Metal oxide nanomaterials

Methods for synthesizing and using metal oxide nanomaterials are provided. The methods include heating a solution including large inverse micelles of a metal chelate in a solvent to a temperature greater than the solvent boiling point to form a dried product and calcining the dried product to form the metal oxide nanomaterial.

Molecular sieve boron ssz-113

Provided is a novel synthetic crystalline borongermanosilicate molecular sieve material, designated boron SSZ-113. The boron SSZ-113 can be synthesized using 1,3 bis(2,3-dimethyl-1H-imidazolium) propane dications as a structure directing agent. The boron SSZ-113 may be used in organic compound conversion reactions and/or sorptive processes, and in particular, in reforming reactions.

Method for manufacture of low silica MFI framework zeolite in the presence of ODSO

The present disclosure is directed to a method of manufacture of low silica zeolite having MFI framework, such as ZSM-5. A sol-gel formulation includes a water-soluble fraction of ODSO as an additional component. The resulting products include low silica zeolite having MFI framework, whereas in the absence of the ODSO, the resulting products are zeolite impurities including analcime.

Molecular sieve boron ssz-113

Provided is a novel synthetic crystalline borongermanosilicate molecular sieve material, designated boron SSZ-113. The boron SSZ-113 can be synthesized using 1,3 bis(2,3-dimethyl-IH-imidazolium) propane dications as a structure directing agent. The boron SSZ-113 may be used in organic compound conversion reactions and/or sorptive processes, and in particular, in reforming reactions.

Methods of making boronated zeolites and processes for cracking butene-containing streams

A method of making a boronated zeolite catalyst includes preparing an initial slurry comprising water, a shape selective zeolite, boric acid, and a weak acid selected from the group consisting of oxalic acid, citric acid, and oxalic acid and citric acid, hydrothermally treating the initial slurry at a temperature of from 70° C. to 90° C. to produce a hydrothermally treated slurry comprising dealuminated zeolite particles, adjusting the pH of the hydrothermally treated slurry to an intermediate pH of from 8 to 9 to produce a basic slurry, after adjusting the pH to the intermediate pH, hydrothermally treating the basic slurry at a temperature of from 70° C. to 90° C. to produce a boronated zeolite slurry, removing liquids from the boronated zeolite slurry to produce a boronated zeolite filtrate, and drying and calcining the boronated zeolite filtrate to produce the boronated zeolite catalyst.

A process for the activation of n2o in the presence of a zeolitic material having the aei-type framework structure

The present invention relates to a process for the activation of N2O, the process comprising (i) providing a zeolitic material comprising one or more transition metals, wherein the zeolitic material has the AEI-type framework structure, wherein the framework structure of the zeolitic material comprises SiO2 and Al2O3, and wherein the 29Si MAS NMR of the zeolitic material comprises a specific first peak (P1), a specific second peak (P2), a specific third peak (P3), and optionally a specific fourth peak (P4), wherein the integration of the first, second, third, and optional fourth peaks in the 29 Si MAS NMR of the zeolitic material offers a specific ratio of the integration values P1 : P2 : P3 : P4, wherein the 29 Si MAS NMR of the zeolitic material is determined on the zeolitic material which is devoid of transition metals; (ii) providing a gas stream comprising N 2 O; and (iii) contacting the gas stream with the zeolitic material at a temperature in the range of from 300 to 600 °C.

Metal oxide nanomaterials

Methods for synthesizing and using metal oxide nanomaterials are provided. The methods include heating a solution including large inverse micelles of a metal chelate in a solvent to a temperature greater than the solvent boiling point to form a dried product and calcining the dried product to form the metal oxide nanomaterial.

Metal oxide nanomaterials

Methods for synthesizing and using metal oxide nanomaterials are provided. The methods include heating a solution including large inverse micelles of a metal chelate in a solvent to a temperature greater than the solvent boiling point to form a dried product and calcining the dried product to form the metal oxide nanomaterial.

Method for the synthesis of tris(ortho-carboranyl)borane

The described process synthesizes a halide-free single-site borane compound product tris(ortho-carboranyl)borane, or BoCb3. BoCb3 has Lewis superacid properties. The compounds, BoCb3, are thermally stable, and not reactive towards oxygen, but are sensitive to water. The characteristic high fluoride ion affinity is further translated to the catalytic C—F bond activation reactions of the unactivated alkyl fluorides towards the reduction and C—C bond forming reactions with silanes, and Fridel-Crafts type reactions with arenes. The potential of the synthesized Lewis acid as a catalysis is anticipated.

Method for manufacture of low silica mfi framework zeolite in the presence of odso

The present disclosure is directed to a method of manufacture of low silica zeolite having MFI framework, such as ZSM-5. A sol-gel formulation includes a water-soluble fraction of ODSO as an additional component. The resulting products include low silica zeolite having MFI framework, whereas in the absence of the ODSO, the resulting products are zeolite impurities including analcime.

A process for the activation of n2o in the presence of a zeolitic material having the aei-type framework structure

The present invention relates to a process for the activation of N2O, the process comprising (i) providing a zeolitic material comprising one or more transition metals, wherein the zeolitic material has the AEI-type framework structure, wherein the framework structure of the zeolitic material comprises SiO2 and Al2O3, and wherein the 29Si MAS NMR of the zeolitic material comprises a specific first peak (P1), a specific second peak (P2), a specific third peak (P3), and optionally a specific fourth peak (P4), wherein the integration of the first, second, third, and optional fourth peaks in the 29 Si MAS NMR of the zeolitic material offers a specific ratio of the integration values P1 : P2 : P3 : P4, wherein the 29 Si MAS NMR of the zeolitic material is determined on the zeolitic material which is devoid of transition metals; (ii) providing a gas stream comprising N 2 O; and (iii) contacting the gas stream with the zeolitic material at a temperature in the range of from 300 to 600 °C.

Selective hydrogenation catalyst of α,β-unsaturated ketone using electronically weakly coupled 4,4′-divinylazoarylene-bridged diruthenium complex bearing two Ru(CO)(2-mercaptoquinolato)(PiPr3)2 moieties

A 4,4′-divinylazoarylene-bridged diruthenium complex bearing two Ru(CO)(2-mercaptoquinolato)(PiPr3)2 moieties, its synthesis, and its use as a catalyst.

Plasmonic vis-nir photothermal activation of olefin metathesis enabling photoresponsive materials

Plasmonic ROM polymer composites optionally comprising a latent catalyst, precursors thereof and uses thereof as a catalyst, are disclosed.

Métodos novedosos y herramientas relacionadas para la conversión de cbd en thc

La presente invención se refiere a métodos de producción de THC a partir de CBD utilizando metodología no agresiva y que resulta en rendimientos sustancialmente elevados, así como dispositivos construidos según estos métodos novedosos. Los métodos y los dispositivos son eficientes en materiales, y en ciertas realizaciones, sin disolventes. En particular, en ciertas realizaciones, estos métodos y dispositivos relacionados son adecuados para la producción comercial de THC a partir de CBD. Además, en ciertas realizaciones, la presente invención proporciona métodos de producción de THC a partir de CBD de manera que permita la sintonización para seleccionar la relación entre THC-8 y THC-9.

A material comprising geminal metal atom pairs supported on a carrier and related methods thereto

There is provided a material comprising a plurality of geminal metal atom pairs supported on a polymeric carrier, and a method of preparing said material. In a particular embodiment, the material comprises a plurality of copper atom pairs supported on a polymeric carbon nitride (PCN) carrier. There is also provided a catalyst comprising said material, and a method of catalyzing coupling reactions.

炭化水素油の水素化処理触媒及び該触媒を用いた水素化処理方法

【課題】 炭化水素を、硫黄分１０質量ｐｐｍ以下、窒素分３質量ｐｐｍ以下という極めて高い深度まで水素化処理を達成することが可能な水素化処理触媒を提供する。 【解決手段】 少なくともアルミニウム、リンおよびケイ素の酸化物より構成される無機多孔質担体に、活性金属として周期律表第８族金属の少なくとも１種、周期律表第６族金属の少なくとも１種およびリンを担持した触媒であって、無機多孔質担体の ３１ Ｐ−ＣＰＭＡＳ−ＮＭＲにおけるリンの化学シフト値が０〜−２０ｐｐｍの範囲にピークを持つことを特徴とする炭化水素油の水素化処理触媒。 【選択図】なし

Method for preparing 3,3',4,4'-dicyclohexyltetracarboxylic acid and method for treating acidic wastewater

The disclosure relates to the technical field of organic synthesis, and provides a method for preparing 3,3',4,4'-dicyclohexyltetracarboxylic acid and a method for treating an acidic wastewater. In the preparation method according to the present disclosure, a ruthenium-rhodium mixed catalyst is used to catalyze the hydrogenation reduction reaction, which improves the selectivity of the reaction and reduces the generation of isomers, thereby reducing the generation of by-products and increasing the purity of 3,3',4,4'-dicyclohexyltetracarboxylic acid. The results of the examples show that the purity of 3,3',4,4'-dicyclohexyltetracarboxylic acid prepared by the method according to the present disclosure is not less than 99.62 %.

一种3,3′,4,4′-二环己基四甲酸的制备方法、酸性废水的处理方法

本发明属于有机合成技术领域，提供了一种3,3',4,4'‑二环己基四甲酸的制备方法、酸性废水的处理方法。本发明提供的制备方法，以钌铑混合催化剂催化加氢还原反应，提高了反应的选择性，减少了异构体的产生，从而减少了副产物的生成，提高了3,3',4,4'‑二环己基四甲酸的纯度。实施例的数据表明：利用本发明提供的方法制备3,3',4,4'‑二环己基四甲酸，纯度≥99.62％。

유기 광촉매 및 이의 제조방법

본 기술은 유기 광촉매(organic photocatalysts; OPC) 및 이의 제조방법에 관한 것으로, 더욱 상세하게는 가시광에 의해 반응이 일어나는 유기촉매 원자 이동 라디칼 중합(organocatalyzed atom transfer radical polymerization; O-ATRP), 유기촉매 라프트 중합(organocatalyzed reversible addition-fragmentation chain transfer; O-RAFT) 또는 유기촉매 디할로겐화 반응에 적용될 수 있는 유기 광촉매 및 이의 제조방법에 관한 것이다. 상기 촉매는 종래의 유기 혹은 유기금속 촉매보다 훨씬 더 작은 양만 사용하여 높은 수율로 고분자 중합 및 유기반응을 진행할 수 있으며, 촉매 적재량이 극히 작아 부가적인 정제공정 없이도 중합된 고분자 및 유기물을 바로 사용할 수 있도록 하는바, 위의 언급된 반응에 효과적으로 이용될 수 있을 것으로 기대된다.

Method for stereospecific cycloaddition reaction

Metal-organic frameworks (MOFs) may have Zn(II), Pb(II), and/or Cd(II) as a central metal ion, a 4,4′-bipyridylethylene (bpe) ligand as a first ligand; and fumaric acid (fum) and/or oxalic acid (ox) as a second ligand, wherein the 4,4′-bipyridylethylene ligands are stacked in the MOF, and wherein a distance between two consecutive 4,4′-bipyridylethylene ligands is less than 5 Å. Cycloadditions, particularly photoinduced [2+2] cycloadditions may be catalyzed by such MOFs, and/or the conversion of photoinduced [2+2] cycloadditions in inventive MOFs may be increased by mechanical force, such as by grinding.

مركبات زيوليت معدَّلة تتضمن شطور فلزية عضوية محتوية على أمين وطرق تكوينها

يتعلق الاختراع الحالي بمركبات زيوليت معدَّلة modified zeolites وطرق لتكوين مركبات الزيوليت المعدَّلة. في واحد أو أكثر من التجسيدات التي يتم الكشف عنها في هذه الوثيقة، يتضمن الزيوليت المُعدَّل إطار مجهري المسام microporous framework يتضمن مجموعة من المسام المجهرية micropores التي لها أقطار أقل من أو تساوي 2 نانو متر وشطور فلزية عضوية organometallic moieties يرتبط كل منها بذرات الأكسجين الرابطة bridging oxygen atoms. يتضمن الإطار مجهري المسام على الأقل ذرات السيليكون silicon atoms وذرات الأكسجين oxygen atoms. تتضمن الشطور الفلزية العضوية ذرة فلزية metal atom وبنية حلقية ring structure تتضمن الذرة الفلزية، ذرة النيتروجين nitrogen atom، وواحدة أو أكثر من ذرات الكربون carbon atoms. يمكن أن ترتبط الذرة الفلزية بذرة أكسجين رابطة، وحيث تربط ذرة الأكسجين الرابطة الذرة الفلزية بالشطر الفلزي العضوي وذرة السيليكون بالإطار مجهري المسام. الشكل 1

Modified zeolites that include zirconium-containing organometallic moieties and methods for making such

Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a zeolite may include a microporous framework comprising a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a zirconium atom. The zirconium atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the zirconium atom of the organometallic moiety and a silicon atom of the microporous framework.

مركبات زيوليت معالجة بمجموعة وظيفية من أمين وطرق تكوينها

يكشف الاختراع الحالي عن مركبات زيوليت معالجة بمجموعة وظيفية من أمين amine functionalized zeolites وطرق لتكوين مركبات الزيوليت المعالجة بمجموعة وظيفية من أمين. في واحد أو أكثر من التجسيدات التي يتم الكشف عنها في هذه الوثيقة، يمكن أن يتضمن زيوليت معالج بمجموعة وظيفية من أمين amine functionalized zeolite إطار مجهري المسام microporous framework يتضمن مجموعة من المسام المجهرية micropores التي لها أقطار أقل من أو تساوي 2 نانو متر. يمكن أن يتضمن الإطار مجهري المسام على الأقل ذرات السيليكون silicon atoms وذرات الأكسجين oxygen atoms. يمكن أن يتضمن الزيوليت المعالج بمجموعة وظيفية من أمين كذلك مجموعة من المسام المتوسطة التي لها أقطار أكبر من 2 نانو متر وأقل من أو تساوي 50 نانو متر وواحدة أو أكثر من المجموعات الوظيفية الطرفية المعزولة من الأمين الأولي المرتبطة بذرات السيليكون بالإطار مجهري المسام أو مجموعات سيلازان الوظيفية silazane functionalities، حيث تربط ذرة النيتروجين nitrogen atom لسيلازان silazane اثنتين من ذرات السيليكون بالإطار مجهري المسام. الشكل 1

Carbon dioxide adsorbent

Disclosed is a modified carbonaceous material, which includes hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks and mainly existing at edges of the layered carbonaceous structure. Accordingly, the close proximity of acid moiety at the edges can resemble the center of hydrolysis enzymes, resulting in enhancement of hydrolytic efficiency. Additionally, the acid-functionalized carbonaceous material can also be applied in the capture and storage of carbon dioxide due to its unexpectedly higher capacity for CO2 molecular.

将费托法的原料加氢异构化和加氢裂化来制备中间馏出物的方法

本发明涉及一种使用加氢裂化/加氢异构化催化剂由通过费托合成产生的链烷烃原料制备中间馏出物的方法，所述催化剂包含至少一种选自元素周期表第VIII族的贵金属的加氢/脱氧元素、含有高于5重量%且低于或等于95重量%的量的二氧化硅(SiO 2 )的二氧化硅-氧化铝基非沸石载体；该催化剂平均孔径为20-140，通过水银孔隙度测定法测定；总孔体积为0.1ml/g-0.6ml/g，通过水银孔隙度测定法测定；总孔体积为0.1ml/g-0.6ml/g，通过氮气孔隙度测定法测定；BET比表面为100-550m 2 /g；直径高于140的孔中所含孔体积小于0.1ml/g，通过水银孔隙度测定法测定；直径高于160的孔中所含孔体积小于0.1ml/g，通过水银孔隙度测定法测定；直径高于200的孔中所含孔体积小于0.1ml/g，通过水银孔隙度测定法测定；直径高于500的孔中所含孔体积小于0.01ml/g，通过水银孔隙度测定法测定；和X-射线衍射图，所述衍射图至少包含至少一种选自α、ρ、χ、η、γ、κ、θ和δ氧化铝的过渡型氧化铝的主要谱线特征。

Improved zeolites and molecular sieves and the use thereof

This invention relates to a process for producing a zeolite wherein said process includes removal of an organic templating agent, the improvement comprising: removing said templating agent at a temperature of no greater than 550°C and under conditions wherein after the removal of the templating agent, said zeolite has an AAI of at least 1.2 and is selected from the group consisting of zeolite Beta, TEA-mordenite, and TEA-ZSM-12.

Modified carbonaceous material, carbon dioxide adsorbent and method for cellulose hydrolysis using the same

Disclosed is a modified carbonaceous material, which includes hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks and mainly existing at edges of the layered carbonaceous structure. Accordingly, the close proximity of acid moiety at the edges can resemble the center of hydrolysis enzymes, resulting in enhancement of hydrolytic efficiency. Additionally, the acid-functionalized carbonaceous material can also be applied in the capture and storage of carbon dioxide due to its unexpectedly higher capacity for CO2 molecular.

一种3,3’,4,4’-二环己基四甲酸的制备方法、酸性废水的处理方法

本发明属于有机合成技术领域，提供了一种3,3',4,4'‑二环己基四甲酸的制备方法、酸性废水的处理方法。本发明提供的制备方法，以钌铑混合催化剂催化加氢还原反应，提高了反应的选择性，减少了异构体的产生，从而减少了副产物的生成，提高了3,3',4,4'‑二环己基四甲酸的纯度。实施例的数据表明：利用本发明提供的方法制备3,3',4,4'‑二环己基四甲酸，纯度≥99.62％。

用于将cbd转化为thc的新颖方法和相关工具

本发明涉及利用非苛刻的研究方法从CBD生产THC并导致产率显著增加的方法，以及建立在这些新颖的方法之上的装置。这些方法和装置是材料高效的，并且在某些实施例中是无溶剂的。特别地，在某些实施例中，这些方法和相关装置适用于从CBD商业生产THC。此外，在某些实施例中，本发明提供了以提供选择THC‑8与THC‑9的比率的可调性的方式从CBD生产THC的方法。

高硅含量形式的沸石rho

本发明涉及组合物，其可以包含具有RHO拓扑结构的Rho沸石，其具有大于或等于8的Si:B比率或Si:Al比率。制备这种组合物的方法可以包括在作为结构定向剂的N,2‑二甲基苯并咪唑的C 4 ‑C 6 双季化物的存在下将含水反应混合物加热到至少75℃的温度以制备Rho沸石，其中含水反应混合物具有原子Si与原子B之间的摩尔比率为约4至约50，或原子Si与原子Al之间的摩尔比率为约4至约50。

稳定的小孔沸石

本发明提供了具有八个四面体原子的最大孔径的结晶铝硅酸盐沸石，其中沸石具有小于2mmol/g的总质子含量。所述沸石可以包含按相应的氧化物计算并基于所述沸石的总重量为0.1重量％至10重量％的至少一种过渡金属。所述沸石可以还包含按相应的金属计算并基于所述沸石的总重量浓度为0重量％至2重量％的至少一种碱金属或碱土金属。沸石可用于从汽车燃烧废气中去除NO x 。

稳定的cha沸石

本发明提供了具有CHA骨架类型的水热稳定的结晶铝硅酸盐沸石，其中所述沸石具有小于2mmol/g的总质子含量。所述沸石可以包含按相应的氧化物计算并基于所述沸石的总重量为0.1重量％至10重量％的至少一种过渡金属。所述沸石可以还包含按相应的金属计算并基于所述沸石的总重量浓度为0重量％至2重量％的至少一种碱金属或碱土金属。本发明还提供了用于制备所述具有CHA骨架类型的铝硅酸盐沸石的一锅合成方法。将包含四乙基铵化合物、二氧化硅源、至少一种碱金属氢氧化物或碱土金属氢氧化物、八面沸石骨架类型的沸石和铜‑四亚乙基戊胺的水性反应混合物混合、匀化和加热，并且最后将产物回收。具有CHA骨架类型的新型水热稳定的沸石适合作为催化活性材料，用于通过与作为还原剂的NH 3 反应来选择性催化还原氮氧化物(NH 3 ‑SCR)，其中使用所述水热稳定的沸石。

包含Ti-MWW沸石并具有特定的路易斯酸度的模制品

本发明涉及包含具有骨架类型MWW的沸石材料的模制品，其中所述骨架结构包含Ti、Si和O，其中所述沸石材料还包含Zn和碱土金属M，所述模制品还包含粘合剂，其中所述模制品显示出特定的路易斯酸度。此外，本发明涉及所述模制品的制备方法及其用途。

Cha沸石材料和相关合成方法

本发明提供了一种合成具有CHA结晶骨架的沸石的方法，所述方法包含：形成反应混合物，所述反应混合物包括包含具有FAU结晶骨架的沸石的氧化铝源、二氧化硅源和有机结构导向剂，所述反应混合物的M/Si+R/Si组合摩尔比高于摩尔比OH ‑ /Si，其中M是碱金属的摩尔数，并且R是有机结构导向剂的摩尔数；以及使所述反应混合物结晶以形成具有CHA结晶骨架的产物沸石，其中所述产物沸石的中孔表面积(MSA)小于约25m 2 /g。本发明还包含使用所述产物沸石制成的催化剂制品、包含所述催化剂制品的废气处理系统以及使用所述催化剂制品处理废气的方法。

用于羧酸酯的酯交换的方法

本发明涉及用于通过使用催化剂的多相催化进行羧酸酯的酯交换的方法，所述催化剂可通过经表面反应的碳酸钙的煅烧获得。本发明还涉及所述方法在生产燃料或燃料组分(例如生物柴油)中的用途。本发明的另外方面涉及可通过本发明的方法获得的经酯交换的酯及其作为燃料或燃料组分的用途。本发明的又一方面涉及相应的酯交换催化剂及其在酯交换反应中的用途。

用于制造仲脂肪醇、内烯烃和内烯烃磺酸酯的方法

披露了一种用于制造仲脂肪醇的方法P 1 ，所述方法P 1 包括通过包括呈液相的脂肪酸等在金属化合物作为催化剂的情况下在反应介质中的脱羧基酮化反应的方法P 0 合成内酮K1，其中将与该内酮K 1 相同或类似的呈液态的酮K 2 引入该反应介质中，并且使该内酮K 1 在氢气作为氢化剂的情况下经受氢化反应以形成该仲脂肪醇。披露了通过该方法P 1 制造的仲脂肪醇用于制造内烯烃或内烯烃磺酸酯的用途。

Single step process for the synthesis of furfuryl ethyl ether

The present invention provides a single step process for the synthesis of furfuryl ethyl ether comprises refluxing the reaction mixture of furfuryl alcohol, ethanol and catalyst at temperature in the range of 80 to 120° C. for the period in the range of 3 to 7 hrs to afford furfuryl ethyl ether. The catalyst used in present invention is Zr incorporated SBA-15. Further, the conversion of furfuryl alcohol is in the range of 60 to 90%. The selectivity of reaction towards furfuryl ethyl ether is in the range of 85 to 95%.

制备具有rth型骨架结构的沸石材料的方法

一种制备具有RTH型骨架结构且具有包含四价元素Y、三价元素X和氧的骨架结构的沸石材料的方法，所述方法包括(i)制备包含具有骨架结构类型FAU且具有包含四价元素Y、三价元素X和氧的骨架结构的沸石材料、水、碱源和包含含N‑甲基‑2,6‑二甲基吡啶鎓阳离子的化合物的RTH型骨架结构导向剂的合成混合物；(ii)使(i)中获得的混合物经历水热结晶条件，从而获得具有RTH型骨架结构的沸石材料。

新型沸石

本发明的目的在于提供具有新型结构的AFX型沸石。一种AFX型沸石，其特征在于，(004)面的晶面间距d为 以上且 以下，且二氧化硅相对于氧化铝的摩尔比为10以上且32以下。这种AFX型沸石可以通过具备将如下组合物以160℃以上进行结晶化的结晶化工序的制造方法来制造：该组合物包含硅源、铝源、1,3‑二(1‑金刚烷基)咪唑鎓阳离子及碱金属，至少为氢氧根离子相对于二氧化硅的摩尔比低于0.25或二氧化硅相对于氧化铝的摩尔比为27以下中的任一者，且1,3‑二(1‑金刚烷基)咪唑鎓阳离子相对于二氧化硅的摩尔比低于0.20。

核壳结构NiSe2@NC电催化材料及其制备方法和用途

本发明提供了一种核壳结构NiSe 2 @NC电催化材料，其通式为NiSe 2 @NC。本发明还提供了该催化材料的制备方法和应用，采用水合肼为还原剂，硒粉为硒源，金属有机框架物为前驱物，通过水热反应对混合配体的金属有机框架物进行选择性硒化。再通过一步管式炉煅烧反应，从而制备出一系列具有可调节的氮掺杂的碳包覆的立方相核壳二硒化镍正八面体材料。通过调节金属有机框架物中混合配体的种类，获得了具有不同吡啶氮含量掺杂的碳包覆的二硒化镍复合材料，再经相应的电化学测试以及理论计算证明，电催化活性与吡啶氮的含量具有很强的相关性。

Método y dispositivo relacionado para la conversión de CBD en THC

La presente invención se refiere a métodos para producir THC a partir de CBD utilizando una metodología no agresiva y que dan como resultado rendimientos sustancialmente mayores, así como a dispositivos basados en estos nuevos métodos. Los métodos y dispositivos son eficientes en el uso de materiales y, en ciertas realizaciones, no utilizan solventes. En particular, en ciertas realizaciones, estos métodos y dispositivos relacionados son adecuados para la producción comercial de THC a partir de CBD. Además, en ciertas realizaciones, la presente invención proporciona métodos para producir THC a partir de CBD de una manera que permite ajustar la proporción de THC-8 a THC-9. (Traducción automática con Google Translate, sin valor legal)

Mww型沸石及其制造方法、以及裂化催化剂

本发明提供在制成质子型时，布朗斯台德酸位点量多、最适于异丙苯的裂化催化剂的MWW型沸石及其制造方法、以及其用途。本发明提供一种MWW型沸石，其在以铵型的形式进行测定的 27 Al MAS NMR中，源自4配位的铝的峰的强度(B)相对于源自6配位的铝的峰的强度(A)之比(B/A)为2以上。本发明还提供一种MWW型沸石的制造方法，其具有在不含有机结构导向剂的MWW型沸石的晶种以及如下反应混合物的共存下进行水热合成的工序，述反应混合物包含二氧化硅源、氧化铝源、碱源、有机结构导向剂和水，前述反应混合物满足下述的摩尔比。X/SiO 2 <0.15(其中，X表示有机结构导向剂的摩尔数)。

金属取代的β型沸石及其制造方法

提供：催化性能比以往优异的金属取代的β型沸石及其制造方法。本发明提供如下金属取代的β型沸石：其是将属于碱金属型且不使用有机结构导向剂而制造的β型沸石通过铵离子进行离子交换、进而利用滤饼法通过铜离子或铁(II)离子进行离子交换而得到的金属取代的β型沸石。另外，本发明提供如下金属取代的β型沸石：其为通过铜离子或铁(II)离子进行离子交换而得到的金属取代的β型沸石，其中，在刚制成的状态下，用氨红外‑质谱升温脱附法测定布朗斯台德酸中心的量和路易斯酸中心的量时，路易斯酸中心的量多于布朗斯台德酸中心的量。

稀土元素骨架置换沸石及其制造方法、以及使用了它们的NOx吸附材料、选择性还原催化剂以及汽车废气催化剂

本发明提供NOx吸附量更高的、新型的稀土元素骨架置换沸石及其制造方法、以及使用了它们的NOx吸附构件以及汽车废气用催化剂等。稀土元素骨架置换沸石，其特征在于，至少含有沸石、以及选自由Ce、La、Nd以及Pr组成的组中的至少1种以上的稀土元素，并且，前述稀土元素的含有比例相对于总量而言合计为1～15质量％且形成前述沸石的骨架的Al原子及/或Si原子的一部分被前述稀土元素置换。

New surface organometallic chemistry processes for improved nh3-scr catalysts

The present invention relates to a process for preparing a catalyst material, comprising the steps of: (a) providing a support material having surface hydroxyl (OH) groups, wherein the support material is ceria (CeO 2 ), zirconia (ZrO 2 ) or a combination thereof; (b) reacting the support material having surface hydroxyl (OH) groups of step (a) with a metal precursor compound containing a metal element from Group 5 (V, Nb, Ta) or Group 6 (Cr, Mo, W) in order to graft a metal element from Group 5 or Group 6 to the support material, wherein said metal precursor compound has at least one alkoxide group bound to metal atom M, the alkoxide group having a hydrogen atom bound to a β carbon atom adjacent to the α carbon atom bound to the oxygen atom linked to metal atom M in an M-O-C-C-H series of atoms; (c) heating the product obtained in step (b) under an inert atmosphere at a temperature of at least 200°C and at most 400°C. The present invention further relates to a catalyst material as may be obtained by the process set out above, and the use of the catalyst material as an ammonia selective catalytic reduction (NH 3 -SCR) catalyst for nitrogen oxides (NOx) reduction.

由羟甲基糠醛制备2,5-呋喃二甲酸二甲酯的方法

本发明的实施方式提供了用于制备2,5‑呋喃二甲酸二甲酯(FDMC)的方法，所述方法包括在金(Au)纳米颗粒负载型催化剂的存在下，使包含5‑羟甲基糠醛(HMF)、空气和醇溶剂的反应混合物经受氧化酯化，来制备2,5‑呋喃二甲酸二甲酯(FDMC)，其中，金(Au)纳米颗粒负载型催化剂包含载体和负载在该载体上的金(Au)纳米颗粒。

Catalyst for hydrogenation reaction and method for producing same

A catalyst for a hydrogenation reaction including: a polymer support; and a catalytic component supported on the polymer support. The polymer support includes a repeating unit represented by Formula 1.

Method for transesterification of carboxylic acid esters

The present invention relates to a method for transesterification of carboxylic acid esters by heterogeneous catalysis using a catalyst that is obtainable by calcination of surface-reacted calcium carbonate. The invention further relates to the use of said method in the production of fuel or fuel components, such as biodiesel. Further aspects of the present invention relate to the transesterified ester obtainable by the inventive method and to its use as fuel or as fuel component. Still another aspect of the present invention relates to a corresponding transesterification catalyst and to its use in transesterification reactions.

Modified carbonaceous material, carbon dioxide adsorbent and method for cellulose hydrolysis using the same

Disclosed is a modified carbonaceous material, which includes hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks and mainly existing at edges of the layered carbonaceous structure. Accordingly, the close proximity of acid moiety at the edges can resemble the center of hydrolysis enzymes, resulting in enhancement of hydrolytic efficiency. Additionally, the acid-functionalized carbonaceous material can also be applied in the capture and storage of carbon dioxide due to its unexpectedly higher capacity for CO2 molecular.

Aei型铝硅酸盐沸石、催化剂和废气处理方法

提供了AEI型铝硅酸盐沸石、催化剂和废气处理方法，具体来说，提供了低成本、高性能的AEI型铝硅酸盐沸石，其不使用昂贵的Y型沸石作为原料并且不使用危险的氢氟酸。所述AEI型铝硅酸盐沸石的酸量为1.2mmol/g以上且3.0mmol/g以下，且通过XRF求得的Si/Al比为6.5以下。

ベータ型ゼオライト及びそれを含む触媒

対をなすヘテロ原子を有するゼオライト触媒及びその方法

本開示は、エージング耐久性及び改善された触媒活性を有するゼオライト触媒に関する。例えば、ゼオライト触媒は、特定のアルミニウム分布、例えば、ゼオライト構造中の２つの骨格アルミニウム原子の、骨格中の第３の最近接（３ＮＮ）相対位置における位置決めを含む。ゼオライト触媒は、２つの四面体配位Ｓｉ部位によって分離されている２つの四面体配位Ａｌ部位を有する。本開示はまた、それらの特徴付け及び使用のためのプロセス及び方法も対象とする。

借助无溶剂沸石间转化制备沸石材料的方法

本发明涉及制备其骨架结构中包含YO 2 和X 2 O 3 的沸石材料的方法，其中Y表示四价元素且X表示三价元素，其中所述方法包括：(1)制备包含一种或多种结构导向剂、晶种和第一沸石材料的混合物，所述第一沸石材料在其骨架结构中包含YO 2 和X 2 O 3 ，其中第一沸石材料具有选自FAU‑、GIS‑、MOR‑和LTA‑型骨架结构，包括其两种或更多种的混合物的骨架结构；(2)将(1)中所得混合物加热以得到其骨架结构中包含YO 2 和X 2 O 3 的第二沸石材料，其中(2)中所得第二沸石材料具有与(1)中所得混合物中所含第一沸石材料不同类型的骨架结构；其中在(1)中制备并在(2)中加热的混合物包含基于第一沸石材料的骨架结构中的100重量％YO 2 为1000重量％或更少的H 2 O，以及根据本发明方法可得到和/或得到的沸石材料及其用途。

Catalyst for hydrogenation reaction and method for manufacturing the same

A method for manufacturing a catalyst for a hydrogenation reaction, the method including: preparing a polymer support including a repeating unit of Formula 1, and supporting a catalytic component on the polymer support: wherein in Formula 1,

制备环氧丙烷的方法

本发明涉及一种制备环氧丙烷的方法，包括(i)提供包含丙烯、过氧化氢或过氧化氢的源、水和有机溶剂的物流；(ii)将(i)中提供的液体进料物流送入包含含有钛沸石的环氧化催化剂的环氧化区中，并使液体进料物流在环氧化区中经受环氧化反应条件，获得包含丙烯、环氧丙烷、水和有机溶剂的反应混合物；(iii)从环氧化区中移出流出物流，所述流出物流包含环氧丙烷、水、有机溶剂和丙烯；(iv)通过蒸馏从流出物流中分离出丙烯，包括(iv.1)使流出物流在蒸馏装置中经受蒸馏条件，获得与经受蒸馏条件的流出物流相比富含丙烯的气态顶部物流S0，和与经受蒸馏条件的流出物流相比富含环氧丙烷、水和有机溶剂的液体底部物流S01；(iv.2)将物流S0的冷凝部分返回到蒸馏装置的上部。

Tin-containing zeolitic material having an MWW-type framework structure

A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.

Catalyst for producing hydrogen and method for producing hydrogen

A metal-supporting catalyst for decomposing ammonia into hydrogen and nitrogen. The catalyst shows a high performance with a low cost and being advantageous from the viewpoint of resources, and an efficient method for producing hydrogen using the catalyst. The catalyst catalytically decomposes ammonia gas to generate hydrogen. The hydrogen generation catalyst includes, as a support, a mayenite type compound having oxygen ions enclosed therein or a mayenite type compound having 10 15 cm −3 or more of conduction electrons or hydrogen anions enclosed therein, and metal grains for decomposing ammonia are supported on the surface of the support. Hydrogen is produced by continuously supplying 0.1-100 vol % of ammonia gas to a catalyst layer that comprises the aforesaid catalyst, and reacting the same at a reaction pressure of 0.01-1.0 MPa, at a reaction temperature of 300-800° C. and at a weight hourly space velocity (WHSV) of 500/mlg −1 h −1 or higher.

LEV-type zeolite and production method therefor

The present invention provides an LEV-type zeolite which is less likely than a conventional LEV-type zeolite to have reduced zeolite crystallinity even when exposed to high-temperature, high-humidity environments, particularly high-temperature, high-humidity environments of at least 700° C. The LEV-type zeolite has a molar ratio of silica to alumina of at least 20 and a molar ratio of silanol groups to silicon of at most 1.5×10 −2 . Such an LEV-type zeolite preferably has a silanol volume of at most 1.5×10 20 /g.

Solid-supported palladium(II) complex for catalyzing Mizoroki-Heck coupling reactions and a method thereof

A solid-supported palladium(II) complex which catalyzes the Mizoroki-Heck coupling reaction efficiently and a method of employing the solid-supported palladium(II) complex to synthesize cinnamic acid and derivatives thereof. The solid-supported palladium(II) complex is also stable and can be recycled without significantly losing catalytic activity.

Stabilized metal-exchanged SAPO material

Described are catalyst materials and catalytic articles comprising a metal exchanged SAPO material comprising a plurality of substitutional sites consisting essentially of Si(4Al) sites and substantially free of Si(0Al) sites. The materials and catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.

Hydrocracking process using a zeolite catalyst containing two distinct hydrogenating functions

Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g −1 , and a crystal parameter a 0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

Mesoporous composite of molecular sieves for hydrocracking of heavy crude oils and residues

A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204° C. to 538° C., decrease the production of the heavy fraction (>538° C.), and increase the production of gasoline fraction (<204° C.). The feedstock to be processed in the last bed contains low amounts of metals and is lighter than the feedstock that is fed to the first catalytic bed.

加氢处理催化剂和用于制备所述催化剂的方法

本发明属于非均相催化的领域。特别地，本发明涉及用于制备可有利地用于烃的加氢处理方法例如加氢脱硫、加氢脱氮、加氢脱芳构化方法的的催化剂的方法。更特别地，本发明涉及用于获得所述催化剂的方法，所述催化剂包含以下的混合氧化物：镍，铝，钼，和钨，和任选地选自Zn、Mn、Cd及其混合物的过渡金属Me，有机组分C，以及可能的无机粘合剂B。所述混合氧化物包含与黑钨矿同构的假晶相和非晶相。本发明还涉及所述加氢处理催化剂和其中使用所述催化剂的加氢处理方法。

Metal modified y zeolite, its preparation and use

The present invention relates to a metal modified Y zeolite, its preparation and use. Said zeolite contains 1-15 wt % of IVB group metal as oxide and is characterized in that the ratio of the zeolite surface's IVB group metal content to the zeolite interior's IVB group metal content is not higher than 0.2; and/or the ratio of the distorted tetrahedral-coordinated framework aluminum to the tetrahedral-coordinated framework aluminum in the zeolite lattice structure is (0.1-0.8):1.

具有增强稳定性的高温层化混合金属氧化物材料

制备混合金属氧化物颗粒(ii)的方法，所述颗粒包含含有M、Al和C的混合金属氧化物相，所述方法通过在400℃至800℃的反应温度下加热金刚烷嵌入层化双氢氧化物(LDH)颗粒(i)以形成混合金属氧化物颗粒来进行，(i)具有通式[M(1‑x)Al(x)(OH)2]A(x).m H2O，其中x为0.14至0.33，m为0.33至0.50，M选自Mg、Ca、Co、Ni、Cu或Zn，并且A为金刚烷羧酸盐，并且纵横比，即颗粒的宽度/厚度大于100。进一步提供MMO颗粒(ii)本身以及通过与(ii)接触通过吸附从工艺流中除去成分的方法([优选CO2或有毒离子，尤其磷酸盐、砷酸盐、铬酸盐、溴化物、碘化物和硫化物。

高纵横比层状双氢氧化物材料和其制备方法

实施例涉及插入有金刚烷的层状双氢氧化物(LDH)颗粒和制备插入有金刚烷的LDH颗粒的方法。所述方法包含向水溶液中加入第一前体和第二前体以形成初始混合物，其中所述第一前体是Al(OH) 3 或Al 2 O 3 ，所述第二前体是氢氧化物M(OH) 2 或氧化物MO，其中M是氧化态为+2的金属；且所述初始混合物的M/Al摩尔比为从1至5。所述方法还包含向所述初始混合物中加入一定量的金刚烷以形成Al/金刚烷摩尔比为从0.5至2的反应混合物；和加热所述反应混合物以制备插入有金刚烷的LDH颗粒，其中所述插入有金刚烷的LDH颗粒具有大于100的纵横比。

Methods to produce molecular sieves with LTA topology and compositions derived therefrom

The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): where substituents R 1 to R 9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H 2 O 2 .

Stabilized metal-exchanged SAPO material

Described are catalyst materials and catalytic articles comprising a metal exchanged SAPO material comprising a plurality of substitutional sites consisting essentially of Si(4Al) sites and substantially free of Si(0Al) sites. The materials and catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.

Delamination of borosilicate layered zeolite

Provided is a surfactant-free, single-step synthesis of delaminated aluminosilicate zeolites. The process comprises the step of heating a borosilicate zeolite precursor in a metal salt solution, e.g., an aluminum nitrate solution, zinc nitrate solution or manganese nitrate solution. The delaminated aluminosilicate zeolite product is then recovered from the solution.

Catalyst composition

The present invention provides an improved catalyst and a method for its manufacture. The catalyst comprises an acidic, porous crystalline material and has a Proton Density Index of greater than about 1.0, for example from greater than 1.0 to about 2.0, e.g. from about 1.01 to about 1.85. This catalyst may be used to effect conversion in chemical reactions, and is particularly useful in a process for selectively producing a monoalkylated aromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under at least partial liquid phase conditions. The acidic, porous crystalline material of the catalyst may comprise an acidic, crystalline molecular sieve having the structure of zeolite Beta, an MWW structure type material, e.g. MCM-22, MCM-36, MCM-49 MCM-56, or a mixture thereof.

Process for preparing propylene oxide

A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt; (ii) passing the feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one potassium salt, optionally propene, and optionally pane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one potassium salt, optionally propene, and optionally propane.

Process for preparing propylene oxide

A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

Zeolite SSZ-57 having enhanced large pore selectvity

The present invention is directed to an alumino-borosilicate SSZ-57 zeolite having enhanced large pore selectivity. The alumino-borosilicate SSZ-57 zeolite of the present invention is characterized as having substantially all of its aluminum atoms located within regions of the zeolite structure which form the 12 ring channels.

Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in a non-aqueous solution to affect delamination of a layered zeolite precursor, generally comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

Molecular sieve SSZ-90, its synthesis and use

A new crystalline zinc (silico)aluminophosphate molecular sieve designated SSZ-90 is disclosed. SSZ-90 is isostructural with the DFO framework type and is synthesized using an ionic liquid as both the solvent and the structure directing agent. The ionic liquid [Q + A − ] comprises a cation (Q + ) selected from the group consisting of 1,3-diisopropylimidazolium, 1,3-diisobutylimidazolium, and 1-isopropyl-3-isobutylimidazolium and an anion (A − ) which is not detrimental to the formation of the molecular sieve.

Silicate-coated MFI-type zeolite, method of producing the same, and method of producing p-xylene using the same

A silicate-coated MFI-type zeolite is obtained by coating an MFI-type zeolite with a silicate, and a peak area ratio b/a of a peak b at 2θ=8.4 to 9.7° to a peak a at 2θ=7.0 to 8.4° in an X-ray diffraction spectrum is 1 or more, and a pKa value measured by a Hammett indicator is +3.3 or more.

Magnetic catalyst composition for hydroformylation of olefins

A functionalized nanomaterial having an average particles size of less than 10 nm comprising an iron oxide nanoparticle core and a bis(diarylphosphinomethyl) dopamine based ligand layer anchored to the iron oxide nanoparticle core is disclosed. In addition, a catalyst composition for use in a variety of chemical transformations wherein the bisphosphine groups of the functionalized nanomaterial chelate a catalytic metal is disclosed. In addition, a method for producing the functionalized nanomaterial and a method for the hydroformylation of olefins to aldehydes employing the functionalized nanomaterial with high conversion percentage and high selectivity are disclosed.

Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams

Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

Metal complex and supported metal complex having disiloxane as ligand, method for production therefor, and supported metal catalyst prepared by using the same

A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R 1 to R 4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, which makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst improved in catalytic activity to a greater extent than conventional supported metal catalysts.

来自无有机模板的合成的CHA骨架结构的铜助催化沸石材料及其在NOx的选择性催化还原中的用途

本发明涉及一种合成的含铜和/或铁的具有CHA骨架结构的沸石材料，其中所述CHA骨架结构包含SiO 2 、X 2 O 3 并任选包含Z 2 O 5 ，其中X是三价元素且Z是五价元素，其中所述沸石材料含有作为各自的元素计算并基于具有CHA骨架结构的沸石材料中所含的100重量％SiO 2 计3.8至12重量％的Cu和/或Fe，且其中所述沸石材料的 29 Si MAS NMR包含在‑96至‑98.8ppm范围内的第一峰(P1)；在‑102至‑104.5ppm范围内的第二峰(P2)；和在‑107.5至‑111ppm范围内的第三峰(P3)；其中所述沸石材料的 29 Si MAS NMR中的第一、第二和第三峰的积分提供(0.35–0.7):1:(0.1–1.6)的积分值比率P1:P2:P3，以及涉及其制备方法及其用途，特别是在NO x 的选择性催化还原方法中的用途。

Method for selective hydrogenation of unsaturated compound

The present invention relates to a method for the selective hydrogenation of an unsaturated compound, particularly a method in an unsaturated compound or a mixture containing unsaturated compounds for increase of the light sulphides weight, hydrogenation of a polyunsaturated compound and isomerization of a monounsaturated compound. The method uses a supported catalyst. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area.

Crystalline molecular sieves and related structure-directing agents, methods and systems

A composition and method for preparing molecular sieves having a STW framework structure are described wherein a structure directing agent comprising quaternary cation 1,2,3,4,5-pentamethyl-1H-imidazol-3-ium is contacted with a source of an oxide of a first tetravalent element with or without a source of an oxide of another tetravalent elements and/or a source of a trivalent element in a molar ratio of tetravalent element:trivalent element 100:1 and greater.

Mixed oxides of transition metals, hydrotreatment catalysts obtained therefrom and preparation process

New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite isostructural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.

Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

Lean NOx trap diesel oxidation catalyst with hydrocarbon storage function

The present invention is directed to a lean NOx trap diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the trapping and reduction of nitrogen oxides (NOx). Catalytic composites can comprise a catalytic material on a carrier, the catalytic material comprising a first NOx trap layer that comprises a NOx sorbent and one or more precious metal components located on the carrier and a second NOx trap layer containing hydrocarbon trapping functionality located over the first NOx trap layer that comprises a NOx sorbent, one or more precious metal components, and a zeolite, for example a beta zeolite, wherein the zeolite is substantially free of framework aluminum. Such zeolites are characterized by high crystallinity and/or by being substantially free of framework aluminum to minimize surface acidity.

High viscosity high quality group II lube base stocks

Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt. % saturates, and less than 10 wt. % aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.

Methods and systems for producing alcohols and amides from carbon dioxide

Methods and systems for producing butanol from carbon dioxide, and water are disclosed. In one embodiment, a method of producing butanol from carbon dioxide and water involves contacting carbon dioxide with a reaction mixture containing water and a catalyst, and heating the carbon dioxide and reaction mixture by fluctuating magnetic field. In some embodiments, the catalyst used may be FeAl 2 O 3 .

Surface bonded Rh-bis(diarylphosphine) on magnetic nanoparticles as a recyclable catalyst for hydroformylation of olefins

A functionalized nanomaterial having an average particles size of less than 10 nm comprising an iron oxide nanoparticle core and a bis(diarylphosphinomethyl) dopamine based ligand layer anchored to the iron oxide nanoparticle core is disclosed. In addition, a catalyst composition for use in a variety of chemical transformations wherein the bisphosphine groups of the functionalized nanomaterial chelate a catalytic metal is disclosed. In addition, a method for producing the functionalized nanomaterial and a method for the hydroformylation of olefins to aldehydes employing the functionalized nanomaterial with high conversion percentage and high selectivity are disclosed.

Catalyst using Pd-Ru solid solution alloy fine particles

The catalyst disclosed is a catalyst including palladium-ruthenium alloy fine particles in which palladium and ruthenium form a solid solution. The palladium-ruthenium alloy fine particles used in this catalyst can be produced by a production method including the step of maintaining a solution containing a protective agent, a reducing agent, a palladium compound or palladium ions, and a ruthenium compound or ruthenium ions at a temperature equal to or higher than a predetermined temperature.

Selective hydrogenation catalyst for unsaturated compound

The present invention relates to a selective hydrogenation catalyst for an unsaturated compound. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area. Using the catalyst of the present invention can have the following advantages: the weight increase of light sulphides in an unsaturated compound or a mixture containing unsaturated compounds, the hydrogenation of a polyunsaturated compound, the isomerization of a monounsaturated compound, high operation flexibility and a significant improvement in the effects of a hydrogenation treatment.