METHOD OF REDUCING SOIL REDEPOSITION ON A HARD SURFACE USING PHOSPHINOSUCCINIC ACID ADDUCTS

Methods employing detergent compositions effective for reducing soil redeposition and accumulation on hard surfaces are disclosed. The detergent compositions employ phosphinosuccinic acid adducts in combination with an alkalinity source and gluconic acid or salts thereof, copolymers of acrylic acid and maleic acids or salts thereof, sodium hypochlorite, sodium dichloroisocyanurate or combinations thereof. 1. A detergent composition comprising:a phosphinosuccinic acid derivative comprising a phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid adducts; andan alkalinity source comprising an alkali metal hydroxide, carbonate, metasilicate, and/or silicate, wherein a use solution of the detergent composition has a pH between about 9 and 12.5.2. The composition of claim 1 , wherein the phosphinosuccinic acid derivative comprises at least 10 mol % of an adduct comprising a ratio of succinic acid to phosphorus from about 1:1 to 20:1.4. The composition of claim 3 , wherein the phosphinosuccinic acid adduct of formula I constitutes between about 1-40 wt-% of the phosphinosuccinic acid derivative claim 3 , the phosphinosuccinic acid adduct of formula II constitutes between about 1-25 wt-% of the phosphinosuccinic acid derivative claim 3 , the phosphinosuccinic acid adduct of formula III constitutes between about 10-60 wt-% of the phosphinosuccinic acid derivative claim 3 , the phosphinosuccinic acid adduct of formula IV constitutes between about 20-70 wt-% of the phosphinosuccinic acid derivative.5. The composition of claim 1 , where the use solution comprises from about 100-1500 ppm of an alkalinity source and from about 5-500 ppm phosphinosuccinic acid derivative.6. The composition of claim 1 , further comprising a compound selected from the group consisting of gluconic acid or salts thereof claim 1 , a copolymer of acrylic and maleic acids or salts thereof claim 1 , sodium hypochlorite claim 1 , sodium dichloroisocyanurate and combinations thereof.7 ...

HIGH ALKALINE WAREWASH DETERGENT WITH ENHANCED SCALE CONTROL AND SOIL DISPERSION

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency. 1: A concentrated detergent comprising:a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, wherein one of the said polycarboxylic acid polymers is a maleic anhydride/olefin copolymer;an alkalinity source comprising an alkali metal carbonate and/or an alkali metal hydroxide;a nonionic surfactant; andwater;wherein said detergent has an alkaline pH.2: The detergent of claim 1 , wherein said polymer system comprises at least two polycarboxylic acid polymers claim 1 , copolymers claim 1 , or terpolymers.3: The detergent of claim 1 , wherein said polymer system further comprises at least one polymaleic acid homopolymer and at least one acrylic acid copolymer.4: The detergent of claim 3 , wherein said polymaleic acid homopolymer claim 3 , acrylic acid copolymer claim 3 , and maleic anhydride/olefin copolymer are present in a ratio between about 1:1:1 to about 3:3:1.5: The detergent of claim 3 , wherein said polymaleic acid homopolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 3 , said acrylic acid copolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 3 , and said maleic anhydride/olefin copolymer is present between about 5 wt. % and about 35 wt. % of the polymer system.6: The detergent of claim 1 , wherein said detergent composition comprises between about 0.01 wt. % and about 20 wt. % polymer system claim 1 , between about 50 wt. % and about 99 wt. % alkalinity source claim 1 , between ...

Stain removal through novel oxidizer and chelant combination

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains.

ACID FORMULATIONS FOR USE IN A SYSTEM FOR WAREWASHING

Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions in combination with alkaline compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles. 1. A method of cleaning articles in a dishmachine comprising:applying an alkaline composition to articles in need of cleaning; andapplying to the articles an acidic composition before or after application of the alkaline composition, wherein said acidic composition comprises: a sulfuric acid derivative; and a chelating agent selected from the group consisting of citric acid, MGDA, GLDA, glutamic acid, and mixtures thereof.2. The method of claim 1 , wherein the acidic composition comprises from about 1000 to about 4000 ppm acid and from about 10 to about 50 ppm of surfactant.3. The method of claim 1 , wherein the acid is selected from the group consisting of urea sulfate claim 1 , urea hydrochloride claim 1 , sulfamic acid claim 1 , methanesulfonic acid claim 1 , citric acid claim 1 , gluconic acid and mixtures thereof and provides superior cleaning efficacy and reduced scaling in comparison to articles treated with a phosphoric acid composition.4. The method of claim 1 , wherein the acidic composition is a concentrated acidic composition claim 1 , wherein the concentrated acidic composition comprises a sulfuric acid derivative and/or an acid selected from the group consisting of urea sulfate claim 1 , urea hydrochloride claim 1 , sulfamic acid claim 1 , methanesulfonic acid claim 1 , citric acid claim 1 , gluconic acid and mixtures thereof claim 1 , and a surfactant selected from the group consisting of an EO/PO block copolymer claim 1 ...

Synergistic protein soil removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising surfactant, alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove protein soil in warewashing applications.

LOW-FOAMING WAREWASH DETERGENT CONTAINING MIXED CATIONIC / NONIONIC SURFACTANT SYSTEM FOR ENHANCED OILY SOIL REMOVAL

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture. 141-. (canceled)43. The composition of claim 42 , wherein said alkalinity source includes an alkali metal carbonate.44. The composition of claim 42 , wherein said metal protector is a polyacrylic or polymaleic acid polymer or an alkali metal silicate and/or said water conditioning agent or polymer is a phosphonate claim 42 , polycarboxylate or combinations thereof.45. The composition of claim 42 , wherein said chelant is one or more of MGDA claim 42 , GLDA claim 42 , or EDTA.46. The composition of claim 42 , wherein said cationic quaternary surfactant is present in an amount of from about 0.1 wt. % to about 5 wt. % and wherein said nonionic low foaming surfactant is present from about 0.5 wt. % to about 10 wt. %.47. The composition of claim 46 , wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant.48. The composition of claim 42 , wherein said cationic quaternary surfactant is a quaternary coco alkyl amine ethoxylate and wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant.49. The composition of claim 42 , wherein said ratio of said nonionic low foaming surfactant to said cationic quaternary surfactant is greater than 1:1 and less than 10:1.50. The composition of claim 42 , wherein said composition is a pressed solid claim 42 , extruded solid claim 42 , or cast solid.51. The composition of claim 50 , wherein said solid composition is diluted to form a use ...

CONCENTRATED DETERGENT COMPOSITION FOR THE IMPROVED REMOVAL OF STARCH IN WAREWASHING APPLICATIONS

The invention provides a concentrated detergent composition comprising 4. The concentrated detergent composition according to claim 2 , wherein Y is selected from the group consisting of Cl claim 2 , Br claim 2 , I claim 2 , NO claim 2 , ClO claim 2 , NCS claim 2 , BPh claim 2 , BF claim 2 , PF claim 2 , R—SO claim 2 , R—SO claim 2 , and R—CO claim 2 , wherein Ris hydrogen or a Cto Calkyl group.5. The concentrated detergent composition according to claim 1 , wherein the composition comprises 0.0005 to 0.12% by weight of the metal M in the form of a peroxidation catalyst complex.6. (canceled)7. The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal carbonate.8. The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 8 when diluted in distilled water at a concentration of 1 g/l.9. The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected from the list consisting of surfactants claim 1 , activating agents claim 1 , chelating/sequestering agents claim 1 , silicates claim 1 , detergent fillers or binding agents claim 1 , defoaming agents claim 1 , anti-redeposition agents claim 1 , enzymes claim 1 , dyes claim 1 , odorants claim 1 , and mixtures thereof.10. The concentrated detergent composition according to claim 1 , wherein the composition is provided in the form of a solid claim 1 , a powder claim 1 , a liquid claim 1 , or a gel.11. Use of a concentrated detergent composition according to as a warewashing detergent for the removal of starch soil.12. The use according to claim 11 , wherein the concentrated detergent composition is diluted to provide a use solution with a concentration of 0.1 to 10 g/l.13. The use according to claim 11 , wherein the concentrated detergent composition is used at a temperature of 20 to 85° C.14. The use according to claim 11 ...

SYNERGISTIC STAIN REMOVAL THROUGH NOVEL CHELATOR COMBINATION

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications. 1. A concentrated detergent composition comprisingalkali metal carbonate,methylglycinediacetic acid,glutamic acid N,N-diacetic acid, andalkali metal tripolyphosphate.2. The concentrated detergent composition according to claim 1 , wherein the molar ratio of methylglycinediacetic acid to alkali metal tripolyphosphate is 0.14 to 14.3.3. The concentrated detergent composition according to claim 1 , wherein the molar ratio of glutamic acid N claim 1 ,N-diacetic acid to the sum of methylglycinediacetic acid and alkali metal tripolyphosphate is 0.03 to 29.4. The concentrated detergent composition according to claim 1 , wherein the molar ratio of the sum of glutamic acid N claim 1 ,N-diacetic acid claim 1 , methylglycinediacetic acid and alkali metal tripolyphosphate to alkali metal carbonate is 0.01 to 0.5.5. The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal carbonate.6. The concentrated detergent composition according to claim 1 , wherein the alkali metal carbonate is sodium or potassium carbonate claim 1 , sodium or potassium bicarbonate claim 1 , sodium or potassium sesquicarbonate claim 1 , or a mixture thereof.7. The concentrated detergent composition according to claim 1 , wherein the alkali metal tripolyphosphate is sodium tripolyphosphate.8. The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 6 when diluted in distilled water at a concentration of 1 g/l and measured at a temperature of 20° C.9. The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected ...

Reducing agent as corrosion inhibitor for machine warewash

Warewash detergent compositions with reducing agents to overcome corrosion challenges in stainless steel dish machines subject to conditions from chlorine sanitizing rinse steps (or other oxidizing chlorine containing compositions) are provided. Liquid and solid detergent composition beneficially containing a reducing agent that reacts with chlorine introduced in sanitizing rinse steps that follow detergent cleaning steps are provided. Methods for ware washing using the detergent compositions with reducing agents and methods for reducing residual chlorine in a ware washing cycle are also provided.

ACID FORMULATIONS FOR USE IN A SYSTEM FOR WAREWASHING

Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions in combination with alkaline compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles. 1. A method of cleaning articles in a dishmachine comprising:applying an alkaline composition to articles in need of cleaning; andapplying to the articles an acidic composition before or after application of the alkaline composition, wherein said acidic composition comprises: a sulfuric acid derivative; and a chelating agent selected from the group consisting of citric acid, MGDA, GLDA, glutamic acid, and mixtures thereof.2. The method of claim 1 , wherein the acidic composition comprises from about 1000 to about 4000 ppm acid and from about 10 to about 50 ppm of surfactant.3. The method of claim 1 , wherein the acid is selected from the group consisting of urea sulfate claim 1 , urea hydrochloride claim 1 , sulfamic acid claim 1 , methanesulfonic acid claim 1 , citric acid claim 1 , gluconic acid and mixtures thereof and provides superior cleaning efficacy and reduced scaling in comparison to articles treated with a phosphoric acid composition.4. The method of claim 1 , wherein the acidic composition is a concentrated acidic composition claim 1 , wherein the concentrated acidic composition comprises a sulfuric acid derivative and/or an acid selected from the group consisting of urea sulfate claim 1 , urea hydrochloride claim 1 , sulfamic acid claim 1 , methanesulfonic acid claim 1 , citric acid claim 1 , gluconic acid and mixtures thereof; and a surfactant selected from the group consisting of an EO/PO block copolymer claim 1 , a PO/ ...

Solid controlled release caustic detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid caustic-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

HIGH ALKALINE WAREWASH DETERGENT WITH ENHANCED SCALE CONTROL AND SOIL DISPERSION

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency. 1. A concentrated detergent comprising:a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer;an alkalinity source comprising an alkali metal carbonate;a nonionic surfactant; andwater;wherein said detergent has an alkaline pH.2. The detergent of claim 1 , wherein said polymer system comprises at least two polycarboxylic acid polymers claim 1 , copolymers claim 1 , or terpolymers.3. The detergent of claim 1 , wherein said polymer system comprises at least one polymaleic acid homopolymer claim 1 , at least one acrylic acid copolymer claim 1 , and at least one maleic anhydride/olefin copolymer.4. The detergent of claim 3 , wherein said polymaleic acid homopolymer claim 3 , acrylic acid copolymer claim 3 , and maleic anhydride/olefin copolymer are present in a ratio between about 1:1:1 to about 3:3:1.5. The detergent of claim 1 , wherein said polymaleic acid homopolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , said acrylic acid copolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , and said maleic anhydride/olefin copolymer is present between about 5 wt. % and about 35 wt. % of the polymer system.6. The detergent of claim 1 , wherein said detergent composition comprises between about 0 wt. % and about 20 wt. % polymer system claim 1 , between about 50 wt. % and about 99 wt. % alkalinity source claim 1 , between about 0 wt. % and about 15 wt. % nonionic surfactant claim 1 , and ...

HIGH ALKALINE WAREWASH DETERGENT WITH ENHANCED SCALE CONTROL AND SOIL DISPERSION

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency. 1. A concentrated detergent comprising:a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer;an alkalinity source comprising an alkali metal carbonate;a nonionic surfactant; andwater;wherein said detergent has an alkaline pH.2. The detergent of claim 1 , wherein said polymer system comprises at least two polycarboxylic acid polymers claim 1 , copolymers claim 1 , or terpolymers.3. The detergent of claim 1 , wherein said polymer system comprises at least one polymaleic acid homopolymer claim 1 , at least one acrylic acid copolymer claim 1 , and at least one maleic anhydride/olefin copolymer.4. The detergent of claim 3 , wherein said polymaleic acid homopolymer claim 3 , acrylic acid copolymer claim 3 , and maleic anhydride/olefin copolymer are present in a ratio between about 1:1:1 to about 3:3:1.5. The detergent of claim 1 , wherein said polymaleic acid homopolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , said acrylic acid copolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , and said maleic anhydride/olefin copolymer is present between about 5 wt. % and about 35 wt. % of the polymer system.6. The detergent of claim 1 , wherein said detergent composition comprises between about 0 wt. % and about 20 wt. % polymer system claim 1 , between about 50 wt. % and about 99 wt. % alkalinity source claim 1 , between about 0 wt. % and about 15 wt. % nonionic surfactant claim 1 , and ...

Solid controlled release caustic detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid caustic-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

CONCENTRATED DETERGENT COMPOSITION FOR THE IMPROVED REMOVAL OF STARCH IN WAREWASHING APPLICATIONS

The invention provides a concentrated detergent composition comprising 4: The concentrated detergent composition according to claim 2 , wherein Y is selected from the group consisting of Cl claim 2 , Br claim 2 , I claim 2 , NO claim 2 , ClO claim 2 , NCS claim 2 , BPh claim 2 , BF claim 2 , PF claim 2 , R—SO claim 2 , R—SO claim 2 , and R—CO claim 2 , wherein Ris hydrogen or a Cto Calkyl group.5: The concentrated detergent composition according to claim 1 , wherein the composition comprises 0.0005 to 0.12% by weight of the metal M in the form of a peroxidation catalyst complex.6: The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 36% by weight alkali metal percarbonate.7: The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal carbonate.8: The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 8 when diluted in distilled water at a concentration of 1 g/l.9: The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected from the list consisting of surfactants claim 1 , activating agents claim 1 , chelating/sequestering agents claim 1 , silicates claim 1 , detergent fillers or binding agents claim 1 , defoaming agents claim 1 , anti-redeposition agents claim 1 , additional enzymes claim 1 , dyes claim 1 , odorants claim 1 , and mixtures thereof.10: The concentrated detergent composition according to claim 1 , wherein the composition is provided in the form of a solid claim 1 , a powder claim 1 , a liquid claim 1 , or a gel.11: A method of using a warewashing detergent for the removal of starch soil comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'diluting the concentrated detergent composition of to provide a use solution; and contacting a ware.'}12: The method according to claim 11 , wherein ...

AMYLASE SYNERGY WITH OXYGEN BLEACH IN WAREWASH APPLICATION

The present disclosure relates to detergent compositions effective for soil removal, particularly for the removal of starch soils. The compositions described herein may be used to remove soil from a surface including both hard and soft surfaces, most preferably on ware. Preferably, the detergent compositions comprise a detergent, a bleach, and an enzyme. Methods of making and using the detergent compositions for the removal of starch are also described herein. 2. The detergent composition of claim 1 , wherein the alkalinity source is an alkali metal carbonate.3. The detergent composition of claim 1 , wherein at least one of the one or more surfactants are a nonionic surfactant claim 1 , and wherein the nonionic surfactant comprises a poloxamer.4. The detergent composition of claim 3 , further comprising one or more additional enzymes.5. The detergent composition of claim 1 , wherein the bleach composition is a peroxygen bleach.6. The detergent composition of claim 5 , wherein the peroxygen bleach is sodium percarbonate claim 5 , sodium perborate claim 5 , hydrogen peroxide claim 5 , and/or a peracid.8. The detergent composition of claim 1 , wherein the one or more chelating agents comprise a phosphate and an aminocarboxylate.9. The detergent composition of claim 8 , wherein the phosphate is an alkali metal phosphate and the aminocarboxylate is EDTA claim 8 , HEDTA claim 8 , DTPA claim 8 , EDDS claim 8 , HEIDA claim 8 , IDS claim 8 , HIDS claim 8 , MGDA and/or GLDA.10. The detergent composition of claim 9 , wherein the alkali metal phosphate is sodium orthophosphate claim 9 , potassium orthophosphate claim 9 , sodium pyrophosphate claim 9 , potassium pyrophosphate claim 9 , sodium tripolyphosphate claim 9 , and/or sodium hexametaphosphate.11. The detergent composition of claim 1 , further comprising a corrosion inhibitor comprising sodium aluminate claim 1 , aluminum bromide claim 1 , aluminum chlorate claim 1 , aluminum chloride claim 1 , aluminum iodide claim 1 , ...

SYNERGISTIC STAIN REMOVAL THROUGH NOVEL CHELATOR COMBINATION

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications. 1. A concentrated detergent composition comprisingalkali metal carbonate,methylglycinediacetic acid,glutamic acid N,N-diacetic acid, andalkali metal tripolyphosphate.2. The concentrated detergent composition according to claim 1 , wherein the molar ratio of methylglycinediacetic acid to alkali metal tripolyphosphate is 0.14 to 14.3.3. The concentrated detergent composition according to claim 1 , wherein the molar ratio of glutamic acid N claim 1 ,N-diacetic acid to the sum of methylglycinediacetic acid and alkali metal tripolyphosphate is 0.03 to 29.4. The concentrated detergent composition according to claim 1 , wherein the molar ratio of the sum of glutamic acid N claim 1 ,N-diacetic acid claim 1 , methylglycinediacetic acid and alkali metal tripolyphosphate to alkali metal carbonate is 0.01 to 0.5.5. The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal carbonate.6. The concentrated detergent composition according to claim 1 , wherein the alkali metal carbonate is sodium or potassium carbonate claim 1 , sodium or potassium bicarbonate claim 1 , sodium or potassium sesquicarbonate claim 1 , or a mixture thereof.7. The concentrated detergent composition according to claim 1 , wherein the alkali metal tripolyphosphate is sodium tripolyphosphate.8. The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 6 when diluted in distilled water at a concentration of 1 g/l and measured at a temperature of 20° C.9. The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected ...

SYNERGISTIC STAIN REMOVAL THROUGH NOVEL CHELATOR COMBINATION

The invention relates to a concentrated detergent composition comprising an alkali metal hydroxide, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications. 1. A concentrated detergent composition comprising alkali metal hydroxide , alkali metal tripolyphosphate , and at least one complexing agent selected from the group consisting of methylglycinediacetic acid and glutamic acid N ,N-diacetic acid.2. The concentrated detergent composition according to claim 1 , wherein the composition comprises methylglycinediacetic acid and glutamic acid N claim 1 ,N-diacetic acid.3. The concentrated detergent composition according to claim 1 , wherein the molar ratio of alkali metal tripolyphosphate to the sum of alkali metal tripolyphosphate claim 1 , methylglycinediacetic acid claim 1 , and glutamic acid N claim 1 ,N-diacetic acid is 0.05 to 0.95.4. The concentrated detergent composition according to claim 1 , wherein the molar ratio of the sum of glutamic acid N claim 1 ,N-diacetic acid claim 1 , methylglycinediacetic acid and alkali metal tripolyphosphate to alkali metal hydroxide is 0.01 to 1.5. The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal hydroxide.6. The concentrated detergent composition according to claim 1 , wherein the alkali metal hydroxide is sodium hydroxide.7. The concentrated detergent composition according to claim 1 , wherein the alkali metal tripolyphosphate is sodium tripolyphosphate.8. The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 9 when diluted in distilled water at a concentration of 1 g/l and measured at a temperature of 20° C.9. The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected ...

STAIN REMOVAL THROUGH NOVEL OXIDIZER AND CHELANT COMBINATION

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains. 2: The detergent composition according to claim 1 , wherein the detergent composition comprises as a chelant MGDA claim 1 , GLDA and an alkali metal tripolyphosphate.3. (canceled)4: The detergent composition according to claim 1 , comprising at most 28% by weight alkali metal tripolyphosphate.5: The detergent composition according to claim 1 , wherein the composition comprises 5 to 30% by weight alkali metal percarbonate.6: The detergent composition according to claim 1 , wherein the composition provides a pH of at least 8 when diluted in distilled water at a concentration of 1 g/l.7. (canceled)9: The detergent composition according to claim 1 , wherein Y is selected from the group consisting of Cl claim 1 , Br claim 1 , I claim 1 , NO claim 1 , ClO claim 1 , NCS claim 1 , BPh claim 1 , BF claim 1 , PF claim 1 , R—SO claim 1 , R—SO claim 1 , and R—CO claim 1 , wherein Ris hydrogen or a Cto Calkyl group.10: The detergent composition according to claim 1 , wherein the composition comprises 0.0005 to 0.12% by weight of the metal M in the form of a peroxidation catalyst complex.11: The detergent composition according to claim 1 , wherein the composition further comprises at least one additional compound comprising surfactants claim 1 , activating agents claim 1 , additional chelating/sequestering agents claim 1 , silicates claim 1 , detergent fillers or binding agents claim 1 , defoaming agents claim 1 , anti-redeposition agents claim 1 , enzymes claim 1 , dyes claim 1 , odorants claim 1 , or mixtures thereof.12: The detergent ...

CONCENTRATED DETERGENT COMPOSITION FOR THE IMPROVED REMOVAL OF STARCH IN WAREWASHING APPLICATIONS

The invention provides a concentrated detergent composition comprising 4: The concentrated detergent composition according to claim 2 , wherein Y is selected from the group consisting of Cl claim 2 , Br claim 2 , I claim 2 , NO claim 2 , ClO claim 2 , NCS claim 2 , BPh claim 2 , BF claim 2 , PF claim 2 , R—SO claim 2 , R—SO claim 2 , and R—CO claim 2 , wherein Ris hydrogen or a Cto Calkyl group.5: The concentrated detergent composition according to claim 1 , wherein the composition comprises from 0.001% to 0.05% by weight of the metal M in the form of a peroxidation catalyst complex.6: The concentrated detergent composition according claim 1 , wherein the composition comprises at least 36% by weight alkali metal percarbonate.7: The concentrated detergent composition according to claim 1 , wherein the composition comprises from 20% to 60% by weight alkali metal carbonate.8: The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 8 when diluted in distilled water at a concentration of 1 g/l.9: The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected from the list consisting of surfactants claim 1 , activating agents claim 1 , chelating/sequestering agents claim 1 , silicates claim 1 , detergent fillers or binding agents claim 1 , defoaming agents claim 1 , anti-redeposition agents claim 1 , enzymes claim 1 , dyes claim 1 , odorants claim 1 , and mixtures thereof.10: The concentrated detergent composition according to claim 1 , wherein the composition is provided in the form of a solid claim 1 , a powder claim 1 , a liquid claim 1 , or a gel.11: Use of a concentrated detergent composition according to as a warewashing detergent for the removal of starch soil.12: The use according to claim 11 , wherein the concentrated detergent composition is diluted to provide a use solution with a concentration of 0.1 to 10 g/l.13: The use ...

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

HIGH ALKALINE WAREWASH DETERGENT WITH ENHANCED SCALE CONTROL AND SOIL DISPERSION

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency. 1. A concentrated detergent comprising:a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer;an alkalinity source comprising an alkali metal carbonate;a nonionic surfactant; andwater;wherein said detergent has an alkaline pH.2. The detergent of claim 1 , wherein said polymer system comprises at least two polycarboxylic acid polymers claim 1 , copolymers claim 1 , or terpolymers.3. The detergent of claim 1 , wherein said polymer system comprises at least one polymaleic acid homopolymer claim 1 , at least one acrylic acid copolymer claim 1 , and at least one maleic anhydride/olefin copolymer.4. The detergent of claim 3 , wherein said polymaleic acid homopolymer claim 3 , acrylic acid copolymer claim 3 , and maleic anhydride/olefin copolymer are present in a ratio between about 1:1:1 to about 3:3:1.5. The detergent of claim 1 , wherein said polymaleic acid homopolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , said acrylic acid copolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , and said maleic anhydride/olefin copolymer is present between about 5 wt. % and about 35 wt. % of the polymer system.6. The detergent of claim 1 , wherein said detergent composition comprises between about 0 wt. % and about 20 wt. % polymer system claim 1 , between about 50 wt. % and about 99 wt. % alkalinity source claim 1 , between about 0 wt. % and about 15 wt. % nonionic surfactant claim 1 , and ...

DETERGENT COMPOSITION AND METHODS OF PREVENTING ALUMINUM DISCOLORATION

Detergent compositions designed to prevent aluminum discoloration while providing high cleaning performance on soils and stains are disclosed. Detergent compositions substantially free of nitrilotriacetic acid (NTA) are disclosed. Methods of using the detergent compositions are also disclosed. 1. A solid , alkaline , non-staining detergent composition comprising:an alkalinity source;an alkali metal silicate;an aminocarboxylate comprising a mixture of ethylenediamine-N,N-diacetic acid (EDTA) and methylglycine-N,N-diacetic acid (MGDA) or salts thereof;at least one water conditioning polymer; anda defoaming agent;wherein the composition is substantially free of nitrilotriacetic acid (NTA).2. The detergent composition of claim 1 , wherein the alkalinity source is an alkali metal carbonate and/or an alkali metal hydroxide.3. The detergent composition of claim 1 , wherein the alkalinity source is sodium carbonate.4. The detergent composition of claim 1 , wherein the alkali metal silicate is sodium silicate.5. The detergent composition of claim 1 , wherein the ratio of the aminocarboxylates ethylenediamine-N claim 1 ,N-diacetic acid (EDTA) or salt thereof to methylglycine-N claim 1 ,N-diacetic acid (MGDA) or salt thereof is at least about 1:1 claim 1 , from about 1:1 to about 3:1 claim 1 , from about 1:1 to about 5:1 claim 1 , or from about 1:1 to about 10:1.6. The detergent composition of claim 1 , wherein the water conditioning polymer is a polymaleic acid homopolymer claim 1 , a polyacrylic acid homopolymer or combinations thereof claim 1 , preferably wherein the polymaleic acid homopolymer has a molecular weight less than about 2 claim 1 ,000 g/mol claim 1 , and wherein the a polyacrylic acid homopolymer has a molecular weight between about 500-50 claim 1 ,000 g/mol claim 1 , more preferably between about 1 claim 1 ,000-25 claim 1 ,000 g/mol claim 1 , and most preferably between about 1 claim 1 ,000-15 claim 1 ,000 g/mol.7. The detergent composition of claim 1 , ...

DETERGENT COMPOSITION AND METHODS OF PREVENTING ALUMINUM DISCOLORATION

Detergent compositions designed to prevent aluminum discoloration while providing high cleaning performance on soils and stains are disclosed. Detergent compositions substantially free of nitrilotriacetic acid (NTA) are disclosed. Methods of using the detergent compositions are also disclosed. 1. A solid , alkaline , non-staining detergent composition comprising:an alkalinity source;an alkali metal silicate;an aminocarboxylate comprising a mixture of ethylenediamine-N,N-diacetic acid (EDTA) and methylglycine-N,N-diacetic acid (MGDA) or salts thereof;at least one water conditioning polymer; anda defoaming agent;wherein the composition is substantially free of nitrilotriacetic acid (NTA).2. The detergent composition of claim 1 , wherein the alkalinity source is an alkali metal carbonate and/or an alkali metal hydroxide.3. The detergent composition of claim 1 , wherein the alkalinity source is sodium carbonate.4. The detergent composition of claim 1 , wherein the alkali metal silicate is sodium silicate.5. The detergent composition of claim 1 , wherein the ratio of the aminocarboxylates ethylenediamine-N claim 1 ,N-diacetic acid (EDTA) or salt thereof to methylglycine-N claim 1 ,N-diacetic acid (MGDA) or salt thereof is at least about 1:1 claim 1 , from about 1:1 to about 3:1 claim 1 , from about 1:1 to about 5:1 claim 1 , or from about 1:1 to about 10:1.6. The detergent composition of claim 1 , wherein the water conditioning polymer is a polymaleic acid homopolymer claim 1 , a polyacrylic acid homopolymer or combinations thereof claim 1 , preferably wherein the polymaleic acid homopolymer has a molecular weight less than about 2 claim 1 ,000 g/mol claim 1 , and wherein the a polyacrylic acid homopolymer has a molecular weight between about 500-50 claim 1 ,000 g/mol claim 1 , more preferably between about 1 claim 1 ,000-25 claim 1 ,000 g/mol claim 1 , and most preferably between about 1 claim 1 ,000-15 claim 1 ,000 g/mol.7. The detergent composition of claim 1 , ...

HARDNESS ADDITIVES AND BLOCK DETERGENTS CONTAINING HARDNESS ADDITIVES TO IMPROVE EDGE HARDENING

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

SYNERGISTIC STAIN REMOVAL THROUGH NOVEL CHELATOR COMBINATION

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications. 1. A concentrated detergent composition comprisingalkali metal carbonate,methylglycinediacetic acid,glutamic acid N,N-diacetic acid, andalkali metal tripolyphosphate.2. The concentrated detergent composition according to claim 1 , wherein the molar ratio of methylglycinediacetic acid to alkali metal tripolyphosphate is 0.14 to 14.3.3. The concentrated detergent composition according to claim 1 , wherein the molar ratio of glutamic acid N claim 1 ,N-diacetic acid to the sum of methylglycinediacetic acid and alkali metal tripolyphosphate is 0.03 to 29.4. The concentrated detergent composition according to claim 1 , wherein the molar ratio of the sum of glutamic acid N claim 1 ,N-diacetic acid claim 1 , methylglycinediacetic acid and alkali metal tripolyphosphate to alkali metal carbonate is 0.01 to 0.5.5. The concentrated detergent composition according to claim 1 , wherein the composition comprises at least 5% by weight alkali metal carbonate.6. The concentrated detergent composition according to claim 1 , wherein the alkali metal carbonate is sodium or potassium carbonate claim 1 , sodium or potassium bicarbonate claim 1 , sodium or potassium sesquicarbonate claim 1 , or a mixture thereof.7. The concentrated detergent composition according to claim 1 , wherein the alkali metal tripolyphosphate is sodium tripolyphosphate.8. The concentrated detergent composition according to claim 1 , wherein the composition provides a pH of at least 6 when diluted in distilled water at a concentration of 1 g/l and measured at a temperature of 20° C.9. The concentrated detergent composition according to claim 1 , wherein the composition further comprises at least one of the compounds selected ...

HIGH ALKALINE WAREWASH DETERGENT WITH ENHANCED SCALE CONTROL AND SOIL DISPERSION

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency. 1. A concentrated detergent comprising:a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer;an alkalinity source comprising an alkali metal carbonate;a nonionic surfactant;a protease enzyme; andwater;wherein said detergent has an alkaline pH.2. The detergent of claim 1 , wherein said polymer system comprises at least two polycarboxylic acid polymers claim 1 , copolymers claim 1 , or terpolymers.3. The detergent of claim 1 , wherein said polymer system comprises at least one polymaleic acid homopolymer claim 1 , at least one acrylic acid copolymer claim 1 , and at least one maleic anhydride/olefin copolymer.4. The detergent of claim 3 , wherein said polymaleic acid homopolymer claim 3 , acrylic acid copolymer claim 3 , and maleic anhydride/olefin copolymer are present in a ratio between about 1:1:1 to about 3:3:1.5. The detergent of claim 1 , wherein said polymaleic acid homopolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , said acrylic acid copolymer is present between about 25 wt. % and about 55 wt. % of the polymer system claim 1 , and said maleic anhydride/olefin copolymer is present between about 5 wt. % and about 35 wt. % of the polymer system.6. The detergent of claim 1 , wherein said detergent composition comprises between about 0 wt. % and about 20 wt. % polymer system claim 1 , between about 50 wt. % and about 99 wt. % alkalinity source claim 1 , between about 0 wt. % and about 15 wt. % nonionic surfactant ...

Alkaline warewash detergent for aluminum surfaces

Detergent compositions designed to prevent aluminum discoloration while providing high cleaning performance on soils and stains are disclosed. Detergent compositions substantially free of nitrilotriacetic acid (NTA) are disclosed. Methods of using the detergent compositions are also disclosed.

SOLID CONTROLLED RELEASE CARBONATE DETERGENT COMPOSITIONS

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid carbonate-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed. 1. A solid controlled release composition for cleaning wares comprising:a carbonate alkalinity source;at least one polysaccharide material comprising less than about 20 wt-% of the composition; andan active ingredient cleaning agent,wherein the solid composition is a homogenous multi-use composition having a mass of at least 50 grams and is not encapsulated with delayed release chemistry.2. The composition of claim 1 , wherein the carbonate alkalinity source is an alkali metal carbonate.3. The composition of claim 1 , wherein the polysaccharide material(s) comprises less than about 15 wt-% of the composition and has a solution viscosity between about 1 wt-% to about 2 wt-% aqueous solution viscosity (25 dC) between about 1 and about 5000 cps claim 1 , and/or wherein the polysaccharide material has a degree of substitution (D.S.) between about zero and about 3 claim 1 , and/or wherein the polysaccharide material has a degree of polymerization between about 200 and about 15 claim 1 ,000.4. The composition of claim 1 , wherein the polysaccharide material is one or more of carboxymethylcellulose (CMC) claim 1 , hydroxyethylcellulose (HEC) claim 1 , hydroxypropylcellulose (HPC) claim 1 , hydroxypropyl methylcelluslose (HPMC) claim 1 , methylcellulose (MC) claim 1 , celluslose acetate claim 1 , cellulose triacetate claim 1 , and xanthan.5. The composition of claim 4 , wherein the polysaccharide material comprises carboxymethylcellulose (CMC).6. The composition of claim 4 , wherein the polysaccharide material comprises xanthan.7. The composition of claim 4 , wherein the polysaccharide material comprises carboxymethylcellulose (CMC) ...

LOW-FOAMING WAREWASH DETERGENT CONTAINING MIXED CATIONIC / NONIONIC SURFACTANT SYSTEM FOR ENHANCED OILY SOIL REMOVAL

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture. 141-. (canceled)42. A warewash alkaline detergent composition comprising:from about 40 wt. % to about 90 wt. % of an alkalinity source;from about 1 wt. % to about 20 wt. % of a surfactant component comprising a nonionic low foaming surfactant and a cationic quaternary surfactant, said surfactants in a ratio of greater than 1:1;from about 0.1 wt. % to about 10 wt. % of a defoaming nonionic surfactant;with the remainder comprising one or more of a metal protector, water conditioning agent or polymer, an enzyme, a chelant, a bleaching agent, a solidification aid, and/or a carrier.43. The detergent of claim 42 , wherein said alkalinity includes an alkali metal carbonate.44. The composition of claim 42 , wherein said metal protector is a polayacrylic or polymaleic acid polymer or an alkali metal silicate and/or said water conditioning agent or polymer is a phosphonate claim 42 , polycarboxylate or combinations thereof.45. The composition of claim 42 , wherein said chelant is one or more of MGDA claim 42 , GLDA claim 42 , or EDTA.47. The composition of claim 46 , wherein said quaternary cationic surfactant is a quaternary alkyl amine alkloxylate surfactant and wherein said low foaming surfactant is an alcohol ethoxylate surfactant.48. The composition of claim 47 , wherein said quaternary cationic alkoxylate surfactant is a quaternary coco alkyl amine ethoxylate and wherein said low foaming surfactant is an alcohol ...

Acid formulations for use in a system for warewashing

Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal hydroxide, methylglycinediacetic acid, glutamic acid Ν,Ν-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid Ν,Ν-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

Non-phosphate detergents and non-phosphoric acids in an alternating alkali/acid system for warewashing

A method of warewashing for the optimization of cleaning is obtained, excess detergent usage is minimized and further where deposit of film on ware is reduced in an alternating acidic and alkaline cleaning method. According to the invention, the type of acid and alkalinity used, or acid salt formed upon application of the acidic and alkaline washes is important to cleaning performance and phosphate or silicates should be avoided.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal hydroxide, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

Amylase synergy with oxygen bleach in warewash application

The present disclosure relates to detergent compositions effective for soil removal, particularly for the removal of starch soils. The compositions described herein may be used to remove soil from a surface including both hard and soft surfaces, most preferably on ware. Preferably, the detergent compositions comprise a detergent, a bleach, and an enzyme. Methods of making and using the detergent compositions for the removal of starch are also described herein.

Concentrated detergent composition for the improved removal of starch in warewashing applications

The invention provides a concentrated detergent composition alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH-, SH-, H02-, O2-, O22-, S2-, F-, CI-, Br-, I-, NO3 -, NO2 -, formula (II), SO4 2-, SO3 2-, PO4 3-, N3-, CN-, NR3, NCS-, RCN, RS-, RCO2 -, RO-, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.

Concentrated detergent for washing utensils and its method of use

DETERGENTE ALTAMENTE ALCALINO PARA LAVAR UTENSÍLIOS COM CONTROLE APRIMORADO DE INCRUSTAÇÕES E DISPERSÃO DE PARTÍCULAS DE SUJIDADE. A presente invenção refere-se a composições de detergentes e a métodos para preparar e utilizar as composições de detergentes. As composições de detergentes compreendem um sistema polimérico incluindo pelo menos um polímero, copolímero ou terpolímero de ácido policarboxílico, uma fonte de alcalinidade compreendendo um carbonato de metal alcalino, um surfactante não iônico e água. As composições de detergentes são adequadas em pH alcalino e reduzem ou evitam a formação de incrustações, melhoram a dispersão de partículas de sujidade e proporcionam detergência eficaz. HIGHLY ALKALINE DETERGENT FOR WASHING UTENSILS WITH IMPROVED CONTROL OF INCRUSTATION AND DISPERSION OF PARTICLES OF DIRT. The present invention relates to detergent compositions and methods for preparing and using detergent compositions. Detergent compositions comprise a polymeric system including at least one polycarboxylic acid polymer, copolymer or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. Detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil particle dispersion and provide effective detergency.

Non-phosphate detergents and non-phosphoric acids in an alternating alkali/acid system for warewashing

Synergistic stain removal through a combination of new chelators

Una composición de detergente concentrada que comprende un hidróxido de metal alcalino, un tripolifosfato de metal alcalino, y el ácido N,N-diacetil glutámico.

Low-foaming warewash detergent containing mixed cationic/nonionic surfactant system for enhanced oily soil removal

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture.

Synergistic protein soil removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising surfactant, alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove protein soil in warewashing applications.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid ?,?-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Synergistic stain removal through novel chelator combination

Acid formulations for use in a system for warewashing

Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Solid controlled release carbonate detergent compositions

A solid controlled release composition for cleaning wares com-prising: a carbonate alkalinity source; at least one polysaccharide material comprising less than about 20 wt-% of the composition; and an active ingredient cleaning agent, wherein the solid is a homogenous multi-use composition having a mass of at least 50 grams and is not encapsulated with delayed release chemistry. A method of dispensing a solid controlled release composition, said method comprising: contacting the solid composition with a water source to generate a use solution of the composition; and contacting wares with the use solution at pH 7-13 to remove and/or solubilize soils. A system for cleaning wares in an automatic dishwashing environment comprising: the solid controlled release composition; wherein the solid composition is a homogenous 2-in-1 composition providing a detergent and rinse aid in a single solid composition; and wherein the system does not include a dispensing system.

Synergistic stain removal through chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal hydroxide, methylglycinediacetic acid, glutamic acid ?,?-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Hardness additives and block detergents containing hardness additives to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

High alkaline warewash detergent with enhanced scale control and soil dispersion.

Se describen las composiciones detergentes y los métodos de preparación y uso de las composiciones detergentes. Las composiciones detergentes comprenden un sistema polimérico que incluye al menos un polímero, copolímero, o terpolímero de ácido policarboxílico, una fuente de alcalinidad que comprende un carbonato de metal alcalino, un tensioactivo no iónico y agua. Las composiciones detergentes son adecuadas a pH alcalino y reducen o previenen la formación de incrustaciones, mejora la dispersión de la suciedad, y proporcionan detergencia efectiva.

Amylase synergy with oxygen bleach in warewash application

The present disclosure relates to detergent compositions effective for soil removal, particularly for the removal of starch soils. The compositions described herein may be used to remove soil from a surface including both hard and soft surfaces, most preferably on ware. Preferably, the detergent compositions comprise a detergent, a bleach, and an enzyme. Methods of making and using the detergent compositions for the removal of starch are also described herein.

Stain removal through novel oxidizer and chelant combination

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains.

Synergistic stain removal through novel MGDA/GLDA/STPP chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Hardness additives and block detergents containing hardness additives to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Stain removal through novel oxidizer and chelant combination

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains.

Low-foaming warewash detergent containing mixed cationic/nonionic surfactant system for enhanced oily soil removal

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture.

Solid controlled release caustic detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid caustic-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

Low-foaming warewash detergent containing mixed cationic / nonionic surfactant system for enhanced oily soil removal

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture.

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

Hardness additives and block detergents containing hardness additives to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Solid controlled release carbonate detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid carbonate-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

Reducing agent as corrosion inhibitor for neutral or low alkaline warewash detergent

Warewash detergent compositions with reducing agents to overcome corrosion challenges in stainless steel dish machines subject to conditions from chlorine sanitizing rinse steps (or other oxidizing chlorine containing compositions) are provided. Detergent compositions or booster compositions used in combination with detergents beneficially containing a reducing agent that reacts with chlorine introduced in sanitizing rinse steps that follow detergent cleaning steps are provided. Methods for ware washing using the detergent compositions with reducing agents and methods for reducing residual chlorine in a ware washing cycle are also provided.

Synergistic protein soil removal through novel chelator combination

Eliminación sinérgica de suciedad de proteínas mediante una nueva combinación de quelantes

La invención se refiere a una composición detergente concentrada que comprende tensioactivo, carbonato de metal alcalino, ácido metilglicinadiacético, ácido glutámico N,N-diacético y tripolifosfato de metal alcalino. La composición es particularmente adecuada para eliminar suciedad proteica en aplicaciones de lavado de vajilla. (Traducción automática con Google Translate, sin valor legal)

Detergent composition and methods of preventing aluminum discoloration

Detergent compositions designed to prevent aluminum discoloration while providing high cleaning performance on soils and stains are disclosed. Detergent compositions substantially free of nitrilotriacetic acid (NTA) are disclosed. Methods of using the detergent compositions are also disclosed.

Hardness additives comprising an aminocarboxylate chelant mixture and block detergents containing this mixture to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Detergente lavavajillas de baja espuma que contiene un sistema tensioactivo mixto catiónico/no iónico para una mejor eliminación de la suciedad aceitosa

La invención incluye composiciones detergentes para vajillas que proporcionan una limpieza superior y eliminación de suciedad aceitosa y grasosa, sin la producción excesiva de espuma. Según la invención, los solicitantes han descubierto que el uso de un tensioactivo catiónico cuaternario en combinación con un tensioactivo no iónico de baja formación de espuma puede proporcionar una eliminación de suciedad aceitosa de la vajilla que es superior a las formulaciones de detergentes para lavavajillas tradicionales. Se describen composiciones para detergentes para lavavajillas alcalinos, preferiblemente sólidos, así como su uso en lavavajillas y métodos de fabricación. (Traducción automática con Google Translate, sin valor legal)

エッジ硬化を改善するための硬度添加剤および硬度添加剤を含有するブロック洗剤

【課題】プレスされた固体の生産を通して、機械的搬送中、かつ型からの排出中に、固体の完全性を維持するように設計された固体洗剤組成物が開示される。【解決手段】相乗比のポリカルボン酸ポリマーキレート剤対アミノカルボキシレートキレート剤を含む硬度添加剤組成物を含めることによって、硬化ステップを伴わない予想外の即時ブロック硬度を有する固体洗剤組成物が提供される。硬度添加剤組成物を含まない固体洗剤組成物と少なくとも実質的に同様の洗浄性能を有する固体洗剤組成物を作製する方法および固体洗剤組成物も提供される。【選択図】図１

Method of warewashing based on the synergistic stain removal through novel chelator combination

Hardness additives and block detergents containing hardness additives to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Solid controlled release carbonate detergent compositions

High alkaline warewash detergent with enhanced scale control and soil dispersion

Detergent compositions and methods of preparing and using the detergent compositions are disclosed. The detergent compositions comprise a polymer system comprising at least one polycarboxylic acid polymer, copolymer, or terpolymer, an alkalinity source comprising an alkali metal carbonate, a nonionic surfactant and water. The detergent compositions are suitable at alkaline pH and reduce or prevent scale formation, improve soil dispersion, and provide effective detergency.

Method of warewashing based on the synergistic stain removal through novel chelator combination

Solid controlled release carbonate detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid carbonate-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

Solid controlled release caustic detergent compositions

Solid detergent compositions for dishwashing or warewashing compositions and applications of use are disclosed. In particular, solid caustic-based compositions that do not require a traditional dispenser for controlled rate of release over multiple cycles are disclosed. Compositions, methods of employ and cleaning using the same are disclosed.

Solid controlled release carbonate detergent compositions

Detergent composition and methods of preventing aluminum discoloration

Detergent compositions designed to prevent aluminum discoloration while providing high cleaning performance on soils and stains are disclosed. Detergent compositions substantially free of nitrilotriacetic acid (NTA) are disclosed. Methods of using the detergent compositions are also disclosed.

Solid controlled release caustic detergent compositions

A solid controlled release composition for cleaning wares comprising: a hydroxide alkalinity source; at least one polysaccharide material comprising less than about 20 wt-% of the composition; and an active ingredient cleaning agent, wherein the solid is a homogenous multi-use composition having a mass of at least 50 grams and is not encapsulated with delayed release chemistry. A method of dispensing a solid controlled release composition, said method comprising: contacting the solid composition with a water source to generate a use solution of the composition; and contacting wares with the use solution at pH 10.5-13 to remove and/or solubilize soils. A system for cleaning wares in an automatic dishwashing environment comprising: the solid controlled release composition; wherein the solid composition is a homogenous 2-in-1 composition providing a detergent and rinse aid in a single solid composition; and wherein the system does not include a dispensing system.

Hardness additives comprising an acrylate/aminocarboxylate mixture and block detergents containing said mixture to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Low-foaming warewash detergent containing mixed cationic / nonionic surfactant system for enhanced oily soil removal

The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture.

Stain removal through novel oxidizer and chelant combination

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains.

Stain removal through novel oxidizer and chelant combination

The present invention relates to a detergent composition comprising alkali metal carbonate, a chelant selected from the group consisting of MGDA, alkali metal tripolyphosphate, GLDA, and mixtures thereof, alkali metal percarbonate, and a peroxidation catalyst, wherein the molar ratio of chelant to alkali metal percarbonate is in the range of 1.8 to 3.4. The detergent composition is particularly suited for the removal of tea and coffee stains.

Hardness additives and block detergents containing hardness additives to improve edge hardening

Solid detergent compositions designed to maintain solid integrity throughout production of the pressed solid, during mechanical conveying and during ejection from molds, are disclosed. Solid detergent compositions having unexpected immediate block hardness without a curing step are provided by inclusion of a hardness additive composition comprising a synergistic ratio of polycarboxylic acid polymer chelants to aminocarboxylate chelants. Methods of making solid detergent compositions and solid detergent compositions having at least substantially similar cleaning performance to solid detergent compositions without the hardness additive composition are also provided.

Concentrated detergent composition for the improved removal of starch in warewashing applications

The invention provides a concentrated detergent composition comprising alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(L p M q ) n X r ]Y s , wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H 2 O, OH − , SH − , HO 2 − , O 2− , O 2 2− , S 2− , F − , Cl − , Br − , I − , NO 3 − , NO 2 − , SO 4 2− , SO 3 2− , PO 4 3− , N 3 − , CN − , NR 3 , NCS − , RCN, RS − , RCO 2 − , RO − , and with R being hydrogen or a C 1 to C 6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.

Synergistic stain removal through an alkali metal hydroxide-based detergent composition with novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal hydroxide, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Synergistic stain removal through novel chelator combination

The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.

Acid formulations for use in a system for warewashing

Methods of acidic warewashing are disclosed. The compositions can include other materials including surfactants and chelating agents, and are preferably phosphorous free. Methods of using the acidic compositions in combination with alkaline compositions are also disclosed. Exemplary methods include using the acidic compositions together with other compositions, including alkaline compositions and rinse aids employed in an alternating alkaline/acid/alkaline manner. The methods also include acidic compositions that serve multiple roles.