Фторидированные соединения для фторполимеров

... 1. Состав, включающий частично фторированное соединение:где x является нечетным целым числом от 3 до 11.2. Полимерный состав, включающий полимеризуемый продукт реакции:(a) частично фторированное соединение,где x является нечетным целым числом от 3 до 11; и(b) фторированный олефиновый мономер.3. Полимерный состав по п. 2, где фторированный олефиновый мономер выбран из группы, состоящей из: гексафторпропилена, трифторэтилена, фторэтилена, фторвинилидена, тетрафторэтилена, перфтора(метилвиниловый эфир), перфтора (пропилвиниловый эфир), перфтора(метоксипропилвиниловый эфир), перфтора(этоксиметилвиниловый эфир), хлортрифторэтилена и их комбинаций.4. Полимерный состав по п. 2, где полимеризуемый продукт реакции далее включает (с) агента передачи цепи, где агент передачи цепи выбран из группы, состоящей из: C1-С10 α, ω-дийодоперфторалкана; I(CF)CHCHI, где у является целым числом от 2 до 10; CHI; и их комбинаций.5. Полимерный состав по п. 4, где агент передачи цепи является 1,3-дийодоперфторпропаном ...

СПОСОБ ПОЛУЧЕНИЯ ДИФТОРМЕТИЛЕНОВОГО СОЕДИНЕНИЯ

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 123 281 A (51) МПК C07C 67/30 (2006.01) C07C 69/62 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019123281, 22.12.2017 (71) Заявитель(и): ДАЙКИН ИНДАСТРИЗ, ЛТД. (JP) Приоритет(ы): (30) Конвенционный приоритет: 26.12.2016 JP 2016-251315; 13.11.2017 JP 2017-218128 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 26.07.2019 JP 2017/046195 (22.12.2017) (87) Публикация заявки PCT: A WO 2018/123890 (05.07.2018) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр. 3, ООО "Юридическая фирма Городисский и Партнеры" R U (57) Формула изобретения 1. Способ получения дифторметиленового соединения, содержащего фрагмент -CF2-, причем способ включает стадию A смешивания: a) карбонильного соединения, содержащего фрагмент -C(O)-; b) необязательно амина; c) фторида, представленного формулой: MF, где M обозначает элемент группы 1 периодической таблицы; d) галогенированного соединения фтора, представленного формулой: XFn, где X обозначает хлор, бром или йод, и n равно натуральному числу от 1 до 5; и e) хлорида серы. 2. Способ получения по п.1, где дифторметиленовое соединение, содержащее фрагмент -CF2-, представляет собой дифторметиленовое соединение, представленное формулой (1): R11-CF2-R12 (1), где R11 представляет R21 или фтор, R12 представляет R22 или фтор, Стр.: 1 A 2 0 1 9 1 2 3 2 8 1 (54) СПОСОБ ПОЛУЧЕНИЯ ДИФТОРМЕТИЛЕНОВОГО СОЕДИНЕНИЯ 2 0 1 9 1 2 3 2 8 1 (86) Заявка PCT: R U (43) Дата публикации заявки: 26.01.2021 Бюл. № 3 (72) Автор(ы): ОЦУКА, Тацуя (JP), КУРОКИ, Йоситика (JP), СИРАИ, Ацуси (JP), ХОСОКАВА, Мое (JP), КИСИКАВА, Йосуке (JP) R21 и R22 одинаковые или разные, и каждый обозначает (a) водород, (b) гидроксил или (c) органическую группу, или R21 и R22, взятые вместе с фрагментом -CF2-, к которому они присоединены, могут образовывать цикл, при условии, что (i) ни R11, ни R12 не является гидроксилом, и R U A 2 0 1 9 1 2 3 2 8 1 2 0 1 9 1 2 3 2 8 ...

ОЛИГОФЕНИЛЕНОВЫЕ МОНОМЕРЫ И ПОЛИМЕРНЫЕ ПРЕДШЕСТВЕННИКИ ДЛЯ ПОЛУЧЕНИЯ ГРАФЕНОВЫХ НАНОЛЕНТ

... 1. Олигофениленовые мономеры общих формул А, В, С, D, Ε и Fв которойAr выбран изв которойAr выбран изв которойAr выбран изв которойAr означаетв которойAr означаетв которойAr означаетгде в каждой из формул А, В, С, D, Ε и F,Χ, Υ означает галоген, трифторметилсульфонат или диазонийR, R, Rнезависимо друг от друга означают Н, галоген, -ОН, -NH, -CN, -NO, линейный или разветвленный, насыщенный или ненасыщенный С-С-углеводородный остаток, который может быть замещен с помощью 1-5 галогенов (F, Cl, Br, I), -ОН, -NH, -CN и/или -NO, и где одна или большее количество групп СНмогут быть заменены на -О-, -S-, -С(O)O-, -О-С(О)-, -С(O)-, -NH- или -NR-, где R означает необязательно замещенный С-С-углеводородный остаток или необязательно замещенный арильный, алкиларильный или алкоксиарильный остаток.2. Олигофениленовые мономеры по п. 1 общих формул I, II, III и IV для синтеза полимерных предшественников, предназначенных для получения графеновых нанолентв которыхR, R, Rнезависимо друг от друга означают Н ...

СПОСОБ ПОЛУЧЕНИЯ ФТОРЗАМЕЩЕННОГО (ГАЛОГЕНСОДЕРЖАЩЕГО) УГЛЕВОДОРОДА

Способ получения фторзамещенного (галогенсодержащего) углеводорода включает контактирование α-фторзамещенного простого эфира в паровой фазе при повышенной температуре с катализатором и катализатор обрабатывают для поддержания и/или восстановления его активности. Обработка катализатора включает либо нагревание катализатора до повышенной температуры, превышающей примерно 250C, при отсутствии a-фторзамещенного простого эфира, либо контактирование катализатора при повышенной температуре с окисляющим веществом в период или между периодами контактирования a-фторзамещенного простого эфира с катализатором. Катализатор может представлять собой промотирующий окисление металл, например цинк, железо или медь, нанесенный на подложку из оксида, фторида или оксифторида металла.

Гербицидная композиция

FLUORHALTIGE 4,4'-BIS-(CYCLOHEXYL)-BIPHENYLDERIVATE ENTHALTENDE DIELEKTRIKA

Verfahren zur Herstellung von Alkylchloriden und-bromiden

VERFAHREN ZUR HERSTELLUNG AROMATISCHER BROMVERBINDUNGEN

Verfahren und Vorrichtung zur Herstellung von Tetrachlorkohlenstoff durch Chlorierung von Schwefelkohlenstoff sowie von hochreinem Schwefel und reiner konzentrierter Salzsaeure

THIAPYRANE, VERFAHREN ZU DEREN HERSTELLUNG UND DIESE VERBINDUNGEN ENTHALTENDE INSEKTIZIDE ZUSAMMENSETZUNGEN

Improvements in or relating to the production of halogen-substituted organic compounds

Halogen-substituted organic compounds are obtained by reacting an organic compounds consisting of an alcohol, ether, aldehyde, ketone, ester, thioalcohol, thioether, thioester, or amine, with an ammonium or organic substituted ammonium halide (but excluding iodides) containing at least one H atom attached to the N atom at a temperature of 250 DEG C. to 500 DEG C. in the presence of a dehydrochlorination type catalyst of acidic to mildly alkaline character. The ammonium chloride used may be that recovered as by-product in the ammonia-soda process for the manufacture of soda ash. In addition to ammonium chloride there may be used ammonium fluoride, ammonium bromide and the corresponding organic substituted ammonium halides, e.g. methylamine hydrochloride, diethyl ammonium chloride, trimethylammonium chloride, dimethylammonium bromide, pyridine hydrochloride and aniline hydrofluoride. The catalyst may be a metallic oxide, silicate, or chloride, alumina being preferred. Other materials specified ...

CHEMICAL PROCESS

Method of producing halogen-substituted derivatives of aliphatic hydrocarbons

Alkyl halides are made by reacting at boiling temperature an alkyl chlorsulphonate Cl-SO2-O-R with excess hydracid HX in the form of an aqueous solution, X being chlorine, bromine, or iodine, and R being an alkyl radicle having three or more carbon atoms, that may be unsaturated, and may contain one or several halogen atoms. The alkyl chlorsulphonate may be obtained from sulphuryl chloride and the corresponding alcohol and used without isolation. In an example, polymethylene chlorobromides of the formula Cl.(CH2)nBr, where n is a number from 3 to 10, are obtained from the chlorosulphonates Cl.SO3(CH2)nCl by boiling with hydrobromic acid. The alkyl chlorosulphonates are obtained by the action of sulphuryl chloride on the alcohols ROH or halogen substituted derivatives thereof. The Specification as open to inspection under Sect. 91 also describes the preparation of methylene chloride, chlorobromomethane, and chloroiodomethane from chloromethyl chlorsulphonate and hydrochloric, hydrobromic ...

THIAPYRAN DERIVATIVES THEIR PREPARATION AND USE

... 1387162 Thiopyran derivatives and their preparation ROUSSEL UCLAF 27 July 1972 [27 July 1971] 35235/72 Heading C2C Compounds of the general formula wherein n is 0 or 1 and alkyl represents a C 1-5 alkyl radical, may be obtained by reacting under strongly basic conditions a compound of formula wherein Hal represents a chlorine or bromine atom, with a compound of formula The reaction is preferably effected in the presence of butyl lithium, an alkali metal hydride, an alkali metal amide or an alkali metal alkoxide in a solvent. The compounds of Formula II (wherein n is 0), may also be obtained by reducing a corresponding compound of Formula II (wherein n is 1), e.g. with anhydrous stannous chloride in the presence of acetyl chloride or with titanium trichloride. Compounds of the formula are obtained by either reducing and desulphurizing a compound of Formula II (wherein n is 1), or desulphurizing a compound of Formula II (wherein n is 0). Both the desulphurization and simultaneous reduction ...

Preparation of chlorodifluorobenzenes

Difluorobenzenes are prepared by reacting a fluoronitrobenzene of the formula: in which Hal represents fluorine, chlorine or bromine, Y represents hydrogen or methyl, Z represents hydrogen or a weakly electrodonating group on a non-electrodonating group and n is 1 to 2, with a source of fluoride ion to replace the nitro group by fluorine. The products are useful intermediates in the preparation of drugs based on a quinoline structure.

Process for the production of fluorine-containing organic compounds

Perchlorofluoromethanes are prepared by heating carbon disulphide with a fluorochloroarsenic complex [ASCl4]+[ASF6]- or a fluorochloro antimony complex [SbCl4]+[SbF6]-. The product is usually a mixture of the mono-, di- and tri-fluoro-chloromethanes. The reaction may be effected at atmospheric pressure, suitably at 80-100 DEG C., or, preferably, at super-atmospheric pressures at temperatures above 100 DEG C. The arsenic or antimony complex may be made in situ by passing chlorine into a mixture of carbon disulphide and arsenic or antimony trifluoride. Examples are provided.

Preparation of chlorobenzotrifluoride compounds

Chlorobenzotrifluoride compounds, especially 3,4,5-trichlorobenzotrifluoride, are obtained by replacement of at least one m-nitro group in a nitrobenzotrifluoride by chlorine using chlorine gas in the presence of a catalyst comprising a metal salt and a sulphur compound.

Method of producing derivatives of 1,3,5-triarylbenzene and truxene

A method of producing 1,3,5-triarylbenzenes comprises subjecting a first compound with the formula Ar-C(=O)Me, where Ar is phenyl (optionally substituted with alkyl, chlorine, bromine, iodine or nitro), pyrenyl, fluoroanthenyl, or triphenylenyl, to an aldol condensation reaction using an alkyl orthosilicate of formula Si(OAk)4, where Ak is C1-10 alkyl and an inorganic or organic non-carboxylic acid in an aprotic organic solvent. Another method concerns the production of truxene derivatives by treating a second compound containing a ketone group attached to a cyclopentyl ring fused to a phenyl ring, the method comprising adding Si(OAk)4 and an acid. The phenyl ring of the second compound is optionally substituted by alkyl, chlorine, bromine, iodine, or nitro. The truxene derivatives may be CH2-bridged derivatives of 1,3,5-triarylbenzenes. The first compound may be 2-bromoacetophenone, 2-nitroacetophenone, 2-acetyltriphenylene, 1-aceylpyrene or the indanone of the second compound. The acid ...

Improvements in and relating to the preparation of 1:4-dihalobutanes

... 1 : 4-Dihalobutanes are prepared by reacting hydrogen chloride or hydrogen bromide with tetramethylene oxide in the liquid phase at a temperature within the range of 60 DEG to 200 DEG C. in the presence of either a heterocyclic amine hydrohalide catalyst corresponding to the hydrogen halide being reacted and having a molecular structure which includes a pyridine nucleus, or a compound of the formula wherein R is a hydrogen atom or an alkyl or aralkyl radical, Y is an alkyl radical and X is a chlorine or bromine atom corresponding to the hydrogen halide being reacted. Examples given of amine catalysts are the hydrochlorides and hydrobromides of pyridine and quinoline and the hydrochlorides of isoquinoline, 2-methyl pyridine, 3-methyl pyridine, 2 : 5-methyl ethyl pyridine, 2-propyl pyridine, 2-ethyl-3 : 5-dimethyl pyridine, 2-methyl quinoline, and 4-methyl quinoline; hydrochlorides and hydrobromides of mono-, di- and tri-alkylamines having 1-6 carbon atoms per alkyl ...

CHEMICAL PROCESS

Catalysts

... 1,143,120. Carbon tetrachloride. FMC CORP. 2 Nov., 1966 [15 Nov., 1965], No. 49117/66. Heading C2C. [Also in Division B1] COCl 2 is converted to CCl 4 by heating COCl 2 at 200-400‹ C. in the presence of at least 10% of a catalyst comprising 1 part of WCl 6 or MoCl 6 and 1-20 parts of Ca, Sr, Ba or Zn chloraluminate. The phosgene may be produced in situ from carbon monoxide and chlorine. Examples describe the conversion of COCl 2 to CCl 4 in an autoclave at 300‹ C. using various catalysts.

Process for the manufacture of homogeneous halogen derivatives of ª‡-chloro-naphthalene

Halogen derivatives of naphthalene are made by halogenating 1-chloronaphthalene-8-sulphonic acid, and splitting off, or replacing by halogen, the sulphonic group. According to examples, chlorine acts on (1) 1-chloro-8-naphthalene sodium sulphonate to give the 1 : 4-dichloronaphthalene-8-sulphonate; (2) the 1 : 4 : 8-trichloronaphthalene; (3) 1 : 4-dichloronaphthalene is obtained by hydrolysis of the product from example (1); (4) 1 : 4-dichloro-8-bromonaphthalene is obtained by brominating the product of example (1); bromine acts on 1-chloronaphthalene-8-sulphonic acid to give (5) 1 : 8-chlorobromonaphthalene, and (6) 1-chloro-4-bromonaphthalene-8-sulphonic acid; (7) 1-chloro-4-bromonaphthalene is obtained by hydrolysis of the product of example (5); (8) 1-chloro-4 : 8 dibromonapthalene is obtained by brominating the product of example (5); (9) 1 : 8 dichloro-4-bromonaphthalene is obtained by chlorination of the product from example (5).

IMPROVEMENTS IN OR RELATING TO THE SYNTHESIS OF CHEMICAL INTERMEDIATES

PREPARATION OF HERBICIDAL FLUOROPHENOXYPROPIONATES

Novel herbicides

TRICHLOROMETHYL-TRIFLUOROMETHYL-BENZENES

... 1510280 Preparation of trichloromethyl trifluoromethylbenzenes BAYER AG 13 Oct 1976 [3 Nov 1975 14 April 1976] 42546/76 Heading C2C The invention comprises a process for the preparation of a compound of Formula I wherein R1 and R2 are independently H, F or Cl by reacting a compound of Formula II wherein m and n are independently 0 or integers from 1 to 3 with a halogen transfer catalyst. During the reaction described above corresponding bis(trichloromethyl)benzenes and compounds having one or two mixed fluorochloromethyl groups are also produced as byproducts. Mixtures of isomers having the general Formula II above are prepared by reacting the corresponding bis(trichloromethyl)benzene with anhydrous HF and where desired specific isomers, e.g. 1-trifluoromethyl-3-difluorochloromethyl - benzene,1 - difluorochloromethyl - 3- fluorodichloromethylbenzene, 1, 4 - bis(difluorochloromethyl)benzene,1,4 - bis(fluorodichloromethyl)benzene,1,4 - bis(trifluoromethyl)benzene,2,5- bis ...

Method of producing alkyl chlorides and polymeric zirconium compounds containing chloride and alkoxy groups

Zirconium dioxide may be prepared by steam hydrolysis at 300-500 DEG C. and calcination at temperatures of up to 1000 DEG C. of polymeric zirconium compounds of the following average formula where R is an alkyl group, x is between 0 and 2.5, and y is between 0 and 1.5, and which may contain a few hydroxyl groups if water was present in the reaction medium; such polymers are prepared either (a) by reacting ZrCl4 with aliphatic ethers at elevated temperatures, or (b) by thermally decomposing the addition compounds of ZrCl4 and aliphatic ethers (see Group IV (a)).ALSO:Polymeric zirconium compounds of the following average formula ZrO2- 1/2 (x+y)Clx(OR)y where R is an alkyl group, x is between 0 and 2.5, and y is between 0 and 1.5, and which may contain a few hydroxyl groups if water is present in the reaction medium, are prepared either (a) by reacting ZrCl4 in the aliphatic ethers at elevated temperatures, or (b) by thermally decomposing the addition compounds of ZrCl4 ...

A process for the production of fluorine, bromine and iodine substituted organic compounds

Fluorine, bromine or iodine substituted organic compounds of the formula RF(Br or I), wherein R is hereinafter defined, are prepared by reacting fluorine, bromine or iodine with an organomagnesium chloride complex of the general formula R(MgCl)x.nQ, wherein R represents a substituted or unsubstituted aryl radical, a substituted or unsubstituted vinyl radical, or a substituted or unsubstituted heterocyclic radical which exhibits aromatic or pseudo-aromatic characteristics, which includes in its heterocyclic ring an oxygen, sulphur or tertiary nitrogen atom and which is bound to magnesium through a carbon atom of the aromatic or pseudo-aromatic ring and R contains no functional group which is reactive under the conditions for the formulation of the complex, n is 1, 2 or 3, x is an integer, and Q represents a substituted or unsubstituted cyclic ether having 5 or 6 carbon atoms in the ring, of which atoms only one is oxygen, the other ring atoms being carbon with the exception that a substituted ...

Herbicidally active bicyclic 1,3-dione compounds

Process for converting gaseous alkanes to olefins and liquid hydrocarbons

4-phenyl-pyrane-3,5-diones, 4-phenyl-thiopyrane-3,5-diones and cyclohexanetriones as novel herbicides

Herbicidally active bicyclic 1,3-dione compounds

New ethers 4-trifluoromethyl-4'-nitrodiphenylic weedkillers and their application to the fight against bad grasses.

Herbicidally active bicyclic 1,3-dione compounds

4-phenyl-pyrane-3,5-diones, 4-phenyl-thiopyrane-3,5-diones and cyclohexanetriones as novel herbicides

Herbicidally active bicyclic 1,3-dione compounds

N-FLUOROTRIAZINIUMVERBINDUNGEN AND YOUR USE AS FLUORIERUNGSMITTEL

VERFAHREN ZUR HERSTELLUNG NEUEN 3-FLUOR-10PIPERAZINO-8-SUBSTITUIERTEN 10,11-DIHYDRODIBENZO (B,F)THIEPINEN UND DEREN SAEUREADDITIONSSALZEN

INDANVERBINDUNGEN WITH NEGATIVE DIELECTRIC ANISOTROPY

PROCEDURE FOR THE PRODUCTION OF AROMATIC FLUORINE COMPOUNDS

PROCEDURE FOR THE EXECUTION OF CARBONYLIERUNGSREAKTIONEN OF AROMATIC CARBOCYCLI ESTERS AND ALKYLIODIDEN.

PROCEDURE FOR THE PRODUCTION OF DESCENDANTS OF CHLOROBENZOTRIFLUORID.

CYCLOHEXANE DERIVATIVE

Procedure for the production of new Biphenylylpropionsäuren as well as of their pharmaceutical usable inorganic and organic salts and its hydroxamic acid

Procedures for the production of new 2,3-Dihydro-5H-imidazo [2,1-a] isoindolderivaten and their salts

FLUORINE BENZENE DERIVATIVES AND LIQUIDCRYSTALLINE MEDIUM

PROCEDURE FOR THE PRODUCTION OF ALPHA, OMEGA BROMOCHLOROALKANEN

Procedure for the production of allyl chloride and/or Methallylchlorid

PRODUCING AROMATIC CARBOCYCLIC OR HETEROCYCLIC FLUORIDE FROM AROMATIC DIAZONIUM FLUORIDE

MONOMERS CONTAINING AT LEAST ONE BIARYL UNIT AND POLYMERS AND DERIVATIVES PREPARED THEREFROM

Perfluoronaphthyl substituted boron containing catalyst activator

FLUOROBENZOLE DERIVATIVES AND MESOMORPHOUS MEDIUM

Novel bromine-containing 1,2-bis(phenyl)difluoromethanes and method of impartingflame retardancy to flammable materials

HERBICIDAL COMBINATIONS

IMPROVED PROCESS FOR PREPARING AROMATIC FLUORIDES

Process for the preparation of fluoro compounds from the corresponding amines

Synthesis of 4-ketocyclopentene and cyclopentadiene compounds

Synthesis of perfluoro aromatic boranes and borates

ANTIFUNGAL TRIAZOLE COMPOUND

PROCESS FOR THE PREPARATION OF HALO AROMATIC COMPOUNDS

LIQUID CRYSTALLINE HALOGEN COMPOUNDS, PROCESS FOR THEIR PREPARATION, DIELECTRICS CONTAINING THESE, AND ELECTRO-OPTICAL DISPLAY ELEMENT

PROCESS FOR OBTAINING FREE CARBON RADICALS

L'invention concerne un procédé de formation de radicaux carbonés libres R. éventuellement fonctionnalisés, caractérisé en ce que l'on apporte de l'énergie thermique et/ou photochimique à un ester thiocarbonylé répondant à la formule générale (I): < IMG > (I) dans laquelle: R représente un radical carboné saturé ou insaturé, linéaire ou ramifié, aliphatique ou aromatique, acyclique ou bien mono- ou poly-cyclique ou encore monoou poly-hétérocyclique, ledit radical carboné R étant en outre éventuellement fonctionnalisé; R' et R" représentent, indépendamment l'un de l'autre, un radical alcoyle, alcényle, aryle, aralcoyle, alcoylaryle, ou bien forment ensemble un hétérocycle azoté à 5 ou 6 chaînons pouvant en outre contenir un hétéroatome additionnel choisi parmi l'azote et le soufre et pouvant éventuellement être substitué par un radical alcoyle inférieur ou accolé à au moins un autre cycle aliphatique ou aromatique; R1 et R2 représentent, indépendamment l'un de l'autre, un atome d'hydrogène ...

FLUORINATION PROCESS

TITLE FLUORINATION PROCESS A continuous process for fluorinating haloalkanes containing at least one nonfluorine halogen atom wherein antimony pentachloride is reacted with HF to produce an antimony chlorofluoride. The antimony chlorofluoride thus produced is then transferred to a separate reaction zone where it is reacted with the haloalkane, thereby replacing a portion of the nonfluorine halogen in the haloalkane with fluorine of the antimony chlorofluoride. The continuous process may be used in the manufacture of fluorinated derivatives of alkanes.

IMMUNOLOGIC ADJUVANTS

Compounds of the formulae Y-R wherein Y is l-thio-.beta.-L-fucose, l-thio-.beta.-D-galactose or l-thio-.beta.-lactose and R is 2-(l-adamantyl)ethyl, 3-¢(p-tetrafluorophenethyl)phenyl!propyl, 6-(5-cholesten-3.beta.-yloxy)hex-3-ynl, oleyl, or hexadecyl are useful immunologic adjuvants in vaccines.

PROCESS FOR PREPARING AROMATIC FLUORIDES

An improved process is disclosed for preparing aromatic fluorides by diazotization-fluorination in hydrogen fluoride wherein the diazotized reaction mixture includes an oxidizing agent such as nitrosonium ion from excess diazotization agent. The improvement includes, prior to decomposing the diazonium fluoride, adding to the diazotized reaction mixture a member selected from hydrazine, aromatic hydrazine, semi-carbazide, thiosemicarbazide, acid salts thereof, sulfur dioxide, sodium sulfite, and sodium bisulfite to remove at least a portion of the oxidizing agent. Urea was found to be ineffective.

PROCESS FOR THE PREPARATION OF N,N-DIMETHYL-N-(2- BROMO-4-METHYL-PHENYL)-TRIAZENE

SYNTHESIS OF LONG-CHAIN ALKANES HAVING TERMINAL FUNCTIONALITY

PROCESSES FOR PRODUCING TRIFLUOROIODOMETHANE AND TRIFLUOROACETYL IODIDE

The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25 °C to about 400 °C to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200 °C to about 600 °C to produce a final product stream comprising the trifluoroiodomethane.

SYNTHESIS OF EPOTHILONES AND RELATED ANALOGS

The present invention relates to methods for use in producing epothilones and analogs and derivatives thereof. A general method according to the present invention broadly comprises performing an aldol condensation of a first compound with a second compund thereby to form a third compound selected from the formulas (I) and (II) and stereoisomers thereof, and performing a macrolactonization of the third compound. The present invention also provides chemical compounds, and methods for producing such chemical compounds, that are useful in producing epothilones and analogs and derivatives thereof.

HERBICIDALLY ACTIVE BICYCLIC 1,3-DIONE COMPOUNDS

Bicyclic dione compounds of formule (I), and derivatives thereof, which are suitable for use as herbicides.

FLUORINATION OF ORGANIC COMPOUNDS

Methods for fluorinating organic compounds are described herein.

PROCESS FOR PREPARING CHLORODIFLUOROBZENE

... 2058294 9113847 PCTABS00007 1-Chloro-3,4-difluorobenzene, an intermediate in the production of certain quinolone drugs, is produced by converting a chlorofluoro-aniline into the corresponding diazonium fluoborate, and pyrolysing the latter to give the 1-chloro-3,4-difluorobenzene. 5-Chloro-2-fluorophenyldiazonium fluoborate is a new compound.

CONVERSION OF HEXAFLUOROBENZENE TO BROMOPENTAFLUOROBENZENE

A method for synthesizing bromopentafluorobenzene from hexafluorobenzene is described.

HYDROGEN FLUORIDE RECOVERY PROCESS

A process for recovery of hydrogen fluoride comprises contacting a gaseous mixture containing hydrogen fluoride and an organic compound with a solution of an alkali metal fluoride in hydrogen fluoride, separating a gas phase depleted in hydrogen fluoride and containing the organic compound from a liquid phase enriched in hydrogen fluoride, and then recovering the hydrogen fluoride from the liquid phase.

Verfahren zum Ersatz der Aminogruppe durch Halogene in aliphatischen und aromatischen Verbindungen.

Verfahren zum Ersatz der Aminogruppe durch Halogene in aliphatischen und aromatischen Verbindungen.

Procédé pour la préparation des dérivés halogénés d'hydrocarbures aliphatiques par action d'un acide halogénhydrique sur un chlorosulfonate aliphatique.

Verfahren zur Herstellung von 2-Chlor-m-xylol

Processo continuo di preparazione di composti alogenati per reazione fra un composto organico ossigenato ed un acido alogenidrico.

Verfahren zur Herstellung von 2-Trifluormethylbenzhydrol

Verfahren zur Herstellung von Alkyljodiden

Procédé de préparation de polyhalogénométhanes

Verfahren zur Herstellung von Trichlormethyl-halogenbenzolen

Verfahren zur Herstellung von m- und p-Difluorbenzolen

Verfahren zur Herstellung von 1,1,1-Trifluor-2-brom-2-chloräthan

Tricyclic cpds antidepressive

... (A) Cpds. of general formula (I) Including salts, and stereoisomers of I. R' = H or Me R = Me or MeCO (B) N-oxides of I (R' = Me). Antidepressants, adrenolytics, antihistamines, and local anaesthetics, with low toxicity and slight anticholinergic activity. 1-Methyl-10,11-dihydro-(3-dimethylamino-propylidene) 5H-dibenzo(a,d)cycloheptene (39.5 g), was hydrogenated at 25 deg./1 atm., over Pt2O (3 g.) in AcOH (400 ml). The mixture was filtered, evapd. and the residue distilled, giving the 3-dimethylaminopropyl deriv., b.p.140 deg./0.01 mm. (Hydrochloride m.p.181-3 deg., from Et2O-EtOH).

Dibenzocycloheptene derivs intermediates for

Cmpds. Intermediates for dibenzocycloheptene tranquillisers and antidepressants.

Substd amidoazoisoindoles

Heterocyclic cpds. of general formulae I, II and IV in racemic or optically active form (I) X = OOH ) R' =H or (II) X=H) (IV) X = OH) Appetite-restraining agents in treatment of obesity and diseases where wt. reduction is desirable e.g. cardiac conditions and diabetes. Compds. I. By oxidn. of II in an inert solvent e.g. ether with air or O at 15-35 deg. for 10-20 mins. Compds. II. By redn. of cpds. III with LiAlH4 below 45 deg. (pref. 15-35 deg.) in an inert solvent under N for 6-96 hrs. II have low stability and it is convenient to convert to I without isolation, in which case excess LiAlH4 is first destroyed by addn. of NaOH, filtering and then oxidising. alternatively HCl gas may be passed into the filtrate to form a salt of II. Starting material III. Netherlands Pat.65,01647 of 12.8.65. Compds. IV. From I by stirring in a polar proton-contng. solvent, specifically MeOH or EtOH for 6-8 hrs. at 15-35 deg. The temp. is critical. Compds. IV can exist as V, VI, or VII and are the subject ...

Verfahren zur Herstellung von Allylchlorid bzw. Methallylchlorid

PROCEDE DE PREPARATION D'ACIDES 2-(BIPHENYLYL SUBSTITUES) PROPIONIQUES.

PROCEDE DE PREPARATION DE TRIENES.

PROCEDE DE PREPARATION DE NOUVEAUX 2H-THIAPYRANNES.

Verfahren zur Herstellung von 2-Trifluormethylbenzophenon

Utilisation de nouveaux esters benzyliques comme insecticides

Procédé pour la préparation de composés organiques fluorés

Verfahren zur Herstellung von 5-Hydroxy-5-phenyl-2,3-dihydro-5H-imidazo(2,1-a)isoindolen

Verfahren zur Herstellung von 3,6-Difluordurol

Leaving substituent-containing compound, organic semiconductor material, organic semiconductor film containing the material, organic electronic device containing the film, method for producing film-like product, pi-electron conjugated compound and method for producing the pi-electron conjugated compound

A leaving substituent-containing compound including a partial structure represented by the following General Formula (I): where a pair of X 1 and X 2 or a pair of Y 1 and Y 2 each represent a hydrogen atom; the other pair each represent a group selected from the group consisting of a halogen atom and a substituted or unsubstituted acyloxy group having one or more carbon atoms; a pair of the acyloxy groups represented by the pair of X 1 and X 2 or the pair of Y 1 and Y 2 may be identical or different, or may be bonded together to form a ring; R 1 to R 4 each represent a hydrogen atom or a substituent; and Q 1 and Q 2 each represent a hydrogen atom, a halogen atom or a monovalent organic group, and may be bonded together to form a ring.

PROCESS FOR THE PREPARATION OF IODIDES

This invention is directed to a process for the preparation of high yield alkyl or aryl iodide from its corresponding carboxylic acid using N-iodo amides. 1. A process for the preparation of iodide , represented by scheme (1):{'br': None, 'R—COOH→R—I\u2003\u2003(1)'}comprising reacting R—COOH with N-iodo amide to yield R—I; wherein R is saturated, linear or branched, substituted or unsubstituted alkyl; substituted or unsubstituted aryl; saturated or unsaturated, substituted or unsubstituted mono- or poly-carbocyclic or heterocyclic ring.2. The process of claim 1 , wherein said amide is carboxamide or sulfonamide.3. The process of claim 1 , wherein said amide is lactame claim 1 , carbamate claim 1 , imide or ureide.4. The process of claim 1 , wherein said amide is 5 claim 1 ,5-dimethylhydantoin claim 1 , 3-benzyl-5 claim 1 ,5-dimethylhydantoin claim 1 , 5-methyl-5-phenylhydantoin claim 1 , 5 claim 1 ,5-diphenylhydantoin claim 1 , 5 claim 1 ,5-hexamethylenehydantoin claim 1 , 5 claim 1 ,5-pentamethylenehydantoin claim 1 , 5 claim 1 ,5-tetramethylenehydantoin claim 1 , succinimide claim 1 , phthalimide claim 1 , saccharine claim 1 , isocyanuric acid claim 1 , 5 claim 1 ,5-dimethylbarbituric acid claim 1 ,-glycoluril claim 1 , 3a claim 1 ,6a-diphenylglycoluril claim 1 , 3a claim 1 ,6a-dimethylglycoluril claim 1 , 4 claim 1 ,4 claim 1 ,5 claim 1 ,5-tetramethyl-2-imidazolidinone claim 1 , 4 claim 1 ,4-dimethyl-2-oxazolidinone or mixture thereof.5. The process of claim 1 , wherein said N-iodo amide is 1 claim 1 ,3-diiodo-5 claim 1 ,5-dimethylhydantoin (DIH) claim 1 , N-iodosuccinimide (NIS) claim 1 , triiodoisocyanuric acid (TICA) claim 1 , 2 claim 1 ,4 claim 1 ,6 claim 1 ,8-tetraiodoglycoluril (TIG) claim 1 , N-iodosaccharine (NISac) claim 1 , or mixture thereof.6. The process of claim 1 , which comprises subjecting the mixture of the R—COOH and N-iodoamide to heat claim 1 , ultrasound claim 1 , or electromagnetic radiation or combination thereof.7. The process of claim 1 ...

SYSTEM FOR FLUORINATING ORGANIC COMPOUNDS

Described herein are fluorinated organic compounds and methods of making fluorinated organic compounds, for example, using palladium complexes. Also described herein are compositions and kits containing compounds and palladium complexes described herein. 2. The palladium complex of claim 1 , wherein the palladium complex further comprises a negatively charged counterion X claim 1 , wherein X is selected from BF claim 1 , BPh claim 1 , PF claim 1 , [BArF] claim 1 , B(CF) claim 1 , SbF claim 1 , and CFSO.3. The palladium complex of claim 1 , wherein Z is —N(R)—.4. The palladium complex of claim 3 , wherein Ris —S(O)R.5. The palladium complex of claim 4 , wherein Ris optionally substituted aryl.7. The palladium complex of claim 1 , wherein Ris pyridyl.8. The palladium complex of claim 1 , wherein Ris halogen claim 1 , an optionally substituted heteroaryl claim 1 , or —OR.9. The palladium complex of claim 8 , wherein Ris —Cl or pyridyl.10. The palladium complex of claim 1 , wherein Ris —C(═O)Ror —S(O)R.11. The palladium complex of claim 10 , wherein Ris an optionally substituted aliphatic.12. The palladium complex of claim 11 , wherein Ris —C(═O)CHor —S(O)CF.15. The method of claim 14 , wherein the organic compound comprises an aryl group.16. The method of claim 14 , wherein the organic compound comprises a boron substituent.18. The method of claim 14 , wherein the fluorinating agent provides a source of F.20. The palladium complex of claim 19 , wherein Ris pyridyl.21. The palladium complex of claim 19 , wherein Ris halogen claim 19 , an optionally substituted heteroaryl claim 19 , or —OR.22. The palladium complex of claim 21 , wherein Ris —Cl or pyridyl.23. The palladium complex of claim 21 , wherein Ris —C(═O)Ror —S(O)R.24. The palladium complex of claim 23 , wherein Ris an optionally substituted aliphatic.25. The palladium complex of claim 24 , wherein Ris —C(═O)CHor —S(O)CF. The present application is a Continuation of U.S. application Ser. No. 12/865,703, which is ...

PROCESS FOR PRODUCING A CHLORINATED ALKANE

A process for producing a chlorinated alkane in which an alkene or an alkane feedstock is contacted with chlorine in a chlorination zone to produce a reaction mixture containing the chlorinated alkane, wherein the chlorine supplied into the chlorination zone has an oxygen content of less than about 2000 ppmv and wherein: 2. The process of claim 1 , wherein all components of the distillation apparatus which claim 1 , in use of the distillation apparatus claim 1 , would come into contact with the distillate or process fluid are produced from a material selected from the group consisting of fluoropolymers claim 1 , fluorochloropolymers claim 1 , glass claim 1 , enamel claim 1 , phenolic resin impregnated graphite claim 1 , silicium carbide and fluoropolymer impregnated graphite. The present invention relates to processes for producing chlorinated alkane compounds having acceptably low levels of oxygenated impurities.Haloalkanes find utility in a range of applications. For example, halocarbons are used extensively as refrigerants, blowing agents and foaming agents. Throughout the second half of the twentieth century, the use of chlorofluoroalkanes increased exponentially until the 1980's, when concerns were raised about their environmental impact, specifically regarding depletion of the ozone layer.Subsequently, fluorinated hydrocarbons such as perfluorocarbons and hydrofluorocarbons have been used in place of chlorofluoroalkanes, although more recently, environmental concerns about the use of that class of compounds have been raised and legislation has been enacted in the EU and elsewhere to reduce their use.New classes of environmentally friendly halocarbons are emerging and have been investigated, and in some cases, embraced in a number of applications, especially as refrigerants in the automotive and domestic fields. Examples of such compounds include hydrofluoroolefins (HFOs) such as 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), 1,3,3,3-tetrafluoropropene (HFO- ...

MONO-SUBSTITUTED CYCLOPENTADIENES AND METAL CYCLOPENTADIENYL COMPLEXES AND SYNTHESIS METHODS THEREOF

Disclosed are mono-substituted cyclopentadienes, metal cyclopentadienyl complexes and methods for synthesizing them. The disclosed mono-substituted cyclopentadienes are synthesized by a selective catalytic carbon-carbon coupling reaction. The disclosed metal cyclopentadienyl complexes are synthesized from the disclosed mono-substituted cyclopentadienes. The disclosed metal cyclopentadienyl complexes include main group metal and transition metal cyclopentadienyl complexes, and may be used as deposition precursors contained in film forming compositions for film depositions in semiconductor industry, such as ALD, CVD, SOD, etc. 1. A method of synthesizing a mono-substituted cyclopentadiene , the method comprising:mixing a metal hydroxide, a halide, a cyclopentadiene monomer, an alkaline earth oxide, and a homogeneous catalyst in a solvent; andallowing a selective catalytic carbon-carbon coupling reaction to form the mono-substituted cyclopentadiene,wherein approximately 20-400% excess amount of the cyclopentadiene monomer is used relative to the amount of the halide.2. The method of claim 1 , further comprising:contacting the mono-substituted cyclopentadiene with a metal compound; andconverting the mono-substituted cyclopentadiene to a metal cyclopentadienyl complex.3. The method of claim 2 , further comprising:maintaining a temperature within a range of from −15° C. to 70° C. under atmospheric pressure.4. The method of claim 2 , further comprising:optionally purifying the mono-substituted cyclopentadiene.5. (canceled)6. The method of claim 1 , wherein approximately 40-80% excess amount of the cyclopentadiene monomer is used relative to the amount of the halide.7. The method of claim 1 , wherein the metal hydroxide is MOH claim 1 , wherein M is Group I alkali metal.8. The method of claim 1 , wherein the halide is an silyl- claim 1 , amino- claim 1 , alkyl- or hydrocarbonyl halide or fluoroalkyl halide has the formula R(Hal) or R(F)(Hal) claim 1 , wherein Hal is ...

PROCESS FOR PREPARING N-(5-CHLORO-2-ISOPROPYLBENZYL)CYCLOPROPANAMINE

The present invention relates to a process for preparing N-(5-chloro-2-isopropylbenzyl)cyclopropanamine by hydrogenation of N-[(5-chloro-2-isopropylphenyl)methylene]cyclopropanamine over specific platinum catalysts. 12. The process according to wherein the acid used in step (g) to convert 3-bromo-4-isopropylaniline of the formula (VII) into the ammonium salts of the formula (VIII) is selected from the group consisting of HSO claim 9 , HCl claim 9 , HCOH claim 9 , HPO. The present invention relates to a process for preparing N-(5-chloro-2-isopropylbenzyl)cyclopropanamine by hydrogenation of N-[(5-chloro-2-isopropylphenyl)methylene]cyclopropanamine over specific platinum catalysts.Preparative processes for brominating strongly deactivated aromatics such as p-alkyl-substituted nitrobenzenes or nitrobenzene itself are described in the literature. The bromination of p-nitroethylbenzene by means of iron and bromine has been described with very low yields (55% yield of crude product and 34% after distillation) and with long reaction times of over 24 hours (1950, 72, 2804). The bromination of nitrobenzene by means of iron and bromine is described with a yield of always 60-75% of isolated compound (cf. 1941, Coll. Vol. I, 123, ibid. 1928, Vol 8, 48). A further possible way of brominating deactivated aromatics by means of potassium bromate is known (1981, 46, 2169-2171). However, reactions are problematical from a safety point of view because of the decomposition of potassium bromate in over 70% strength sulphuric acid solution. Furthermore, the bromination of p-nitrotoluene or nitrobenzene by means of N-bromosuccinimide in half-concentrated sulphuric acid is known (2006, 8, 645-6471965, 30, 304-306). However, this reaction requires N-bromosuccinimide as brominating reagent. Dimethyldibromohydantoin is found to be significantly more efficient (cf. 1994, 67, 1918-1921). However, trifluoromethanesulphonic acid, a very expensive reagent, is used here as proton source, which ...

MONO-SUBSTITUTED CYCLOPENTADIENES AND METAL CYCLOPENTADIENYL COMPLEXES AND SYNTHESIS METHODS THEREOF

A metal cyclopentadienyl complex has the formula:

Method for manufacturing difluoromethylene compound

The problem to be solved by the present invention is to provide a novel method for producing a difluoromethylene compound. This problem is solved by a method for producing a difluoromethylene compound containing a —CF 2 — moiety, the method comprising step A of mixing: a) a carbonyl compound containing a —C(O)— moiety; b) optionally an amine; c) a fluoride represented by the formula: MF, wherein M represents a Group 1 element of the periodic table; d) a halogenated fluorine compound represented by the formula: XF n , wherein X represents chlorine, bromine, or iodine, and n is a natural number of 1 to 5; and e) sulfur chloride.

PHOSPHINE LIGANDS FOR CATALYTIC REACTIONS

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions. 130-. (canceled)33. The method of claim 31 , wherein X is attached to an atom of Aradjacent to the atom bonded to Ar.35. The method of claim 34 , wherein Rand Rare hydrogen.36. The method of claim 34 , wherein Rand Rtogether with the carbon atom to which they are attached form a 3- claim 34 , 4- claim 34 , 5- claim 34 , 6- claim 34 , or 7-membered spirocyclic ring containing 0 claim 34 , 1 claim 34 , or 2 ring heteroatoms.38. The method of claim 31 , wherein Arand Arare each aryl.39. The method of claim 31 , wherein Aris substituted with two Rand Aris substituted with three R.40. The method of claim 31 , wherein Ris alkyloxy and wherein Ris alkyl.41. The method of claim 31 , wherein Ris isopropyl.43. The method of claim 42 , wherein Rtogether with Rform a 5-membered spiro ring containing two heteroatoms.44. The method of claim 43 , wherein the two heteroatoms are each oxygen.45. The method of claim 31 , wherein R claim 31 , R claim 31 , R claim 31 , and Rare each methyl.48. The method of claim 47 , wherein the compound is selected from the group consisting of:2,2,6,6-tetramethyl-1-(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphinane;2,2,6,6-tetramethyl-1-(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphinan-4-one;2,2,6,6-tetramethyl-1-(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphinan-4-ol;7,7,9,9-tetramethyl-8-(2′,4′,6′-triisopropylbiphenyl-2-yl)-1,4-dioxa-8-phosphaspiro[4.5]decane;8,8,10,10-tetramethyl-9-(2′,4′,6′-triisopropylbiphenyl-2-yl)-1,5-dioxa-9-phosphaspiro[5.5]undecane;3,3,8,8,10,10-hexamethyl-9-(2′,4′,6′-triisopropylbiphenyl-2-yl)-1,5-dioxa-9-phosphaspiro[5.5]undecane;1-(2′-(dimethylamino)-6′-methoxybiphenyl-2-yl)-2,2,6,6-tetramethylphosphinan-4-one;1-(2′,6′-bis(dimethylamino)biphenyl-2-yl)-2,2,6,6-tetramethylphosphinan-4-one;1-(2′,6′-dimethoxybiphenyl-2 ...

CONVERSION OF ALKANES TO ORGANOSELENIUMS AND ORGANOTELLURIUMS

The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins. 1. A process for the conversion of an alkane or a heteroalkane , wherein the alkane or heteroalkane comprises at least one sp-hybridized carbon atom , to a corresponding alkylselenium or alkyltellurium compound comprising(a) contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium; to form the corresponding alkylselenium or alkyltellurium compound and optionally(b) separating the respective alkylselenium or alkyltellurium compound.2. The process of claim 1 , further comprising a step of regeneration of the soft oxidizing electrophile by contacting a Se- or Te-containing electrophile reduction product of the soft oxidizing electrophile and the alkane or heteroalkane with an oxidant under conditions suitable to regenerate the soft oxidizing electrophile comprising Se(VI) or Te(VI).3. (canceled)4. The process of claim 1 , wherein the alkane is methane claim 1 , ethane claim 1 , or propane claim 1 , or any mixture thereof.5. The process of claim 1 , wherein the acidic medium is free of a superacid.6. The process of claim 2 , wherein the regenerating oxidant comprises any of molecular oxygen claim 2 , hydrogen peroxide claim 2 , chlorine claim 2 , nitric acid claim 2 , or ozone.7. The process of claim 2 , wherein the regenerating oxidant ...

CATALYSTS AND INTEGRATED PROCESSES FOR PRODUCING TRIFLUOROIODOMETHANE

The present disclosure provides a process for producing trifluoroiodomethane (CFI). The process may include providing a vapor-phase reactant stream comprising trifluoroacetic acid and iodine and reacting the reactant stream in the presence of a catalyst to produce a product stream comprising the trifluoroiodomethane. The catalyst includes silicon carbide. 1. A process for producing trifluoroiodomethane (CFI) , the process comprising:providing a vapor-phase reactant stream comprising trifluoroacetic acid and iodine; andreacting the reactant stream in the presence of a catalyst to produce a product stream comprising the trifluoroiodomethane, the catalyst comprising silicon carbide.2. The process of claim 1 , wherein in the providing step claim 1 , the trifluoroacetic acid comprises less than about 500 ppm by volume of water.3. The process of claim 1 , wherein in the providing step claim 1 , the iodine comprises less than about 500 ppm by weight of water.4. The process of claim 1 , wherein in the providing step claim 1 , a mole ratio of the iodine to the trifluoroacetic acid is from about 0.1:1 to about 2:1.5. The process of claim 1 , wherein the catalyst further comprises a metal carbide.6. The process of claim 5 , wherein the metal carbide is titanium carbide.7. The process of claim 1 , wherein the catalyst further comprises at least one selected from the group of a metal and a metal salt deposited on a surface of the catalyst.8. The process of claim 7 , wherein the metal or metal salt is from about 0.1 wt. % to about 25 wt. % of the total weight of the catalyst.9. The process of claim 7 , wherein the metal salt comprises at least one selected from the group of potassium iodide claim 7 , copper iodide claim 7 , and rubidium iodide.10. The process of claim 1 , wherein in the reacting step claim 1 , a contact time of the reactant stream with the catalyst is from about 1 second to about 120 seconds.11. The process of claim 1 , further comprising heating the catalyst to ...

Oligophenylene monomers and polymeric precursors for producing graphene nanoribbons

Oligophenylene monomers for the synthesis of polymeric precursors for the preparation of graphene nanoribbons, the polymeric precursors, and methods for preparing them, as well as methods for preparing the graphene nanoribbons from the polymeric precursors and the monomers are provided.

METHOD FOR MANUFACTURING FLUORINATED HYDROCARBON

The present invention is a method for producing a fluorinated hydrocarbon represented by a structural formula (3), wherein an ether compound represented by a structural formula (1) and an acid fluoride represented by a structural formula (2) are brought into contact with each other in a hydrocarbon-based solvent, in the presence of a catalyst in which boron trifluoride is supported on a metal oxide: wherein Rand Rrepresent an alkyl group having 1 to 3 carbon atoms, Rrepresents a hydrogen atom, a methyl group or an ethyl group, and Rand Rrepresent a methyl group or an ethyl group; and Rand Rmay be bonded to each other to form a cyclic structure. Through the present invention, a method for industrially advantageously producing 2-fluorobutane is provided. 2. The production method according to claim 1 , wherein the metal oxide is at least one selected from aluminum oxide claim 1 , titanium oxide and zirconium oxide.3. The production method according to claim 1 , wherein the ether compound represented by the structural formula (1) is sec-butyl methyl ether or t-butyl methyl ether.4. The production method according to claim 1 , wherein the acid fluoride represented by the structural formula (2) is acetyl fluoride.5. The production method according to claim 1 , wherein the fluorinated hydrocarbon represented by the structural formula (3) is 2-fluorobutane. The present invention relates to a method for producing fluorinated hydrocarbons useful as plasma reaction gases in plasma etching, plasma chemical vapor deposition (plasma CVD) and the like effective in the field of producing semiconductor devices, useful as fluorine-containing medical intermediates, and useful as hydrofluorocarbon-based solvents. Highly purified fluorinated hydrocarbons are suitable as plasma etching gases, plasma CVD gases and the like, in particular, in the field of producing semiconductor devices using plasma reaction.Recently, miniaturization of semiconductor production techniques has increasingly ...

Synthesis of diiodoperfluoro-c3 to c7-alkanes

The present invention is the process comprising forming a stable mixture comprising I(CF 2 ) n I, wherein n is at least 3 and at least one of I(CF 2 ) n I, wherein n is 1 or 2, as a contaminant in said mixture and heating said mixture to a temperature of at least 220° C. to reduce the amount of said contaminant to be no greater than 1% when said contaminant is ICF 2 I (n=1) and no greater than 0.1% when said contaminant is ICF 2 CF 2 I (n=2).

METHOD FOR AROMATIC FLUORINATION

Disclosed is a fluorination method comprising providing an aryl fluorosulfonate and a fluorinating reagent to a reaction mixture; and reacting the aryl fluorosulfonate and the fluorinating reagent to provide a fluorinated aryl species.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions.

FLUOROIODO COMPOUNDS FOR FLUOROPOLYMERS

Described herein is a composition comprising a partially fluorinated compound selected from the group consisting of: I(CF)CH═CH(Formula III); and I(CF)XCHCHI (Formula II) wherein x is an odd integer selected from 3 to 11. 1. A composition comprising a partially fluorinated compound of:{'sub': 2', 'x', '2, '(a) I(CF)CH═CH(Formula III); and'}wherein x is an odd integer selected from 3 to 11.2. A polymer composition comprising the polymerized reaction product of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) the partially fluorinated compound of ; and'}(b) a fluorinated olefinic monomer.3. The polymer composition of claim 2 , wherein the fluorinated olefinic monomer is selected from the group consisting of: hexafluoropropylene claim 2 , trifluoroethylene claim 2 , fluoroethylene claim 2 , vinylidene fluoride claim 2 , tetrafluoroethylene claim 2 , perfluoro(methyl vinyl ether) claim 2 , perfluoro(propyl vinyl ether) claim 2 , perfluoro(methoxypropyl vinyl ether) claim 2 , perfluoro(ethoxymethyl vinyl ether) claim 2 , chlorotrifluoroethylene claim 2 , and combinations thereof.4. The polymer composition of claim 2 , wherein the polymerized reaction product further comprises (c) a chain transfer agent claim 2 , wherein the chain transfer agent is selected from the group consisting of: a C1 to C10 α claim 2 ,ω-diiodoperfluoroalkane; I(CF)CHCHI claim 2 , wherein y is an integer from 2 to 10; CHI; and combinations thereof.5. The polymer composition of claim 4 , wherein the chain transfer agent is 1 claim 4 ,3-diiodoperfluoropropane or 1 claim 4 ,4-diiodoperfluorobutane.6. The polymer composition of claim 2 , wherein x is 3.7. The polymer composition of claim 2 , wherein the polymerized reaction product further comprises a non-fluorinated olefinic monomer.8. The polymer composition of claim 2 , wherein the polymer composition comprises 0.05 to 1% by weight of iodine.9. An article comprising the cured polymer composition according to .10. A method of making a polymer ...

Alkenes as alkyne equivalents in radical cascades terminated by fragmentations

Disclosed are methods for rerouting radical cascade cyclizations by using alkenes as alkyne equivalents. The reaction sequence is initiated by a novel 1,2 stannyl shift which achieves chemo- and regioselectivity in the process. The radical “hopping” leads to the formation of the radical center necessary for the sequence of selective cyclizations and fragmentations to follow. In the last step of the cascade, the elimination of a rationally designed radical leaving group via β-C—C bond scission aromatizes the product without the need for external oxidant. The Bu 3 Sn moiety, which is installed during the reaction sequence, allows further functionalization of the product via facile reactions with electrophiles as well as Stille and Suzuki cross-coupling reactions. This selective radical transformation opens a new approach for the controlled transformation of enynes into extended polycyclic structures of tunable dimensions.

COMPOSITIONS BASED ON 1,1,3,3-TETRACHLOROPROPENE

Compositions based on F-1230za (1,1,3,3-tetrachloropropene), or on a mixture consisting of F-1230za and F-1230zd (1,3,3,3-tetrachloropropene), the manufacture thereof, and also the use thereof in particular for the production of F-1233zdE (trans-1-chloro-3,3,3-trifluoropropene), F-1234zeE (trans-1,3,3,3-tetrafluoropropene), and/or F-245fa (1,1,1,3,3-pentafluoropropane). A process for manufacturing the composition, the process including the following steps: reaction of carbon tetrachloride with ethylene to produce 1,1,1,3-tetrachloropropane (F-250fb); chlorination of F-250fb to obtain 1,1,1,3,3-pentachloropropane (F-240fa); dehydrochlorination of F-240fa to obtain 1,1,3,3-tetrachloropropene (F-1230za); one or more steps for separating out the F-1230za. 1. A composition comprising at least 99.5% by weight of 1 ,1 ,3 ,3-tetrachloropropene (F-1230za) , or a mixture of 1 ,1 ,3 ,3-tetrachloropropene and of 1 ,3 ,3 ,3-tetrachloropropene (F-1230zd) , and at least one additional compound chosen from a list of compounds consisting of pentachloropropanes , tetrachloropropenes other than F-1230za and F-1230zd , chlorobutenes , chlorobutanes and oxygenated compounds , said compound and/or the total amount of said compounds being present in the composition in a content of less than or equal to 0.5% by weight.2. The composition as claimed in claim 1 , in which said additional compound represents a content of less than or equal to 1000 ppm; or less than or equal to 500 ppm; or less than or equal to 450 ppm; or less than or equal to 400 ppm; or less than or equal to 350 ppm; or less than or equal to 300 ppm; or less than or equal to 250 ppm; or less than or equal to 200 ppm; or less than or equal to 150 ppm; or less than or equal to 100 ppm; or less than or equal to 75 ppm; or less than or equal to 50 ppm; or less than or equal to 25 ppm; or less than or equal to 10 ppm; or less than or equal to 5 ppm claim 1 , in the composition.3. The composition as claimed in claim 2 , in which ...

METHOD FOR AROMATIC FLUORINATION

Disclosed is a fluorination method comprising providing an aryl fluorosulfonate and a fluorinating reagent to a reaction mixture; and reacting the aryl fluorosulfonate and the fluorinating reagent to provide a fluorinated aryl species. 1. A fluorination method comprising: 'where Ar is an aryl or heteroaryl;', 'providing a compound having the structure Ar—OH to a reaction mixture;'}{'sub': 2', '2, 'providing SOFto the reaction mixture;'}providing a fluorinating reagent to the reaction mixture;{'sub': 2', '2, 'reacting the SOF, the fluorinating reagent and the compound having the structure Ar—OH to provide a fluorinated aryl species having the structure Ar—F.'}2. The fluorination method of claim 1 , wherein the fluorinating reagent is selected from the group consisting of sodium fluoride claim 1 , potassium fluoride claim 1 , cesium fluoride claim 1 , tetrabutylammonium fluoride claim 1 , and tetramethylammonium fluoride.3. A method according to claim 1 , further comprising providing a solvent to the reaction mixture.4. The fluorination method of claim 3 , wherein the solvent is selected from the group consisting of polar aprotic solvents claim 3 , alkoxy ether solvents claim 3 , nitrile solvents claim 3 , aromatic solvents claim 3 , and mixtures thereof.5. The fluorination method of claim 4 , wherein the solvent comprises a polar aprotic solvent.6. The fluorination method of claim 4 , wherein the solvent comprises an alkoxy ether solvent.7. The fluorination method of claim 4 , wherein the solvent comprises a nitrile solvents.8. The fluorination method of claim 4 , wherein the solvent comprises an aromatic solvent.9. The fluorination method of claim 3 , wherein the fluorinating reagent is selected from the group consisting of sodium fluoride claim 3 , potassium fluoride claim 3 , cesium fluoride claim 3 , tetrabutylammonium fluoride claim 3 , and tetramethylammonium fluoride.10. The fluorination method of claim 4 , wherein the fluorinating reagent is selected from the ...

Conversion of hexafluorobenzene to bromopentafluorobenzene

A method for producing tetrakis (pentafluorophenyl) borates is described. Hexafluorobenzene is converted to bromopentafluorobenzene which may be isolated and then reacted with an alkyl lithium to produce pentafluorophenyl lithium which in turn is reacted directly with an appropriate reagent to produce the desired borate.

4-phenyl-pyrane-3,5-diones, 4-phenyl-thiopyrane-3,5-diones and cyclohexanetriones as novel herbicides

Pyrandione, thiopyrandione and cyclohexanetrione compounds, which are suitable for use as herbicides.

Herbicidally active bicyclic 1,3-dione compounds

Bicyclic dione compounds of formule (I), and derivatives thereof, which are suitable for use as herbicides.

Synthesis of 4-ketocyclopentene compounds

A process for forming 4-ketocyclopentene and substituted 4-ketocyclopentene compounds starting from the corresponding 1-carbohydrocarbyloxy-2-keto-4-hydroxy-5-cyclopentene by reduction followed by decarboxylation.

Synthesis of cyclopentadiene or substituted cyclopentadiene compounds

Substituted or unsubstituted cyclopentadienyl are prepared by reducing 4-ketocyclopentene to an alcohol, replacing the hydroxyl functionality with a leaving group and deprotonating the resulting product under base induced elimination conditions.

Perfluoronaphthyl substituted boron containing catalyst activator

A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 100 non-hydrogen atoms.

Synthesis of perfluoro aromatic boranes and borates

SYNTHESIS OF PERFLUORAROMATIC BORANAS AND BORATES

Synthesis of perfluoro aromatic boranes and borates

ペルフルオロ芳香族ボランおよびホウ酸塩の合成

(57)【要約】 ヘキサフルオロベンゼンからブロモペンタフルオロベンゼンを合成する方法が開示される。

Synthesis of perfluoro aromatic boranes and borates

Synthesis of perfluoro aromatic boranes and borates

A method for synthesizing bromopentafluorobenzene from hexafluorobenzene is described.

Synthesis of fluorophenyl boranes

Process for converting gaseous alkanes to olefins and liquid hydrocarbons

A process for converting gaseous alkanes to olefins and liquid hydrocarbons wherein a gaseous feed containing alkanes is reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid are then reacted over a synthetic crystalline alumino-silicate catalyst, such as an X or Y type zeolite, at a temperature of from about 250° C. to about 500° C. so as to form olefins, higher molecular weight hydrocarbons and hydrobromic acid vapor. Various methods are disclosed to remove the hydrobromic acid vapor from the higher molecular weight hydrocarbons and to generate bromine from the hydrobromic acid for use in the process.

Perfluoroisopropylbenzene derivatives

Perfluoroisopropylbenzene derivatives of the general formula (I) or salts thereof, useful as intermediates or raw materials in the synthesis of various industrial materials including agricultural chemicals, drugs and surfactants, wherein X1 is H, halogeno, formyl, optionally halogenated C1-6 alkyl, C1-6 alkylthio, or the like; X2 is H, halogeno, formyl, hydroxyl, C1-6 alkyl, -C(=O)-R1 (wherein R1 is H, halogeno, hydroxyl, C1-6 alkyl, or NR2R3, with R2 and R3 being each H, C1-6 alkyl, or the like), or the like; X3 is H, halogeno, hydroxyl, cyano, isocyanato, hydrazino, diazo, -C(=O)-R1, -SO2-R4 (wherein R4 is halogeno, hydroxyl, C1-6 alkyl, or NR5R6, with R5 and R6 being each H or C1-6 alkyl), or the like; and X4 is H, halogeno, C1-6 alkyl, or C1-6 alkoxy, with publicly known compounds being excepted.

全氟异丙基苯衍生物

通式(I)的全氟异丙基苯衍生物，适合在合成农用化学品、药物和表面活性剂中作为中间体或原料：其中X 1 为H、卤素、甲酰基、可选地卤代的(C 1 －C 6 )烷基、(C 1 －C 6 )烷硫基等；X 2 为H、卤素、甲酰基、羟基、(C 1 －C 6 )烷基、－C(＝O)－R 1 (其中R 1 为H、卤素、羟基、(C 1 －C 6 )烷基、或NR 2 R 3 (其中R 2 和R 3 均为H、C 1－6 烷基等))等；X 3 为H、卤素、羟基、氰基、异氰酸基、肼基、重氮基、－C(＝O)－R 1 、－SO 2 －R 4 (其中R 4 为卤素、羟基、(C 1 －C 6 )烷基或NR 5 R 6 (其中R 5 和R 6 均为H或(C 1 －C 6 )烷基)等；和X 4 为H、卤素、(C 1 －C 6 )烷基或(C 1 －C 6 )烷氧基，公知的化合物除外。

Perfluoroisopropybenzene derivative

Perfluoroisopropylbenzene derivatives of the general formula (I) or salts thereof, useful as intermediates or raw materials in the synthesis of various industrial materials including agricultural chemicals, drugs and surfactants, wherein X 1 is H, halogeno, formyl, optionally halogenated C 1-6 alkyl, —C(═O)—R 1 (wherein R 1 is H, halogeno, hydroxyl, C 1-6 alkyl, or NR 2 R 3 , with R 2 and R 3 being each H, C 1-6 alkyl, or the like), or the like; X 3 is H, halogeno, hydroxyl, cyano, isocyanato, hydrazino, diazo, —C(═O)—R 1 , —SO 2 —R 4 (wherein R 4 is halogeno, hydroxyl, C 1-6 alkyl, or NR 5 R 6 , with R 5 and R 6 being each H or C 1-6 alkyl), or the like; and X 4 is H, halogeno, C 1-6 alkyl, or C 1-6 alkoxy, with publicly known compounds being excepted.

Metho dof obtaining cyclopropyl acetylene

Synthesis of 4-ketocyclopentene and cyclopentadiene compounds

A process for forming 4-ketocyclopentene and substituted 4-ketocyclopentene compounds starting from the corresponding 1-carbohydroxarbyloxy-2-keto-4-hydroxy-5-cyclopentene by reduction followed by decarboxylation. The ketone may thereafter be converted to a cyclopentadiene compound by reducing the ketone to form an alcohol, replacing the hydroxyl functionality of the alcohol under substitution conditions with a leaving group, and deprotonating the resulting product under base induced elimination conditions to form the cyclopentadiene compound. Alternatively functionalized cyclopentadienyl compounds can be produced without isolation of an unsubstituted cyclopentadienyl compound by combining the elimination and deprotonation steps with a replacement step in a single unit operation.

Process for converting gaseous alkanes to olefins and liquid hydrocarbons

A process for converting gaseous alkanes to olefins and higher molecular weight hydrocarbons wherein a gaseous feed containing alkanes is reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid are then reacted over a synthetic crystalline alumino-silicate catalyst, such as an X or Y type zeolite, at a temperature of from about 250° C. to about 500° C. so as to form olefins, higher molecular weight hydrocarbons and hydrobromic acid vapor. Various methods are disclosed to remove the hydrobromic acid vapor from the olefins and higher molecular weight hydrocarbons and to generate bromine from the hydrobromic acid for use in the process.

Perfluoronaphthyl substituted boron containing catalyst activator

A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 1000 non-hydrogen atoms.

Perfluoronaphthyl substituted boron containing catalyst activator

Method for producing difluoroalkylated organics

본 발명은 다이플루오로알킬기가 도입된 알케인(alkane) 및 알켄(alkene)을 선택적으로 제공할 수 있는 다이플루오로알킬기가 도입된 유기 화합물의 제조 방법에 관한 것이다. 일 구현예에 따르면, 상기 제조 방법은 광촉매, 알켄 화합물, 할로다이플루오로아세테이트, 베이스 및 용매를 포함하는 혼합물을 제조하되, 상기 베이스로 3차 아민 또는 비양성자성 음이온을 사용하고, 상기 혼합물에 가시광선을 조사하는 것을 포함한다. The present invention relates to a process for the preparation of an organic compound into which a difluoroalkyl group is introduced and which can selectively provide an alkane and an alkene to which a difluoroalkyl group is introduced. According to one embodiment, the process comprises preparing a mixture comprising a photocatalyst, an alkene compound, halodifluoroacetate, a base and a solvent, wherein the base is a tertiary amine or an aprotic anion, And irradiating visible light.

Halogenated phosphinic acids and their active metal derivatives

Compounds of formula (I), their preparation and compositions thereof for optical devices). The compounds are formula (I), where A1 is selected from O and S; A2 is selected from -OH, -SH, and OR3; Rf and Rf1 can be the same or different, can be branched or unbranched, and are selected from perfluorinated C1-20alkyl, perfluorinated C1-6alkyl C1-10alkyl ethers, n-C8F17, n-C6F13, n-C4F9, n-C2F5, (CF3)2CF(CF2)4, n-C10F21, n-C12F25,(CF3)2CF(CF2)6, and (CF3)2CFO(CF2)2; and R3 can be branched or unbranched and is selected from C1-15 alkyl, C3-15 aryl, C4-15alkylaryl, and C4-15 arylalkyl, wherein, (i) if Rf and Rf1 are the same and selected from n-C2F5, n-C4F9, n-C6F13, n-C7F15, and n-C8F17, then A1 is not O; (ii) if Rf and Rf1 are the same and selected from n-C2F5, n-C4F9, n-C6F13, n-C7F15, and n-C8F17, then A2 is not -OH; and (iii) if A1 is O, and if Rf and Rf1 are the same and selected from n-C6F13, n-C7F15 and n-C8F17, then A2 is not -OCH3.

Fluorinated and halogenated phosphinic acids and their active metal derivatives

Compounds of formula (I), methods of making and method of using (including optical compositions and devices) are provided. The compounds are where A 1 is selected from O and S; A 2 is selected from —OH, —SH, and —OR 3 ; R f and R f1 can be the same or different, can be branched or unbranched, can be linked to form cyclic or extended structures, and are selected from halogenated alkyl, halogenated aryl, halogenated cyclic alkyl, halogenated arylalkyl, halogenated alkylaryl, halogenated polyether, halogenated thioether, halogenated ether thioether, halogenated aklyl amino groups, halogenated alkylene, halogenated silylene, halogenated siloxanes, halogenated silazanes, halogenated olefins, perfluorinated C 1-20 alkyl, perfuorinated C 1-6 alkyl C 1-10 alkyl ethers, n-C 8 F 17 , n-C 6 F 13 , n-C 4 F 9 , n-C 2 F 5 , (CF 3 ) 2 CF(CF 2 ) 4 , n-C 10 F 21 , n-C 12 F 25 , (CF 3 ) 2 CF(CF 2 ) 6 , and (CF 3 ) 2 CFO(CF 2 ) 2 ; and R 3 can be branched or unbranched and is selected from C 1-15 alkyl, C 3-15 aryl, C 4-15 alkylaryl, and C 4-15 arylalkyl. Wherein, (i) if R f and R f1 are the same and selected from n-C 2 F 5 , n-C 4 F 9 , n-C 6 F 13 , n-C 7 F 15 , and n-C 8 F 17 , then A 1 is not O; (ii) if R f and R f1 , are the same and selected from n-C 2 F 5 , n-C 4 F 9 , n-C 6 F 13 , n-C 7 F 15 , and n-C 8 F 17 , then A 2 is not —OH; and (iii) if A 1 is O, and if R f and R f1 are the same and selected from n-C 6 F 13 , n-C 7 F 15 and n-C 8 F 17 , then A 2 is not —OCH 3 .

全氟异丙基苯衍生物

通式(I)的全氟异丙基苯衍生物，适合在合成农用化学品、药物和表面活性剂中作为中间体或原料：其中X 1 为H、卤素、甲酰基、可选地卤代的(C 1 -C 6 )烷基、(C 1 -C 6 )烷硫基等；X 2 为H、卤素、甲酰基、羟基、(C 1 -C 6 )烷基、-C(＝O)-R 1 (其中R 1 为H、卤素、羟基、(C 1 -C 6 )烷基、或NR 2 R 3 (其中R 2 和R 3 均为H、C 1-6 烷基等))等；X 3 为H、卤素、羟基、氰基、异氰酸基、肼基、重氮基、-C(＝O)-R 1 、-SO 2 -R 4 (其中R 4 为卤素、羟基、(C 1 -C 6 )烷基或NR 5 R 6 (其中R 5 和R 6 均为H或(C 1 -C 6 )烷基))等；和X 4 为H、卤素、(C 1 -C 6 )烷基或(C 1 -C 6 )烷氧基，公知的化合物除外。

DIRECT SYNTHESIS OF TRIFLUOROMETHYLIODIDE IN ONE STEP

Process for converting gaseous alkanes to olefins and liquid hydrocarbons

본 발명은, 알칸을 함유하는 가스상 공급물을 무수 브롬 증기와 반응시켜 알킬 브로마이드 및 브롬화수소산 증기를 형성시키는, 가스상 알칸의 올레핀 및 고분자량 탄화수소로의 전환방법에 관한 것이다. 이어서, 알킬 브로마이드와 브롬화수소산과의 혼합물을 합성 결정질 알루미노-실리케이트 촉매(예: X형 또는 Y형 제올라이트) 상에서 약 250 내지 약 500℃의 온도에서 반응시켜 올레핀, 고분자량 탄화수소 및 브롬화수소산 증기를 형성한다. 올레핀 및 고분자량 탄화수소로부터 브롬화수소산 증기를 제거하고 상기 방법에서 사용하기 위한 브롬화수소산으로부터 브롬을 생성시키는 다양한 방법이 기술된다. The present invention relates to a process for converting gaseous alkanes to olefins and high molecular weight hydrocarbons by reacting a gaseous feed containing alkanes with anhydrous bromine vapor to form alkyl bromide and hydrobromic acid vapors. The mixture of alkyl bromide and hydrobromic acid is then reacted on a synthetic crystalline alumino-silicate catalyst (e.g., type X or Y zeolite) at a temperature of about 250 to about 500 ° C. to give olefin, high molecular weight hydrocarbon and hydrobromic acid vapors. Form. Various methods are described for removing hydrobromic acid vapor from olefins and high molecular weight hydrocarbons and producing bromine from hydrobromic acid for use in the process. 가스상 알칸, 올레핀, 액상 탄화수소, 합성 결정질 알루미노-실리케이트 촉매, 브롬화수소산 증기 제거. Gas phase alkanes, olefins, liquid hydrocarbons, synthetic crystalline alumino-silicate catalysts, hydrobromic acid vapor removal.

Method of making chlorobenzenes

Disclosed is a method of making a chlorobenzene having the general formulas ##STR1## where X is Cl or F, and X' is X or CF 3 . A compound having the formula ##STR2## is sulfonated using at least 2 moles per mole of said compound of a sulfonating agent selected from the group consisting of sulfuric acid, chlorosulfonic acid, and mixtures thereof, to produce a sulfonated compound. The sulfonated compound is chlorodesulfonated to produce a chlorobenzene, such as 1,2,4-trichlorobenzene. Preferably, the starting material is ortho-dichlorobenzene.

PROCESS FOR THE PREPARATION OF FLUORO-HALOGENAL CANS

ジハロジフルオロメタンおよびその同族体の製造方法

(57)【要約】 高度にフッ素化したエポキシドを、金属および金属含有の反応プロモーターの存在下にジハロゲンと反応させて、ジハロフルオロメタンおよびその同族体を得る。得られるジハロジフルオロアルカンは、機能性フルオロモノマーや、その他の有用な有機フッ素化材料を製造するのに有用である。ジヨードペルフルオロアルカンも、フルオロエラストマーの連鎖移動剤として有用である。

PROCESS FOR THE PURIFICATION OF HYDROGEN CHLORIDE

A kind of new OLED intermediary material preparation methods

本发明属于有机电致发光材料技术领域，公开了一种新型的OLED中间体材料制备方法，具体为一种4',4”'‑(1‑(4‑碘苯基)乙基‑1,1‑2‑二)双(4‑溴‑1,1'‑二苯基)的合成方法，本发明以4‑硝基苯乙酮和苯酚为原料，合成产物与三氟甲基磺酸酐在吡啶的作用下反应，得到产物和双联频哪醇硼酸酯反应，得到产物与4‑溴碘苯通过suzuki反应，得到产物通过铁粉和浓盐酸，得到产物通过重氮化上碘反应，得到最终目标产物。本发明原料简单、易于实现工业化生产、生产周期短；通过在有机物中引入Br基团可进一步改善其溶解性和热稳定性，便于有机物进一步反应生成光电性能更好的材料。

Production of hydrofluorocarbons

본 발명은 증기상의 α-플루오로에테르를 고온에서 촉매와 접촉시키고, 당해 촉매의 처리를 통해 촉매의 활성을 유지 및/또는 재건시키는 것으로 구성되는 하이드로(할로) 플루오로카본의 생산방법에 관한 것인바, 당해 촉매법은 촉매처리법이 (i) α - 플루오로에테르의 부재 하에서 촉매를 약 250℃ 이상의 고온으로 가열하거나, 또는 (ii) 고온에서 촉매를 산화제와 접촉시키는 것으로 구성되는 방법으로 구성되며, 당해 촉매는 금속산화물, 플루오라이드 또는 옥시플루오라이드 담체 상에 존재하는, 예컨대, 아연, 철, 또는 동과 같은 산화촉진 금속이 될 수 있다. The present invention relates to a process for producing a hydro (halo) fluorocarbon consisting of contacting the vapor phase α-fluoroether with a catalyst at a high temperature and maintaining and / or rebuilding the activity of the catalyst through treatment of the catalyst. Inba, the catalyst process consists of a process in which the catalytic treatment consists of (i) heating the catalyst to a high temperature of about 250 ° C. or higher in the absence of α-fluoroether, or (ii) contacting the catalyst with an oxidant at a high temperature. The catalyst may be an oxidation promoting metal such as, for example, zinc, iron, or copper, present on a metal oxide, fluoride or oxyfluoride carrier.

Fluorinated indenes and 1,7-dihydroindacenes of negative ??

본 발명은 음의 유전 비등방성(Δε<0)을 갖는 하기 화학식 1 및 2의 불화 인덴 및 1,7-디하이드로인다센에 관한 것이다: The present invention relates to indene fluoride and 1,7-dihydroindacene of formulas (1) and (2) having negative dielectric anisotropy (Δε <0): 화학식 1 Formula 1 화학식 2 Formula 2 상기 식에서, T, A, R, L, X, Y, U, W, Z, n, m, p 및 q는 청구항에 정의된 바와 같다. Wherein T, A, R, L, X, Y, U, W, Z, n, m, p and q are as defined in the claims.

Perfluoronaphthyl substituted boron containing catalyst activator

A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 100 non-hydrogen atoms.

Process

Process for the preparation of n-iodoamides

Tripodal cyclopentadiene derivatives and their use

Perfluoronaphthyl substituted boron containing catalyst activator

A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 100 non-hydrogen atoms.

Substituted phenylthiotrifluoride and other similar fluorinating agents

FIELD: chemistry. SUBSTANCE: described is a compound of formula (I): , in which R 1a and R 1b independently denote a hydrogen atom; a primary or secondary alkyl group containing 1-8 carbon atoms; or a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; and R 2a , R 2b independently denote a hydrogen atom; a halogen atom; a primary, secondary or tertiary alkyl group containing 1-8 carbon atoms; or a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; and R 3 denotes a hydrogen atom; a primary, secondary or tertiary alkyl group containing 1-8 carbon atoms; or a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; where, if R 3 denotes a hydrogen atom, then at least two of R 1a , R 1b , R 2a and R 2b each independently denotes a primary, secondary or tertiary alkyl group containing 1-8 carbon atoms, where R 1a and R 1b do not denote a tertiary alkyl group; or a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; or at least one of R 1a , R 1b , R 2a and R 2b denotes a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; and where, if R 3 denotes a primary alkyl group containing 1-8 carbon atoms, then at least one of R 1a , R 1a , R 2a and R 2b denotes a primary, secondary or tertiary alkyl group containing 1-8 carbon atoms, where R 1a and R 1b does not denote a tertiary alkyl group; or a primary, secondary or tertiary alkyl group containing 2-8 carbon atoms and at least one ether bond; and where, if at least two of R 2a , R 2b and R 3 denote tertiary alkyl groups, then the tertiary alkyl groups are adjacent. Described also is a method of introducing one or more fluorine atoms into a desired compound, which involves bringing the fluorinating agent of formula (I) into contact with the desired compound under conditions which enable ...

Method for producing fluorinated hydrocarbon

본 발명은, 하기 구조식 (1) 로 나타내는 2 급 또는 3 급의 에테르 화합물과, 구조식 (2) 로 나타내는 산플루오라이드를, 탄화수소계 용매 중, 삼불화붕소 착물 존재하에 접촉시키는 것을 특징으로 하는, 구조식 (3) 으로 나타내는 불소화 탄화수소를 제조하는 방법이다 (구조식 (1) ∼ (3) 중, R 1 과 R 2 는 탄소수 1 ∼ 3 의 알킬기를 나타내고, R 1 과 R 2 는 결합하여 고리 구조를 형성해도 된다. R 3 은 수소 원자, 메틸기 또는 에틸기를 나타내고, R 4 , R 5 는 메틸기 또는 에틸기를 나타낸다.). The present invention is characterized in that a secondary or tertiary ether compound represented by the following structural formula (1) is brought into contact with an acid fluoride represented by the structural formula (2) in a hydrocarbon solvent in the presence of a boron trifluoride complex, A method for producing a fluorinated hydrocarbon represented by Structural Formula (3) (in Structural Formulas (1) to (3), R 1 and R 2 represent an alkyl group having 1 to 3 carbon atoms, and R 1 and R 2 are bonded to form a ring structure. R 3 represents a hydrogen atom, a methyl group or an ethyl group, and R 4 , R 5 represents a methyl group or an ethyl group).

Fluorobenzene derivatives and liquid-crystalline medium.

본 발명은 액정 매질의 성분으로서 적합한 하기 화학식 I의 화합물에 관한 것이다: The present invention relates to compounds of formula (I) which are suitable as components of the liquid crystal medium: 화학식 I Formula I 상기식에서, In the above formula, R 은 H, C 1 내지 C 15 의 알킬 또는 알케닐 라디칼(이 라디칼들은 치환되지 않거나, 또는 CN 또는 CF 3 에 의해 일치환되거나 할로겐에 의해 적어도 일치환되며; 이 라디칼들중의 하나 이상의 CH 2 그룹들은 또한, 각각의 경우에 서로 독립적으로, O 원자가 서로 직접 결합되지 않도록 하는 방법으로 -O-, -S-, , -CO-, -CO-O-, -O-CO- 또는 -O-CO-O- 에 의해 치환될 수 있다)이고, R is H, C 1 to C 15 alkyl or alkenyl radicals (the radicals are unsubstituted or monosubstituted by CN or CF 3 or at least monosubstituted by halogen; at least one CH 2 of these radicals The groups are also, in each case independent of each other, in such a way that the O atoms are not bonded directly to each other. , -CO-, -CO-O-, -O-CO- or -O-CO-O- may be substituted) A 1 및 A 2 는 각각의 경우에 서로 독립적으로 A 1 and A 2 in each case independently of each other (a) 트랜스-1,4-사이클로헥실렌 라디칼(여기서, 하나이상의 인접하지 않은 CH 2 그룹들은 또한 -O- 및/또는 -S- 에 의해 치환될 수 있다), (a) a trans-1,4-cyclohexylene radical, wherein one or more non-contiguous CH 2 groups may also be substituted by -O- and / or -S-, (b) 1,4-페닐렌 라디칼 (여기서, 1 또는 2 개의 CH 그룹들은 또한 N 에 의해 치환될 수 있다), (b) 1,4-phenylene radicals, wherein one or two CH groups may also be substituted by N, (c) 1,4-사이클로헥세닐렌, 1,4-비사이클로[2.2.2]옥틸렌, 피페리딘-1,4-디일, 나프탈렌-2,6-디일, 데카하이드로나프탈렌-2,6-디일 및 1,2,3,4-테트라하이드로나프탈렌-2,6-디일로 이루어진 그룹중에서 선택된 라디칼(여기서, 라디칼(a) 및 (b)는 CN 또는 불소에 의해 치환될 수 있다)이며, (c) 1,4-cyclohexenylene, 1,4-bicyclo [2.2.2] octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2, Radicals selected from the group consisting of 6-diyl and 1,2,3,4-tetrahydronaphthalene-2,6-diyl, wherein the radicals (a) and (b) may be substituted by CN or fluorine) , Z 1 및 Z 2 는 각각의 경우에 서로 독립적으로, -CO-O-, -O-CO-, -CH 2 O-, -OCH 2 -, -CH 2 CH 2 -, -CH=CH-, -C=C- 또는 단일결합이고, 라디칼 Z 1 과 Z 2 중 어느 하나는 또한 -(CH 2 ) 4 - 또는 -CH=CH-CH 2 CH 2 - 이며, Z 1 and Z 2 in each occurrence independently of one another are -CO-O-, -O-CO-, -CH 2 O-, ...

Method of extraction of hydrogen fluoride

FIELD: inorganic chemistry, chemical technology. SUBSTANCE: invention relates to method of separation of hydrogen fluoride from gaseous organic compounds and extraction of separated hydrogen fluoride from a mixture. Method involves treatment of gaseous mixture with alkaline metal fluoride solution in hydrogen fluoride, separation of gaseous phase depleted by hydrogen fluoride and comprising organic compound from liquid phase enriched with hydrogen fluoride and the following extraction of hydrogen fluoride from liquid phase. Invention ensures to extract hydrogen fluoride from mixture comprising small amount of hydrogen fluoride and extract hydrogen fluoride from mixture where organic compound and hydrogen fluoride form azeotropic or close to azeotropic mixture. EFFECT: improved method of extraction and separation. 20 cl, 1 dwg д обу6бгс пы сэ (19) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ ВИ” 2194 007‘ (51) МПК? 13) С2 С О1В 7/19, С 07С 17/20 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 99123531/12, 06.04.1998 (24) Дата начала действия патента: 06.04.1998 (30) Приоритет: 09.04.1997 СВ 9707176.5 (46) Дата публикации: 10.12.2002 (56) Ссылки: МО 94/20412 А, 15.09.1994. ЗЦ 189409 А, 12.10.1966. $Ц 3968171 А, 29.01.1974. $4 380629 А, 03.08.1973. КЦ 2022914 СЛ, 15.11.1994. КЦ 94019408 А1, 10.01.1996. ЕР 596514 А, 11.05.1994. \МО 9516654 А, 19.10.1995. СВ 1332968 АЛ, 10.10.1973. 4$ 5362469 А, 08.11.1994. ЕК 2675496 АЛ, 23.10.1992. ЕР 612709 АЛ, 31.08.1994. (85) Дата перевода заявки РСТ на национальную фазу: 09.11.1999 (86) Заявка РСТ: СВ 98/01016 (06.04.1998) (87) Публикация РСТ: М/О 98/45209 (15.10.1998) (98) Адрес для переписки: 103735, Москва, ул. Ильинка 5/2, "Союзпатент", Высоцкой Н.Н. (71) Заявитель: ИНЕОС ФЛУОР ХОЛДИНГЗ ЛИМИТЕД (СВ) (72) Изобретатель: ЭВИНГ Пол Николас (СВ), ЛОУ Роберт Эллиотг (СВ), ШИЛДЗ Чарльз Джон (СВ) (73) Патентообладатель: ИНЕОС ФЛУОР ХОЛДИНГЗ ЛИМИТЕД (СВ) (74) Патентный поверенный: Фомичева Тамара ...

Method for producing fluorinated hydrocarbon

本发明为制造由结构式(3)表示的氟化烃的方法，其特征在于，在烃系溶剂中、在三氟化硼配位化合物存在下使由下述结构式(1)表示的仲醚化合物或叔醚化合物与由结构式(2)表示的酰氟接触(结构式(1)～(3)中，R 1 和R 2 表示碳原子数为1～3的烷基，R 1 和R 2 可键合而形成环结构。R 3 表示氢原子、甲基或乙基，R 4 、R 5 表示甲基或乙基。)。

A kind of method of new synthesis Cyclopropyl Bromide

本发明提供一种新的合成环丙基溴的方法，在保护剂的保护下，按一定比例加入溴化物、氨基环丙烷、酸性物质，控制好适宜的温度，再流加配制好的催化剂溶液，在酸性物和催化剂作用下，使溴化物与氨基环丙烷进行取代反应而得到环丙基溴，最后经过分层、水洗、减压蒸馏和精馏而得到纯度较高的环丙基溴产品。本发明原料易得，操作简单，产品产率较高，总收率达80%以上，纯度较高，达98%以上，成本较低，环境友好，能够避免使用氯化亚砜、氧化汞、溴素等有害化学品，具有安全性高，利于工业化大规模生产等优点。

Catalyst Promoter

1. Способ получения фториодалкана формулы: ! CF3(CF2)n-I, ! в которой n равен 0 или 1; причем способ включает контактирование: ! (i) соединения формулы ! CF3(CF2)n-Y, ! в которой Y выбирают из группы, состоящей из: Н, Cl, Br и COOH; ! где n равен 0 или 1; ! (ii) источника йода; ! (iii) катализатора, содержащего соль щелочного или щелочноземельного металла, нанесенную на носитель; и ! (iv) промотора катализатора - соли щелочного или щелочноземельного металла при температуре и в течение времени, достаточного для получения фториодалкана; ! где промотор катализатора включает по меньшей мере один элемент, выбранный из группы, состоящей из переходного металла, редкоземельного металла, элемента главной группы, отличного от щелочного или щелочноземельного элементов, любых их солей и любых их комбинаций. ! 2. Способ по п.1, в котором реакцию проводят в присутствии кислорода. ! 3. Способ по п.1, в котором реакцию проводят в отсутствие кислорода. ! 4. Способ по п.1, в котором носитель является углеродным носителем. ! 5. Способ по п.1, в котором носитель является неуглеродным носителем. ! 6. Способ по п.1, в котором катализатор является солью щелочного металла, причем щелочной металл выбирают из группы, состоящей из Li, Na, K, Rb, Cs, Fr и их комбинаций. ! 7. Способ по п.6, в котором щелочной металл представляет собой K. ! 8. Способ по п.1, в котором катализатор является солью щелочноземельного металла, который выбирают из группы, состоящей из Be, Mg, Ca, Sr, Ba, Ra и их комбинаций. ! 9. Способ по п.1, в котором щелочноземельный металл представляет собой Mg. ! 10. Способ по п.1, в котором промотор катализатора на основе соли щелочного или щелочноземельного металла является переходным металлом, выбранным из групп� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2007 138 259 (13) A (51) МПК C07C 1/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21), (22) Заявка: 2007138259/04, 16.10.2007 (71) Заявитель(и): Ханивелл ...

Fluorene compound, organic light emitting device and display device using the fluorene compound

An organic light emitting device having a high efficiency and durability is provided. The organic light emitting device includes an anode, a cathode and a layer formed of an organic compound interposed between the anode and the cathode, and contains at least one kind of the fluorene compound represented by the following general formula (I) or (II): wherein R 1 to R 4 each represent an alkyl group, a fluorinated alkyl group, a substituted or unsubstituted aralkyl group, or a substituted or unsubstituted aryl group; and Ar 1 to Ar 8 represent a substituted or unsubstituted aryl group or a substituted or unsubstituted polycondensed aromatic group.

Fluoridated compounds for fluoropolymers

FIELD: chemistry. SUBSTANCE: invention relates to a partially fluorinated compound I (CF 2 ) x CH=CH 2 , where x is 3, as well as the method for its preparation, comprising the reaction of a compound of the formula I (CF 2 ) x I with ethylene to produce a compound of the formula I (CF 2 ) x CH 2 CH 2 I and the dehydroiodination thereof to obtain the claimed compound (the value of x in these formulas is 3). The invention relates to a fluoropolymer for vulcanization comprising a polymerized reaction product of: (a) a partially fluorinated compound and (b) a fluorinated olefin monomer; to a rubber product for sealing moulded from a vulcanized fluoropolymer; to a process for producing a fluoropolymer, comprising: (a) providing a partially fluorinated compound, a fluorinated olefin monomer, and an initiator; and (b) polymerizing a partially fluorinated compound and a fluorinated olefin monomer to produce a fluoropolymer. EFFECT: good physical properties, vulcanization properties and curing time, long-term stability. 13 cl, 2 tbl, 4 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 645 156 C2 (51) МПК C07C 17/25 (2006.01) C07C 17/275 (2006.01) C08F 214/22 (2006.01) C07C 19/16 (2006.01) C07C 21/17 (2006.01) C07C 21/18 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C08F 214/18 (2006.01); C07C 17/093 (2006.01); C07C 17/25 (2006.01); C07C 17/275 (2006.01); C07C 19/16 (2006.01); C07C 21/18 (2006.01) (21)(22) Заявка: 2015114338, 10.10.2013 10.10.2013 Дата регистрации: 16.02.2018 (56) Список документов, цитированных в отчете о поиске: EP 1262497 A2, 04.12.2002 . WO 18.10.2012 US 61/715,413 (43) Дата публикации заявки: 10.12.2016 Бюл. № 34 (45) Опубликовано: 16.02.2018 Бюл. № 5 (86) Заявка PCT: US 2013/064249 (10.10.2013) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 18.05.2015 2012/082703 A2, 21.06.2012. WO 2012/083107 A2 , 21.06.2012. SLOAN JOHN P et al., Free radical addition to olefins. XVI. ...

Polymerizable compound, polymerizable resin composition, cured polymer and liquid crystal display device

본 발명의 중합성 화합물은 하기 화학식(101)으로 표시된다: The polymerizable compound of the present invention is represented by the following general formula (101): (101) (101) 식중에서, R은 H, R', R'O, R'COO 또는 R'OCO이고; R'은 1 내지 15개 탄소 원자를 갖는 직쇄 또는 측쇄의 알킬 기 또는 알케닐기이며; A 1 및 A 2 는 독립해서 하기 화학식(102)로 표시되는 치환기를 포함할 수 있는 시클로헥산 고리 또는 벤젠 고리이며; X는 H 또는 CH 3 이고; 또 Y 1 , Y 2 , Y 3 및 Y 4 가 독립해서 H, F, Cl, CH 3 , CH 3 O, CF 3 또는 CF 3 O이며, 이때 Y 1 , Y 2 , Y 3 및 Y 4 의 2개 이상은 H이고, 또 A 1 및 A 2 가 모두 시클로헥산 고리이면, Y 1 , Y 2 , Y 3 및 Y 4 의 한 개 이상이 H가 아니며; Wherein R is H, R ', R'O, R'COO or R'OCO; R 'is a straight or branched alkyl or alkenyl group having 1 to 15 carbon atoms; A 1 and A 2 are independently a cyclohexane ring or a benzene ring which may include a substituent represented by the following general formula (102); X is H or CH 3 ; And Y 1 , Y 2 , Y 3 and Y 4 are independently H, F, Cl, CH 3 , CH 3 O, CF 3 or CF 3 O, wherein Y 1 , Y 2 , Y 3 and Y 4 are At least one is H and if A 1 and A 2 are both cyclohexane rings, then at least one of Y 1 , Y 2 , Y 3 and Y 4 is not H; (102) (102) 식중에서, Y 5 , Y 6 , Y 7 및 Y 8 은 독립해서 H, F, Cl, CH 3 , CH 3 O, CF 3 또는 CF 3 O이고, Y 5 , Y 6 , Y 7 및 Y 8 의 2개 이상은 H임. Wherein Y 5 , Y 6 , Y 7 and Y 8 are independently H, F, Cl, CH 3 , CH 3 O, CF 3 or CF 3 O, and Y 5 , Y 6 , Y 7 and Y 8 Two or more are H.

Method

本发明提供了一种用于生产氯化烷烃的方法，其中使烯烃或烷烃原料与氯在氯化区中接触以产生含有所述氯化烷烃的反应混合物，其中所述供应到所述氯化区中的氯具有少于约2000ppmv的氧含量并且其中：所述氯化区对于大气是封闭的；和/或所述氯化区是在大气压或高于大气压的压力下操作的；和/或所述氯化区是在惰性气氛下操作的；和/或所述烯烃或烷烃原料中溶解氧的含量少于2000ppm。

Process for the synthesis of 1-aryl-1-trifluoromethylcyclopropanes

The present invention relates to a process for the manufacturing of 1-aryl-1-trifluoromethylcyclopropanes, which serve as intermediates for the manufacturing of calcium T channel blockers of the general formula (A) which are described in WO 2015/186056.

4-Phenyl-pyrane-3,5-diones, 4-phenyl-thiopyrane-3,5-diones and cyclohexanetriones as novel herbicides

본 발명은 제초제로서 사용하기에 적합한 피란디온, 티오피란디온 및 사이클로헥산트리온 화합물에 관한 것이다. The present invention relates to pyrandione, thiopyran dione and cyclohexanthrone compounds suitable for use as herbicides. 피란디온, 티오피란디온, 사이클로헥산트리온, 제초제, 약해경감제 Pyrandione, thiopyran dione, cyclohexanetrione, herbicide, weak relief agent

The method of producing alpha, omega-diiodoperfluoroalkanes

1. Способ получения α,ω-дийодоперфторалканов включает объединение компонентов, включающих:(i) двухатомный йод;(ii) оксид перфторалкилена, представленный формулой,где Rпредставляет перфторалкильную группу; и(iii) по крайней мере, одно из:a) первое металлическое соединение, включающее никель; и второе металлическое соединение, включающее молибден, который композиционно отличается от первого металлического соединения; илиb) металлический сплав, включающий от 50 до 70 % по массе никеля и от 20 до 40 % по массе молибдена, на основе общей массы металлического сплава,таким образом, производя, по крайней мере, один продукт, представленный формулойI(CF)I,где n независимо представляет целое число в диапазоне от 1 до 11, и где на основе веса, общая масса, по крайней мере, одного продукта, где n равняется 3, или больше превышает общую массу, по крайней мере, одного продукта, где n равняется 1 или 2 на фактор 4, как минимум.2. Способ по п. 1, где компонент iii) включает и первое металлическое соединение, и второе металлическое соединение.3. Способ по п. 1, где первое металлическое соединение включает порошок.4. Способ по п. 1, где второе металлическое соединение далее включает никель, и где весовое соотношение молибдена к никелю во втором металлическом соединении, по крайней мере, 0,28.5. Способ по п. 1, где второе металлическое соединение дополнительно включает никель, и где весовое соотношение молибдена к никелю во втором металлическом соединении, по крайней мере, 0,4.6. Способ по п. 1, где молибден включает, по крайней мере, 16 % по массе второго металлического соединения.7. Способ по п. 1, где способ применяется в химическом реакторе, имеющем внутреннюю поверхность, контактирующую с компонентами, и где, по крайней мере, часть внутренней РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2015 113 941 A (51) МПК C07C 17/26 (2006.01) C07C 19/16 (2006.01) C07C 17/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2015113941, 09.10. ...

Process for the preparation of aromatic fluorine compounds

Continuous method of obtaining chlorfluormethanes or chlor fluorethanes

A continuous process for fluorinating haloalkanes containing at least one nonfluorine halogen atom wherein antimony pentachloride is reacted (A) with HF to produce an antimony chlorofluoride. The antimony chlorofluoride thus produced is then transferred to a separate reaction zone (C) where it is reacted with the haloalkane, thereby replacing a portion of the nonfluorine halogen in the haloalkane with fluorine of the antimony chlorofluoride.

Process for preparing aromatic compound substituted ring with nucleophillic group

Fluoroiodo compounds for fluoropolymers

本文描述了一种组合物，所述组合物包含选自以下物质的部分氟化化合物：I(CF 2 ) x CH＝CH 2 (式III)；和I(CF 2 )XCH 2 CH 2 I(式II)，其中x为选自3至11的奇数。

Reactor and agitator useful in process for making 1-chloro-3,3,3-trifluoropropene

本发明公开了用于制备1-氯-3，3，3-三氟丙烯(1233zd)的高压方法的反应器和搅拌器，所述1-氯-3，3，3-三氟丙烯由1，1，1，3，3-五氯丙烷(240fa)与HF的反应获得，其中所述搅拌器包括一种或多种以下设计改进：(a)带有惰性隔离液的双机械密封件或单密封件；(b)所述密封件的旋转面上的陶瓷；(c)所述密封件的静止面上的陶瓷；(d)由弹性蓄能Teflon构造的接液O型圈和PTFE楔形或动态O型圈设计；和(e)由耐腐蚀合金构造的搅拌器的接液金属表面。

Method for producing perfluoroalkyliodes

FIELD: chemistry.SUBSTANCE: invention relates to a method for producing perfluoroalkyl iodides, including the interaction of trimethylsilyl esters of perfluorocarboxylic acids with potassium fluoride when heated in a polar aprotic solvent such as acetonitrile, with simultaneous distillation of trimethylfluorosilane and the solvent and subsequent treatment of the bottom residue with polar iodine or aprotol dimethylformamide, in the presence of copper halide in an amount of 15-20 mole percent.EFFECT: technological method for producing perfluoroalkyl iodides under mild conditions from available raw materials that do not require special preliminary preparation.1 cl, 7 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 748 928 C1 (51) МПК C07C 19/16 (2006.01) C07C 17/093 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C07C 17/093 (2021.02) (21)(22) Заявка: 2020132848, 06.10.2020 (24) Дата начала отсчета срока действия патента: 01.06.2021 Приоритет(ы): (22) Дата подачи заявки: 06.10.2020 (45) Опубликовано: 01.06.2021 Бюл. № 16 (54) СПОСОБ ПОЛУЧЕНИЯ ПЕРФТОРАЛКИЛЙОДИДОВ (57) Реферат: Изобретение относится к способу получения полярном апротонном растворителе, таком как перфторалкилйодидов, включающему сульфолан или диметилформамид, в присутствии взаимодействие триметилсилиловых эфиров галогенида меди в количестве 15-20 мольных перфторкарбоновых кислот с фтористым калием процентов. Технический результат изобретения при нагревании в полярном апротонном технологичный способ получения растворителе, таком как ацетонитрил, с перфторалкилйодидов в мягких условиях из одновременной отгонкой триметилфторсилана доступного сырья, не требующего специальной и растворителя и последующую обработку предварительной подготовки. 1 з.п. ф-лы, 7 пр. кубового остатка йодом при нагревании в R U 2 7 4 8 9 2 8 (56) Список документов, цитированных в отчете о поиске: RU 2359953 C1, 27.06.2009. US 4067916 A1, 10.01.1978. SU 458124 A3, 25.01.1975. Стр ...

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) methods of using such phosphacycle ligands in bond forming reactions; and (c) methods of preparing phosphacycle ligands.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions.

Liponucleotide-containing liposomes

Compounds are disclosed for treating AIDS, herpes, and other viral infections by means of lipid derivatives of antiviral agents. The compounds consist of nucleoside analogues having antiviral activity which are linked, commonly through a phosphate group at the 5' position of the pentose residue, to one of a selected group of lipids. The lipophilic nature of these compounds provide advantages over the use of the nucleoside analogue alone. It also makes it possible to incorporate them into the lamellar structure of liposomes, either alone or combined with similar molecules. In the form of liposomes, these antiviral agents are preferentially taken up by macrophages and monocytes, cells which have been found to harbor the target HIV virus. Additional site specificity may be incorporated into the liposomes with the addition of ligands, such as monoclonal antibodies or other peptides or proteins which bind to viral proteins. Effective nucleoside analogues are dideoxynucleosides, azidothymine (AZT), and acyclovir; lipid groups may be glycolipids, sphingolipids, phospholipids or fatty acids. The compounds persist, after intracellular hydrolysis, as phosphorylated or non-phosphorylated antiviral nucleosides. The compounds are effective in improving the efficacy of antiviral nucleoside analogues by prolonging the antiviral activity after the administration of the drug has ended, and in preventing retroviral replication in HIV infections which have become resistant to therapy with conventional forms of the antiretroviral agents.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) catalyst compositions comprising phosphacycle ligands; and (c) methods of using such phosphacycle ligands and catalyst compositions in bond forming reactions.

Phosphine ligands for catalytic reactions

The disclosure is directed to: (a) phosphacycle ligands; (b) methods of using such phosphacycle ligands in bond forming reactions; and (c) methods of preparing phosphacycle ligands.

Process for the production of halogenated, aliphatic compounds from compounds with polymethylene oxide rings

Process for the preparation of 1,4-dichloro- or 1,4-dibromobutane

Fluorine-containing 1-aryl alkoxytris(dialkyl amino)phosphonium salts, and process for their preparation and their use

4-phenyl-pyrane-3,5-diones,4-phenyl-thiopyrane-3,6-diones and cyclohexanetriones as novel herbicides

Pyrandione, thiopyrandione and cyclohexanetrione compounds, which are suitable for use as herbicides.

Novel Herbicides

Method for pretreating and regenerating catalysts used in a process for making fluoroiodoalkanes

本发明涉及用于氟碘代烷制备工艺的催化剂的预处理和再生的方法。一种由结构式CF 3 (CF 2 ) n －I表示的氟碘代烷烃的制备方法，其中n为0或1。该方法包括了将碘源与由结构式CF 3 (CF 2 ) n －Y表示的化合物进行反应的步骤，其中Y选自H、Cl、Br和COOH，且其中n是0或1。该反应在温度为约100℃到约750℃，压力为约0.001到约100atm，接触时间为约0.001秒到约300小时的条件下，并且在催化剂存在下进行。将催化剂进行下列之一或者两者的处理：a)在反应前，通过与选自氟化氢、三氟甲烷、氢、碘化氢、碘、氟和氧的气体接触，对催化剂进行处理，其中所述接触在足以缩短催化剂的诱导期长度的温度和接触时间下进行；和b)在反应后，通过与选自氟化氢、氢、氟、氧或者空气的气体接触，在足以再生该催化剂的温度和接触时间下对催化剂进行处理。

Method for manufacturing methyl fluoride

An object of the present invention is to provide a method which is more suitable for industrial production as a process for producing methane fluoride useful as a dry etching gas or the like. (CH 3 F) is produced by reacting at least one member selected from the group consisting of (A) dimethylsulfuric acid and (B) a fluorine compound, hydrogen fluoride and a fluoride salt, or a fluoride metal salt in a liquid phase, (B) is hydrogen fluoride or a fluoric acid salt, or a polar solvent is used as a solvent, and when the fluorine compound (B) is a fluoride metal salt, water as a solvent In the presence of a catalyst.

Method for producing 3-chloro-pentafluoropropene

本发明的目的在于提供通过全氟烯丙基氟代硫酸酯的氯化来利用1个工序的反应收率良好地制造3-氯-五氟丙烯的方法。本发明的3-氯-五氟丙烯的制造方法的特征在于，其包括使全氟烯丙基氟代硫酸酯与氯化鎓化合物接触来得到3-氯-五氟丙烯的工序。

Method for manufacturing methyl fluoride

본 발명은, 드라이 에칭 가스 등으로서 유용한 불화메탄의 제조 방법으로서, 공업적 생산에 보다 적합한 방법을 제공하는 것을 과제로 한다. 그 해결 수단으로서, (A) 디메틸황산과 (B) 불소화합물로서, 불화수소 및 불산염으로 이루어지는 군으로부터 선택되는 적어도 1종, 또는 불화물 금속염을 액상으로 반응시킴으로써 불화메탄(CH 3 F)을 제조하는 방법으로서 : 상기 불소화합물(B)이 불화수소 또는 불산염을 포함하는 경우에 무용매로, 또는 용매로서 극성 용매를 이용하고, 또한 상기 불소화합물(B)이 불화물 금속염인 경우에 용매로서 물을 이용하여 반응시키는 것을 특징으로 하는 방법을 제공한다.

Patent SU421194A3

Synthesis method of tetrabromo-neopentane

本发明公开了一种四溴新戊烷的合成方法，其特征在于：以季戊四醇或二溴新戊二醇或三溴新戊醇为原料，先与甲基磺酰氯或对甲基苯磺酰氯反应进行羟基活化，然后以二甘醇或聚乙二醇为溶剂，聚乙二醇为催化剂，与溴化钠进行取代反应得到四溴新戊烷；或，以二溴新戊二醇或三溴新戊醇为原料，先与对甲基苯磺酰氯反应进行羟基活化，然后以二甘醇为溶剂，与溴化钠进行取代反应得到四溴新戊烷。整个过程避免水汽产生，容易控制温度，环保，收率高，产品纯度好。