04-10-2018 дата публикации
Номер: US20180282603A1
Принадлежит:
Arkema France
The use of an alcoholic compound to improve the miscibility of ammonia with 2,3,3,3-tetrafluoropropene, as well as to compositions of ammonia, 2,3,3,3-tetrafluoropropene and an alcoholic compound, and the use thereof, in particular in heat-transfer applications. A composition including 2,3,3,3-tetrafluoropropene, ammonia and an alcoholic compound having a melting point less than or equal to 0° C. 1. A composition comprising 2 ,3 ,3 ,3-tetrafluoropropene , ammonia and an alcoholic compound having a melting point less than or equal to 0° C.2. The composition as claimed in claim 1 , wherein the alcoholic compound has a melting point less than or equal to −50° C.; and/or in that the alcoholic compound has a viscosity at 20° C. less than or equal to 32.5 mm/s.3. The composition as claimed in claim 1 , wherein the alcoholic compound is a primary alcohol of formula R—CH—OH claim 1 , or a secondary alcohol of formula RR—CH—OH claim 1 , or a tertiary alcohol of formula RRR—C—OH claim 1 , or an enol of formula RRC═CROH claim 1 , or a phenol of formula R—OH claim 1 , the groups R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Reach representing independently a linear or branched alkyl group comprising from 1 to 20 carbon atoms claim 1 , optionally substituted partially or completely with F claim 1 , Br claim 1 , Cl or OH; and Rrepresents a benzene ring optionally substituted partially or completely with F claim 1 , Br claim 1 , Cl claim 1 , OH or with alkyl groups as defined above.4. The composition as claimed in claim 1 , wherein the alcoholic compound is selected from propan-1-ol claim 1 , propan-2-ol claim 1 , 2-perfluorohexylethanol claim 1 , 1 claim 1 ,1 claim 1 ,1 claim 1 ,3 claim 1 ,3 claim 1 ,3-hexafluoropropan-2-ol and mixtures thereof.5. The composition as claimed in claim 1 , comprising:from 1 to 60% of ammonia and from 40 to 99% of 2,3,3,3-tetrafluoropropene;the proportions being given relative to the sum of ammonia and 2,3,3 ...
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