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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3041. Отображено 100.
24-05-2012 дата публикации

Crosslinked Flame Retardant Thermoplastic Elastomer Gels

Номер: US20120129962A1
Автор: Mark W. Ellsworth, Michael A. Oar, Miguel A. Morales
Принадлежит: Tyco Electronics Corp

Crosslinked flame retardant thermoplastic elastomer gels are provided. The crosslinked flame retardant thermoplastic elastomer gels comprise a char catalyst, a char former, a maleic anhydride-modified styrene ethylene/butylene styrene polymer, and a softener oil. Methods are provided of making crosslinked flame retardant thermoplastic elastomer gels.

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Номер записи: 1
15-08-2013 дата публикации

Styrene resin composition, and molded article thereof

Номер: US20130209742A1
Автор: Junpei Fujiwara, Masatoshi Kawata
Принадлежит: Denki Kagaku Kogyo KK

Provided are a styrene resin composition for use in electronic component packaging such as embossed carrier tape, a sheet which has a large drawing ratio (pocket depth) and in which pockets exhibiting superior transparency and strength and can be thermoformed, and a carrier tape which is thermoformed from the sheet and which allows the verification of letters and the like formed on packaged electronic components from outside the pockets. The electronic component packaging sheet includes: (A) 29-65 mass parts of a styrene-conjugated diene block copolymer; (B) 51-15 mass parts of a polystyrene resin; and (C) 20-9 mass parts of an impact resistant polystyrene resin. Components (A)-(C) each have a weight average molecular weight within a specified range.

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Номер записи: 2
10-04-2014 дата публикации

Epoxy resin composition, prepreg and fiber-reinforced composite material

Номер: US20140100320A1
Автор: Maki Nagano, Nobuyuki Tomioka, Shiro Honda, Takayuki Imaoka
Принадлежит: TORAY INDUSTRIES INC

An epoxy resin composition comprising an epoxy resin [A], an amine-based curing agent [B] and a block copolymer [C] as components, wherein the epoxy resin [A] contains [Aa] an epoxy resin having at least one structure selected from a condensed polycyclic structure, biphenyl structure and oxazolidone ring structure; [Ab] an epoxy resin selected from a polyfunctional amine type epoxy resin [Ab1] and a liquid bisphenol type epoxy resin [Ab2], and the block copolymer [C] is at least one block copolymer selected from the group consisting of S-B-M, B-M and M-B-M. The present invention provides an epoxy resin composition that can be cured to form a cured product excellent in heat resistance, elastic modulus and toughness.

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Номер записи: 3
01-01-2015 дата публикации

POLYPROPYLENE-BASED RESIN COMPOSITION AND FOAM SHEET

Номер: US20150004394A1
Автор: Asuka Kazuo, Hotta Sachio, Kitade Shinichi, Kouzai Iku, Takahashi Kuninori, Tayano Takao
Принадлежит: Japan Polypropylene Corporation

Provided is a polypropylene-based resin composition which gives uniform and fine cells and from which a foamed sheet and thermoform excellent in appearance, thermoformability, impact resistance, lightness, stiffness, heat resistance, heat insulating properties, oil resistance and the like can be produced. A polypropylene-based resin composition comprising (X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which block copolymer comprises (Y-1) a propylene (co)polymer and (Y-2) a propylene-ethylene copolymer, said resin (X) having properties (X-i) to (X-iv) and said block copolymer (Y) having properties (Y-i) to (Y-v), and the like. 1: A polypropylene-based resin composition comprising:(X) 5 to 99% by weight of a polypropylene resin comprising a structure with long chain branches, and (Y-1) a propylene (co)polymer, and', '(Y-2) a propylene-ethylene copolymer, and wherein said resin (X) has:, '(Y) 1 to 95% by weight of a sequentially polymerized propylene-based block copolymer wherein said resin (Y) comprises(X-i): a melt flow rate (MFR) of 0.1 to 30.0 g/10 minutes,(X-ii): a molecular weight distribution Mw/Mn of 3.0 to 10.0 measured by GPC and Mz/Mw of 2.5 to 10.0, [{'br': None, 'log(MT)≧−0.9×log(MFR)+0.7, or'}, {'br': None, 'MT≧15,'}], '(X-iii): a melt tension (MT) (unit: g) where'}(X-iv): a content of p-xylene soluble components (CXS) at 25° C. of less than 5% by weight based on the total amount of said resin (X), and whereinsaid block copolymer (Y) has:(Y-i): a weight ratio of 50 to 99% of (Y-1) and 1 to 50% of (Y-2) where said ratio is calculated based on the total weight of said block copolymer (Y) regarded as 100% by weight, and(Y-ii): an MFR of said block copolymer (Y) of 0.1 to 200.0 g/10 minutes,(Y-iii): a melting point of said block copolymer (Y) of more than 155° C.,(Y-iv): an ethylene content of said (Y-2) of 11.0 ...

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Номер записи: 4
07-01-2021 дата публикации

COMPLIANT SOLID-STATE IONICALLY CONDUCTIVE COMPOSITE MATERIALS AND METHOD FOR MAKING SAME

Номер: US20210005889A1
Автор: Burdynska Joanna, Nasybulin Eduard, Rupert Benjamin, Teran Alexander, Uppal Simmi Kaur, Venugopal Saranya
Принадлежит:

Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions. 180.-. (canceled)81. A solid-state electrode for use in an alkali ion or alkali metal battery , comprising an inorganic phase comprising an ionically conductive inorganic material , an electrochemically active material , and an electronically conductive additive; andan organic phase comprising a first component and a binder, wherein the first component is a non-ionically conductive polymer having a number average molecular weight of between 500 g/mol and 50,000 g/mol and the binder is a non-ion conducting polymer having a number average molecular weight of at least 100 kg/mol.82. The solid-state electrode of claim 81 , wherein the ionically conductive inorganic material constitutes between 15% and 60% by weight of the inorganic phase claim 81 , the electrochemically active material constitutes between 30% and 80% by weight of the inorganic phase claim 81 , and the electronically conductive additive constitutes between 5% and 25% of the inorganic phase.83. The solid-state electrode of claim 81 , wherein the first component constitutes between 50% and 99% by weight of the organic phase claim 81 ...

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Номер записи: 5
09-01-2020 дата публикации

Method for producing polymer latex

Номер: US20200010651A1
Автор: Junji Kodemura, Shunjin Aihara, Yoshitaka Satoh
Принадлежит: Zeon Corp

A method for producing a polymer latex, includes a step of emulsifying a polymer solution of a synthetic polyisoprene and/or a styrene-isoprene-styrene block copolymer, in water in the presence of a rosin and/or a rosin metal salt, thereby obtaining an emulsified liquid, wherein the rosin and/or the rosin metal salt to be used have/has a total content rate of abietic acid, neoabietic acid and palustric acid, and salts thereof, of 5% by weight or less.

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Номер записи: 6
18-01-2018 дата публикации

Process for Reducing the Assembly Time of Ordered Films of Block Copolymer

Номер: US20180015645A1
Автор: Chevalier Xavier, Inoubli Raber, Navarro Christophe, Nicolet Celia
Принадлежит: Arkema France

The present invention relates to a process for reducing the assembly time comprising a block copolymer (BCP). The invention also relates to the compositions used to obtain these ordered films and to the resulting ordered films that can be used in particular as masks in the lithography field. 1. A process for reducing the assembly time of an ordered film of block copolymer , said ordered film comprising a mixture of at least one block copolymer having an order-disorder transition temperature (TODT) and at least one Tg with at least one compound not having a TODT , wherein said compound is selected from the group consisting of block-copolymers , light or heat stabilizers , photo-initiators , polymeric ionic compounds , non-polymeric compounds , homopolymers , and statistical copolymers , this mixture having a TODT below the TODT of the block copolymer alone , the process comprising the steps of:mixing at least one block copolymer having a TODT and at least one compound not having a TODT, in a solvent to form a mixture;depositing the mixture on a surface; andcuring the mixture deposited on the surface at a temperature between the highest Tg of the block copolymer and the TODT of the mixture.2. The process according to claim 1 , wherein the block copolymer having a TODT is a diblock copolymer.3. The process according to claim 2 , wherein one of the blocks of the diblock copolymer comprises a styrene monomer and the other block comprises a methacrylic monomer.4. The process according to claim 3 , wherein one of the blocks of the diblock copolymer comprises styrene and the other block comprises methyl methacrylate.5. The process according to claim 1 , wherein the block copolymer not having a TODT is a diblock copolymer.6. The process according to claim 5 , wherein one of the blocks of the diblock copolymer comprises a styrene monomer and the other block comprises a methacrylic monomer.7. The process according to claim 6 , wherein which one of the blocks of the diblock ...

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Номер записи: 7
17-01-2019 дата публикации

ASSEMBLY, METHOD FOR PRODUCING SAME, AND SHEET COMPRISING MODIFIED BLOCK COPOLYMER HYDRIDE

Номер: US20190016106A1
Автор: CHIBA Daido, Ishiguro Atsushi, KOHARA Teiji, Kurihara Ryuta
Принадлежит: ZEON CORPORATION

The present invention provides: an assembly obtained by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet, wherein a peel strength of the adherend surface is 4 N/cm or higher; a method for producing an assembly by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet, the method comprising steps of: (1) activating an adherend surface of the thermoplastic resin sheet with at least one selected from plasma exposure, excimer UV exposure and corona discharge; and (2) superposing the sheet made of the modified hydrogenated block copolymer having the alkoxysilyl group introduced therein with the adherend surface of the thermoplastic resin sheet to be subjected to thermally press-bonding; and a sheet made of a modified hydrogenated block copolymer, comprising at least one surface activated. 1. An assembly obtained by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet , whereina peel strength of the adherend surface is 4 N/cm or higher.2. A method for producing an assembly by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet , the method comprising steps of:(1) activating an adherend surface of the thermoplastic resin sheet with at least one selected from plasma exposure, excimer UV exposure and corona discharge; and(2) superposing the sheet made of the modified hydrogenated block copolymer having the alkoxysilyl group introduced therein with the adherend surface of the thermoplastic resin sheet to be subjected to thermally press-bonding.3. The method for producing the assembly according to claim 2 , whereinthe step (1) is a step of activating both surfaces of the adherend surface of the sheet made of the ...

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Номер записи: 8
22-01-2015 дата публикации

FOAMABLE COMPOSITIONS, FOAMS AND ARTICLES THEREOF

Номер: US20150025165A1
Автор: Chen Yong, Kummer Kyle G., Rego Jose M., Walton Kim L., Wang David
Принадлежит: Dow Global Technologies LLC

A foamable composition comprising at least an olefin block copolymer, an olefin copolymer, an oil, a blowing agent and a crosslinking agent is provided. The olefin block copolymer has a Mw/Mn from 1.7 to 3.5, and at least one melting point, Tm, in degrees Celsius, and a density, d, in gram/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm>−2002.9+4538.5(d)−2422.2(d). Foams, laminates, articles and wetsuits made from the foams are also provided. 1. A foamable composition comprising: {'br': None, 'i': Tm>−', 'd', 'd, 'sup': '2', '2002.9+4538.5()−2422.2();'}, 'a) one or more olefin block copolymers having a Mw/Mn from 1.7 to 3.5, and at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationshipb) one or more olefin copolymers;c) an oil;d) a crosslinking agent; and,e) a blowing agent.2. The foamable composition of wherein one or more of the olefin block copolymers is mesophase separated and has a delta comonomer of greater than 18.5 mol %.3. The foamable composition of wherein the olefin copolymer comprises ethylene-propylene-diene monomer rubber and/or an ethylene/α-olefin copolymer.4. The foamable composition of whereina) the olefin block copolymer is present in an amount of 5 wt % to 40 wt %, preferably 10 wt % to 30 wt %, more preferably 10 wt % to 25 wt %;b) the ethylene-propylene-diene-monomer rubber is present in an amount of 5 wt % to 40 wt %, preferably 5 wt % to 30 wt %;c) the mineral oil is present in an amount of 15 wt % to 45 wt %, preferably 20 wt % to 40 wt %, more preferably 25 wt % to 35 wt %;d) the crosslinking agent is present in an amount of 1-6 phr, preferably 2-5 phr;e) the blowing agent is present in an amount of 1-8 phr, preferably 2-6.5. A foam made from the foamable composition of .6. The foam of having a density of 0.05 g/cc to 0.2 g/cc claim 5 , a 60% modulus of 0.60 Kg/cmto 1.50 Kg/cm claim 5 ...

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Номер записи: 9
24-01-2019 дата публикации

COMPOSITION FOR PREPARING A FOAM, FOAM, AND SHOE EMPLOYING THE SAME

Номер: US20190023884A1
Автор: LIN Hsuan-Tsung, SHIH HSI-HSIN, TSAI Han-Ming, TU Ying-Pin
Принадлежит: TSRC CORPORATION

A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight. 1. A composition for preparing a foam , comprising:3-30 parts by weight of a first polymer, wherein the first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof; andat least one of a second polymer and a third polymer, wherein the total weight of the second polymer and the third polymer is 70-97 parts by weight, the second polymer is polyolefin, olefin copolymer, or a combination thereof, the third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof, and the total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.2. The composition for preparing a foam as claimed in claim 1 , wherein the cyclic olefin copolymer is a copolymer of a norbornene-based monomer and an olefin-based monomer.3. The composition for preparing a foam as claimed in claim 2 , wherein the norbornene-based monomer ...

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Номер записи: 10
02-02-2017 дата публикации

Hydrophilic porous polytetrafluoroethylene membrane (i)

Номер: US20170028363A1
Автор: Amarnauth Singh, Hassan Ait-Haddou, Khaled Abdel-Hakim Helmy Aamer, Marcin Stasiak
Принадлежит: Pall Corp

Disclosed are hydrophilic porous PTFE membranes comprising PTFE and an amphiphilic copolymer, for example, a copolymer of the formula: wherein m and n are as described herein. Also disclosed are a method of preparing hydrophilic porous PTFE membranes and a method of filtering fluids through such membranes.

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Номер записи: 11
17-02-2022 дата публикации

Foam Bead and Sintered Foam Structure

Номер: US20220049065A1
Автор: Van Dun Jozef J I, Yang Yunfeng, Yu Haiyang
Принадлежит:

The present disclosure provides a foam bead. The foam bead contains at least one of the following components: (A) a block composite; and/or (B) a crystalline block composite. The present disclosure also provides a sintered foam structure formed from a composition comprising at least one of the following components: (A) a block composite; and/or (B) a crystalline block composite. 1. A foam bead comprising at least one of the following components:(A) a block composite; and/or(B) a crystalline block composite.2. The foam bead of comprising (A) the block composite.3. The foam bead of comprising (B) the crystalline block composite.4. The foam bead of claim 1 , wherein the foam bead has a weight ratio of (A) the block composite and (B) the crystalline block composite of from 0.25:1.0 to 4.0:1.0.5. The foam bead of claim 1 , wherein the foam bead has two melting peaks.6. The foam bead of claim 1 , wherein the foam bead has a first melting peak (Tm1) and a second melting peak (Tm2) claim 1 , and the difference between Tm1and Tm2is greater than claim 1 , or equal to claim 1 , 20° C.7. A sintered foam structure formed from a composition comprising at least one of the following components:(A) a block composite; and/or(B) a crystalline block composite.8. The sintered foam structure of claim 7 , wherein the sintered foam structure has a foam density of less than 0.20 g/cc; and a linear shrinkage of less than claim 7 , or equal to claim 7 , 1.0%.9. The sintered foam structure of comprising (A) the block composite.10. The sintered foam structure of claim 7 , wherein the sintered foam structure has a Type C Tear from 4.5 N/mm to 15 N/mm; and an average stress at break greater than claim 7 , or equal to claim 7 , 0.50 MPa. The present disclosure relates to polyolefin foams, and further polypropylene-based polymer foams. Polyolefin foams are conventionally utilized in footwear components, such as midsole applications. Crosslinked ethylene-based polymers including ethylene vinyl ...

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Номер записи: 12
31-01-2019 дата публикации

Thermoplastic elastomer hydrogels

Номер: US20190031835A1
Автор: CHEN GUO, Dilanji Wijayasekara, Douglas L. Gin, Jackson T. LEWIS, Kristine FISCHENICH, Matthew G. Cowan, Richard D. Noble, Tammy Haut DONAHUE, Travis S. BAILEY
Принадлежит: COLORADO STATE UNIVERSITY RESEARCH FOUNDATION, University of Colorado

Provided herein is a block copolymer hydrogel, comprising a glass formed from a dry blend of polystyrene-poly(ethylene oxide) diblock copolymer (SO) and polystyrene-poly(ethylene oxide)-polystyrene triblock copolymer (SOS) in a molar ratio from between 95:5 and 1:99 SO/SOS and a liquid medium at a concentration between about 32:1 and about 2:1 liquid medium/SO—SOS by weight. The block copolymer hydrogel has a fatigue resistance to at least 500,000 compression cycles. Also provided are methods for forming the hydrogel.

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Номер записи: 13
01-02-2018 дата публикации

Compliant solid-state ionically conductive composite electrolytes and materials

Номер: US20180034096A1
Автор: Alexander Teran, Benjamin Rupert, Eduard Nasybulin, Joanna Burdynska, Saranya Venugopal, Simmi Kaur Uppal
Принадлежит: Blue Current Inc

Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions.

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Номер записи: 14
09-02-2017 дата публикации

Polylactide Based Compositions

Номер: US20170037242A1
Автор: Thierry Coupin
Принадлежит: Total Research and Technology Feluy SA

Embodiments of polylactide based compositions are disclosed herein. The compositions may comprise at least one first polymer selected from polylactide-polybutadiene (PLA-PB) block copolymer, polylactide-urethane-polybutadiene block copolymer, or a mixture thereof; and at least one second polymer selected from polylactide, polylactide-urethane, or a mixture thereof. The composition may also comprise from 20% to 50% by weight of said first polymer based on the total weight of the composition and from 50% to 80% by weight of said second polymer based on the total weight of the composition. Embodiments of the present invention also relate to a process for preparing the polylactide based compositions and articles comprising the polylactide compositions.

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Номер записи: 15
12-02-2015 дата публикации

Method for manufacturing foam-molded article, and foam-molded article

Номер: US20150045468A1
Автор: Masaaki Onodera
Принадлежит: Kyoraku Co Ltd

A foam-molded article has high weldability to a polypropylene-based resin molded article, a high expansion ratio, and a predetermined level of impact resistance despite using inexpensive polyethylene-based resin. The foam-molded article includes a foamed and molded base material resin in which a first polyethylene-based resin, a second polyethylene-based resin, and a polypropylene-based resin are mixed. The first polyethylene-based resin has a long-chain branched structure and a density of 0.920 g/cm 3 or more. The second polyethylene-based resin is manufactured by a low pressure slurry method, and has a long-chain branched structure and a density of 0.920 g/cm 3 or less. The second polyethylene-based resin has a melt tensile force of 70 mN or more at 160° C. The polypropylene-based resin has a compounding ratio of 20% or more by weight of the base material resin.

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Номер записи: 16
16-02-2017 дата публикации

FILM FOR LIQUID PACKAGING CONTAINERS AND LIQUID PACKAGING CONTAINER

Номер: US20170042766A1
Автор: Jogo Yosuke, Nojima Yusuke, Oshita Shinya, Tanaka Yusuke
Принадлежит: KURARAY CO., LTD.

A film for a liquid packaging container, comprising at least one of a layer containing a resin composition (X) containing a polypropylene resin (a) and at least one of a hydrogenated block copolymer (b), the hydrogenated block copolymer (b) being a hydrogenated product of a block copolymer containing a polymer block (A) mainly containing an aromatic vinyl compound unit, and a polymer block (B) mainly containing an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units, in the resin composition (X), the hydrogenated block copolymer (b) having a phase separation structure having formed therein both (i) an island phase having a long axis of 1 μm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, and in the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) being from 61/100 to 95/100. 111-. (canceled)12: A liquid packaging container , comprising: at least one of a layer containing a resin composition (X) containing a polypropylene resin (a) and at least one of a hydrogenated block copolymer (b),', 'the hydrogenated block copolymer (b) being a hydrogenated product of a block copolymer containing a polymer block (A) mainly containing an aromatic vinyl compound unit, and a polymer block (B) mainly containing an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units,', 'in the resin composition (X), the hydrogenated block copolymer (b) having a phase separation structure having formed therein both (i) an island phase having a long axis of 1 mm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, and', 'in the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) being from 61/100 to 95/100,', 'wherein the film has a structure containing three or more layers including at ...

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Номер записи: 17
18-02-2016 дата публикации

Thermoplastic resin composition, molded article and coated molded article

Номер: US20160046804A1
Автор: Takayuki Wakita, Yoshikazu Ueda
Принадлежит: Asahi Kasei Chemicals Corp

A thermoplastic resin composition, comprising: an aromatic polycarbonate (A); a copolymer mixture (B) comprising a copolymer (b1) of a vinyl cyanide-based monomer and one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer, and a graft copolymer (b2) of a vinyl cyanide-based monomer, one or more kinds of monomers copolymerizable with said vinyl cyanide-based monomer and a rubbery polymer; and at least one kind of metal atom selected from the group consisting of Mg, Al and Ca, wherein the copolymer mixture (B) comprises an acetone-soluble component, wherein said acetone-soluble component has at least two peak tops, being peak top 1 and peak top 2, within the range of 15 to 50% of vinyl cyanide component content rate, when measuring the vinyl cyanide component content rate by high performance liquid chromatography, wherein the peak top 1 is present in the range of 15% or more to 30% or less of vinyl cyanide component content rate, wherein the peak top 2 is present in the range of from more than 30% to 50% or less of vinyl cyanide component content rate, and wherein the total content of the metal atoms is 10 to 1000 ppm, based on 100 parts by mass of total amount of the aromatic polycarbonate (A) and the copolymer mixture (B).

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Номер записи: 18
28-02-2019 дата публикации

Polylactide Based Compositions

Номер: US20190062549A1
Автор: Thierry Coupin
Принадлежит: Total Research and Technology Feluy SA

Embodiments of poly-lactide compositions are disclosed herein. The compositions may comprise at least one first polymer selected from polylactide-polybutadiene (PLA-PB) block copolymer, polylactide-urethane-polybutadiene block copolymer, or a mixture thereof; and at least one second polymer selected from polylactide, polylactide-urethane, or a mixture thereof. The composition may also comprise from 20% to 50% by weight of said first polymer based on the total weight of the composition and from 50% to 80% by weight of said second polymer based on the total weight of the composition. Embodiments of the present invention also relate to a process for preparing the poly-lactide compositions and articles comprising the poly-lactide compositions.

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Номер записи: 19
10-03-2016 дата публикации

NANOSCALE ß-NUCLEATING AGENT FOR POLYPROPYLENE

Номер: US20160068643A1
Автор: Busch Detlef, Klein Dominic, Schmitz Bertram
Принадлежит:

The invention relates to a method for producing a dispersion of nanoscale dicarboxylic acid salts, to the use of these dispersions for producing a compound, and to the use for producing films. The invention further relates to the use of the compounds for producing films. 134-. (canceled)35. A porous , biaxially stretched film of polypropylene and nanoscale dicarboxylic acid alkaline earth salt , wherein said film has a Gurley value of <100 s and wherein a divalent metal salt of an aliphatic dicarboxylic acid is disintegrated to a particle size of from 5 to 300 nm and the biaxially stretched polypropylene film has a uniform distribution of a mean pore diameter (bubble point) of from 50 to 350 nm and the film has a porosity of >50%.36. The porous claim 35 , biaxially stretched film according to claim 35 , wherein the thickness of said film is <25 μm.37. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said dicarboxylic acid is an aliphatic dicarboxylic acid with 4 to 15 C-atoms and said non-aqueous claim 35 , liquid phase is an alcohol.38. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said dicarboxylic acid is pimelic acid or suberic acid.39. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said metal salt is an alkaline earth salt.40. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said metal salt is a hydroxide claim 35 , a carbonate or a chloride.41. The porous claim 38 , biaxially stretched film according to claim 38 , wherein said metal salt is a hydroxide claim 38 , a carbonate or a chloride.42. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said propylene polymer is an isotactic propylene homopolymer and/or a propylene block copolymer.43. The porous claim 35 , biaxially stretched film according to claim 35 , wherein said polypropylene of said mixture is an isotactic polypropylene with a melting point in the ...

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Номер записи: 20
27-02-2020 дата публикации

ULTRAHIGH MOLECULAR WEIGHT BLOCK COPOLYMERS AND POLYMERS, METHODS OF MAKING SAME, AND USES OF SAME

Номер: US20200062882A1
Автор: Lin Haiqing, MAPAS Jose, Rzayev Javid
Принадлежит:

Provided are UHMW polymers having a molecular weight of 500 kg/mol or greater. The UHMW polymers can be block copolymers, homopolymers, and random/statistical copolymers. The UHMW polymers can be used to form porous layers, which may be used in filtration membranes, such as, for example, ultrafiltration membranes. The filtration membranes can be used in various separation methods. 2. The membrane of claim 1 , wherein first block comprises acrylate moieties claim 1 , methacrylate moieties claim 1 , acrylamide moieties claim 1 , methacrylamide moieties claim 1 , or a combination thereof claim 1 , wherein the moieties have at least one acid-reactive group or at least one base-reactive group.3. The membrane of claim 1 , wherein the acid-reactive groups are chosen from ketal groups claim 1 , acetal groups claim 1 , ester groups claim 1 , anhydride groups claim 1 , carbonate groups claim 1 , silyl ether groups claim 1 , and combinations thereof.4. The membrane of claim 1 , wherein the base-reactive groups are chosen from ester groups claim 1 , anhydride groups claim 1 , carbonate groups claim 1 , silyl ether groups claim 1 , and combinations thereof.5. The membrane of claim 1 , wherein the first block has 10-100 mol percent (based on the moles of repeat moieties in the first block) moieties comprising acid-reactive groups or base-reactive groups.6. The membrane of claim 1 , wherein the first block has a molecular weight (Mw or Mn) of 200-2000 kg/mol.7. The membrane of claim 1 , wherein second block comprises acrylate moieties claim 1 , methacrylate moieties claim 1 , vinyl pyridine moieties claim 1 , styrenic moieties claim 1 , saturated or unsaturated aliphatic moieties claim 1 , or a combination thereof.8. The membrane of claim 1 , wherein the second block has a molecular weight (Mw or Mn) of 200-2000 kg/mol.9. The membrane of claim 1 , wherein:the first block is a poly(solketal methacrylate) (PSM) block and the second block is a polystyrene block.10. The membrane of ...

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Номер записи: 21
08-03-2018 дата публикации

Method for producing polyethylene-based resin extruded foam sheet, polyethylene-based resin extruded foam sheet, and plate interleaf sheet using the same for glass sheets

Номер: US20180066121A1
Автор: Takashi Nishimoto, Takeshi Aoki
Принадлежит: JSP Corp

Provided is a method for producing a polyethylene-based resin extruded foam sheet by extruding and foaming a foamable molten resin composition formed by kneading a mixture containing a low-density polyethylene, a physical blowing agent, and an antistatic agent, wherein the foam sheet has a thickness in a range of from 0.05 to 0.5 mm, and the antistatic agent is a polymeric antistatic agent having a melting point whose different from the melting point of the low-density polyethylene is in a range of from −10 to +10° C., and having a melt flow rate of 10 g/10 min or more. This method enables a novel polyethylene-based resin extruded foam sheet to be obtained that is of high quality such that formation of a small hole or a through-hole has been reduced or eliminated, and has both excellent strength and a shock-absorbing property despite a very small thickness even in medium- or long-term continuous production, and besides, exhibits a sufficient antistatic property, thus suitable as a glass plate interleaf sheet.

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Номер записи: 22
11-03-2021 дата публикации

WATERBORNE CROSSLINKABLE DISPERSIONS

Номер: US20210070977A1
Автор: BARBOSA John, CRONIN Jon Andrew, DE BONT Johannes Hendrikus, Gebhard Matthew Stewart, Overbeek Gerardus Cornelis, SCHELLEKENS Michael Arnoldus Jacobus, SHEARER Charles
Принадлежит:

The present invention further relates to a waterborne dispersion comprising (A) polymer P; (B) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and (C) crosslinker, characterized in that the polymer P is crosslinkable and comprises ethylenically unsaturated monomer(s) bearing crosslinkable functional groups different from monomer(s) (i) and monomer(s) (ii) (monomer(s) (iii)) in an amount of from 1 to 10 wt. %, based on the total weight of monomers used to prepare the polymer P, the amount of lock copolymer is higher than 1 wt. % and lower than 30 wt. %, based on the total weight of monomers used to prepare the block copolymer and polymer P; the acid value of the composition consisting of block copolymer and polymer P is higher than 1 and lower than 17 mg KOH per g of the block copolymer-polymer P composition. 1. A waterborne dispersion comprising(A) polymer P; block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and', 'block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and, '(B) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby'}(C) crosslinker,wherein the polymer P is crosslinkable and comprises ethylenically unsaturated monomer(s) bearing crosslinkable functional groups different from monomer(s) (i) and monomer(s) (ii) (monomer(s) (iii)) in an amount of from 1 to 10 wt. %, based on the total weight of monomers used to prepare the polymer P,the amount of block copolymer is higher than 1 wt. % and lower than ...

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Номер записи: 23
24-03-2022 дата публикации

Thermoplastic elastomer overmold composition

Номер: US20220089898A1
Автор: Krishna Venkataswamy, Pei-Zhen JIAN, Prakash SANJEEVAIAH
Принадлежит: Star Thermoplastic Alloys & Rubbers Inc

A thermoplastic elastomer composition for overmolding a plastic article or substrate, a method for the preparation of an overmolded article, and an overmolded article having a layer of thermoplastic elastomer is provided. The thermoplastic elastomer composition comprises a blend of hydrogenated styrene block copolymers and unsaturated styrene block copolymer. The method for the preparation of the overmolded article comprises applying a thermoplastic elastomer composition to at least a portion of the exterior surface of a rigid plastic substrate.

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Номер записи: 24
24-03-2016 дата публикации

Advanced Thermal Insulation by Pore Morphology Control in Foaming

Номер: US20160082628A1
Автор: Arthur Jing-Min Yang
Принадлежит: Industrial Science and Technology Network Inc

A foam extrusion slot die is provided, comprising a plurality of parallel dividers extending transversely across the slot, wherein the plurality of dividers define a plurality of adjacent rectangular slit openings, each having a length extending perpendicularly across the lateral length of the slot die. An article of manufacture is provided, comprising a polymer material system with at least 95% porosity comprising greater than 10%>asymmetrical pores. A method for an article of manufacture is provided comprising: extruding polymer material through an extruder die opening having an output orifice partitioned by a plurality of parallel dividers defining a plurality of adjacent slit openings each having a vertical height greater than a lateral width.

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Номер записи: 25
26-03-2015 дата публикации

WEATHER-PROOF THERMOPLASTIC MOULDING COMPOUNDS WITH IMPROVED TOUGHNESS ON THE BASIS OF STYRENE COPOLYMERS AND POLYAMIDES

Номер: US20150087784A1
Автор: Blinzler Marko, Weber Martin
Принадлежит:

A thermoplastic moulding compound that has proved to be extremely weather-resistant and low-emission containing the following components: A) 3-77% by weight of one or more styrene copolymers, component A; B) 15-89% by weight of one or more polyamides, component B; C) 5-50% by weight of two or more graft rubbers without olefinic double bonds in the rubber phase, component C; D) 1-25% by weight of a terpolymer of styrene, acrylonitrile and maleic anhydride, component D; E) 2-30% by weight of rubber based on olefinic monomers, component E; F) 0-50% by weight of fibrous or particulate filler or mixtures thereof, component F; G) 0-40% by weight of further additives, component G. 1. A thermoplastic molding composition comprising the following components:A) 3 to 77 wt % of one or more styrene copolymers, as component A,B) 15 to 89 wt % of one or more polyamides, as component B,C) 5 to 50 wt % of two or more graft rubbers without olefinic double bonds in the rubber phase, as component C,D) 1 to 25 wt % of a terpolymer of styrene, acrylonitrile, and maleic anhydride, as component D,E) 2 to 30 wt % of rubber based on olefinic monomers, as component E,F) 0 to 50 wt % of fibrous or particulate filler or mixtures thereof, as component F,G) 0 to 40% of further adjuvants, as component G,the wt % being based in each case on the total weight of components A to G and together making 100 wt %.2. The thermoplastic molding composition as claimed in claim 1 , comprising:A) 10 to 70 wt % of one or more styrene copolymers, as component A,B) 20 to 60 wt % of one or more polyamides, as component B,C) 14 to 35 wt % of two or more graft rubbers without olefinic double bonds in the rubber phase, as component C,D) 2 to 10 wt % of a terpolymer of styrene, acrylonitrile, and maleic anhydride, as component D,E) 3 to 30 wt % of rubber based on olefinic monomers, as component E,F) 0 to 50 wt % of fibrous or particulate filler or mixtures thereof, as component F,G) 0 to 40% of further adjuvants, as ...

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Номер записи: 26
25-03-2021 дата публикации

THERMOPLASTIC ELASTOMER COMPOSITION, FOAMED MATERIAL AND MANUFACTURING METHOD THEREOF

Номер: US20210087347A1
Автор: Cheng Wen Wei, HSU Chia-Hung, SHIH HSI-HSIN, Tseng Yu Tsan
Принадлежит:

The present invention provides a thermoplastic elastomer composition for foaming. The thermoplastic elastomer composition comprises: (A) an ethylene-based copolymer; (B) an olefin block copolymer; (C) an unsaturated aliphatic rubber; and (D) a crosslinking agent. The olefin block copolymer is different from the ethylene-based copolymer. The weight ratio of the unsaturated aliphatic rubber (C) to the olefin block copolymer (B) is 1:1.5 to 1:5. 1. A thermoplastic elastomer composition for foaming , comprising:(A) an ethylene-based copolymer;(B) an olefin block copolymer, the olefin block copolymer being different from the ethylene-based copolymer;(C) an unsaturated aliphatic rubber; and(D) a crosslinking agent; wherein a weight ratio of the unsaturated aliphatic rubber (C) to the olefin block copolymer (B) is 1:1.5 to 1:5.2. The thermoplastic elastomer composition of claim 1 , comprising 20-45 wt % of the ethylene-based copolymer (A) claim 1 , 30-50 wt % of the olefin block copolymer (B) and 10-25 wt % of the unsaturated aliphatic rubber (C) claim 1 , based on a total weight of the thermoplastic elastomer composition.3. The thermoplastic elastomer composition of claim 1 , wherein the ethylene-based copolymer (A) is selected from an ethylene-based copolymer with a carbonyl group claim 1 , an ethylene-α-olefin random copolymer and a combination thereof.4. The thermoplastic elastomer composition of claim 3 , wherein the ethylene-based copolymer with a carbonyl group is ethylene/vinyl acetate copolymer claim 3 , ethylene/methyl methacrylate copolymer claim 3 , ethylene/butyl methacrylate copolymer claim 3 , ethylene/butyl acrylate copolymer claim 3 , ethylene/ethyl acrylate copolymer claim 3 , ethylene/acrylic acid copolymer claim 3 , ethylene/acrylic acid ionomer or a mixture thereof.5. The thermoplastic elastomer composition of claim 3 , wherein the ethylene-α-olefin random copolymer is ethylene-propylene random copolymer claim 3 , ethylene-1-butene random copolymer ...

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Номер записи: 27
05-05-2022 дата публикации

THERMOPLASTIC GEL WITH LOW OIL BLEED OUT

Номер: US20220135801A1
Автор: ADAMS Gary William, DELA RUELLE Marie-Christine Alma, RADELET Christiaan
Принадлежит: CommScope Technologies LLC

Disclosed herein is a thermoplastic gel prepared from a composition comprising: a styrene triblock copolymer; a styrene diblock copolymer; an oil extender; and optionally an additive. The composition comprises greater than 21 wt % up to about 35 wt % of a combination of the styrene triblock copolymer and the styrene diblock copolymer. The thermoplastic gel exhibits a very low oil bleed out of less than about 5% after 1500 hours at 60° C. and 120 kPa.

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Номер записи: 28
05-04-2018 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20180094129A1
Автор: Baghdadi Hossein A.
Принадлежит:

Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding. 1. A component for an article of footwear , the component comprising the crosslinked reaction product of a first composition , wherein the first composition comprises a first block and a third block, each independently comprising a linear or branched chain aliphatic polymer having a plurality of aromatic groups attached pendantly thereto,', 'a second block located between the first block and the third block and comprising an aliphatic polymer having a plurality of aliphatic side chains attached thereto, and', 'a plurality of first ethylenically unsaturated group present on one or more of the first block, second block, and third block;', 'wherein the block copolymer comprises about 60% to about 90% of the second blocks by weight based upon the weight of the block copolymer;, 'a block copolymer comprising'}an olefinic copolymer comprising a plurality of first olefinic segments and a plurality of second olefinic segments having a different chemical structure from the first olefinic segments;one or more linking polymers, each linking polymer comprising one or more third olefinic segments; andan ethylene-vinyl acetate (EVA) copolymer.wherein a sum of a ratio I, II, III, IV, and V is from about 1.00 to about 10.00;wherein the ratio I is a ratio of a total parts by weight ...

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Номер записи: 29
28-03-2019 дата публикации

PHOTOCHROMIC ARTICLE

Номер: US20190092950A1
Автор: Blackburn Sapna, Cetin Erdem, Jin Ren-Zhi, Phan Quang
Принадлежит:

Disclosed are articles having a thermoplastic photochromic coating. The articles exhibit a Bayer Abrasion ratio of at least 2 and desirable photochromic properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light. 1. A photochromic article comprising:a) a substrate; i) a thermoplastic acrylic polymer wherein the polymer or at least one segment of the polymer has a Tg below 55° C.;', 'ii) a photochromic amount of one or more photochromic compounds; and', 'iii) a non-reactive organic solvent;', 'wherein the total amount of photochromic compound(s) is at least 40 parts by weight per 100 parts by weight of the total amount of thermoplastic acrylic polymer in the coating composition;, 'b) a thermoplastic photochromic coating composition solidified on at least one surface of the substrate, the photochromic coating composition comprising'}c) an optional first organic adhesion promoter layer interposed between the substrate and the photochromic coating;d) a protective polymeric hard coating superposed over the photochromic coating; ande) an optional second organic adhesion promoter layer interposed between the photochromic coating and the protective hard coating.2. The article of wherein the acrylic polymer is a copolymer comprising poly(alkyl methacrylate) and poly(alkyl acrylate) segments.3. The article of wherein the copolymer is an ABA triblock copolymer wherein A and B are two different polymer segments selected from poly(methyl acrylate) claim 2 , poly(methyl acrylate-co-dialkylacrylamide) claim 2 , poly(methyl methacrylate) claim 2 , poly(butyl acrylate) claim 2 , poly(methyl methacrylate-co-dialkylacrylamide) claim 2 , and poly(butyl acrylate-co-dialkylacrylamide).4. The article of wherein A is poly(methyl methacrylate-co-dialkylacrylamide) and B is poly(butyl acrylate).5. The article of wherein A contains 1 to 40 mole percent dialkylacrylamide.6. The article of wherein the ...

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Номер записи: 30
26-03-2020 дата публикации

POLYMER COMPOSITIONS FOR SHRINK-WRAP FILMS

Номер: US20200095416A1
Автор: Knoll Konrad, Niessner Norbert, Schuster Michael, Wagner Daniel
Принадлежит:

Polymer compositions comprising styrene butadiene block-copolymers (SBC) can be used for shrink-wrap films, a stiff star-shaped SBC block copolymer A having two short branches of a single copolymer block (B/S)and two long branches of the structure S-[(B/S)]-(B/S)or [(B/S)]-(B/S)are used in said polymer composition, and the production of shrink-wrap films and of multilayer films is described. 120-. (canceled)21. A star-shaped block copolymer A having:{'sub': Ai', 'A, 'two short branches consisting of a single copolymer block (B/S)made from 65 to 95 wt.-% vinylaromatic monomers and 35 to 5 wt.-% dienes and having a glass transition temperature Tgin the range from 40 to 90° C., and'}{'sub': t', 'A', 'n', 'Ai', 'A', 'n', 'Ai', 'Ai', 't', 'A', 'n', 'A', 'A', 'Ai, 'two long branches of the structure S-[(B/S)]-(B/S)or [(B/S)]-(B/S), linked by way of the inner blocks (B/S), where the block Sis made from 95 to 100 wt.-% of vinylaromatic monomers and 0 to 5 wt.-% of dienes; the block [(B/S)]consists of one or more different or identical copolymer blocks (B/S), each made from 65 to 95 wt.-% vinylaromatic monomers and 35 to 5 wt.-% dienes and have a glass transition temperature Tgin the range from 40 to 90° C.; n is a regular number of at least 1, and the block (B/S)is as defined above, wherein'}{'sub': Ai', 'n', 'A', 'n', 'n, 'the block (B/S)has a number average molar mass Min the range of from 5000 to 15000 g/mol and the entire block [(B/S)]has a number average molar mass Mof 50000 to 150000 g/mol.'}22. The star-shaped block copolymer A according to claim 21 , wherein the number-average molar mass Mn of the block Sis in the range from 3000 to 8000 g/mol.23. The star-shaped block copolymer A according to claim 21 , wherein the copolymer blocks (B/S)and (B/S)are composed of polymerized vinylaromatic monomers and of dienes with random distribution.24. The star-shaped block copolymer A according to claim 21 , wherein the block [(B/S)]consists of 2 to 10 different copolymer blocks ...

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Номер записи: 31
11-04-2019 дата публикации

Non-humidified proton-conductive membrane, method for producing the same, and fuel cell

Номер: US20190109343A1
Автор: Atsushi Noro, Takahiro Mori, Takato KAJITA, Yushu Matsushita
Принадлежит: Nagoya University NUC

A non-humidified proton-conductive membrane according to the present invention includes a polymer and a proton-conductive substance. The polymer includes a glassy or crystalline first site having a glass-transition temperature or melting temperature higher than the service temperature of the proton-conductive membrane and a second site capable of forming a noncovalent bond. The proton-conductive substance includes a proton-releasing/binding site capable of noncovalently binding to the second site of the polymer and a proton coordination site capable of coordinating to protons, the proton-releasing/binding site and the proton coordination site being included in different molecules that interact with each other or being included in the same molecule. A proton-conductive mixed phase that includes the second site to which the proton-releasing/binding site of the proton-conductive substance is bound and the proton-conductive substance is lower than the service temperature of the proton-conductive membrane. The amount of the proton-releasing/binding site is excessively large compared with the amount of the second site of the polymer.

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Номер записи: 32
04-05-2017 дата публикации

Painted polyolefin articles

Номер: US20170121478A1
Автор: HONG Yang, Jeffrey C. Munro, Lisa S. Madenjian, Tao T. Han
Принадлежит: Dow Global Technologies LLC

A painted article includes a primer layer between a substrate and a paint layer, of which the substrate is the product of a substrate forming composition including an olefin block copolymer and a polypropylene polymer having a density from 0.89 g/cm 3 and 0.92 g/cm 3 . The substrate is free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer.

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Номер записи: 33
25-08-2022 дата публикации

RESIN COMPOSITION TO BE CROSS-LINKED AND FOAMED

Номер: US20220267549A1
Автор: Sasamori Tetsuya
Принадлежит:

The resin composition to be cross-linked and foamed contains a thermoplastic resin, a cross-linking agent, and a foaming agent, and further contains a fatty acid and a fatty acid ester. 1. A resin composition to be cross-linked and foamed , the resin composition comprising: a thermoplastic resin; a cross-linking agent; and a foaming agent; the resin composition further comprising:a fatty acid; and a fatty acid ester.2. The resin composition of claim 1 , whereinthe thermoplastic resin is at least one selected from the group consisting of a polyolefin-based elastomer (POE), an olefin block copolymer (OBC), an ethylene-vinyl acetate (EVA) copolymer, a polyamide (PA), a polyether block amide (PEBA), and a styrene-based thermoplastic elastomer (TPS).3. The resin composition of claim 1 , whereina sum of a content of the fatty acid and a content of the fatty acid ester ranges from 0.5 parts by mass to 4.0 parts by mass relative to 100 parts by mass of the thermoplastic resin.4. The resin composition of claim 3 , whereinthe content of the fatty acid ranges from 0.25 mass % to 1.0 mass %.5. The resin composition of claim 3 , whereinthe content of the fatty acid ester ranges from 0.25 mass % to 3.0 mass %.6. The resin composition of claim 1 , whereinthe fatty acid is at least one selected from the group consisting of stearic acid, lauric acid, and myristic acid.7. The resin composition of claim 1 , whereinthe fatty acid ester is at least one of a polyhydric alcohol fatty acid ester or a higher fatty acid ester.8. A cross-linked foam formed from the resin composition of .9. The cross-linked foam of with a specific gravity of 0.6 g/cmor less.10. The cross-linked foam of for a midsole of a shoe. This application claims priority to Japanese Patent Application No. 2021-028438 filed on Feb. 25, 2021, the entire disclosure of which is incorporated by reference herein.The present disclosure relates to a resin composition to be cross-linked and foamed into a cross-linked foam used for ...

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Номер записи: 34
25-08-2022 дата публикации

USE OF A COMPOSITION FOR THE MANUFACTURE OF A FOAMED ARTICLE

Номер: US20220267550A1
Автор: Bouyahyi Miloud, Duchateau Robbert, Jasinska-Walc Lidia
Принадлежит:

The present invention relates to the use of a composition comprising 60-98 wt. % of polypropylene, 2-40 wt. % of low density polyethylene, 0.1-10 wt. % of compatibiliser wherein the compatibiliser is a BAB or AB type of block copolymer comprising a polypropylene block A and a polyester block B, or wherein the compatibiliser is a graft copolymer of the type ABn having a polypropylene backbone A and polyester block(s) B grafted thereon, with n being at least 1, and the polyester block(s) B have an average M/F ratio from 8-32, wherein M is the number of backbone carbon atoms in the polyester not including carbonyl carbon atoms, and F is the number of ester groups in the polyester block(s), wherein the wt. % is based on the sum of the amount polypropylene, low density polyethylene and compatibiliser, for the manufacture of a foamed article. 1. A foamed article formed from a composition comprising60-98 wt. % of polypropylene2-40 wt. % of low density polyethylene0.1-10 wt. % of compatibiliserwhereinthe compatibiliser is a BAB or AB type of block copolymer comprising a polypropylene block A and a polyester block B, or wherein the compatibiliser is a graft copolymer of the type ABn having a polypropylene backbone A and polyester block(s) B grafted thereon, with n being at least 1, andthe polyester block(s) B have an average M/F ratio from 8-32, wherein M is the number of backbone carbon atoms in the polyester not including carbonyl carbon atoms, and F is the number of ester groups in the polyester block(s),wherein the wt. % is based on the sum of the amount polypropylene, low density polyethylene and compatibiliser.2. The foamed article of wherein the M/F ratio is at least 10.3. The foamed article of wherein the amount of compatibiliser is from 1-8 wt. %.4. The foamed article of wherein in the compatibiliser the block B is a polyester obtained by the ring opening polymerisation of at least one of cyclic ethylene brassylate claim 1 , dodecalactone claim 1 , tridecanolactone ...

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Номер записи: 35
16-04-2020 дата публикации

RESIN-METAL COMPOSITE MEMBER FOR TIRE, AND TIRE

Номер: US20200115515A1
Автор: Fudemoto Hiroyuki, NAKAKITA Yukinori, Suzuki Takahiro
Принадлежит:

A resin-metal composite member for a tire, the member including a metal member (), an adhesion layer (), and a covering resin layer () in the listed order, in which the adhesion layer () includes a polyester-based thermoplastic elastomer having a polar functional group, and the covering resin layer () includes a polyester-based thermoplastic elastomer. 1. A resin-metal composite member for a tire , the member comprising a metal member , an adhesion layer , and a covering resin layer in this order , wherein:the adhesion layer comprises a polyester-based thermoplastic elastomer having a polar functional group, andthe covering resin layer comprises a polyester-based thermoplastic elastomer.2. The resin-metal composite member for a tire according to claim 1 , wherein the polyester-based thermoplastic elastomer having a polar functional group has claim 1 , as the polar functional group claim 1 , at least one group selected from the group consisting of an amino group claim 1 , an epoxy group claim 1 , a carboxy group and an anhydride group thereof.3. The resin-metal composite member for a tire according to claim 1 , wherein the adhesion layer comprises 50% by mass or more of the polyester-based thermoplastic elastomer having a polar functional group with respect to an entire adhesion layer.4. The resin-metal composite member for a tire according to claim 1 , wherein the covering resin layer comprises 50% by mass or more of a polyester-based thermoplastic elastomer having no polar functional group claim 1 , as the polyester-based thermoplastic elastomer claim 1 , with respect to an entire covering resin layer.5. The resin-metal composite member for a tire according to claim 1 , wherein the polyester-based thermoplastic elastomer having a polar functional group in the adhesion layer has a melting point of from 160° C. to 230° C.6. The resin-metal composite member for a tire according to claim 1 , wherein the polyester-based thermoplastic elastomer in the covering resin ...

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Номер записи: 36
11-05-2017 дата публикации

ION EXCHANGE MEMBRANE, METHOD FOR MANUFACTURING SAME, MODULE, AND DEVICE

Номер: US20170128931A1
Автор: Inoue Kazuomi, Kaminaga Kuniyuki
Принадлежит:

An object of the present invention is to provide a high-performance ion exchange membrane having a small defect and a sufficient mechanical strength, a method for manufacturing the ion exchange membrane, and a module and a device which include the ion exchange membrane. 3. The ion exchange membrane according to claim 1 ,{'sup': a', 'b', 'c', 'd, 'wherein Rand Rand/or Rand Rform a ring by being bonded to each other.'}4. The ion exchange membrane according to claim 2 ,{'sup': e', 'f', 'g', 'h, 'wherein Rand Rand/or Rand Rform a ring by being bonded to each other.'}5. The ion exchange membrane according to claim 1 ,{'sub': 1', '2, 'sup': −', '−, 'wherein X and X each independently are a halide ion.'}6. The ion exchange membrane according to claim 1 ,wherein the resin further has a cross-linked structure in addition to the constitutional unit represented by Formula 1.7. The ion exchange membrane according to claim 6 ,wherein a content of the cross-linked structure other than the constitutional unit represented by Formula 1 is 0.05 to 0.5 mmol/g with respect to a total mass of the resin.10. The method for manufacturing the ion exchange membrane according to claim 9 ,wherein the compound represented by Formula 5 is a liquid at 25° C.11. The method for manufacturing the ion exchange membrane according to claim 9 ,wherein a content of the compound represented by Formula 5 in the composition is equal to or greater than 50% by weight.12. The method for manufacturing the ion exchange membrane according to claim 9 ,wherein the composition does not contain an organic solvent, or a content of an organic solvent in the composition is greater than 0% by mass and equal to or less than 1% by mass.13. The method for manufacturing the ion exchange membrane according to claim 8 ,wherein X is a halogen atom.14. The method for manufacturing the ion exchange membrane according to claim 8 ,wherein in the reaction step, both of the constitutional unit represented by Formula 1 and the ...

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Номер записи: 37
23-04-2020 дата публикации

DIP FORMABLE SOLUTIONS AND DISPERSIONSAND ARTICLES MADE THEREFROM

Номер: US20200123374A1
Автор: Plamthottam Sebastian S.
Принадлежит:

This invention relates to eco-friendly dip formable solutions and dispersions for making dip formed articles. Some embodiments of the invention include coatable, dip formable, or emulsifiable solution composition comprising one or more styrenic block copolymers in cyclic natural terpenes, such as citrus peel extract which can be used to form an article. In some embodiments dip formable solutions and dispersions comprise of styrenated block copolymers and polyolefins. In some embodiments the styrenated block copolymers are saturated, unsaturated, or a blend. In some embodiments, the styrenated block copolymers comprises an oil or a plasticizer. In some embodiments the articles are made from an emulsion. In some embodiments the articles are made from a plastisol. 1. A dip formable composition comprising a styrenic block copolymer disposed in a cyclic terpene.2. The dip formable composition of claim 1 , in which the styrenic block copolymer is chosen from a saturated styrenic block copolymer or a mixture of saturated styrenic block copolymers.3. The dip formable composition of claim 1 , wherein the composition further comprises an oil or plasticizer.4. The dip formable composition of claim 1 , wherein the composition further comprises a polyolefin.5. The dip formable composition of claim 4 , wherein the styrenic block copolymer is saturated.6. The dip formable composition of claim 5 , wherein the composition comprises an oil or plasticizer.7. The dip formable composition of claim 6 , wherein the block copolymer is a styrene-ethylene-butylene-styrene block copolymer.8. The dip formable composition of claim 6 , wherein composition comprises the styrenic block copolymer is present in an amount of from about 5% to about 50% by weight claim 6 , the polyolefin in an amount of from about 0.1% to about 25% by weight claim 6 , and the oil in an amount of from about 25% to about 75% by weight claim 6 , where the % by weight refers to the % by weight of a dry film formed from the ...

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Номер записи: 38
19-05-2016 дата публикации

HOT-MELT ADHESIVE AND USE THEREOF

Номер: US20160137793A1
Автор: SCHNEIDER Jörg
Принадлежит:

The present invention relates to the use of a hot-melt adhesive for adhesive bonding of at least a first packaging and a second packaging, the hot-melt adhesive comprising: (a) 7-48 parts per weight of a polymer component, the polymer component comprising a styrene block copolymer; (b) 15-52 parts per weight of a tackifying component, wherein the tackifying component comprises thermoplastic adhesive resin, aliphatic hydrocarbon, cycloaliphatic hydrocarbon, aromatic hydrocarbon, the respective hydrocarbon optionally being modified and/or hydrogenated, terpenes, the terpenes optionally being modified or hydrogenated, rosins, the rosins optionally being modified or hydrogenated, or mixtures thereof; (c) 5-25 parts per weight of a plasticizer component, wherein the plasticizer component comprises paraffinic oils, naphthenic oils, polybuten, polybutadien, dibasic esters, polyols or mixtures thereof; and d) 0.02-1.2 parts per weight of a stabilizer component, wherein the stabilizer component is a light stabilizer, preferably as a sterically hindered phenolic antioxidant and/or a sterically hindered amine, most preferably is pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate). 1. Use of a hot-melt adhesive for adhesive bonding of at least a first packaging and a second packaging , the hot-melt adhesive comprising:(a) 7-48 parts per weight of a polymer component, the polymer component comprising a styrene block copolymer;(b) 15-52 parts per weight of a tackifying component, wherein the tackifying component comprises thermoplastic adhesive resin, aliphatic hydrocarbon, cycloaliphatic hydrocarbon, aromatic hydrocarbon, the respective hydrocarbon optionally being modified and/or hydrogenated, terpenes, the terpenes optionally being modified or hydrogenated, rosins, the rosins optionally being modified or hydrogenated, or mixtures thereof;(c) 5-25 parts per weight of a plasticizer component, wherein the plasticizer component comprises paraffinic oils, ...

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Номер записи: 39
19-05-2016 дата публикации

Ethylene-based polymer compositions and foams

Номер: US20160137803A1
Автор: Bee Tin Low
Принадлежит: Dow Global Technologies LLC

The invention provides a composition comprising the following: A) a first polymer selected from the following: i) an ethylene/α-olefin interpolymer; or ii) an ethylene/α-olefin multi-block interpolymer; B) a second polymer selected from the following: iii) an ethylene/α-olefin interpolymer; iv) an ethylene/α-olefin/non-conjugated diene interpolymer; or v) an ethylene/α-olefin multi-block interpolymer; and wherein the first polymer has a density from 0.880 to 0.910 g/cc, and the second polymer has a density less than, or equal to, 0.867 g/cc, and wherein the weight ratio of the first polymer to the second polymer is from 0.5 to 9.

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Номер записи: 40
19-05-2016 дата публикации

STABILIZERS FOR POLYMERS CONTAINING ALIPHATICALLY-BOUND BROMINE

Номер: US20160137826A1
Автор: Beulich Inken, Kram Shari L., Stobby William G.
Принадлежит:

Aliphatic bromine-containing polymers are stabilized using a mixture of an alkyl phosphite and an epoxy compound. This stabilizer package is very effective at preventing cross-linking reactions from occurring when the aliphatic bromine-containing polymer is subjected to high temperatures as are seen in melt processing operations. The stabilized aliphatic bromine-containing polymer is useful as a flame retardant for other polymers, notably polystyrene foam. 1. A polymer composition comprising (a) a bulk polymer , (b) an aliphatic bromine-containing polymer , and (c) a mixture of at least one alkyl phosphite and at least one epoxy compound.2. The polymer composition of claim 1 , wherein from 1 to 40 parts by weight of the epoxy compound are present per 100 parts by weight of the aliphatic bromine-containing polymer.3. The polymer composition of claim 1 , wherein from 1 to 40 parts by weight of the alkyl phosphite are present per 100 parts by weight of the aliphatic bromine-containing polymer.4. The polymer composition of claim 1 , wherein the aliphatic bromine-containing polymer is a brominated butadiene homopolymer or a brominated styrene/butadiene block copolymer.5. The polymer composition of wherein the aliphatic bromine-containing polymer is a copolymer of styrene and allylmaleimide; an aliphatically unsaturated polyester; an allyl ether of a novolac novolac resin claim 1 , or a ROMP polymer or copolymer.6. The polymer composition of wherein the bulk polymer is a polymer or copolymer of styrene.7. The polymer composition of claim 2 , which is in the form of a foam.10. The polymer composition of claim 9 , wherein the alkyl phosphite is bis (2 claim 9 ,4-dicumylphenyl)pentaerythritol diphosphite claim 9 , distearylpentaerythritol diphosphite or di(2 claim 9 ,4-di-(t-butyl)phenyl)pentaerythritol diphosphite.11. A method for producing a polymer composition of claim 1 , comprising melt processing a mixture containing a molten bulk polymer and an aliphatic bromine- ...

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Номер записи: 41
18-05-2017 дата публикации

Polyolefin-Based Resin Composition, Film, Medical Bag, and Tube

Номер: US20170137618A1
Автор: Horiuchi Mika, Yagi Noriko
Принадлежит: ASAHI KASEI KABUSHIKI KAISHA

A polyolefin-based resin composition comprising: 1. A polyolefin-based resin composition comprising:a polyolefin-based resin, anda hydrogenated block copolymer having a polymer block A mainly comprising a vinyl aromatic monomer unit and a polymer block B mainly comprising a conjugated diene monomer unit, whereina mass ratio of the polyolefin-based resin/the hydrogenated block copolymer is 95 to 5 parts by mass/5 to 95 parts by mass,a total vinyl aromatic monomer unit content in the hydrogenated block copolymer is 12 to 25 mass %,a degree of hydrogenation of double bonds based on the conjugated diene monomer unit in the hydrogenated block copolymer is 90 mol % or more, anda melt flow rate value is 7 to 26 g/10 min.2. The polyolefin-based resin composition according to claim 1 , whereinthe hydrogenated block copolymer has a melt flow rate value of 10 to 30 g/10 min, andthe polyolefin-based resin has a melt flow rate value of 5 to 20 g/10 min.3. The polyolefin-based resin composition according to claim 1 , wherein a difference between a melt flow rate value of the polyolefin-based resin and a melt flow rate value of the hydrogenated block copolymer is 5 to 15 g/10 min.4. The polyolefin-based resin composition according to claim 1 , wherein a ratio of elastic modulus in an MD direction to elastic modulus in a TD direction (elastic modulus in MD direction/elastic modulus in TD direction) is 0.85 to 1.2 when the polyolefin-based resin composition is formed into a film having a thickness of 0.25 mm.5. The polyolefin-based resin composition according to claim 1 , wherein a mass ratio of the polyolefin-based resin to the hydrogenated block copolymer (the polyolefin-based resin/the hydrogenated block copolymer) is 50 to 10 parts by mass/50 to 90 parts by mass.6. The polyolefin-based resin composition according to claim 1 , wherein a sum of an amount of 1 claim 1 ,2-bond and an amount of 3 claim 1 ,4-bond before hydrogenation of the hydrogenated block copolymer is 65 to 90 mol ...

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Номер записи: 42
08-09-2022 дата публикации

Bacteria Repellant Polymer Composites

Номер: US20220282053A1
Автор: AU Ho-Man, Daniel, KONG Hoi-Kuan, LEE Yuen-Fat, Peter, SUNG Cheuk-Nang, WONG Wai-Chung, WU You, ZHAO Yan-Hua
Принадлежит:

A method for preparing a bacteria repellant masterbatch, bacteria repellant polymer composites comprising the same, and compositions and articles prepared therefrom. 1. A method of preparing a bacteria repellant polymer composite , the method comprising exposing the surface of a porous thermoplastic polymer to plasma thereby forming a surface activated porous thermoplastic polymer; blending the surface activated porous thermoplastic polymer with a bacteria repellant agent thereby grafting the bacteria repellant agent to a surface of the activated porous thermoplastic polymer and forming a masterbatch; and combining the masterbatch with a thermoplastic polymer thereby forming the bacteria repellant polymer composite , wherein the bacteria repellant agent is a non-ionic surfactant.2. The method of claim 1 , wherein the bacteria repellant polymer composite does not comprise a bactericide.3. The method of claim 1 , wherein the porous polymer has a porosity between 50-95%.4. The method of further comprising the step of injection molding the bacteria repellant polymer composite.5. The method of claim 4 , wherein the method does not further comprise a screw extrusion step claim 4 , Banburry mixing step or a melt blending step.6. The method of claim 1 , wherein the porous thermoplastic polymer is selected from the group consisting of polyurethane claim 1 , styrene-ethylene-butylene-styrene block thermoplastic elastomer claim 1 , polyolefin elastomer claim 1 , thermoplastic polyester elastomer claim 1 , polyethylene claim 1 , polypropylene claim 1 , polystyrene claim 1 , styrene-acrylonitrile copolymer claim 1 , acrylonitrile-butadiene-styrene terpolymer claim 1 , terephthalic acid-tetramethylcyclobutanediol-cyclohexanediol copolymer claim 1 , polylactic acid claim 1 , polymethyl methacrylate claim 1 , polyethylene terephthalate claim 1 , polycarbonate claim 1 , polymethylpentene claim 1 , polyamide claim 1 , polyvinyl chloride claim 1 , ethylene-vinyl acetate copolymer ...

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Номер записи: 43
09-05-2019 дата публикации

Extruded styrene resin foam and process for producing same

Номер: US20190136003A1
Автор: Koji Shimizu, Shunji Kurihara, Takenori Kikuchi
Принадлежит: Kaneka Corp

An extruded styrenic resin foam may include 100 parts by weight of a styrenic resin; 0.5 to 8.0 parts by weight of a flame retardant; 1.0 to 5.0 parts by weight of graphite; a saturated hydrocarbon having 3 to 5 carbon atoms; and a hydrofluoroolefin. 1 kg of the extruded styrenic resin foam includes the hydrofluoroolefin in an amount of 0.05 to 0.40 mol, and the saturated hydrocarbon in an amount of 0.10 to 0.40 mol, a total amount of the saturated hydrocarbon and the hydrofluoroolefin being 0.30 to 0.50 mol relative to 1 kg of the extruded styrenic resin foam.

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Номер записи: 44
07-05-2020 дата публикации

LOW DIELECTRIC CONSTANT (DK) AND DISSIPATION FACTOR (DF) MATERIAL FOR NANO-MOLDING TECHNOLOGY (NMT)

Номер: US20200140679A1
Автор: Guan Bing, PENG Hui, Shan Wei
Принадлежит: Sabic Global Technologies B.V.

The disclosure concerns thermoplastic resin compositions including a polymer resin, a dielectric glass fiber component, a hollow glass fiber, and an impact modifier. 1. A thermoplastic composition comprising:from 15 wt. % to 80 wt. % of a polymer resin; andfrom 10 wt. % to 50 wt. % of a low dielectric constant glass fiber component, wherein the glass fiber component has a Dk of less than 5.0 at a frequency of from 1 MHz to 1 GHz and a Df of less than 0.002 at a frequency of from 1 MHz to 1 GHz;from 3 wt. % to 40 wt. % of a hollow filler; andfrom 0.1 wt. % to 10 wt. % of an impact modifier,wherein the thermoplastic composition exhibits a dielectric constant of less than 3.2 at a frequency of 1.9 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 100 mm by 70 mm and 1.6 mm thickness;wherein the thermoplastic composition exhibits a dissipation factor Df of less than 0.01 at a frequency of 1.9 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 100 mm by 70 mm and 1.6 mm thickness,wherein the thermoplastic composition exhibits a nano-molding technology bonding strength of at least 18 MPa when tested in accordance with a bonding strength test adapted from ISO 19095 with a T treatment,wherein the thermoplastic composition exhibits a notched impact strength of at least 70 Jim when tested in accordance with ASTM D256 at 23° C.,wherein the thermoplastic composition exhibits a flow rate of less than 25 cm3/10 min when tested in accordance with ISO 1133 at 275° C. at 5 kg and 300 seconds, andwherein the combined weight percent value of all components does not exceed 100 wt. %, and all weight percent values are based on the total weight of the composition.2. The thermoplastic composition of claim 1 , wherein the polymer base resin comprises a polyalkylene terephthalate claim 1 , polyamide claim 1 , polyetherketone claim 1 , polyphthalamide claim 1 , polyarylene ether claim 1 , a ...

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Номер записи: 45
07-06-2018 дата публикации

FUNCTIONALIZED HYDROPHILIC AND LUBRICIOUS POLYMERIC MATRIX AND METHODS OF USING SAME

Номер: US20180155466A1
Автор: Lee William
Принадлежит: AST Products, Inc.

Compositions are provided herein comprising a base polymer having engrafted with a secondary polymeric matrix having hydrophilic and lubricious copolymer brushes. Each copolymer brush further comprises functional groups immobilized along the surface of the brush in a plurality of layers, the functional groups conferring hydrophilic and lubricious properties to the base polymer. These polymer compositions are useful for e.g., fabricating devices for delivery of intraocular lenses (IOLs) as well as improving the hydrophilic properties of contact lenses. 1. A medical device comprising: a base polymer having one or more engrafted surfaces , the engrafted surfaces comprising an engrafted hydrophilic and lubricious copolymer matrix.2. The medical device of claim 1 , wherein the base polymer has a substantially tubular geometry defining a lumen claim 1 , where the luminal surface comprises an engrafted hydrophilic and lubricious copolymer matrix.3. The medical device of claim 1 , wherein the base polymer has a substantially concave surface and a substantially convex surface claim 1 , and the substantially concave surface and substantially convex surface tube both include an engrafted hydrophilic and lubricious copolymer matrix.6. The method of claim 5 , wherein the base polymer is a hydrophobic bulk matrix selected from the group consisting of polypropylene claim 5 , polycarbonate claim 5 , polyethylene claim 5 , acrylbutadienestyrene claim 5 , polyamide claim 5 , polychlorotrifluoroethylene claim 5 , polytetrafluoroethylene claim 5 , polyvinyl chloride claim 5 , polyvinyldene fluoride claim 5 , polyvinylchloride claim 5 , polydimethylsiloxane claim 5 , polyethylene terephthalate claim 5 , ethylene tetrafluoroethylene claim 5 , ethylene chlortrifluoroethylene claim 5 , perfluoroalkoxy claim 5 , styrene claim 5 , polymethylpentene claim 5 , polymethylmetyacrylate claim 5 , polystyrene claim 5 , polyetheretherketone claim 5 , tetrafluoroethylene claim 5 , polyurethane claim ...

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Номер записи: 46
07-06-2018 дата публикации

FUNCTIONALIZED HYDROPHILIC AND LUBRICIOUS POLYMERIC MATRIX AND METHODS OF USING SAME

Номер: US20180155467A1
Автор: Lee William
Принадлежит: AST Products, Inc.

Compositions are provided herein comprising a base polymer having engrafted with a secondary polymeric matrix having hydrophilic and lubricious copolymer brushes. Each copolymer brush further comprises functional groups immobilized along the surface of the brush in a plurality of layers, the functional groups conferring hydrophilic and lubricious properties to the base polymer. These polymer compositions are useful for e.g., fabricating devices for delivery of intraocular lenses (IOLs) as well as improving the hydrophilic properties of contact lenses. 1. A medical device comprising: a base polymer having one or more engrafted surfaces , the engrafted surfaces comprising an engrafted hydrophilic and lubricious copolymer matrix.2. The medical device of claim 1 , wherein the base polymer has a substantially tubular geometry defining a lumen claim 1 , where the luminal surface comprises an engrafted hydrophilic and lubricious copolymer matrix.3. The medical device of claim 1 , wherein the base polymer has a substantially concave surface and a substantially convex surface claim 1 , and the substantially concave surface and substantially convex surface tube both include an engrafted hydrophilic and lubricious copolymer matrix.4. A base polymer comprising: a hydrophilic surface claim 1 , said hydrophilic surface having a secondary engrafted surface matrix of hydrophilic and lubricious copolymers claim 1 , the engraftment method further comprising the steps of:a. contacting the base polymer with a surface modifying composition having a hydrophilic reactive monomer, a lubricious reactive monomer and a solvent; andb. initiating radical formation in the base polymer, thereby engrafting the hydrophilic reactive monomers and the lubricious reactive monomers on to the surface of the base polymer.6. The method of claim 5 , wherein the base polymer is a hydrophobic bulk matrix selected from the group consisting of polypropylene claim 5 , polycarbonate claim 5 , polyethylene claim 5 ...

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Номер записи: 47
22-09-2022 дата публикации

Expandable Vinyl Aromatic Polymers with Improved Flame Retardancy

Номер: US20220298320A1
Автор: Amelio Iacolina, Jaques Michel, Jean-Claude DELEYE, Magali VACHAUDEZ
Принадлежит: TotalEnergies Onetech Belgium SA

The present invention is related to an expandable vinyl aromatic polymer composition comprising:from 0.5 to 15 parts by weight of dispersed athermanous particles selected from the group consisting of coke, carbon black, graphite and combinations of them, having a volume median particle diameter (D50) comprised between 0.5 and 35 μm, as obtained from laser light scattering measurements according to ISO 13320 using MEK as solvent for vinyl aromatic polymers;from 2 to 10 parts by weight of blowing agent;from 0.2 to 5 parts by weight of halogenated flame retardant; andfrom 0.02 to 5 parts by weight of zinc-modified hydrotalcite;per 100 parts of vinyl aromatic polymer.

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Номер записи: 48
08-06-2017 дата публикации

ACRYLIC RESIN FILM

Номер: US20170158830A1
Автор: MAEDA Kaori, Takahashi Toru, Tsujimoto Takuya
Принадлежит: KURARAY CO., LTD.

An acrylic resin film comprising 50 to 99 parts by mass of a methacrylic resin (A) comprising not less than 80% by mass of a structural unit derived from methyl methacrylate, and 50 to 1 part by mass of a block copolymer (B) comprising 40 to 90% by mass of methacrylic acid ester polymer block[s] (b1) and 10 to 60% by mass of acrylic acid ester polymer block[s] (b2), provided that the total of the methacrylic resin (A) and the block copolymer (B) is 100 parts by mass, wherein the methacrylic resin (A) and the block copolymer (B) satisfy the inequations (1) and (2): 1: An acrylic resin film comprising50 to 99 parts by mass of a methacrylic resin (A) comprising not less than 80% by mass of a structural unit derived from methyl methacrylate and50 to 1 part by mass of a block copolymer (B) comprising 40 to 90% by mass of one or more methacrylic acid ester polymer blocks (b1) and 10 to 60% by mass of one or more acrylic acid ester polymer blocks (b2), [{'br': None, 'sub': (A)', '(b1), '0.5≦Mw/Mw≦2.3\u2003\u2003(1)'}, {'br': None, 'sub': '(b2)', '30000≦Mw≦120000\u2003\u2003(2)'}], 'wherein a total of the methacrylic resin (A) and the block copolymer (B) is 100 parts by mass, and the methacrylic resin (A) and the block copolymer (B) satisfy inequalities (1) and (2){'sub': (A)', '(b1)', '(b2), 'wherein Mwis a weight average molecular weight of the methacrylic resin (A), Mwis a largest weight average molecular weight among the methacrylic acid ester polymer blocks (b1) and Mwis a largest weight average molecular weight among the acrylic acid ester polymer blocks (b2).'}2: The acrylic resin film according to claim 1 , wherein the block copolymer (B) has a refractive index of 1.485 to 1.495.3: The acrylic resin film according to claim 1 , wherein the acrylic acid ester polymer blocks (b2) comprise 50 to 90% by mass of a structural unit derived from an acrylic acid alkyl ester claim 1 , and 50 to 10% by mass of a structural unit derived from an aromatic (meth)acrylic acid ester. ...

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Номер записи: 49
18-06-2015 дата публикации

IN-SITU GELATINOUS TRIBLOCK COPOLYMER ELASTOMERS IN POLYURETHANE FLEXIBLE FOAMS

Номер: US20150166756A1
Автор: Crawford Mark L., Peterson Bruce W.
Принадлежит:

Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized A-B-A triblock copolymer resin and/or an A-B diblock copolymer resin into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form the gelatinous elastomer in-situ while simultaneously polymerizing the polyol and the isocyanate to form polyurethane foam. The polyurethane reaction is exothermic and can generate sufficient temperature to melt the styrene-portion of the A-B-A triblock copolymer resin thereby extending the crosslinking and in some cases integrating the A-B-A triblock copolymer within the polyurethane polymer matrix. The combination has a marbled appearance. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink. Another advantage of in situ gel-foam is that the gel component provides higher support factors compared to the base foam alone. 2. The method of further comprising at least partially polymerizing the in-situ copolymer resin by heat produced by polymerizing the polyol and the polyisocyanate to form the open cell flexible polyurethane foam.3. The method of where the copolymer resin is a triblock copolymer resin and the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam.4. The method of where the copolymer resin is plasticized.5. The method of where the copolymer resin is formed by compounding a copolymer with at least one plasticizing oil and optionally a component selected from the group consisting of colorants; solvents; elastomeric diblock copolymer; antioxidants; antistatic agents; antimicrobial agents; flame retardants; ultraviolet stabilizers; phase change materials; surface tension modifiers; emulsifying agents; surfactants; fragrances; active hydrogen-containing components selected from the ...

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Номер записи: 50
16-06-2016 дата публикации

Elastomeric compositions for blown-film extrusion

Номер: US20160168345A1
Автор: Frank Eschenbacher, Leopoldo V. Cancio
Принадлежит: Clopay Plastic Products Co Inc

Improving processability of homogeneous extrusion blown elastomeric films by compatibilizing impact polystyrene in an effective amount with olefin elastomers and styrenic block copolymers.

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Номер записи: 51
25-06-2015 дата публикации

BLOCK COPOLYMER AND PROCESS FOR PRODUCTION OF HEAT SHRINKABLE FILM

Номер: US20150175758A1
Автор: FUKUOKA Ryoko, Hoshi Susumu, Nakamura Yasutaka
Принадлежит: ASAHI KASEI CHEMICALS CORPORATION

The present invention provides a production process of a heat shrinkable film which is transparent, excellent in the balance of physical properties such as rigidity, elongation and shrink properties in both MD and TD, especially has a uniform film thickness and good stability in extrusion molding film while utilizing an inflation method; a block copolymer or hydrogenated product thereof, or a composition composed thereof excellent in tensile properties, optical properties, hardness, stretch properties, molding processability, shrink properties and solvent resistance and therefore suited for extrusion, injection molding and foams. The production process of a heat shrinkable film has a first inflation step of forming a tube having a thickness of from 0.05 to 0.5 mm by using a block copolymer having a vinyl aromatic hydrocarbon content of from 65 to 95 wt. % and a conjugated diene content of from 5 to 35 wt. %, or a hydrogenated product of the block copolymer; and a second inflation step, successively to the first inflation step, stretching the tube to from 1.5 to 5 times the original length in the TD in a fluid of from 65 to 100° C. 18-. (canceled)9. A heat shrinkable film{'sup': 9', '9, 'produced by a first inflation step of forming, at a temperature of from 150 to 250° C., a raw sheet tube having a thickness of from 0.05 to 0.5 mm by using a material which contains a block copolymer having a vinyl aromatic hydrocarbon content of from 65 to 95 wt. % and a conjugated diene content of from 5 to 35 wt. % or hydrogenated product thereof (I) and has a storage elastic modulus (E′), at 50° C., of from 0.7×10to 2.5×10Pa; and'}a second inflation step, successively to the first inflation step, of stretching the tube to from 1.5 to 5 times the original length in the transverse direction (TD) in a fluid having a viscosity of film, wherein a ratio of the diameter of the raw sheet tube to the diameter of the tube of heat shrinkable film is from 1.5 to 5;the film having a shrinkage ...

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Номер записи: 52
25-06-2015 дата публикации

EPOXY-RESIN COMPOSITION AND FILM, PREPREG, AND FIBER-REINFORCED PLASTIC USING SAME

Номер: US20150175760A1
Автор: Fukuhara Yasuhiro, Ishimoto Tomoko, Kaneko Manabu, Kita Sanae, Watanabe Kenichi
Принадлежит: MITSUBISHI RAYON CO., LTD.

An epoxy-resin composition of the components (A), (B), (D) and (E), where component (A) is an epoxy resin having an oxazolidone-ring structure, (B) is a bisphenol bifunctional epoxy resin with a number-average molecular weight of at least 600 but no more than 1300, which does not have an oxazolidone-ring structure, (D) is a triblock copolymer, and (E) is a curing agent. A film made of the epoxy-resin composition, a prepreg and a fiber-reinforced plastic is also disclosed. The epoxy resin composition is capable of achieving both a processability of a prepreg at room temperature and a suppression of voids in the molded product. A fiber-reinforced plastic having excellent mechanical properties, especially excellent fracture toughness and heat tolerance, is also obtained by using the epoxy-resin composition. 1. An epoxy-resin composition , comprising components (A) , (B) , (D) and (E) , wherein:component (A) is an epoxy resin comprising an oxazolidone-ring structure;component (B) is a bisphenol bifunctional epoxy resin with a number-average molecular weight of at least 600 but no more than 1300, which does not comprise an oxazolidone-ring structure;component (D) is a triblock copolymer; andcomponent (E) is a curing agent.2. The epoxy-resin composition according to claim 1 , wherein the content of component (A) in the epoxy resin composition is set at 3˜45 mass % of the total mass of epoxy resin in the epoxy-resin composition.3. The epoxy-resin composition according to claim 1 , wherein component (D) is a triblock copolymer of poly(methyl methacrylate)/poly(butyl acrylate)/poly(methyl methacrylate).4. The epoxy-resin composition according to claim 1 , wherein component (D) is a triblock copolymer copolymerized with dimethylacrylamide.5. The epoxy-resin composition according to claim 4 , wherein the proportion of the dimethylacrylamide in the triblock copolymer copolymerized with dimethylacrylamide is set at 10˜15 mass % with respect to the total mass of the triblock ...

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Номер записи: 53
01-07-2021 дата публикации

Cushion and shoe

Номер: US20210195993A1
Автор: Junichiro Tateishi
Принадлежит: Asics Corp

Provided is a cushion partially or entirely composed of a foam, wherein the foam is composed of: a hydrocarbon-based oil including ethylene and α-olefin as constituent units; and a polymer composition including one or a plurality of polymers.

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Номер записи: 54
02-07-2015 дата публикации

ASPHALT MODIFIED WITH AN SBS/MMWCNT NANOCOMPOSITE AND PRODUCTION METHOD THEREOF

Номер: US20150184026A1
Автор: Quintero Rangel Luz Stella, Sanabria Grajales Luis Enrique
Принадлежит:

The invention relates to a method for modifying an asphalt binder using, as an additive, a nanocomposite of: functionalized multi-walled carbon nanotubes dispersed in a styrene-butadiene-styrene polymer matrix (SBS/MMWCNT). The asphalt modified with the SBS/MMWCNT nanocomposite has substantially improved mechanical resistance to deformations and to loads at high temperatures, such that the life of the flexible paving is improved. The asphalt mixtures produced with this novel modified asphalt binder have considerably less rutting, are classified as high-modulus asphalt mixtures when produced from asphalt of medium (60/70) or greater hardness, and are not sensitive to moisture effects. 1. A method for preparing asphalt modified with SBS/MMWCNT nanocomposite comprising:1) preparing a polymer nanocomposite additive by means of a styrene-butadiene-styrene (SBS) polymer with functionalized multi-walled carbon nanotubes (MMWCNTs) and the addition of solvents;2) introducing and mixing the polymer nanocomposite with the asphalt base in order to form the modified asphalt composition.2. The method for preparing asphalt modified with SBS/MMWCNT nanocomposite as claimed in claim 1 , wherein in the preparation stage of the polymer nanocomposite claim 1 , the styrene-butadiene-styrene polymer is in the form of pellets or crumbs claim 1 , and the multi-walled carbon nanotubes (MMWCNT) are functionalized.3. The method for preparing asphalt modified with SBS/MMWCNT nanocomposite as claimed in claim 2 , wherein the multi-walled carbon nanotubes (MMWCNT) are functionalized with functional groups selected from the group consisting of hydroxyl groups claim 2 , MWCNT-OH claim 2 , with carboxylic acid groups claim 2 , MWCNT-COOH claim 2 , with amino groups claim 2 , MWCNT-amine claim 2 , phenol claim 2 , MWCNT-phenol claim 2 , and alkyl groups.4. The method for preparing asphalt modified with SBS/MMWCNT nanocomposite as claimed in claim 3 , wherein the SBS polymer and the functionalized ...

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Номер записи: 55
09-07-2015 дата публикации

Epoxy-resin composition, and film, prepreg and fiber-reinforced plastic using the same

Номер: US20150191592A1
Автор: Kenichi Watanabe, Manabu Kaneko, Sanae Kita, Tomoko Ishimoto, Yasuhiro Fukuhara
Принадлежит: Mitsubishi Rayon Co Ltd

The present invention relates to An epoxy-resin composition comprising the following components (A), (B), (C) and (D), a film made of the epoxy resin composition, a prepreg and a fiber-reinforced plastic. The present invention can provide an epoxy-resin composition that cures at a low temperature in a short period of time. Also, the present invention can provide a fiber-reinforced plastic having excellent mechanical characteristics, especially excellent fracture toughness and heat tolerance, is made from the epoxy-resin composition. component (A): an epoxy resin having a monomer unit represented by formula (1) in the molecule; component (B): a bifunctional epoxy resin with a number-average molecular weight of at least 600 but no greater than 1300, which does not have a monomer unit represented by formula (1) below in the molecule; component (C): a triblock copolymer; and component (D): a curing agent.

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Номер записи: 56
13-07-2017 дата публикации

RESIN COMPOSITION CONTAINING BLOCK COPOLYMER

Номер: US20170198079A1
Автор: Ohishi Masayuki, SATO Eiji, Yoshida Jun
Принадлежит: Denka Company Limited

To provide a resin composition containing a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene, from which a formed product such as a sheet or a film, having excellent transparency and impact resistance, can be obtained. 1. A resin composition comprising a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene , which satisfies (A) to (D):(A) a content of the conjugated diene is from 22 to 32% by mass,(B) a block ratio of the vinyl aromatic hydrocarbon is from 90 to 98%,(C) Mw/Mn, wherein Mw is a weight average molecular weight and Mn is a number average molecular weight, is from 1.1 to 1.6 as obtained by gel permeation chromatography (GPC) by a differential refractive index method,(D) a loss tangent, tan δ , obtained by dynamic viscoelasticity measurement has one local maximum value, tan δ (max), within a temperature range of from −90 to −30° C., and tan δ (max+30° C.), which is tan δ at a temperature higher by 30° C. than the temperature at the local maximum value, tan δ peak temperature, is at least 0.6 relative to tan δ (max) at the temperature at the local maximum value.2. The resin composition according to claim 1 , wherein the block copolymer is a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene represented by a formula (I) and/or (II):{'br': None, 'S—(R—S)n-R—S \u2003\u2003(I)'}{'br': None, '(S—(R—S)n-R—S)m-X \u2003\u2003(II)'}wherein S is a polymer block in which a monomer unit consists of the vinyl aromatic hydrocarbon, R is a random copolymer block in which a monomer unit consists of the vinyl aromatic hydrocarbon and the conjugated diene, m is an integer of at least 1, representing a number of a polymer chain bonded to a coupling agent residue, n is an integer of at least 1, representing a number of repeating units, and X represents a residue of a coupling agent.3. The resin composition according to claim 1 , comprising a block copolymer (a) of a vinyl aromatic hydrocarbon and a conjugated diene ...

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Номер записи: 57
29-07-2021 дата публикации

Resin Composition, Prepreg, Metal Foil-Clad Laminate, Resin Sheet, and Printed Wiring Board

Номер: US20210229407A1
Автор: Katsuya Yamamoto, Kazuyuki Higashita, Saori Honda, Yoshitaka Ueno
Принадлежит: Mitsubishi Gas Chemical Co Inc

Provided are a resin composition that can form a printed wiring board with a low dielectric constant and dielectric loss tangent and excellent alkali resistance and desmear resistance; and a prepreg, a resin sheet, a metal foil-clad laminate, and a printed wiring board formed using this resin composition. The resin composition contains a styrene-based elastomer (A), a styrene oligomer (B), a maleimide compound (C), and a cyanate ester compound (D).

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Номер записи: 58
06-08-2015 дата публикации

Ethylene-based polymer compositions and foams

Номер: US20150218331A1
Автор: Bee Tin Low
Принадлежит: Dow Global Technologies LLC

The invention provides a composition comprising the following: A) a first polymer selected from the following: i) an ethylene/α-olefin interpolymer; or ii) an ethylene/α-olefin multi-block interpolymer; B) a second polymer selected from the following: iii) an ethylene/α-olefin interpolymer; iv) an ethylene/α-olefin/non-conjugated diene interpolymer; or v) an ethylene/α-olefin multi-block interpolymer; and wherein the first polymer has a density from 0.880 to 0.910 g/cc, and the second polymer has a density less than, or equal to, 0.867 g/cc, and wherein the weight ratio of the first polymer to the second polymer is from 0.5 to 9.

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Номер записи: 59
26-07-2018 дата публикации

THERMOPLASTIC ELASTOMER COMPOSITION FOR CROSSLINKED FOAM AND USE THEREOF

Номер: US20180208723A1
Автор: LIN Hsuan-Tsung, Ting Ching, TU Ying-Pin, Wen Wen-Hsien, Yang Feng-Yu
Принадлежит:

A thermoplastic elastomer composition for crosslinked foam and the manufacturing method thereof are provided. The thermoplastic elastomer composition comprising (A) an ethylene-based copolymer; (B) a first copolymer; (C) a second copolymer, wherein the component (B) and (C) are copolymers comprising a vinyl aromatic monomer and a conjugated diene monomer, the first copolymer having a conjugated diene hydrogenation rate of at least 80% and the second copolymer having a conjugated diene hydrogenation rate of no more than 10%; (D) an organic peroxide; and (E) a foaming agent, wherein a mass ratio (A/(B+C)) of the component (A) to a combination of the component (B) and the component (C) is 95/5 to 5/95; and a mass ratio (B/C) of the component (B) to the component (C) is 9/1 to 1/9. A crosslinked foam made from the composition and the manufacturing method thereof are also provided. 1. A thermoplastic elastomer composition for crosslinked foam , comprising:(A) an ethylene-based copolymer;(B) a first copolymer;(C) a second copolymer, wherein the components (B) and (C) are copolymers comprising a vinyl aromatic monomer and a conjugated diene monomer, the first copolymer having a conjugated diene hydrogenation rate of at least 80% and the second copolymer having a conjugated diene hydrogenation rate of no more than 10%;(D) an organic peroxide; and(E) a foaming agent,wherein a mass ratio (A/(B+C)) of the component (A) to a combination of the component (B) and the component (C) is 95/5 to 5/95, and a mass ratio (B/C) of the component (B) to the component (C) is 9/1 to 1/9.2. The composition of claim 1 , wherein the vinyl aromatic monomer is independently selected from the group consisting of styrene claim 1 , 4-tert-butylstyrene claim 1 , α-methylstyrene claim 1 , o-methylstyrene claim 1 , p-methylstyrene claim 1 , divinylbenzene claim 1 , 1 claim 1 ,1-diphenylethylene claim 1 , vinylnaphthalene claim 1 , N claim 1 ,N-dimethyl-p-aminoethylstyrene claim 1 , N claim 1 ,N-diethyl ...

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Номер записи: 60
25-06-2020 дата публикации

Process for Producing Foam Beads Using a Modified Ethylene-Based Polymer

Номер: US20200199320A1
Автор: CHEN Hongyu, Gong Yonghua, Hu Xiaolian, Yu Haiyang, Zhang Yi
Принадлежит:

The present disclosure provides a process. The process includes (i) forming a composition containing a peroxide-modified ethylene-based polymer selected from the group consisting of a peroxide-modified ethylene/a-olefin multi-block copolymer, a peroxide-modified low density polyethylene, and combinations thereof; (ii) contacting the composition with a blowing agent to form a foam composition; and (iii) forming foam beads comprising the foam composition. The present disclosure also provides a foam bead produced by said process. 1. A process comprising:(i) forming a composition comprising a peroxide-modified ethylene-based polymer selected from the group consisting of a peroxide-modified ethylene/α-olefin multi-block copolymer, a peroxide-modified low density polyethylene, and combinations thereof;(ii) contacting the composition with a blowing agent to form a foam composition; and(iii) forming foam beads comprising the foam composition.2. The process of comprising contacting the composition with the blowing agent at a temperature of from 100° C. to 130° C.3. The process of wherein the blowing agent is a physical blowing agent.4. The process of comprising forming the composition solely from the peroxide-modified ethylene/α-olefin multi-block copolymer.5. The process of wherein the forming step comprises:melt blending the peroxide-modified ethylene/α-olefin multi-block copolymer with an ethylene/α-olefin multi-block copolymer.6. The process of wherein the forming step comprises:melt blending the peroxide-modified low density polyethylene withan ethylene/α-olefin multi-block copolymer.7. The process of wherein the composition has a melt strength from 9 cN to 30 cN.8. The process of wherein the foam beads have a foam density of less than 0.300 g/cc.9. A foam bead produced by the process of claim 1 , wherein the composition has (a) a melt strength from 9 cN to 30 cN and (b) a gel content of 0%; andthe foam bead has a foam density of less than 0.300 g/cc.10. A foam bead ...

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Номер записи: 61
04-08-2016 дата публикации

Performance APAO hot melt adhesives containing high melt flow rate hydrogenated styrene block copolymers

Номер: US20160222258A1
Автор: Buenacosa Enrico L., Fowler James Nicholas, Haselman James, Sustic Andres
Принадлежит:

Adding a compatible high melt flow rate (MFR), low melt viscosity, hydrogenated styrene block copolymer to amorphous poly alpha-olefins (APAOs) results in adhesives that show acceptably high elongation and tensile strength, and which, when applied by different hot melt application methods onto elastic strands, result in personal hygiene article components that perform comparably to such components assembled using just styrene block copolymer components formulated with compatible tackifiers, processing oils and other additives. 1. A hot-melt adhesive comprising:at least one amorphous poly alpha-olefin; and,a high melt flow rate (MFR), low melt viscosity, hydrogenated styrene block copolymer that is compatible with the amorphous poly alpha-olefin.2. The hot-melt adhesive recited in wherein the high melt flow rate (MFR) claim 1 , low melt viscosity claim 1 , hydrogenated styrene block copolymer is high melt flow rate hydrogenated styrene-butadiene-styrene.3. The hot-melt adhesive recited in wherein the amorphous poly alpha-olefin is a propylene-butene-1 APAO copolymer.4. The hot-melt adhesive recited in wherein the amorphous poly alpha-olefin is an ethylene-propylene-butene-1 terpolymer.5. The hot-melt adhesive recited in wherein the MFR of the hydrogenated styrene block copolymer is higher than 1 dg/min.6. The hot-melt adhesive recited in wherein the MFR of the hydrogenated styrene block copolymer is higher than 25 dg/min.7. The hot-melt adhesive recited in wherein the MFR of the hydrogenated styrene block copolymer is higher than 100 dg/min.8. The hot-melt adhesive recited in wherein the MFR of the hydrogenated styrene block copolymer is about 250 dg/min.9. A method for producing a hot melt adhesive comprising:melting a high 1-butene/propylene APAO in a mixer heated to about 375° F. (190° C.);adding about 3000 ppm of a binary blend of a hindered phenol-type antioxidant and a phosphite stabilizer;adding a styrene block copolymer;mixing the components; and,adding a ...

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Номер записи: 62
03-08-2017 дата публикации

FILM FOR LIQUID PACKAGING CONTAINERS AND LIQUID PACKAGING CONTAINER

Номер: US20170218147A1
Автор: Jogo Yosuke, Nojima Yusuke, Oshita Shinya, Tanaka Yusuke
Принадлежит: KURARAY CO., LTD.

A film for a liquid packaging container, comprising at least one of a layer containing a resin composition (X) containing a polypropylene resin (a) and at least one of a hydrogenated block copolymer (b), the hydrogenated block copolymer (b) being a hydrogenated product of a block copolymer containing a polymer block (A) mainly containing an aromatic vinyl compound unit, and a polymer block (B) mainly containing an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units, in the resin composition (X), the hydrogenated block copolymer (b) having a phase separation structure having formed therein both (i) an island phase having a long axis of 1 μm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, and in the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) being from 61/100 to 95/100. 1: A film , comprising a layer comprising a resin composition (X) comprising a polypropylene resin (a) and a hydrogenated block copolymer (b) ,wherein:the hydrogenated block copolymer (b) is a hydrogenated product of a block copolymer comprising a polymer block (A) mainly comprising an aromatic vinyl compound unit, and a polymer block (B) mainly comprising an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units,in the resin composition (X), the hydrogenated block copolymer (b) has a phase separation structure having formed therein both (i) an island phase having a long axis of 1 μm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, andin the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) is in a range from 61/100 to 95/100.2: The film according to claim 1 , wherein the hydrogenated block copolymer (b) comprises a hydrogenated block copolymer (b-1) and a hydrogenated block ...

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Номер записи: 63
03-08-2017 дата публикации

IN-SITU GELATINOUS TRIBLOCK COPOLYMER ELASTOMERS IN LATEX FOAMS

Номер: US20170218156A1
Автор: Crawford Mark L., Peterson Bruce W.
Принадлежит: Peterson Chemical Technology LLC

Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized A-B-A triblock copolymer resin and/or an A-B diblock copolymer resin into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form the gelatinous elastomer in-situ while simultaneously polymerizing the polyol and the isocyanate to form polyurethane foam. The polyurethane reaction is exothermmic and can generate sufficient temperature to melt the styrene-portion of the A-B-A triblock copolymer resin thereby extending the crosslinking and in some cases integrating the A-B-A triblock copolymer within the polyurethane polymer matrix. The combination has a marbled appearance. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink. Another advantage of in situ gel-foam is that the gel component provides higher support factors compared to the base foam alone. 2. The combination of gelatinous elastomer and latex foam of where the triblock copolymer resin is selected from the group consisting of styrene-ethylene-butylene-styrene (SEBS) claim 1 , styrene-ethylene-propylene-styrene (SEPS) claim 1 , styrene-ethylene-ethylene-propylene-styrene (SEEPS) claim 1 , and combinations thereof; and the diblock copolymer resin is selected from the group consisting of styrene-ethylene-propylene (SEP) claim 1 , styrene-ethylene-butylene (SEB) claim 1 , styrene-ethylene-ethylene (SEE) claim 1 , and combinations thereof.3. The combination of gelatinous elastomer and latex foam of where the in-situ copolymer resin is at least partially polymerized by the curing the mixture to form the latex foam.4. The combination of gelatinous elastomer and latex foam of where the copolymer resin is a triblock copolymer resin.5. The combination of gelatinous elastomer and latex foam of where the copolymer resin is formed by compounding a copolymer with ...

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Номер записи: 64
11-07-2019 дата публикации

FOAMING OF STYRENE POLYMER

Номер: US20190211172A1
Автор: CREAZZO JOSEPH ANTHONY, HITCHENS BRUCE P, KONTOMARIS KONSTANTINOS, Wysong Ernest Byron
Принадлежит:

The present invention is a process for foaming thermoplastic polymer comprising polystyrene said process comprising forming a molten foamable composition comprising said thermoplastic polymer, block copolymer, and blowing agent comprising at least one of Z-1,1,1,4,4,4-hexafluoro-2-butene and E-1,1,1,4,4,4-hexafluoro-2-butene and expanding said foamable composition to obtain as a result thereof foamed thermoplastic polymer, the process being preferably carried out by extruding the composition in molten form, whereupon the foaming of the thermoplastic polymer occurs. 1. Process for foaming thermoplastic polymer comprising polystyrene , said process comprising forming a molten foamable composition comprising said thermoplastic polymer , block copolymer , and blowing agent comprising at least one of Z-1 ,1 ,1 ,4 ,4 ,4-hexafluoro-2-butene and E-1 ,1 ,1 ,4 ,4 ,4-hexafluoro-2-butene and expanding said foamable composition to obtain as a result thereof foamed thermoplastic polymer.2. The process of wherein said molten foamable composition is in an extruder and said expanding is the result of extruding said composition.3. The process of wherein said block copolymer is non-polar.4. The process of wherein the amount of said block copolymer present in said composition is 5 to 15 wt % claim 1 , based on the weight of said foamable composition.5. The process of wherein said Z-1 claim 1 ,1 claim 1 ,1 claim 1 ,4 claim 1 ,4 claim 1 ,4-hexafluoro-2-butene and E-1 claim 1 ,1 claim 1 ,1 claim 1 ,4 claim 1 ,4 claim 1 ,4-hexafluoro-2-butene are highly insoluble in said molten thermoplastic polymer as indicated by a weight gain of no greater than 8 wt %6. The process of wherein said block copolymer is insoluble in said Z-1 claim 1 ,1 claim 1 ,1 claim 1 ,4 claim 1 ,4 claim 1 ,4-hexafluoro-2-butene and E-1 claim 1 ,1 claim 1 ,1 claim 1 ,4 claim 1 ,4 claim 1 ,4-hexafluoro-2-butene.7. The process of wherein said Z-1 claim 1 ,1 claim 1 ,1 claim 1 ,4 claim 1 ,4 claim 1 ,4-hexafluoro-2-butene ...

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Номер записи: 65
11-07-2019 дата публикации

BLENDS FOR FOAMS, FOAMS MANUFACTURED THEREFROM AND ARTICLES COMPRISING THE SAME

Номер: US20190211199A1
Автор: CHEN Hongyu, Hu Xiaolian, Liu Xiaochun, Yu Haiyang, Zhang Chao, Zhang Yi
Принадлежит:

Disclosed herein is a foam composition comprising an olefin copolymer that comprises ethylene and an α-olefin or propylene and an α-olefin; an unneutralized carboxylated olefin copolymer; a crosslinking agent; and a blowing agent; where the foam composition is substantially free from neutralized carboxylated ethylene copolymer. Disclosed herein too is a method of manufacturing a foam composition comprising blending together an olefin copolymer that comprises ethylene and an α-olefin or propylene and an α-olefin; an unneutralized carboxylated olefin copolymer; a crosslinking agent; and a blowing agent to form the foam composition; where the foam composition is substantially free from neutralized carboxylated ethylene copolymer; heating the foam composition to activate the blowing agent to form a foam; and crosslinking the foam. 1. A foam composition comprising:an olefin copolymer that comprises ethylene and an α-olefin or propylene and an α-olefin;an unneutralized carboxylated olefin copolymer;a crosslinking agent; anda blowing agent; where the foam composition is substantially free from neutralized carboxylated ethylene copolymer.2. The foam composition of claim 1 , where the olefin copolymer is an olefin block copolymer and is present in the foam composition in an amount of 50 to 99 wt % claim 1 , based on the total weight of the foam composition.3. The foam composition of claim 1 , where the α-olefin is octene.4. The foam composition of claim 1 , where the carboxylated olefin copolymer is present in the foam composition in an amount of 0.5 to 10 wt % claim 1 , based on the total weight of the foam composition.5. The foam composition of claim 1 , where the carboxylated olefin copolymer comprises a carboxylic acid; where the carboxylic acid is acrylic acid or methacrylic acid.6. The foam composition of claim 1 , where the crosslinking agent is a peroxide and where the blowing agent is a azodicarbonamide.7. The foam composition of claim 1 , where a foam manufactured ...

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Номер записи: 66
12-08-2021 дата публикации

WATERBORNE SIZING COMPOSITION FOR TREATING NATURAL FIBERS AND A PROCESS TO TREAT NATURAL FIBERS BY SAID COMPOSITION

Номер: US20210246607A1
Автор: EUAPERMKIATI Anucha, LOSIRIWAT Takul
Принадлежит:

The present invention relates to a waterborne sizing composition for treating natural fibers to be used as reinforcing material in thermoplastic, comprising: (a) a polymeric material having structure (I) wherein, R represents an alkyl group, X represents a reversible covalently bonded crosslinkable group, p, q, and r represent order on a main polymer chain, wherein the total sum of order greater than 50; (b) a water-soluble metal complex having an antimicrobial property; and (c) a redox active water-soluble compound. 2. The composition according to claim 1 , wherein R is selected from a linear alkyl group claim 1 , a branched alkyl group claim 1 , or a cyclic alkyl group.3. (canceled)4. The composition according to claim 1 , wherein X is reversible covalently bonded crosslinkable group obtained from a mixture of boric acid and dialdehydes selected from glyoxal claim 1 , succindialdehyde claim 1 , glutaraldehyde claim 1 , or a mixture thereof.5. The composition according to claim 1 , wherein the ratio of boric acid to dialdehydes is in a range of 1:2-1:4 based on the mole basis.6. (canceled)7. The composition according to claim 1 , wherein the total sum of p claim 1 , q claim 1 , and r orders is more than 100.8. The composition according to claim 1 , wherein the percentage of p order is 70-90%; q order 10-30% claim 1 , and r order 0.02-1.25% based on 100% of the total sum of p claim 1 , q claim 1 , and r orders.9. The composition according to claim 1 , wherein the water-soluble metal complex is selected from copper complexes claim 1 , silver complexes comprises ligand selected from polyamines or aminocarboxylates.10. (canceled)11. The composition according to claim 1 , wherein the redox active water-soluble compound is selected from aldohexoses claim 1 , aldopentoses claim 1 , or mixture thereof.12. The composition according to claim 1 , wherein further comprises the polymeric material from 7 to 15 weight by volume percentage (% w/v) claim 1 , the water-soluble metal ...

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Номер записи: 67
11-08-2016 дата публикации

Foamed styrenic polymers containing a brominated styrene-butadiene copolymer and having enhanced cell size homogeneity

Номер: US20160229970A1
Автор: Kenji Matsue, Lawrence S. Hood, Mark A. Barger, Naganori NISHIOKA, Shari L. Kram, Stephane Costeux, Yoshihiro Shirakawa
Принадлежит: Dow Global Technologies LLC

Extruded polymer foams are made from a polymer composition that includes an unbrominated styrenic polymer, a brominated vinyl aromatic/butadiene flame retardant, and an unbrominated vinyl aromatic/butadiene polymer. The unbrominated vinyl aromatic/butadiene polymer improves the cell homogeneity.

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Номер записи: 68
09-08-2018 дата публикации

POROUS PARTICLE, METHOD FOR PRODUCING POROUS PARTICLE, AND BLOCK COPOLYMER

Номер: US20180223067A1
Автор: ISHIZUKA Norio, KONISHI Kyoko, ODA Toshikazu, Sakakibara Keita, Sato Takaya, Tsujii Yoshinobu
Принадлежит:

The present invention provides porous particles uniform in shape and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle. 1. Porous particles having a substantially spherical shape , whereineach of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other,the through holes are formed by spinodal decomposition, andends of the through holes are open toward an outside of the porous particle.2. (canceled)3. The porous particles according to claim 1 , whereineach of the porous particle is shaped so that the longest diameter is not more than 1.6 times the shortest diameter.4. The porous particles according to or claim 1 , having a mean particle size in a range from 0.5 to 30 claim 1 ,000 μm.5. A method for producing the porous particles according to claim 1 , claim 1 , or claim 1 , the method comprising:a dispersion preparation step of preparing a dispersion by dispersing a porous particle raw material comprising a monomer and/or a prepolymer in a dispersion medium; anda polymerization step of polymerizing the porous particle raw material in the dispersion,wherein, in the polymerization step, the through holes are formed by spinodal decomposition.6. The method according to claim 5 , whereinin the dispersion preparation step, the porous particle raw material is dispersed in the dispersion medium together with a dispersant.7. The method according to claim 6 , whereinthe dispersant is a block copolymer comprising a hydrophobic polymer block and a hydrophilic polymer block.8. The method according to claim 7 , further comprising a dispersant production step ...

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Номер записи: 69
18-07-2019 дата публикации

FOAMED THERMOPLASTIC MATERIAL, METHOD FOR THE MANUFACTURE THEREOF, ARTICLES PREPARED THEREFROM, AND ARTICLE-FORMING METHOD

Номер: US20190218356A1
Автор: MA Shuailei, Maddikeri Raghavendra Raj, Sheth Kapil Chandrakant, Yang Jian, Zhou Ji
Принадлежит: Sabic Global Technologies B.V.

A foamed thermoplastic material includes a thermoplastic material exhibiting, in its unfoamed state, a particular flammability index, flame growth rate, and specific extinction area. The foamed thermoplastic material further includes a plurality of cells having a number average mean diameter of 5 to 150 micrometers present in an amount effective to provide the foamed thermoplastic material with a density that is 10 to 90 percent of the density of the unfoamed thermoplastic material. The foamed thermoplastic material exhibits a desirable tensile elongation and dielectric constant. A process for forming the foamed thermoplastic material, articles including the foamed thermoplastic material, and an article-forming process are also described. 1. A foamed thermoplastic material comprising: [ a flammability index of 0.1 to 15, determined according to ASTM D7309 Method A at a heating rate of 1° C. per second under nitrogen from 25 to 750° C.;', {'sup': '2', 'a flame growth rate of 0.1 to 1.5 kW/ms, determined according to ASTM E1354 or ISO 5660 using an applied heat flux of 35 kilowatt per square meter;'}, 'a specific extinction area of 300 to 1200 square meters per kilogram, determined according to ASTM E1354 or ISO 5660 using an applied heat flux of 35 kilowatt per square meter;', 'a tensile elongation of greater than 100%, measured according to UL 1581 at a temperature of 23° C., using a coated wire test sample; and', 'a dielectric constant of 2 to 4, determined according to ASTM D150-11 at 1 MHz; and, 'in its unfoamed state,'}, a tensile elongation of 100 to 500%, measured according to UL 1581 at a temperature of 23° C., using a coated wire test sample; and', 'a dielectric constant of 1.4 to 4, determined according to ASTM D150-11 at 1 MHz; and, 'in its foamed state,'}], 'a thermoplastic material exhibiting,'}a plurality of cells having a number average mean diameter of 5 to 150 micrometers;wherein the cells are present in an amount effective to provide the foamed ...

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Номер записи: 70
09-07-2020 дата публикации

FILMS DERIVED FROM TWO OR MORE CHEMICALLY DISTINCT BLOCK COPOLYMERS, METHODS OF MAKING SAME, AND USES THEREOF

Номер: US20200216618A1
Автор: Li Yuk Mun, WIESNER Ulrich B., ZHANG Qi
Принадлежит:

Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers. 1. A blended film comprising at least two chemically distinct block copolymers , i) a surface layer having a thickness of 20 nm to 500 nm,', 'ii) a plurality of pores 5 nm to 100 nm in size,', {'sup': 14', '2, 'iii) a pore density of at least 1×10pores/m, and'}, 'iv) an asymmetric hierarchical substructure having a thickness of 5 microns to 500 microns and pores having a size of 5 nm to 100 microns., 'wherein the film comprises2. The blended film of claim 1 , wherein the at least two chemically distinct block copolymers are selected from the group consisting of diblock copolymers claim 1 , triblock terpolymers claim 1 , tetrablock copolymers and combinations thereof.3. The blended film of claim 1 , wherein at least one of the at least two chemically distinct block copolymers is a triblock terpolymer or at least two of the at least two structurally distinct block copolymers is a triblock terpolymer.4. The blended film of claim 1 , wherein the two ...

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Номер записи: 71
16-08-2018 дата публикации

Porous particle made of organic polymer, method for producing porous particle made of organic polymer, and block copolymer

Номер: US20180230284A1
Автор: Keita Sakakibara, Kyoko Konishi, Norio Ishizuka, Takaya Sato, Toshikazu Oda, Yoshinobu Tsujii
Принадлежит: Emaus Kyoto Inc, KYOTO UNIVERSITY, National Institute of Technology Japan

The present invention provides porous particles made of an organic polymer, uniform in shape, and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. The porous particles are made of an organic polymer. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle.

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Номер записи: 72
16-08-2018 дата публикации

Compositions based on acrylic block copolymer blends

Номер: US20180230303A1
Автор: David J. Yarusso, Thu-Van T. Tran
Принадлежит: 3M Innovative Properties Co

Described herein is a composition comprising a polymeric blend of: (i) a first polymer comprising at least one acrylic block copolymer, wherein the at least one acrylic block copolymer comprises: (a) at least two A block polymeric units wherein each A block has a glass transition temperature of at least 90 C and each A block is independently derived from a monoethylenically unsaturated monomer comprising a first (meth)acrylate monomer; and (b) at least one B block polymeric unit wherein the at least one B block has a glass transition temperature no greater than −30 C and wherein the at least one B block is derived from a monoethylenically unsaturated monomer comprising a second (meth)acrylate monomer; and (ii) a second polymer selected from at least one of a polyvinyl acetal resin, a polyvinyl acetate, and a cellulose ester.

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Номер записи: 73
26-08-2021 дата публикации

ARTICLES INCLUDING POLYESTER BACKING AND PRIMER LAYER AND RELATED METHODS

Номер: US20210260724A1
Автор: Batra Saurabh, Gao Yaohua, Koenig Amelia W., McLEAN Angela S., Priolo Morgan A., Sanocki Stephen M., Song Liming, Upadhye Aniruddha A., Yang Yu
Принадлежит:

An article () has a polyester film backing () and a primer layer () including a carboxylated styrene butadiene copolymer crosslinked with a polyfunctional aziridine disposed on a major surface of the polyester film backing (). Another article includes a polyester backing (), a primer layer () including a carboxylated styrene butadiene copolymer crosslinked with a polyfunctional aziridine disposed on a major surface of the polyester backing (), and a phenolic layer () disposed on the primer layer () on a surface opposite the polyester backing (). The phenolic layer () can include abrasive particles (). Processes for making the articles are also described, as well as methods for abrading a workpiece and improving adhesion between a polyester film backing () and a phenolic layer () on the polyester backing (). 1. An article comprising:a polyester film backing; anda primer layer comprising a carboxylated styrene butadiene copolymer crosslinked with a polyfunctional aziridine disposed on a major surface of the polyester film backing.2. The article of claim 1 , wherein the primer layer has a thickness of at least ten micrometers.3. The article of claim 1 , wherein the polyester film backing is surface-treated.4. The article of claim 1 , wherein the polyester film backing comprises polyethylene terephthalate.5. The article of claim 1 , further comprising a layer of phenolic disposed on the primer layer on a surface opposite the polyester film backing.6. The article of claim 5 , wherein the phenolic is rubber modified.7. The article of claim 5 , wherein the layer of phenolic further comprises abrasive particles.8. The article of claim 7 , further comprising a size layer disposed over the abrasive particles.9. A process for making the article of claim 1 , the process comprising:coating a composition comprising the carboxylated styrene butadiene copolymer and the polyfunctional aziridine onto the major surface of the polyester film backing; andcrosslinking the carboxylated ...

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Номер записи: 74
16-07-2020 дата публикации

MODIFIED ASPHALT AND PREPARATION METHOD THEREFOR

Номер: US20200223987A1
Автор: CHEN Fuda, CHEN Lijuan, LU Jianyuan, MO Guangliang, SU Guocheng, YU Jiangmiao
Принадлежит:

The modified asphalt provided by the disclosure is prepared from the following raw materials in parts by weight: 100 to 120 parts of asphalt, 6 to 20 parts of a modifier, 3 to 9 parts of a compatibilizer, 0.15 to 0.25 parts of sulfur, 0.4 to 0.6 parts of a non-amine anti-stripping agent and 0.2 to 0.4 parts of a coupling agent; and the modifier comprises a styrene-butadiene-styrene block copolymer, a rubber, and a polyurethane. The modified asphalt provided by the disclosure can simultaneously satisfy an elastic recovery at 25° C. of ≥98%, a dynamic viscosity at 60° C. of ≥500,000 Pa·s, a composite shear modulus at 60° C. of ≥10 Pa, and a critical temperature at W/Sin≥2.2 kPa of ≥94° C.

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Номер записи: 75
16-07-2020 дата публикации

LAMINATED OPTICAL FILM AND TOUCH PANEL

Номер: US20200223995A1
Автор: SUDEJI Hironari
Принадлежит: ZEON CORPORATION

An optical layered film includes at least one A layer including a thermoplastic resin [A] and a B layer formed of a thermoplastic resin [B], wherein the at least one A layer is provided on at least one of surfaces of the B layer, a thickness-direction retardation Rthb of the B layer satisfies the following formula (1), and a tensile elongation at break Sa of a 1.5 mm-thick film (a1) formed of the thermoplastic resin [A] satisfies the following formula (2): (1) |Rthb|≤40 nm, and (2) Sa≤100%. 1. An optical layered film comprising at least one A layer including a thermoplastic resin [A] and a B layer formed of a thermoplastic resin [B] , whereinthe at least one A layer is provided on at least one of surfaces of the B layer,a thickness-direction retardation Rthb of the B layer satisfies the following formula (1), and [{'br': None, 'i': 'Rthb|≤', '|40 nm, and\u2003\u2003(1)'}, {'br': None, 'i': 'Sa≥', '100%.\u2003\u2003(2)'}], 'a tensile elongation at break Sa of a 1.5 mm-thick film (a1) formed of the thermoplastic resin [A] satisfies the following formula (2)2. The optical layered film according to claim 1 , whereina modulus of elasticity in flexure Ea of a 4 mm-thick film (a2) formed of the thermoplastic resin [A] satisfies the following formula (3), and [{'br': None, 'i': 'Ea≤', '300 MPa≤900 MPa, and\u2003\u2003(3)'}, {'br': None, 'i': 'Eb≤', '2200 MPa≤2800 MPa.\u2003\u2003(4)'}], 'a modulus of elasticity in flexure Eb of a 4 mm-thick film (b) formed of the thermoplastic resin [B] satisfies the following formula (4)3. The optical layered film according to claim 1 , whereinthe thermoplastic resin [A] includes a hydrogenated product [2] of a block copolymer or an alkoxysilyl group-modified product [3] of the hydrogenated product [2] of the block copolymer,the hydrogenated product [2] of the block copolymer is a substance having a structure formed by hydrogenating the block copolymer [1],the block copolymer [1] includes two or more polymer blocks [C] per one molecule of ...

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Номер записи: 76
06-11-2014 дата публикации

Biaxially oriented polyamide-based resin film, and production method therefor

Номер: US20140329078A1
Автор: Gaku Maruyama, Takanori Ishikura, Yoshinori Miyaguchi
Принадлежит: Toyobo Co Ltd

To provide a biaxially oriented polyamide-based resin film being excellent in laminate strength, pin-hole resistance under a low-temperature environment, impact resistance, and transparency, and which retains satisfactory a good external appearance even after being sterilized in hot water. A biaxially oriented polyamide-based resin film comprising a polyamide resin and 1 to 5% by mass of a polyamide-based block copolymer, wherein the polyamide-based block copolymer comprises a hard part including a residue of cyclic lactam having 4 to 10 carbon atoms, and a soft part including a residue of polyoxypropylene glycol or polyoxytetramethylene glycol having a weight average molecular weight of 500 to 3000, and the content X of the hard part and the content Y and the weight average molecular weight Mw of the soft part satisfy the following formulae (1) and (2): X+Y =100 (parts by mass)   (1) 478.74×Mw −0.2989 ≦Y ≦93 (parts by mass)   (2).

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Номер записи: 77
25-08-2016 дата публикации

HYBRID TOPOGRAPHICAL AND CHEMICAL PRE-PATTERNS FOR DIRECTED SELF-ASSEMBLY OF BLOCK COPOLYMERS

Номер: US20160244581A1
Автор: Brink Markus, Cheng Joy, Doerk Gregory S., Friz Alexander M., Guillorn Michael A., Liu Chi-chun, Sanders Daniel P., Singh Gurpreet, TJIO Melia, Tsai Hsinyu
Принадлежит:

Hybrid pre-patterns were prepared for directed self-assembly of a given block copolymer capable of forming a lamellar domain pattern. The hybrid pre-patterns have top surfaces comprising independent elevated surfaces interspersed with adjacent recessed surfaces. The elevated surfaces are neutral wetting to the domains formed by self-assembly. Material below the elevated surfaces has greater etch-resistance than material below the recessed surfaces in a given etch process. Following other dimensional constraints of the hybrid pre-pattern described herein, a layer of the given block copolymer was formed on the hybrid pre-pattern. Self-assembly of the layer produced a lamellar domain pattern comprising self-aligned, unidirectional, perpendicularly oriented lamellae over the elevated surfaces, and parallel and/or perpendicularly oriented lamellae over recessed surfaces. The domain patterns displayed long range order along the major axis of the pre-pattern. The lamellar domain patterns are useful in forming transfer patterns comprising two-dimensional customized features. 1. A method , comprising: the SA material is capable of self-assembling to form a phase separated lamellar domain pattern having a characteristic pitch Lo,', 'the pre-pattern is disposed on a substrate,', 'the top surface of the pre-pattern has a geometrical major axis,', 'the top surface of the pre-pattern comprises a) independent elevated surfaces interspersed with adjacent recessed surfaces and b) sidewalls joining elevated surfaces to recessed surfaces,', 'material underlying the elevated surfaces of the pre-pattern has greater etch-resistance in a given etch process compared to material underlying the recessed surfaces of the pre-pattern,', {'sub': 'E', 'a given elevated surface has width Wdefined as the length of the given elevated surface in a direction perpendicular to the major axis,'}, {'sub': 'R', 'a given recessed surface has width Wdefined as the length of the recessed surface in a ...

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Номер записи: 78
23-08-2018 дата публикации

Hydrogenated Block Copolymer and Polypropylene-Based Resin Composition Using the Same and Molded Article Thereof

Номер: US20180237556A1
Автор: Ichino Hiroyuki, Kusanose Yasuhiro, Yamamoto Masashi
Принадлежит: ASAHI KASEI KABUSHIKI KAISHA

The present invention provides a hydrogenated block copolymer: having a polymer block (S) containing an aromatic vinyl compound unit as a main constituent; and a polymer block (B) containing a conjugated diene compound unit as a main constituent, in a molecule. 3. The hydrogenated block copolymer according to claim 1 , wherein the structure represented by Formula (1) has the polymer block (S) claim 1 , the polymer block (B1) and the polymer block (B2) in this order.4. The hydrogenated block copolymer according to claim 1 , wherein the amount of the vinyl bond of the polymer block (B1) before hydrogenation is 40 to 60 mol %.5. The hydrogenated block copolymer according to claim 1 , wherein the content of the structure represented by Formula (1) is 50 to 85% by mass.6. A polypropylene-based resin composition comprising: 10 to 90% by mass of the hydrogenated block copolymer according to ; and 10 to 90% by mass of a polypropylene-based resin.7. The polypropylene-based resin composition according to claim 6 , wherein the polypropylene-based resin is a random polypropylene.8. A molded article comprising the polypropylene-based resin composition according to .9. A sheet comprising the polypropylene-based resin composition according to . The present invention relates to a hydrogenated block copolymer and a polypropylene-based resin composition using the same and a molded article thereof.A polypropylene-based resin composition is generally excellent in chemical resistance and mechanical properties and thus used in a wide variety of fields including packaging materials, mechanical parts and car parts. Recently, in order to satisfy the needs for overcoming environmental problems, development of halogen-free transparent polymer materials has been accelerated. Particularly in the fields including sheets, films and tubes, a polypropylene-based resin composition is used and a request for making a polypropylene-based resin composition soft and/or transparent to meet various uses ...

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Номер записи: 79
24-08-2017 дата публикации

BLENDS OF STYRENE-BUTADIENE COPOLYMERS

Номер: US20170240740A1
Автор: COCHRAN Thomas W., Hamilton Michael, Knoll Konrad, Niessner Norbert
Принадлежит:

Polymer blend comprising 95 to 100% of a component A) and 0 to 5% of additives, where A) is consisting of polymers A ) to A4): A ) 50 to 75% of a star shaped block copolymer A which comprises at least 2 terminal vinylaromatic hard blocks S and diene soft blocks B, where the proportion of the hard blocks S is from 65 to 90%, and Mn of block S is 35000 to 200000; A2) 5 to 15% of block copolymer A2 which comprises 2 terminal vinylaromatic hard blocks S1 and S2 and random copolymer blocks (B/S) consisting of 20 to 60% vinylaromatic monomers, and 80 to 40% dienes where the proportion of blocks S1 and S2 is 40 to 60%; and Mn of blocks S1 is 35000 to 200000, and Mn of blocks S2 is 5000 to 30000 and the molar S1/S2 ratio is 1:0.5 to 1:10; A3) 3 to 10% of an block copolymer A3 built up from vinylaromatic hard blocks S and from random soft blocks B/S consisting of 60 to 30% vinylaromatic monomers and 40 to 70% dienes, where the diene content is less than 50% and the proportion of the soft phase is at least 60%; and A4) 10 to 35% polystyrene A4; whereby the ratio of A ) to A2) to A3) is from 7 : [1.2 to 1.9] : [0.5 to 12], have particular mechanical properties. 117-. (canceled)18. A polymer blend comprising the components: A1) 50 to 70% by weight of at least one star shaped block copolymer A1 which comprises at least 2 terminal hard blocks S consisting of vinylaromatic monomers, and comprises one or more soft blocks B in each case consisting of 98 to 100% by weight of diene, and from 0 to 2% by weight of vinyl aromatic monomers, where the proportion by weight of the hard blocks S in the block copolymer A1 is from 65 to 90% by weight and the number-average molecular weight Mn of at least one block S is in the range from 35000 to 200000 g/mol;', 'A3) 3 to 10% by weight of at least one elastomeric star-shaped or linear block copolymer A3 which has been built up from hard blocks S made from vinylaromatic monomers, and from one or more random soft blocks B/S consisting of from 60 ...

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Номер записи: 80
23-07-2020 дата публикации

PHASE STABLE POLYMER-ASPHALT COMPOSITIONS

Номер: US20200231816A1
Автор: McKibben Lauren F., Moran Lyle E., Noel John A.
Принадлежит:

Phase stable compositions of styrenic block copolymers (SBC) and high asphaltene content asphalts and methods for their preparation are provided. In particular the styrenic block copolymer is a styrene-conjugated diene-styrene block copolymer such as styrene-butadiene-styrene (SBS) and phase stability is achieved through addition of low levels of sulfur based crosslinkers. The compositions find use in, for example, the manufacture of roofing membranes. 1. A phase stable polymer-asphalt composition , said composition comprising one or more styrenic block copolymers , one or more asphalts , and one or more crosslinking agents , wherein the one or more asphalts has a total asphaltene content of greater than or equal to about 12% by weight.2. A phase stable polymer-asphalt composition according to claim 1 , wherein the phase stable polymer-asphalt composition comprises 75 to 99% by weight of one or more asphalts claim 1 , 1 to 20% by weight of one or more styrenic block copolymers and about 0.01 to about 1.0% by weight of one or more cross-linking agents.3. A phase stable polymer-asphalt composition according to claim 1 , wherein the crosslinking agent is present in an amount from about 0.01 to about 0.5% by weight based on the total weight of the composition.4. A phase stable polymer-asphalt composition according to claim 1 , wherein the total asphaltene content of the one or more asphalts is greater than or equal to about 15% by weight.5. A phase stable polymer-asphalt composition according to claim 1 , wherein the total asphaltene content of the one or more asphalts is from about 12% by weight to about 25% by weight.6. A phase stable polymer-asphalt composition according to claim 1 , wherein the composition comprises from about 2% to about 15% by weight of the one or more styrenic block copolymers.7. A phase stable polymer-asphalt composition according to claim 6 , wherein the styrenic block copolymer (SBC) is selected from the group consisting of linear SBC claim 6 ...

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Номер записи: 81
08-09-2016 дата публикации

PRIMERLESS PAINT COMPOSITION, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME

Номер: US20160257836A1
Автор: Han Tao, Yang Hong, Yu Haiyang
Принадлежит:

Disclosed herein is a primerless paint composition comprising a carboxylated chlorinated polyolefin elastomer; one or more of a polyacrylic binder, a polyvinylchloride binder and a vinyl aromatic block copolymer binder; a pigment; and a liquid carrier. Disclosed herein too is a method comprising blending a primerless paint composition comprising a carboxylated chlorinated polyolefin elastomer; one or more of a polyacrylic binder, polyvinylchloride binder and a vinyl aromatic block copolymer binder; a pigment; and a liquid carrier; and disposing the primerless paint composition on a polyolefin elastomer substrate that does not have a primer disposed on it prior to the disposing of the primerless paint composition. 1. A primerless paint composition comprising:a carboxylated chlorinated polyolefin elastomer;one or more of a polyacrylic binder, a polyvinylchloride binder and a vinyl aromatic block copolymer binder;a pigment; anda liquid carrier.2. The paint composition of claim 1 , where the carboxylated chlorinated polyolefin elastomer is a maleic anhydride modified chlorinated polyolefin copolymer.3. The paint composition of claim 1 , where the carboxylated chlorinated polyolefin elastomer comprises an ethylene-α-olefin random interpolymer claim 1 , a ethylene-α-olefin block interpolymer claim 1 , homogenous polypropylene and propylene-α-olefin random interpolymers claim 1 , block interpolymers claim 1 , or a combination thereof.4. The paint composition of claim 1 , where the carboxylated chlorinated polyolefin elastomer comprises a linear polymer or a crosslinked polymer and has an elastic modulus of less than 100 megapascals.5. The paint composition of claim 1 , where the carboxylated chlorinated polyolefin elastomer comprises a carboxylating monomer in an amount of 0.1 to 25 wt % claim 1 , based on a total weight of the carboxylated chlorinated polyolefin elastomer.6. The paint composition of claim 1 , where the carboxylated chlorinated polyolefin elastomer ...

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Номер записи: 82
30-07-2020 дата публикации

POROUS MATERIALS FROM COMPLEX BLOCK COPOLYMER ARCHITECTURES

Номер: US20200238227A1
Автор: Dorin Rachel Mika, Robbins Spencer William
Принадлежит: TeraPore Technologies, Inc.

Self-assembled porous block copolymer materials with a complex block copolymer architecture, methods of preparing, uses for separation and detection, and devices for using as such. The porous materials contain at least one of macro, meso, or micro pores, at least some of which are isoporous, and include at least one block copolymer with at least two chemically distinct blocks, which further comprises a complex architecture such as: multiple distinct monomers in or between blocks, branching, crosslinking, or ring architectures. 1. A self-assembled polymer material containing at least one of macro , meso , or micro pores , at least some of which are isoporous , comprising a block copolymer or block copolymers (BCPs) , with at least two chemically distinct blocks , which further comprises a complex architecture.2. The material of wherein at least a portion of the material is a block copolymer containing more than one monomer/chemistry/configuration/structure/composition in at least one block or adjacent to at least one block.3. The material of wherein at least a portion of the material is a diblock copolymer claim 1 , triblock copolymer claim 1 , or higher order (i.e. tetrablock claim 1 , pentablock claim 1 , etc.) with more than one monomer/chemistry/configuration/structure/composition in at least one block or adjacent to at least one block.4. The material of claim 1 , wherein the material has mesopores comprising a diameter of about 1 nm to about 200 nm.5. The material of claim 1 , wherein at least one block copolymer has an Mof about 1×10to about 1×10g/mol.6. The material of claim 1 , wherein at least one block copolymer has a PDI of 1.0 to 3.0.7. The material of of claim 1 , wherein at least one block of the BCP has at least one of the following properties:{'sub': 'g', 'a. Low T(25° C. or less)'}{'sub': 'g', 'b. High T(more than 25° C.)'}c. Hydrophilicd. Hydrophobice. Chemically resistantf. Chemically responsiveg. Chemically functional8. The material of wherein at ...

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Номер записи: 83
30-07-2020 дата публикации

Biaxially oriented porous film having a particles-containing porous layer and an inorganic coating

Номер: US20200238672A1
Автор: Bertram Schmitz, Melanie WISNIEWSKI
Принадлежит: Treofan Germany GmbH and Co KG

The invention relates to a biaxially oriented, single- or multi-layer porous film, containing a β-nucleating agent and comprising at least one porous layer, which contains at least one propylene polymer and particles, said particles having a melting point of more than 200° C. On the outer surface of the porous layer, said porous film has a coating of inorganic, preferably ceramic particles.

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Номер записи: 84
30-07-2020 дата публикации

IMPROVED ADHESION OF POLYOLEFINS TO POLYESTERS

Номер: US20200239672A1
Автор: Kay Christopher, Morris Shaun, Scott Peter, Waddington Simon
Принадлежит:

The use of a block copolymer of the following structure. Wherein R and Rmay be the same or different and each independently represents an alkyl or aryl group, X may be hydrogen or Cto Calkyl group which may be branched or linear and wherein the aromatic ring substituent joined to polymer B is positioned meta or para to the aromatic ring substituent joined to polymer A and, wherein polymer A is a polymer (or copolymer) of ethylene and polymer B is a polymer of monomers selected from vinyl acetate, C-Cacrylate esters, acrylic acid and mixtures thereof as an additive in polyethylene or polyethylene terephthalate to improve the adhesion between co-extruded layers of the polyethylene and the polyethylene terephthalate and laminated films derived from such use. 226-. (canceled)28. The polyethylene or polyethylene terephthalate according to claim 27 , wherein each R and Rgroup independently represents an alkyl group having from 1 to 4 carbon atoms.29. The polyethylene or polyethylene terephthalate according to claim 27 , wherein the aromatic ring substituent joined to polymer B is positioned meta to the aromatic ring substituent joined to polymer A.30. The polyethylene or polyethylene terephthalate according to claim 27 , wherein block A of the block copolymers is produced by the metallocene catalyzed polymerization of ethylene optionally together with other alkene-1 compounds.31. The polyethylene or polyethylene terephthalate according to claim 27 , wherein block A has a number average molecular weight (Mn) in the range 1000 to 10 claim 27 ,000.32. The polyethylene or polyethylene terephthalate according to claim 27 , wherein block B is produced by the free radical catalyst polymerization of vinyl acetate.33. The polyethylene or polyethylene terephthalate according to claim 27 , wherein block B has a molecular weight (Mn) in the range of 1000 to 20 claim 27 ,000 claim 27 , preferably in the range 3000 to 6000.35. The laminate according to claim 34 , wherein the inherent ...

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Номер записи: 85
06-09-2018 дата публикации

Polyolefin Resin Foam Particles, Foam-Particle Moulded Body, And Composite Stacked Body Including Said Moulded Body

Номер: US20180251619A1
Автор: OIKAWA Masaharu, SHINOHARA Mitsuru
Принадлежит:

The present invention relates to polyolefin resin expanded beads containing multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer, the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin, and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10, and a composite laminated body using an expanded beads molded body thereof, and the expanded beads molded body is excellent in solvent resistance and also excellent in adhesiveness to a thermosetting resin on the surface of the molded body, and can provide a composite laminated body excellent in productivity with a thermosetting resin. 1. A method for producing a composite laminated body comprising:laminating a thermosetting resin on a surface of a polyolefin expanded beads molded body obtained through in-mold molding, andcuring the thermosetting resin layer adhered and laminated on the surface of the polyolefin expanded beads molded body,wherein the expanded beads comprise multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer, the core layer consisting essentially of a polypropylene resin, the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin, and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10.2. The method of claim 1 , wherein a melting point (Ts) of the polyolefin resin (A) contained in the cover layer is lower than a melting point (Tc) of the polyolefin resin contained in the core layer.3. The method of claim 1 , wherein the mixed resin contained in the cover layer further contains a compatibilizing agent of the polyolefin resin (A) and ...

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Номер записи: 86
13-09-2018 дата публикации

Composition and formed article

Номер: US20180258239A1
Автор: Akihiko Ookubo, Masahiro Shibata, Shuugo MAEDA
Принадлежит: JSR Corp

Provided is a composition capable of providing a formed article that, even when using continuous fibers, has excellent interfacial adhesion between the continuous fibers and a matrix resin, and as a result, has excellent mechanical strength (e.g., impact resistance and flexural strength). One aspect of a composition according to the present invention includes a polymer (A) including an amino group, fibers (B), and a thermoplastic resin (C), in which a content ratio of the fibers (B) is 70 parts by mass or more and 250 parts by mass or less based on 100 parts by mass of the thermoplastic resin (C). Another aspect of the composition according to the present invention includes a polymer (A) including an amino group, a non-woven fabric (B′), and a thermoplastic resin (C).

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Номер записи: 87
13-09-2018 дата публикации

CYCLIC OLEFIN-BASED RESIN COMPOSITION FILM

Номер: US20180258273A1
Автор: HIRATA Kazuki, HORII Akihiro, HOSOYA Ken, ISHIMORI Taku, Obata Kei, Sugata Hiroshi
Принадлежит: DEXERIALS CORPORATION

A cyclic olefin resin composition film having high toughness with less difference in toughness between length and width directions. The cyclic olefin resin composition film contains a cyclic olefin resin, a styrene elastomer and inorganic oxide fine particles having an average particle diameter of 40 nm or smaller, and has a linear expansion coefficient of 40 ppm/° C. to 60 ppm/° C. This film attains high toughness with less difference in toughness between length and width directions. 1. A cyclic olefin resin composition film , comprising:a cyclic olefin resin;a styrene elastomer; andinorganic oxide fine particles having an average particle diameter of 40 nm or smaller,the cyclic olefin resin composition film having a linear expansion coefficient of 40 ppm/° C. to 60 ppm/° C.2. The cyclic olefin resin composition film according to claim 1 , wherein the cyclic olefin resin composition film has a tensile modulus of 1500 MPa to 2000 MPa.3. The cyclic olefin resin composition film according to claim 1 , wherein the styrene elastomer has a styrene content of 20 mol % or more.4. The cyclic olefin resin composition film according to claim 1 , wherein the average particle diameter of the inorganic oxide fine particles is 15 nm or smaller.5. The cyclic olefin resin composition film according to claim 1 , wherein the cyclic olefin resin is an addition copolymer of ethylene and norbornene.6. The cyclic olefin resin composition film according to claim 1 , wherein the styrene elastomer is at least one kind selected from the group consisting of styrene/ethylene/butylene/styrene block copolymers claim 1 , styrene/ethylene/propylene/styrene block copolymers and hydrogenated styrene/butadiene copolymers.7. A transparent conductive element comprising the cyclic olefin resin composition film according to as a substrate.8. An input device comprising the cyclic olefin resin composition film according to .9. A display device comprising the cyclic olefin resin composition film according ...

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Номер записи: 88
21-09-2017 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20170267845A1
Автор: Baghdadi Hossein A.
Принадлежит:

Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

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Номер записи: 89
21-09-2017 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20170267847A1
Автор: Baghdadi Hossein A.
Принадлежит:

Articles of footwear and component for articles of footwear and athletic equipment are provided including a foam. A variety components and articles of footwear containing the components are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the components and articles of footwear are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

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Номер записи: 90
21-09-2017 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20170267848A1
Автор: Baghdadi Hossein A.
Принадлежит:

Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

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Номер записи: 91
21-09-2017 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20170267850A1
Автор: Baghdadi Hossein A.
Принадлежит:

Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

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Номер записи: 92
20-09-2018 дата публикации

EXTRUDED STYRENE RESIN FOAM AND METHOD FOR PRODUCING SAME

Номер: US20180265661A1
Автор: Kikuchi Takenori, Kurihara Shunji, Shimizu Koji
Принадлежит: KANEKA CORPORATION

A styrene resin extruded foam includes a styrene resin, a flame retarder, a hydrofluoroolefin, an alcohol, and at least one selected from the group consisting of a saturated hydrocarbon having 3 to 5 carbon atoms, dimethyl ether, and alkyl chloride. An amount of the flame retarder is 0.5 to 8.0 parts by weight relative to 100 parts by weight of the styrene resin. The styrene resin extruded foam has an apparent density of 20 to 45 kg/mand a closed cell ratio of not less than 90%. An amount of the hydrofluoroolefin added is 65 to 90 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added. An amount of the alcohol added is 10 to 35 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added. 1. A styrene resin extruded foam , comprising:a styrene resin;a flame retarder;a hydrofluoroolefin;an alcohol; andat least one selected from the group consisting of a saturated hydrocarbon having 3 to 5 carbon atoms, dimethyl ether, and alkyl chloride,wherein an amount of the flame retarder is 0.5 to 8.0 parts by weight relative to 100 parts by weight of the styrene resin,{'sup': '3', 'wherein the styrene resin extruded foam has an apparent density of 20 to 45 kg/mand a closed cell ratio of not less than 90%,'}wherein an amount of the hydrofluoroolefin added is 65 to 90 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added, andwherein an amount of the alcohol added is 10 to 35 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added.2. The styrene resin extruded foam according to claim 1 , wherein an amount of the hydrofluoroolefin added to 100 parts by weight of the styrene resin is 3.0 to 14.0 parts by weight.3. The styrene resin extruded foam according to claim 1 , further comprising 1.0 to 5.0 parts by weight of graphite relative to 100 parts by weight of the styrene resin.4. The styrene resin extruded foam according to claim 1 , ...

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Номер записи: 93
04-11-2021 дата публикации

HIGH-ELASTICITY EXTRUDED FOAM COMPOSITION

Номер: US20210340348A1
Автор: LEE Soo Jung
Принадлежит:

Provided is a composition for a highly elastic extruded foam. The composition includes a peroxide-crosslinkable thermoplastic polymer, an organic peroxide, thermo-expandable microspheres, and a silane coupling agent. 1. A composition for a highly elastic extruded foam , comprising a peroxide-crosslinkable thermoplastic polymer , an organic peroxide , thermo-expandable microspheres , and a silane coupling agent.2. The composition according to claim 1 , wherein the peroxide-crosslinkable thermoplastic polymer is selected from the group consisting of ethylene-based polymers claim 1 , chlorinated polyethylene claim 1 , ethylene-propylene rubbers claim 1 , thermoplastic elastomers claim 1 , and mixtures thereof.3. The composition according to claim 2 , wherein the ethylene-based polymer is an ethylene homopolymer or ethylene copolymer.4. The composition according to claim 2 , wherein the ethylene-propylene rubber is an EPM rubber or EPDM rubber.5. The composition according to claim 2 , wherein the thermoplastic elastomer is selected from the group consisting of styrene-butadiene-styrene (SBS) block copolymers claim 2 , styrene-isoprene-styrene (SIS) block copolymers claim 2 , styrene-ethylene-butadiene-styrene (SEBS) block copolymers claim 2 , styrene-butylene-butadiene-styrene (SBBS) block copolymers claim 2 , and styrene-ethylene-propylene-styrene (SEPS) block copolymers claim 2 , 1 claim 2 ,2-polybutadiene (1 claim 2 ,2-PB) claim 2 , thermoplastic polyolefin (TPO) claim 2 , thermoplastic vulcanizates (TPVs) claim 2 , and mixtures thereof.6. The composition according to claim 1 , wherein the expansion start temperature (T) of the thermo-expandable microspheres is equal to or lower than the 1 minute half-life temperature of the organic peroxide crosslinking agent.7. The composition according to claim 1 , wherein the content of the thermo-expandable microspheres is 0.5 to 20 parts by weight claim 1 , based on 100 parts by weight of the peroxide-crosslinkable ...

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Номер записи: 94
29-09-2016 дата публикации

BITUMEN/POLYMER COMPOSITION HAVING IMPROVED LOW-TEMPERATURE MECHANICAL PROPERTIES

Номер: US20160280919A1
Автор: BOTEL Romuald, Chaminand Julien, DRIDI Nour, MOUAZEN Mouhamad, RUOT Carole
Принадлежит: TOTAL MARKETING SERVICES

The invention relates to a bitumen/polymer composition and to its process of manufacture. The bitumen/polymer composition includes first bitumen base having an intrinsic stability S of greater than 2.5 and/or a degree of peptization Sof greater than 0.60, and a second bitumen base having an intrinsic stability S of less than or equal to 2.50 and/or a degree of peptization Sof less than or equal to 0.60, an elastomer and an olefinic polymer adjuvant functionalized by at least glycidyl functional groups. The values of intrinsic stability S and of the degree of peptization Sare measured according to the standard ASTM D 7157-12. The bitumen/polymer composition exhibits improved low-temperature mechanical properties. 124-. (canceled)27. The composition as claimed in claim 25 , wherein the percentage by weight of the second bitumen base claim 25 , with respect to the total weight of said composition claim 25 , is less than or equal to 50%.28. The composition as claimed in claim 25 , wherein the percentage by weight of the second bitumen base claim 25 , with respect to the total weight of said composition claim 25 , is between 25% and 40%.29. The composition as claimed in claim 25 , wherein the first bitumen base is chosen from residues from the direct distillation of oil claim 25 , and residues from the vacuum distillation of oil.30. The composition as claimed in claim 29 , wherein said residues have been blown claim 29 , or deasphalted claim 29 , or blown and desasphalted.31. The composition as claimed in claim 29 , wherein the first bitumen base is chosen from the residues (VR) from the vacuum distillation of the atmospheric residues originating from the direct distillation of oil.32. The composition as claimed in claim 25 , wherein the second bitumen base is chosen from the products resulting from the visbreaking of vacuum distillation residues (visbroken VR) claim 25 , said vacuum distillation residues (VR) originating from the vacuum distillation of atmospheric ...

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Номер записи: 95
29-08-2019 дата публикации

Improved Expandable Vinyl Aromatic Polymers

Номер: US20190263991A1
Автор: Cassart Michel, Deleye Jean-Claude, Iacolina Amelio, Michel Jacques, Urbanczyk Laetitia, VACHAUDEZ Magali
Принадлежит:

The present invention is related to expandable vinyl aromatic polymers comprising from 1 to 10% by weight of homogeneously dispersed coke particles having a volume median particle diameter (D50) comprised between 0.5 and 8.5 μm and from 0.1 to 5% by weight of a halogenated block copolymer. The invention further is related to a method for producing said expandable vinyl aromatic polymers and to the expanded foams. 115.-. (canceled)16. An expandable vinyl aromatic polymer comprising:from 1% to 10% by weight of dispersed coke particles having a volume median particle diameter (D50) comprised between 0.5 and 8.5 μm as obtained from laser light scattering measurements according to ISO 13320 using MEK as solvent for vinyl aromatic polymers; 'from 0.1 to 5.0 by weight of a halogenated block copolymer, characterized by a weight average molecular weight comprised between 20 and 300 kDa as determined by gel permeation chromatography against polystyrene standards and comprising:', 'from 2 to 10% by weight of a C3-C6 alkane;'}from 20 to 60% by weight of sequences (A) of polymerized monovinyl arenes and from 40 to 80% by weight of sequences (B) of polymerized conjugated alkadienes or copolymerized conjugated alkadienes and monovinyl arenes; andfrom 20 to 80% by weight of halogen substituents.17. The expandable vinyl aromatic polymer according to additionally comprising from 0.01 to 1.0% by weight of high density polyethylene as cell regulator.18. The expandable vinyl aromatic polymer according to wherein the polyethylene is characterized by a weight average molecular weight (Mw) comprised between 1.5 and 10 kDa and with a polydispersity of 3 or less as determined by gel permeation chromatography (GPC) in tetrahydrofuran using polystyrene standards.19. The expandable vinyl aromatic polymers according to wherein the polyethylene is characterized by a homogeneous crystallization temperature (T) comprised between 50 and 100 C as determined by DSC claim 17 , according to ASTM D3418 ...

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Номер записи: 96
20-08-2020 дата публикации

DAMPING THERMOPLASTIC OLEFIN ELASTOMERS

Номер: US20200263014A1
Автор: GU Jiren
Принадлежит: POLYONE CORPORATION

A thermoplastic elastomer compound includes polyolefin elastomer, high softening point tackifier, and, optionally, styrenic block copolymer. When styrenic block copolymer is present, the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 1:1. The polyolefin elastomer has a POE Tan Delta Peak Temperature, the styrenic block copolymer has a SBC Tan Delta Peak Temperature, and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the POE Tan Delta Peak Temperature. When styrenic block copolymer is present, Compound Tan Delta Peak Temperature is also greater than the SBC Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature and can be formed into plastic articles, including foamed plastic articles and/or crosslinked plastic articles, which can be useful for a variety of damping applications. 1. A thermoplastic elastomer compound comprising:(a) polyolefin elastomer having a POE Tan Delta Peak Temperature;(b) tackifier having a softening point of at least about 80° C. according to ASTM 6493; and(c) optionally, styrenic block copolymer having a SBC Tan Delta Peak Temperature, provided that, when the styrenic block copolymer is present, the polyolefin elastomer is present relative to the styrenic block copolymer at a weight ratio of no less than about 1:1;wherein the compound has a Compound Tan Delta Peak Temperature, and the Compound Tan Delta Peak Temperature is greater than the POE Tan Delta Peak Temperature;wherein, when the styrenic block copolymer is present, the Compound Tan Delta Peak Temperature is greater than the SBC Tan Delta Peak Temperature.2. The compound of claim 1 , wherein the styrenic block copolymer is present claim 1 , and wherein the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 3:1.3. The compound of claim 1 , wherein the ...

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Номер записи: 97
05-09-2019 дата публикации

LATENT ELASTIC OLEFIN FILM LAMINATES AND METHODS OF MAKING ABSORBENT ARTICLES INCORPORATING THE SAME

Номер: US20190270877A1
Автор: Barnes Craig A., Boggs Lavada C., Bouchard Isabelle R., Fitts, Hesse Daniel W., Jenkins Shawn E., JR. James R., Zimmerman Lauren E.
Принадлежит:

A latent elastic film laminate is provided including a film predominantly comprising olefin elastomers. The film is stretched and maintained in a stretched state in order to impart the desired level of latent elasticity such that the conditioned film laminate will shrink upon activation, such as by heating. The latent elastic film laminate can be advantageously used in the manufacture of various elasticated articles, including absorbent personal care articles, by activating the latent elasticity after attachment to the article and thereby shining and elasticizing components to which the film laminate is attached. 1. A heat shrinkable composite material comprising:an elastic film having a polymeric portion and wherein the polymeric portion comprises at least 90% semi-crystalline polyolefin polymer;a support layer intermittently bonded to said elastic film;wherein the composite material has a % heat shrinkage greater than 15% at 72° C.2. The heat shrinkable composite material of wherein the polymeric portion of the elastic film comprises at least 95% by wt. semi-crystalline polyolefin polymer.3. The heat shrinkable composite material of wherein the semi-crystalline polyolefin polymer comprises a blend of an ethylene semi-crystalline polymer having a density between about 0.85 g/cmand 0.89 g/cmand a propylene semi-crystalline polymer having a density between about 0.85 g/cmand 0.89 g/cm.4. The heat shrinkable composite material of wherein the ethylene semi-crystalline polymer comprises about 80% to 99% of the polymeric portion of the film and the propylene semi-crystalline polymer comprises about 20% to 1% by wt. of the polymeric portion of the film.5. The heat shrinkable composite material of wherein the propylene semi-crystalline polymer comprises about 80% to 99% of the polymeric portion of the film and the ethylene semi-crystalline polymer comprises about 20% to about 1% by wt. of the polymeric portion of the film.6. The heat shrinkable composite material of any of ...

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Номер записи: 98
04-10-2018 дата публикации

High Melt Flow Thermoplastic Polyolefins with Modifier

Номер: US20180282533A1
Автор: Hu Yushan, Jones Mary Ann, Munro Jeffrey C., Walton Kim L.
Принадлежит: Dow Global Technologies LLC

Embodiments relate to a high melt flow thermoplastic polyolefin composition and of a method of preparing a high melt flow thermoplastic polyolefin composition, in which the composition includes from 5 wt % to 45 wt % of a modifier including a blend of from 5 wt % to 40 wt % of a block composite and from 60 wt % to 95 wt % of a polyolefin copolymer, based on a total weight of the modifier, and from 30 wt % to 95 wt % of a polypropylene polymer base that has a melt flow rate of at least 40 g/10 min. The high melt flow thermoplastic polyolefin composition has a blended melt flow rate of at least 25 g/10 min and an MFR ratio is less than 2.0, the MFR ratio being a ratio of the melt flow rate of the polypropylene polymer base to the blended melt flow rate of the high melt flow thermoplastic polyolefin composition. 1. A high melt flow thermoplastic polyolefin composition , comprising: (a) from 5 wt % to 40 wt % of a block composite, based on a total weight of the modifier, the block composite including (i) an ethylene-propylene copolymer, (ii) an isotactic polypropylene polymer, and (iii) a block copolymer including an ethylene-propylene soft block that has essentially a same composition as the ethylene-propylene polymer and an isotactic polypropylene hard block that has essentially a same composition as the isotactic polypropylene polymer, the soft block comprising from 20 wt % to 80 wt % of ethylene based on a total weight of the soft block, and the block copolymer including from 20 wt % to 75 wt % of the hard block, based on the total weight of the block copolymer, and', {'sub': 3', '10, 'sup': 3', '3, '(b) from 60 wt % to 95 wt % of a polyolefin copolymer, based on a total weight of the modifier, the polyolefin copolymer being derived from ethylene and at least one of a Cto Calpha-olefin, and the polyolefin copolymer having a melt index from 10 g/10 min to 1500 g/10 min, according to ASTM D1238 and at 190° C./2.16 kg, and a density from 0.850 g/cmto 0.900 g/cm, and ...

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Номер записи: 99
25-12-2014 дата публикации

Foam Composition with Olefin Block Copolymer Gel Particles

Номер: US20140378566A1
Автор: Aou Kaoru, Gamboa Rogelio R., JR. Raymond L., Laakso, Marchand Gary R., Munro Jeffrey C.
Принадлежит:

The present disclosure is directed to a composition and articles containing the composition. The composition comprises a foam and a plurality of gel particles dispersed in the foam. The gel particles comprise an olefin block copolymer and an oil. 1. A composition comprising:a foam selected from the group consisting of a polyurethane foam, a latex foam, a polystyrene foam, an epoxy foam, a polyvinyl foam and combinations thereof; anda plurality of gel particles having a D50 particle size from 50 microns to 1500 microns dispersed in the foam, the gel particles comprising an olefin block copolymer and an oil.2. (canceled)3. The composition of wherein the foam is a viscoelastic polyurethane foam.4. The composition of wherein the oil is selected from the group consisting of an aromatic oil claim 1 , a naphthenic oil claim 1 , paraffinic oil claim 1 , a mineral oil claim 1 , and combinations thereof.5. The composition of wherein the gel particles comprise from 30 wt % to 70 wt % olefin block copolymer and from 70 wt % to 30 wt % oil.6. (canceled)7. The composition of wherein the olefin block copolymer is an ethylene/octene multi-block copolymer.8. The composition of comprising a viscoelastic foam and gel particles comprising ethylene/octene multi-block copolymer with a soft segment comprising from 10 mol % to 35 mol % units derived from octene.9. The composition of wherein the composition has a support factor from 2.0 to 3.5.10. An article comprising:a composition comprising a foam and a plurality of gel particles dispersed in the foam;the foam selected from the group consisting of a polyurethane foam, a latex foam, a polystyrene foam an epoxy foam, a polyvinyl foam, and combinations thereof; andthe gel particles having a D50 particle size from 50 microns to 1500 microns and comprising an olefin block copolymer and an oil. The present disclosure is directed to compositions composed of foam with gel particles dispersed therein and articles containing same.Known are ...

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Номер записи: 100