07-02-2019 дата публикации
Номер: US20190040195A1
To provide a surface treatment agent capable of imparting excellent water/oil repellency, fingerprint stain removability, abrasion resistance and lubricity to the surface of a substrate. 1: A surface treatment agent , comprising a perfluoropolyether group-containing phosphate compound , wherein the perfluoropolyether group-containing phosphate compound is a compound represented by formula (1):{'br': None, 'sup': 1', '1, 'sub': m', '2m', 'n1, 'B—(CFO)-A\u2003\u2003(1)'}{'sup': 1', '1', 'F1', '1', '1', '1', '1', '2', '1', '2', '1', 'F1', '1', '1, 'sub': 2', '2, 'wherein Ais a monovalent organic group having at least one phosphoric acid group at its terminal, Bis R—O— or D-Q-O—CH— and a compound represented by the formula (1) wherein Ais a monovalent organic group having at least one phosphoric acid group at its terminal, Bis A-O—, wherein a content of the compound represented by the formula (1) wherein Bis A-O— is from 10 to 60 parts by mass, per 100 parts by mass in total of the compound represented by the formula (1) wherein Bis R—O— or D-O—O—CH—,'}{'sup': F1', '1', '1', '2, 'sub': 1-6', '3', '3', '1-20', '2-20', '1-20', '2-20, 'wherein Ris a Cperfluoroalkyl group, Dis CF— or CF—O—, Ois a Cfluoroalkylene group comprising a hydrogen atom, a Cfluoroalkylene group comprising a hydrogen atom and having an etheric oxygen atom between carbon-carbon atoms, a Calkylene group, or a Calkylene group having an etheric oxygen atom between carbon-carbon atoms, and Ais a monovalent organic group having at least one phosphoric acid group at its terminal,'}m is an integer of from 1 to 6, and{'sub': m', '2m', 'n1', 'm', '2m, 'n1 is an integer of from 1 to 200, provided that when n1 is at least 2, (CFO)may be one composed of at least two types of (CFO) different in m.'}2: (canceled)3: The surface treatment agent according to claim 1 , wherein (CFO)is a group represented by formula (2-1):{'br': None, 'sub': r', '2r', 'n2', 's', '2s', 'n3, '(CFO)(CFO)\u2003\u2003(2-1)'}{'sub': r', '2r', ...
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