27-08-2020 дата публикации
Номер: US20200270506A1
This invention relates to water-soluble or water-swellable polymers, containing a) 25-35 mol. % of one or more recurrent structural units of formula (1), where Rand Rrepresent hydrogen, methyl or ethyl, A represents a linear or branched C-C-alkylene, and Qstands for NH, Li, Na, K, ½ Ca, ½ Mg, ½ Zn, ⅓ Al, or organic ammonium ions of the formula [HNRRR], b) 3 to 8 mol. % of one or more recurrent structural units of formula (2), where Rrepresents hydrogen, methyl, or ethyl, Xstands for H, NH, Li, Na, K, ½ Ca, ½ Mg, ½ Zn, ⅓ Al, or organic ammonium ions of the formula [HNRRR], B is a linear or branched alkylene group with 1 to 6 carbon atoms, and n is a whole number between 0 and 5, and c) 57 to 72 mol. % of a (meth)acrylamide. 124-. (canceled)26. The method as claimed in claim 25 , wherein the structural units of the formula (1) are derived from monomers from the group consisting of acryloyldimethyltaurate claim 25 , acryloyl-1 claim 25 ,1-dimethyl-2-methyltaurate claim 25 , acryloyltaurate claim 25 , acryloyl-N-methyltaurate.27. The method as claimed in claim 25 , wherein the structural units of the formula (2) are derived from methacrylic acid claim 25 , acrylic acid claim 25 , carboxyethyl acrylate or higher oligomers of the formula (2) in which n is an integer of 2 or more.28. The method as claimed in claim 25 , wherein the structural units of the formula (3) are derived from acrylamide claim 25 , N-methylacrylamide claim 25 , N-ethylacrylamide claim 25 , N claim 25 ,N-diethylmethacrylamide claim 25 , N claim 25 ,N-diethylacrylamide claim 25 , N claim 25 ,N--dimethylmethacrylamide claim 25 , N claim 25 ,N-dimethylacrylamide claim 25 , N-isopropylacrylamide claim 25 , N-tert-butylacrylamide and N-butylacrylamide.29. The method as claimed in claim 25 , wherein Q in formula (1) is selected from the group consisting of NH claim 25 , Na and mixtures of these ions and X in formula (2) is selected from the group consisting of H claim 25 , NH claim 25 , Na and mixtures of ...
Подробнее