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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 287. Отображено 180.
24-01-2008 дата публикации

AGGLOMERATED ZEOLITIC ADSORBENTS, THEIR METHOD OF PREAPRATION AND THEIR USES

Номер: CA0002657750A1
Принадлежит: ROBIC

La pr‚sente invention concerne des adsorbants z‚olitiques agglom‚r‚s … ba se de z‚olite X de rapport Si/Al tel que 1,15 Подробнее

21-03-2003 дата публикации

Co-production of para-, meta- and/or orthoxylene, e.g. to obtain pure paraxylene, from a charge containing xylenes, ethylbenzene and 9- 10C hydrocarbons,

Номер: FR0002829758A1
Принадлежит: IFP Energies Nouvelles IFPEN

Co-production of para-xylene, meta-xylene and/or orthoxylene uses a chromatographic column initially to separate off and extract para-xylene and a raffinate containing a mixture of meta- and orthoxylenes which may be separated by crystallisation. Co-production of para-xylene, meta-xylene and/or ortho-xylene comprises an initial passage of the charge to a distillation column from which a mixture comprising most of the meta- and para-xylene, ethylbenzene and part of the ortho-xylene is withdrawn at the head, and from the base, a mixture of 9- 10C hydrocarbons and remaining orthoxylene, followed by a separation of the mixture from the head in a simulated mobile bed in a chromatographic column containing several interconnected adsorbent beds in a closed loop with differing selectivities for the xylene and ethylbenzene. The column comprises at least 5 zones defined by injection of the distilled mixture and a desorbent and withdrawals of an extract, containing para-xylene, and intermediate fraction containing ethylbenzene and a raffinate containing ortho and meta-xylenes. A zone 1 comprises the desorption of para-xylene, a zone 2 defining the desorption of ethylbenzene, ortho and meta-xylenes, a zone 3A of adsorption of paraxylene and a zone 3B of adsorption of ethylbenezene. Zone 4 comprises the withdrawal of the raffinate. The raffinate is distilled to eliminate the desorbent and withdraw a distilled raffinate and the extract is distilled to recover a fraction enriched in para-xylene. The process is characterized in that the distilled raffinate is conveyed to a crystallisation zone where meta-xylene is recovered with a purity of at least 99 % or the distilled raffinate is conveyed to a second distillation zone to recover a head flow containing meta-xylene which may be crystallized to 99 % and a base fraction from which orthoxylene can be crystallized to 98.5 %

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26-02-2010 дата публикации

PROCESS AND DISPOSTIF OF SEPARATION IN MOBILE BED SIMULATE HAS FLOW OF FLUID OF DERIVATION AUTOMATICALLY NOT BABBIT METAL

Номер: FR0002935101A1

Procédé de séparation d'une charge F par adsorption en lit mobile simulé dans un dispositif LMS comprenant une zone 1 de désorption des composés produits à l'extrait, une zone 2 de désorption des composés produits au raffinat, une zone 3 pour l'adsorption des composés produits à l'extrait, une zone 4 située entre le soutirage du raffinat et l'alimentation du désorbant, le dispositif comprenant des lignes de dérivation externes Li/i+1 joignant directement deux plateaux successifs Pi, Pi+1 équipées de moyens non automatisés de réglage du débit et de moyens de fermeture, dans lequel on règle le degré d'ouverture de moyens de restriction du débit de balayage des lignes de dérivation Li/i+1' de manière à obtenir la meilleure performance du LMS.

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26-06-2009 дата публикации

AGGLOMERATED ADSORBENTS ZEOLITIQUES, THEIR METHOD OF PREPARATION AND THEIR USES

Номер: FR0002925366A1

L'invention concerne des adsorbants zéolitiques agglomérés à base de poudre de zéolite de type faujasite X à faible teneur en silice et à petits cristaux, échangée au baryum ou à base de zéolite de type faujasite X à faible teneur en silice et à petits cristaux, échangée au baryum et au potassium.L'invention concerne également le procédé de préparation desdits adsorbants zéolitiques agglomérés, ainsi que leurs utilisations dans la séparation de sucres, d'alcools polyhydriques, d'isomères de toluène substitué, des crésols ou de récupération de paraxylène de très haute pureté. The invention relates to agglomerated zeolite adsorbents of zeolite powder type faujasite X low silica and small crystals, barium exchange or low silica and small crystal faujasite X type zeolite, The invention also relates to the process for the preparation of said agglomerated zeolite adsorbents, as well as their uses in the separation of sugars, polyhydric alcohols, isomers of substituted toluene, cresols or paraxylene recovery. of very high purity.

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16-02-2007 дата публикации

PROCESS OF SEPARATION OF the METAXYLENE Of an AROMATIC HYDROCARBON LOAD BY ADSORPTION IN LIQUID PHASE USING TETRALIN LIKE DESORBING

Номер: FR0002889698A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention a trait à un procédé de séparation du métaxylène d'une charge d'hydrocarbures comprenant des isomères à 8 atomes de carbone comprenant :- une étape de mise en contact de ladite charge avec un adsorbant comprenant une zéolithe du type faujasite, le pourcentage en eau de la zéolithe étant compris entre 0 et 8% en poids et la température d'adsorption allant de 25 degree C à 250 degree C;- une étape de désorption mettant en oeuvre un désorbant choisi parmi la tétraline, ses dérivés alkylés ;- une étape de séparation du métaxylène du désorbant. The invention relates to a method for separating metaxylene from a hydrocarbon feedstock comprising isomers containing 8 carbon atoms, comprising: a step of bringing said feedstock into contact with an adsorbent comprising a zeolite of the faujasite type, the water percentage of the zeolite being between 0 and 8% by weight and the adsorption temperature ranging from 25 degree C to 250 degree C; a desorption step using a desorbent chosen from tetralin, its alkylated derivatives; a step of separating the metaxylene from the desorbent.

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16-09-2009 дата публикации

Aggregate zeolitic adsorbents, their method of preparation and their uses

Номер: TW0200938297A
Принадлежит:

The invention relates to aggregate zeolitic adsorbents based on faujasite X type zeolite powder having a low silica content and small crystals, exchanged with barium or based on faujasite X type zeolite having a low silica content and small crystals, exchanged with barium and potassium. The invention also relates to the method for preparing said aggregate zeolitic adsorbents, and also their uses for separating sugars, polyhydric alcohols, isomers of substituted toluene, cresols, or for recovering very high purity paraxylene.

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01-05-2014 дата публикации

PROCESS AND APPARATUS FOR THE SIMULATED COUNTER-CURRENT PRODUCTION OF PARA-XYLENE, CONSTITUTED BY TWO ADSORBERS IN SERIES WITH A TOTAL NUMBER OF 22 OR FEWER BEDS

Номер: US20140121436A1
Принадлежит: IFP Energies nouvelles

The present invention describes a novel configuration for simulated counter-current para-xylene production units, constituted by two adsorbers, characterized in that the volume occupied by the solid adsorbent is reduced by at least 8% compared with the volume of solid adsorbent contained in the adsorbers of a prior art unit. This novel configuration can be used to minimize the quantity of solid adsorbent necessary to produce a given quantity of para-xylene. 1. A process for separating xylenes by simulated counter-current (SCC) using two adsorbers , the process containing a total number of beds Nt of 22 or fewer , and having a line for introducing feed (F) , a line for introducing eluent (D) , a line for withdrawing extract (E) and a line for withdrawing raffinate (R) and being divided into 4 chromatographic zones defined as follows:zone 1: para-xylene desorption zone, included between the injection of desorbant D and the removal of extract E;zone 2: isomers of para-xylene desorption zone, included between the removal of the extract E and the injection of the feed to be fractionated F;zone 3: para-xylene adsorption zone, included between the injection of the feed and the withdrawal of the raffinate R;zone 4: zone located between the withdrawal of the raffinate and the injection of the desorbant;the two adsorbers functioning in series, i.e. the last bed of the first adsorber is connected to the first bed of the second adsorber via a line containing a recirculation pump, and the last bed of the second adsorber is connected to the first bed of the first adsorber via a line containing a recirculation pump which is distinct from the preceding pump, and said process operating under the following operating conditions:a temperature of 100° C. to 250° C., preferably 120° C. to 180° C.;{'sup': 5', '5, 'a pressure in the range between the bubble pressure of the xylenes at the process temperature and 30×10Pa (1 bar=10Pa);'}a ratio of desorbent to feed flow rates of 0.7 to 2.5;a ...

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02-02-2021 дата публикации

ZEOLITIC ADSORBENTS, PROCESS FOR PREPARING SAME AND USES THEREOF

Номер: CA2894606C

La présente invention concerne des adsorbants zéolithiques à base de petits cristaux agglomérés de zéolithe X comprenant du baryum, combinant des propriétés optimales en termes de sélectivité et de résistance mécanique. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes, dans la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, dans la séparation des crésols, et dans la séparation des alcools polyhydriques, tels que les sucres.

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12-09-2008 дата публикации

PROCESS AND SEPARATION DEVICE IN MOBILE BED SIMULATE HAS MANY VALVES OF LARGE DIAMETER AND VOLUME OF LINES REDUCED

Номер: FR0002913346A1
Принадлежит:

L'invention concerne un dispositif de séparation par adsorbtion en lit mobile simulé comprenant des vannes de grande dimension en nombre limité. Selon l'invention, le dispositif comprend une colonne avec une pluralité de tronçons Sk à 2 plateaux superposés Pi à réseau unique de distribution, chaque tronçon Sk comprenant une ligne de dérivation externe principale Lk connectée à chaque plateau Pi de Sk par une vanne de plateau Vi de grand diamètre, et une ligne de dérivation externe secondaire Mk comprenant une vanne VMk de petit diamètre connectée au tronçon adjacent Sk-1. Chaque ligne Lk comprend un moyen de limitation de débit, et est reliée à chacun des réseaux de fluides via une une vanne unique de grand diamètre. De plus, les piquages des lignes Lk sur la colonne sont décalés d'au plus 20° à l'intérieur de Sk, pour limiter le volume des lignes Lk ,et décalés d'un angle moyen compris entre 70° et 110° entre 2 tronçons voisins Sk et Sk+1 pour ne pas fragiliser mécaniquement la colonne ...

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19-06-2014 дата публикации

ZEOLITIC ADSORBENTS, PROCESS FOR PREPARING SAME AND USES THEREOF

Номер: CA0002894606A1
Принадлежит:

La présente invention concerne des adsorbants zéolithiques à base de petits cristaux agglomérés de zéolithe X comprenant du baryum, combinant des propriétés optimales en termes de sélectivité et de résistance mécanique. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes, dans la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, dans la séparation des crésols, et dans la séparation des alcools polyhydriques, tels que les sucres.

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06-02-2009 дата публикации

PROCESS AND SEPARATION DEVICE IMPROVE OF METAXYLENE IN MOBILE BED SIMULATES

Номер: FR0002919604A1
Принадлежит:

Procédé de séparation de métaxylène à au moins 99 % poids de pureté d'une charge aromatique F, en une seule étape d'adsorption en lit mobile simulé dans un dispositif SMB comprenant: - une zone 1 entre l'alirrientation du désorbant D et le soutirage de l'extrait E; - une zone 2 entre le soutirage de l'extrait E et l'alimentation de la charge F; - une zone 3 entre l'alirnentation de la charge et le soutirage du raffinat R; - une zone 4 entre le soutirage du raffinat R et l'alimentation du désorbant D, le procédé étant opéré selon une configuration de zones (a, b, c, d), a, b, c, d représentant le nombre de lits d'adsorbant opérant respectivement en zone 1, 2, 3, 4 dans lequel on utilise: - soit un SMB de 12 lits d'adsorbant opérant selon la configuration (2, 5, 3, 2), - soit un SMB de 13 lits ci'adsorbant opérant selon la configuration (2 ,5 ,4, 2), - soit un SMB de 15 lits d'adsorbant opérant selon la configuration (2 ,6, 4, 3).

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26-02-2010 дата публикации

PROCESS AND SEPARATION DEVICE IN MOBILE BED SIMULATE HAS FLOW OF FLUID OF DERIVATION MODULATES

Номер: FR0002935100A1

Procédé de séparation d'une charge F par adsorption en lit mobile simulé dans un dispositif LMS comprenant au moins une zone 1 de désorption des composés produits à l'extrait, une zone 2 de désorption des composés produits au raffinat, une zone 3 pour l'adsorption des composés produits à l'extrait, une zone 4 située entre le soutirage du raffinat et l'alimentation du désorbant, le dispositif comprenant des lignes de dérivation externes Li/i+1 joignant directement deux plateaux successifs Pi, Pi+1, dans lequel on modifie séquentiellement le degré d'ouverture de moyens de restriction du débit de balayage des lignes de dérivation Li/i+1, de façon que : 1) dans une zone de fonctionnement où existe au moins une ligne de dérivation fermée, on établit une sur-synchronicité du débit de balayage sur toutes les lignes de dérivation non fermées appartenant à la zone considérée, la dite sur-synchronicité étant définie par la formule suivante: S =a +b (nf/nt) dans laquelle la constante a est une constante ...

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26-06-2015 дата публикации

PROCESS FOR HYDRODESULFURIZATION OF HYDROCARBON CUTS

Номер: KR1020150071665A
Принадлежит:

The present invention relates to a method of manufacturing at least two kinds of hydrocarbon cuts which have low sulfuric contents from hydrocarbon mixtures which have an initial boiling point of 35-100 deg. C and a final boiling point of 260-340 deg. C and a sulfuric content of 30-10,000 weight ppm. According to the present invention, a method comprises: a) a first hydrodesulfurization step under the presence of hydrogen and hydrodesulfurization catalysts; b) an extraction step of extracting hydrogen sulfide from an extract which is partially desulfurized as obtained in step a); c) a second hydrodesulfurization step with hydrogen and hydrodesulfurization for the mixture which is partially desulfurized as obtained in step b), under the temperature higher than that of the first hydrodesulfurization step; and d) a separation step of separating the desulfurized mixture obtained in step c) into at least two kinds, light and heavy, of hydrocarbon cuts, the light hydrocarbon cuts having a boiling ...

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16-06-2014 дата публикации

Process and apparatus for the simulated counter-current production of para-xylene, constituted by two adsorbers in series with a total number of 22 or fewer beds

Номер: TW0201422582A
Принадлежит:

The present invention describes a novel configuration for simulated counter-current para-xylene production units, constituted by two adsorbers, characterized in that the volume occupied by the solid adsorbent is reduced by at least 8% compared with the volume of solid adsorbent contained in the adsorbers of a prior art unit. This novel configuration can be used to minimize the quantity of solid adsorbent necessary to produce a given quantity of para-xylene.

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01-05-2018 дата публикации

Process for producing a gasoline with a low sulphur and mercaptans content

Номер: US0009957448B2

The present application concerns a process for the treatment of a gasoline containing sulphur-containing compounds and olefins, with the following steps: a) a step for hydrodesulphurization of said gasoline in order to produce an effluent which is depleted in sulphur by passing the gasoline mixed with hydrogen over at least one hydrodesulphurization catalyst; b) a step for separating the partially desulphurized gasoline from the hydrogen introduced in excess as well as the H2S formed during step a); c) a catalytic step for sweetening desulphurized gasoline obtained from step b), which converts residual mercaptans into thioethers via an addition reaction with the olefins.

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16-08-2012 дата публикации

PROCESS FOR SEPARATION BY SELECTIVE ADSORPTION ON SOLID CONTAINING ZEOLITE WITH IM-12 CRYSTALLINE STRUCTURE

Номер: JP2012153711A
Принадлежит:

PROBLEM TO BE SOLVED: To provide an adsorption/separation method using a solid containing zeolite having a specific structure of an IM-12 structure as an adsorbent mass. SOLUTION: The method for adsorbing/separating a certain molecular species from a mixture containing the certain molecular species and other molecular species by optional ratios includes a step of bringing the mixture into contact with a solid absorbent. The solid adsorbent contains the solid having the crystalline structure of IM-12 and the chemical composition shown by chemical formula: XO2:mYO2:pZ2O3:qR2/nO (wherein R is one or more n-valent cations; X is one or more tetravalent elements except germanium; Y is germanium; and Z is at least one trivalent element) as the anhydride base by molar ratios of oxides. COPYRIGHT: (C)2012,JPO&INPIT ...

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17-04-2003 дата публикации

Verfahren zur Koproduktion von Paraxylol, Metaxylol und/oder Orthoxylol

Номер: DE0010242880A1
Принадлежит:

Beschrieben wird ein Verfahren der Koproduktion von Paraxylol, Metaxylol und/oder Orthoxylol, ausgehend von einer Kohlenwasserstoffcharge (1), umfassend: DOLLAR A (1) eine Stufe der Trennung der Charge im simulierten beweglichen Bett in einer chromatographischen Kolonne (9), die eine Vielzahl von Betten eines Adsorbens, in der Schleife verbunden, enthält, wobei diese Kolonne eine Injektion (3) der Charge, eine Entnahme (10) eines Extrakts, bestehend aus Paraxylol und Desorbens, eine Ethylbenzol enthaltende Zwischenfraktion (11) (Extrakt oder Raffinat) und ein Raddinat (12) umfasst, das ein Gemisch aus Metaxylol und Orthoxylol enthält, welches im wesentlichen frei von Ethylbenzol und Paraxylol ist und DOLLAR A (2) eine Stufe der Kristallisation (27) der Fraktion aus Metaxylol und/oder Orthoxylol. Vor der Adsorptionszone und/oder vor der Kristallisationszone kann man das eintretende Gemisch destillieren, um am Boden eine an Orthoxylol angereicherte Fraktion und am Kopf eine an Metaxylol angereicherte ...

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25-06-2020 дата публикации

METHOD FOR REGENERATING A SPENT CATALYST NOT REGENERATED BY A PROCESS FOR THE HYDRODESULFURIZATION OF GASOLINES

Номер: CA3119861A1
Принадлежит:

L'invention concerne un procédé de réjuvénation d'un catalyseur au moins partiellement usé issu d'un procédé d'hydrotraitement, ledit catalyseur au moins partiellement usé étant issu d'un catalyseur frais comprenant un métal du groupe VIII (en particulier, Co), un métal du groupe VIB (en particulier, Mo), un support d'oxyde, et optionnellement du phosphore, ledit catalyseur au moins partiellement usé comprenant en outre du carbone dans une teneur comprise entre 2 et 20 % poids par rapport au poids total du catalyseur au moins partiellement usé et du soufre dans une teneur comprise entre 1 et 8 % poids par rapport au poids total du catalyseur au moins partiellement usé, ledit procédé comprenant les étapes suivantes : a) on met en contact ledit catalyseur usé avec une solution d'imprégnation contenant un composé comportant un métal du groupe VIB, b) on effectue une étape de séchage à une température inférieure à 200°C.

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16-02-2007 дата публикации

PROCESS OF SEPARATION OF the METAXYLENE Of an AROMATIC HYDROCARBON LOAD BY ADSORPTION IN LIQUID PHASE

Номер: FR0002889699A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention a trait à un procédé de séparation du métaxylène d'une charge d'hydrocarbures comprenant des isomères à 8 atomes de carbone comprenant :- une étape de mise en contact de ladite charge avec un adsorbant zéolithe du type faujasite, la teneur en eau de l'adsorbant étant compris entre 0 et 1% en poids et la température d'adsorption allant de 160 degree C à 180 degree C;- une étape de désorption mettant en oeuvre un solvant choisi parmi le toluène, l'indane et les mélanges de ceux-ci. The invention relates to a process for separating metaxylene from a hydrocarbon feedstock comprising isomers containing 8 carbon atoms, comprising: - a step of bringing said feedstock into contact with a zeolite adsorbent of the faujasite type, the content of water of the adsorbent being between 0 and 1% by weight and the adsorption temperature ranging from 160 degree C to 180 degree C; a desorption step using a solvent chosen from toluene, indane and mixtures thereof.

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26-06-2009 дата публикации

Device for the separation of paraxylene from the aromatic hydrocarbon cut by adsorption, comprises ordinary elementary zones in series functioning as a closed loop, and a specific elementary zone

Номер: FR0002925350A1
Принадлежит:

Dispositif (SMB) de séparation par adsorption en lit mobile simulé comprenant une pluralité de zones élémentaires Zi en série fonctionnant en boucle fermée, chacune de ces zones comprenant, entre deux points successifs d'injection ou d'extraction séquentielle de fluide, un lit unique Li de solide adsorbant de volume VAi et un volume vide non sélectif Vi, dans lequel la majorité des zones sont des zones élémentaires ordinaires ayant chacune un volume identique VA du même adsorbant S, et un volume vide non sélectif sensiblement identique égal à V, le dispositif comprenant également au moins une zone élémentaire particulière Z0, appelée zone élémentaire particulière, comprenant un volume vide non sélectif V0 supérieur à V, et un lit unique L0 d'adsorbant S0 de volume VA0 inférieur à VA, S0 ayant une capacité d'adsorption volumique C0 supérieure à celle C de S, de façon à ce que la capacité d'adsorption globale C0 x VA0 de Z0 soit plus proche de la capacité d'adsorption globale C x VA de chacune ...

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21-02-2008 дата публикации

Process and device for simulated moving bed seperation with a reduced number of valves

Номер: US2008041788A1
Принадлежит:

The invention concerns a simulated moving bed (SMB) separation device comprising a column, beds Ai of adsorbent separated by plates Pi with a single distribution and extraction network for fluids, in particular feed F, desorbant D, raffinate R and extract E, and a plurality of two-way valves for distribution of said fluids, said valves being limited in number compared with the prior art. According to the invention, the column is divided into a plurality of sectors Sk with 2 or 3 superimposed plates, each sector Sk comprising an external bypass line Lk connected to each plate Pi of Sk via a connector comprising a plate valve Vi. Each line Lk comprises a controlled means for limiting its internal flow, and is connected to each of the fluid networks F, D, R, E via a single line comprising a single controlled two-way isolation valve to supply for sequential supply or withdrawal of the corresponding fluid F, D, R or E towards or from the sector Sk under consideration. The invention also concerns ...

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15-02-2008 дата публикации

METHOD AND DEVICE FOR THE PRODUCTION OF REDUCED

Номер: FR0002904776A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention concerne un dispositif de séparation en lit mobile simulé (SMB), comprenant une colonne, des lits d'adsorbant Ai séparés par des plateaux Pi à réseau unique de distribution et d'extraction de fluides, en particulier de charge F, de désorbant D, de raffinat R, et d'extrait E, et une pluralité de vannes à 2 voies pour la distribution de ces fluides, ces vannes étant en nombre limité par rapport à l'art antérieur. Selon l'invention, la colonne est divisée en une pluralité de tronçons Sk à 2 ou 3 plateaux superposés, chaque tronçon Sk comprenant une ligne de dérivation externe Lk connectée à chaque plateau Pi de Sk par un embout comprenant une vanne de plateau Vi. Chaque ligne Lk comprend un moyen commandé de limitation de son débit interne, et est reliée à chacun des réseaux de fluides F, D, R, E via une ligne unique comprenant une vanne de sectionnement commandée unique à 2 voies pour l'alimentation ou le soutirage séquentiel du fluide correspondant F, D, R ou E vers ou à partir du tronçon Sk considéré.L'invention concerne également un procédé de séparation utilisant ce dispositif, ou l'utilisation de ce dispositif notamment pour la séparation du paraxylène ou du métaxylène à partir d'une coupe C8 aromatique. The invention relates to a simulated mobile bed separating device (SMB), comprising a column, adsorbent beds Ai separated by trays Pi with a single network for dispensing and extracting fluids, in particular F charges, desorbent D, raffinate R, and extract E, and a plurality of 2-way valves for the distribution of these fluids, these valves being limited in number compared to the prior art. According to the invention, the column is divided into a plurality of sections Sk with 2 or 3 superimposed trays, each section Sk comprising an external bypass line Lk connected to each plate Pi of Sk by a tip comprising a plate valve Vi. Each line Lk comprises a controlled means of limiting its internal flow, and is ...

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12-09-2008 дата публикации

PROCESS AND SEPARATION DEVICE IN MOBILE BED SIMULATE HAS MANY REDUCED VALVES AND VOLUME OF LINES

Номер: FR0002913345A1
Принадлежит:

L'invention concerne un dispositif de séparation par adsorbtion en lit mobile simulé comprenant des vannes en nombre limité. Selon l'invention, le dispositif comprend une colonne avec une pluralité de tronçons Sk à 2 plateaux superposés Pi à réseau unique de distribution, chaque tronçon Sk comprenant une ligne de dérivation externe principale Lk connectée à chaque plateau Pi de Sk par une vanne de plateau Vi. Chaque ligne Lk comprend un moyen de limitation de débit, et est reliée à chacun des réseaux de fluides via une une vanne unique. De plus, les piquages des lignes Lk sur la colonne sont décalés d'au plus 20° à l'intérieur de Sk, pour limiter le volume des lignes Lk, et décalés d'un angle moyen compris entre 70° et 110° entre 2 tronçons voisins Sk et Sk+1 pour ne pas fragiliser mécaniquement la colonne. Les plateaux comprennent de préférence des panneaux DMEi,j à secteurs parallèles dont la direction varie plateau par plateau ou par groupe de 2 plateaux. L'invention concerne également ...

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18-04-2008 дата публикации

Device for separating normal-paraffinic hydrocarbons/olefinic hydrocarbons from fraction comprising hydrocarbons by adsorption in simulated mobile bed, comprises column having adsorbent beds separated by distributor/extractor plates

Номер: FR0002907021A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention concerne un dispositif de séparation en lit mobile simulé (SMB), comprenant une colonne, des lits d'adsorbant Ai séparés par des plateaux Pi à réseau unique de distribution et d'extraction de fluides, en particulier de charge F, de désorbant D, de raffinat R, et d'extrait E, et une pluralité de vannes à 2 voies pour la distribution de ces fluides, ces vannes étant en nombre limité, et surtout de plus petite dimension que dans l'art antérieur. Selon l'invention, la colonne est divisée en une pluralité de tronçons Sk à 2 plateaux superposés, chaque tronçon Sk comprenant une ligne de dérivation externe principale Lk connectée à chaque plateau Pi de Sk par une vanne de plateau Vi de grand diamètre, et une ligne de dérivation externe secondaire Mk comprenant une vanne VMk de petit diamètre connectée au secteur adjacent Sk-1. Chaque ligne Lk comprend un moyen de limitation de débit , et est reliée à chacun des réseaux de fluides F, D, R, E via une une vanne unique de grand diamètre pour l'alimentation ou le soutirage séquentiel du fluide correspondant F, D, R ou E vers ou à partir du tronçon Sk.L'invention concerne également un procédé de séparation, utilisant ce dispositif.

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20-06-2003 дата публикации

Production of p-xylene and o-xylene by two-stage adsorption comprises separating o- and m-xylene in the second stage

Номер: FR0002833592A1
Принадлежит: IFP Energies Nouvelles IFPEN

Production of p-xylene, o-xylene from hydrocarbon feed by simulated moving bed adsorption in first chromatography column to produce raffinate, o-xylene and m-xylene comprises distilling raffinate to remove desorbent, separating o- and m-xylene in second chromatography column (17) and distilling extract or raffinate containing o-xylene to remove desorbent and recover o-xylene with purity above 98.5%. Production of p-xylene and o-xylene from a hydrocarbon feed (1) by simulated moving bed adsorption in a first chromatography column (6) to produce a raffinate (5) comprising desorbent, o-xylene and m-xylene comprises distilling the raffinate to remove the desorbent, separating the o- and m-xylene in a second chromatography column (17) and distilling the extract or raffinate containing o-xylene to remove desorbent and recover o-xylene with a purity above 98.5%.

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19-05-2006 дата публикации

PROCESS FOR ADSORPTION SEPARATION USING, AS AN ADSORBENT, A SOLID CONTAINING A ZEOLITE HAVING A PARTICULAR STRUCTURE SIMILAR TO THAT OF IM-12

Номер: KR1020060052294A
Принадлежит:

PURPOSE: A group of processes for adsorption separation using an adsorbent that contains a solid having a crystalline structure similar to that of solid IM-12 crystalline structure and has a chemical composition of a formula which is XO2:mYO2:pZ2O3:qR2/nO when expressed in moles of oxides as the anhydrous base is provided. CONSTITUTION: A process for adsorption separation of the one molecular species from a mixture containing one molecular species and other molecular species in an arbitrary ratio comprises the step of contacting the mixture with a solid adsorbent, wherein the adsorbent is characterized in that it contains a solid having a crystalline structure similar to a crystallite structure of IM-12 and has a chemical composition of a formula which is XO2:mYO2:pZ2O3:qR2/nO when expressed in moles of oxides as the anhydrous base, wherein R represents one or more cations having valence n, X represents one or more tetravalent elements except germanium, Y represents germanium, and Z represents ...

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22-10-2004 дата публикации

PROCESS OF STYRENE AND PARAXYLENE COPRODUCTION

Номер: FR0002844790B1
Принадлежит:

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27-05-2005 дата публикации

Producing p-xylene from a feed comprising xylenes, ethylbenzene and heavy hydrocarbons comprises a simulated moving bed adsorption step and two isomerization steps

Номер: FR0002862638A1
Принадлежит:

On décrit un procédé de production de paraxylène à partir d'une charge d'hydrocarbures, dans une colonne d'adsorption travaillant en lit mobile simulé à au moins cinq zones et délivrant un extrait, un raffinat-2 et un raffinat intermédiaire. On distille l'extrait et on recristallise éventuellement le distillat pour récupérer du paraxylène avec une pureté d'au moins 99,7 %. On distille puis on isomérise le raffinat-2 dans un réacteur fonctionnant préférentiellement en phase liquide et à basse température. Le raffinat intermédiaire à teneur enrichie en éthylbenzène est distillé puis isomérisé en phase vapeur.

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23-10-2009 дата публикации

DEVICE IMPROVES SEPARATION IN MOBILE BED SIMULATES

Номер: FR0002930174A1
Принадлежит: IFP Energies Nouvelles IFPEN

Dispositif (SMB) de séparation par adsorption en lit mobile simulé comprenant une pluralité de zones élémentaires d'adsorption Zi en série fonctionnant en boucle fermée, et au moins une zone d'adsorption singulière possédant un volume mort plus important que les zones d'adsorption Zi, le solide adsorbant de la dite zone d'adsorption singulière ayant une granulomètrie inférieure à celle du solide adsorbant des zones d'adsorption ordinaires. Simulated moving bed adsorption separation device (SMB) comprising a plurality of closed loop series Zi elementary adsorption zones, and at least one singular adsorption zone having a greater dead volume than the adsorption zones Zi, the adsorbent solid of said singular adsorption zone having a particle size smaller than that of the adsorbent solid of ordinary adsorption zones.

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24-04-2009 дата публикации

Preparing paraxylene from an aromatic hydrocarbon charge, comprises separation by adsorption in simulated moving bed producing distilled extract, and recycling a part of distilled raffinate upstream of simulated moving bed

Номер: FR0002922547A1
Принадлежит:

Procédé de production de paraxylène à partir d'une charge d'aromatiques en C8 comprenant les étapes suivantes: - une étape de séparation par adsorption en lit mobile simulé SMB produisant un extrait contenant au moins 95% de paraxylène, et au moins un raffinat R contenant de l'éthylbenzène, - un recyclage de raffinat à l'étape de séparation SMB après isomérisation, dans lequel on sépare R dans des moyens de séparation membranaire pour obtenir une première fraction F1 relativement riche en éthylbenzène, qui est purgée, et une fraction complémentaire F2 relativement pauvre en éthylbenzène, qui est recyclée au SMB après une isomérisation unique, préférentiellement en phase liquide.

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31-10-2008 дата публикации

PROCEEDED OF PRODUCTION OF METAXYLENE HIGH PURITY HAS INCLUDING/UNDERSTANDING AN ADSORPTION IN MOBILE BED SIMULATES AND A CRYSTALLIZATION

Номер: FR0002915481A1
Принадлежит:

L'invention concerne un procédé de production de métaxylène à haute pureté comprenant une étape de séparation par adsorption en lit mobile simulé à partir d'une charge en C8 aromatique délivrant une fraction riche en métaxylène et une fraction pauvre en métaxylène, et une étape de cristallisation de la fraction riche en métaxylène. Le métaxylène produit présente une pureté d'au moins 99,5%.

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25-01-2008 дата публикации

METHOD FOR SEPARATING PROPYLENE IN MIXTURE WITH PROPANE BY SIMULATED MOVING BED ADSORPTION

Номер: FR0002903981A1
Принадлежит:

On décrit un procédé de séparation du propylène en mélange avec du propane par adsorption en lit mobile simulé. Le procédé fonctionne en phase gaz ou en phase liquide, en utilisant comme solide adsorbant une zéolithe de type faujasite 13X, et comme désorbant un hydrocarbure contenant 4 ou 5 atomes de carbone.

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26-06-2009 дата публикации

ADSORBENTS ZEOLITIQUES AGLLOMERES, THEIR METHOD OF PREPARATION AND THEIR USES

Номер: FR0002925367A1
Принадлежит:

La présente invention concerne des adsorbants zéolitiques agglomérés à base de zéolite X et de zéolite LSX. Ces adsorbants sont particulièrement bien adaptés pour la séparation des isomères aromatiques en C8 et notamment des xylènes, la séparation de sucres, la séparation d'alcools polyhydriques, la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, la séparation des crésols, la séparation des dichlorobenzènes.

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05-05-2006 дата публикации

PROCESS OF SEPARATION BY SELECTIVE ADSORPTION ON A SOLID CONTAINING UNEZEOLITHE OF CRYSTALLINE STRUCTURE SIMILAR TO THE IM-12.

Номер: FR0002877237A1
Принадлежит:

Procédé de séparation par adsorption faisant appel à un solide adsorbant de type IM-12, permettant de séparer une espèce moléculaire à partir d'une charge quelconque.

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04-10-2002 дата публикации

PROCESS OF COPRODUCTION OF PARAXYLENE AND METAXYLENE INCLUDING/UNDERSTANDING TWO STAGES OF SEPARATION

Номер: FR0002822820A1
Принадлежит: IFP Energies Nouvelles IFPEN

On décrit un procédé de coproduction de métaxylène et de paraxylène à partir d'une charge d'hydrocarbures comprenant deux étapes de séparation. La première étape du procédé est un système de lit mobile simulé à contre-courant dans une colonne chromatographique contenant au moins cinq zones, comprenant une injection de la charge et une injection de désorbant et délivrant un extrait, un raffinat et un raffinat intermédiaire de manière continue ou discontinue. On distille l'extrait pour obtenir du paraxylène avec une pureté d'au moins 99, 7%. Le raffinat, plus riche en métaxylène est distillé pour extraire le désorbant et injecté dans un lit mobile simulé à contre-courant délivrant en continu un extrait et un raffinat. L'un de ces deux flux est enrichi en métaxylène. On distille le flux le plus riche en métaxylène pour obtenir du métaxylène avec une pureté supérieure à 99%.

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01-11-2011 дата публикации

Process and device for separation in a simulated moving bed with a bypass fluid flow rate that is not regulated automatically

Номер: US0008049055B2

Process for separation of a feedstock F by adsorption in a simulated moving bed in an SMB device that comprises a zone 1 for desorption of compounds produced by extraction, a zone 2 for desorption of compounds produced with a raffinate, a zone 3 for adsorption of compounds produced by extraction, and a zone 4 that is located between the draw-off of the raffinate and the supply of the desorbent, whereby the device comprises external bypass lines Li/i+1 directly joining two successive plates Pi, Pi+, that are equipped with non-automated means for adjusting flow rate and closing means, in which the degree of opening of the restriction means of the scavenging flow rate of the bypass lines Li/i+1 is adjusted so as to obtain the best performance of the SMB.

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20-05-2021 дата публикации

METHOD FOR REMOVING ARSENIC USING A REMOVAL MASS MADE OF NICKEL OXIDE PARTICLES

Номер: US20210146330A1
Принадлежит: IFP Energies nouvelles

The invention describes a process for the capture of organometallic impurities in a hydrocarbon feedstock of gasoline type containing olefins and sulfur, in which a capture body is brought into contact with the feedstock to be treated and a stream of hydrogen, said capture body comprises an active phase based on nickel oxide particles with a size of less than or equal to 15 nm, said active phase not comprising other metal elements of Group VIb or Group VIII, which are deposited on a porous support chosen from the group consisting of aluminas, silica, silicas/aluminas, or also titanium or magnesium oxides, used alone or as a mixture with alumina or silica/alumina.

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04-01-2018 дата публикации

ZEOLITE ADSORBENT IN THE FORM OF LOW-TORTUOSITY AGGLOMERATES

Номер: CA0003028868A1
Принадлежит:

L'invention concerne un adsorbant zéolithique sous forme d'agglomérés, ayant: - un facteur de tortuosité t, calculé à partir de la distribution poreuse déterminée par porosimétrie par intrusion de mercure strictement supérieur à 1 et strictement inférieur à 3, - une porosité ep, déterminée par porosimétrie mercure, comprise entre 25% et 35%, où Vma désigne le volume macroporeux, Vme le volume mésoporeux et Vg, le volume de grain de l'adsorbant, en cm3.g-1. L'invention concerne également son procédé de préparation et un procédé de séparation de para-xylène à partir de coupes d'isomères d'hydrocarbures aromatiques contenant 8 atomes de carbone par adsorption du para-xylène au moyen dudit adsorbant.

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20-03-2012 дата публикации

AGGLOMERATED ZEOLITIC ADSORBENTS, THEIR METHOD OF PREAPRATION AND THEIR USES

Номер: CA0002657750C

La présente invention concerne des adsorbants zéolitiques agglomérés à base de zéolite X de rapport Si/Al tel que 1,15 Подробнее

23-01-2009 дата публикации

PROCESS AND SEPARATION DEVICE IN MOBILE BED SIMULATE HAS REDUCED NUMBER OF VALVES

Номер: FR0002904776B1
Принадлежит:

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25-01-2008 дата публикации

Agglomerated zeolite adsorbents, especially useful for recovering p-xylene from aromatic fractions, comprise a barium X zeolite powder and an inert binder

Номер: FR0002903978A1

Agglomerated zeolite adsorbents comprising a barium X zeolite powder and an inert binder have a Dubinin volume of at least 0.245 cm 3>/g and a mechanical strength (Shell SMS1471-74) of at least 2 MPa. The zeolite powder has a crystal diameter of 1.6 mu m or less and a silicon/aluminum ratio of 1.15-1.5, where at least 90% of the cation exchange sites are occupied by barium ions or by barium and potassium ions, provided that no more than 1/3 of these sites are occupied by potassium ions. Independent claims are also included for: (1) process (P1) for producing adsorbents as above by agglomerating an X zeolite powder with a binder comprising at least 80 wt.% zeolitizable clay and a silica source, drying and calcining the agglomerates, zeolitizing the binder with an alkali solution, substituting at least 90% of the exchange sites with barium, washing and drying the product, optionally substituting up to 33% of the exchange sites with potassium, and washing, drying and activating the product, where potassium exchange can be effected before or after barium exchange; (2) process (P2) for recovering p-xylene from C 8aromatic fractions in the liquid or gas phase by adsorption on an adsorbent as above in the presence of a desorbent.

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26-03-2004 дата публикации

Co-production of paraxylene and styrene from a mixture of xylenes and ethylbenzene, useful as raw materials for the synthesis of polymers such as polyamides and polystyrene

Номер: FR0002844790A1
Принадлежит: IFP Energies Nouvelles IFPEN

Process for the co-production of paraxylene and styrene of high purity by stages of separation, dehydrogenation and isomerization. Co-production of high purity paraxylene and styrene from a charge containing xylenes, ethylbenzene and 9 - 10C hydrocarbons comprising the following stages: (1) distillation of the charge to separate xylenes, from which a head flux comprising mainly metaxylene, paraxylene , ethylbenzene and part of the orthoxylene, and at the base 9 - 10C hydrocarbons and remaining orthoxylene; (2) an adsorption stage of the head flux in a primary adsorption column containing numerous adsorbent beds, interconnected in a closed loop, with varying selectivities for paraxylene, ethylbenzene, metaxylene and orthoxylene and comprising 4 zones ; a desorption zone for paraxylene, a desorption zone for ethylbenzene, an adsorption zone for paraxylene and a zone between extraction of raffinate and injection of desorbent; (3) distillation of the extract to obtain pure(99.7%) paraxylene and desorbent which is recycled to the adsorption column; (4) distillation of the raffinate, containing metaxylene, orthoxylene and ethylbenzene; (5) dehydrogenation of the distilled raffinate , the effluent containing styrene, metaxylene, orthoxylene, unconverted ethylbenzene and by-products, at least 50% of the ethylbenzene being converted to styrene; (6) elimination of by-products to produce a mixture containing mainly styrene, ethylbenzene, metaxylene and orthoxylene; (7) separation of the mixture to produce a primary flux containing styrene (99.8%) and a secondary flux containing metaxylene and orthoxylene; (8) isomerization of the second flux and recovery of paraxylene, orthoxylene and metaxylene which are recycled to the distillation column for the charge.

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21-04-2008 дата публикации

DEVICE FOR SIMULATED MOVING BED SEPARATION WITH A REDUCED NUMBER OF LARGE DIAMETER VALVES, COMPRISING A COLUMN, BEDS Ai OF ADSORBENT SEPARATED BY PLATES Pi HAVING A SINGLE DISTRIBUTING AND EXTRACTING NETWORK FOR FLUIDS, AND A PLURALITY OF TWO-WAY VALVES FOR DISTRIBUTING THE FLUIDS, AND SEPARATION PROCESS USING THE SAME

Номер: KR1020080034413A
Принадлежит:

PURPOSE: An improved device for SMB(Simulated Moving Bed) separation belonging to the major simulated moving bed technique using a plurality of two-way(on-off or gradually opened) control valves, typically standard valves that are mass-produced at low cost and at the required high standard(seal/reliability), is provided, and a process for SMB separation using the device is provided. CONSTITUTION: A simulated moving bed(SMB) separation device comprises a column, beds Ai of an adsorbent separated by plates Pi having a single distributing and extracting network for fluids, in particular feed F, desorbant D, raffinate R and extract E, and a plurality of two-way valves for distributing the fluids, wherein the valves are limited in the number and particularly have small sizes as compared with the prior art. The column is divided into a plurality of sectors Sk with two superimposed plates, and each sector Sk comprises an external major bypass line Lk connected to each plate Pi of Sk through a ...

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01-07-2009 дата публикации

Process and device for improved separation of paraxylene in a simulated moving bed

Номер: TW0200927704A
Принадлежит:

Process for separating paraxylene with a purity that is at least equal to 99. 5% by weight from an aromatic feedstock F in a single adsorption stage in a simulated moving bed in an SMB device, comprising A zone 1 between the supply of the desorbent D and the draw-off the extract E; A zone 2 between the draw-of the extract E and the supply of the feedstock F; A zone 3 between the supply of the feedstock and the draw-off of the raffinate R; A zone 4 between the draw-off of the raffinate R and the of the desorbent D, whereby the process is performed according to a configuration of zones (a, b, c, d), whereby a, b, c, d represent the number of adsorbent beds operating respectively in zones 1, 2, 3, 4 in which they use; Either an SMB of 12 adsorbent beds operating according to the configuration (2, 5, 3, 2), Or an SMB of 15 adsorbent beds operating according to the configuration (3, 6, 4, 2), Or an SMB of 19 adsorbent beds operating according to the configuration (4, 7, 6, 2), whereby the desorbent ...

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06-10-2016 дата публикации

ZEOLITIC GRANULAR MATERIAL HAVING A CONNECTED STRUCTURE

Номер: US20160289146A1
Принадлежит: CECA S.A., IFP ENERGIES NOUVELLES

The present invention relates to a zeolitic granular material having a connected zeolitic structure across the entire volume thereof, having high mechanical resistance to crushing in the bed, and optimised material transfer in the macro-mesopores. The invention also relates to the method for preparing said zeolitic granular material, as well as to the use thereof as an adsorbent material in co-current or counter-current liquid phase separation methods, typically in a simulated mobile bed. 1. A zeolitic granular material with a size of between 0.1 mm and 1 mm , limits inclusive , whose zeolite structure forms a connected assembly over the entire volume of said material , and which has a mechanical bulk crushing strength of greater than or equal to 1.0 MPa.2. The zeolitic granular material as claimed in claim 1 , comprising at least one zeolite selected from the group consisting of zeolites of FAU structure and zeolites of EMT claim 1 , LTA and MFI structure.3. The zeolitic granular material as claimed in claim 1 , comprising at least one zeolite selected from the group consisting of zeolites LSX claim 1 , MSX and X.4. The zeolitic granular material as claimed in claim 1 , comprising more than 94% by weight of zeolite(s) claim 1 , relative to the total weight of the zeolitic granular material.6. A process for preparing a zeolitic granular material as claimed in claim 1 , comprising at least the steps of:a) mixing crystals of at least one zeolite with a clay binder containing at least 80% , by weight of zeolitizable clay, and optionally a source of silica to form a mixture,b) placing the mixture in contact with an alkaline basic solution to form a suspension,c) bringing the suspension to a temperature between 80° C. and 600° C., in a closed and leaktight container, at a pressure at least equal to the autogenous pressure, to obtain zeolitic granular material,d) optionally, carrying out cationic exchange of the cations contained in the reaction medium of step c) by ...

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28-08-2018 дата публикации

ZEOLITIC ADSORBENTS WITH LARGE EXTERNAL SURFACE AREA, PROCESS FOR PREPARING SAME AND USES THEREOF

Номер: CA0002922167C

La présente invention concerne des adsorbants zéolithiques à base de cristaux agglomérés de zéolithe FAU comprenant du baryum et/ou du potassium, de haute surface externe, combinant des propriétés optimales en termes de sélectivité et de résistance mécanique. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes, dans la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, dans la séparation des crésols, et des alcools polyhydriques, tels que les sucres.

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05-06-2012 дата публикации

Method for on-line measurement in simulated moving bed units and application to control and regulation of said units

Номер: US0008194245B2

The present invention describes a method for measuring the concentrations of species present at one point of a separation unit functioning in simulated moving bed mode (SMB), using an immersing probe located at one point in the unit or on one of the streams entering or leaving said unit, and a thermocouple located in the vicinity of the immersing probe, in which a Raman spectrum obtained using a laser source functioning at a wavelength of 785 nm is utilized.

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12-03-2015 дата публикации

ZEOLITIC ADSORBENTS WITH LARGE EXTERNAL SURFACE AREA, PROCESS FOR PREPARING SAME AND USES THEREOF

Номер: CA0002922167A1
Принадлежит:

La présente invention concerne des adsorbants zéolithiques à base de cristaux agglomérés de zéolithe FAU comprenant du baryum et/ou du potassium, de haute surface externe, combinant des propriétés optimales en termes de sélectivité et de résistance mécanique. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes, dans la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, dans la séparation des crésols, et des alcools polyhydriques, tels que les sucres.

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30-04-2010 дата публикации

DEVICE IMPROVES SEPARATION IN MOBILE BED SIMULATES

Номер: FR0002930174B1

Dispositif (SMB) de séparation par adsorption en lit mobile simulé comprenant une pluralité de zones élémentaires d'adsorption Zi en série fonctionnant en boucle fermée, et au moins une zone d'adsorption singulière possédant un volume mort plus important que les zones d'adsorption Zi, le solide adsorbant de la dite zone d'adsorption singulière ayant une granulomètrie inférieure à celle du solide adsorbant des zones d'adsorption ordinaires. Device (SMB) for separation by adsorption in a simulated moving bed comprising a plurality of elementary adsorption zones Zi in series operating in closed loop, and at least one singular adsorption zone having a greater dead volume than the adsorption zones Zi, the solid adsorbent of said singular adsorption zone having a particle size smaller than that of the solid adsorbent of ordinary adsorption zones.

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27-04-2018 дата публикации

METHOD FOR HYDRODESULFURIZING OLEFINIC GASOLINE

Номер: KR1020180043181A
Принадлежит:

The present invention relates to a method for the treatment of a gasoline containing sulfur-containing compounds, olefins, and diolefins, comprising the following steps of: a) fractionating the gasoline into at least a light gasoline cut LCN, a primary intermediate gasoline cut MCN, and a primary heavy gasoline cut HHCN; b) desulfurizing the primary intermediate gasoline cut MCN alone in a way to produce an at least partially desulfurized primary intermediate gasoline cut MCN; c) desulfurizing the primary heavy gasoline cut HHCN alone in a way to produce an at least partially desulfurized primary heavy gasoline cut HHCN; d) sending, as a mixture, the partially desulfurized primary intermediate gasoline cut MCN and the partially desulfurized primary heavy gasoline cut HHCN to a separation column in a way to separate a gaseous stream containing hydrogen and H_2S, a secondary intermediate gasoline cut MCN with low sulfur and mercaptans contents, and a secondary heavy gasoline cut HHCN containing ...

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27-01-2010 дата публикации

Method and device for separation into simulated mobile bed with reduced valve number and duct volume

Номер: CN0101636210A
Принадлежит:

The invention relates to a device for the adsorption separation into a simulated mobile bed that comprises a limited number of valves. According to the invention, the device includes a column with a plurality of sections Sk with 2 superimposed plates Pi with a unique distribution network, each section Sk including a main outer bypass duct Lk connected to each Pi of Sk by a plate valve Vi. Each duct Lk includes flow limiting means and is connected to each of the fluid networks via a single valve. Moreover, the tappings of the lines Lk on the column are offset by 20 DEG at most inside Sk in order to limit the volume of the lines Lk and are offset by an average angle of between 70 DEG and 110 DEG between two adjacent sections Sk and S in order not to mechanically weaken the column. The trays preferably include DME plates with parallel sectors the direction of which varies from one plate to the other or by groups of two plates. The invention also relates to a separation method that ...

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06-02-2009 дата публикации

PROCESS AND SEPARATION DEVICE IMPROVE OF PARAXYLENE IN MOBILE BED SIMULATES

Номер: FR0002919603A1
Принадлежит:

Procédé de séparation de paraxylène à une pureté au moins égale à 99,5% poids d'une charge aromatique F en une seule étape d'adsorption en lit mobile simulé dans un dispositif SMB, comprenant - une zone 1 entre l'alimentation du désorbant D et le soutirage de l'extrait E; - une zone 2 entre le soutirage de l'extrait E et l'alimentation de la charge F; - une zone 3 entre l'alimentation de la charge et le soutirage du raffinat R; - une zone 4 entre le soutirage du raffinat R et l'alimentation du désorbant D, le procédé étant opéré selon une configuration de zones (a, b, c, d) a, b, c, d représentant le nombre de lits d'adsorbant opérant respectivement en zone 1, 2, 3, 4 dans lequel on utilise; - soit un SMB de 12 lits d'adsorbant opérant selon la configuration (2, 5, 3, 2), - soit un SMB de 15 lits d'adsorbant opérant selon la configuration (3, 6, 4, 2), - soit un SMB de 19 lits d'adsorbant opérant selon la configuration (4, 7, 6, 2), le désorbant dans ce dernier cas étant le paradiéthylbenzène ...

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01-08-2008 дата публикации

Agglomerated zeolitic adsorbents, their production process and their uses

Номер: TW0200831183A
Принадлежит:

The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15 < Si/Al 1.5 and consisting of crystals with a mean diameter 1.7 m or less and an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X of which are occupied by barium ions. They may be obtained by agglomerating zeolite X powder with a mean particle diameter of 1.7 m or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged. These adsorbents exhibit, simultaneously, a selectivity, a reduced mass transfer resistance and a mechanical strength that are excellent, which adsorbents are particularly suitable for adsorbing para-xylene contained in C8 aromatic hydrocarbon fractions in liquid phase in processes of a simulated moving bed type, and especially for separating para-xylene from C8 aromatic hydrocarbon fractions by adsorption, but ...

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12-10-2017 дата публикации

PROCESS FOR THE TREATMENT OF A GASOLINE

Номер: US20170292080A1
Принадлежит: IFP Energies nouvelles

A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins, comprising the following steps: 1. A process for the treatment of a gasoline containing sulphur-containing compounds , olefins and diolefins , the process comprising the following steps:a) fractionating the gasoline in a manner such as to recover at least one intermediate gasoline cut, MCN, comprising hydrocarbons and wherein the temperature difference (ΔT) between the 5% and 95% by weight distillation points is less than or equal to 60° C.;{'sup': −1', '3', '3', '3', '3', '3', '3, 'b) desulphurizing the intermediate gasoline cut MCN alone and in the presence of a hydrodesulphurization catalyst and hydrogen, at a temperature in the range 160° C. to 450° C., at a pressure in the range 0.5 to 8 MPa, with a liquid space velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/min a manner such as to produce a partially desulphurized intermediate gasoline cut MCN; and'}c) fractionating, in a splitter, the partially desulphurized intermediate gasoline cut MCN which has not undergone catalytic treatment subsequent to step b), in a manner such as to recover an intermediate gasoline with low sulphur and mercaptans contents from the column head and a cut of hydrocarbons containing sulphur-containing compounds including mercaptans from the column bottom.2. The process as claimed in claim 1 , in which: a light gasoline cut LCN;', 'an intermediate gasoline cut, MCN, comprising hydrocarbons and wherein the temperature difference (ΔT) between the 5% and 95% by weight distillation points is less than or equal to 60° C.; and', 'a heavy gasoline cut HHCN containing hydrocarbons;, 'a) the gasoline is fractionated into at least{'sup': −1', '3', '3', '3', '3', '3', '3, 'b) the intermediate gasoline cut ...

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07-12-2004 дата публикации

Coproduction process for para-xylene and ortho-xylene comprising two separation steps

Номер: US0006828470B2

A coproduction process for ortho-xylene and para-xylene starting with a batch of hydrocarbons comprises a simulated counter-current fluidized bed system in a chromatographic column (6) containing at least five zones, comprising injection (1) of the batch and injection (2) of desorption agent and delivering an extract (3), a refined product (5), and an intermediate refined product (4). Refined product (5), richer in ortho-xylene than the intermediate refined product, is distilled (9) to extract desorption agent (15) and is injection, according to the second step of the process, into a simulated counter-current fluidized bed system (17) delivering an extract (18) and a refined product (19) continuously.

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26-03-2004 дата публикации

CO-PRODUCTION OF PARAXYLENE AND STYRENE FROM MIXTURE OF XYLENES AND ETHYLBENZENE, USEFUL AS RAW MATERIALS FOR SYNTHESIS OF POLYMERS SUCH AS POLYAMIDES AND POLYSTYRENE

Номер: KR20040025871A
Принадлежит:

PURPOSE: A process for the co-production of paraxylene and styrene of high purity by stages of separation, dehydrogenation and isomerization is provided. CONSTITUTION: The process for co-production of high purity paraxylene and styrene from a charge containing xylenes, ethylbenzene and 9 - 10C hydrocarbons comprises the following stages: (1) distillation of the charge to separate xylenes, from which a head flux comprising mainly metaxylene, paraxylene, ethylbenzene and part of the orthoxylene, and at the base 9 - 10C hydrocarbons and remaining orthoxylene; (2) an adsorption stage of the head flux in a primary adsorption column containing numerous adsorbent beds, interconnected in a closed loop, with varying selectivity for paraxylene, ethylbenzene, metaxylene and orthoxylene and comprising 4 zones of a desorption zone for paraxylene, a desorption zone for ethylbenzene, an adsorption zone for paraxylene and a zone between extraction of raffinate and injection of desorbent; (3) distillation ...

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13-10-2010 дата публикации

Process and apparatus for simulated moving bed separation comprising bypass lines in every other bed and with modulated bypass fluid flow rate

Номер: CN0101856568A
Принадлежит:

The invention relates to a process and apparatus for simulated moving bed separation comprising bypass lines in every other bed and with modulated bypass fluid flow rate. The process for separating a feed F by simulated moving bed adsorption in a SMB device is described, the device comprising external bypass lines Li/i+1 which directly connect two successive plates Pi, Pi+1, the index i being either even or (exclusive of the foregoing) odd, along the whole length of the column, in order to flush said plates, in which each of the bypass lines Li/i+1 comprises automated means for regulating the flow rate in the bypass lines, the degree of opening of said regulating means being defined by the following three rules: a) establishing a flow rate corresponding to an oversynchronicity in the range 15% to 30% in all of the open bypass lines of zone 1; b) establishing a flow rate corresponding to the synchronicity to within plus or minus 8% in all of the open bypass lines of zones 2 and 3; c) establishing ...

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14-10-2010 дата публикации

PROCESS AND APPARATUS FOR SIMULATED MOVING BED SEPARATION COMPRISING BYPASS LINES IN EVERY OTHER BED AND WITH A MODULATED BYPASS FLUID FLOW RATE

Номер: US20100258505A1
Принадлежит: IFP

A process for separating a feed F by simulated moving bed adsorption in a SMB device is described, the device comprising external bypass lines Li/i+1 which directly connect two successive plates Pi, Pi+1, the index i being either even or (exclusive of the foregoing) odd, along the whole length of the column, in order to flush said plates, in which each of the bypass lines Li/i+1 comprises automated means for regulating the flow rate in the bypass lines, the degree of opening of said regulating means being defined by the following three rules: a) establishing a flow rate corresponding to an oversynchronicity in the range 15% to 30% in all of the open bypass lines of zone 1; b) establishing a flow rate corresponding to the synchronicity to within plus or minus 8% in all of the open bypass lines of zones 2 and 3; c) establishing a flow rate corresponding to an oversynchronicity in the range 20% to 40% in all of the open bypass lines of zone 4.

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22-02-2007 дата публикации

METHOD FOR SEPARATING m-XYLENE FROM AROMATIC HYDROCARBON SUPPLY MATERIAL BY LIQUID-PHASE ADSORPTION USING TETRALIN AS DESORPTION AGENT

Номер: JP2007045824A
Принадлежит:

PROBLEM TO BE SOLVED: To provide a method for separating m-xylene from an aromatic-hydrocarbon supply material, capable of separating m-xylene with good selectivity and adsorption capacity and improved mass transfer. SOLUTION: This method is for separating m-xylene from a hydrocarbon supply material containing an isomer having eight carbon atoms and comprises the following steps: a step wherein the supply material is brought into contact with a faujasite-type zeolite adsorbent, the percentage of water in the adsorbent is 0-8 wt.%, and the adsorption temperature is 25-250°C; a desorption step utilizing a solvent selected from among tetralin and its alkylated derivatives as a desorption agent; and a step for separating m-xylene from the desorption agent. COPYRIGHT: (C)2007,JPO&INPIT ...

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15-02-2007 дата публикации

Process for separating meta-xylene from a feed of aromatic hydrocarbons by liquid phase adsorption

Номер: US2007038012A1
Принадлежит:

The invention concerns a process for separating meta-xylene from a hydrocarbon feed comprising isomers containing 8 carbon atoms, comprising: a step for bringing said feed into contact with a faujasite type zeolite adsorbant, the water content of the adsorbant being in the range 0 to 1% by weight and the adsorption temperature being from 160° C. to 180° C.; a desorption step employing a solvent selected from toluene, indane and mixtures thereof.

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05-06-2014 дата публикации

PROCESS AND APPARATUS FOR SIMULATED COUNTER-CURRENT CHROMATOGRAPHIC SEPARATION FOR HIGH-PRODUCTIVITY PRODUCTION OF PARAXYLENE

Номер: US20140155672A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention describes a process for the separation of xylenes in simulated counter-current utilising at least one adsorber with a limited cumulated total height (Hcu) of adsorbent and a superficial velocity (Vsl) of less than 2 cm/s. 2. A process for the separation of xylenes according to wherein the atomic ratio Si/Al of the adsorbent is such that 1.05 Подробнее

04-04-2018 дата публикации

METHOD FOR PROCESSING GASOLINE BY SEPARATION INTO THREE CUTS

Номер: KR1020180034257A
Принадлежит:

The present invention relates to a desulfurization method of gasoline cuts containing sulfur-containing compounds, olefins and diolefins, wherein the method comprises the following steps, at least: a) separating the gasoline to recover a hard gasoline cut LCN and a first medium quality gasoline cut HCN; b) performing a first step for desulfurizing the first medium quality gasoline cut HCN; c) partially condensing a first desulfurization effluent with a method for producing HCN on a liquid hydrocarbon phase comprising gaseous and dissolved H_2S consisting essentially of hydrogen and H_2S; d) separating the liquid hydrocarbon phase HCN into medium quality gasoline cut MCN second medium quality gasoline cut HHCN; e) performing a second step for desulfurizing the second medium quality gasoline cut HHCN. COPYRIGHT KIPO 2018 ...

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11-06-2019 дата публикации

Process for seperating xylenes by simulated counter-current, treating a feed including oxygen-containing aromatic impurities of the phenol type

Номер: US0010315132B2

The present invention describes a process for separating xylenes in simulated counter-current (simulated moving bed, SMB) for the treatment of feeds including oxygen-containing aromatic impurities of the phenol type and/or derivatives thereof, by controlled injection of water in the ingoing streams.

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03-06-2009 дата публикации

AGGLOMERATED ZEOLITIC ADSORBENTS, THEIR METHOD OF PREPARATION AND THEIR USES

Номер: KR1020090056962A
Принадлежит:

The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15 < Si/Al <=1.5, consisting of crystals with a mean diameter of 1.7 mm or less and of an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X being occupied by barium ions. They may be obtained by agglomerating zeolite X powder having a mean diameter of 1.7 mm or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged. These adsorbents exhibit, simultaneously, excellent selectivity, reduced mass transfer resistance and excellent mechanical strength and are particularly suitable for the adsorption of the paraxylene contained in C8 aromatic hydrocarbon fractions in liquid phase in processes of the simulated moving bed type and especially for the separation of paraxylene of C8 aromatic hydrocarbon fractions by adsorption, but also for ...

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14-02-2007 дата публикации

PROCESS FOR SEPARATING META-XYLENE FROM A FEED OF AROMATIC HYDROCARBONS BY LIQUID PHASE ADSORPTION USING TETRALINE AS A DESORBENT

Номер: KR1020070018743A
Принадлежит:

PURPOSE: A process for separating meta-xylene from an aromatic hydrocarbon feed which can separate meta-xylene with a selectivity substantially identical to or even excellent than that obtained by processes of the prior art, an adsorbent capacity substantially identical to or more excellent than that obtained by the prior art processes, and furthermore, which can separate meta-xylene with an improved matter transfer is provided. CONSTITUTION: A process for separating meta-xylene from a hydrocarbon feed comprising isomers containing 8 carbon atoms comprises: a step of contacting the feed with a meta-selective adsorbent comprising a faujasite type zeolite, wherein the percentage of water existing in the adsorbent is in a range from 0 to 8 wt.%, and the adsorption temperature is 25 to 250 deg.C; a desorption step of using a desorbent; and a step of separating meta-xylene from the desorbent, wherein the desorbent is selected from tetraline and its alkylated derivatives. The faujasite type zeolite ...

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17-09-2010 дата публикации

METHOD FOR MEASURING ONLINE IN A SIMULATED MOVING BED UNIT AND AN EXAMPLE FOR CONTROLLING AND ADJUSTING THE SIMULATED MOVING BED UNIT

Номер: KR1020100101530A
Принадлежит:

PURPOSE: A method for measuring online in a simulated moving bed unit is provided to measure concentration accepting temperature using matrix inverse induced from prior correction. CONSTITUTION: Monochromatic signals generated from a laser source(1) are transmitted through a first optical signal connected to an immersion probe(3). Raman signals are obtained through a second optical fiber connected to the immersion probe. The Raman signal is transmitted to a spectrometer(5) using a filter determining cut-off threshold value. The Raman spectrum of object signals is collected from the outlet of the spectrometer. COPYRIGHT KIPO 2011 ...

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07-07-2020 дата публикации

Process for the treatment of a gasoline by separation into three cuts

Номер: US0010703997B2
Принадлежит: IFP Energies nouvelles, IFP ENERGIES NOW

A process for the desulphurization of a gasoline cut containing sulphur-containing compounds, olefins and diolefins, involving (a) fractionating the gasoline in order to recover a light gasoline cut LCN and a first heavy gasoline cut HCN; (b) desulphurization of the first heavy gasoline cut HCN; (c) partially condensing desulphurization effluent obtained from b) in a manner such as to produce a gaseous phase of hydrogen and H2S and a liquid hydrocarbon phase HCN of dissolved H2S; (d) separating the liquid hydrocarbon phase HCN into an intermediate gasoline cut MCN and a second heavy gasoline cut HHCN; (e) carrying out a second desulphurization of the second heavy gasoline cut HHCN.

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28-07-2020 дата публикации

Zeolitic granular material having a connected structure

Номер: US0010723677B2

The present invention relates to a zeolitic granular material having a connected zeolitic structure across the entire volume thereof, having high mechanical resistance to crushing in the bed, and optimised material transfer in the macro-mesopores. The invention also relates to the method for preparing said zeolitic granular material, as well as to the use thereof as an adsorbent material in co-current or counter-current liquid phase separation methods, typically in a simulated mobile bed.

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14-02-2008 дата публикации

Verfahren und Vorrichtung zur Trennung im simulierten Bewegtbett mit reduzierter Anzahl von Ventilen

Номер: DE102007036830A1
Принадлежит:

Die Erfindung betrifft eine Vorrichtung zur Trennung im simulierten Bewegbett (SMB), die eine Kolonne, Adsorptionsbetten Ai, die durch Böden Pi mit einem Netz zur Verteilung und Extraktion von Fluiden, insbesondere der Beschickung F, des Desorptionsmittels D, des Raffinats R und des Extrakts E getrennt sind, und eine Vielzahl von 2-Wege-Ventilen zur Verteilung dieser Fluide umfasst, wobei diese Ventile im Vergleich zum Stand der Technik in begrenzter Zahl vorhanden sind. Gemäß der Erfindung ist die Kolonne in eine Vielzahl von Abschnitten Sk mit 2 oder 3 übereinander liegenden Böden gegliedert, wobei jeder Abschnitt Sk eine externe Ableitungslinie Lk umfasst, die mit jedem Boden Pi des Sk über ein Anschlussstück verbunden ist, das ein Bodenventil Vi umfasst. Jede Linie Lk umfasst ein Steuerungsmittel zur Begrenzung ihrer inneren Durchflussmenge und ist mit jedem Netze der Fluide F, D, R, E über eine einzige Linie verbunden, die ein einziges gesteuertes 2-Wege-Zonenventil umfasst, zur Zufuhr ...

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04-08-2009 дата публикации

Process and device for simulated moving bed separation with a reduced number of large diameter valves and a reduced line volume

Номер: US0007569141B2

The invention concerns a simulated moving bed adsorption separation device comprising a limited number of large diameter valves. According to the invention, the device comprises a column with a plurality of sectors Sk with 2 superimposed plates Pi with a single distribution network, each sector Sk comprising an external principal bypass line Lk connected to each plate Pi of Sk via a large diameter plate valve Vi and an external secondary bypass line Mk comprising a small diameter valve VMk connected to the adjacent sector Sk-1. Each line Lk comprises a flow rate limitation means and is connected to each fluid network via a single large diameter valve. Further, the connectors of lines Lk onto the column are offset by at most 20° inside Sk to limit the volume of lines Lk, and are offset by a mean angle in the range 70° to 110° between two neighbouring sectors Sk and Sk+1 so as not to weaken the column mechanically. The plates preferably comprise panels DMEi,j with parallel segments the direction ...

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16-12-2009 дата публикации

PROCESS AND DEVICE FOR SIMULATED MOVING BED SEPARATION WITH A REDUCED NUMBER OF LARGE DIAMETER VALVES AND A REDUCED LINE VOLUME

Номер: KR1020090129431A
Принадлежит:

The invention relates to a simulated moving bed adsorption separation device having a limited number of large-diameter valves. According to the invention, the device includes a column comprising a plurality of sections Sk having two stacked plates Pi with a single distribution network, each section Sk comprising a main outer bypass line Lkconnected to each plate Pj of Sk by a large-diameter plate valve Vj and a secondary outer bypass line Mk comprising a small-diameter valve VMkconnected to the adjacent section Sk-i. Each line Lk includes a flow limiting means and is connected to each of the fluid networks via a single large-diameter valve. In addition, the branch pipes from lines Lk to the column are offset by a maximum angle of 20° inside Skin order to limit the volume of lines Lkand by an average angle of between 70° and 110° between two adjacent sections Skand Sk+1 so as not to weaken the column mechanically. The plates preferably include DMEij panels with parallel sectors, the direction ...

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31-07-2018 дата публикации

Process for the production of high-purity paraxylene from a xylenes cut, using two simulated moving bed separation units operating in series and two isomerization units

Номер: US10035739B2
Принадлежит: IFP ENERGIES NOW, IFP Energies nouvelles

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.

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29-03-2011 дата публикации

Method for producing paraxylene comprising an adsortion step and two isomerization steps

Номер: US0007915471B2

A process for producing para-xylene from a hydrocarbon feed is described in which an adsorption column operating as a simulated moving bed with at least five zones delivers an extract, a 2-raffinate and an intermediate raffinate. The extract is distilled and the distillate is optionally re-crystallized to recover para-xylene with a purity of at least 99.7%. The 2-raffinate is distilled then isomerized in a reactor preferably operating in the liquid phase and at a low temperature. The intermediate raffinate with an enriched ethylbenzene content is distilled then isomerized in the vapour phase.

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18-07-2017 дата публикации

Zeolite adsorbents comprising zeolite EMT, process for preparing the same and uses thereof

Номер: US0009707539B2

The present invention relates to zeolite adsorbents based on agglomerated crystals of zeolite EMT comprising barium and/or potassium. These adsorbents find applications in the separation of aromatic C8 isomer fractions, especially of xylenes, in the separation of substituted toluene isomers, such as nitrotoluene, diethyltoluene and toluenediamine, and in the separation of cresols, and in the separation of polyhydric alcohols, such as sugars.

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09-09-2015 дата публикации

Process and device for improved separation of paraxylene in a simulated moving bed

Номер: CN104892338A
Принадлежит:

Process for separating paraxylene with a purity that is at least equal to 99.5% by weight from an aromatic feedstock F in a single adsorption stage in a simulated moving bed (SMB), comprising different numbers of beds, allocated to a zone 1 between the supply of the desorbent D and the draw-off of the extract E; a zone 2 between the draw-off of the extract E and the supply of the feedstock F; a zone 3 between the supply of the feedstock and the draw-off of the raffinate R; a zone 4 between the draw-off of the raffinate R and the supply of the desorbent D, wherein an SMB of 12 adsorbent beds has bed configuration (2, 5, 3, 2), an SMB of 15 adsorbent beds has bed configuration (3, 6, 4, 2), or an SMB of 19 adsorbent beds has bed configuration (4, 7, 6, 2), wherein the desorbent in this latter case is paradiethylbenzene.

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01-10-2014 дата публикации

PROCESS FOR SEPARATION BY SELECTIVE ADSORPTION ON A SOLID CONTAINING A ZEOLITE WITH A CRYSTALLINE STRUCTURE ANALOGOUS TO IM-12

Номер: CN104069804A
Принадлежит:

An adsorbent comprises a crystalline structure analogous to the zeolite IM-12, which is a mixed oxide contining germanium, one or more tetravalent elements other than germanium and a trivalent element. An independent claim is also included for the application of the process.

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13-08-2019 дата публикации

Process for hydrodesulphurizing an olefinic gasoline

Номер: US0010377956B2
Принадлежит: IFP Energies nouvelles, IFP ENERGIES NOW

A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins: a) fractionating the gasoline into at least: a light gasoline cut LCN; a primary intermediate gasoline cut, MCN; and a primary heavy gasoline cut HHCN; b) desulphurizing the primary intermediate gasoline cut MCN alone producing an at least partially desulphurized primary intermediate gasoline cut MCN; c) desulphurizing the primary heavy gasoline cut HHCN alone producing an at least partially desulphurized primary heavy gasoline cut HHCN; d) sending, as a mixture, the partially desulphurized primary intermediate gasoline cut MCN and the partially desulphurized primary heavy gasoline cut HHCN to a separation column separating a gaseous stream containing hydrogen and H2S, a secondary intermediate gasoline cut MCN with low sulphur and mercaptans contents and a secondary heavy gasoline cut HHCN containing sulphur-containing compounds including recombinant mercaptans; e) desulphurizing the ...

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24-09-2010 дата публикации

NEW METHOD FOR ON-LINE MEASURING IN SIMULATED MOVING BED, AND APPLICATION TO CONTROL AND ADJUSTMENT OF THE BED

Номер: JP2010210624A
Принадлежит:

PROBLEM TO BE SOLVED: To provide a new method of analysis for on-line concentration measurement of flow composition in hydrocarbon traveling within various separated bands of the simulated moving bed based on simultaneous measurement of Raman spectrum and temperature for a sample in the measuring point. SOLUTION: This invention is the method using an immersion probe and a thermocouple to measure concentration of a form existed in one point of a separator which functions in a manner of the simulated moving bed (SMB). The immersion probe is located in one of the flows entering or coming from one point inside the above separator or the separator itself, while the thermocouple is located near the immersion probe. Further the Raman spectrum obtained by using a laser light source which functions in wavelength of 785 nm is also used. COPYRIGHT: (C)2010,JPO&INPIT ...

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13-02-2008 дата публикации

DEVICE FOR SIMULATED MOVING BED SEPARATION COMPRISING A REDUCED NUMBER OF PLURAL TWO-WAY ON-OFF VALVES WITH RESPECT TO THE PRIOR ART AND PROCESS FOR SIMULATED MOVING BED SEPARATION USING THE SAME

Номер: KR1020080013819A
Принадлежит:

PURPOSE: A process and a device for simulated moving bed separation with a reduced number of valves are provided to reduce the number of controlled two-way valves while maintaining the advantage of being able to provide effective flushing of dead zones of the "long duration with a small or non-concentration gradient" type, and increase the reliability of the system by reducing the number of valves, thereby limiting the statistical risks of malfunctioning of the valves. CONSTITUTION: A device for separating at least one desired compound from a mixture comprising the compound by simulated moving bed adsorption is characterized in that: the device comprises at least one column divided into a plurality of adsorption beds(Ai) separated by distributor/extractor plates(Pi) for sequentially supplying and extracting at least two supply fluids and at least two recovery fluids, the supplying fluids being a feed(F) and a desorbant(D), the recovery fluids being a raffinate(R) and an extract(E), and ...

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13-07-2011 дата публикации

Simulated-moving-bed separation method and device with modulated tapped-off fluid flow

Номер: CN0102123775A
Принадлежит:

Provided is a method of separating a charge F by simulated-moving-bed adsorption in an SMB device comprising at least one zone 1 for desorption of the compounds produced in the extract, a zone 2 for desorption of the compounds produced in the raffinate, a zone 3 for adsorption of the compounds produced in the extract, a zone 4 located between the raffinate withdrawal and the desorbent feed, the device including external tap-off lines Li/i+1 directly joining two successive plates Pi, Pi+1, in which device the degree of opening of means for restricting the purge flow rate of the tap-off lines Li/i+1 is modified sequentially so that: 1) in an operating zone in which at least one tap-off line is closed, an oversynchronicity of the purge flow rate is established over all the non-closed tap-off lines belonging to the zone in question, said oversynchronicity being defined by the following formula: S=a+b(nf/nt) in which the constant a is a constant between -5 and 5, and b is a constant between ...

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30-10-2008 дата публикации

METHOD FOR PRODUCING HIGH-PURITY META-XYLENE, COMPRISING SIMULATED MOVING BED ADSORPTION AND CRYSTALLIZATION PROCESS

Номер: KR1020080096448A
Принадлежит:

PURPOSE: A method for producing high-purity meta-xylene is provided to obtain a ultra high pure meta-xylene having the purity more than 99.5% by uniting two processes(a simulated moving bed separation and crystallization) with an original and simple method to perform the separation of the ultra high pure meta-xylene. CONSTITUTION: A method for producing high-purity meta-xylene comprises an isolation step by the simulated moving bed absorption inducing the fraction in which meta-xylene is abundant and the fraction in which meta-xylene is exhausted, from the feed of an aromatic C8 group and a crystallization step of the fraction in which meta-xylene is abundant. © KIPO 2009 ...

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11-10-2002 дата публикации

PROCESS FOR CO-PRODUCING PARA-XYLENE AND METAXYLENE, COMPRISING TWO SEPARATION STEPS

Номер: KR20020077204A
Принадлежит:

PURPOSE: Provided is a process for co-producing paraxylene and metaxylene from a hydrocarbon feed containing them, wherein the process comprising two separation steps. CONSTITUTION: In a process for co-producing paraxylene and metaxylene from a hydrocarbon feed comprising them, it comprises a first step for separating the feed in a simulated moving bed in at least a first chromatographic column(6) containing a plurality of beds of at least one adsorbent interconnected into a loop, wherein the column comprising a feed injection(1), a take-off for a first raffinate(4), a take-off for a second raffinate(5) comprising a desorbent, and a mixture containing metaxylene and orthoxylene that is substantially free of ethylbenzene and paraxylene, an injection point for desorbent(2) and a take-off for an extract delivering very high purity paraxylene. The process also comprises periodic simultaneous shifting of the feed and desorbent injection positions and for the extract take-off position by one ...

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24-07-2018 дата публикации

Method for the production of paraxylene, comprising two simulated moving bed separation and two isomerization units, one being in the gas phase

Номер: US0010029958B2
Принадлежит: IFP Energies nouvelles, IFP ENERGIES NOW

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut containing xylenes and ethylbenzene, a process using two simulated moving bed separation units and two isomerization units.

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28-02-2013 дата публикации

HIGHLY FLEXIBLE PROCESS AND APPARATUS FOR THE SIMULATED COUNTER-CURRENT PRODUCTION OF PARA-XYLENE

Номер: US20130053610A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the production of para-xylene by simulated counter-current adsorption with high flexibility with respect to a reference run (100%) uses 2 adsorbers each with 12 beds, said adsorbers being able to be connected in accordance with 3 different modes; the flexibility obtained is 50% to 150%. 3. A simulated counter-current separation process according to claim 1 , in which in “high productivity” mode claim 1 , one of the adsorbers shifts the feed and desorbant introduction points and the extract and raffinate withdrawal points simultaneously claim 1 , and the other adsorber is in Varicol type shift mode claim 1 , the number of beds per zone for the adsorber in simultaneous shift mode being 2/5/3/2 and the mean number of beds per zone for the adsorber in Varicol type shift mode being:2.5 (+ or −0.5) beds in zone 1;4.5 (+ or −0.5) beds in zone 2;3.5 (+ or −0.5) beds in zone 3;1.5 (+ or −0.5) beds in zone 4.4. A simulated counter-current separation process according to claim 1 , in which in “high productivity” mode claim 1 , the two adsorbers a) and b) shift the feed and desorbant introduction points and the extract and raffinate withdrawal points in Varicol type mode claim 1 , the mean number of beds per zone being:2.5 (+ or −0.5) beds in zone 1;4.5 (+ or −0.5) beds in zone 2;3.5 (+ or −0.5) beds in zone 3;1.5 (+ or −0.5) beds in zone 4.5. A simulated counter-current separation process according to claim 1 , in which in “intermediate productivity” mode claim 1 , the two adsorbers a) and shift the feed and desorbant introduction points and the extract and raffinate withdrawal points simultaneously claim 1 , the number of beds per zone being 5/9/7/3.6. A simulated counter-current separation process according to claim 1 , in which in “intermediate productivity” mode claim 1 , the two adsorbers a) and b) shift the feed and desorbant introduction points and the extract and raffinate withdrawal points simultaneously claim 1 , the number of beds per zone being 4/10/7 ...

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09-05-2013 дата публикации

Process for separation by selective adsorption on a solid containing a zeolite with a crystalline structure analogous to im-12

Номер: US20130116485A1
Принадлежит: IFP Energies Nouvelles IFPEN

A process for adsorption separation uses a solid IM-12 type adsorbent to separate a molecular species from any feed.

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03-10-2013 дата публикации

PROCESS FOR THE SELECTIVE HYDROGENATION OF A GASOLINE

Номер: US20130261357A1
Принадлежит: IFP ENERGIES NOUVELLES

The present application relates to a process for the selective hydrogenation of a gasoline which contains polyunsaturated compounds and sulphurous light compounds, the process allowing conjointly the hydrogenation of polyunsaturated compounds into mono-unsaturated compounds, increasing weight of the sulphurous light compounds by reaction with the unsaturated compounds, and maximisation of the isomerisation of the monounsaturated compounds comprising an external C═C double bond into their internal C═C double bond isomer, said process implementing a catalyst containing at least one group VIb metal and at least one group VIII metal deposited on a porous support. 1. A process of selective hydrogenation of a gasoline comprising polyunsaturated compounds and sulphurous light compounds , the said process enabling , conjointly , hydrogenation of the polyunsaturated compounds into monounsaturated compounds , weighting of the sulphurous saturated light compounds by reaction with the unsaturated compounds , and isomerisation of the monounsaturated compounds comprising an external C═C double bond into their isomer having an internal C═C double bond , the said process implementing a catalyst containing at least one group VIb metal and at least one group VIII metal deposited on a porous support , wherein:the content by weight of oxide of the group VIb element with reference to the weight of the catalyst is within the range 6 to 18%;the content by weight of oxide of the group VIII element with reference to the weight of the catalyst is within the range 4 to 12%;{'sup': '2', 'the specific surface area of the catalyst is within the range 200 to 270 m/g;'}{'sup': −4', '2, 'the density of the group VIb element, expressed as being the ratio of the said content by weight of oxide of the group VIb element to the specific surface area of the catalyst, is within the range 4 to 6.10g/m;'}the molar ratio between the group VIII metal and the group VIb metal is within the range 0.6 to 3 mol/ ...

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14-01-2016 дата публикации

METHOD FOR SEPARATING XYLENES IN A SIMULATED MOVING BED BY MEANS OF A ZEOLITIC ADSORBENT SOLID HAVING A PARTICLE SIZE OF BETWEEN 150 AND 500 MICRONS

Номер: US20160009614A1
Принадлежит:

Process for separating xylenes starting from a feed comprising cuts of isomers of aromatic hydrocarbons containing 8 carbon atoms, in a simulated moving bed, by selective adsorption of a xylene isomer in the presence of a desorbent, by means of particles of agglomerated zeolitic adsorbent based on zeolite crystals with a number-average diameter less than or equal to 1.2 μm, wherein the number-average diameter of said particles of adsorbent is between 150 μm and 500 μm and the mechanical strength measured by the Shell method series SMS1471-74 adapted for agglomerates with a size below 500 μm is greater than or equal to 2 MPa. 1. A process for separating xylenes starting from a feed comprising cuts of isomers of aromatic hydrocarbons containing 8 carbon atoms , the process comprising selectively adsorbing a xylene isomer from the feed in a simulated moving bed in the presence of a desorbent , using particles of agglomerated zeolitic adsorbent based on zeolite crystals with a number-average diameter less than or equal to 1.2 μm , wherein the number-average diameter of said particles of adsorbent is between 150 μm and 500 μm and the mechanical strength measured by the Shell method series SMS1471-74 adapted for agglomerates with a size below 500 μm is greater than or equal to 2 MPa.2. The process for separating xylenes according to claim 1 , wherein the number-average diameter of said particles of agglomerated zeolitic adsorbent is between 200 μm and 400 μm.3. The process for separating xylenes according to claim 1 , wherein the granulometric distribution of said particles of adsorbent is such that there is no particle with size less than 100 μm.4. The process for separating xylenes according to claim 1 , wherein the number-average diameter of the zeolite crystals is between 0.1 μm and 1.2 μm.5. The process for separating xylenes according to claim 4 , wherein the number-average diameter of the zeolite crystals is between 0.5 μm and 0.8 μm.6. The process for separating ...

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10-02-2022 дата публикации

METHOD FOR REGENERATING A CATALYST WHICH IS SPENT AND REGENERATED BY A HYDRODESULFURIZATION PROCESS OF GASOLINES

Номер: US20220040680A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for rejuvenating an at least partially spent catalyst resulting from a hydrodesulfurization process of a sulfur-containing olefinic gasoline cut, where the at least partially spent catalyst result is from a fresh catalyst a metal from group VIII, a metal from group VIb, and an oxide support, where the process includes 1. A process for the rejuvenation of an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut , said at least partially spent catalyst resulting from a fresh catalyst comprising at least one metal from group VIII , at least one metal from group VIb , an oxide support , and optionally phosphorus , said process comprising the following stages:a) the at least partially spent catalyst is regenerated in an oxygen-containing gas stream at a temperature of between 350° C. and 550° C. so as to obtain a regenerated catalyst,b) the regenerated catalyst is brought into contact with at least one impregnation solution containing at least one compound comprising a metal from group VIb, the molar ratio of the metal from group VIb added per metal from group VIb already present in the regenerated catalyst being between 0.15 and 2.5 mol/mol,c) a drying stage is carried out at a temperature of less than 200° C. so as to obtain a rejuvenated catalyst.2. The process as claimed in claim 1 , in which claim 1 , in stage b) claim 1 , the impregnation solution additionally contains a compound comprising a metal from group VIII; the molar ratio of the metal from group VIII added per metal from group VIII already present in the regenerated catalyst is between 0.1 and 2.5 mol/mol.3. The process as claimed in claim 1 , in which claim 1 , in stage b) claim 1 , the impregnation solution additionally contains phosphorus; the molar ratio of the phosphorus added per metal from group VIb already present in the regenerated catalyst is between 0.1 and 2.5 mol/mol.4. The process as claimed in claim 1 , ...

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25-01-2018 дата публикации

METHOD FOR SOFTENING SULFIDE-TYPE COMPOUNDS OF AN OLEFINIC GASOLINE

Номер: US20180023010A1
Принадлежит: IFP ENERGIES NOUVELLES

This invention relates to a method for reducing the content of sulfide-type compounds of formula R1-S—R2, with R1 and R2 selected from among the methyl (CH) and ethyl (CH) radicals, of a gasoline that contains diolefins, monoolefins, and sulfur. The method implements a first catalytic step for selective hydrogenation of diolefins at a temperature of between 60° C. and 150° C. and then a step for heating the effluent that is obtained from the first step with a temperature difference ΔT of between 10° C. and 100° C. and a second catalytic step on the effluent that is heated in such a way as to produce an effluent that has a content of sulfide-type compounds of formula R1-S—R2, with R1 and R2 selected from among the methyl (CH3) and ethyl (C2H5) radicals, lower than that of the starting gasoline. 1. Method for reducing the content of sulfide-type compounds of formula R1-S—R2 , with R1 and R2 selected from among the methyl (CH) and ethyl (CH) radicals , of a gasoline that contains diolefins , monoolefins , and sulfur , in which:{'sup': '−1', 'claim-text': {'sup': '−1', 'sub': '2', '10 h, a pressure of between 0.5 and 5 MPa, and with a volumetric ratio of added H/gasoline feedstock of between 1 to 40 normal liters of hydrogen per liter of gasoline (vol/vol), in such a way as to produce an effluent at a temperature T1 of between 60° C. and 150° C. and having a lower diolefin content than that of the starting gasoline;'}, 'A) In a first reactor, the gasoline is brought into contact with hydrogen and a catalyst A that comprises at least one metal of group VIb and at least one non-noble metal of group VIII that are deposited on a substrate, with step A being carried out at a temperature in the reactor of between 60° C. and 150° C. with an hourly volumetric flow rate (VVH) of between 1 hand'}B) The effluent that is obtained from the first reactor is heated in a heating device at a temperature T2 with a temperature difference ΔT (T2-T1) of between 10° C. and 100° C.; {'sup': − ...

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24-02-2022 дата публикации

PROCESS FOR THE HYDROSULFURIZATION OF SULFUR-CONTAINING OLEFINIC GASOLINE CUTS USING A REGENERATED CATALYST HAVING AN ORGANIC COMPOUND

Номер: US20220056348A1
Принадлежит: IFP ENERGIES NOUVELLES

The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a rejuvenated catalyst are brought into contact, said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 hand a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII, at least one metal from group VIb, an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur. 1. A process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut , hydrogen and a rejuvenated catalyst are brought into contact , said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C. , a total pressure of between 1 and 3 MPa , an hourly space velocity , defined as being the flow rate by volume of feedstock relative to the volume of catalyst , of between 1 and 10 hand a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l , said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII , at least one metal from group VIb , an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur.2. The process as claimed in claim 1 , in which the organic compound containing oxygen and/or nitrogen and/or sulfur is chosen from a compound comprising one or more chemical functional groups chosen from a carboxylic claim 1 , alcohol claim 1 , thiol claim 1 , thioether claim 1 , sulfone claim 1 , sulfoxide claim 1 , ether claim 1 , aldehyde claim 1 , ketone claim 1 , ester claim 1 , carbonate ...

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03-03-2022 дата публикации

Method for rejuvenating a nonregenerated spent catalyst from a process for the hydrodesulfurization of gasolines

Номер: US20220062873A1
Принадлежит: IFP Energies Nouvelles IFPEN

The invention relates to a process for the rejuvenation of an at least partially spent catalyst resulting from a hydrotreating process, said at least partially spent catalyst resulting from a fresh catalyst comprising a metal from group VIII, a metal from group VIb, an oxide support, and optionally phosphorus, said at least partially spent catalyst additionally comprising carbon in a content of between 2% and 20% by weight, with respect to the total weight of the at least partially spent catalyst, and sulfur in a content of between 1% and 8% by weight, with respect to the total weight of the at least partially spent catalyst, said process comprising the following stages: a) said spent catalyst is brought into contact with an impregnation solution containing a compound comprising a metal from group VIb, b) a drying stage is carried out at a temperature of less than 200° C.

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17-03-2022 дата публикации

PROCESS FOR THE HYDRODESULFURIZATION OF SULFUR-CONTAINING OLEFINIC GASOLINE CUTS USING A REGENERATED CATALYST

Номер: US20220081627A1
Принадлежит: IFP ENERGIES NOUVELLES

The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a regenerated catalyst are brought into contact, said process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 h; and a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said regenerated catalyst resulting from an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut and comprises at least one metal from group VIII, at least one metal from group VIb and an oxide support. 1. A process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut , hydrogen and a regenerated catalyst are brought into contact , said process being carried out at a temperature of between 200° C. and 400° C. , a total pressure of between 1 and 3 MPa , an hourly space velocity , defined as being the flow rate by volume of feedstock relative to the volume of catalyst , of between 1 and 10 hand a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l , said regenerated catalyst resulting from an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut , said regenerated catalyst comprises at least one metal from group VIII , at least one metal from group VIb and an oxide support.2. The process as claimed in claim 1 , in which the regenerated catalyst has a content of metal from group VIb of between 1% and 20% by weight of oxide of said metal from group VIb claim 1 , with respect to the total weight of the regenerated catalyst claim 1 , and a content of metal from group VIII of between 0.1% and 10% by weight of oxide of ...

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10-03-2016 дата публикации

ZEOLITE ADSORBENTS COMPRISING ZEOLITE EMT, PROCESS FOR PREPARING THE SAME AND USES THEREOF

Номер: US20160067673A1
Принадлежит:

The present invention relates to zeolite adsorbents based on agglomerated crystals of zeolite EMT comprising barium and/or potassium. These adsorbents find applications in the separation of aromatic C8 isomer fractions, especially of xylenes, in the separation of substituted toluene isomers, such as nitrotoluene, diethyltoluene and toluenediamine, and in the separation of cresols, and in the separation of polyhydric alcohols, such as sugars. 1. A zeolite adsorbent comprising zeolite EMT crystals and comprising barium and/or potassium , in which the total content of alkali metal or alkaline-earth metal ion oxides other than barium oxide BaO and potassium oxide KO is between 0 and 5% , limits included , relative to the total mass of the adsorbent.2. The zeolite adsorbent according to claim 1 , also comprising a non-zeolite phase.3. The zeolite adsorbent according to claim 1 , wherein the zeolite EMT crystals have an Si/Al atomic ratio of between 1.00 and 2.00 claim 1 , limits included.4. The zeolite adsorbent according to claim 1 , wherein the number-average diameter of the zeolite EMT crystals is between 5 nm and 1500 nm claim 1 , limits included.5. The zeolite adsorbent according to claim 1 , which also comprises crystals of at least one other zeolite claim 1 , selected from the group consisting of zeolites of FAU structure claim 1 , zeolites of LTA structure claim 1 , and zeolites of MFI structure.6. The zeolite adsorbent according to claim 5 , wherein the said at least one other zeolite is selected from the group consisting of zeolites of faujasite structure claim 5 , alone or as a mixture and wherein the mass fraction of zeolite EMT is between 1% and 50%.7. The zeolite adsorbent according to claim 1 , wherein the mass fraction of zeolite EMT is greater than 50% relative to the total weight of adsorbent.8. The zeolite adsorbent according to claim 1 , comprising zeolite phases of EMT-FAU intergrowth.9. The zeolite adsorbent according to claim 1 , wherein:the barium ...

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29-05-2014 дата публикации

SIMULATED COUNTERCURRENT CHROMATOGRAPHIC SEPARATION PROCESS AND DEVICE WITH LOW PRESSURE DROP AND HIGH NUMBER OF ZONES

Номер: US20140148633A1
Принадлежит: IFP ENERGIES NOUVELLES

A simulated moving bed separation process is characterized in that the feed and desorbant injection streams are each divided into N streams (N being a whole number strictly greater than 1) injected respectively at N distinct feed injection points and at N distinct desorbant injection points, and in that the extract and raffinate withdrawal points are also each divided into N streams each withdrawn from N distinct withdrawal points, the device being constituted by 4×N chromatographic zones. 1. A process for simulated counter-current (SCC) chromatographic separation of a feed F having at least one adsorption column divided into zones , each zone comprising a certain number of beds , said column being composed of a plurality of beds of adsorbent separated by plates P , each comprising a distribution/extraction system , in which process the feed F is supplied to at least one supply point and a desorbant D is supplied to at least one supply point , and at least one extract E and at least one raffinate R are extracted , the supply and withdrawal points being shifted over time by a value corresponding to one bed of adsorbent with a switch period ST and determining a plurality of functional zones of the SMB , each zone being included between an injection point and the immediately consecutive withdrawal point , or between a withdrawal point and the immediately consecutive injection point; a desorbant injection point is positioned between the raffinate withdrawal point and an extract withdrawal point, the 3 points: raffinate withdrawal, desorbant injection and extract withdrawal, being consecutive;', 'an extract withdrawal point is positioned between a desorbant injection point and a feed injection point, the 3 points: desorbant injection, extract withdrawal and feed injection, being consecutive;', 'a feed injection point is positioned between an extract withdrawal point and a raffinate withdrawal point, the 3 points: extract withdrawal, feed injection and raffinate ...

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05-06-2014 дата публикации

PROCESS AND DEVICE FOR SIMULATED-COUNTERCURRENT CHROMATOGRAPHIC SEPARATION FOR THE PRODUCTION OF METAXYLENE WITH HIGH YIELD

Номер: US20140155673A1
Принадлежит: IFP ENERGIES NOUVELLES

This invention describes a process for separation of xylenes for the purpose of the production of high-purity metaxylene, a simulated countercurrent process using at least one adsorber with a limited cumulative total level (Hcu) of adsorbent at a surface velocity (Vsl) that is less than 2 cm/s. 2. Process for separation of xylenes according to claim 1 , wherein the Si/Al atomic ratio of the adsorbent is preferably such that 2.0 Подробнее

26-03-2015 дата публикации

Process for seperating xylenes by simulated counter-current, treating a feed including oxygen-containing aromatic impurities of the phenol type

Номер: US20150087878A1
Принадлежит: IFP Energies Nouvelles IFPEN

The present invention describes a process for separating xylenes in simulated counter-current (simulated moving bed, SMB) for the treatment of feeds including oxygen-containing aromatic impurities of the phenol type and/or derivatives thereof, by controlled injection of water in the ingoing streams.

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29-03-2018 дата публикации

PROCESS FOR THE TREATMENT OF A GASOLINE BY SEPARATION INTO THREE CUTS

Номер: US20180086989A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention concerns a process for the desulphurization of a gasoline cut containing sulphur-containing compounds, olefins and diolefins, comprising at least the following steps: 1. A process for the desulphurization of a gasoline containing sulphur-containing compounds , olefins and diolefins , the process comprising at least the following steps:a) fractionating the gasoline in order to recover a light gasoline cut LCN and a first heavy gasoline cut HCN;{'sup': −1', '3', '3', '3', '3', '3', '3, 'b) carrying out a first step for desulphurization of the first heavy gasoline cut HCN in the presence of a hydrodesulphurization catalyst and hydrogen, at a temperature in the range 160° C. to 450° C., at a pressure in the range 0.5 to 8 MPa, with a liquid velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/min a manner such as to produce a first desulphurization effluent;'}{'sub': 2', '2, 'c) partially condensing the first desulphurization effluent obtained from step b) in a manner such as to produce a gaseous phase essentially constituted by hydrogen and HS and a liquid hydrocarbon phase HCN comprising dissolved HS;'}d) separating the liquid hydrocarbon phase HCN into an intermediate gasoline cut MCN and a second heavy gasoline cut HHCN;{'sup': −1', '3', '3', '3', '3', '3', '3, 'e) carrying out a second step for desulphurization of the second heavy gasoline cut HHCN in the presence of a hydrodesulphurization catalyst and hydrogen, at a temperature in the range 160° C. to 450° C., at a pressure in the range 0.5 to 8 MPa, with a liquid velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/min a manner ...

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19-04-2018 дата публикации

PROCESS FOR HYDRODESULPHURIZING AN OLEFINIC GASOLINE

Номер: US20180105756A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins: 1. A process for the treatment of a gasoline containing sulphur-containing compounds , olefins and diolefins , comprising the following steps: a light gasoline cut LCN;', 'a primary intermediate gasoline cut, MCN; and', 'a primary heavy gasoline cut HHCN;, 'a) fractionating the gasoline into at least{'sup': −1', '3', '3', '3', '3', '3', '3, 'b) desulphurizing the primary intermediate gasoline cut MCN alone and in the presence of a hydrodesulphurization catalyst and hydrogen, at a temperature in the range 160° C. to 450° C., at a pressure in the range 0.5 to 8 MPa, with a liquid space velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/min a manner such as to produce an at least partially desulphurized primary intermediate gasoline cut MCN;'}{'sup': −1', '3', '3', '3', '3', '3', '3, 'c) desulphurizing the primary heavy gasoline cut HHCN alone in the presence of a hydrodesulphurization catalyst and hydrogen, at a temperature in the range 200° C. to 450° C., at a pressure in the range 0.5 to 8 MPa, with a liquid space velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/min a manner such as to produce an at least partially desulphurized primary heavy gasoline cut HHCN;'}{'sub': '2', 'd) sending, as a mixture, the partially desulphurized primary intermediate gasoline cut MCN which has not undergone treatment following step b) and the partially desulphurized primary heavy cut HHCN which has not undergone treatment following step c) to a separation column in order to separate a gaseous stream containing ...

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17-07-2014 дата публикации

PROCESS FOR THE PRODUCTION OF A GASOLINE WITH A LOW SULFUR CONTENT

Номер: US20140197073A1
Принадлежит: IFP ENERGIES NOUVELLES

This invention relates to a process for treatment of a gasoline comprising diolefins, olefins, and sulfur-containing compounds including mercaptans, in which: 1. Process for treatment of a gasoline comprising diolefins , olefins , and sulfur-containing compounds including mercaptans , in which:{'b': 3', '4', '4', '4', '3, 'Gasoline is injected into a distillation column () comprising at least one reaction zone () including at least a first catalyst comprising a substrate and at least one element of group VIII, with the injection being carried out at a level located below the reaction zone (), in such a way as to bring into contact at least one fraction of the gasoline with the catalyst of the reaction zone () and to transform at least a portion of the mercaptans of said fraction into sulfur-containing compounds by reaction with the diolefins and to produce a desulfurized light gasoline that is drawn off at the top of said distillation column (); with the process also comprising the following stages{'b': 4', '3, 'An intermediate gasoline fraction is drawn off at a level located above the reaction zone () and below the top of the distillation column ();'}A heavy gasoline comprising the majority of the sulfur-containing compounds is drawn off at the bottom of the column;{'b': '13', 'In a demercaptization reactor (), said intermediate gasoline fraction is brought into contact optionally with hydrogen, in the presence of a second catalyst in sulfide form comprising a substrate, at least one element selected from group VIII and at least one element selected from group VIB, with the element content of group VIII being between 1 and 30% by weight of oxide relative to the total weight of catalyst, the element content of group VIB being between 1 and 30% by weight of oxide relative to the total weight of the catalyst in such a way as to produce an effluent that contains sulfides;'}{'b': '3', 'The effluent that is obtained from the demercaptization reactor is recycled in the ...

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25-08-2022 дата публикации

METHOD FOR PRODUCING GASOLINE WITH LOW SULPHUR AND MERCAPTAN CONTENT

Номер: US20220267686A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the treatment of a gasoline containing sulfur compounds and olefins includes the following stages: 1. A process for the treatment of a gasoline containing sulfur compounds , olefins and diolefins , the process comprising at least the following stages:{'sup': −1', '3', '3', '3', '3, 'sub': '2', 'a) the gasoline, hydrogen and a hydrodesulfurization catalyst comprising an oxide support and an active phase comprising a metal from group VIB and a metal from group VIII are brought into contact in at least one reactor at a temperature of between 210 and 320° C., at a pressure of between 1 and 4 MPa, with a space velocity of between 1 and 10 hand a ratio of the hydrogen flow rate, expressed in normal mper hour, to the flow rate of feedstock to be treated, expressed in mper hour at standard conditions, of between 100 and 600 Nm/m, so as to convert at least a portion of the sulfur compounds into HS,'}{'sub': '2', 'sup': −1', '3', '3', '3', '3, 'b) the effluent resulting from stage a) without removal of the HS formed, hydrogen and a hydrodesulfurization catalyst comprising an oxide support and an active phase consisting of at least one metal from group VIII are brought into contact in at least one reactor at a temperature of between 280 and 400° C., at a pressure of between 0.5 and 5 MPa, with a space velocity of between 1 and 10 hand a ratio of the hydrogen flow rate, expressed in normal mper hour, to the flow rate of feedstock to be treated, expressed in mper hour at standard conditions, of between 100 and 600 Nm/m, said temperature of stage b) being higher than the temperature of stage a),'}{'sub': '2', 'c) a stage of separation of the HS formed and present in the effluent resulting from stage b) is carried out,'}{'sub': '2', 'sup': '−1', 'd) the effluent depleted in HS resulting from stage c), hydrogen and a hydrodesulfurization catalyst comprising an oxide support and an active phase comprising a metal from group VIB and a metal from group VIII or an active ...

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01-09-2022 дата публикации

Method for producing a petrol with low sulphur and mercaptan content

Номер: US20220275291A1
Принадлежит: IFP Energies Nouvelles IFPEN

The present application relates to a method for treating a petrol containing sulphur compounds, olefins and diolefins, the method comprising the following steps: a) a step of hydrodesulphurisation in the presence of a catalyst comprising an oxide support and an active phase comprising a group VIB metal and a group VIII metal from, b) a step of hydrodesulphurising at least one portion of the effluent from step a) at a higher hydrogen flow rate/feed ratio and a temperature higher than those of step a) without removing the H2S formed in the presence of a catalyst comprising an oxide support and an active phase consisting of at least one group VIII metal, c) a step of separating the H2S formed in the effluent from step b).

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31-05-2018 дата публикации

METHOD FOR SWEETENING AN OLEFINIC PETROL OF SULPHIDE-TYPE COMPOUNDS

Номер: US20180148658A1
Принадлежит: IFP ENERGIES NOUVELLES

A process reducing sulfides R1-S—R2, with R1 and R2 methyl or ethyl, in a gasoline containing diolefins, mono-olefins and sulphur: 1. Process for reducing the content of compounds of the sulphide type of formula R1-S—R2 , with R1 and R2 selected from the methyl (CH) and ethyl (CH) radicals , in a gasoline containing diolefins , mono-olefins and sulphur , in which:{'sup': −1', '−1, 'sub': 2', '3', '2', '5, 'A) the gasoline in a mixture with a light gasoline cut recycled from step C) and hydrogen are brought into contact in a reactor with catalyst A comprising at least one metal of group VIb and at least one non noble metal of group VIII deposited on a support, step A) being carried out at a temperature in the reactor comprised between 60° C. and 150° C. with a liquid hourly space velocity (LHSV) comprised between 1 hand 10 h, a pressure comprised between 0.5 and 5 MPa and with a ratio by volume (added H/mixture of gasolines) comprised between 1 to 40 normal litres of hydrogen per litre of the mixture of gasolines (vol/vol), so as to produce an effluent having a content of diolefins and a content of compounds of the sulphide type of formula R1-S—R2, with R1 and R2 selected from the methyl (CH) and ethyl (CH) radicals lower than that that of the starting gasoline;'}B) said effluent originating from step A) is sent into a fractionating column in order to separate at the top of the column a light gasoline cut containing hydrocarbons having less than 6 carbon atoms per molecule and at the bottom of the column a heavy gasoline cut containing hydrocarbons having 6 and more than 6 carbon atoms per molecule;C) a part of the light gasoline cut originating from step B) is recycled into the reactor of step A) with a recycle ratio comprised between 0.1 and 0.7, a content of oxide of the metal of group VIb comprised between 4 and 20% by weight with respect to the total weight of the catalyst,', 'a content of oxide of the metal of group VIII comprised between 4 and 15% by weight ...

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18-06-2015 дата публикации

PROCESS FOR THE HYDRODESULPHURIZATION OF HYDROCARBON CUTS

Номер: US20150166907A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the concomitant production of at least two hydrocarbon cuts with low sulphur contents from a mixture of hydrocarbons having a total sulphur content in the range 30 to 10000 ppm by weight, by 2. The process according to claim 1 , in which the catalyst for step a) comprises a metal from group VIII selected from nickel and cobalt and a metal from group VI selected from molybdenum and tungsten.3. The process according to claim 1 , in which the catalyst for step a) comprises phosphorus.4. The process according to claim 1 , in which the catalyst for step c) comprises a metal from group VIII selected from nickel and cobalt and a metal from group VI selected from molybdenum and tungsten.5. The process according to claim 4 , in which the catalyst for step c) further comprises phosphorus.6. The process according to claim 1 , in which the first hydrocarbon fraction is a gasoline cut obtained from a catalytic cracking unit.7. The process according to claim 6 , in which the first hydrocarbon fraction is a C6 hydrocarbon cut obtained by distillation of a gasoline cut obtained from a catalytic cracking unit.8. The process according to in which claim 7 , before the distillation step claim 7 , the gasoline cut has undergone a step for selective hydrogenation of the diolefins present in said gasoline cut.9. The process according to claim 1 , in which the second hydrocarbon fraction is selected from a light cycle oil claim 1 , a heavy diesel cut claim 1 , a vacuum distillate cut claim 1 , a hydrocarbon cut obtained from a visbreaking unit and a hydrocarbon cut obtained from a coking unit.10. The process according to claim 1 , in which the mixture contains a gasoline cut and a light cycle oil.11. The process according to claim 10 , in which said mixture is the product of a distillation of an effluent obtained from a catalytic cracking unit.12. The process according to claim 1 , in which the temperature of step c) is higher than the temperature of step a) by at least 5° C. ...

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18-06-2015 дата публикации

PROCESS FOR DESULPHURIZATION OF A GASOLINE

Номер: US20150166908A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for treatment of gasoline comprising diolefins, olefins and sulphur-containing compounds including mercaptans. The process comprises: 1. A process for the treatment of a gasoline comprising diolefins , olefins and sulphur-containing compounds including mercaptans , said process comprising the following steps:{'sup': '−1', 'claim-text': [{'sup': 2', '2, 'a support constituted by a gamma alumina with a specific surface area in the range 180 m/g to 270 m/g;'}, 'the quantity of metal from group VIb, expressed in the oxide form, is in the range 4% to 20% by weight with respect to the total catalyst weight;', 'the quantity of metal from group VIII, expressed in the oxide form, is in the range 3% to 15% by weight with respect to the total catalyst weight;', 'the molar ratio between the metal from group VIII and the metal from group VIB is in the range 0.6 to 3 mol/mol;, 'a) carrying out a step for demercaptanization by addition of at least a portion of the mercaptans onto the olefins by bringing gasoline into contact with at least one first catalyst, at a temperature in the range 50° C. to 250° C., at a pressure in the range 0.4 to 5 MPa and with a liquid hourly space velocity (LHSV) in the range 0.5 to 10 h, the first catalyst being in the sulphide form and comprising a first support, at least one metal selected from group VIII and at least one metal selected from group VIb of the periodic classification of the elements, the first catalyst having the following characteristicsb) in a distillation column, carrying out fractionation of the gasoline obtained from step a) into at least one first intermediate light gasoline cut with a total sulphur content below that of the starting gasoline and a second intermediate heavy gasoline cut containing the major proportion of the starting sulphur-containing compounds;{'b': 14', '15, 'sub': '2', 'c) introducing a stream of hydrogen and at least the second intermediate heavy gasoline cut obtained from step b) into a catalytic ...

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14-06-2018 дата публикации

ZEOLITIC ADSORBENTS WITH LARGE EXTERNAL SURFACE AREA, PROCESS FOR PREPARING THEM AND USES THEREOF

Номер: US20180161754A1
Принадлежит:

The present invention relates to zeolitic adsorbents based on agglomerated crystals of FAU zeolite containing barium and/or potassium, with large external surface area, combining optimum properties in terms of selectivity and mechanical strength. These adsorbents find applications in the separation of cuts of C8-aromatic isomers and notably of xylenes, in the separation of isomers of substituted toluene such as nitrotoluene, diethyltoluene, toluenediamine, in the separation of cresols, and in the separation of polyhydric alcohols such as sugars. 1. A method for separating para-xylene from cuts of aromatic isomers with 8 carbon atoms , using , as an agent for adsorption of para-xylene , a zeolitic adsorbent comprising at least one FAU zeolite and comprising at least one of barium and potassium , wherein the external surface area of said zeolitic adsorbent , measured by nitrogen adsorption , is greater than 20 m·g , said method comprising:contacting aromatic isomers with 8 carbon atoms with said zeolitic adsorbent; andadsorbing para-xylene.2. A method according to claim 1 , wherein the method is in the liquid phase claim 1 , and wherein adsorbing para-xylene is performed in the presence of a desorbent.3. A method according to claim 2 , wherein the desorbent is selected from the group consisting of toluene and para-diethylbenzene.4. A method according to claim 1 , wherein the method is a simulated moving-bed method.5. A method according to claim 1 , wherein the method is a simulated countercurrent moving-bed method.6. A method according to claim 1 , wherein the zeolitic adsorbent has a content of barium oxide (BaO) above 10% relative to the total weight of the zeolitic adsorbent and a barium content between 23% and 42% claim 1 , inclusive claim 1 , by weight relative to the total weight of the zeolitic adsorbent.7. A method according to claim 1 , wherein the zeolitic adsorbent has a content of potassium oxide KO below 25% by weight relative to the total weight of the ...

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30-05-2019 дата публикации

ZEOLITE ADSORBENT IN THE FORM OF LOW-TORTUOSITY AGGLOMERATES

Номер: US20190160450A1
Принадлежит:

Provided is a zeolite-based adsorbent in the form of agglomerates, where the adsorbent having a tortuosity factor, calculated from the pore distribution determined by mercury intrusion porosimetry, of greater than 1 and less than 3. The adsorbent also has a porosity as determined by mercury intrusion porosimetry of between 25% and 35%. The adsorbent is useful in the field of separations in particular in a process for separating para-xylene from aromatic hydrocarbon isomer fractions containing 8 carbon atoms. 2. The zeolite-based adsorbent as claimed in claim 1 , in which the tortuosity factor t is between 1.5 and 2.7.3. The zeolite-based adsorbent as claimed in claim 1 , wherein the high mechanical bulk crushing strength (BCS) claim 1 , measured via the Shell method series SMS1471-74 adapted for agglomerates less than 1.6 mm in size claim 1 , is greater than or equal to 1.0 MPa.4. The zeolite-based adsorbent as claimed claim 1 , wherein said adsorbent has a size of between 0.1 mm and 1 mm claim 1 , limits inclusive.5. The zeolite-based adsorbent as claimed in claim 1 , wherein claim 1 , said adsorbent comprises a zeolite chosen from the zeolites of FAU structure.6. The zeolite-based adsorbent as claimed in claim 5 , said zeolite being zeolite X claim 5 , alone or as a mixture with other zeolites.7. The zeolite-based adsorbent as claimed in claim 1 , wherein claim 1 , said adsorbent comprising more than 90% by weight of zeolite(s).8. The zeolite-based adsorbent as claimed in claim 1 , wherein said zeolite(s) are in the form of crystals between 10 nm and 1500 nm in size.10. The zeolite-based adsorbent as claimed in claim 1 , further comprising barium and/or potassium.11. A process for preparing a zeolite-based adsorbent as claimed in claim 1 , comprising at least following steps:a) a step of mixing crystals of at least one zeolite with an agglomeration binder containing at least 80 of zeolitizable clay, and optionally a source of silica, followed by forming and a ...

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25-06-2015 дата публикации

PROCESS FOR THE PRODUCTION OF A LIGHT GASOLINE WITH A LOW SULPHUR CONTENT

Номер: US20150175910A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the treatment of a gasoline comprising diolefins, olefins and sulphur-containing compounds including mercaptans: 1. A process for the treatment of a gasoline comprising diolefins , olefins and sulphur-containing compounds including mercaptans , said process comprising the following steps:{'sup': '−1', 'a) carrying out a step for demercaptanization by addition of at least a portion of the mercaptans onto the olefins by bringing gasoline into contact with at least one first catalyst, at a temperature in the range 50° C. to 250° C., at a pressure in the range 0.4 to 5 MPa and with a liquid hourly space velocity (LHSV) in the range 0.5 to 10 h, the first catalyst being in the sulphide form and comprising a first support, at least one metal selected from group VET and at least one metal selected from group VIb of the periodic classification of the elements, the % by weight, expressed as the oxide equivalent of the metal selected from group VIII with respect to the total catalyst weight, being in the range 1% to 30% by weight and the % by weight, expressed as the oxide equivalent of the metal selected from group VIb, being in the range 1% to 30% with respect to the total catalyst weight;'}b) carrying out a step for treating the gasoline obtained from step a) with hydrogen in a distillation column comprising at least one reaction zone comprising at least one second catalyst comprising a second support and at least one metal from group VIII, the conditions of step b) being selected such that the following operations are carried out simultaneously in said distillation column:I) distillation in order to separate the gasoline obtained from step a) into a light gasoline fraction which is depleted in sulphur-containing compounds and into a heavy gasoline fraction with a boiling point which is higher than that of the light gasoline and comprising the majority of the sulphur-containing compounds, the light gasoline fraction being evacuated at a point located above ...

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20-06-2019 дата публикации

HYDRODESULPHURIZATION CATALYST SELECTIVE OF GASOLINES FROM FCC

Номер: US20190185764A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention relates to a hydrotreating catalyst comprising at least one group VIB metal, at least one group VIII metal and an alumina support having a gamma alumina content greater than 50% by weight and less than 100% by weight with respect to the weight of the support, said support having a specific surface area comprised between 25 and 150 m/g. 1. Hydrotreating catalyst comprising at least one group VIB metal , at least one group VIII metal and an alumina support having a gamma alumina content greater than 50% by weight and less than 100% by weight with respect to the weight of the support , said support having a specific surface area comprised between 25 and 150 m/g.2. Catalyst according to claim 1 , in which the alumina support has a gamma alumina content comprised between 60% and 95% by weight with respect to the weight of the support.3. Catalyst according to claim 1 , in which the group VIB metal content is comprised between 3 and 35% by weight of oxide of said group VIB metal with respect to the total weight of the catalyst claim 1 , and the group VIII metal content is comprised between 0.1 and 10% by weight of oxide of said group VIII metal with respect to the total weight of the catalyst.4. Catalyst according to claim 1 , in which the molar ratio (group VIII metal)/(group VIB metal) is comprised between 0.1 and 0.8.5. Catalyst according to claim 1 , which also contains phosphorus claim 1 , the phosphorus content being comprised between 0.3 and 10% by weight expressed as POwith respect to the total weight of the catalyst and the molar ratio of phosphorus/(group VIB metal) in the catalyst is comprised between 0.1 and 0.7.6. Catalyst according to claim 1 , in which the support has a specific surface area comprised between 60 and 100 m/g.7. Catalyst according to claim 1 , in which the density of group VIB metal claim 1 , expressed as the number of atoms of group VIB metal per unit of area of the catalyst is comprised between 3 and 30 atoms of group ...

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21-07-2016 дата публикации

ZEOLITIC ADSORBENTS WITH LARGE EXTERNAL SURFACE AREA, PROCESS FOR PREPARING THEM AND USES THEREOF

Номер: US20160207025A1
Принадлежит:

The present invention relates to zeolitic adsorbents based on agglomerated crystals of FAU zeolite comprising barium and/or potassium, with large external surface area, combining optimum properties in terms of selectivity and mechanical strength. 1. A zeolitic adsorbent comprising at least one FAU zeolite and comprising at least one of barium or potassium , wherein the external surface area of said zeolitic adsorbent , measured by nitrogen adsorption , is greater than 20 m·g.2. A zeolitic adsorbent according to claim 1 , having a content of barium oxide (BaO) above 10% claim 1 , relative to the total weight of the adsorbent claim 1 , and having a barium content is between 23% and 42% claim 1 , inclusive claim 1 , by weight relative to the total weight of the zeolitic adsorbent.3. A zeolitic adsorbent according to claim 1 , having a content of potassium oxide KO below 25% by weight relative to the total weight of the zeolitic adsorbent.4. A zeolitic adsorbent according to claim 1 , wherein said FAU zeolite has an Si/Al atomic ratio between 1.00 and 1.50 inclusive.5. A zeolitic adsorbent according to claim 1 , wherein no zeolitic structure other than a faujasite structure is detected by X-ray diffraction.6. A zeolitic adsorbent according to claim 1 , wherein the fraction by weight of FAU zeolite is greater than or equal to 80% relative to the total weight of zeolitic adsorbent.7. A zeolitic adsorbent according to claim 1 , having a loss on ignition measured at 900° C. according to standard NF EN 196-2 of less than or equal to 7.7%.8. A zeolitic adsorbent according to claim 1 , having a total volume of macropores and mesopores claim 1 , measured by mercury intrusion porosimetry claim 1 , of between 0.15 cm·gand 0.5 cm·g.9. A zeolitic adsorbent according to claim 1 , having a volume fraction of macropores of between 0.2 and 1 of the total volume of macropores and mesopores claim 1 , inclusive.10. A zeolitic adsorbent according to claim 1 , having a number-average ...

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20-07-2017 дата публикации

Process for the production of high-purity paraxylene based on a xylene cut, a process using one simulated mobile bed separation unit and two isomerization units, one in gas phase and the other in liquid phase

Номер: US20170204024A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention describes a process for the production of high-purity paraxylene based on a xylene cut, a process using one simulated mobile bed separation unit and two isomerization units, one in gas phase and the other in liquid phase. 2- Process for the production of high-purity paraxylene according to claim 1 , in which the catalyst used in the isomerization unit (ISOM-2) contains from 1 to 70% by weight of a zeolite of the EUO structure type (EU-1 for example) comprising silicon and at least one element T preferably selected from aluminium and boron claim 1 , the Si/T ratio of which is comprised between 5 and 100.3- Process for the production of high-purity paraxylene according to claim 1 , in which the zeolite forming part of the isomerization unit (ISOM-2) is at least partially in the form of hydrogen claim 1 , and the sodium content is such that the Na/T atomic ratio is less than 0.1.4- Process for the production of high-purity paraxylene according to claim 1 , in which the catalyst of the isomerization unit (ISOM-2) can contain between 0.01 and 2% by weight of tin or indium claim 1 , and sulphur at a content of 0.5 to 2 atoms per atom of the group VIII metal.5- Process for the production of high-purity paraxylene according to claim 1 , in which the total number of beds of the separation unit (SMB) is comprised between 6 and 24 beds claim 1 , and preferably between 8 and 15 beds claim 1 , distributed over one or more adsorbers claim 1 , the number of beds being adjusted so that each bed has a height comprised between 0.70 m and 1.40 m.6- Process for the production of high-purity paraxylene according to claim 1 , in which the distribution of the quantity of solid adsorbent in each zone of the separation unit (SMB) is as follows:the quantity of solid adsorbent in zone 1 is 17%±5%,the quantity of solid adsorbent in zone 2 is 42%±5%,the quantity of solid adsorbent in zone 3 is 25%±5%,the quantity of solid adsorbent in zone 4 is 17%±5%,7- Process for the ...

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27-07-2017 дата публикации

PROCESS FOR THE PRODUCTION OF HIGH-PURITY PARAXYLENE FROM A XYLENES CUT, USING TWO SIMULATED MOVING BED SEPARATION UNITS OPERATING IN SERIES AND TWO ISOMERIZATION UNITS.

Номер: US20170210682A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units. 11212) Process for the production of high-purity paraxylene from a xylenes cut containing ethylbenzene and C9+ compounds , a process using two simulated moving bed separation units (SMB- et SMB-) , and two isomerization units (ISOM- et ISOM-) consisting of the following series of stages:{'b': 2', '1', '3', '4, 'the feedstock () is sent to a distillation column (S-) from where a mixture () is drawn off at the top comprising the major part of the metaxylene, paraxylene, ethylbenzene, and at least a part of the orthoxylene, and from where a flow () of C9-C10 hydrocarbons and the remaining part of the orthoxylene is drawn off at the bottom.'}{'b': 3', '1', '3', '16', '5', '7', '8, 'the mixture from the top () is separated in the separation unit (SMB-) comprising at least one adsorber containing a plurality of interconnected beds and operating in a closed loop, said adsorber comprising at least five zones delimited by the injections of the flow () and of the desorbent (), and a first extract () containing paraxylene, a first intermediate raffinate () containing ethylbenzene, and a first raffinate-2 () containing orthoxylene and metaxylene are drawn off,'}{'b': 11', '1', '2', '11', '17', '12', '14', '15, 'a simulated moving bed separation of the isomerate () originating from the isomerization unit (ISOM-), is carried out in the separation unit (SMB-) constituted by at least one adsorber containing a plurality of interconnected beds and operating preferentially in a closed loop, and said adsorber comprising at least five zones delimited by the injections of the flow () and of the desorbent (), and a second extract () containing paraxylene, a second intermediate raffinate () containing ethylbenzene, and a ...

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27-07-2017 дата публикации

METHOD FOR THE PRODUCTION OF PARAXYLENE, COMPRISING TWO SIMULATED MOVING BED SEPARATION AND TWO ISOMERIZATION UNITS, ONE BEING IN THE GAS PHASE

Номер: US20170210683A1
Принадлежит: IFP ENERGIES NOUVELLES

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut containing xylenes and ethylbenzene, a process using two simulated moving bed separation units and two isomerization units. 1) Process for the production of high-purity paraxylene based on a xylenes cut containing ethylbenzene and C9+ compounds , a process using two simulated moving bed separation units (SMB-1 et SMB-2) , and two isomerization units (ISOM-1 et ISOM-2) consisting of the following series of stages:the feedstock (2) is sent into a distillation column (S-1) from which a mixture (3) is drawn off at the top comprising the major part of the metaxylene, paraxylene, ethylbenzene, and at least a part of the orthoxylene, and a flow (4) of C9-C10 hydrocarbons and the remaining part of the orthoxylene is drawn off at the bottom.a first separation of the mixture from the top (3) is carried out in the separation unit (SMB-1) comprising at least one adsorber containing a plurality of interconnected beds and operating in a closed loop, said unit comprising at least four zones delimited by the injections of the flow (3) and of the desorbent (10), resulting from the mixture of the flows (9) and (7), and the draw-offs of a first extract (5) enriched with paraxylene, and of a first raffinate (8) depleted of paraxylene,a second separation of the isomerate (12) originating from the isomerization unit (ISOM-1) is carried out in the separation unit (SMB-2), said separation unit (SMB-2) being constituted by at least one adsorber containing a plurality of interconnected beds and operating preferentially in a closed loop, and said unit comprising at least four zones delimited by the injections of the feedstock (12) and of the desorbent (18) resulting from the flows (17) and (15), and the draw-offs of a second extract (13) enriched with paraxylene, and of a second raffinate (16) depleted of paraxylene,the first extract (5) originating from the separation unit (SMB-1) is ...

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10-08-2017 дата публикации

METHOD FOR SEPARATING META-XYLENE USING A ZEOLITIC ADSORBENT WITH A LARGE EXTERNAL SURFACE AREA

Номер: US20170226031A1
Принадлежит:

The invention relates to a method for separating meta-xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area. 1. A process for separating meta-xylene using a zeolite adsorbent comprising at least one faujasite-type zeolite Y comprising sodium or sodium and lithium , in which process the external surface area of said zeolite adsorbent , measured by nitrogen adsorption , is greater than 40 m·g , said external surface area being associated with a population of mesopores with a mean diameter of between 2 nm and 50 nm.2. The process according to claim 1 , wherein the pore size distribution of said zeolite adsorbent claim 1 , as determined via the Barrett-Joyner-Halenda method from the nitrogen adsorption isotherm at 77 K claim 1 , for pores between 2 nm and 50 nm claim 1 , is unimodal and narrow.3. The process according to claim 1 , wherein the zeolite adsorbent is an adsorbent based on FAU-type zeolite(s) Y claim 1 , the Si/Al atomic ratio of said adsorbent being greater than 1.50.4. The process according to claim 1 , in wherein said zeolite adsorbent has a mass fraction of FAU-type zeolite(s) Y of greater than or equal to 80% relative to the total weight of the adsorbent.5. The process according to claims 1 , wherein said zeolite adsorbent has a lithium content of less than 8% claims 1 , expressed as weight of lithium oxide LiO relative to the total mass of the adsorbent.6. The process according to claim 1 , wherein the zeolite adsorbent simultaneously comprises pores whose diameter is greater than 50 nm claim 1 , pores whose diameter is between 2 nm and 50 nm claim 1 , limits not included claim 1 , and pores whose diameter is less than 2 nm.7. The process according to claims 1 , in wherein the zeolite adsorbent has a total volume contained in the macropores and the mesopores (sum of the macropore volume and of the mesopore volume) ...

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30-10-2014 дата публикации

CATALYTIC ADSORBENT FOR THE CAPTURE OF ARSENIC AND THE SELECTIVE HYDRODESULFURIZATION OF GASOLINES

Номер: US20140323778A1
Принадлежит: IFP ENERGIES NOUVELLES

A catalytic adsorbent, comprising at least cobalt and molybdenum deposited on a porous substrate in which the content of cobalt, expressed in terms of CoO oxide, is between 11 and 30% by weight relative to the total weight of said adsorbent and the content of molybdenum, expressed in terms of MoOoxide, is between 3 and 30% by weight relative to the total weight of said adsorbent, is described. This invention also relates to a process for hydrotreatment using said catalytic adsorbent. 1. Catalytic adsorbent comprising at least cobalt and molydenum deposited on a porous substrate in which the content of cobalt , expressed in terms of CoO oxide , is between 11 and 30% by weight relative to the total weight of said adsorbent , and the content of molybdenum , expressed in terms of MoOoxide , is between 3 and 30% by weight relative to the total weight of said adsorbent.2. Adsorbent according to claim 1 , in which the Co/Mo molar ratio is between 0.9 and 7 claim 1 , preferably between 1 and 6.3. Adsorbent according to claim 1 , in which the cobalt content claim 1 , expressed in terms of CoO oxide claim 1 , is between 11 and 25% by weight relative to the total weight of said adsorbent.4. Adsorbent according to claim 1 , in which the molybdenum content claim 1 , expressed in terms of MoOoxide claim 1 , is between 5 and 20% by weight relative to the total weight of said adsorbent.5. Adsorbent according to claim 1 , also comprising phosphorus.6. Adsorbent according to claim 5 , in which the phosphorus content claim 5 , expressed in terms of POoxide claim 5 , is between 0.2 and 8% by weight relative to the total weight of said adsorbent.7. Process for hydrotreatment of a hydrocarbon-containing feedstock comprising at least one catalytic adsorption stage in which the hydrocarbon-containing feedstock is brought into contact claim 1 , in the presence of hydrogen claim 1 , with the catalytic adsorbent according to .8. Process according to claim 7 , in which the catalytic adsorbent ...

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24-09-2015 дата публикации

Process for separating propylene mixed with propane by adsorption in a simulated moving bed

Номер: US20150266797A1
Принадлежит: IFP Energies Nouvelles IFPEN

A process for separating propylene mixed with propane by adsorption in a simulated moving bed is described. The process operates in the gaseous phase or in the liquid phase, and it uses a 13X faujasite-type zeolite as adsorbent solid and butene-1 or isobutane or any mixture of these 2 components as desorbent.

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01-10-2015 дата публикации

PROCESS FOR THE PRODUCTION OF A GASOLINE WITH A LOW SULFUR CONTENT

Номер: US20150275105A1
Принадлежит: IFP ENERGIES NOUVELLES

This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column () comprising at least one reaction zone () including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column. 123. Process for the treatment of a gasoline comprising diolefins , olefins , and sulfur-containing compounds including mercaptans , consisting of a stage for treating gasoline in the presence of hydrogen in a distillation column () comprising at least one reaction zone () including at least one catalyst , with the catalyst being in sulfide form and comprising a substrate that consists of gamma-alumina or delta-alumina with a specific surface area of between 70 m/g and 350 m/g , a content by weight of oxide of the element of group VIb of between 1 and 30% by weight relative to the total weight of the catalyst , a content by weight of oxide of the element of group VIII of between 1 and 30% by weight relative to the total weight of the catalyst , a sulfurization rate of the metals that constitute said catalyst that is at least equal to 60% , a molar ratio between the metal of group VIII and the metal of group VIb of between 0.6 and 3 mol/mol , in which:{'b': '3', 'Gasoline is injected into the distillation column at a level located below the reaction zone () in such a way as to separate a desulfurized light gasoline at a point located above the reaction zone and a heavy gasoline comprising the majority of the sulfur-containing compounds at the bottom of the column, and;'}{'b': '3', 'The gasoline that distills at the top of the catalytic column is brought into contact with the catalyst of the reaction zone () and the hydrogen in such a way as to provide desulfurized light gasoline.'}2. Process according to ...

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25-12-2014 дата публикации

PROCESS FOR PRODUCING A GASOLINE WITH A LOW SULPHUR AND MERCAPTANS CONTENT

Номер: US20140374315A1
Принадлежит: IFP ENERGIES NOUVELLES

The present application concerns a process for the treatment of a gasoline containing sulphur-containing compounds and olefins, with the following steps: 1. A process for the treatment of a gasoline containing sulphur-containing compounds and olefins , the process comprising at least the following steps:{'sup': −1', '3', '3', '3', '3', '3', '3, 'sub': '2', 'a) bringing the gasoline, hydrogen and a hydrodesulphurization catalyst into contact in at least one reactor at a temperature in the range 200° C. to 400° C., at a pressure in the range 0.5 to 5 MPa, at an hourly space velocity in the range 0.5 to 20 hand with a ratio between the flow rate of hydrogen, expressed in normal mper hour, and the flow rate of the feed to be treated, expressed in mper hour under standard conditions, in the range 50 Nm/mto 1000 Nm/m, in order to convert at least a portion of the sulphur-containing compounds into HS;'}{'sub': '2', 'b) carrying out a step for separating the HS which is formed and present in the effluent obtained from step a);'}{'sub': 2', '2, 'sup': −1', '3', '3, 'c) bringing the HS -depleted effluent obtained from step b) into contact, in a reactor, with a catalyst containing at least one sulphide of at least one transition metal or lead deposited on a porous support, step c) being carried out at a temperature in the range 30° C. to 250° C., with a liquid hourly space velocity in the range 0.5 to 10 h, a pressure in the range 0.2 to 5 MPa and with a H/feed ratio in the range 0 to 25 Nmof hydrogen per mof feed, in order to produce a gasoline obtained from step c) with a reduced mercaptans content compared with that of the effluent obtained from step b).'}2. The process according to claim 1 , in which the transition metal of the catalyst for step c) is selected from a metal from group VIB claim 1 , a metal from group VIII and copper claim 1 , used alone or as a mixture.3. The process according to claim 2 , in which the catalyst for step c) comprises:{'sup': 2', '2, 'a ...

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29-10-2015 дата публикации

ZEOLITIC ADSORBENTS, THEIR PROCESS OF PREPARATION AND THEIR USES

Номер: US20150306565A1
Принадлежит:

The present invention relates to zeolitic adsorbents based on small agglomerated crystals of zeolite X comprising barium, combining optimum properties in terms of selectivity and of mechanical strength. 1. An agglomerated zeolitic adsorbent , based on crystals of zeolite X and on at least one non-zeolitic phase , wherein: i. a number-average diameter of less than or equal to 1.7 μm', 'ii. an Si/Al atomic ratio of between 1.00 and 1.50, limits included,, 'the crystals of zeolite X exhibitthe content by weight of non-zeolitic phase (NZP) is such that 2.0% Подробнее

01-01-2016 дата публикации

PROCESS FOR PRODUCING LOW SULFUR CONTENT

Номер: FR3000964B1
Принадлежит: IFP Energies Nouvelles IFPEN

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15-10-2010 дата публикации

SIMPLE MOBILE BED SEPARATION METHOD AND DEVICE HAVING TWO BED DERIVATION LINES AND MODULE DERIVATION FLUID FLOW RATE

Номер: FR2944215A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé de séparation d'une charge F par adsorption en lit mobile simulé dans un dispositif LMS, le dispositif comprenant des lignes de dérivation externes L joignant directement deux plateaux successifs P , P l'indice i étant soit pair, soit ( de manière exclusive de la précédente) impair, ceci tout au long de la colonne, et permettant le balayage desdits plateaux, dans lequel chacune des lignes de dérivation L comprend des moyens automatisés de régulation du débit dans les lignes de dérivation, le degré d'ouverture desdits moyens de régulation étant défini par les trois règles suivantes : a) on établit dans toutes les lignes de dérivation ouvertes de la zone 1 un débit correspondant à une sursynchronicité comprise entre 15 et 30 %, b) on établit dans toutes les lignes de dérivation ouvertes des zones 2 et 3 un débit correspondant à la synchronicité à plus ou moins 8 % près, c) on établit dans toutes les lignes de dérivation ouvertes de la zone 4 un débit correspondant à une sursynchronicité comprise 20 et 40 %. A method for separating a charge F by simulated moving bed adsorption in an LMS device, the device comprising external bypass lines L directly joining two successive trays P, P the index i being either even or (exclusively the previous) odd, this all along the column, and allowing the scanning of said trays, wherein each of the branch lines L comprises automated flow control means in the branch lines, the degree of opening of said means of Regulation being defined by the following three rules: a) a flow corresponding to an oversynchronicity of between 15% and 30% is established in all the open bypass lines in zone 1, and (b) in all the open bypass lines, 2 and 3 a flow corresponding to the synchronicity within plus or minus 8%, c) is established in all open bypass lines of zone 4 a d bit corresponding to a sursynchronicité comprised 20 and 40%.

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09-07-2021 дата публикации

PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS

Номер: FR3099173B1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente demande concerne un procédé de traitement d'une essence contenant des composés soufrés, des oléfines et des dioléfines comprenant les étapes suivantes:a) une étape d'hydrodésulfuration en présence d’un catalyseur comprenant un support d’oxyde et une phase active comprenant un métal du groupe VIB et un métal du groupe VIII,b) une étape d'hydrodésulfuration d’au moins une partie de l’effluent de l’étape a) à un rapport débit hydrogène/charge plus élevé et à une température plus élevés que ceux de l’étape a) sans élimination de l’H2S formé en présence d’un catalyseur comprenant un support d’oxyde et une phase active constituée d’au moins un métal du groupe VIII, c) une étape de séparation de l'H2S formé dans l’effluent issu de l’étape b). The present application relates to a process for treating a gasoline containing sulfur compounds, olefins and diolefins comprising the following steps: a) a hydrodesulfurization step in the presence of a catalyst comprising an oxide support and an active phase comprising a metal from group VIB and a metal from group VIII, b) a step of hydrodesulfurization of at least part of the effluent from step a) at a higher hydrogen flow rate / feed ratio and at a higher temperature higher than those of step a) without removing the H2S formed in the presence of a catalyst comprising an oxide support and an active phase consisting of at least one metal from group VIII, c) a step of separation of the H2S formed in the effluent from step b).

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01-03-2013 дата публикации

METHOD AND DEVICE FOR PRODUCING SIMULTANEOUS VS-CURRENT PARAXYLENE WITH HIGH FLEXIBILITY

Номер: FR2979252A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé de production de paraxylène par adsorption en contre courant simulé présentant une grande flexibilité par rapport à une marche de référence (100%), et faisant appel à 2 adsorbeurs de 12 lits chacun, ces adsorbeurs pouvant être connectés selon 3 modes différents, permettant de réaliser une flexibilité allant de 50% à 150%. Process for the production of paraxylene by adsorption in simulated counter-current having a great flexibility with respect to a reference step (100%), and making use of 2 adsorbers of 12 beds each, these adsorbers being able to be connected in 3 different modes, making it possible to achieve a flexibility ranging from 50% to 150%.

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12-11-2021 дата публикации

Hydrogenation catalyst comprising a support and a specific NiMo ratio

Номер: FR3109899A1
Принадлежит: IFP Energies Nouvelles IFPEN

Catalyseur d’hydrogénation sélective comprenant une phase active à base de nickel et de molybdène, et un support poreux constitué d’alumine et/ou d’aluminate de nickel, caractérisé en ce que le ratio molaire entre le nickel et le molybdène est supérieur à 2,5 mol/mol et inférieur à 3,0 mol/mol. Selective hydrogenation catalyst comprising an active phase based on nickel and molybdenum, and a porous support consisting of alumina and / or nickel aluminate, characterized in that the molar ratio between nickel and molybdenum is greater than 2.5 mol / mol and less than 3.0 mol / mol.

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30-07-2021 дата публикации

Hydrodesulfurization process of olefinic gasoline cuts containing sulfur using a regenerated catalyst.

Номер: FR3090005B1
Принадлежит: IFP Energies Nouvelles IFPEN

L’invention concerne un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l'hydrogène et un catalyseur régénéré, ledit procédé étant effectué à une température comprise entre 200 et 400°C, une pression totale comprise entre 1 et 3 MPa, une vitesse volumique horaire, définie comme étant le débit volumique de charge rapporté au volume de catalyseur, comprise entre 1 et 10 h-1; et un rapport volumique hydrogène/charge essence compris entre 100 et 1200 NL/L, ledit catalyseur régénéré étant issu d’un catalyseur au moins partiellement usé issu d’un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre et comprend au moins un métal du groupe VIIl, au moins un métal du groupe VIB et un support d’oxyde. The invention relates to a process for hydrodesulfurizing an olefinic gasoline cut containing sulfur in which said gasoline cut is brought into contact with hydrogen and a regenerated catalyst, said process being carried out at a temperature of between 200 and 400 ° C. C, a total pressure of between 1 and 3 MPa, an hourly volume speed, defined as being the volume flow rate of feed relative to the volume of catalyst, of between 1 and 10 h-1; and a hydrogen / gasoline feed volume ratio of between 100 and 1200 NL / L, said regenerated catalyst being obtained from an at least partially spent catalyst resulting from a hydrodesulphurization process of an olefinic gasoline cut containing sulfur and comprising at least minus one metal from group VIIl, at least one metal from group VIB and an oxide support.

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03-06-2022 дата публикации

HYDRODESULPHURIZATION PROCESS USING A CATALYST COMPRISING A FLASH ALUMINA SUPPORT

Номер: FR3116826A1
Принадлежит: IFP Energies Nouvelles IFPEN

L’invention concerne un procédé d’hydrodésulfuration d’une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l’hydrogène et un catalyseur comprenant un support d’alumine obtenu par déshydratation d’un hydroxyde ou d’un oxyhydroxyde d’aluminium à une température comprise entre 400 et 1200°C et pendant une durée comprise entre 0,1 seconde et 5 secondes, au moins un métal du groupe VIB, au moins un métal du groupe VIII, et du phosphore, le rapport molaire entre le phosphore et le métal du groupe VIB étant compris entre 0,2 et 0,35.

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19-06-2015 дата публикации

PROCESS FOR HYDRODESULFURIZATION OF HYDROCARBON CUT

Номер: FR3014896A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention concerne un procédé de production concomitante d'au moins deux coupes d'hydrocarbures à basses teneurs en soufre à partir d'un mélange d'hydrocarbures ayant une température d'ébullition initiale comprise entre 35°C et 100°C et une température d'ébullition finale comprise entre 260°C et 340°C et ayant une eneur en soufre total comprise entre 30 et 10000 ppm poids. Le procédé comprend les étapes suivantes: a) une première étape d'hydrodésulfuration en présence d'hydrogène et d'un catalyseur d'hydrodésulfuration; b) une séparation du sulfure d'hydrogène de l'effluent partiellement désulfuré issu de l'étape a); c) une seconde étape d'hydrodésulfuration du mélange partiellement désulfuré issu de l'étape b) en présence d'hydrogène et d'un catalyseur d'hydrodésulfuration, la température de la seconde étape d'hydrodésulfuration étant supérieure à celle de la première étape d'hydrodésulfuration; d) un fractionnement du mélange désulfuré issu de l'étape c) en au moins deux coupes d'hydrocarbures légère et lourde désulfurées, la coupe d'hydrocarbures légère ayant une température d'ébullition comprise entre la température d'ébullition initiale et une température d'ébullition finale comprise entre 160°C et 220°C et dont la teneur en soufre total est inférieure à 50 ppm poids.

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03-04-2020 дата публикации

PROCESS FOR THE CAPTATION OF ARSENIC USING A CAPTATION MASS BASED ON NICKEL OXIDE PARTICLES

Номер: FR3080117B1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention décrit un procédé de captation d'impuretés organométalliques dans une charge d'hydrocarbures de type essence contenant des oléfines et du soufre, dans lequel une masse de captation est mise en contact avec la charge à traiter et un flux d'hydrogène, ladite masse de captation comprend une phase active à base de particules d'oxyde de nickel de taille inférieure ou égale à 15 nm, ladite phase active ne comprenant pas d'autres éléments métalliques du groupe VIB ou du groupe VIII, déposées sur un support poreux choisi dans le groupe constitué par les alumines, la silice, les silices alumines, ou encore les oxydes de titane ou de magnésium utilisés seuls ou en mélange avec l'alumine ou la silice alumine. The invention describes a process for capturing organometallic impurities in a charge of petroleum type hydrocarbons containing olefins and sulfur, in which a capture mass is brought into contact with the charge to be treated and a flow of hydrogen, said capture mass comprises an active phase based on nickel oxide particles of size less than or equal to 15 nm, said active phase not comprising other metallic elements of group VIB or group VIII, deposited on a porous support chosen from the group consisting of aluminas, silica, aluminas silicas, or alternatively titanium or magnesium oxides used alone or as a mixture with alumina or silica alumina.

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01-01-2021 дата публикации

H2 PHOTOCATALYTIC PRODUCTION PROCESS IMPLEMENTING A MICROPOREOUS CRYSTALLIZED METAL SULPHIDE PHOTOCATALYZER

Номер: FR3097854A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention décrit un procédé de production photocatalytique de dihydrogène effectué en phase liquide et/ou en phase gazeuse sous irradiation mettant en œuvre un photocatalyseur de type sulfure métallique cristallisé microporeux. Ledit procédé étant effectué en mettant en contact une charge contenant H2O sans autre agent sacrificiel avec ledit photocatalyseur, puis en irradiant le photocatalyseur de manière à réduire H2O en H2 de manière à produire un effluent contenant au moins en partie du dihydrogène. The invention describes a process for the photocatalytic production of hydrogen carried out in the liquid phase and / or in the gas phase under irradiation, using a photocatalyst of the microporous crystallized metal sulfide type. Said process being carried out by contacting a charge containing H2O without other sacrificial agent with said photocatalyst, then by irradiating the photocatalyst so as to reduce H2O to H2 so as to produce an effluent containing at least in part dihydrogen.

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24-01-2014 дата публикации

METHOD OF DESULFURIZING A GASOLINE

Номер: FR2993571A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention concerne une procédé de traitement d'une essence comprenant des dioléfines, des oléfines et des composés soufrés incluant des mercaptans. Le procédé comprend les étapes suivantes : a) on effectue une étape de démercaptisation par addition d'au moins une partie des mercaptans sur les oléfines par mise en contact de l'essence avec au moins un premier catalyseur ; b) on effectue une séparation de l'essence issue de l'étape a) en une coupe d'essence légère intermédiaire et une coupe d'essence lourde intermédiaire c) on introduit un flux d'hydrogène et au moins la seconde coupe d'essence lourde intermédiaire issue de l'étape b) dans une colonne de distillation catalytique comprenant au moins une zone réactionnelle incluant au moins un second catalyseur sous forme sulfure comprenant un second support, au moins un métal du groupe VIII et un métal du groupe Vlb, afin de réaliser la décomposition des composés soufrés en H S, d) on évacue de la colonne de distillation catalytique au moins une fraction d'essence légère finale comprenant de l'H S et une fraction d'essence lourde désulfurée, la fraction d'essence légère finale étant évacué en un point situé au dessus de la zone réactionnelle et la fraction d'essence lourde désulfurée étant évacuée en un point situé en dessous de la zone réactionnelle. The present invention relates to a process for treating a gasoline comprising diolefins, olefins and sulfur compounds including mercaptans. The process comprises the following steps: a) a demercaptation step is carried out by adding at least a portion of the mercaptans to the olefins by contacting the gasoline with at least a first catalyst; b) the gasoline resulting from step a) is separated into a light intermediate gasoline cut and an intermediate heavy gasoline cut; c) a stream of hydrogen is introduced and at least the second cut of intermediate heavy gasoline from step b) in a catalytic ...

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19-06-2020 дата публикации

Process for hydrodesulfurization of olefinic gasoline cuts containing sulfur using a catalyst rejuvenated with an organic compound.

Номер: FR3090006A1
Принадлежит: IFP Energies Nouvelles IFPEN

L’invention concerne un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l'hydrogène et un catalyseur réjuvéné, ledit procédé d'hydrodésulfuration étant effectué à une température comprise entre 200 et 400°C, une pression totale comprise entre 1 et 3 MPa, une vitesse volumique horaire, définie comme étant le débit volumique de charge rapporté au volume de catalyseur, comprise entre 1 et 10 h-1, et un rapport volumique hydrogène/charge essence compris entre 100 et 1200 NL/L, ledit catalyseur réjuvéné étant issu d’un procédé d'hydrotraitement et comprend au moins un métal du groupe VIIl, au moins un métal du groupe VIB, un support d’oxyde et au moins un composé organique contenant de l'oxygène et/ou de l'azote et/ou du soufre.

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03-06-2022 дата публикации

METHOD FOR CAPTURING ORGANOMETALLIC IMPURITIES IN THE PRESENCE OF A CAPTURE MASS ON A MESO-MACROPOROUS SUPPORT

Номер: FR3116833A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé de captation d'impuretés organométalliques dans une charge hydrocarbonée de type essence contenant des composés soufrés et des oléfines dans lequel on met en contact ladite charge, de l’hydrogène et d’une masse de captation comprenant une phase active à base de nickel, et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ; le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 et 50% en volume du volume poreux total dudit support. Process for capturing organometallic impurities in a gasoline-type hydrocarbon charge containing sulfur compounds and olefins, in which said charge is brought into contact with hydrogen and a capture mass comprising an active phase based on nickel, and a mesoporous and macroporous alumina support comprising a bimodal distribution of mesopores and in which:- the volume of mesopores with a diameter greater than or equal to 2 nm and less than 18 nm corresponds between 10 and 30% by volume of the total pore volume of said support; - the volume of mesopores with a diameter greater than or equal to 18 nm and less than 50 nm corresponds between 30 and 50% by volume of the total porous volume of said support; the volume of the macropores with a diameter greater than or equal to 50 nm and less than 8000 nm corresponds between 30 and 50% by volume of the total pore volume of said support.

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18-10-2019 дата публикации

MASS OF CAPTATION OF ARSENIC BASED ON NICKEL SULFIDE NANOPARTICLES

Номер: FR3080048A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention décrit une masse de captation de l'arsenic et d'autres métaux lourds particulièrement adaptée au traitement de coupes essences oléfiniques et chargées en soufre telles que les essences issues du craquage catalytique. La masse de captation comprend une phase active à base de particules de sulfure de nickel de taille inférieure ou égale à 20 nm, déposées sur un support poreux choisi dans le groupe constitué par les alumines, la silice, les silices alumines, les oxydes de titane seuls ou en mélange avec l'alumine ou de la silice alumine, les oxydes de magnésium seuls ou en mélange avec l'alumine ou de la silice alumine. L'invention concerne également un procédé de mise en œuvre de ladite masse de captation. The invention describes a mass of capture of arsenic and other heavy metals particularly suitable for the treatment of olefinic gasoline sections and loaded with sulfur such as gasoline from catalytic cracking. The capture mass comprises an active phase based on nickel sulphide particles less than or equal to 20 nm in size, deposited on a porous support selected from the group consisting of aluminas, silica, silica aluminas and titanium oxides. alone or in admixture with alumina or silica alumina, magnesium oxides alone or in admixture with alumina or silica alumina. The invention also relates to a method for implementing said capture mass.

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19-06-2020 дата публикации

Process for hydrodesulfurization of olefinic gasoline cuts containing sulfur using a regenerated catalyst.

Номер: FR3090005A1
Принадлежит: IFP Energies Nouvelles IFPEN

L’invention concerne un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l'hydrogène et un catalyseur régénéré, ledit procédé étant effectué à une température comprise entre 200 et 400°C, une pression totale comprise entre 1 et 3 MPa, une vitesse volumique horaire, définie comme étant le débit volumique de charge rapporté au volume de catalyseur, comprise entre 1 et 10 h-1; et un rapport volumique hydrogène/charge essence compris entre 100 et 1200 NL/L, ledit catalyseur régénéré étant issu d’un catalyseur au moins partiellement usé issu d’un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre et comprend au moins un métal du groupe VIIl, au moins un métal du groupe VIB et un support d’oxyde. The invention relates to a process for hydrodesulfurization of an olefinic gasoline cut containing sulfur in which said gasoline cut is brought into contact with hydrogen and a regenerated catalyst, said process being carried out at a temperature between 200 and 400 °. C, a total pressure between 1 and 3 MPa, an hourly volume velocity, defined as being the volume flow rate of feed relative to the volume of catalyst, between 1 and 10 h -1; and a hydrogen / gasoline volume ratio of between 100 and 1,200 NL / L, said regenerated catalyst being obtained from an at least partially used catalyst resulting from a hydrodesulfurization process of an olefinic gasoline fraction containing sulfur and comprises at least at least one group VIIl metal, at least one group VIB metal and an oxide support.

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24-01-2014 дата публикации

PROCESS FOR THE PRODUCTION OF A LIGHT LOW SULFUR CONTENT

Номер: FR2993570A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention concerne une procédé de traitement d'une essence comprenant des dioléfines, des oléfines et des composés soufrés incluant des mercaptans. Le procédé comprend les étapes suivantes : a) on effectue une étape de démercaptisation par addition d'au moins une partie des mercaptans sur les oléfines par mise en contact de l'essence avec au moins un premier catalyseur ; b) on effectue une étape de traitement de l'essence issue de l'étape a) avec de l'hydrogène dans une colonne de distillation comprenant au moins une zone réactionnelle incluant au moins un second catalyseur. Les conditions opératoires et le second catalyseur de l'étape b) sont choisis de sorte que dans ladite colonne de distillation on réalise simultanément une séparation de l'essence issue de l'étape a) en une fraction d'essence légère et une fraction d'essence lourde et une réaction de thioéthérification et d'hydrogénation sélective de dioléfines d'une fraction de l'essence issue de l'étape a) par mise en contact avec le second catalyseur.

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03-06-2022 дата публикации

FINISHING HYDRODESULPHURIZATION PROCESS IN THE PRESENCE OF A CATALYST ON A MESO-MACROPOROUS SUPPORT

Номер: FR3116832A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé de traitement d’une charge hydrocarbonée contenant du soufre, partiellement désulfurée issue d’une étape préliminaire d’hydrodésulfuration, en présence d’un catalyseur comprenant une phase active comprenant un métal du groupe VIII et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ;- le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 et 50% en volume du volume poreux total dudit support. Process for treating a partially desulfurized sulfur-containing hydrocarbon feed resulting from a preliminary hydrodesulfurization step, in the presence of a catalyst comprising an active phase comprising a group VIII metal and a mesoporous and macroporous alumina support comprising a bimodal distribution of mesopores and in which:- the volume of mesopores with a diameter greater than or equal to 2 nm and less than 18 nm corresponds between 10 and 30% by volume of the total pore volume of said support;- the volume of mesopores with a diameter greater or equal to 18 nm and less than 50 nm corresponds between 30 and 50% by volume of the total pore volume of said support; - the volume of macropores with a diameter greater than or equal to 50 nm and less than 8000 nm corresponds between 30 and volume of the total pore volume of said support.

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15-07-2016 дата публикации

PROCESS FOR THE PRODUCTION OF HIGH PURITY PARAXYLENE FROM XYLENE CUTTING USING TWO SERIES MOBILE BED SEPARATION UNITS OPERATING IN SERIES AND TWO ISOMERIZING UNITS

Номер: FR3023840B1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention décrit un procédé de production de paraxylène à haute pureté à partir d'une coupe xylènes pouvant contenir de l'éthylbenzène et des composés en C9, ledit procédé utilisant deux unités de séparation en lit mobile simulé fonctionnant en série et deux unités d'isomérisation. The present invention describes a process for the production of high purity paraxylene from a xylene cut which may contain ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two separation units. isomerization.

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03-06-2022 дата публикации

HYDRODESULPHURIZATION PROCESS IN THE PRESENCE OF A CATALYST ON A MESO-MACROPOROUS SUPPORT

Номер: FR3116829A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé d’hydrodésulfuration d’une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l’hydrogène et un catalyseur comprenant un métal du groupe VIB, un métal du groupe VIII, et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ;- le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 à 50% en volume du volume poreux total dudit support. Process for the hydrodesulphurization of an olefinic gasoline cut containing sulfur, in which said gasoline cut is brought into contact with hydrogen and a catalyst comprising a group VIB metal, a group VIII metal, and a mesoporous alumina support and macroporous comprising a bimodal distribution of mesopores and in which:- the volume of mesopores with a diameter greater than or equal to 2 nm and less than 18 nm corresponds between 10 and 30% by volume of the total pore volume of said support;- the volume of mesopores of diameter greater than or equal to 18 nm and less than 50 nm corresponds between 30 and 50% by volume of the total pore volume of said support; - the volume of macropores with a diameter greater than or equal to 50 nm and less than 8000 nm corresponds between 50% by volume of the total pore volume of said support.

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27-05-2016 дата публикации

PROCESS FOR REMOVING THE ARSENIC FROM A HYDROCARBON LOAD

Номер: FR3007415B1
Принадлежит: IFP Energies Nouvelles IFPEN

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21-10-2016 дата публикации

PROCESS FOR SOFTENING OF SULFIDE COMPOUNDS OF AN OLEFINIC ESSENCE

Номер: FR3035117A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention concerne un procédé pour réduire la teneur en composés du type sulfure de formule R1-S-R2, avec R1 et R2 choisis parmi les radicaux méthyl (CH3) et éthyl (C2H5), d'une essence contenant des dioléfines, des mono-oléfines et du soufre, dans lequel: A) on met en contact dans un réacteur, l'essence en mélange avec une partie de la coupe essence légère recyclée de l'étape C) et de l'hydrogène et avec un catalyseur A comprenant au moins un métal du groupe VIb et au moins un métal non noble du groupe VIII déposés sur un support, de manière à produire un effluent ayant une teneur en dioléfines et une teneur en composés du type sulfure de formule R1-S-R2, avec R1 et R2 choisis parmi les radicaux méthyl (CH3) et éthyl (C2H5) plus faibles que celle de l'essence de départ; B) on envoie l'effluent issu de l'étape A) dans une colonne de fractionnement afin de séparer en tête une coupe d'essence légère contenant des hydrocarbures ayant moins de 6 atomes de carbone par molécule et en fond de la colonne une coupe essence lourde contenant des hydrocarbures ayant 6 et plus de 6 atomes de carbone par molécule; C) on recycle une partie de la coupe essence légère issue de l'étape B) dans le réacteur de l'étape A) avec un taux de recyclage compris entre 0,1 et 0,7.

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13-03-2015 дата публикации

EXTERNAL HIGH SURFACE ZEOLITHIC ADSORBENTS, PROCESS FOR THEIR PREPARATION AND USES THEREOF

Номер: FR3010402A1

La présente invention concerne des adsorbants zéolithiques à base de cristaux agglomérés de zéolithe FAU comprenant du baryum, de haute surface externe, combinant des propriétés optimales en termes de sélectivité et de résistance mécanique. Ces adsorbants trouvent des applications dans la séparation de coupes d'isomères aromatiques en C8 et notamment des xylènes, dans la séparation d'isomères de toluène substitué tels que nitrotoluène, diéthyltoluène, toluènediamine, dans la séparation des crésols, et des alcools polyhydriques, tels que les sucres. The present invention relates to zeolite zeolite agglomerated zeolite adsorbents comprising barium, with a high outer surface, combining optimum properties in terms of selectivity and mechanical strength. These adsorbents find applications in the separation of sections of C8 aromatic isomers and in particular xylenes, in the separation of isomers of substituted toluene such as nitrotoluene, diethyltoluene, toluenediamine, in the separation of cresols, and polyhydric alcohols, such as as sugars.

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30-07-2021 дата публикации

Finishing hydrodesulfurization process in the presence of a catalyst obtained by additivation

Номер: FR3106506A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé de traitement d’une charge hydrocarbonée contenant du soufre en présence d’un catalyseur comprenant une phase active comprenant au moins un métal du groupe VIII, ladite phase active ne comprenant pas de métal du groupe VIB, ladite phase active étant au moins en partie sous forme sulfurée, et un support poreux, ledit catalyseur étant préparé par un procédé comprenant une étape de mise en contact du support poreux avec un composé organique comportant de l’oxygène et/ou de l’azote et/ou du soufre.  Process for treating a hydrocarbon feedstock containing sulfur in the presence of a catalyst comprising an active phase comprising at least one metal from group VIII, said active phase not comprising a metal from group VIB, said active phase being at least in part in sulfur form, and a porous support, said catalyst being prepared by a process comprising a step of bringing the porous support into contact with an organic compound comprising oxygen and / or nitrogen and / or sulfur.

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06-06-2014 дата публикации

SIMPLE BACK-CURRENT CHROMATOGRAPHIC SEPARATION METHOD AND DEVICE FOR THE PRODUCTION OF HIGH PRODUCTIVITY METAXYLENE

Номер: FR2998808A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention décrit un procédé de séparation des xylènes en vue de la production de metaxylène à haute pureté, procédé en contre courant simulé utilisant au moins un adsorbeur avec une hauteur total cumulée (Hcu) d'adsorbant limitée, et une vitesse superficielle (Vsl) inférieure à 2 cm/s. The present invention describes a process for the separation of xylenes for the production of high purity metaxylene, a simulated countercurrent process using at least one adsorber with a cumulative overall height (Hcu) of limited adsorbent, and a superficial velocity (Vsl ) less than 2 cm / s.

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07-01-2022 дата публикации

PROCESS FOR THE PHOTOCATALYTIC REDUCTION OF CO2 USING A PHOTOCATALYST OF THE MICROPOROUS CRYSTALLIZED METAL SULPHIDE TYPE

Номер: FR3097778B1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention décrit un procédé de réduction photocatalytique du dioxyde de carbone effectué en phase liquide et/ou en phase gazeuse sous irradiation mettant en œuvre un photocatalyseur de type sulfure métallique cristallisé microporeux. Ledit procédé étant effectué en mettant en contact une charge contenant le CO2 et au moins un composé sacrificiel avec ledit photocatalyseur, puis en soumettant le photocatalyseur à un champ électrique externe et en irradiant le photocatalyseur de manière à réduire le CO2 et oxyder le composé sacrificiel de manière à produire un effluent contenant au moins en partie des molécules carbonées en C1 ou plus, différentes du CO2. The invention describes a process for the photocatalytic reduction of carbon dioxide carried out in the liquid phase and/or in the gaseous phase under irradiation using a photocatalyst of the microporous crystallized metal sulphide type. Said process being carried out by bringing a filler containing CO2 and at least one sacrificial compound into contact with said photocatalyst, then by subjecting the photocatalyst to an external electric field and by irradiating the photocatalyst so as to reduce the CO2 and oxidize the sacrificial compound by so as to produce an effluent containing at least in part carbonaceous molecules of C1 or more, different from CO2.

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03-06-2022 дата публикации

PROCESS FOR THE SELECTIVE HYDROGENATION OF A GASOLINE IN THE PRESENCE OF A CATALYST ON A MESO-MACROPOROUS SUPPORT

Номер: FR3116831A1
Принадлежит: IFP Energies Nouvelles IFPEN

Procédé d’hydrogénation sélective d'une essence comprenant des composés polyinsaturés et des composés soufrés légers dans lequel procédé on met en contact l’essence, de l’hydrogène avec un catalyseur comprenant un métal du groupe VIB, un métal du groupe VIII, et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ;- le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 à 50% en volume du volume poreux total dudit support. Process for the selective hydrogenation of a gasoline comprising polyunsaturated compounds and light sulfur compounds, in which process the gasoline, hydrogen is brought into contact with a catalyst comprising a metal from group VIB, a metal from group VIII, and a mesoporous and macroporous alumina support comprising a bimodal distribution of mesopores and in which:- the volume of mesopores with a diameter greater than or equal to 2 nm and less than 18 nm corresponds between 10 and 30% by volume of the total pore volume of said support - the volume of mesopores with a diameter greater than or equal to 18 nm and less than 50 nm corresponds between 30 and 50% by volume of the total pore volume of said support; - the volume of macropores with a diameter greater than or equal to 50 nm and less than 8000 nm corresponds between 30 to 50% by volume of the total pore volume of said support.

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30-10-2015 дата публикации

PROCESS FOR PRODUCING LOW TEMPERATURE GASOLINE IN SULFUR AND MARCAPTANS

Номер: FR3020376A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente demande concerne un procédé de traitement d'une essence contenant des composés soufrés et des oléfines comprenant les étapes suivantes : a) une étape d'hydrodésulfuration de ladite essence afin de produire un effluent appauvri en soufre consistant à faire passer ladite essence en mélange avec de l'hydrogène sur au moins un catalyseur d'hydrodésulfuration b) une étape de séparation de l'essence partiellement désulfurée, de l'hydrogène introduit en excès ainsi que de l'H2S formé lors de l'étape a) c) une étape catalytique d'adoucissement de la l'essence désulfurée issue de l'étape b) qui réalise la conversion des mercaptans résiduels en thioéthers, via une réaction d'addition sur les oléfines. Figure 1 à publier. The present application relates to a process for treating a gasoline containing sulfur compounds and olefins comprising the following steps: a) a step of hydrodesulfurizing said gasoline in order to produce a sulfur-depleted effluent comprising passing said gasoline in a mixture with hydrogen on at least one hydrodesulphurization catalyst b) a step of separating the partially desulphurized gasoline, excess hydrogen introduced as well as the H2S formed during step a) c) a catalytic step of softening the desulfurized gasoline from step b) which converts the residual mercaptans into thioethers, via an addition reaction on the olefins. Figure 1 to publish.

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03-06-2022 дата публикации

Process for the hydrodesulphurization of a gasoline cut using a catalyst containing a graphitic material characterized by NMR13C MAS spectroscopy

Номер: FR3116827A1
Принадлежит: IFP Energies Nouvelles IFPEN

L’invention concerne un procédé d'hydrodésulfuration d'une coupe essence contenant des composés soufrés et des oléfines dans lequel on met en contact ladite coupe essence, de l'hydrogène et un catalyseur, ledit catalyseur comprend un support d’oxyde, du soufre et une phase active comprenant au moins un métal du groupe VIB et au moins un métal du groupe VIII, ledit catalyseur contenant entre outre un matériau graphitique contenant du carbone et de l’hydrogène, ledit catalyseur étant caractérisé en spectroscopie RMN 13C MAS par un rapport SAromatiques/SAliphatiques de la surface de pic SAromatiques dans une gamme de déplacements chimiques de 100 à 160 ppm à la surface de pic SAliphatiques dans une gamme de déplacements chimiques de 0 à 60 ppm supérieur à 4. The invention relates to a process for the hydrodesulphurization of a gasoline cut containing sulfur compounds and olefins, in which said gasoline cut is brought into contact with hydrogen and a catalyst, said catalyst comprises an oxide support, sulfur and an active phase comprising at least one metal from group VIB and at least one metal from group VIII, said catalyst additionally containing a graphitic material containing carbon and hydrogen, said catalyst being characterized by 13C MAS NMR spectroscopy by a ratio SAromatics/SAliphatics from the peak surface SAromatics in the chemical shift range of 100 to 160 ppm at the peak surface SAliphatics in the chemical shift range from 0 to 60 ppm greater than 4.

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06-04-2018 дата публикации

PROCESS FOR TREATING A GASOLINE

Номер: FR3049955B1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente invention concerne un procédé de traitement d'une essence contenant des composés soufrés, des oléfines et des dioléfines, comprenant les étapes suivantes : a) on fractionne l'essence de manière à récupérer au moins une coupe essence intermédiaire MCN comprenant des hydrocarbures et dont la différence de température (AT) entre les points à 5% et à 95% de masse distillée est inférieure à 60°C; b) on désulfure la coupe essence intermédiaire MCN seule et en présence d'un catalyseur d'hydrodésulfuration et de l'hydrogène de manière à produire une coupe essence intermédiaire MCN partiellement désulfurée ; et c) on fractionne dans une colonne de fractionnement la coupe essence intermédiaire MCN au moins partiellement désulfurée n'ayant pas subi de traitement catalytique postérieur à l'étape b) de manière à récupérer en tête de la colonne une essence intermédiaire à basses teneurs en soufre et en mercaptans et en fond de la colonne une coupe hydrocarbures contenant des composés soufrés dont des mercaptans. The present invention relates to a process for treating a gasoline containing sulfur compounds, olefins and diolefins, comprising the following steps: a) the gasoline is fractionated so as to recover at least one MCN intermediate gasoline cut comprising hydrocarbons and whose temperature difference (AT) between the points at 5% and at 95% of distilled mass is less than 60°C; b) desulfurizing the MCN intermediate gasoline cut alone and in the presence of a hydrodesulfurization catalyst and hydrogen so as to produce a partially desulfurized MCN intermediate gasoline cut; and c) the at least partially desulfurized MCN intermediate gasoline cut which has not undergone catalytic treatment subsequent to step b) is fractionated in a fractionation column so as to recover at the top of the column an intermediate gasoline with low sulfur and mercaptans and at the bottom of the column a hydrocarbon cut containing sulfur compounds including ...

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18-06-2021 дата публикации

Mercaptan capture mass prepared by molten salt route

Номер: FR3104459A1
Принадлежит: IFP Energies Nouvelles IFPEN

L'invention décrit une masse de captation de mercaptans particulièrement adaptée au traitement de coupes essences oléfiniques et chargées en soufre telles que les essences issues du craquage catalytique. La masse de captation comprend une phase active à base de particules de métal du groupe VIII, IB ou IIB préparée par une étape de mise en contact d’un support poreux avec un sel métallique dudit métal du groupe VIII, IB ou IIB et une étape de chauffage du mélange obtenu à une température supérieure à la température de fusion dudit sel métallique. L'invention concerne également un procédé de mise en œuvre de ladite masse de captation pour l’adsorption de mercaptans. The invention describes a mercaptan capture mass which is particularly suitable for the treatment of olefinic gasoline cuts loaded with sulfur, such as gasolines obtained from catalytic cracking. The capture mass comprises an active phase based on particles of metal from group VIII, IB or IIB prepared by a step of bringing a porous support into contact with a metal salt of said metal from group VIII, IB or IIB and a step heating the mixture obtained to a temperature above the melting point of said metal salt. The invention also relates to a method of using said capture mass for the adsorption of mercaptans.

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04-10-2013 дата публикации

METHOD FOR SELECTIVELY HYDROGENATING A GASOLINE

Номер: FR2988732A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente demande concerne un procédé d'hydrogénation sélective d'une essence comprenant des composés polyinsaturés et des composés soufrés légers, ledit procédé permettant conjointement l'hydrogénation des composés polyinsaturés en composés mono-insaturés, l'alourdissement des composés soufrés légers saturés par réaction avec les composés insaturés et de maximiser l'isomérisation des composés mono insaturés comportant une double liaison C=C externe en leur isomère à double liaison C=C interne, ledit procédé mettant en oeuvre un catalyseur contenant au moins un métal du groupe Vlb et au moins un métal du groupe VIII déposés sur un support poreux dans lequel : . la teneur en poids d'oxyde de l'élément du groupe VIb est comprise entre 6 et 18% par rapport au poids du catalyseur; . la teneur en poids d'oxyde de l'élément du groupe VIII est comprise entre 4 et 12% par rapport au poids du catalyseur; . la surface spécifique du catalyseur est comprise entre 200 et 270 m /g; . la densité de l'élément du groupe VIb, exprimée comme étant le rapport entre ladite teneur en poids d'oxyde de l'élément du groupe VIb et la surface spécifique du catalyseur, est comprise entre 4 et 6.10 g/m ; . le rapport molaire entre le métal du groupe VIII et le métal du groupe VIb est compris 0,6 et 3 mol/mol. The present application relates to a process for the selective hydrogenation of a gasoline comprising polyunsaturated compounds and light sulfur compounds, said process jointly allowing the hydrogenation of the polyunsaturated compounds to monounsaturated compounds, the increase of the saturated light sulfur compounds by reaction. with the unsaturated compounds and to maximize the isomerization of the mono-unsaturated compounds having an external C = C double bond in their internal C = C double bond isomer, said process using a catalyst containing at least one metal of the group VIb and at least one group VIII metal deposited on a porous ...

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29-01-2021 дата публикации

PROCESS FOR THE PRODUCTION OF A GASOLINE WITH LOW SULFUR AND MERCAPTANS

Номер: FR3099173A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente demande concerne un procédé de traitement d'une essence contenant des composés soufrés, des oléfines et des dioléfines comprenant les étapes suivantes:a) une étape d'hydrodésulfuration en présence d’un catalyseur comprenant un support d’oxyde et une phase active comprenant un métal du groupe VIB et un métal du groupe VIII,b) une étape d'hydrodésulfuration d’au moins une partie de l’effluent de l’étape a) à un rapport débit hydrogène/charge plus élevé et à une température plus élevés que ceux de l’étape a) sans élimination de l’H2S formé en présence d’un catalyseur comprenant un support d’oxyde et une phase active constituée d’au moins un métal du groupe VIII, c) une étape de séparation de l'H2S formé dans l’effluent issu de l’étape b). The present application relates to a process for treating a gasoline containing sulfur compounds, olefins and diolefins comprising the following steps: a) a hydrodesulfurization step in the presence of a catalyst comprising an oxide support and an active phase comprising a metal from group VIB and a metal from group VIII, b) a step of hydrodesulfurization of at least part of the effluent from step a) at a higher hydrogen flow rate / feed ratio and at a higher temperature higher than those of step a) without removing the H2S formed in the presence of a catalyst comprising an oxide support and an active phase consisting of at least one metal from group VIII, c) a step of separation of the H2S formed in the effluent from step b).

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26-12-2014 дата публикации

PROCESS FOR PRODUCING LOW SULFUR AND MERCAPTAN GASOLINE

Номер: FR3007416A1
Принадлежит: IFP Energies Nouvelles IFPEN

La présente demande concerne un procédé de traitement d'une essence contenant des composés soufrés et des oléfines comprenant les étapes suivantes : α) une étape d'hydrodésulfuration de ladite essence afin de produire un effluent appauvri en soufre consistant à faire passer ladite essence en mélange avec de l'hydrogène sur au moins un catalyseur d'hydrodésulfuration b) une étape de séparation de l'essence partiellement désulfurée, de l'hydrogène introduit en excès ainsi que de l'H2S formé lors de l'étape a) c) une étape catalytique d'adoucissement de la l'essence désulfurée issue de l'étape b) qui réalise la conversion des mercaptans résiduels en thioéthers, via une réaction d'addition sur les oléfines. The present application relates to a process for treating a gasoline containing sulfur compounds and olefins, comprising the following steps: α) a step of hydrodesulphurizing said gasoline in order to produce a sulfur-depleted effluent comprising passing said gasoline in a mixture with hydrogen on at least one hydrodesulphurization catalyst b) a step of separating the partially desulphurized gasoline, excess hydrogen introduced as well as the H2S formed during step a) c) a catalytic step of softening the desulfurized gasoline from step b) which converts the residual mercaptans into thioethers, via an addition reaction on the olefins.

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