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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 1604. Отображено 188.
08-11-1967 дата публикации

Improvements in or relating to explosive compositions

Номер: GB0001090184A
Принадлежит:

An explosive composition free from nitro-cellulose is made by mixing a liquid nitric acid ester and/or a liquid aromatic nitro-compound with a gelatinizing or plasticizing agent consisting of one or more high polymers free from nitro groups and perchlorate groups. Suitable polymers or copolymers are obtained from unsaturated acids, their esters and anhydrides, unsaturated alcohols, their esters and ethers, unsaturated ketones and acetals, and condensation products of aldehydes and phenols and of diols and dicarboxylic acids. Several examples of such polymers are given. In examples the nitric esters and nitro-compounds are nitroglycerine, nitroglycol, nitroglycerine - nitroglycol mixture, diethyl glycol dinitrate, and a liquid mixture of isomeric dinitrotoluenes; the polymers and copolymers are polymethacrylic acid, polyvinyl acetate, a copolymer of ethyl acrylate and vinyl chloride, phenol-formaldehyde resin, and polyvinyl pyrrolidone or a copolymer thereof with vinyl acetate.

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27-01-1993 дата публикации

Preparation of composite double base propellants

Номер: GB0002257968A
Принадлежит:

A composite double base propellant is provided by the in situ casting method, at least one polyisocyanate crosslinking agent being introduced together with the casting solvent into the base powder. The propellant may include nitroglycerin, TMETN, TRENO, BTTN, propanediol dinitrate; a plasticiser such as triacetin, and a stabiliser, such as NDPA, centralite or N-methyl-para-nitroaniline.

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24-07-2002 дата публикации

Propellant compositions and propellants produced therefrom

Номер: GB0002371297A
Принадлежит:

An energetic composition suitable for use as a propellant comprises the following components in the following relative proportions:
```Component A: from 5% to 25% by weight of a polymeric binder;
```Component B: from 65% to 90% by weight of a highly energetic filler comprising at least one nitramine compound such as RDX, HMX or TATND; and
```Component C: from 1% to 15% by weight of a plasticiser which comprises at least one nitroaromatic compound such as nitrobenzene, nitrotoluene, nitrocresol or nitroxylese;
```the percentages by weight of Components A, B and C adding to 100%, wherein Component A comprises from 10 to 100 per cent by weight of a poly(ethylene/vinyl acetate), and may include nitrocellulose, cellulose acetate butyrate or other energetic or non-energetic binder materials.

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19-07-1995 дата публикации

Glycidyl azide polymer azide

Номер: GB0002285624A
Принадлежит: Rockwell International Corp

A glycidyl azide polymer azide is prepared by a process in which alpha -(2-chloroethyl)- omega -benzenesulfonyl polyepichlorohydrin is reacted with sodium azide in a polar solvent such as dimethylsulfoxide. The compound has a polyether structure with 2 - 10 repeating units and is azido-terminated.

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17-11-1982 дата публикации

Gun propellants

Номер: GB0002098195A
Принадлежит:

A propellant composition comprises polyglycidyl azide and nitrocellulose. The composition may also contain resorcinol as a stabiliser. There may also be present cyclotetramethylene tetranitramine (HMX) and/or triaminoguanidine nitrate (TAGN). This family of propellant compositions is said to combine reduced flame temperatures with high mass impetus.

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23-01-1985 дата публикации

GUN PROPELLANTS

Номер: GB0002098195B
Автор:
Принадлежит: ROCKWELL INTERNATIONAL CORP

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06-08-2008 дата публикации

AZIDOALKYLFORMALS, THEIR PREPARARION AND USE

Номер: GB0009312945D0
Автор:
Принадлежит:

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13-11-1996 дата публикации

High performance pressable expolsive compositions

Номер: GB0009524749D0
Автор:
Принадлежит:

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02-12-1999 дата публикации

Azido polymers having improved burn rate

Номер: AU0000713392B2
Принадлежит:

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09-03-2006 дата публикации

ENERGETIC PLASTICIZER FOR EXPLOSIVE CHARGES

Номер: CA0002570622A1
Автор: WEITZ, AMIR
Принадлежит:

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25-01-1983 дата публикации

ENERGETIC HYDROXY-TERMINATED AZIDO POLYMER

Номер: CA1140296A

An energetic binder comprises a hydroxy-terminated aliphatic polymer having dependent alkyl azide groups and method for producing same.

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19-04-2001 дата публикации

PROCESS OF PREPARING A HIGH-ENERGY SOFTENING AGENT

Номер: CA0002370145A1
Принадлежит:

The present invention relates to a continuous process of preparing N-alkyl- nitratoethylamines and a production plant for carrying out a continuous process of preparing such N-alkyl-nitratoethylamines.

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16-08-2007 дата публикации

BLACK POWDER SUBSTITUTES FOR SMALL CALIBER FIREARMS

Номер: CA0002652642A1

Propellant compositions are provided herein for use in small arms cartridges. Such propellant compositions include from about 70 to about 90 % by weight of a cellulose-based organic fuel, from about 5 to about 30 % by weight of a non-azide, nitrogen-containing primary organic oxidizer and from about 0.5 to about 10.0 % by weight of a secondary nitrate, perchlorate, chlorate or peroxide oxidizer. Preferably, such compositions are in the form of extruded shaped hollow cylindrical grains having a length in the range of 0.030 to 0.200 inch, a diameter in the range 0.040 to 0.070 inch, and having a coaxial opening there through having a wall grain thickness in the range 0.008 to 0.016 inch. Ignition grains are also provided for use alone or in a mixture with the propellant compositions. When used in a small caliber firearm or muzzleloader, the temperature of combustion is at a level that ensures substantially complete combustion of the fuel during firing so that the products of combustion are mostly gaseous.

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19-02-2015 дата публикации

METHOD OF MANUFACTURING MULTI-LAYERED PROPELLANT GRAINS

Номер: CA0002920690A1
Принадлежит:

A method of manufacturing a multi-layered propellant grain is provided. The method of the present disclosure simplifies the setup necessary to produce multi-layered propellants by using industrial equipment that is more energy and space efficient than the machinery that is conventionally employed for such processes. The method comprises providing a first propellant formulation; providing a die configured to provide a structure having an outer shell and a hollow interior when material is extruded therethrough; extruding the first propellant formulation through said die, to produce a first propellant layer having an outer shell defining a hollow interior in the form channel having open ends; providing a second propellant formulation, said second propellant formulation being of low viscosity; injecting said second propellant formulation into said channel defined by said first propellant layer to form a second propellant layer disposed in said channel; and hardening said second propellant layer ...

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01-07-2010 дата публикации

METAL HYDRAZIDE MATERIALS

Номер: CA0002747821A1
Принадлежит:

The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN2]- as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof; and (ii) a polymer comprising -[M2N3]- as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof.

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07-09-1999 дата публикации

STABLE PLASTICIZERS FOR NITROCELLULOSE/NITROGUANIDINE-TYPE COMPOSITIONS

Номер: CA0002053832C
Принадлежит:

Stable plasticizer system and corresponding nitrocellulose/nitroguanidine nitramine-type propellant compositions utilizing such system.

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12-06-1992 дата публикации

Stable Plasticizers for Nitrocellulose/Nitroguanidine-Type Compositions

Номер: CA0002053832A1
Принадлежит:

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05-04-1995 дата публикации

BRANCHED ENERGETIC AZIDO POLYMERS

Номер: CA0002133507A1
Автор: AHAD ELIE, AHAD, ELIE
Принадлежит:

Improved Branched Energetic Azido Polymers The invention disclosed relates to novel branched chain hydroxy terminated aliphatic azido polymers and copolymers, and to a single step process for their production. The properties of the materials are preferably adjusted through the incorporation of suitable polyols which can provide additional branching of the materials.

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13-09-1994 дата публикации

HIGH-DENSITY INSENSITIVE EXPLOSIVES

Номер: CA0002107256A1

ABSTRACT OF THE INVENTION High-density insensitive explosives including a binder and an oxidizer wherein the binder is selected from a halogenated polymer, a halogenated plasticizer and mixtures thereof. Such explosives display enhanced performance with decreased sensitivity.

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20-07-2004 дата публикации

NON-DETONABLE POLY(GLYCIDYL AZIDE) PRODUCT

Номер: CA0002039928C

A normally liquid, non-detonable product having less than about 45.7 weight percent nitrogen comprising polymer which can be represented by the general formula: R(G)n R1 where, in the above formula, n is a number between 2 and 18; G is an azidomethyloxyethylene moiety; R is a monovalent residue of an organic initiator compound or a monovalent alkyl radical, R is essentially free of isocyanate-reactive moieties and may be substituted with non-interfering atoms or moieties and it cannot be substituted with energetic nitrogen-containing moieties other than azido moieties; R1 is a monovalent alkoxy radical, oxyaryl radical or combinations thereof, or R1 is an azido moiety, R1 is essentially free of isocyanate-reactive atoms or moieties and it may be substituted with non-interferring atoms or moieties and it cannot be substituted with energetic nitrogen-containing moieties other than azido moieties; or R and R1, taken together, are a carbon-oxygen bond when said polymer is a cyclic compound.

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15-03-1966 дата публикации

Verfahren zur Darstellung von Nitroacetalen

Номер: CH0000398521A

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21-04-2020 дата публикации

COMPOSITION MONOBASIC POWDER CHARGE FOR AMMUNITION AND AMMUNITION, PROVIDED WITH SUCH COMPOSITION

Номер: EA0201992796A1
Автор:
Принадлежит:

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29-04-2016 дата публикации

PYROTECHNIC PRODUCT HIGH PERFORMANCE COMPOSITE PB IN ITS COMPOSITION AND ITS PREPARATION

Номер: FR0003027597A1
Принадлежит: HERAKLES

La présente invention a pour principal objet un produit pyrotechnique composite, performant, sans plomb dans sa composition, dont l'obtention à l'échelle industrielle ne se heurte pas à un problème de vie de pot de la pâte intermédiaire. Ledit produit renferme, dans un liant plastifié, comprenant un polymère énergétique réticulé et au moins un plastifiant énergétique, des charges énergétiques organiques et un catalyseur de combustion. De façon caractéristique, ledit polymère énergétique réticulé consiste en un polyazoture de glycidyle (PAG), ayant une masse moléculaire moyenne en nombre (Mn) comprise entre 700 et 3000 g/mol, réticulé, via ses fonctions terminales hydroxyles, avec au moins un agent de réticulation de type polyisocyanate, et ledit catalyseur de combustion consiste en le citrate de bismuth.

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21-01-1977 дата публикации

Patent FR2196998B1

Номер: FR0002196998B1
Принадлежит: Rockwell International Corp

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17-06-2005 дата публикации

New composite solid propergol based on a polyether with hydroxyl terminations with reduced sensitivity to impact or heating useful in the preparation of insensitive munitions

Номер: FR0002863608A1
Принадлежит:

La présente invention concerne un propergol solide composite dont le liant est à base d'un copolymère de polyéthers à terminaisons hydroxyles peu sensible dans l'épreuve d'échauffement lent. Ledit propergol comporte au moins un plastifiant énergétique, des charges pulvérulentes oxydantes et combustibles et des additifs dont un catalyseur de combustion, il est tel ce que d'une part le catalyseur de combustion est de l'oxyde de fer Fe2O3 et que d'autre part le propergol comporte au moins un additif modérateur de la réaction du propergol lors d'un échauffement lent choisi parmi la nitroguanidine et le nitrate d'ammonium représentant au plus 10 % en poids du propergol.

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31-01-2014 дата публикации

REACTIVE PLASTICIZER BASED ETHER FOR EXPLOSIVES WITH A PLASTIC BINDER

Номер: FR0002993883A1
Принадлежит:

La présente invention concerne un plastifiant réactif énergétique pour un explosif à liant plastique (PBX), et spécifiquement un plastifiant réactif énergétique pour PBX qui possède des performances et une insensibilité élevées sans fuite de plastifiant, en étant lié à un liant polymère pour un explosif à liant plastique.

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30-03-2018 дата публикации

COMPOSITE PYROTECHNIC PRODUCT CONTAINING AN ANTI-GLOW TYPE POTASSIUM SALT

Номер: FR0003056583A1
Принадлежит: AIRBUS SAFRAN LAUNCHERS SAS

La présente invention a pour principal objet un produit pyrotechnique composite renfermant, dans un liant plastifié, comprenant un polymère énergétique réticulé et au moins un plastifiant énergétique, des charges énergétiques organiques et au moins un agent anti-lueur de type sel de potassium. De façon caractéristique, ledit polymère énergétique réticulé consiste en un polyazoture de glycidyle (PAG), ayant une masse moléculaire moyenne en nombre (Mn) comprise entre 700 et 3000 g/mol, réticulé, via ses fonctions terminales hydroxyles, avec au moins un agent de réticulation de type polyisocyanate, et ledit au moins un agent anti-lueur de type sel de potassium est choisi parmi la cryolite de potassium (K3AIF6), le tartrate de potassium monobasique (C4H5KO6) et leurs mélanges. Le produit pyrotechnique composite en cause est intéressant en termes de discrétion et de pouvoir énergétique.

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10-12-1993 дата публикации

Extrudable gun propellant compsn.

Номер: FR0002691963A1
Принадлежит:

L'invention concerne les agents propulsifs. Elle se rapporte à une composition d'agent propulsif extrudable pour canon, caractérisée en ce qu'elle contient les ingrédients suivants: 65 à 85 % en poids d'une charge explosive particulaire, 10 à 30 % en poids d'un mélange durcissable d'un prépolymère d'un éther alkylique à substituant nitratoalkyle à terminaison fonctionnelle et d'un agent de réticulation, et 1 à 12 % en poids d'un agent plastifiant d'énergie élevée. Application aux munitions.

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11-12-2018 дата публикации

추진제 충전물 또는 그레인

Номер: KR1020180132082A
Принадлежит:

... 본 발명은 추진제 충전물, 추진제 충전물의 제조 방법, 및 추진제 충전물의 용도에 관한 것이다. 본 발명의 추진제 충전물 또는 그레인은 상이한 선형 연소 속도를 갖는 2개 이상의 에너지성 물질들을 포함하고, 이때 상기 2개 이상의 에너지성 물질들은 상기 추진제 충전물 또는 그레인의 2개의 수직 단면들이 비-평행한 방향들로 2개 이상의 선형 연소 속도 구배들을 가지도록 상기 충전물 또는 그레인 내에 분포되고, 상기 추진제 충전물 또는 그레인이 1 내지 10 000 ㎛ 범위의 층 두께를 갖는 층들로 적층되고, 상기 추진제 충전물 또는 그레인이 종축을 갖는 경우, 상기 수직 단면들 중 적어도 하나가 상기 종축을 따르고, 상기 추진제 충전물 또는 그레인이 하나 이상의 천공을 추가로 포함한다.

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13-02-1984 дата публикации

Explosif compressible

Номер: BE893143A
Автор:
Принадлежит:

Cet explosif compressible destiné à la formation de charges creuses est caractérisé en ce qu'il comporte un ou plusieurs corps explosifs et au moins un liant tel que le copolymère de butadiène-styrène à 3 séquences.

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17-11-1997 дата публикации

Strängsprutbar drivmedelskomposition för eldvapen och strängsprutat drivmedel framställt därav

Номер: SE0000506194C2
Автор:
Принадлежит:

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24-06-1999 дата публикации

Номер: WO1999030550A2
Автор:
Принадлежит:

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26-10-2000 дата публикации

FAMILY OF PROPELLANT COMPOSITIONS AND METHOD

Номер: WO0000063139A3
Принадлежит:

L'invention concerne une famille de compositions propulsives de classe 1.3 renfermant de la nitrocellulose, au moins un ester choisi parmi les esters de nitrate plastifiants, un stabilisant thermique, du carbone, et un solide énergétique. Cette invention concerne également un procédé d'élaboration de cette famille de compositions propulsives.

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13-03-2003 дата публикации

Minimum signature propellant

Номер: US2003047260A1
Автор:
Принадлежит:

This invention relates to energetic compositions, which offer increased performance in conjunction with a total absence of halogen based oxidizers to eliminate exhaust products, such as hydrogen chloride. The oxidizers of choice are various combinations neat ammonium dinitramide, ammonium dinitramide prills and CL-20, because these oxidizers do not produce halogen containing exhaust products, such as the HCl gas of ammonium perchlorate. The exhaust these novel propellants consist mostly of CO2, H2O, N2, and small amounts of CO. These exhaust species are friendlier and much less hazardous to the environment than those emitted by conventional AP-based propellants. The plasticizers are selected from energetic plasticizers that do not contain halogens, but maintain other desirable properties.

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23-01-1917 дата публикации

EXPLOSIVE AND METHOD OF PRODUCING SAME.

Номер: US1213369A
Автор:
Принадлежит:

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18-03-1975 дата публикации

OXALACETIC ACID BIS(2-SUBSTITUTED-2,2-DINITROETHYL)ESTERS

Номер: US0003872158A
Автор:
Принадлежит:

Oxal acetic acid esters of the formula WHERE R represents NO2, H, F and CH3 are produced by the reaction of acetylenedicarboxylic acid, water and an alcohol of the formula IN FUMING SULFURIC ACID. These compounds find use as high-energy plasticizers.

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28-07-1987 дата публикации

Polyazido esters

Номер: US0004683085A
Автор:
Принадлежит:

Energetic plasticizers comprising 4,4,4-trinitrobutyryl and 1,3,5-benzene tricarboxylic acid esters of pentaerythritol triazide and pentaerythritol diazido mononitrate, prepared by reacting the appropriate acid chloride, e.g. 4,4,4-trinitrobutyryl chloride, with pentaerythritol triazide or pentaerythritol diazido mononitrate.

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08-05-2001 дата публикации

Extrudable gun propellant composition

Номер: US0006228190B1

The invention provides an extrudable gun propellant having a specific energy content of at least 1100 kJ/kg and typically over 1200 kJ/kg, but with reduced vulnerability to shaped charge attack compared to known colloidal propellants. This is achieved by using an energetic binder prepolymer and an energetic plasticiser with a reduced content of explosive filler. The composition comprises 65-85% by weight particulate explosive filler, 10-30% by weight of a mixture of a funtionally-terminated poly(nitratoalkyl-substituted)alkyl ether prepolymer and a cross-linking agent, and 1-12% by weight of energetic plasticiser.

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25-06-2002 дата публикации

Polymeric amine for a gas generating material

Номер: US0006410682B1
Принадлежит: TRW Inc., TRW INC, TRW INC.

A gas generating material (16) comprises a polymeric amine. The polymeric amine has a polymer backbone that includes units ofwherein R is a nitrogen containing organic radical of a nitrogen containing organic fuel that includes a primary amino group.

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21-02-1984 дата публикации

Azido esters

Номер: US0004432814A
Автор:
Принадлежит:

This invention involves the synthesis of a novel family of azido esters and their utilization as energetic plasticizers for advanced solid propellant compositions. This family includes as an illustrative member, the novel compound 6-azidohexyl-6-azidohexanoate.

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07-12-1988 дата публикации

Azide-terminated azido compound

Номер: EP0000293555A3
Принадлежит:

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23-10-1986 дата публикации

Номер: DE0002752166C2
Принадлежит: DYNAMIT NOBEL AG, 5210 TROISDORF, DE

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05-03-2015 дата публикации

Treibladung und Verfahren zu ihrer Herstellung

Номер: DE102010020776B4

Treibladung (TL) für Rohrwaffen mit mindestens einem Energieträger sowie Nitrocellulose (NC) und Celluloseacetatbutyrat (CAB), dadurch gekennzeichnet, dass zumindest ein Teil der NC alkohollösliche NC ist, wobei die NC als Bindemittel dient und dazu in einer Konzentration von mindestens 15 Gewichtsprozent (Gew.-%) in der TL enthalten ist, wobei das CAB einen Schmelzpunkt von über 200°C und eine Glasübergangstemperatur von über 130°C aufweist.

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04-02-2010 дата публикации

Weichmacher für einen Treibsatz mit umgebungstemperaturunabhängigem Abbrand

Номер: DE102004004529B4

Treibsatz mit mindestens einem energetischen Stoff bzw. einer Mischung von energetischen Stoffen und einer Weichmacherzusammensetzung, dadurch gekennzeichnet, dass die Weichmacherzusammensetzung mindestens 55 Masse-% 2,4-Dinitro-2,4-diazahexan (DNDA6) enthält.

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12-07-2006 дата публикации

Energy - producing material

Номер: GB0000611035D0
Автор:
Принадлежит:

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21-08-2002 дата публикации

Desensitisation of energetic materials

Номер: GB0000011861D0
Автор:
Принадлежит:

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05-06-1974 дата публикации

COMPOSITION FOR INFLATION OF PASSIVE RESTRAINT SYSTEMS

Номер: GB0001354866A
Автор:
Принадлежит:

... 1354866 Crash restraint bags DOW CHEMICAL CO 17 Aug 1972 [19 Aug 1971] 38509/72 Heading B7B [Also in Division C1] A gas-producing composition for inflating an automobile passenger restraint device comprises potassium chlorate, oxamide, and a reaction product of a glycidyl ether of glycerine having 2 to 3 glycidyl groups per molecule with triethylene tetramine or maleic anhydride (see Division C1). Sodium bicarbonate may be used in a separate compartment in the gas generating device to reduce flaming and cool the gases.

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12-02-1964 дата публикации

Improvements in composite propellants and the like

Номер: GB0000949086A
Принадлежит:

A composite propellant or a mixture for a gas generator comprises an elastomeric binder which contains substituent nitro groups in a polyurethane resin. The nitro groups may be present in any part of the molecule and in the cross-linking agents. In examples, the resin is obtained from sebacic acid, propyleneglycol, and 3-nitrophthalic acid or trinitroresorcinol or nitrated 2,4-toluene-diisocyanate. Ammonium perchlorate is added as the oxidizing agent.ALSO:The binder for a propellant composition (see Division C1) comprises an elastomeric polyurethane resin containing substituent No. 2 groups. These groups may be present in the polyester chain; in the polyether chain; in the mono- or polyisocyanate; or in the cross linking agent if present. In Examples, (No. 1), a sebacic acid, propylene glycol, 3-nitrophthalic acid polyester and toluene -2, 4-diisocyanate are reacted together; and in Example 3 the resin is prepared from polypropylene glycol, trinitroresorcinol, dibutylsebacate, glycol ester ...

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10-03-1976 дата публикации

PROCESS FOR PRODUCING CROSS-LINKED PROPELLANTS

Номер: GB0001427697A
Автор:
Принадлежит:

... 1427697 Propellants HERCULES Inc 12 Aug 1969 15323/68 Heading C1D A solid propellant is made by mixing nitrocellulose, a solid oxidizer, a metal fuel, a plasticizer, and a diisocyanate blocked with phenolic end groupings, and then curing the mixture under conditions to effect unblocking of the diisocyanate and cross-linking of the nitrocellulose. Non-porous propellants may be formed even in the presence of small amounts of water. Many examples of suitable diisocyanates and substituted phenol blocking agents are given. In examples the ingredients are nitrocellulose, nitroglycerine, ammonium perchlorate, metallic aluminium, resorcinol, MnO 2 , 2-nitrodiphenyl amine, dibutyl tin diacetate catalyst, and a prepolymer of polyglycol adipate and tolylene diisocyanate blocked with m-nitrophenol. Other ingredients referred to are ammonium, alkali metal and alkaline earth metal nitrates, chlorates, perchlorates, chromates, dichromates, and permanganates, RDX, HMX, PETN, dipentaerythritol hexanitrate ...

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13-09-1989 дата публикации

HYDROXYL-TERMINATED POLYEPICHLOROHYDRIN AND DERIVATIVES

Номер: GB0008616796D0
Автор:
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20-09-1967 дата публикации

Difluoramino compounds from ª‡-diketones

Номер: GB0001084451A
Принадлежит:

A difluoroamino polymeric binder is formed by the polymerization of a 1,2-dialkyl derivative of 1,2-bis-(difluoramino) epoxyethane (see Division C2).ALSO:A propellant composition contains ammonium perchlorate, aluminium, and a difluoramino compound (see Division C2) made by reacting a compound of the formula RCO-COR1, where R and R1 are hydrogen or alkyl, with difluoramine in the presence of chlorosulphonic acid or fluorosulphonic acid.ALSO:A difluoramino compound is made by refluxing a compound of the formula RCO-COR1, where R and R1 are hydrogen or alkyl, with difluoramine in the presence of chlorosulphonic acid or fluorosulphonic acid. If either R or R1 is hydrogen, two molecules condense to give a tetrakis (difluoramino) derivative of p-dioxane, while if R and R1 are both alkyl, a 1,2-dialkyl derivative of 1,2-bis-(difluoramino) epoxyethane is formed. In Examples (1 to 4), di-difluoramine is added slowly to a solution or suspension of monoglyoxal or glyoxal monohydrate in methylene ...

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26-10-1994 дата публикации

Polymer curing

Номер: GB0009215603D0
Автор:
Принадлежит:

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09-05-1973 дата публикации

MONOMERS POLYMERISABLE TO FORM BINDERS FOR EXPLOSIVE AND PROPELLANT COMPOSITIONS AND POLYMERS AND COMPOSITIONS FORMED THEREFROM

Номер: GB0001316692A
Принадлежит: North American Rockwell Corp

1316692 Explosive and propellent compositions NORTH AMERICAN ROCKWELL CORP 4 May 1970 21426/70 Heading ClD [Also in Divisions C2 and C3] A polymer of a compound of the formula where R is alkylene of 1 to 4 carbon atoms (see Division C2), is used as an energetic binder in explosive and propellent compositions. Prepolymerization of the monomer may be carried out using a Lewis acid catalyst and a hydroxygroup-containing initiating compound. The compositions also contain an oxidizing agent, a fuel, a curing agent, and bis-(2-fluoro-2,2-dinitroethyl) formal as an energetic plasticizer. The fuel may be powdered boron, Al, Mg, Be, or alloys of Al-B, Al-Mg, or Al-Cu, and the oxidizing agent ammonium, alkali metal, or alkaline earth metal salts of nitric, perchloric, or chloric acid. Various di- and poly-isocyanates are specified as suitable curing agents. Examples describe the preparation of propellent compositions in which aluminium powder is used as the fuel, ammonium perchlorate as the oxidizing agent, polymethylene polyphonylisocyanate as the curing agent, and ferric acetonyl acetate as a curing catalyst. Higher density impulse figures are obtained by using hydroxylamine perchlorate in place of ammonium perchlorate.

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12-03-1973 дата публикации

Procedure for making explosive loads of unglazed nitrocellulose grains

Номер: AT0000305851B
Автор:
Принадлежит:

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15-05-2003 дата публикации

HIGH-ENERGY FUELS FOR PROJECTILE AMMUNITION

Номер: AT0000237565T
Принадлежит:

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14-01-1993 дата публикации

CASTABLE SMOKE-PRODUCING PYROTECHNIC COMPOSITIONS

Номер: AU0000632918B2
Принадлежит:

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24-01-1994 дата публикации

Branched energetic polyether elastomers

Номер: AU0002181492A
Автор: AHAD ELIE, ELIE AHAD
Принадлежит:

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15-11-1983 дата публикации

FRAGMENTABLE CHARGES OF PROPELLANT POWDER COATED WITH POLYVINYL NITRATE, AND THE PROCESS FOR THEIR MANUFACTURE

Номер: CA1156839A

The process for the manufacture of fragmentable charges of propellant powder containing nitrocellulose, according to the invention, is characterized in that, in a conventional process for the manufacture of propellant powder containing nitrocellulose, with solvent, a glazing operation is carried out, in which a glazing solution containing at least polyvinyl nitrate and a stabilizer is sprayed onto the grains of powder, and in that, after evaporation of the solvent from the said solution, the grains of powder thus obtained are compressed at between about 80 and 120.degree.C. The fragmentable charges of the present invention are useful for weapons of small and medium calibre.

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15-12-1992 дата публикации

POLYMER BINDER FOR EXPLOSIVE COMPOSITIONS

Номер: CA0001311361C
Принадлежит: POLYSAR LTD, POLYSAR LIMITED

POLYMER BINDER FOR EXPLOSIVE COMPOSITIONS The present invention relates to an energetic binder for use in an explosive composition. The present energetic binder comprises an adduct of a hydroformylated, monovinyl aromatic/conjugated diene thermoplastic elastomer (e.g. hydroformylated styrene/butadiene thermoplastic elastomer) and a hydrazine derivative selected from 2, 4 dinitrophenylhydrazine and 2, 4, 6, dinitrophenylhydrazine and 2, 4, 6 trinitrophenylhydrazine. The present energetic binder is used to bind together the components of an explosive in a solid form. When the explosive is detonated, the energetic binder decomposes and provides gaseous nitrogen or nitrogen oxides.

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20-12-1994 дата публикации

THERMOPLASTIC ELASTOMER-BASED LOW VULNERABILITY AMMUNITION GUN PROPELLANTS

Номер: CA0001333526C
Принадлежит: THIOKOL CORP, THIOKOL CORPORATION

Low vulnerability ammunition (LOVA) gun propellant compositions are provided by the present invention. These compositions comprise from about 60 to 85 wt. percent of particulates of a high energy oxidizer such as tetramethylenetetranitramine (HMX) or trimethylenetrinitramine (RDX) and between about 15 wt. percent and about 40 wt. percent of a thermoplastic, elastomeric binder system, said binder system being substantially free of metallic particulates and materials which leave a solid residue, said binder system comprising a thermoplastic elastomer and from 0 to about 80 wt. percent of a plasticizer.

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23-01-1973 дата публикации

HOT MOLED PROPELLANT

Номер: CA0000919433A1
Автор: SCANLON J J, OLSON T A
Принадлежит:

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28-05-2015 дата публикации

COMPOSITE PYROTECHNICAL PRODUCT WITH CROSSLINKED BINDER AND METHOD FOR PREPARING SAME

Номер: CA0002930488A1
Принадлежит:

La présente invention a pour objet un produit pyrotechnique composite, notamment une poudre propulsive pour armes à tube, renfermant des charges énergétiques organiques dans un liant réticulé. De façon caractéristique, la composition dudit produit, exprimée en pourcentages massiques, renferme : - de 78 à 90 %, avantageusement de 80 à 86 %, de charges énergétiques organiques, et - de 10 à 22 % d'un liant réticulé énergétique obtenu par réticulation, via seulement 8 à 12 % de ses fonctions azoture, d'un polyazoture de glycidyle ayant une masse moléculaire moyenne en nombre comprise entre 700 et 3 000 g/mol, avec au moins un agent de réticulation renfermant au moins deux fonctions propargyle dans sa formule chimique, en présence d'une gomme polymérique, choisie parmi les gommes polyuréthanne-polyester, les gommes polyuréthanne-polyéther et leurs mélanges, dont la masse moléculaire moyenne en nombre est supérieure à 20 000 g/mol et dont la viscosité Mooney est comprise entre 20 et 70 ML (5 ...

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19-12-1993 дата публикации

AZIDO THERMOPLASTIC ELASTOMERS

Номер: CA0002087740A1
Автор: AHAD ELIE, AHAD, ELIE
Принадлежит:

Novel energetic azido thermoplastic elastomers (ATPE's) are described. Such materials are useful as binders in energetic formulations to replace conventional inert thermosetting prepolymers. The ATPE's are easily formulated either by blending or chemically bonding an energetic azido elastomeric component and a thermoplastic component. The elastomeric component is a branched chain hydroxy-terminated azido polymer or copolymer. The thermoplastic component is a commercial polyether or polyethylene oxide.

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06-01-1994 дата публикации

BRANCHED ENERGETIC POLYETHER ELASTOMERS

Номер: CA0002137776A1
Автор: AHAD ELIE
Принадлежит:

The invention disclosed relates to novel branched chain hydroxy-terminated aliphatic azido polymers and copolymers with variable molecular weight (MW) and a single step method for the preparation thereof which involves respectively reacting a high (MW) (0.5 - 5.0 x 106) solid rubbery polyepichlorohydrin (PECH) homopolymer and epichlorohydrin/alkylene oxide copolymer (PEEC), with an alkali metal azide in a suitable organic solvent, in the presence of an initiator at elevated temperature. The MW of the azido product may be controlled by including in the reaction mixture a basic degradation catalyst (such as LiOCH3 or NaOH) and varying the amount of catalyst. When the reaction is catalyzed, the MW of the proudct varies within the range 1,000-40,000 and the hydroxyl functionality is 2-10. Uncatalyzed reactions yield products with MW between 40,000 and 200,000 and a functionality of about 10. The branched azido polymers and copolymers yield energetic binders with improved mechanical properties ...

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19-07-1991 дата публикации

Synthesis of a Diazido Terminated Energitic Plasticizer

Номер: CA0002008154A1
Принадлежит:

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04-02-1994 дата публикации

NITRO-AROMATIC POLYMERS USEFUL AS PROPELLANTS.

Номер: FR0002654722B1
Автор:
Принадлежит:

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07-08-1998 дата публикации

PROPELLANTS HAS STRONG SPECIFIC IMPULSE COMPRISING OF DERIVED FROM THE FURAZANE

Номер: FR0002750421B1
Автор: CHASSAING, FINCK
Принадлежит: HERAKLES

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29-12-1989 дата публикации

Composes polyepichlorhydrine a terminaison hydroxyle, derives, et procedes pour leur fabrication

Номер: FR0002633300A
Принадлежит:

On polymerise l'epichlorhydrine avec un initiateur renfermant de l'hydrogene actif, puis on fait reagir la polyepichlorhydrine a hydroxyle secondaire obtenue pour produire un compose polyepichlorhydrine a terminaison hydroxyle dont des chaines se terminent par un groupe hydroxyle primaire, ce compose polyepichlorhydrine pouvant reagir avec un acide non organique pour produire un compose poly(glycidyl acide) utilisable comme liant pour des propulseurs solides de fusees.

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02-08-1996 дата публикации

Product poly (glycidyl azide compound) non-detonation.

Номер: FR0002711985B1
Принадлежит: Minnesota Mining and Manufacturing Co

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22-02-1980 дата публикации

LIANT THERMOPLASTIQUE ACTIF POUR MATIERE EXPLOSIVE

Номер: FR0002432030A
Принадлежит:

La présente invention concerne un procédé de préparation d'un liant actif à fort taux de groupement NO2 pour l'enrobage de matière explosive. Le procède comporte une première étape selon laquelle on fait reagir un diisocyanate en excès sur un premier polyol aromatique polynitré dissous dans un solvant exempt d'hydrogènes mobiles et de fonctions hydroxyles à une température comprise entre environ 60 et 100 degrés C en présence d'un catalyseur permettant d'obtenir un prépolymère et une seconde étape selon laquelle on fait réagir le prépolymère obtenu avec un mélange constitué d'au moins un diol linéaire et un second polyol, le produit de la réaction étant soumis à une cuisson à une température comprise entre environ 80 et 110 degrés C. Le polymère obtenu est particulièrement apte à l'enrobage d'explosifs très puissants tels l'octogène, l'hexogène, la pentrite.

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17-08-1973 дата публикации

Explosive compsn - with nitrated binder

Номер: FR0002166614A5
Автор: [UNK]

Explosive compsns. having high deterioration speeds are made from (a) a crystalline substance, pref. octogen, hexogen and pentrite, but may be Al or inorganic nitrates, and (b) an explosive binder consisting of a nitrated polymer, pref. nitrocellulose, polyvinyl nitrate and nitropolystyrene, pref. as spherical particles of 1-200 mu dia., and an explosive oil based on a polyalcohol nitrate, pref. nitroglycerine, ethyleneglycol dinitrate, triethyleneglycol dinitrate and polyglycidyl nitrate, and these may include a cpd. to reduce sensitivity such as triacetin. The ratio of (a)/(b) is 60-85/15-40, and the proportion of nitrated polymer in (b) is 15-50%.

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22-02-1974 дата публикации

Solid fuel (propellant) compsn - which burns at constant intermittent rate

Номер: FR0002193799A1
Автор:
Принадлежит:

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22-06-1979 дата публикации

POLYMERS OF COMPOSE POLYNITROAROMATIQUES

Номер: FR0002410011A1
Принадлежит:

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14-02-2014 дата публикации

REACTIVE PLASTICIZER ESTER PLASTIC BINDER FOR EXPLOSIVES.

Номер: FR0002994431A1
Принадлежит: Agency for Defence Development

L'invention concerne un plastifiant réactif énergétique pour un explosif à liant plastique (PBX), et précisément un plastifiant réactif énergétique pour PBX qui présente des performances élevées et une insensibilité sans fuite de plastifiant en étant lié par un liant polymère pour un explosif à liant plastique. An energetic reactive plasticizer for a plastic binder explosive (PBX), and specifically a PBX energetic reactive plasticizer that exhibits high performance and plasticizer-free insensitivity by being bound by a polymeric binder for a binder explosive plastic.

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13-08-1999 дата публикации

NEW PYROTECHNICAL MATERIALS NOT DETONABLES FOR MICROSYSTEMS

Номер: FR0002774684A1
Принадлежит:

L'invention concerne de nouveaux matériaux pyrotechniques non détonables qui ont une épaisseur inférieure à 500 µm ou une masse inférieure à 15 mg, qui sont auto-combustibles après initiation ponctuelle par une puissance électrique comprise entre 150 mW et 800 mW, pendant un temps compris entre 20 ms et 600 ms et qui comprennent de 25 à 80 % en poids d'un liant énergétique à base de polyazoture de glycidyle, ou de poly-3, 3-bis (azidométhyl) oxétane, ou de polyester ou polyéther et d'au moins un plastifiant énergétique, de 10 à 70 % en poids de perchlorate d'ammonium dont la dimension des grains est comprise entre 0,5 et 30 µm, et de 0 % à 45 % en poids d'au moins une nitramine. Ces nouveaux matériaux sont utiles comme microgénérateurs de gaz, micropropulseurs ou microgénérateurs de chaleur.

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07-06-2012 дата публикации

Black Powder Substitutes for Small Caliber Firearms

Номер: US20120138200A1
Принадлежит: Individual

Propellant compositions are provided herein for use in small arms cartridges. Such propellant compositions include a cellulose-based organic fuel, a non-azide, nitrogen-containing primary organic oxidizer and a secondary nitrate, perchlorate, chlorate of peroxide oxidizer. Preferably, such compositions are in the form of extruded shaped hollow cylindrical grains having dimensions that makes it loadable in a muzzleloader firearm or small calibre firearm cartridge case. Ignition grains are also provided for use alone or in a mixture with the propellant compositions. When used in a small calibre firearm or muzzleloader, the temperature of combustion is at a level that ensures substantially complete combustion of the fuel during firing so that the products of combustion are mostly gaseous.

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30-01-2014 дата публикации

Ether-based reactive plasticizer for plastic bonded explosives

Номер: US20140031593A1
Принадлежит: Agency for Defence Development

Disclosed is an energetic reactive plasticizer for a plastic bonded explosive (PBX), and specifically an energetic reactive plasticizer for PBX which has high performance and insensitiveness without a plasticizer leak by being bonded with a polymer binder for a plastic bonded explosive.

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18-02-2016 дата публикации

Insensitive munition propellants

Номер: US20160046537A1
Принадлежит: BAE SYSTEMS plc

The invention relates to Insensitive Munition (IM) energetic materials particularly IM propellant compositions, and yet further to nitrocellulose-free IM propellants. An energetic composition suitable for use as a propellant comprises the following components in the following relative proportions: component A; from 5% to 25% by weight of an IM energetic filler; component B: from 50% to 80% by weight of a highly energetic filler comprising at least one nitramine compound; component C of from 5% to 20% by weight of a binder; and component D of from 3% to 15% by weight of a plasticiser; the percentages by weight of components A, B, C and D together with minor additives, if any, adding to 100%.

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16-03-2017 дата публикации

Additive Manufactured Thermoplastic-Aluminum Nanocomposite Hybrid Rocket Fuel Grain and Method of Manufacturing Same

Номер: US20170073280A1
Автор: Jones Ronald D.
Принадлежит:

A hybrid rocket solid fuel grain having a cylindrical shape and defining a center port is additive manufactured from a compound of thermoplastic fuel and passivated nanocomposite aluminum additive. The fuel grain comprises a stack of fused layers, each formed as a plurality of fused abutting concentric circular beaded structures of different radii arrayed defining a center port. During operation, an oxidizer is introduced along the center port, with combustion occurring along the exposed port wall. Each circular beaded structure possesses geometry that increases the surface area available for combustion. As each layer ablates the next abutting layer, exhibiting a similar geometry is revealed, undergoes a gas phase change, and ablates. This process repeats and persists until oxidizer flow is terminated or the fuel grain material is exhausted. To safety achieve this construction, a fused deposition additive manufacturing apparatus, modified to shield the nanocomposite material from the atmosphere is used. 1. A method of making a fuel grain for use in a hybrid rocket engine , the method comprising:compounding a first material suitable as a hybrid rocket fuel and a second energetic and pyrophoric nanoscale metallic material according to a predetermined mixture ratio to form a third material;the third material serving as feedstock material for use in an additive manufacturing apparatus; andoperating the additive manufacturing apparatus using the feedstock material to fabricate a fuel grain comprising a plurality of fused stacked layers of solidified fuel grain material, each layer of the plurality of layers comprising a plurality of bonded and concentric substantially circular ring-shaped beads of different radii and defining a center combustion port.2. The method of further comprising drying the feedstock material and then elevating a temperature of the feedstock material to attain a predetermined viscosity for the feedstock material.3. The method of the step of ...

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22-03-2018 дата публикации

Solid-rocket Propellants

Номер: US20180079697A1
Принадлежит: PURDUE RESEARCH FOUNDATION

Solid-fuel rocket propellants comprising an oxidizer, an oxophilic metal-halophilic metal formulation, and a binder are described herein. Further described are processes for preparing such propellants and methods of reducing hydrogen chloride production via the combustion of such propellants. Non-limiting examples of such formulations include aluminum-lithium alloys. 1. A solid-rocket propellant comprising an aluminum-lithium alloy , an oxidizer , and a binder , wherein the ratio of lithium to aluminum in the alloy is between about 14% and about 34% by weight.2. The solid-rocket propellant of claim 1 , wherein the alloy is crystalline.3. The solid-rocket propellant of wherein the crystalline phase of the alloy is simple cubic.4. The solid-rocket propellant of claim 1 , wherein the amount of aluminum-lithium alloy in the propellant is between about 5% and about 40% by weight claim 1 , the amount of oxidizer is between about 55% and about 79% by weight claim 1 , and the amount of binder is between about 5% and about 25% by weight.5. The solid-rocket propellant of claim 4 , wherein the amount of aluminum-lithium alloy in the propellant is between about 20% and about 40% by weight claim 4 , the amount of oxidizer is between about 55% and about 65% by weight claim 4 , and the amount of binder is from about 8% to about 15%.6. The solid-rocket propellant of claim 1 , further comprising an additive.7. The solid-rocket propellant of claim 6 , wherein the additive is a high explosive claim 6 , a catalyst claim 6 , a burn-rate modifier claim 6 , or a combination thereof.8. The solid-rocket propellant of claim 1 , wherein the oxidizer is ammonium perchlorate claim 1 , and the binder is hydroxyl-terminated polybutadiene claim 1 , carboxyl terminated polybutadiene claim 1 , Polybutadiene acrylonitrile claim 1 , dicyclopentadiene claim 1 , Polyurethane claim 1 , Plasticized nitrocellulose claim 1 , Glycidyl Azide polymers claim 1 , oxetane polymers claim 1 , oxirane polymers claim ...

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05-04-2018 дата публикации

Rocket motor with concentric propellant structures for shock mitigation

Номер: US20180094606A1
Автор: Peter J. Cahill, JR.
Принадлежит: Aerojet Rocketdyne Inc

A solid rocket motor includes a first solid propellant and a second solid propellant at least partially surrounding the first solid propellant. The second solid propellant is resistant to fragment impact and the first solid propellant has a higher impulse than the second solid propellant.

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04-04-2019 дата публикации

PROPELLANT CHARGE OR GRAIN

Номер: US20190100474A1

The invention is directed to a propellant charge, to a method of preparing a propellant charge, and to uses of the propellant charge. The propellant charge or grain of the invention comprises two or more energetic materials with different linear burn rate, wherein the two or more energetic materials are distributed within the charge or grain such that two perpendicular cross-sections of said propellant charge or grain have at least two linear burn rate gradients in non-parallel directions, wherein said propellant charge or grain is layered with layers having a layer thickness in the range of 1-10 000 μm, wherein, if the propellant charge or grain has a longitudinal axis, at least one of said perpendicular cross-sections is along said longitudinal axis, and wherein said propellant charge or grain further comprises one or more perforations. 1. A propellant charge or grain , comprising two or more energetic materials with different linear burn rate , wherein the two or more energetic materials are distributed within the charge or grain such that two perpendicular cross-sections of said propellant charge or grain each have at least two linear burn rate gradients in non-parallel directions ,wherein said propellant charge or grain is layered with layers having a layer thickness in the range of 1-10 000 μm, wherein, if the propellant charge or grain has a longitudinal axis, at least one of said perpendicular cross-sections is along said longitudinal axis, andwherein said propellant charge or grain further comprises one or more perforations.2. The propellant charge or grain of claim 1 , wherein the two or more energetic materials are present in different layers.3. The propellant charge or grain of claim 1 , wherein said propellant charge or grain further comprises two or more perforations.4. The propellant charge or grain of claim 1 , wherein the propellant charge or grain is layered with layers having a layer thickness in the range of 10-5000 μm.5. The propellant charge or ...

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28-05-2015 дата публикации

POLYPHOSPHAZENES

Номер: US20150144017A1
Принадлежит:

Optically sensitised binders which are energetic polyphosphazenes tailored at the molecular level to achieve enhanced absorption of electromagnetic radiation by having attached thereto a chromophore to absorb light and therefore ignite the binder in use. 1. An optically sensitised binder which is an energetic polyphosphazene tailored at the molecular level to achieve enhanced absorption of electromagnetic radiation by having attached thereto a chromophore to absorb light and therefore ignite the binder in use.2. The binder of being a substituted polyphosphazene compound comprising an energetic group and a chromophore group.4. The binder of wherein at least one Rand/or at least one Rcomprises an optionally substituted alkyl- or alkyl ether-based bridging group having 1 to 10 carbon atoms.5. The binder of wherein at least one Ror energetic group contains nitro claim 1 , nitramine claim 1 , nitrate ester claim 1 , azide claim 1 , an ammonium compound moiety with energetic counter-ion claim 1 , or combinations thereof.6. The binder of wherein at least one Rcomprises one or more of: C(alkyl)CH(ONO)CH(ONO); C(alkyl)CH(N)CH(N); C(alkyl)CH(N); C(alkyl)CH(ONO); and an alkyl or alkyl ether based ammonium compound side chain with an energetic counter ion; or combinations thereof.7. The binder of claim 1 , wherein the chromophore absorbs claim 1 , or is suitable for enhancing the absorption of claim 1 , radiation having a wavelength in the range of from 600 to 1000 nm.8. The binder of claim 1 , wherein the chromophore is selected and attached in an amount sufficient to allow the binder to be more readily ignited by light generated by laser or flash tubes.9. The binder of claim 1 , wherein the chromophore is selected and attached to provide a binder which is ignitable by a diode laser with a power of 44.5 W at 801 nm wavelength claim 1 , a pulse duration of approximately 0.3 s claim 1 , with the laser beam being focussed to produce a nominal beam spot size of 0.3 mm diameter on ...

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18-09-2014 дата публикации

Desensitisation of energetic materials

Номер: US20140261928A1
Автор: Douglas C. Wagstaff

An energetic material comprises an energetic crystalline material substantially coated in an energetic plasticiser material. Advantageously the energetic material comprises from 90 to 99% by weight of an energetic crystalline material and from 1 to 10% by weight of an energetic plasticiser material comprising a plasticiser selected from the group comprising Butane Triol trinitrate (BTTN), Trimethylanol ethane trinitrate (TMETN), Diazidonitrazapentane (DANPE), Glycidyl Azide Polymer (Azide Derivative) (GAP Azide), Bis(2,2-dinitropropyl)acetal/bis(2,2-dinitropropyl)formal (BDNPA/F) or mixtures of two or more of these plasticisers. The inventors have found that the combination of just a small quantity of energetic plasticiser material to the energetic crystalline material prior to incorporation into the bulk plasticiser, binder and filler mixture of an explosive or propellant composition has unexpected and advantageous effects.

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24-08-2017 дата публикации

Solid-rocket Propellants

Номер: US20170240484A1
Принадлежит: PURDUE RESEARCH FOUNDATION

Solid-fuel rocket propellants comprising an oxidizer, an oxophilic metal-halophilic metal formulation, and a binder are described herein. Further described are processes for preparing such propellants and methods of reducing hydrogen chloride production via the combustion of such propellants. Non-limiting examples of such formulations include aluminum-lithium alloys. 1. A solid-rocket propellant comprising an aluminum-lithium alloy wherein the ratio of lithium to aluminum is between about 14% and about 34% by weight , an oxidizer , and a binder.2. The solid-rocket propellant of claim 2 , wherein the alloy is crystalline.3. The solid-rocket propellant of wherein the crystalline phase of the alloy is simple cubic.4. The solid-rocket propellant of claim 1 , wherein the amount aluminum-lithium alloy in the propellant is between about 5% and about 40% by weight claim 1 , the amount of oxidizer is between about 55% and about 79% by weight claim 1 , and the amount of binder is between about 5% and about 25% by weight.5. The solid-rocket propellant of claim 4 , wherein the amount aluminum-lithium alloy in the propellant is between about 20% and about 40% by weight claim 4 , the amount of oxidizer is between about 55% and about 65% by weight claim 4 , and the amount of binder is about 8% claim 4 , 9% claim 4 , 10% claim 4 , 11% claim 4 , 12% claim 4 , 13% claim 4 , 14% claim 4 , or 15%.6. The solid-rocket propellant of claim 1 , further comprising an additive.7. The solid-rocket propellant of claim 6 , wherein the additive is a high explosive claim 6 , a catalyst claim 6 , a burn-rate modifier claim 6 , or a combination thereof.8. The solid-rocket propellant of claim 1 , wherein the oxidizer is ammonium perchlorate claim 1 , and the binder is hydroxyl-terminated polybutadiene claim 1 , carboxyl terminated polybutadiene claim 1 , Polybutadiene acrylonitrile claim 1 , dicyclopentadiene claim 1 , Polyurethane claim 1 , Plasticized nitrocellulose claim 1 , Glycidyl Azide ...

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05-09-2019 дата публикации

POLYMER COMPOSITE HAVING DISPERSED TRANSITION METAL OXIDE PARTICLES

Номер: US20190270684A1
Принадлежит:

A method of forming polymer composites includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including the transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles. 1. A method of forming polymer composites , comprising:mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for said polymer, and water to form a first solution including polymer-transition metal complexes;hydrolyzing said polymer-transition metal complexes to produce a plurality of transition metal oxide nanoparticles, wherein said water is added in said mixing in a stoichiometric excess for said hydrolyzing, andremoving said solvent and residual of said water remaining after said hydrolyzing,wherein a polymer composite including said plurality of transition metal oxide nanoparticles dispersed in said polymer results after said removing, andwherein some of said polymer is chemically conjugated to a surface of said transition metal oxide nanoparticles.2. The method of claim 1 , wherein said polymer provides OH functionality or COOH functionality.3. The method of claim 1 , wherein said transition metal comprises titanium.4. The method of claim 1 , wherein before said mixing said transition metal oxide precursor is combined with a chelating agent claim 1 , and wherein said mixing comprises adding said transition metal oxide precursor ...

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06-10-2016 дата публикации

COMPOSITE PYROTECHNIC PRODUCT WITH CROSSLINKED BINDER AND METHOD FOR PREPARING SAME

Номер: US20160289134A1
Принадлежит:

A composite pyrotechnic product, especially a propellant powder for barrel weapons, containing organic energetic charges in a crosslinked binder, has a composition, expressed as weight percentages, that contains from 78% to 90% of organic energetic charges, and from 10% to 22% of an energetic crosslinked binder obtained by crosslinking, via 8% to 12% of its azide functions, a polyglycidyl azide with a number-average molecular weight of between 700 and 3000 g/mol, with a crosslinking agent containing at least two propargyl functions in its chemical formula, in the presence of a polymeric gum, chosen from polyurethane-polyester gums, polyurethane-polyether gums and mixtures thereof, the number-average molecular weight of which is greater than 20000 g/mol and the Mooney viscosity of which is between 20 and 70 ML (5+4) at 100° C.; the at least one polymeric gum representing from 1% to 5% by weight of the composition of the pyrotechnic product. 1. A composite pyrotechnic product containing organic energetic charges in a crosslinked binder , wherein a composition of said composite pyrotechnic product , expressed as weight percentages , contains:from 78% to 90% of organic energetic charges, andfrom 10% to 22% of an energetic crosslinked binder obtained by crosslinking, via only 8% to 12% of its azide functions, a polyglycidyl azide with a number-average molecular weight of between 700 and 3000 g/mol, with at least one crosslinking agent containing at least two propargyl functions in its chemical formula, in the presence of a polymeric gum, chosen from polyurethane-polyester gums, polyurethane-polyether gums and mixtures thereof, a number-average molecular weight of which is greater than 20000 g/mol and a Mooney viscosity of which is between 20 and 70 ML (5+4) at 100° C.; said at least one polymeric gum representing from 1% to 5% by weight of the composition of said pyrotechnic product.2. The composite pyrotechnic product as claimed in claim 1 , wherein said organic ...

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11-10-2018 дата публикации

HIGH PERFORMANCE COMPOSITE PYROTECHNIC PRODUCT WITHOUT Pb IN ITS COMPOSITION, AND PREPARATION THEREOF

Номер: US20180290945A1
Принадлежит:

A high performance composite pyrotechnic product without lead in its composition, and that can be obtained on an industrial scale without encountering a problem of potlife for the intermediate paste, the product containing organic energetic charges and a combustion catalyst in a plasticized binder including a cured energetic polymer and at least one energetic plasticizer. In characteristic manner, the cured energetic polymer consists of a glycidyle azide polymer (GAP) having number average molecular weight (Mn) lying in the range 700 g/mol to 3000 g/mol, cured via its hydroxyl terminal functions with at least one curing agent of polyisocyanate type; and the combustion catalyst consists of bismuth citrate. 1. A composite pyrotechnic product containing organic energetic charges and a combustion catalyst in a plasticized binder comprising a cured energetic polymer and at least one energetic plasticizer , wherein:said cured energetic polymer consists of a glycidyle azide polymer (GAP) having number average molecular weight (Mn) lying in the range 700 g/mol to 3000 g/mol, cured via its hydroxyl terminal functions with at least one curing agent of polyisocyanate type; andsaid combustion catalyst consists of bismuth citrate.2. The composite pyrotechnic product according to claim 1 , wherein said glycidyle azide polymer (GAP) has number average molecular weight (Mn) lying in the range 1700 g/mol to 2300 g/mol.3. The composite pyrotechnic product according to claim 1 , wherein said at least one energetic plasticizer is of the nitrate and/or nitramine type.4. The composite pyrotechnic product according to claim 1 , wherein said organic energetic charges are selected from:hexogen, octogen, hexanitrohexaazaisowurtzitane, nitroguanidine, ethylene dinitramine, N-guanylurea dinitramide, 1,1 -diamino-2,2-dinitro ethylene, bis(triaminoguanidinium)-5,5′-azotetrazolate, dihydrazinium 5,5′-azotetrazolate, 5,5′-bis(tetrazolyl)hydrazine, bis(2,2-dinitropropyl) nitramine, and ...

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09-11-2017 дата публикации

A composite pyrotechnic product with adn and rdx charges in a gap type binder, and preparation thereof

Номер: US20170320787A1
Принадлежит: AIRBUS SAFRAN LAUNCHERS SAS

A composite pyrotechnic product containing energetic charges in a plasticized binder includes a cured energetic polymer and at least one energetic plasticizer, wherein: the cured energetic polymer consists of a glycidyl azide polymer (GAP) having a number average molecular weight (Mn) lying in the range 700 g/mol to 3000 g/mol and cured via its hydroxyl terminal functions with at least one curing agent of polyisocyanate type; and the energetic charges present at a content in the range 50% to 70% by weight consisting, for at least 95% of their weight, of large crystals of ammonium dinitramide (ADN) and of small crystals of hexogen (RDX): the large crystals of ammonium dinitramide (ADN) being present at a content in the range 8% to 65% by weight; and the small crystals of hexogen (RDX) being present at a content in the range 5% to 55% by weight.

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10-12-2015 дата публикации

POLYMER COMPOSITE HAVING DISPERSED TRANSITION METAL OXIDE PARTICLES

Номер: US20150353438A1

A method of forming polymer composites having transition metal oxide nanoparticles dispersed therein includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including a plurality of transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles. 1. A method of forming polymer composites having transition metal oxide nanoparticles dispersed therein , comprising:mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for said polymer, and water to form a first solution including polymer-transition metal complexes;hydrolyzing said polymer-transition metal complexes to produce a plurality of transition metal oxide nanoparticles, wherein said water is added in said mixing in a stoichiometric excess for said hydrolyzing, andremoving said solvent and residual of said water remaining after said hydrolyzing,wherein a polymer composite including said plurality of transition metal oxide nanoparticles dispersed in said polymer results after said removing, and wherein some of said polymer is chemically conjugated to a surface of said transition metal oxide nanoparticles.2. The method of claim 1 , wherein said polymer provides OH functionality or COOH functionality.3. The method of claim 1 , wherein said transition metal comprises titanium.4. The method of claim 1 , wherein before said mixing said transition metal oxide ...

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22-10-2020 дата публикации

IN-SITU SOLID ROCKET MOTOR PROPELLANT GRAIN AGING USING HYDRAULICALLY ACTUATED BLADDER

Номер: US20200333226A1
Принадлежит: GOODRICH CORPORATION

A method for non-destructively determining a mechanical property of a solid rocket motor propellant grain may comprise applying a force to a surface of the solid rocket motor propellant grain, wherein a deformation is formed on the surface of the solid rocket motor propellant grain in response to the applying, and calculating a value of the mechanical property of the solid rocket motor propellant grain based on the deformation. This process may be performed over time to determine a lifespan of the propellant grain. 1. A method for non-destructively aging a solid rocket motor propellant grain , comprising:applying a force to a surface of the solid rocket motor propellant grain via a liquid, wherein a deformation is formed on the surface of the solid rocket motor propellant grain in response to the application of the force; andmeasuring at least one of a pressure of the liquid and a volume of the liquid.2. The method of claim 1 , wherein the solid rocket motor propellant grain is a solid mass with an exposed inner surface area defining a perforation in the interior of the solid rocket motor propellant grain.3. The method of claim 1 , further comprising determining a lifespan of the solid rocket motor propellant grain based on at least one of the pressure of the liquid and the volume of the liquid.4. The method of claim 2 , further comprising:disposing a bladder into the perforation;moving the liquid into the perforation, wherein the force is applied to the surface in response to the liquid being moved into the perforation of the solid rocket motor propellant grain; andmeasuring the pressure of the liquid immediately after the liquid has reached equilibrium with the solid rocket motor propellant grain.5. The method of claim 4 , wherein the liquid is pressurized in response to moving the liquid into the perforation claim 4 , wherein the deformation is formed in response to the liquid being pressurized.6. The method of claim 5 , wherein the liquid is contained within the ...

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11-12-2020 дата публикации

Cross-linking type fusible casting energetic polymer adhesive material

Номер: CN112062926A
Автор: 李霄羽, 胡耀芳
Принадлежит: Beijing Institute of Technology BIT

本发明涉及一种交联型可熔铸含能高分子粘合剂材料,属于推进剂领域。本发明原料包括:含能高分子,二异氰酸酯,二硫化物和交联剂;溶剂包括:四氢呋喃、二氯甲烷、三氯甲烷、丙酮、丁酮、N,N‑二甲基甲酰胺、N,N‑二甲基乙酰胺等。本发明制备的粘合剂材料,粘度大、可流动、力学性能优良、产率高且循环可持续。在中等温度下(90℃),这种交联的高分子粘合剂可以转变为熔融态的线性高分子流体,在推进剂体系中,可以有效地阻止固体组分的沉降,从而制备出均一的推进剂燃料。

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11-12-2017 дата публикации

Solid propellant composition using a energetic thermoplastic binder

Номер: KR101807432B1

The present invention relates to a solid propelling composition using a high energy thermoplastic binder. The composition comprises: 5-40 wt% of a thermoplastic binder; 20-90 wt% of an oxidizer; 1-20 wt% of a plasticizer; 0.1-30 wt% of a metal compound; and 0.1-3.0 wt% of pentaerythritol tetrakis, polyisobutylene, dioctyl tin-monooctyl tin compound, fluoric surfactant, and stearic acid calcium each as additives. The thermoplastic binder comprises an elastic polymer containing 10-90 wt% of glycidyl azide polymer. The plasticizer comprises at least one selected from a group comprising n-ethylic toluene sulfone amide, dioctyl phthalate, and dioctyl adipate. As such, the present invention is capable of providing a solid propellant having thermal plasticity even after a curing reaction and having specific thrust that is 2.5% higher than those of existing propellants.

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29-11-2019 дата публикации

One kind terminal isocyanate group curing agent containing energy and its synthetic method

Номер: CN110511372A

本发明属于固体推进剂领域,具体涉及一种含能端异氰酸酯基固化剂及其合成方法,其结构式如下:

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09-01-2013 дата публикации

Thermosetting solid propellant composition comprising tertiary amine, and method for controling cure rate of the composition

Номер: KR101213410B1
Автор: 박영철, 유지창, 임유진
Принадлежит: 국방과학연구소

본 발명은 연소 특성 개선제로서 비스무스 서브살리실레이트(bismuth subsalicylate)를 포함하는 나이트레이트 에스테르 폴리에테르계 열경화성 고체 추진제 조성물에 있어서, 3차 아민을 추가적으로 포함하는 것을 특징으로 하는 조성물에 관한 것이다. The present invention relates to a nitrate ester polyether-based thermosetting solid propellant composition comprising bismuth subsalicylate as a combustion characteristics improving agent, wherein the composition further comprises a tertiary amine.

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29-03-2022 дата публикации

Preparation method of energy-containing thermoplastic elastomer compound

Номер: CN112047793B

发明公开一种含能热塑性弹性体复合物的制备方法,特别涉及一种巯基功能化氧化石墨烯/聚叠氮缩水甘油醚基含能热塑性弹性体(GAP‑ETPE)复合物的制备方法,该方法制备的巯基功能化氧化石墨烯/GAP‑ETPE复合物的玻璃化温度可以提高原有GAP‑ETPE的热稳定性,热分解温度推迟了0.5℃~3.7℃,并降低原有GAP‑ETPE的玻璃化温度,降低温度范围0.6℃~3.8℃,并且制备方法容易,成本较低。

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10-12-2010 дата публикации

DENSE EXPLOSIVE LOAD AND DECOUPAGE DETONATING CORDE

Номер: FR2936796B1
Принадлежит: Eurenco France SA

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29-05-2015 дата публикации

COMPOSITE PYROTECHNIC PRODUCT WITH RETICULATED BINDER AND PROCESS FOR PREPARING THE SAME

Номер: FR3013706A1
Принадлежит: Eurenco France SA, Eurenco SA, Herakles SA

La présente invention a pour objet un produit pyrotechnique composite, notamment une poudre propulsive pour armes à tube, renfermant des charges énergétiques organiques dans un liant réticulé. De façon caractéristique, la composition dudit produit, exprimée en pourcentages massiques, renferme : - de 78 à 90 %, avantageusement de 80 à 86 %, de charges énergétiques organiques, et - de 10 à 22 % d'un liant réticulé énergétique obtenu par réticulation, via seulement 8 à 12 % de ses fonctions azide, d'un polyazoture de glycidyle ayant une masse moléculaire moyenne en nombre comprise entre 700 et 3 000 g/mol, avec au moins un agent de réticulation renfermant au moins deux fonctions propargyle dans sa formule chimique, en présence d'au moins une gomme polymérique, choisie parmi les gommes polyuréthanne-polyester , les gommes polyuréthanne-polyéther et leurs mélanges, dont la masse moléculaire moyenne en nombre est supérieure à 20 000 g/mol et dont la viscosité Mooney est comprise entre 20 et 70 ML (5 +4) à 100°C ; ladite au moins une gomme polymérique représentant de 1 à 5 % en masse de la composition dudit produit pyrotechnique. Elle concerne également l'obtention desdits produits. Lesdits produits sont particulièrement intéressants de par leur propriétés et la simplicité de leur obtention.

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03-03-2000 дата публикации

NEW NON-DETONATED PYROTECHNIC MATERIALS FOR MICROSYSTEMS

Номер: FR2774684B1

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28-12-1993 дата публикации

Energetic materials containing heteroalicyclic nitramine compound

Номер: CA1325518C
Принадлежит: Royal Ordnance PLC

ABSTRACT An energetic composition comprising the following components in the following relative proportions: Component A: from 5% to 25% by weight of a polymeric binder; Component B: from 65% to 90% by weight of a highly energetic filler comprising at least one heteroalicyclic nitramine compound; and Component C: from 1% to 15% by weight of a plasticiser which comprises at least one nitroaromatic compound; the percentages by weight of Components A, B and C adding to 100%.

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17-01-1992 дата публикации

MATERIALS RICH IN ENERGY.

Номер: FR2664587A1
Принадлежит: Royal Ordnance PLC

Une composition riche en énergie contenant les constituants suivants, dans les proportions relatives suivantes: constituant A: 5 à 25 % en poids d'un liant polymère, constituant B: 65 à 90 % en poids d'une charge très riche en énergie contenant au moins un composé de nitramine hétéroalicyclique, et constituant C: 1 à 15 % en poids d'un plastifiant qui contient au moins un composé nitroaromatique, les pourcentages pondéraux des constituants A, B et C atteignant 100 %. An energy-rich composition containing the following constituents, in the following relative proportions: component A: 5 to 25% by weight of a polymer binder, component B: 65 to 90% by weight of a very high energy filler containing less one heteroalicyclic nitramine compound, and component C: 1 to 15% by weight of a plasticizer which contains at least one nitroaromatic compound, the weight percentages of components A, B and C reaching 100%.

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14-12-1973 дата публикации

Propellant powder - contg ammonium nitrate, nitrocellulose and polyvinyl nitrate

Номер: FR2182662A2
Автор:
Принадлежит: ETAT FRANCAIS

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29-12-1989 дата публикации

HYDROXYLALLY TERMINATED POLYEPICHLORHYDRIN COMPOUNDS, DERIVATIVES, AND PROCESSES FOR THEIR MANUFACTURE

Номер: FR2633300A1
Принадлежит: Minnesota Mining and Manufacturing Co

On polymérise l'épichlorhydrine avec un initiateur renfermant de l'hydrogène actif, puis on fait réagir la polyépichlorhydrine à hydroxyle secondaire obtenue pour produire un composé polyépichlorhydrine à terminaison hydroxyle dont des chaînes se terminent par un groupe hydroxyle primaire, ce composé polyépichlorhydrine pouvant réagir avec un acide non organique pour produire un composé poly(glycidyl acide) utilisable comme liant pour des propulseurs solides de fusées. Epichlorohydrin is polymerized with an initiator containing active hydrogen, then the resulting secondary hydroxyl polyepichlorohydrin is reacted to produce a hydroxyl terminated polyepichlorohydrin compound whose chains terminate in a primary hydroxyl group, which polyepichlorohydrin compound can react with an inorganic acid to produce a poly (glycidyl acid) compound useful as a binder for solid rocket propellants.

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12-10-2001 дата публикации

ENERGETIC PLASTICIZER COMPRISING A EUTECTIC MIXTURE OF BIS (2,2-DINITROPROPYL) FORMAL, 2,2 DINITROPROPYL-2,2-DINITROBUTYLFORMAL AND BIS (2,2-DINITROBUTYL) FORMAL, AND PROCESS FOR PREPARING THE SAME

Номер: FR2807427A1
Принадлежит: Agency for Defence Development

L'invention concerne un plastifiant énergétique comprenant du bis (2,2-dinitropropyl) formal, du 2, 2-dinitropropyl-2, 2-dinitrobutylformal et du bis (2, 2-dinitrobutyl) formal dans un rapport molaire de 20 à 68 %/ 28 à 50 %/ 4 à 30 % ainsi qu'un procédé pour sa préparation qui comprend la dissolution de 2, 2-dinitropropanol et de 2, 2-dinitrobutanol dans un solvant organique pour former une solution organique dans laquelle le rapport molaire du 2, 2-dinitropropanol au 2, 2-dinitrobutanol est 3 : 1-6 : 1, l'addition à la solution organique d'une solution d'acide sulfurique dans laquelle une source de formaldéhyde a été dissoute, tandis que la température du mélange réactionnel est maintenue inférieure à 20degreC, et la séparation et la purification du produit à partir du mélange réactionnel. The invention relates to an energetic plasticizer comprising bis (2,2-dinitropropyl) formal, 2,2-dinitropropyl-2,2-dinitrobutylformal and bis (2,2-dinitrobutyl) formal in a molar ratio of 20 to 68. % / 28 to 50% / 4 to 30% and a process for its preparation which comprises dissolving 2, 2-dinitropropanol and 2,2-dinitrobutanol in an organic solvent to form an organic solution in which the molar ratio from 2, 2-dinitropropanol to 2, 2-dinitrobutanol is 3: 1-6: 1, adding to the organic solution a sulfuric acid solution in which a source of formaldehyde has been dissolved, while the temperature the reaction mixture is kept below 20 ° C, and the separation and purification of the product from the reaction mixture.

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09-04-2010 дата публикации

DENSE EXPLOSIVE LOAD AND DECOUPAGE DETONATING CORDE

Номер: FR2936796A1
Принадлежит: Eurenco France SA

La présente invention a pour objet : - une charge explosive dense (C) se présentant sous la forme d'une barre (1) qui comporte une rainure longitudinale (2) ; ainsi qu' - un cordeau détonant de découpage (10). Ledit cordeau (10) comprend, voire consiste en, une telle charge (C). En effet, une telle charge (C) est per se efficace à titre de cordeau détonant de découpage. The present invention relates to: - a dense explosive charge (C) in the form of a bar (1) which comprises a longitudinal groove (2); as well as - a detonating cutting line (10). The cord (10) comprises, or even consists of, such a charge (C). Indeed, such a load (C) is per se effective as a detonating cutting line.

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13-02-1976 дата публикации

Explosive powder contg nitrocellulose and polyvinyl nitrate - plus aluminium or magnesium to enhance power and reduce combustion temp

Номер: FR2278657A1
Автор: Louis Leneveu

A powder compsn. used in explosives and firing devices and contg. polyvinylnitrate and nitrocellulose in the wt. ratio between 0.10 and 0.66 is improved by the incorporation of a strongly reducing metal chosen from Al and Mg. The powder has increased power and lower combustion temperature. Amt. of metal used is 0-5 wt. % based on the other components. Particle size of the metal is approx. 20 mu. The powder is pref. made porous by incorporating (0-60%) a soluble salt at the time of mixing and then washing the salt out of the compsn.

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27-02-1981 дата публикации

Patent FR2436766B1

Номер: FR2436766B1
Автор: [UNK]

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25-12-2015 дата публикации

STABILIZED COMPOSITE PROPERGOLS

Номер: FR3014431B1
Принадлежит: Herakles SA

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30-08-1985 дата публикации

POLYMERS OF POLYNITROAROMATIC COMPOUNDS

Номер: FR2410011B1
Автор: [UNK]
Принадлежит: Dynamit Nobel AG

Подробнее
16-07-1976 дата публикации

Tertiary powder for large calibre weapons= - comprising nitrocellulose, polyvinyl nitrate and nitro-guanidine (BE170676)

Номер: FR2294998A1
Автор: Louis Leneveu

Tertiary powder for large calibre weapons comprising 80-20 wt.% nitrocellulose, 10-45 wt.% polyvinyl nitrate and 10-35 wt.% nintroguanidine. the nitrocellulose pref. has high nitogen content to confer max. propulsive power. The powder is prod. by the well-known methods used for powders based on nitrocellulose, the prodn. being concluded by graphitisation to achieve a very hgh apparent density. Pref. a muzzle-flash dampening agent, eg. caclcium cryolite is added. The powder has use capabilities comparable with a powder based on nitroglycerine, nitrocellulose and nitroguanidine but has a lower burning temp.

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10-03-1995 дата публикации

Solid propellant with a binder containing a noncrystalline polyether and an energetic plasticiser.

Номер: FR2709488A1
Принадлежит: HERCULES LLC

Solid propellant composition including an oxidising agent, a fuel, a binder and at least one other additive. This composition contains a binder including, relative to the weight of the total propellant composition: (a) 3 to 12 % of a noncrystalline polyether which has a molecular weight of between 1250 and 9000 and (b) 1 to 12 % of an energetic plasticiser which has a positive heat of explosion. The propellant composition according to the invention is intended in particular for surface-to-air or surface-to-surface interceptors, for air-to-surface or air-to-air tactical engines and for space boosters.

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29-04-2016 дата публикации

COMPOSITE PYROTECHNIC PRODUCT WITH DNA AND RDX LOADS IN PAG TYPE BINDER AND PREPARATION THEREOF

Номер: FR3027598A1
Принадлежит: Herakles SA

La présente invention a pour objet un produit pyrotechnique composite, renfermant des charges d'ADN et de RDX dans un liant plastifié, comprenant un polymère énergétique, de type PAG, réticulé et au moins un plastifiant énergétique, et sa préparation. De façon caractéristique : - ledit polymère énergétique réticulé consiste en un polyazoture de glycidyle (PAG), ayant une masse moléculaire moyenne en nombre (Mn) comprise entre 700 et 3000 g/mol, réticulé, via ses fonctions terminales hydroxyles, avec au moins un agent de réticulation de type polyisocyanate ; et - lesdites charges énergétiques, présentes à un taux massique de 50 à 70 %, consistent, pour au moins 95 % de leur masse, en de gros cristaux de dinitroamidure d'ammonium (ADN) et de petits cristaux d'hexogène (RDX) : + lesdits gros cristaux d'ADN étant présents à un taux massique de 8 à 65 %, avantageusement de 10 à 60 %, et + lesdits petits cristaux d'hexogène (RDX) étant présents à un taux massique de 5 à 55 %, avantageusement de 8 à 50 %. The present invention relates to a composite pyrotechnic product containing DNA and RDX fillers in a plasticized binder, comprising an energy polymer, of the PAG type, crosslinked and at least one energetic plasticizer, and its preparation. Typically: said crosslinked energy polymer consists of a glycidyl polyazide (PAG) having a number-average molecular weight (Mn) of between 700 and 3000 g / mol, crosslinked, via its hydroxyl terminal functions, with at least one polyisocyanate crosslinking agent; and said energetic charges, present at a mass ratio of 50 to 70%, consist, for at least 95% of their mass, of large ammonium dinitroamide crystals (ADN) and small hexogen crystals (RDX) + said large crystals of DNA being present at a mass ratio of 8 to 65%, advantageously from 10 to 60%, and + said small hexogen crystals (RDX) being present at a mass ratio of 5 to 55%, advantageously from 8 to 50%.

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12-12-2003 дата публикации

DESENSITIZATION OF ENERGY MATERIALS

Номер: FR2840604A1
Принадлежит: Royal Ordnance PLC

Un matériau énergétique comprend un matériau cristallin énergétique pratiquement enrobé dans un matériau plastifiant énergétique. Le matériau énergétique comprend avantageusement de 90 à 99% en poids d'un matériau cristallin énergétique et de 1 à 10% en poids d'un matériau plastifiant énergétique comprenant un plastifiant sélectionné parmi le butanetrioltrinitrate (BTTN), le triméthylanoléthanetrinitrate (TMETN), le diazidonitrazapentane (DANPE), le polymère de glycidylazide (dérivé d'azide) (GAP Azide), le bis (2, 2-dinitropropyl) acétal / bis (2, 2-dinitropropyl) formal (BDNPA/F), ou des mélanges de deux ou plus de ces plastifiants.Application aux charges propulsives ou explosives. An energetic material comprises an energetic crystalline material substantially embedded in an energetic plasticizer material. The energetic material advantageously comprises from 90 to 99% by weight of an energetic crystalline material and from 1 to 10% by weight of an energetic plasticizer material comprising a plasticizer selected from butanetrioltrinitrate (BTTN), trimethylanolethanetrinitrate (TMETN), diazidonitrazapentane (DANPE), polymer of glycidylazide (azide derivative) (GAP Azide), bis (2, 2-dinitropropyl) acetal / bis (2, 2-dinitropropyl) formal (BDNPA / F), or mixtures of two or more of these plasticizers.Application to propellant or explosive charges.

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30-01-1996 дата публикации

Composite gun propellant processing technique

Номер: US5487851A
Принадлежит: Thiokol Corp

A continuous extrusion process for manufacturing composite gun propellant is disclosed. The disclosed process is particularly suitable for preparing gun propellant formulations based upon a cellulose ester binder. In the process, the binder ingredients are dissolved in an organic solvent and then pumped directly into a twin-screw extruder. The other ingredients, except the oxidizer, may optionally be dissolved in the organic solvent prior to introduction into the twin-screw extruder. The oxidizer is dried, ground, and also fed dry to the twin-screw extruder. In the extruder, the materials are thoroughly mixed and the solvent is reduced to sufficient level for direct extrusion through the desired dies.

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15-05-1997 дата публикации

Solid propellant composition

Номер: DE4026468A1
Принадлежит: HERCULES LLC

Solid propellant composition comprises an oxidant, a fuel, a binder and an additive selected from a stabiliser, an additive for increasing combustion, an adhesive, a scavenger, or a catalyst. The novelty is that a binder is used which contains: (a) 3-12% non-crystalline polyether having a molecular weight of 1250-9000; and (b) 1-12% of an energy-rich plasticiser having a positive heat of explosion.

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10-02-1981 дата публикации

Polymers obtained from polynitroaromatic compounds

Номер: US4250294A
Принадлежит: Dynamit Nobel AG

A polymer having aromatic or heterocyclic rings as the only structural elements said aromatic or heterocyclic rings containing at least two nitro groups is disclosed as well as a method of preparing the same. The polymers are useful as binding agents for thermo stable propellants and can be easily formed into films. They remain thermally stable up to temperatures of at least 200° C.

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18-01-1994 дата публикации

Vapor generator with porous partition

Номер: CA2100301A1
Автор: Bernard Dangreau

"Générateur de vapeur à cloisons poreuses" Société dite : ETS TROUVAY \A CAUVIN et Société dite : ARMSTRONG INTERNATIONAL INC. a) Générateur de vapeur comprenant une alimentation en eau à évaporer, une sortie de vapeur et une source de chaleur ; b) générateur de vapeur caractérisé en ce qu'il est formé d'un boîtier subdivise en deux chambres (2, 3) par une cloison poreuse (4), perméable à l'eau, - l'une (3) des deux chambres recevant la source de chaleur (6), - l'autre chambre (2) recevant l'eau d'alimentation (5). Figure 1 jointe. "Steam generator with porous partitions" Company known as: ETS TROUVAY \ A CAUVIN and Company known as: ARMSTRONG INTERNATIONAL INC. a) Steam generator comprising a water supply to be evaporated, a steam outlet and a heat source; b) steam generator characterized in that it is formed from a housing subdivided into two chambers (2, 3) by a porous partition (4), permeable to water, - one (3) of the two chambers receiving the heat source (6), - the other chamber (2) receiving the supply water (5). Figure 1 attached.

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06-03-2014 дата публикации

Nitroglycerine-free multi-perforated high-performing propellant system

Номер: AU2011264361A1
Принадлежит: Nitrochemie Wimmis AG

The propulsion system for the acceleration of projectiles is based on a multi-perforated grain propellant and is composed from nitrocellulose, a crystalline energy carrier of a nitramine type and an inert plasticizing additive. The number of perforations is 2 to 6, preferably 4. The propellant grains can have round or polygonic profiles, depending on the number of perforations. The preferred grain geometry is cubic with a rectangular grain profile. The nitramine compound contains a structural element of the general chemical structure formula R-N-N02, where R is a residual group. The nitramine compound is present in a concentration in the range from 0 to 35% by mass, in particular in the range from 5 to 25% by mass. The nitramine compound is preferably RDX. The inert plasticizing additive is a water-insoluble polyoxo compound, if necessary in combination with a substance containing carboxyl groups. In layers near the surface an increased concentration can be present. The inert plasticizing additive is present in a concentration of 0 to 10% by mass, preferred 0 to 5% by mass.

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07-12-2021 дата публикации

Method of manufacturing multi-layered propellant grains

Номер: CA2920690C

A method of manufacturing a multi-layered propellant grain is provided. The method of the present disclosure simplifies the setup necessary to produce multi-layered propellants by using industrial equipment that is more energy and space efficient than the machinery that is conventionally employed for such processes. The method comprises providing a first propellant formulation; providing a die configured to provide a structure having an outer shell and a hollow interior when material is extruded therethrough; extruding the first propellant formulation through said die, to produce a first propellant layer having an outer shell defining a hollow interior in the form channel having open ends; providing a second propellant formulation, said second propellant formulation being of low viscosity; injecting said second propellant formulation into said channel defined by said first propellant layer to form a second propellant layer disposed in said channel; and hardening said second propellant layer. The first and second propellant layers have different rates of burning.

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19-02-2015 дата публикации

Method of manufacturing multi-layered propellant grains

Номер: WO2015021545A1
Принадлежит: Gd-Ots Canada Valleyfield Inc.

A method of manufacturing a multi-layered propellant grain is provided. The method of the present disclosure simplifies the setup necessary to produce multi-layered propellants by using industrial equipment that is more energy and space efficient than the machinery that is conventionally employed for such processes. The method comprises providing a first propellant formulation; providing a die configured to provide a structure having an outer shell and a hollow interior when material is extruded therethrough; extruding the first propellant formulation through said die, to produce a first propellant layer having an outer shell defining a hollow interior in the form channel having open ends; providing a second propellant formulation, said second propellant formulation being of low viscosity; injecting said second propellant formulation into said channel defined by said first propellant layer to form a second propellant layer disposed in said channel; and hardening said second propellant layer. The first and second propellant layers have different rates of burning.

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27-08-1974 дата публикации

Energetic polynitro halogenated diol ethers

Номер: US3832390A
Автор: E Witucki, M Frankel
Принадлежит: Rockwell International Corp

This invention is concerned with novel, monomeric, aliphatic diols of the general formula: WHEREIN R is a lower alkylene of one to three carbon atoms.

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15-12-2011 дата публикации

Nitroglycerine-free multi-perforated high-performing propellant system

Номер: WO2011153655A2
Принадлежит: Nitrochemie Wimmis AG

The propulsion system for the acceleration of projectiles is based on a multi-perforated grain propellant and is composed from nitrocellulose, a crystalline energy carrier of a nitramine type and an inert plasticizing additive. The number of perforations is 2 to 6, preferably 4. The propellant grains can have round or polygonic profiles, depending on the number of perforations. The preferred grain geometry is cubic with a rectangular grain profile. The nitramine compound contains a structural element of the general chemical structure formula R-N-N02, where R is a residual group. The nitramine compound is present in a concentration in the range from 0 to 35% by mass, in particular in the range from 5 to 25% by mass. The nitramine compound is preferably RDX. The inert plasticizing additive is a water-insoluble polyoxo compound, if necessary in combination with a substance containing carboxyl groups. In layers near the surface an increased concentration can be present. The inert plasticizing additive is present in a concentration of 0 to 10% by mass, preferred 0 to 5% by mass.

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16-06-2009 дата публикации

New non-detonatable pyrotechnical materials for microsystems

Номер: CA2267512C
Принадлежит: SNPE Materiaux Energetiques SA

Un matériau pyrotechnique non détonable, auto--combustible à la pression atmosphérique ou à une pression voisine de celle-ci, comprend un liant énergétique et du perchlorate d'ammonium; le matériau a une épaisseur inférieure à 500 .mu.m ou une masse inférieure à 15 mg, il est auto-combustible après initiation ponctuelle par une puissance électrique P, telle que 150 mW .ltoreq. P .ltoreq. 800 mW, pendant un temps t, tel que 20 ms .ltoreq. t .ltoreq. 600 ms; il comprend aussi: - de 25% à 80% en poids d'un liant énergétique à base de polyazoture de glycidyle (PAG), ou de poly--3,3-bis(azidométhyl)oxétane (BAMO), ou de polyester et d'au moins un plastifiant énergétique, ou de polyéther et d'au moins un plastifiant énergétique, - de 10% à 70% en poids de perchlorate d'ammonium dont la dimension des grains est comprise entre 0,5 et 30 .mu.m, et - de 0% à 45% en poids d'au moins une nitramine.

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22-03-1983 дата публикации

Granular propellant powders based on nitrocellulose, nitrated oil and polyvinyl nitrate, and the process for their manufacture

Номер: CA1143165A

A B S T R A C T The present invention relates to propellant powders based on nitrocellulose, nitrated oil and poly-vinyl nitrate and also to the process for their manu-facture. The powders according to the invention contain between 50 and 75 parts by weight of nitrocellulose, between 5 and 25 parts by weight of nitrated oil and between 5 and 25 parts by weight of polyvinyl nitrate. The manufacturing process consists in malax-ating the energy-producing bases in the presence of an acetone/alcohol mixture until a homogeneous paste is obtained, which is extruded, drained, chopped, soaked and dried, and the process is characterized in that (i) the proportion of acetone in the paste during malaxation is between 30 and 36% by weight, relative to the dry nitrocellulose and the dry polyvinyl nitrate, and in that the weight ratio acetone/alcohol is between 1.10 and 1.50, (ii) the first step is to mix the nitro-cellulose with the nitrated oil in the presence of solvents, and in that the solid polyvinyl nitrate is added to the mixture in portions, and (iii) the draining before chopping is carried out at a temperature below 30°C. The powders according to the invention are particularly suitable as gunpowder for combat tanks.

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28-09-2017 дата публикации

Propellant charge or grain

Номер: WO2017164732A1

The invention is directed to a propellant charge, to a method of preparing a propellant charge, and to uses of the propellant charge. The propellant charge or grain of the invention comprises two or more energetic materials with different linear burn rate, wherein the two or more energetic materials are distributed within the charge or grain such that two perpendicular cross-sections of said propellant charge or grain have at least two linear burn rate gradients in non-parallel directions, wherein said propellant charge or grain is layered with layers having a layer thickness in the range of 1-10 000 μm, wherein, if the propellant charge or grain has a longitudinal axis, at least one of said perpendicular cross-sections is along said longitudinal axis, and wherein said propellant charge or grain further comprises one or more perforations.

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29-07-2002 дата публикации

Synthesis of energetic polyester thermoplastic homopolymers and energetic thermoplastic elastomers formed therefrom

Номер: CA2367795A1

Polymerization of .alpha.-bromomethyl-.alpha.-methyl-.beta.-propiolactone (BMMPL) or .alpha.-chloromethyl-.alpha.-methyl-.beta.-propiolactone (CMMPL) yielded thermoplastic homopolymers that upon azidation led to a novel energetic thermoplastic polyester: poly(.alpha.-azidomethyl-.alpha.-methyl-.beta.-propiolactone) (PAMMPL). An energetic copolyether-ester thermoplastic elastomer was prepared by using glycidyl azide polymer, a dihydroxyl terminated energetic polymer, as a macroinitiator for the polymerization of BMMPL or CMMPL. The azidation of the resulting copolyether-ester yielded an energetic thermoplastic elastomer that melted at between 80°C and 85°C. Polymerization of .alpha.-dibromomethyl-.beta.-propiolactone (DBMPL) resulted in a polymer which upon azidation yielded a new energetic polymer that can be used as a binder or into an energetic thermoplastic elastomer synthesis.

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15-08-2000 дата публикации

Triazole cross-linked polymers

Номер: US6103029A
Автор: Russell Reed, Jr.
Принадлежит: US Department of Navy

Polyethers containing pendant azide groups are cured without a catalyst byyclo-addition with diacetylenes to form triazole cross-linked, energetic binders having improved mechanical properties and stability. The polyethers typically have three hydroxy-terminated chains each of about 5000 to about 50,000 daltons. Ideally, only one azide group per chain reacts by cyclo-addition since the diacetylene is added in a proportion of about one molecule to each two polyether chains. Repeating units of glycidal azide, azidomethylmethyloxetane, bis-azidomethyloxetane/nitratomethylmethyloxetane, and bis-azidomethyloxetane/azidomethylmethyloxetane are believed effective as polyethers when used with the diethynlbenzenes 1,4-bis(ethynl)benzene, 1,4-bis(ethynlcarbonyl)benzene, and 1,3-bis(cyanoethynl)benzene. The polyethers may be further cross-liked at the hydroxyl terminations by urethane bonds.

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07-01-1998 дата публикации

Furazan derivatives containing propellants with a high specific impulse

Номер: EP0816306A1

Propergols containing furazane derivatives with high specific impulse are claimed. They contain a binder, some additives and an energetic feed chosen from dinitro bifurazane consisting of 3,3'-azoxybis Ä4 nitrofurazaneÜ C4N8O7, 3,3'-azobis Ä4 nitrofurazaneÜ C4N8O6 and, 3,3' bis Ä4 nitrofurazaneÜ C4N6O6. They also contain 10 wt.% of a pulverulent metallic feed.

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26-09-2000 дата публикации

Non-detonable pyrotechnic material

Номер: NO991464L
Принадлежит: S N P E Service Propriete Ind

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18-10-1995 дата публикации

Application of beta-octogen with polymodal particle size distribution

Номер: EP0528392B1
Принадлежит: Dynamit Nobel AG

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04-06-1998 дата публикации

Ammonium nitrate propellants with molecular sieve

Номер: CA2273335A1
Принадлежит: Individual

The present invention is directed to an age-stabilized and/or strengthened ammonium nitrate propellant composition wherein the strengthening agent is selected from the group consisting of azodicarbonamide, dicyandiamide, oxamide and mixtures thereof and wherein the age-stabilizing agent is a molecular sieve having a pore size of 13 angstroms or less.

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06-05-2003 дата публикации

Solid solution vehicle airbag clean gas generator propellant

Номер: CA2272558C
Принадлежит: ECOTECH

An ignitable solid gas generating composition comprises a polyalkylammonium binder, usually polyvinylamine nitrate or polyethyleneimmonium nitrate, an oxidizer mixture comprising ammonium nitrate and a first additive which produces an eutectic melt which is liquid at a temperature well below the melting point of the ammonium nitrate as well as that of the first additive, and an additional quantity of the ammonium nitrate and a second additive. Further, combustion modifier additives may be added to the composition.</SDO AB>

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27-03-2003 дата публикации

Production of a mixture of N,N'-dimethylbisnitramine and N,N'-diethylbisnitramine, useful as a plasticizer in propellant charges, comprises nitration using highly concentrated nitric acid

Номер: DE10142126A1

A process for the production of DNDA (I) (a mixture of N,N'-dimethylbisnitramine and N,N'-diethylbisnitramine) by nitration of N,N'-dimethylurea and N,N'-diethylurea, hydrolysis of the dinitrodimethylurea and the dinitrodiethylurea and condensation of the methyl- and ethylnitramines is characterized in that highly concentrated nitric acid is used for the nitration of the ureas.

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01-09-2020 дата публикации

Propellant charge or grain with printed energetic material layers

Номер: US10759719B2

Propellant charges or grains having printed layers of two or more energetic materials are described along with methods for preparing and using them.

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12-10-2010 дата публикации

Desensitisation of energetic materials

Номер: CA2301392C

An energetic material comprises an energetic crystalline material substantially coated in an energetic plasticiser material. Advantageously the energetic material comprises from 90 to 99% by weight of an energetic crystalline material and from 1 to 10% by weight of an energetic plasticiser material comprising a plasticiser selected from the group comprising Butane Triol trinitrate (BTTN), Trimethylanol ethane trinitrate (TMETN), Diazidonitrazapentane (DANPE), Glycidyl Azide Polymer (Azide Derivative) (GAP Azide), Bis(2,2-dinitropropyl)acetal / bis(2,2-dinitropropyl)formal (BDNPA/F) or mixtures of two or more of these plasticisers. The inventors have found that the combination of just a small quantity of energetic plasticiser material to the energetic crystalline material prior to incorporation into the bulk plasticiser, binder and filler mixture of an explosive or propellant composition has unexpected and advantageous effects.

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06-08-1980 дата публикации

Granular propellants based on nitrocellulose, nitrated oil and polyvinyl nitrate and process for producing them

Номер: EP0013850A2

La présente invention concerne des poudres propulsives à base de nitrocellulose, d'huile nitrée et de nitrate de polyvinyle ainsi que leur procédé de fabrication. Les poudres selon l'invention contiennent entre: - 50 et 75 parties en poids de nitrocellulose, - 5 et 25 parties en poids d'huile nitrée, - 5 et 25 parties en poids de nitrate de polyvinyle. Le procédé de fabrication consiste à malaxer les bases énergétiques en présence d'un mélange acétone/alcool jusqu'à l'obtention d'une pâte homogène qui est filée, essorée, découpée, trempée et séchée et se caractérise en ce que: (i) - la teneur de la pâte en acétone au malaxage est comprise entre 30 et 36% en poids par rapport à la nitrocellulose et au nitrate de polyvinyle secs et en ce que le rapport pondéral acétone/alcool est compris entre 1,10 et 1,50. (ii) - on commence par mélanger la nitrocellulose avec l'huile nitrée en présence de solvants et en ce que l'on rajoute le nitrate de polyvinyle solide par fraction au mélange, (iii) - l'essorage avant découpage est effectué à une température inférieure à 30°C. Les poudres selon l'invention conviennent particulièrement bien comme poudres à canon pour chars de combat. The present invention relates to propellant powders based on nitrocellulose, nitrated oil and polyvinyl nitrate as well as their manufacturing process. The powders according to the invention contain between: - 50 and 75 parts by weight of nitrocellulose, - 5 and 25 parts by weight of nitrated oil, - 5 and 25 parts by weight of polyvinyl nitrate. The manufacturing process consists in kneading the energy bases in the presence of an acetone / alcohol mixture until a homogeneous paste is obtained which is spun, wrung, cut, soaked and dried and is characterized in that: (i ) - the content of the acetone in the kneading during mixing is between 30 and 36% by weight relative to the nitrocellulose and the dry polyvinyl nitrate and in that the acetone / alcohol weight ...

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20-12-2019 дата публикации

Non-isocyanate-cured azido polyether adhesive system and propellant

Номер: CN110590484A

本发明涉及一种非异氰酸酯固化的叠氮聚醚粘合剂体系及推进剂,属于固体推进剂技术领域。所述体系包括以下质量份组分:粘合剂54%~96.6%、固化剂3.2%~45.3%、固化催化剂0.2%~1.5%;其中所述粘合剂为聚叠氮缩水甘油醚GAP,所述固化剂为两官能度或多官能度的端炔基聚醚,所述固化催化剂为纳米铜粉和一价铜盐中的至少一种。本发明提供的推进剂固化反应活性较高、反应速率较快,能够在常温下实现固化,解决了药柱固化残留热应力问题;反应机理不受水分影响,可消除环境湿度和原材料水分对固化及力学性能的影响;得到的推进剂力学性能优良,尤其是具有较高的伸长率,伸长率可达到100%以上,远高于国外报道的力学性能水平。

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05-02-2001 дата публикации

Composite propellants

Номер: JP3132524B2
Принадлежит: Daicel Chemical Industries Ltd

Подробнее
02-09-2003 дата публикации

High energy propellant with reduced pollution

Номер: US6613168B2
Принадлежит: US Department of Navy

This invention relates to energetic compositions, which offer increased performance in conjunction with a total absence of hydrogen chloride in the combustion products. The formulation avoid the use of halogen based oxidizers to prevent the formation of halogen based byproducts. The formulations disclosed herein use ammonium dinitramide as a primary oxidizer, which is a more energetic molecule than ammonium perchlorate. The solid propellant formulations disclosed herein comprise about 5.0 to about 10.0 weight % of at least one energetic binder; about 20.0 to about 35.0 weight % of an energetic plasticizer; about 25.0 to about 45.0 weight % of ammonium dinitramide as a primary oxidizer; about 0.0 to about 20.0 weight % of particulate aluminum having a particle size of about 1 μm to about 60 μm; and about 0.0 to about 20.0 weight % of ultrafine aluminum having a particle size of less than 1 μm. In addition to the ingredients in this basic formulation will be cure catalysts, curatives, crosslinkers, burn rate catalysts and modifiers, thermal and aging stabilizers other such ingredients commonly utilized in solid propellant formulations.

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26-12-2002 дата публикации

An energetic plasticizer comprising bis(2,2-dinitropropyl)formal and bis(2,2-dinitropropyl)diformal, and a preparative method thereof

Номер: KR100365648B1
Принадлежит: 국방과학연구소

본 발명은 비스(2,2-디니트로프로필)포름알(BDNPF)과 결정화 방지제를 함유하는 고에너지 가소제에 있어서, 상기 결정화 방지제가 비스(2,2-디니트로프로필)디포름알(BDNPDF)인 것을 특징으로 하는 가소제 및 그 제조 방법에 관한 것이다. The present invention provides a high energy plasticizer containing bis (2,2-dinitropropyl) formal (BDNPF) and an anti-crystallization agent, wherein the anti-crystallization agent is bis (2,2-dinitropropyl) diformal (BDNPDF). It is related with the plasticizer and its manufacturing method characterized by the above-mentioned. BDNPF의 결정화 방지를 위해 BDNPDF를 사용할 경우, -20℃의 온도에서 6개월 이상 방치하더라도 결정화되지 아니하며, 열적/화학적 특성도 우수한 것으로 밝혀졌다. 그리고 반응 부산물로 간주되어온 BDNPDF를 결정화 방지제로 사용함에 의해 BDNPDF를 제거하기 위한 부차적 공정이 불필요하고, 생산비가 저렴하다는 이점이 있다. When BDNPDF was used to prevent crystallization of BDNPF, it was found that even if left at a temperature of -20 ° C. for more than 6 months, it did not crystallize and the thermal / chemical properties were excellent. In addition, the use of BDNPDF, which has been regarded as a reaction by-product, as an anti-crystallization agent has the advantage that a secondary process for removing BDNPDF is unnecessary and the production cost is low.

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02-01-1998 дата публикации

HIGH SPECIFIC IMPULSE PROPERGOLS WITH FURAZANE DERIVATIVES

Номер: FR2750421A1

La présente invention concerne des propergols solides à forte impulsion spécifique et/ou forte impulsion volumique, plus particulièrement des propergols dits "propres", c'est-à-dire ne contenant pas de constituants dont la combustion donne des produits halogénés ou des produits liquides ou solides. Les propergols solides selon l'invention comportent notamment un liant, au moins une charge énergétique et divers additifs, la charge énergétique est essentiellement choisie dans le groupe des bifurazanes dinitrés constitué par le 3,3'-axoxy bis [4 nitofurazane], le 3,3'-azobis [4 nitrofurazane] et le 3,3'bis [4 nitrofurazane]. The present invention relates to solid propellants with a high specific impulse and / or high volumetric impulse, more particularly so-called "clean" propellants, that is to say not containing constituents whose combustion gives halogenated products or liquid products. or solid. The solid propellants according to the invention comprise in particular a binder, at least one energetic filler and various additives, the energetic filler is essentially chosen from the group of dinitrated bifurazanes consisting of 3,3'-axoxy bis [4 nitofurazane], 3 , 3'-azobis [4 nitrofurazane] and 3,3'bis [4 nitrofurazane].

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24-05-1995 дата публикации

Glycidyl azide polymer esters

Номер: EP0403727B1
Принадлежит: Rockwell International Corp

Подробнее
25-11-2015 дата публикации

Nitroglycerine-free multi-perforated high-performing propellant system

Номер: ZA201401092B
Принадлежит: Nitrochemie Wimmis AG

Подробнее
08-05-2020 дата публикации

Polypentafluoropropyl glycidyl ether, use thereof and preparation method thereof

Номер: CN111116890A

本发明公开了下式所示的聚五氟丙基缩水甘油醚及其制备方法。以五氟丙氧基环氧丙烷为原料,用醇作为引发剂,三氟化硼乙醚作为催化剂,将五氟丙氧基环氧丙烷聚合,生成聚五氟丙基缩水甘油醚。该聚合物作为一种含能聚合物在炸药、推进剂及火工品等含能材料领域获得应用。 式中:n为4‑30。

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15-07-2014 дата публикации

Energetic compositions including nitrate esters and articles including such energetic compositions

Номер: US8778103B2
Принадлежит: Alliant Techsystems Inc

Methods of forming energetic compositions include forming a premix comprising a nitrate ester, a polymer, and a stabilizer, and combining solids with the premix. Additional stabilizer may be added with the solids and may remain in a crystalline state. Some methods include dissolving a stabilizer in at least one of a plurality of nitrate esters. Energetic compositions include a continuous matrix and a stabilizer. The continuous matrix includes a nitrate ester and surrounds a solid energetic material. Some compositions include a first nitrate ester, a second nitrate ester having a decomposition rate lower than the first nitrate ester, and a stabilizer. An article includes a housing and an energetic composition in the housing.

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15-12-2011 дата публикации

Nitroglycerine-free multi-perforated high-performing propellant system

Номер: CA2845852A1
Принадлежит: Nitrochemie Wimmis AG

The propulsion system for the acceleration of projectiles is based on a multi-perforated grain propellant and is composed from nitrocellulose, a crystalline energy carrier of a nitramine type and an inert plasticizing additive. The number of perforations is 2 to 6, preferably 4. The propellant grains can have round or polygonic profiles, depending on the number of perforations. The preferred grain geometry is cubic with a rectangular grain profile. The nitramine compound contains a structural element of the general chemical structure formula R-N-N02, where R is a residual group. The nitramine compound is present in a concentration in the range from 0 to 35% by mass, in particular in the range from 5 to 25% by mass. The nitramine compound is preferably RDX. The inert plasticizing additive is a water-insoluble polyoxo compound, if necessary in combination with a substance containing carboxyl groups. In layers near the surface an increased concentration can be present. The inert plasticizing additive is present in a concentration of 0 to 10% by mass, preferred 0 to 5% by mass.

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25-02-2000 дата публикации

New composite explosive consisting of filled plastic polyurethane binder containing 5-oxo 3-nitro 1,2,4-triazole as explosive charge

Номер: FR2782510A1

Composite explosive consisting of filled plastic polyurethane binder containing at least 5-oxo 3-nitro 1,2,4-triazole as explosive charge comprises: 20-35%, preferably 22-30% polyurethane binder comprising 25-50% polyurethane and 50-75% plasticizer containing at least a nitro or nitric ester group; and 40-80%, preferably 60-78% 5-oxo 3-nitro 1,2,4-triazole. Independent claims are also included for method for synthesizing the explosive; and hollow charge using the explosive.

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06-10-1992 дата публикации

Branched energetic polyether elastomers

Номер: CA2061744A1
Автор: Elie Ahad
Принадлежит: Minister of National Defence of Canada

ABSTRACT The invention disclosed relates to novel branched chain hydroxy-terminated aliphatic azido polymers and copolymers with variable molecular weight (MW) and a single step method for the preparation thereof which involves respectively reacting a high (MW) 0.5 - 5.0 x 106) solid rubbery polyepichlorohydrin (PECH) homopolymer and epichlorohydrin/alkylene oxide copolymer (PEEC), with an alkali metal azide in a suitable organic solvent, in the presence of an initiator at elevated temperature. The MW of the azido product may be controlled by including in the reaction mixture a basic degradation catalyst (such as LioCH3 or NaOH) and varying the amount of catalyst. When the reaction is catalyzed, the MW of the product varies within the range 1,000 - 40,000 and the hydroxyl functionality is 2 - 10. Uncatalyzed reactions yield products with MW between 40,000 and 200,000 and a functionality of about 10. The branched azido polymers and copolymers yield energetic binders with improved mechanical properties and thermal stability which are useful in rocket propellants and composite explosives formulations.

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10-01-1991 дата публикации

Energetic azido curing agents

Номер: AU605314B2
Принадлежит: Rockwell International Corp

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20-02-2001 дата публикации

Extrudable gun propellant composition

Номер: CA2045926C
Автор: David F. Debenham
Принадлежит: UK Secretary of State for Defence

The invention provides an extrudable gun propellant having a specific energy content of at least 1100kJ/kg and typically over 1200kJ/kg, but with reduced vulnerability to shaped charge attack compared to known colloidal propellants. This is achieved by using an energetic binder prepolymer and an energetic plasticiser with a reduced content of explosive filler. The composition comprises 65-85% by weight particulate explosive filler. 10-30% by weight of a mixture of a funtionally-terminated poly(nitratoalkyl-substituted)alkyl ether prepolymer and a cross-linking agent, and 1-12% by weight of energetic plasticiser.

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04-01-1977 дата публикации

Solid propellant with NF2 containing binder and energetic plasticizer

Номер: US4001057A
Принадлежит: Rohm and Haas Co

1. Compositions suitable for the manufacture of propellants consisting essentially of A. 15 to 40 parts of a monomer selected from the group consisting of compounds of the formula ##STR1## in which R is selected from the group consisting of hydrogen, methyl and ethyl, and R 1 is selected from the group consisting of ##STR2## in which n is an integer from 1 to 5, and R 4 is selected from the group consisting of H and CH 3 , ##STR3## in which R 2 is selected from the group consisting of hydrogen and lower alkyl containing 1 to 4 carbon atoms, and R 3 is selected from the group consisting of hydrogen and lower alkyl containing 1 to 4 carbon atoms, B. greater than 0 and less than 20 parts of a plasticizer for the polymers prepared by polymerizing the monomers of A), said plasticizers consisting essentially of a major proportion of compounds containing groups selected from the group consisting of NF 2 and ONO 2 , C. 40 to 60 parts of a solid powdered oxidizer, selected from the group consisting of lithium, sodium, potassium and ammonium salts of nitric and perchloric acids and D. 0 to 25 parts of a finely particled readily combustible solid selected from the group consisting of carbon black, aluminum, magnesium, zinc, zirconium, boron, and beryllium.

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18-06-1998 дата публикации

Solid solution vehicle airbag clean gas generator propellant

Номер: CA2272558A1

An ignitable solid gas generating composition comprises a polyalkylammonium binder, usually polyvinylamine nitrate or polyethyleneimmonium nitrate, an oxidizer mixture comprising ammonium nitrate and a first additive which produces an eutectic melt which is liquid at a temperature well below the melting point of the ammonium nitrate as well as that of the first additive, and an additional quantity of the ammonium nitrate and a second additive. Further, combustion modifier additives may be added to the composition.

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12-05-2021 дата публикации

Method for preparing composite pyrotechnical products

Номер: EP3656753B1
Принадлежит: ARIANEGROUP SAS

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25-05-1965 дата публикации

New method for the preparation of high energy fuel

Номер: US3185726A
Автор: Jean P Picard, Walter Hans
Принадлежит: Individual

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02-08-2006 дата публикации

Isotactic polyglycidyl epihalohydrine compound, isotactic polyglycidyl azide compound derived from the same and method of synthesizing isothactic polyglycidyl azide compound

Номер: KR100608295B1
Автор: 김형석, 유재철, 최근배
Принадлежит: 주식회사 헵스켐

하기 화학식으로 표시되고, -45℃ 내지 -65℃의 유리전이온도, 1000 내지 6000의 중량평균 분자량 및 상온에서 노랑색의 유체상을 갖는 이소택틱 폴리글리시딜 아자이드 화합물을 개시한다. An isotactic polyglycidyl azide compound represented by the following formula and having a glass transition temperature of -45 ° C to -65 ° C, a weight average molecular weight of 1000 to 6000, and a yellow fluid phase at room temperature is disclosed. 상기 화학식에서, n은 4 내지 28의 정수이다. 상기 이소택틱 폴리글리시딜 아자이드 화합물은 고체 추진제용 에너제틱 엘라스토머의 제조에 사용될 수 있다. In the above formula, n is an integer of 4 to 28. The isotactic polyglycidyl azide compound may be used for the preparation of an energetic elastomer for a solid propellant.

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22-01-2015 дата публикации

Metal hydrazide materials

Номер: AU2009329742B2
Принадлежит: UNIVERSITY OF WINDSOR

The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN

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05-04-1995 дата публикации

Improved branched energetic azido polymers

Номер: EP0646614A1
Автор: Elie Ahad

The invention disclosed relates to novel branched chain hydroxy terminated aliphatic azido polymers and copolymers, and to a single step process for their production. The properties of the materials are preferably adjusted through the incorporation of suitable polyols which can provide additional branching of the materials.

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14-09-1999 дата публикации

Process for preparing a vinyl terminated polymer

Номер: US5952458A
Принадлежит: US Department of Navy

Synthesis of a vinyl terminated polymer by reacting a cationically polymerizable monomer in the form of a cyclic ether with an acid chloride in a suitable solvent and in the presence of a Lewis acid. The vinyl-terminated polymers can be polymerized with other appropriate monomers resulting in thermoplastic elastomers having suitable properties for use as binders for explosives and propellants.

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23-06-2021 дата публикации

Insensitive munition propellants

Номер: EP3838877A1
Принадлежит: BAE SYSTEMS plc

The invention relates to Insensitive Munition (IM) energetic materials particularly IM propellant compositions, and yet further to nitrocellulose-free IM propellants. An energetic composition suitable for use as a propellant comprises the following components in the following relative proportions: component A; from 5% to 25% by weight of an IM energetic filler; component B: from 50% to 80% by weight of a highly energetic filler comprising at least one nitramine compound; component C of from 5% to 20% by weight of a binder; and component D of from 3% to 15% by weight of a plasticiser; the percentages by weight of components A, B, C and D together with minor additives, if any, adding to 100%.

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