation pursuant to predicted duty cycle operating conditions

An engine control system configured to operate an engine is configured to predict an expected duty cycle including an expected demand from the engine, and calculate two or more future operating conditions, each future operating condition including engine control parameters that, when used to control the engine, are expected to result in the engine meeting the expected demand. One of the future operating conditions is selected, and a present operation of the engine is adjusted in response to the selected future operating condition. A vehicle and/or offroad diesel apparatus may comprise the engine control system.

ZEOLITIC ABSORBENTS COMPRISING A ZEOLITE WITH HIERARCHICAL POROSITY

The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.

ГРАНУЛИРОВАННЫЙ ЦЕОЛИТНЫЙ МАТЕРИАЛ СО СВЯЗНОЙ СТРУКТУРОЙ

FIELD: chemistry.SUBSTANCE: group of inventions refers to a granular zeolite material with a zeolite structure that is connected throughout the bulk of the material, a process for its production and use. Material is used as an adsorbent in a co-current or countercurrent separation processes in the liquid phase, usually in a pseudo-mobile layer.EFFECT: invention provides a material with a high mechanical crush strength in the layer that has an optimized mass transfer in the macropores.9 cl, 4 dwg, 3 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 666 447 C2 (51) МПК B01J 20/18 (2006.01) C01B 39/22 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B01J 20/18 (2006.01); C01B 39/22 (2006.01) (21)(22) Заявка: 2016123934, 20.11.2014 (24) Дата начала отсчета срока действия патента: Дата регистрации: 07.09.2018 20.11.2013 FR 1361380 (43) Дата публикации заявки: 25.12.2017 Бюл. № 36 (56) Список документов, цитированных в отчете о поиске: RU 2451543 C2 27.05.2012. US (45) Опубликовано: 07.09.2018 Бюл. № 25 8530367 B2 10.09.2013. US 20110105301 A1 05.05.2011. SU 1381067 A1 15.03.1988. (85) Дата начала рассмотрения заявки PCT на национальной фазе: 20.06.2016 (86) Заявка PCT: C 2 C 2 (73) Патентообладатель(и): ИФП ЭНЕРЖИ НУВЕЛЛЬ (FR), АРКЕМА ФРАНС (FR) EP 2014/075191 (20.11.2014) (87) Публикация заявки PCT: 2 6 6 6 4 4 7 WO 2015/075140 (28.05.2015) R U 2 6 6 6 4 4 7 Приоритет(ы): (30) Конвенционный приоритет: R U 20.11.2014 (72) Автор(ы): ЛАРОШ Катрин (FR), БУВЬЕ Людивин (FR), ЛЕФЛЕВ Филибер (FR), ЛЮТЦ Сесиль (FR), ГАЙ Анн-Софи (FR), МОРО Флоран (FR) Адрес для переписки: 129090, Москва, ул. Большая Спасская, д. 25, строение 3, ООО "Юридическая фирма Городисский и Партнеры" (54) ГРАНУЛИРОВАННЫЙ ЦЕОЛИТНЫЙ МАТЕРИАЛ СО СВЯЗНОЙ СТРУКТУРОЙ (57) Реферат: Группа изобретений относится к псевдоподвижном слое. Изобретение гранулированному цеолитному материалу с обеспечивает получение материала с высокой цеолитной структурой, связной во ...

ХРОМАТОГРАФИЧЕСКИЕ СРЕДЫ И УСТРОЙСТВА

... 1. Хроматографическое устройство, содержащее:корпус устройства ихроматографическую среду, расположенную внутри упомянутого корпуса устройства, где упомянутая среда содержит пористые неорганические частицы, имеющие функционализированную поверхность, где упомянутые пористые неорганические частицы имеют средний размер пор, по меньшей мере, 300 Å; распределение размера пор с относительным разбросом, по меньшей мере, приблизительно 0,8; и упомянутая функционализированная поверхность содержит, по меньшей мере, одну молекулу, имеющую молекулярную массу больше чем приблизительно 300 г/моль.2. Хроматографическое устройство по п. 1, в котором упомянутые пористые неорганические частицы имеют средний размер пор, по меньшей мере, 500 Å.3. Хроматографическое устройство по п. 1 или 2, в котором упомянутые пористые неорганические частицы имеют средний размер пор, по меньшей мере, 800 Å.4. Хроматографическое устройство по п. 1 или 2, в котором упомянутые пористые неорганические частицы имеют площадь поверхности ...

Sphärische Hochleistungsadsorbenzien mit Mikrostruktur und ihre Verwendung

Hochleistungsadsorbenzien, umfassend Adsorberpartikel, die aus Polymerharzen hergestellt sind, dadurch gekennzeichnet, dass die Adsorberpartikel eine Mikrostruktur mit Poren in einem Größenbereich zwischen 0 Å und 40 Å aufweisen und dass die Porenverteilung so ist, dass eine Porengröße im Bereich zwischen 40 Å und 20 Å bei 5 % bis 10 % des Gesamtmikroporenvolumens vorliegt, eine Porengröße im Bereich zwischen 20 Å und 10 Å bei 15 % bis 25 % des Gesamtmikroporenvolumens vorliegt, eine Porengröße im Bereich zwischen 10 Å und 8 Å bei 10 % bis 20 % des Gesamtmikroporenvolumens vorliegt, eine Porengröße im Bereich zwischen 8 Å und 5 Å bei 40 % bis 50 % des Gesamtmikroporenvolumens und eine Porengröße im Bereich zwischen 5 Å und 0 Å bei 15 % bis 25 % des Gesamtmikroporenvolumens vorliegt.

Superficially porous hybrid monoliths with ordered pores and methods of making and using same

The invention provides superficially porous metal oxide or hybrid metal oxide monoliths with ordered pore structures. The superficially porous hybrid silica monoliths of the invention provide several major advantages over existing silica monoliths. When used in chromatography, the superficially porous hybrid silica monoliths of the invention deliver fast separation at very low back pressure and possess superb pH stability and much improved mechanical strength.

Improved-performance trapping mass and use thereof in heavy metal trapping

The invention relates to the elimination of heavy metals, in particular mercury and optionally arsenic and lead, from a gaseous or liquid effluent, using a trapping mass comprising a support essentially based on alumina obtained by gel method and at least one element selected from the group containing copper, molybdenum, tungsten, iron, nickel and cobalt. Advantageously, the invention can be used for the treatment of industrial gas, synthesis gas, natural gas, gas-phase condensates and liquid hydrocarbon feedstocks.

Superficially porous hybrid monoliths with ordered pores and methods of making and using same

ADSORBENT AND PROCESS FOR RECOVERING CO.

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

La présente invention concerne l'utilisation, pour la séparation et/ ou le séchage de gaz, d'au moins un matériau adsorbant zéolithique comprenant au moins une zéolithe de type A, ledit adsorbant présentant une surface externe supérieure à 20 m2 · g-1, une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ = 30%, et de ratio atomique Si/AI compris entre 1,0 et 2,0. L'invention concerne également un matériau adsorbant zéolithique présentant un rapport Si/AI compris entre 1,0 et 2,0, un volume mésoporeux compris entre 0,07 cm3 · g-1 à 0,18 cm3 ·g-1, un rapport (Vmicro - Vméso) / Vmicro compris entre -0,3 et 1,0, bornes non incluses, et une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ = 30%.

PRECIPITATED SILICA SORBENTS

The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.

DISPOSABLE FILTERS AND MANUFACTURING PROCESS

Disposable paper filters suitable for removal of contaminants from fluids such as water or air are disclosed. Specific embodiments include single-ply and multi-ply filters in which metal removal additives and/or halogen and organic contaminant removal additives have been distributed during the manufacturing process. Special manufacturing methods for producing such composite filters are also described.

Adsorbent and its mfr. method for separation and recovery of carben monoxide, and the method of using it to separate and recover high-purity carben monoxide

本发明是分离回收CO用的吸附剂。是以氧化硅和/或氧化铝构成的载体(a)为核心，并在其表面形成活性有机质碳化物层(b)，构成复合载体(X)，再使它载带铜化合物(Y)。用此吸附剂，并通过实施压力变动式吸附分离法和/或温度变动式吸附分离法，就可以大规模从转炉气及其它含CO和气体中分离回收高纯CO。

Zeolitic particulate material having a connecting structure

Porous body and production method therefor

Hierarchical pore sugar-based carbon material as well as preparation method and application thereof

METHOD FOR PREPARING AN ADSORBENT FOR VOLATILE ORGANIC COMPOUNDS, METHOD FOR QUANTITATION OF VOLATILE ORGANIC COMPOUNDS

L'invention se rapporte à un procédé de préparation 100 d'un adsorbant adapté pour l'adsorption de composés organiques volatils, ledit procédé comportant des étapes de : - mélange (101), à une température comprise entre -45°C et +30°C, d'un ou plusieurs premier(s) polyalcoxysilane(s) avec un solvant organique miscible à l'eau pour former un premier mélange ; - addition (102) d'un ou plusieurs second(s) polyalcoxysilane(s), dans un rapport molaire premier(s) polyalcoxysilane(s)/ second(s) polyalcoxysilane(s) de 1/0,01 à 1/1, et d'eau au premier mélange pour former un matériau sol-gel, - séchage (104) du matériau sol-gel à une température comprise entre 25°C et 60°C pour obtenir un matériau sol-gel sec, - chauffage (108) du matériau sol-gel sec à une température comprise entre 150°C et 320°C pendant une durée minimale de 8h et sous un flux d'air sec ou de gaz inerte sec pour obtenir l'adsorbant attendu. The invention relates to a method of preparing 100 an adsorbent adapted for the adsorption of volatile organic compounds, said process comprising steps of: - mixing (101), at a temperature between -45 ° C and +30 ° C, one or more first polyalkoxysilane (s) with an organic solvent miscible with water to form a first mixture; - addition (102) of one or more second polyalkoxysilane (s), in a molar ratio of first (s) polyalkoxysilane (s) / second (s) polyalkoxysilane (s) from 1 / 0.01 to 1/1 and water to the first mixture to form a sol-gel material, - drying (104) of the sol-gel material at a temperature of between 25 ° C and 60 ° C to obtain a dry sol-gel material, - heating ( 108) dry sol-gel material at a temperature between 150 ° C and 320 ° C for a minimum period of 8 hours and under a stream of dry air or dry inert gas to obtain the expected adsorbent.

MASS COLLECTING HAS PERFORMANCES AMELIOREES AND ITS USE IN COLLECTING OF HEAVY METALS

La présente invention concerne l'élimination de métaux lourds et notamment de mercure et éventuellement d'arsenic et de plomb présents dans un effluent gazeux ou liquide, au moyen d'une masse de captation comprenant un support essentiellement à base d'alumine obtenue par voie gel et au moins un élément choisi dans le groupe constitué par le cuivre, le molybdène, le tungstène, le fer, le nickel et le cobalt. L'invention s'applique avantageusement au traitement de gaz d'origine industrielle, de gaz de synthèse, de gaz naturel, de condensats en phase gazeuse et de charges hydrocarbonées liquides. The present invention relates to the elimination of heavy metals and in particular of mercury and possibly arsenic and lead present in a gaseous or liquid effluent, by means of a capture mass comprising a support essentially based on alumina obtained by gel and at least one member selected from the group consisting of copper, molybdenum, tungsten, iron, nickel and cobalt. The invention is advantageously applicable to the treatment of gases of industrial origin, synthesis gas, natural gas, condensates in the gas phase and liquid hydrocarbon feeds.

ZEOLITE ADSORBENTS PICK X LOW LOW BINDER AND OUTER SURFACE, PROCESS FOR THEIR PREPARATION AND USES THEREOF

L'invention concerne un adsorbant comprenant une phase zéolithique et une phase non zéolithique, ledit adsorbant présentant : - une surface externe inférieure ou égale à 30 m2.g-1, de préférence inférieure ou égale à 20 m2.g-1, - une phase zéolithique comprenant au moins une zéolithe de structure FAU de type X, - et une distribution de diamètre de pores, déterminée par intrusion de mercure selon la norme ASTM D4284-83 et exprimée par la distribution en volume dV/dlogDHg, où DHg est le diamètre apparent des pores, et V, le volume poreux, dont le mode est compris entre 100 nm et 250 nm, bornes incluses. L'invention concerne également un procédé de préparation dudit adsorbant et leurs utilisations, notamment pour la séparation des isomères de xylènes.

높은 외부 표면적을 갖는 제올라이트 흡착제들 및 그것의 용도들

... 본 발명은 적어도 하나의 유형 A 제올라이트를 포함하는 적어도 하나의 제올라이트 흡착제 재료의, 가스 분리 및/또는 가스 건조를 위한, 용도에 관한 것으로, 상기 흡착제는 20 m2.g-1 초과의 외부 표면적, 0 < PNZ ≤ 30% 인 비제올라이트 상 (PNZ) 함량, 및 1.0 과 2.0 사이 Si/Al 원자 비를 갖는다. 본 발명은 또한 1.0 과 2.0 사이의 Si/Al 비, 0.07 cm3.g-1 과 0.18 cm3.g-1 사이의 메소포러스 체적, -0.3 과 1.0 사이 (경계 미포함) 의 (Vmicro - Vmeso)/Vmicro, 및 0 < PNZ ≤ 30% 인 비제올라이트 상 (PNZ) 함량을 갖는 제올라이트 흡착제 재료에 관한 것이다.

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

본 발명은 적어도 하나의 유형 A 제올라이트를 포함하는 적어도 하나의 제올라이트 흡착제 재료의, 가스 분리 및/또는 가스 건조를 위한, 용도에 관한 것으로, 상기 흡착제는 20 m 2 .g -1 초과의 외부 표면적, 0 < PNZ ≤ 30% 인 비제올라이트 상 (PNZ) 함량, 및 1.0 과 2.0 사이 Si/Al 원자 비를 갖는다. 본 발명은 또한 1.0 과 2.0 사이의 Si/Al 비, 0.07 cm 3 .g -1 과 0.18 cm 3 .g -1 사이의 메소포러스 체적, -0.3 과 1.0 사이 (경계 미포함) 의 (Vmicro - Vmeso)/Vmicro, 및 0 < PNZ ≤ 30% 인 비제올라이트 상 (PNZ) 함량을 갖는 제올라이트 흡착제 재료에 관한 것이다. The present invention relates to the use of at least one zeolite adsorbent material comprising at least one type A zeolite, for gas separation and / or gas drying, wherein the adsorbent has an external surface area of greater than 20 m 2 .g −1 , A non-zeolitic phase (PNZ) content with 0 <PNZ <30%, and a Si / Al atomic ratio between 1.0 and 2.0. The invention also provides a Si / Al ratio between 1.0 and 2.0, a mesoporous volume between 0.07 cm 3 .g −1 and 0.18 cm 3 .g −1 , and a (Vmicro-Vmeso) of between -0.3 and 1.0 (without boundary). / Vmicro, and a zeolitic adsorbent material having a non-zeolitic phase (PNZ) content with 0 <PNZ <30%.

Adsorbent having capability of decomposing organic halogen compounds and method for producing the same

An adsorbent and process for producing an absorbent capable of decomposing an organic halogen compound, is provided. The adsorbent can adsorb organic halogen compounds contained in waste gases and can assuredly decompose them without synthesizing them. A salt of Pt and/or Pd, an organic titanium compound and an organic binder are reacted in a solvent, to thereby synthesize a dispersion of an organic metal compound precursor containing Pt and/or Pd and Ti in molecules thereof, a sol of TiO2 is added to the dispersion to prepare a catalyst-coating solution, an activated carbon is impregnated with the catalyst-coating solution, and the resulting mixture is heated, thereby allowing the activated carbon to carry thereon an organic halogen compound-decomposing catalyst comprising TiO2 and, dispersed therein, fine particles of Pt and/or Pd. In a low temperature range of 130 to 150° C. in which the activated carbon is usable, organic halogen compounds in the exhaust gases can be decomposed, and ...

Carbon nanotube-containing catalysts, methods of making, and reactions catalyzed over nanotube catalysts

Methods have been developed to form catalysts having active metals disposed on a carbon nanotube coated porous substrate. Catalysts and reactions over nanotube-containing catalysts are also disclosed. Results are presented showing enhanced performance resulting from use of the inventive catalyst. Mesoporous oxide layers can be utilized to improve catalyst properties.

ADSORBENT FOR ADSORBING VIRUS AND/OR BACTERIUM, CARBON/POLYMER COMPOSITE AND ADSORBENT SHEET

[Object] To provide an adsorbent, an adsorbent sheet, and a carbon/polymer composite for adsorbing a virus having further improved virus adsorption capability. 113-. (canceled)14. An adsorbent comprising:{'sup': −9', '−7', '2', '3, 'a porous carbonaceous material comprising pores having diameters in a range from 1×10m to 5×10m, wherein the porous carbonaceous material has a specific surface area of 10 m/g or more as measured by a nitrogen BET method, a total pore volume of 0.1 cm/g or more as determined by Non Localized Density Functional Theory, and one or more peaks between 70 nm and 180 nm in a pore diameter distribution as determined by Non Localized Density Functional Theory.'}151. The adsorbent of claim , wherein the porous carbonaceous material has at least one peak in a pore diameter distribution in a range from 3 nm to 20 nm as determined by Non Localized Density Functional Theory , and a ratio of the volume of pores with diameters in the range from 3 nm to 20 nm to the total pore volume of 0.2 or more.162. The adsorbent of claim , wherein the porous carbonaceous material comprises mesopores having a pore diameter in a range of about 2 nm to about 50 nm and macropores having a pore diameter greater than about 50 nm.173. The adsorbent of claim , wherein the porous carbonaceous material further comprises micropores having a pore diameter less than about 2 nm.181. The adsorbent of claim , wherein the porous carbonaceous material has a pore volume of 0.5 cm/g or more as measured by a BJH method.191. The adsorbent of claim , wherein the porous carbonaceous material has a pore volume of 4.12 cm/g or more as measured by a mercury intrusion method.201. The adsorbent of claim , wherein the porous carbonaceous material has a pore volume of 0.515 cm/g or more as measured by an MP method.211. The adsorbent of claim , wherein the porous carbonaceous material is made from a plant-based material; and the plant-based material comprises at least one material selected from ...

Adsorptive Filtereinheit mit verlängerter Einsatz- und/oder Standzeit

Die Erfindung betrifft ein Verfahren zur Bereitstellung einer adsorptiven Filtereinheit mit verlängerter Einsatz- und/oder Standzeit, insbesondere mit verbesserter und/oder erhöhter Beständigkeit und/oder Resistenz gegenüber biologischer Kontamination und/oder biologischem Befall, insbesondere einer adsorptiven Filtereinheit zur Behandlung und/oder Aufreinigung eines fluiden Mediums.

Cross-reference to related applications

ADSORBENT AND PROCESS FOR RECOVERING CO.

Nanoporous carbide derived carbon with tunable pore size

The present invention provides a method for producing a nanoporous carbide-derived carbon composition with a tunable pore structure and a narrow pore size. Also provided are compositions prepared by the method.

Regenerable filter unit for removing metal, regenerable filter system including the same, and method of operating regenerable filter system

A filter unit may include a water permeable first electrode, a second electrode arranged so as to be spaced apart from and opposite to the first electrode, and a non-water permeable separator that is positioned between the first electrode and the second electrode. The first electrode may include a metal adsorbent (metal-adsorbing material) and thus may adsorb a metal included in the water. At least one of the first electrode and the second electrode may induce a water hydrolysis reaction to produce H + ions to regenerate the metal adsorbent. The filter unit may further include a voltage applier to provide a filter system.

Synthesis of fibrous nano-silica spheres with controlled particle size, fibre density, and various textural properties

The present disclosure provides a method for synthesizing fibrous silica nanospheres, the method can include, in sequence, the steps of: a) providing a reaction mixture comprising a silica precursor, a hydrolyzing agent, a template molecule, a cosurfactant and one or more solvents; b) maintaining the reaction mixture under stirring for a length of time; c) heating the reaction mixture to a temperature for a length of time; d) cooling the reaction mixture to obtain a solid, and (e) calcinating the solid to pro duce fibrous silica nanospheres, wherein desirable product characteristics such as particle size, fiber density, surface area, pore volume and pore size can be obtained by controlling one or more parameters of the method. The present disclosure further provides a method for synthesizing fibrous silica nanospheres using conventional heating such as refluxing the reactants in an open reactor, thereby eliminating the need for microwave heating in a closed reactor or the need for any pressure reactors.

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

The present invention concerns the use, for gas separation, of at least one zeolite adsorbent material comprising at least one FAU zeolite, said adsorbent having an external surface area greater than 20 m·g, a non-zeolite phase (PNZ) content such that 0 Подробнее

COMPOSITION FOR PURIFICATION OF BIOFLUIDS

Disclosed is a composition for the purification of biofluids, for example, for hemodialysis and peritoneal dialysis, comprising an osmotic agent and a toxin-removal reagent, wherein the toxin-removal reagent can remove a toxin from a biofluid under a condition for osmosis. Provided are a dialysis solution and a kit comprising the aforementioned composition, a method for removing a toxin from a biofluid using the aforementioned composition, and a method for treating a toxin-related disease. 1. A composition comprising an osmotic agent and a toxin-removal reagent , wherein the osmotic agent provides an osmotic pressure substantially equal to or higher than that of a biofluid , and the toxin-removal reagent reduces a toxin in the biofluid under a condition for osmosis.2. The composition according to claim 1 , wherein the toxin-removal reagent reduces free amount claim 1 , non-free amount claim 1 , and/or total amount of the toxin in the biofluid.3. (canceled)4. (canceled)5. The composition according to claim 1 , wherein the toxin-removal reagent has one or more characteristics selected from the group consisting of: 1) having a porous structure; 2) capable of forming a charged structure; 3) capable of binding to the toxin through a non-covalent bond or a covalent bond or an ionic bond; and 4) capable of degrading the toxin.6. The composition according to claim 5 , wherein the toxin-removal reagent has a porous structure claim 5 , and the porous structure has one or more of the following characteristics:{'sup': 2', '2, '1) having a specific surface area of 70 cm/g−1000 m/g;'}2) having a pore size in a range of 0.1 nm-10 μm;3) having a pore size distribution of 0.1 nm-100 μm;4) having a porosity of about 5-95%; and5) capable of adsorbing the toxin at an adsorption rate of at least 0.2 mg/g.7. The composition according to claim 6 , wherein the toxin-removal reagent having a porous structure is selected from the group consisting of a silicon-based porous material claim 6 , ...

POROUS ZIRCONIA PARTICLES, AND AGGREGATE FOR IMMOBILIZING PROTEIN

Porous zirconia particles exhibit high specificity to a protein to be immobilized thereto and are used in immobilization of the protein. The porous zirconia particles have a pore diameter D50, at which a ratio of a cumulative pore volume to a total pore volume is 50%, the pore diameter D50 being in a range of 3.20 nm or more and 6.50 nm or less; and a pore diameter D90, at which a ratio of a cumulative pore volume to a total pore volume is 90%, the pore diameter D90 being in a range of 10.50 nm or more and 100.00 nm or less. The total pore volume of the particles is greater than 0.10 cm/g. D50, D90, and the total pore volume are determined based on a pore diameter distribution measured through a BET method. 1. Porous zirconia particles used for immobilization of a protein , characterized in that the particles have:a pore diameter D50, at which a ratio of a cumulative pore volume to a total pore volume is 50%, the pore diameter D50 being in a range of 3.20 nm or more and 6.50 nm or less; anda pore diameter D90, at which a ratio of a cumulative pore volume to the total pore volume is 90%, the pore diameter D90 being in a range of 10.50 nm or more and 100.00 nm or less, wherein{'sup': '3', 'the total pore volume is greater than 0.10 cm/g, and'}D50, D90, and the total pore volume are determined based on a pore diameter distribution measured through a BET method.2. The porous zirconia particles according to claim 1 , wherein the protein is immunoglobulin.3. The porous zirconia particles according to claim 2 , wherein the immunoglobulin is at least one species selected from the group consisting of IgG claim 2 , IgE claim 2 , and IgD.4. The porous zirconia particles according to claim 1 , wherein the porous zirconia particles have surfaces onto which a chelating agent is bound.5. An aggregate for immobilizing a protein claim 1 , wherein the porous zirconia particles according to are aggregated. This application is a U.S. National Phase Application under 35 U.S.C. § 371 of ...

MESOPOROUS CARBON MATERIAL AND RELATED METHODS

Mesoporous carbon material and methods of forming and using the same are provided. 1. A mesoporous carbon material having:an average pore size of between 0.3 nm and 50 nm;a pore size distribution of less than 5 nm; and{'sup': 2', '2, 'a surface area of between 50 m/g and 1000 m/g.'}2. The mesoporous carbon material of claim 1 , wherein the surface area is between 400 m/g and 1000 m/g.3. The mesoporous carbon material of claim 1 , wherein the pore size distribution is less than 3 nm.4. The mesoporous carbon material of claim 1 , wherein the pore size distribution is between 1 nm and 2 nm.5. The mesoporous carbon material of claim 1 , wherein the average pore size is between 0.3 nm and 12 nm.6. The mesoporous carbon material of claim 1 , wherein the material includes crystalline walls.7. A method of adsorping gas;{'sup': 2', '2, 'adsorbing gas with a mesoporous carbon material, wherein the mesoporous carbon material has an average pore size of between 0.3 nm and 50 nm, a pore size distribution of less than 5 nm and a surface area of between 50 m/g and 1000 m/g.'}8. The method of claim 6 , wherein the gas is a biogas.9. The method of claim 6 , wherein the gas is a siloxane.10. The method of claim 6 , wherein the gas is hydrogen sulfide or carbonyl sulfide.11. The method of claim 7 , wherein the mesoporous carbon material is confined in a column into which the gas introduced.12. A method of forming a mesoporous carbon material comprising:forming a mesoporous silica template;forming a carbon precursor on surfaces of the silica template;removing the silica template to yield mesoporous carbon material.13. The method of claim 12 , wherein the silica template is formed using a sol-gel method.14. The method of claim 13 , wherein the sol-gel method comprises formation of micelles.15. The method of claim 14 , wherein the micelles are . . . .16. The method of claim 12 , wherein the carbon precursor is carbonized.17. The method of claim 16 , wherein the carbon precursor is ...

POROUS MATERIAL AND DEVICES FOR PERFORMING SEPARATIONS, FILTRATIONS, AND CATALYSIS AND EK PUMPS, AND METHODS OF MAKING AND USING THE SAME

Embodiments of the present invention are directed to a porous monolith polymeric composition having utility in catalysis, chromatography, filtration, and electro-kinetic pumps, devices incorporating such composition and methods or making and using such monoliths. The monoliths are characterized by a substantially homogeneous skeletal core with little shrinkage, few voids and few channels. 154.-. (canceled)56. The composition of matter of wherein said aliphatic groups are lower alkyl groups.57. The composition of matter of wherein said aliphatic groups are methyl claim 55 , ethyl claim 55 , propyl claim 55 , butyl claim 55 , pentyl claim 55 , hexyl claim 55 , heptyl and octyl.58. The composition of matter of wherein said first monomer is methyltrimethoxysilane.59. The composition of matter of wherein said second monomer is dimethyldimethoxysilane.60. The composition of matter of wherein said third monomer is tetramethoxysilane.61. The composition of matter of wherein said third monomer is bis(trimethoxysilyl)ethane.62. The composition of matter of wherein said first monomer claim 55 , second monomer and third monomer define proportions of the skeletal core of 10-15 parts first monomer claim 55 , 1-10 parts second monomer and 0.5 to 5 parts third monomer.63. The composition of matter of wherein said monolith has a skeletal volume and a pore volume claim 55 , said pore volume and skeletal volume forming a monolith volume which monolith volume exhibits less than 1% shrinkage as said monolith is formed in a polymerization reaction.64. The composition of matter of wherein said skeletal core has a core mass and a skeletal volume and said pores have a pore volume which core mass claim 55 , skeletal volume and pore volume define a density claim 55 , and such density varies by less than 5% throughout said monolith.65. The composition of matter of wherein said skeletal core has polymers which deviate from the substantially homogeneous polymeric composition to form nodules ...

PROCESS FOR MANUFACTURING A COMPOSITE SORBENT MATERIAL FOR CHROMATOGRAPHICAL SEPARATION OF BIOPOLYMERS

The present invention relates to a sorbent material for separation and purification of biopolymers, particularly nucleic acids, having a solid support substantially modified with a copolymer coating comprising aromatic monomers and crosslinking compounds and unsaturated esters or ethers preferably attached to the support via a vinylchlorsilane. The use of these materials for separation of nucleic acids, particularly a one-step isolation of DNA from lysates of different biological sources, is an object of the invention as well as a chromatographic column or cartridge at least partially filled with the sorbent material of the invention, a membrane-like device comprising the sorbent material of the invention, and a kit comprising the sorbent material of the invention in bulk or packed in chromatographic devices as well as other devices necessary for performing sample preparations. 122-. (canceled)24. The process of wherein the support is a porous inorganic material comprising inorganic metal oxide.25. The process of wherein the porous inorganic metal oxides show a bidisperse distribution of pore sizes.26. The process of wherein the support has an average pore size of 2-200 nm.27. The process of wherein the polymer coating has a thickness of about 10 to 250 Angström.28. The process of wherein the inorganic metal oxide is selected from the group consisting of oxides of aluminum claim 24 , titanium claim 24 , zirconium claim 24 , silicon oxides claim 24 , iron oxides claim 24 , controlled pore glass (CPG) claim 24 , diatomaceous earth and combinations thereof.29. The process of wherein the porous inorganic metal oxide shows a bidisperse distribution with mean pore diameters in the range of 20-100 nm for the larger pore size.30. The process of wherein the porous inorganic metal oxide has a mean pore diameter in the range of 2-15 nm for the smaller pore size.31. The process of wherein the ratio of the mean diameter of the large pore size distribution and the lower pore size ...

Adsorbent Biprocessing Clarification Agents and Methods of Making and Using The Same

Adsorbent clarification agents suitable for use in bioprocessing procedures are disclosed. Methods of making and using the adsorbent clarification agents are also disclosed. 1118-. (canceled)119. Adosrbents comprising:metal oxide particles having a wide pore size distribution as measured by a pore size distribution span 90 value of at least about 1.0; andpolymeric material covalently bonded to surfaces of said metal oxide particles.120. The adsorbents of claim 119 , wherein said metal oxide particles have a median particle size of less than about 150 μm.121. The adsorbents of any one of or claim 119 , wherein said metal oxide particles have a median pore size of less than about 2000 Å.122. The adsorbents of claim 121 , wherein said metal oxide particles have a pore size distribution of from about 30 to about 5000 Å.123. The adsorbents of claim 119 , wherein said metal oxide particles have a BET particle surface area of at least about 100 m/g.124. The adsorbents of claim 119 , wherein said metal oxide particles have a pore volume claim 119 , as measured by mercury intrusion claim 119 , of at least about 0.25 ml/g.125. The adsorbents of claim 124 , wherein said metal oxide particles have a pore size distribution span 90 value of at least about 2.0.126. The adsorbents of claim 119 , further comprising at least one bifunctional moiety extending from said surfaces of said metal oxide particles claim 119 , each of said at least one bifunctional moiety comprising (i) one or more functional groups capable of bonding to said surfaces claim 119 , and either (iia) said polymeric material claim 119 , or (iib) one or more reactive groups capable of bonding to said polymeric material.127. The adsorbents of claim 126 , wherein said at least one bifunctional moiety comprises an epoxy silane.128. The adsorbents of claim 127 , wherein said at least one bifunctional moiety comprises (3-glycidoxypropyl)-trimethoxysilane.129. The adsorbents of any one of claim 127 , claim 127 , or claim ...

Separation material, column provided with said separation material, and method for producing separation material

Disclosed is a separation material comprising: a porous polymer particle containing a crosslinked polymer containing a structural unit derived from a crosslinkable monomer having an aromatic group and two or more vinyl groups bonded to the aromatic group; and a coating layer coating at least part of the surface of the porous polymer. The coating layer contains a first graft chain that is a polymer having a hydroxyl group bonded to the crosslinked polymer, and a second graft chain that is a polymer having a hydroxyl group, bonded to the first graft chain, and being different from the first graft chain.

Biochar

The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.

Monolithic Natural Gas Storage Delivery System Based on Sorbents

The invention provides methods for producing a strong, light, sorbent-based storage/dispenser system for gases and fuels. The system comprises a porous monolithic material with an adherent strong impervious skin that is capable of storing a gas under pressure in a safe and usable manner.

Loudspeaker System with Improved Sound

A loudspeaker device is presented which includes a zeolite material comprising zeolite particles having a silicon to aluminum mass ratio of at least 200. For an increased pore fraction of pores with a diameter in a range between 0.7 micrometer and 30 micrometer shows an increased shift of the resonance frequency down to lower frequencies has been observed. 1. A zeolite granule for a back volume of an acoustic device , the zeolite granule comprising:a plurality of zeolite particles, each comprising silicon dioxide and aluminum constituents, and wherein the silicon to aluminum mass ratio is at least 200; anda binder agent that adheres the plurality of zeolite particles together into the zeolite granule;wherein the zeolite granule has a diameter that is less than 0.9 millimeters and is greater than 0.1 millimeters; andwherein the zeolite granule is adapted to shift a resonant frequency of the back volume of the acoustic device and to reduce the electrical impedance of the acoustic device.2. The zeolite granule according to claim 1 , wherein the zeolite granule comprises zeolite particles having a mean diameter less than or equal to 10 micrometers.3. The zeolite granule according to claim 1 , wherein the zeolite granule comprises zeolite particles having a mean diameter greater than or equal to 0.1 micrometers.4. The zeolite granule according to claim 1 , wherein the zeolite granule comprises zeolite particles having a plurality of micropores claim 1 , and the micropores have pore diameters between 0.4 nanometers and 0.7 nanometers.5. The zeolite granule according to claim 1 , wherein the zeolite granule comprises zeolite particles having the structure FER.6. The zeolite granule according to claim 1 , wherein the zeolite granule comprises zeolite particles having the structure MFI.7. The acoustic element according to claim 1 , wherein the zeolite granule comprises zeolite particles having the structure MFI and the structure FER.8. The zeolite granule according to claim ...

THE USE OF A POLYMERIC MESH FOR THE PURIFICATION OF MACROMOLECULES

Method for recovering a target protein from a feedstock comprising said target protein and at least one impurity compound selected from host cell proteins (HCP), DNA, RNA or other nucleic acid, the target protein being characterized by a hydrodynamic radius Rand the impurity compound being characterized by a hydrodynamic radius R, wherein R>R, comprising the following steps (i) to (iv) and optionally step (v): (i) providing a polymeric mesh comprising at least one crosslinked polymer containing positively charged amino groups, wherein the polymer has a pore size exclusion limit Rhi which can be set variably; (ii) adapting the variable pore size exclusion limit Rhi of the polymeric mesh such that RR; (iii) contacting the polymeric mesh with the feedstock; (iv) separating the polymeric mesh containing the retained impurity compound from the feedstock containing the excluded target protein. 1. A method for recovering a target protein from a feedstock , said feedstock comprising said target protein and at least one impurity compound selected from host cell proteins (HCP) , DNA , RNA or other nucleic acid , or a combination of two or more thereof , and optionally further comprising albumins , endotoxins , detergents and microorganisms , or fragments thereof , or a combination of two or more thereof , the feedstock being in the form of a solution or suspension , and the target protein being characterized by a hydrodynamic radius Rand the impurity compound being characterized by a hydrodynamic radius R , wherein R>R , the method comprising the following steps (I) to (iv) and optionally step (v):{'sub': 'hi', '(i) providing a polymeric mesh comprising at least one crosslinked polymer containing positively charged amino groups, the polymer being characterized by a pore size exclusion limit Rwhich can be set variably;'}{'sub': hi', 'h1', 'h2', 'h2', 'hi', 'h1', 'hi, '(ii) adapting the variable pore size exclusion limit Rof the polymeric mesh to the hydrodynamic radii ...

ACTIVATED CARBON FOR ADSORBING GAS-PHASE

Activated carbon for adsorbing a gas phase is provided, wherein the activated carbon has a maximal peak value of 11 Å or larger in a pore size distribution measured using a water vapor adsorption method. 1. Activated carbon for adsorbing a gas phase , having a maximal peak value of 11 Å or larger in a pore size distribution measured using a water vapor adsorption method.2. The activated carbon for adsorbing a gas phase according to claim 1 , wherein the activated carbon has carbon tetrachloride adsorption performance of 70% or higher.3. The activated carbon for adsorbing a gas phase according to claim 1 , wherein the activated carbon has a particle size in a range from 4 mesh to 150 mesh.4. The activated carbon for adsorbing a gas phase according to claim 1 , wherein a raw material of the activated carbon is a coconut shell.5. A gas mask comprising the activated carbon for adsorbing a gas phase according to .6. The activated carbon for adsorbing a gas phase according to claim 2 , wherein the activated carbon has a particle size in a range from 4 mesh to 150 mesh.7. The activated carbon for adsorbing a gas phase according to claim 2 , wherein a raw material of the activated carbon is a coconut shell.8. The activated carbon for adsorbing a gas phase according to claim 3 , wherein a raw material of the activated carbon is a coconut shell.9. The activated carbon for adsorbing a gas phase according to claim 6 , wherein a raw material of the activated carbon is a coconut shell.10. The gas mask according to claim 5 , wherein the activated carbon has carbon tetrachloride adsorption performance of 70% or higher.11. The gas mask according to claim 5 , wherein the activated carbon has a particle size in a range from 4 mesh to 150 mesh.12. The gas mask according to claim 5 , wherein a raw material of the activated carbon is a coconut shell.13. The gas mask according to claim 10 , wherein the activated carbon has a particle size in a range from 4 mesh to 150 mesh.14. The gas ...

Superficially Porous Hybrid Monoliths with Ordered Pores and Methods of Making and using same

The invention provides superficially porous metal oxide or hybrid metal oxide monoliths with ordered pore structures. The superficially porous hybrid silica monoliths of the invention provide several major advantages over existing silica monoliths. When used in chromatography, the superficially porous hybrid silica monoliths of the invention deliver fast separation at very low back pressure and possess superb pH stability and much improved mechanical strength. 1. A porous monolith , comprising:an organically modified solid skeleton comprising continuous macropores; anda substantially porous outer shell comprising substantially ordered mesopores, wherein both the skeleton and the outer shell are independently metal oxide or hybrid metal oxide; and wherein the metal oxide is selected from silica, alumina, titania and zirconia.2. The porous monolith of claim 1 , wherein the metal oxide is silica.3. The porous monolith of claim 2 , wherein the continuous macropores have a median pore size ranges from about 0.2 μm to about 10 μm.4. The porous monolith of claim 2 , wherein the substantially ordered mesopores have a median pore size ranges from about 1 nm to about 100 nm with a pore size distribution (one standard deviation) of no more than 50% of the median pore size.5. The porous monolith of claim 4 , wherein the substantially ordered mesopores have a median pore size ranges from about 2 nm to about 50 nm with a pore size distribution (one standard deviation) of no more than 50% of the median pore size.6. The porous monolith of claim 2 , wherein the hybrid silica skeletons are modified by silsesquioxane.7. The porous monolith of claim 6 , wherein silsesquioxane comprises bridged polysilsesquioxane.8. The porous monolith of claim 2 , wherein the silica monoliths have a median surface area in the range from about 5 m/g to about 1 claim 2 ,000 m/g.9. The porous monolith of claim 8 , wherein the silica monoliths have a median surface area in the range from about 100 m/g to ...

ZEOLITE-BASED ADSORBENTS BASED ON ZEOLITE X WITH A LOW BINDER CONTENT AND A LOW OUTER SURFACE AREA, PROCESS FOR PREPARING THEM AND USES THEREOF

The invention relates to an adsorbent comprising a zeolite-based phase and a non-zeolite-based phase, said adsorbent having: 1. An adsorbent comprising a zeolite-based phase and a non-zeolite-based phase , wherein said adsorbent:{'sup': 2', '−1, 'has an outer surface area of less than or equal to 30 m·g,'}{'sub': Hg', 'Hg, 'a pore diameter distribution, determined by mercury intrusion according to standard ASTM D 4284-83 and expressed by the volume distribution dV/d log D, wherein Dis the apparent pore diameter and V is the pore volume, the mode of which is between 100 nm and 250 nm, limits inclusive,'}and the zeolite-based phase comprises at least one zeolite of FAU structure of X type.2. The adsorbent according to claim 1 , wherein the pore diameter distribution corresponds to a unimodal distribution.3. The adsorbent according to claim 1 , having a micropore volume claim 1 , evaluated via the t-plot method from the nitrogen adsorption isotherm at a temperature of 77 K claim 1 , which is greater than 0.200 cm·g.4. The adsorbent according to claim 1 , wherein the adsorbent has a content of non-zeolite-based phase between 2% and 8% by weight relative to the total weight of the adsorbent.5. The adsorbent according to any one of the preceding claim 1 , further comprising barium or barium and potassium.6. The adsorbent according to claim 1 , having macropores and the mesopores claim 1 , wherein a total volume contained in the macropores and the mesopores as measured by mercury intrusion according to standard ASTM D4284 83 is between 0.15 cm·gand 0.5 cm·g claim 1 , limits inclusive.7. The adsorbent according to having a ratio defined as (macropore volume)/(macropore volume+mesopore volume) of between 0.2 and 1 claim 6 , limits inclusive.8. The adsorbent according to claim 1 , further having an Si/Al atomic ratio of between 1.00 and 1.50 claim 1 , limits inclusive.9. A process for preparing the adsorbent according to claim 1 , comprising the steps of:{'sup': 2', '−1, 'a) ...

Sampling for monitoring Per- and Polyfluoroalkyl Substances (PFAS) in surface water, groundwater and pore water

Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

Affinity Chromatography Media and Chromatography Devices

Chromatography media and devices containing chromatography media are disclosed. Methods of making chromatography devices and methods of using chromatography devices containing the chromatography media are also disclosed.

BIOCHAR

The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. (canceled)12. (canceled)13. (canceled)14. (canceled)15. (canceled)16. (canceled)17. (canceled)18. (canceled)19. (canceled)20. (canceled)21. (canceled)22. (canceled)23. A article of manufacture comprising:a. a biochar core that is stable and has a degradation rate of less than 2.5% a year;b. wherein said biochar core is produced from a biomass that is pyrolized at:(i) a heating rate between about 0.1. degree. C./second and 50. degree. C./second,(ii) a temperature greater than 250. degree. C., and(iii) a heating time greater than about 0.01 days.24. The article of manufacture of claim 23 , wherein the rate of degradation of said biochar core is less than 0.5% per year.25. The article of manufacture of claim 23 , wherein the rate of degradation of said biochar core is determined by measuring the loss of carbon.26. The article of manufacture of claim 25 , wherein the carbon of said biochar core is organic carbon.27. The article of manufacture of claim 1 , wherein the degradation of said biochar core is oxidative claim 1 , chemical claim 1 , biotic claim 1 , or abiotic degradation.28. The article of ...

MULTIFUNCTIONAL POROUS MATERIALS FOR WATER PURIFICATION AND REMEDIATION

A variety of compositions and materials are provided for water purification and remediation. The compositions including multiple functionalities for treating a variety of pollutants or contaminants. The compositions can include a porous organic polymer with one or more of a variety of functional groups for binding the contaminants and with a hierarchical pore size distribution over a range of pore sizes to facilitate enhanced removal of the contaminants. Functional groups can include one, two, or more different functional groups such as amines, halides, ammoniums, pyridiuiums, thiols, imidazoliums, salts thereof, or others. The range of pore sizes can be about 1 nm to 10 nm or more. Contaminants can include antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, technetium, thallium, uranium, radium, urea, and phosphate. Methods of removing the contaminants from water using the compositions are also provided. 2. The composition according to claim 1 , wherein each occurrence of Ris —NH claim 1 , —NHR claim 1 , or —NRR.3. The composition according to claim 1 , wherein each occurrence of Ais none.5. The composition according to claim 4 , wherein each occurrence of Ris —NH claim 4 , —NHR claim 4 , or —NRR.6. The composition according to claim 4 , wherein at least one occurrence of Ris —NH claim 4 , —NHR claim 4 , or —NRR.7. The composition according to claim 4 , wherein each occurrence of Ais none.9. The composition according to claim 8 , wherein the binding moiety comprises a halide selected from the group consisting of a chloride claim 8 , a bromide claim 8 , and an iodide.10. The composition according to claim 8 , wherein the binding moiety comprises a conjugate base substituent or a salt thereof claim 8 , wherein the conjugate base is selected from the group consisting of sulfate and nitrate.12. The composition according to claim 8 , wherein the binding moiety comprises a thiol substituent having a structure according to the ...

複合吸収体及び高分子吸収剤

【課題】細孔容積に比して吸液量が低下することを抑制することができ、吸収性能に優れた衛生用品用の複合吸収体を提供する。【解決手段】液体を吸収するための衛生用品用の複合吸収体（４）は、親水性の連続骨格及び連続空孔を備えた高分子吸収剤を含んでいる。その高分子吸収剤において、細孔半径が１μｍ以上の細孔による細孔容積の割合は、全細孔の細孔容積の９０％以上である。【選択図】図１

Process For Manufacturing a Composite Sorbent Material For Chromatographical Separation of Biopolymers

The present invention relates to a sorbent material for separation and purification of biopolymers, particularly nucleic acids, having a solid support substantially modified with a copolymer coating comprising aromatic monomers and crosslinking compounds and unsaturated esters or ethers preferably attached to the support via a vinylchlorsilane. The use of these materials for separation of nucleic acids, particularly a one-step isolation of DNA from lysates of different biological sources, is an object of the invention as well as a chromatographic column or cartridge at least partially filled with the sorbent material of the invention, a membrane-like device comprising the sorbent material of the invention, and a kit comprising the sorbent material of the invention in bulk or packed in chromatographic devices as well as other devices necessary for performing sample preparations.

Process for manufacturing a composite sorbent material for chromatographical separation of biopolymers

The present invention relates to a sorbent material for separation and purification of biopolymers, particularly nucleic acids, having a solid support substantially modified with a copolymer coating comprising aromatic monomers and crosslinking compounds and unsaturated esters or ethers preferably attached to the support via a vinylchlorsilane. The use of these materials for separation of nucleic acids, particularly a one-step isolation of DNA from lysates of different biological sources, is an object of the invention as well as a chromatographic column or cartridge at least partially filled with the sorbent material of the invention, a membrane-like device comprising the sorbent material of the invention, and a kit comprising the sorbent material of the invention in bulk or packed in chromatographic devices as well as other devices necessary for performing sample preparations.

効率的なウラン抽出のためのウランナノトラップとしての官能化多孔質有機ポリマー

廃水、海水、または他の水源等から効率的にウランを抽出するための組成物が提供される。この組成物は、１つ以上のウラン結合部分で官能化された、例えば、それに共有結合した複数のアミドキシムまたはアミドラゾン基を有する、官能化多孔質有機ポリマーを含むことができる。組成物は、共有結合性有機骨格、多孔質芳香族骨格、および種々の多孔質有機ポリマー、特に、一定の孔径の範囲にわたって階層的な孔径分布を有するものを含むことができる。この組成物は、アミドキシムまたはアミドラゾンのような官能基が共有結合していてもよい。階層的細孔径分布は、７７Ｋにおける孔径分布において少なくとも０．０１ｃｍ３ｇ−１の孔容積を有する孔径の範囲における孔径の少なくとも６０％に基づいて決定することができる。組成物の製造方法および組成物の使用方法も提供される。

Absorbent for Separating Nitrogen from Mixed Gas of Oxygen And Nitrogen

산소ㆍ질소 혼합 가스로부터 질소를 분리하기 위한 흡착제는, 산소와 질소의 분리비α와 산소 평형 흡착량의 50%를 흡착하는 시간 t 50 과 산소 평형 흡착량의 95%를 흡착하는 시간 t 95 의 비(t 95 /t 50 )의 관계에서, The adsorbent for separating nitrogen from the oxygen-nitrogen mixed gas has a time t 50 for adsorbing the separation ratio α and 50% of the oxygen balance adsorption amount of oxygen and nitrogen and a time t 95 for adsorbing 95% of the oxygen balance adsorption amount. in relation to (t 95 / t 50 ), (t 95 /t 50 ) < 0.4(α-24) 단, α≥35 (t 95 / t 50 ) <0.4 (α-24) provided α≥35 인 식을 만족하는 조건을 가지는 MSC이며, 그리고, 이것을 사용하여, 산소ㆍ질소 혼합 가스로부터 PSA 식으로 질소를 분리하여 제조하는 방법이기 때문에, 소정의 질소 발생량에 대하여 사용하는 흡착제의 양을 감소시키는 것이 가능하고, 이것에 의해 장치의 코스트의 절감 및 장치 규모의 축감 소형화를 가능하게 함과 동시에, 동력 소비량을 저감시킬 수 있다. It is an MSC having a condition that satisfies the expression, and it is a method of producing nitrogen by separating PSA from an oxygen-nitrogen mixed gas using the same, so that the amount of adsorbent used for a predetermined amount of nitrogen is reduced. This makes it possible to reduce the cost of the device, reduce the size of the device, and reduce the power consumption. 산소, 질소 분리 Oxygen, nitrogen separation

用于从氧气·氮气混合气体中分离氮气的吸附剂以及使用它的氮气制造方法

一种用于从氧气·氮气混合气体分离氮气的吸附剂，是氧气和氮气的分离比α、与吸附氧气平衡吸附量的50%所需时间t 50 和吸附氧气平衡吸附量的95%所需时间t 95 的比(t 95 /t 50 )之间的关系满足下式条件的MSC，(t 95 /t 50 )＜0.4×(α-24)其中，α≥35并由此构成使用该MSC从氧气和氮气的混合气体通过PSA式而分离氮气的制造方法。根据本发明，相对于一定的氮气发生量，可以减少所使用的吸附剂的量，由此，可以减少装置成本并使装置规模的缩减小型化，同时还能有效降低动力消费量。

Verfahren zum abbau zumindest eines kohlenstoffhaltigen schadstoffes, abbaumittel und reinigungsvorrichtung

Verfahren zum Abbau zumindest eines organischen kohlenstoffhaltigen Schadstoffes, wobei der Schadstoff an zumindest einem Adsorptionsmittel adsorbiert wird. Das Adsorptionsmittel weist zumindest einen Kautschuk und zumindest einen damit gemischten feinteiligen bzw. pulverförmigen Füllstoff auf. In bzw. an dem Adsorptionsmittel werden Mikroorganismen aufgenommen, mit denen die Schadstoffe abgebaut werden.

Affinity chromatography media and chromatography devices

Chromatography media and devices containing chromatography media are disclosed. Methods of making chromatography devices and methods of using chromatography devices containing the chromatography media are also disclosed.

Porous polymeric material with gradients

Porous polymeric matrix materials in the form of an integral body having a property gradient selected from any of pore size distribution, chemical composition or a combination thereof are disclosed along with a process for making the same.

Zeolite adsorbents with high external surface area and application thereof

本发明涉及包含至少一种A类沸石的至少一种沸石吸附剂材料用于气体分离和/或气体干燥的用途，所述吸附剂具有大于20 m 2 .g ‑1 的外表面积，非沸石相（PNZ）含量使得0<PNZ≤30%，以及1.0至2.0的吸附剂的Si/Al原子比。本发明还涉及沸石吸附剂材料，其具有1.0至2.0的吸附剂的Si/Al比，0.07 cm 3 .g ‑1 至0.18 cm 3 .g ‑1 的介孔体积，‑0.3至1.0（不含边界）的(V micro ‑V meso )/V micro 比，非沸石相（PNZ）含量使得0<PNZ≤30%。

Co-agglomerated composite materials and methods for making co-agglomerated composite materials

Co-agglomerated composite materials, methods for making co-agglomerated composite materials, and methods for using co-agglomerated composite materials

A composite filter aid may include a first mineral selected from diatomaceous earth and natural glass. The filter aid may also include a second mineral having and aspect ratio greater than about 2:1, and a binder. The filter aid may have a permeability ranging from 0.2 to 20 darcys. A method for making a composite filter aid may include blending a first mineral, a second mineral, and a binder, wherein the first mineral comprises at least one of diatomaceous earth and natural glass, and the second mineral has an aspect ratio greater than about 2:1. The method may further include agglomerating the first mineral and second mineral in the presence of the binder to form the composite filter aid. A method for filtering a beverage may include using the composite filter aid.

Spherical high-performance adsorbents with microstructure

Spherical high-performance adsorbents, which are manufactured from polymer resin by water vapor activation with an activation time of at least 6 hours. The adsorbents have a pronounced microstructure in the range of 0 to 40 Å pore diameter and an overall micropore volume of at least 0.6 cm 3 /g. A substantial increase in the adsorption capacity for gases and vapors is achieved which is also represented by the very favorable ratio of weight capacity to volume capacity of upto 2 to 1. The spherical high-performance adsorbents with microstructure can be used for many purposes, in particular, textile fabrics for the adsorption of chemical warfare agents and toxic gases and vapors, in adsorption refrigerating plants in combination with the refrigerating agent methanol, in motor vehicle filters and biofilters.

Sorbent for separation of carbon dioxide (CO2) from gas mixtures

A reaction-based process has been developed for the selective removal of carbon dioxide (CO 2 ) from a multicomponent gas mixture to provide a gaseous stream depleted in CO 2 compared to the inlet CO 2 concentration in the stream. The proposed process effects the separation of CO 2 from a mixture of gases (such as flue gas/fuel gas) by its reaction with metal oxides (such as calcium oxide). The Calcium based Reaction Separation for CO 2 (CaRS-CO 2 ) process consists of contacting a CO 2 laden gas with calcium oxide (CaO) in a reactor such that CaO captures the CO 2 by the formation of calcium carbonate (CaCO 3 ). Once “spent”, CaCO 3 is regenerated by its calcination leading to the formation of fresh CaO sorbent and the evolution of a concentrated stream of CO 2 . The “regenerated” CaO is then recycled for the further capture of more CO 2 . This carbonation-calcination cycle forms the basis of the CaRS-CO 2 process. This process also identifies the application of a mesoporous CaCO 3 structure, developed by a process detailed elsewhere, that attains >90% conversion over multiple carbonation and calcination cycles. Lastly, thermal regeneration (calcination) under vacuum provided a better sorbent structure that maintained reproducible reactivity levels over multiple cycles.

ZEOLITHIC ADSORBENTS COMPRISING A ZEOLITH WITH HIERARCHIZED POROSITY

La présente invention concerne des adsorbants zéolithiques à base de zéolithe(s) à porosité hiérarchisée contenant du baryum ou du baryum et du potassium, leurs utilisations pour la séparation de para-xylène à partir de coupes aromatiques contenant 8 atomes de carbone, ainsi que le procédé de séparation de para-xylène à partir de coupes aromatiques contenant 8 atomes de carbone. The present invention relates to zeolite adsorbents based on zeolite(s) with hierarchical porosity containing barium or barium and potassium, their uses for the separation of para-xylene from aromatic cuts containing 8 carbon atoms, as well as the process for the separation of para-xylene from aromatic cuts containing 8 carbon atoms.

ACTIVATED CARBON REGENERATION PROCESS BY ELECTRO-FENTON PROCESS

L'invention concerne un dispositif de régénération du charbon actif sous la forme de fibres poreuses de par réaction électro-Fenton, un procédé de régénération de charbon actif chargé en polluants organiques utilisant le dispositif de l'invention et l'utilisation d'un filtre composé de fibres poreuses de charbon actif, ledit filtre ayant été préalablement chargé en polluants organiques par filtration d'eau polluée ou d'air pollué, en tant que cathode d'une réaction électro-Fenton pour régénérer les fibres poreuses de charbon actif chargées en polluants organiques. The invention relates to a device for regenerating activated carbon in the form of porous fibers by electro-Fenton reaction, a process for regenerating activated carbon loaded with organic pollutants using the device of the invention and the use of a filter. composed of porous activated carbon fibers, said filter having been previously loaded with organic pollutants by filtration of polluted water or polluted air, as the cathode of an electro-Fenton reaction to regenerate the porous activated carbon fibers loaded with organic pollutants.

Polymeric sorbents for aldehydes and methods of making

Polymeric sorbents for aldehydes including formaldehyde and acetaldehyde are provided. More particularly, the polymeric sorbents are sulfonic acid-containing polymeric materials with impregnated urea-based compounds. Additionally, methods of making the polymeric sorbent, methods of sorbing aldehydes (i.e., aldehydes that are volatile under use conditions) on the polymeric sorbents, compositions resulting from the sorption of aldehydes on the polymeric sorbents, and filters containing the polymeric sorbents are provided.

Biochar

The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.

Zeolite adsorbents made from x zeolite with low binder content and low external surface area, method for preparation of same and uses thereof

The invention relates to an absorbent comprising a zeolite phase and a non-zeolite phase, said absorbent having: an external surface area less than or equal to 30 m 2 .g -1 , preferably less than or equal to 20 m 2 .g -1 , a zeolite phase comprising at least one X zeolite with FAU structure, and a pore diameter distribution, as determined by mercury intrusion according to the standard ASTM D4284-83 and expressed by the volume distribution dV/dlogDHg, where DHg is the apparent diameter of the pores, and V, the porous volume, the mode of which lies between 100 nm and 250 nm, terminals included. The invention also relates to a method for preparation of said absorbent and uses thereof, in particular for the separation of xylene isomers.

Loudspeaker system with improved sound

Porous body and method for producing the same

Absorbents having the capability of decomposing organic halogen compounds and a process for producing the same

A method for producing an adsorbent having the capability of decomposing an organic halogen compound, characterized in that it comprises reacting a salt of Pt and/or Pd, an organic titanium compound and an organic binder in a solvent, to thereby synthesize a dispersion of an organic metal compound precursor containing Pt and/or Pd and Ti in a molecule thereof, adding a TiO2 sol to the dispersion to prepare a catalyst coating solution, impregnating an active carbon with the catalyst coating solution and heating the resultant mixture, thereby allowing the active carbon to carry thereon an organic halogen compound decomposition catalyst comprising TiO2 and, dispersed therein, fine particles of Pt and/or Pd. An adsorbent produced by the method can be used for adsorbing an organic halogen compound contained in an exhaust gas and also decomposing it with reliability without re-synthesis of the compound and further for adsorbing and removing Sox, Nox, HCl, a heavy metal and the like, in a low temperature range of 130 to 150 ~ allowing the use of an active carbon.

Porous materials to remove impurities from feedstock

본 발명은 알루미나를 포함하는 다공성 물질에 관한 것이며, 상기 알루미나는 알파-알루미나를 포함하고, 상기 다공성 물질은 Co, Mo, Ni, W 및 이들의 조합으로부터 선택된 하나 이상의 금속을 포함하며, 상기 다공성 물질은 1-110 m 2 /g의 BET 표면적, 수은 침입 기공측정법에 의해 측정된 바 0.50-0.80 ml/g의 전체 공극 부피, 및 전체 공극 부피의 적어도 30 vol%가 ≥400Å의 반경을 가진 공극, 적합하게 ≥500Å의 반경을 가진 공극, 예컨대 최대 5000Å의 반경을 가진 공극에 있는 공극 크기 분포(PSD)를 가진다. 본 발명은 또한 재생가능 원료와 같은 공급원료로부터 인(P)과 같은 불순물을 제거하는 방법에 관한 것이며, 이것은 상기 공급원료를 상기 다공성 물질을 포함하는 가드층과 접촉시키는 것에 의해 달성된다. 본 발명은 또한 다공성 물질을 포함하는 수소처리 시스템을 위한 가드층, 및 수소처리 과정에서 인 가드로서 다공성 물질의 사용에 관한 것이며, 수소처리 시스템은 다공성 물질을 포함하는 가드층 및 적어도 하나의 수소처리 촉매를 포함하는 하류 수소처리 섹션를 포함한다.

Multi-functional protective materials and methods for use

A reactive-adsorptive protective material having an activated carbon adsorbent for adsorbing chemical impurities, wherein nanoparticular entities are loaded into and onto a surface of said activated carbon adsorbent to further impart chemically reactive and biocidal properties onto the activated carbon for providing protection against chemical and biological agents in the atmosphere. Advantageously, a superior reactive-adsorptive material is provided having the ability to kill microorganisms in addition to the ability to neutralize and decompose chemical substances, while at the same time not diminishing the adsorptive/reactive capabilities and effectiveness of either the substrate carbon or the loaded nanoparticular entities used.

A separating material, a column provided with the separating material, and a method for manufacturing the separating material.

Porous bodies and methods

Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Zeolitic adsorbents comprising a zeolite with hierarchical porosity

Plate-shaped structure with adsorptive properties

Plattenförmiger Aufbau (1) mit einem insbesondere gitter- oder plattenförmigen Träger (2), wobei der Träger (2) eine Vielzahl von Durchbrechungen (3) aufweist, dadurch gekennzeichnet, daß in den Durchbrechungen (3) ein geruchs- und/oder schadstoffadsorbierendes Material (4) aufgenommen oder vorgesehen ist. panel-form Structure (1) with a particular grid or plate-shaped Carrier (2), wherein the carrier (2) a plurality of openings (3), characterized in that in the openings (3) an odor and / or Schadadsadsorbierendes material (4) is included or intended.

A method of making the porous carbon material and porous carbon materials produced by the method

A method for making the microporous carbon with modified pore size distribution and advanced sorption behaviour. The carbon is derived from metal or metalloid carbides. The method uses of oxidant in reaction medium that during the carbide conversion into carbon expands small micropores, or the temperature T1 in the beginning of the reaction is higher than the temperature T2 in following reaction. Both approaches improve the penetrability in outer layers of the microporous carbon particle and can be used separately of each other or combined. The microporous carbon obtained is free of impurities and possesses extremely narrow pore size distribution.

Composition for biological fluid purification

本申请公开了一种可用于生物流体净化(例如血液透析、腹膜透析)的组合物，其包括渗透剂和毒素去除试剂，其中所述毒素去除试剂能够在渗透交换的条件下去除生物流体中的毒素。本申请还提供了含有本申请组合物的透析溶液、试剂盒等，以及使用本申请组合物去除生物流体中的毒素的方法、以及治疗与毒素相关的疾病的方法。

Adsorbent having capability of decomposing organic halogen compound and method for producing the same

制造具有分解有机卤化物功能的吸附剂方法,其特征在于,包括使Pt和/或Pd的盐、有机钛化合物和有机结合体在溶剂中反应,由此合成在分子中含有Pt和/或Pd和Ti的有机金属化合物前体的分散液,向该分散液中加入TiO 2 溶胶,制造催化剂涂布溶液,用该催化剂涂布溶液浸渍活性炭并加热所得的该混合物,由此使活性炭上负载含TiO 2 的有机卤化物分解催化剂,并且其中分散有Pt和/或Pd的微细粒子。由该方法制得的吸附剂,可用于吸收含在排放废气中的有机卤化物,并且也可以在不再合成这些化合物的情况下将它们分解,而且还能用于吸收和除去SO x 、NO x 、HCl和重金属类等。

Zeolite adsorbents having a high external surface area and uses thereof

The present invention concerns the use, for gas separation and/or gas drying, of at least one zeolite adsorbent material comprising at least one type A zeolite, said adsorbent having an external surface area greater than 20 m

Multi-functional protective textiles and methods for decontamination

A reactive and adsorptive (i.e., multi-functional protective) textile and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. In one aspect, a protective spatially-distributed biocidal interface is provided comprising a textile having interior structures, wherein protective nanoparticles bonded to said interior structures such that an article or portions of an article which are maintained in proximity to the textile are permitted to safely pass through a contaminated environment without dispersing the nanoparticles from protective proximity to the article.

Absorbents having the capability of decomposing organic halogen compounds and a process for producing the same

An adsorbent having the capability of decomposing an organic halogen compound, which adsorbent cannot only adsorb organic halogen compounds contained in waste gases but also can assuredly decompose them without synthesizing them as well as a process for producing the same are provided A salt of Pt and/or Pd, an organic titanium compound and an organic binder are reacted in a solvent, to thereby synthesize a dispersion of an organic metal compound precursor containing Pt and/or Pd and Ti in molecules thereof, a sol of TiO2 is added to the dispersion to prepare a catalyst-coating solution, an activated carbon is impregnated with the catalyst-coating solution, and the resulting mixture is heated, thereby allowing the activated carbon to carry thereon an organic halogen compound-decomposing catalyst comprising TiO2 and, dispersed therein, fine particles of Pt and/or Pd. In a low temperature range of 130 to 150°C in which the activated carbon is usable, the organic halogen compounds in the exhaust gases can be decomposed, and SOx, NOx, HCl and heavy metals can be removed through adsorption.

Precipitated silica sorbents

The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.

Porous biochar and preparation method and application thereof

本发明公开了一种多孔生物炭的制备方法，包括如下步骤：S1：氮气气氛下低温炭化得到初级生物炭；S2：将初级生物炭碱液浸渍，水分蒸干后得到碱改性生物炭；S3：在氮气气氛下将碱改性生物炭进行高温热解炭化，得到高比表面积初级多孔生物炭；S4：将S3步骤所得的样品用去离子水冲洗，直到滤液的pH值为中性，干燥，得到多孔生物炭材料。本发明方法制备的高比表面积多孔生物炭材料的比表面积达到1900‑2050m 2 /g，总孔体积为1.165‑1.190cm 3 /g，具有多级孔结构。所制备的多孔生物炭可用于吸附水体中有机污染物。

Cross-reference to related applications

A reactive and adsorptive (i.e., protective) fiber, a mufti-element protective filter and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. When arranged upstream of an activated carbon filter, the nanoparticles provide enhanced adsorption or additional reactive properties to the protective filter. When used with carbon specially treated with metal ions, the protective filter retains the ability to adsorb blood agents as well. Significant advances in nanoparticle technology are described wherein clusters made from about 1nm to about 200nm sized nanoparticles are reduced to tangible filter element precursors.

EXTERNAL HIGH SURFACE ZEOLITHIC ADSORBENTS, PROCESS FOR THEIR PREPARATION AND USES THEREOF

La présente invention concerne l'utilisation, pour la séparation et/ou le séchage de gaz, d'au moins un matériau adsorbant zéolithique comprenant au moins une zéolithe de type A, ledit adsorbant présentant une surface externe supérieure à 20 m2.g-1, une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ ≤ 30%, et de ratio atomique Si/Al compris entre 1,0 et 2,0. L'invention concerne également un matériau adsorbant zéolithique présentant un rapport Si/Al compris entre 1,0 et 2,0, un volume mésoporeux compris entre 0,07 cm3.g-1à 0,18 cm3.g-1, un rapport (Vmicro - Vméso)/Vmicro compris entre -0,3 et 1,0, bornes non incluses, et une teneur en phase non zéolithique (PNZ) telle que 0 < PNZ ≤ 30%. The present invention relates to the use, for the separation and / or drying of gases, of at least one zeolite adsorbent material comprising at least one type A zeolite, said adsorbent having an external surface greater than 20 m 2 g -1 , a non-zeolitic phase (PNZ) content such that 0 <PNZ ≤ 30%, and an Si / Al atomic ratio of between 1.0 and 2.0. The invention also relates to a zeolitic adsorbent material having an Si / Al ratio of between 1.0 and 2.0, a mesoporous volume of between 0.07 cm3g-1 to 0.18 cm3g-1, a ratio of Vmicro - Vmeso) / Vmicro between -0.3 and 1.0, terminals not included, and a non - zeolitic phase (PNZ) content such that 0 <PNZ ≤ 30%.

Adsorbent for separating nitrogen from mixed gas of oxygen and nitrogen

An adsorbent for separating nitrogen from a mixed gas of oxygen and nitrogen is MSC wherein an oxygen and nitrogen separation ratio α and a ratio (t 95 /t 50 ) of a time t 50 required for adsorbing 50% of the oxygen equilibrium adsorption amount and a time t 95 required for adsorbing 95% of the oxygen equilibrium adsorption amount satisfy the inequality ( t 95 /t 50 )<0.4×(α−24)α≧ 35. The amount of adsorbent used with respect to a predetermined amount of nitrogen generated can be reduced since a method is carried out which uses this adsorbent to produce nitrogen by separating nitrogen from the mixed gas of oxygen and nitrogen by means of a PSA method. By this means, it is possible to reduce the cost of the apparatus and reduce and miniaturize the scale of the apparatus, and the power consumption amount can be reduced.

Chromatography media and devices

Chromatography devices contain chromatography media and methods of making and methods of using chromatography devices. Chromatography devices enable a more efficient, productive and/or environmentally friendly chromatographic operation due to one or more of the following advantages over conventional chromatographic operations: elimination of a device packing step by the user; elimination of clean-in-place (CIP) steps; elimination of clean-in-place (CIP) steps utilizing sodium hydroxide solution; elimination of any validation steps by the user; and use of a chromatography device comprising biodegradable material. The chromatography media includes porous inorganic particles having a functionalized surface and having a median pore size of at least about 300 Angstroms (A), or at least about 300 A up to about 3000 A. The inorganic particles may have a BET surface area of at least about 20 m2/g, or at least about 25 m2/g, or about 30 m2/g, up to about 2000 m2/g.

Guard layers for rapid cycle pressure swing adsorption devices

Gas absorption granular material

The invention relates to a granular material composed of a build-up agglomeration of porous granules for absorbing harmful gases, such as SOx, from exhaust gases of thermal processes, the granules of said granular material being designed for use in a solid matter - exhaust gas reactor in terms of their strength properties and their granular grain size distribution, and containing at least one calcium compound in the form of calcium hydroxide and/or limestone powder as an active substance.

Separation material

本発明は、モノマ単位としてスチレン系モノマを含む多孔質ポリマ粒子と、該多孔質ポリマ粒子の表面の少なくとも一部を被覆する、水酸基を有する高分子を含む被覆層と、を備える分離材であって、上記分離材は、５％圧縮変形弾性率が１００〜１０００ＭＰａであり、かつ細孔径分布におけるモード径が０．１〜０．５μｍである分離材を提供する。

Carbon nanotube-containing structures, methods of making, and processes using same

Carbon nanotube structures are disclosed in which nanotubes are disposed over a porous support such as a foam, felt, mesh, or membrane. Techniques of making these structures are also disclosed. In some of these techniques, a support is pretreated with a templated surfactant composition to assist with the formation of a nanotube layer.

Polymeric sorbents for aldehydes and methods of making

Polymeric sorbents for aldehydes including formaldehyde and acetaldehyde are provided. More particularly, the polymeric sorbents are sulfonic acid-containing polymeric materials with impregnated urea-based compounds. Additionally, methods of making the polymeric sorbent, methods of sorbing aldehydes (i.e., aldehydes that are volatile under use conditions) on the polymeric sorbents, compositions resulting from the sorption of aldehydes on the polymeric sorbents, and filters containing the polymeric sorbents are provided.

Multi-functional protective materials and methods for use

A reactive-adsorptive protective material having an activated carbon adsorbent for adsorbing chemical impurities, wherein nanoparticular entities are loaded into and onto a surface of said activated carbon adsorbent to further impart chemically reactive and biocidal properties onto the activated carbon for providing protection against chemical and biological agents in the atmosphere. Advantageously, a superior reactive-adsorptive material is provided having the ability to kill microorganisms in addition to the ability to neutralize and decompose chemical substances, while at the same time not diminishing the adsorptive/reactive capabilities and effectiveness of either the substrate carbon or the loaded nanoparticular entities used.

Activated charcoal

Adsorbent, method for removing carbon dioxide, carbon dioxide remover, and air conditioner

This adsorbent, which is used in order to remove carbon dioxide from a gas to be processed including carbon dioxide, includes a cerium oxide. The pore size of the adsorbent is such that, in the pore distribution measured using the Horvath-Kawazoe method, the differential pore volume in an area in which the pore size is equal to or less than 7Å is at least 0.0085 cm3/g-Å.

Adsorbent for adsorbing virus and/or bacterium, carbon/polymer complex, and adsorption sheet

[目的]提供用于吸附病毒的吸附剂、吸附板和碳/聚合物复合物，其中，可进一步改善病毒吸附能力。[技术手段]本发明的用于吸附病毒的吸附剂基于氮BET法的比表面积值为10m 2 /g以上；以及基于BJH法的孔容积为0.1cm 3 /g以上。本发明的用于吸附病毒的吸附板提供了包含多孔碳材料的板状部件，所述多孔碳材料基于氮BET法的比表面积值为10m 2 /g以上；以及基于BJH法的孔容积为0.1cm 3 /g以上。本发明的用于吸附病毒的碳/聚合物复合物包含多孔碳材料和粘合剂，所述多孔碳材料基于氮BET法的比表面积值为10m 2 /g以上；以及基于BJH法的孔容积为0.1cm 3 /g以上。

Special adsorbent for carbon dioxide acquisition on mars

A carbon dioxide adsorbent comprises a carbonized, shaped precursor material, with such material being characterized by a total micropore volume of at least about 0.525 cm 3 /g and a median pore diameter of at least about 0.439 nm, whereby the material has a carbon dioxide capacity of at least about 28.6% g/g at a carbon dioxide partial pressure of about 6 mm Hg and a temperature of about 196° K. Also provided is a method of making a carbon dioxide adsorbent, which includes the steps of polymerizing a monomer to produce a precursor material; shaping the precursor material to produce a shaped precursor material; and carbonizing the shaped precursor material to produce the adsorbent, whereby the adsorbent is characterized by a carbon dioxide capacity of at least about 28.6% g/g at a carbon dioxide partial pressure of about 6 mm Hg and a temperature of about 196° K.

Adsorbent, the removing method of carbon dioxide, carbon dioxide remover and air-conditioning device

本发明提供一种吸附剂，其为用于从含有二氧化碳的处理对象气体中除去二氧化碳的吸附剂，所述吸附剂含有铈氧化物，在通过Horvath‑Kawazoe法测定的细孔分布中，在细孔径小于或等于 的区域具有微分细孔容积大于或等于 的细孔径。

Porous material and devices for performing separations, filtrations, and catalysis and EK pumps, and methods of making and using the same

Embodiments of the present invention are directed to a porous monolith polymeric composition having utility in catalysis, chromatography, filtration, and electro-kinetic pumps, devices incorporating such composition and methods or making and using such monoliths. The monoliths are characterized by a substantially homogeneous skeletal core with little shrinkage, few voids and few channels.

Nitrogen dioxide adsorbent, nitrogen dioxide absorbing device and manufacturing method of nitrogen dioxide absorbing device

本发明公开了一种二氧化氮吸附剂、二氧化氮吸附装置及其制造方法，所述二氧化氮吸附剂，按重量份计包括：氧化钙15～60份；氧化铝10～50份；氢氧化钾20～70份；该吸附剂对笑气中的二氧化氮进行高效吸附，纯化笑气；二氧化氮吸附装置的制造方法，包括1)在水热釜中放入去离子水；2)钙盐、铝盐和钾盐加入水热釜中；3)将改性剂配制为盐溶液，然后加入水热釜中；4)将空白的填充层放入水热釜中，进行水热处理；5)将填充层取出，得到吸附剂填充层；6)将吸附剂填充层安装在二氧化氮吸附装置的过滤通道上；该制造方法在填充层上均匀附着纳米级的二氧化氮吸附剂，使吸附剂填充层具有高效的二氧化氮吸附性能。

Composite material and process for extracting lithium using the same

The invention relates to composite material comprising polymer microfibers and lithium- adsorbent particles characterized in that said polymer microfibers have a diameter comprised between 10 µm and 500 µm, and said composite material has an open porosity comprised between 70% and 99% and a density comprised between 0.05 g/cm3 and 0.5 g/cm3. It also relates to a cartridge comprising such a material and to a process for extracting lithium from a brine using such a material.

Multu-functional protective textiles and methods for decontamination

A reactive and adsorptive (i.e., multi -functional protective) textile and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. In one aspect, a protective spatially-distributed biocidal interface is provided comprising a textile having interior structures, wherein protective nanoparticles bonded to said interior structures such that an article or portions of an article which are maintained in proximity to the textile are permitted to safely pass through a contaminated environment without dispersing the nanoparticles from protective proximity to the article.

Zeolite adsorbents comprising a zeolite with hierarchical porosity and process for separating para-xylene

本發明係關於含有鋇或鋇及鉀之基於具階層式孔隙度沸石之沸石吸附劑，其用於自含有8個碳原子之芳族溶離份分離對二甲苯之用途，以及自含有8個碳原子之芳族溶離份分離對二甲苯之方法。

Porous carbon adsorbent and preparation method and application thereof

本发明涉及一种多孔碳吸附剂及其制备方法和应用，所述多孔碳吸附剂由蚕茧作为碳源直接制备得到。本发明所提供的方法可控性强，重复性好，所制备的多孔碳为分级多孔碳，含有大量的微孔和介孔，具有吸附位点多，吸附剂扩散快的优点，适用于作为快速吸附水中六价铬和/或重金属离子的吸附剂。

Porous body and production method therefor

Adsorbent for purifying VOCs waste gas and preparation method and application thereof

本发明公开了一种用于净化VOCs废气的吸附剂的制备方法，包括如下步骤：S1、将原料煤进行烘干、粉碎，得到煤粉；S2、然后将有机溶剂、有机助剂、无机助剂、有机粘合剂混入煤粉中，混合时还加入聚合物树脂；混捏搅拌后，进行挤条，得到湿润的成型吸附剂；S3、最后对成型吸附剂进行干燥、炭化、活化，得到用于净化VOCs废气的吸附剂。本发明吸附剂制备简单，具有丰富的中孔及良好的疏水性，且强度优异，吸附、再生性能优良，更加节能，从而在该吸附剂的基础上能够实现提供一种成本降低，工艺流程简单、操作简便、净化效果优异且安全的基于吸附的VOCs废气深度净化方法。