04-06-2020 дата публикации
Номер: US20200171534A1
Принадлежит:
A composition comprising nano- or micro-particles grafted onto a surface are disclosed. Process of preparing the compositions and methods of using the same, such as for anti-fogging, anti-fouling and anti-scratching are provided. 1. A process for coating a substrate with a plurality of oxide particles , comprising the steps of (i) providing a substrate selected from an hydrophilic substrate , or an at least partially oxidized substrate; and (ii) contacting one or more oxide monomers with said substrate , under conditions suitable for said one or more oxide monomers to polymerize into oxide particles bound to said substrate , thereby forming a first layer of a plurality of oxide particles coating a substrate.2. The process of claim 1 , further comprising a step (iii) of washing the substrate to remove non-bound oxide particles.3. The process of claim 1 , further comprising a step (iv) of contacting one or more oxide monomers with said substrate under conditions suitable for said one or more oxide monomers to polymerize into oxide particles bound to said first layer claim 1 , thereby forming a second layer.4. The process of claim 1 , wherein said contacting is via dipping claim 1 , spraying claim 1 , spreading claim 1 , curing claim 1 , or printing.5. The process of claim 1 , wherein said one or more oxide monomers are selected from having a general formula of M(OR) claim 1 , M(R′)(OR) claim 1 , or a combination thereof claim 1 , wherein M is a metal selected from Si claim 1 , Ti claim 1 , Zn claim 1 , or Fe claim 1 , and R and R′ are each independently selected from hydrogen claim 1 , methyl claim 1 , alkyl claim 1 , alkenyl claim 1 , alkynyl claim 1 , cycloalkyl claim 1 , heteroalicyclic claim 1 , aryl claim 1 , heteroaryl claim 1 , hydroxy claim 1 , alkoxy claim 1 , aryloxy claim 1 , thiohydroxy claim 1 , thioalkoxy claim 1 , thioaryloxy claim 1 , halide claim 1 , amine claim 1 , amide claim 1 , carbonyl claim 1 , thiocarbonyl claim 1 , carboxy claim 1 , ...
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