31-08-2017 дата публикации
Номер: US20170248051A1
Принадлежит:
In general, this disclosure describes method of capturing and storing COon a vehicle. The method includes contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition sufficient to separate COfrom the exhaust gas, contacting the separated COwith one or more of a second MOF composition sufficient to store the COand wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3. Embodiments also describe an apparatus or system for capturing and storing COonboard a vehicle. 1. A method of capturing and storing COon a vehicle , comprising:{'sub': '2', 'contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition, sufficient to separate COfrom the exhaust gas;'}{'sub': 2', '2, 'contacting the separated COwith one or more of a second MOF composition, sufficient to store the CO; and'}wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3.2. The method of claim 1 , wherein the one or more second MOF composition comprises a soc-MOF analogue.3. The method of claim 1 , wherein the metal comprises zinc or copper.4. The method of claim 1 , wherein the metal comprises Cu claim 1 , Zn claim 1 , Co claim 1 , Mn claim 1 , Mo claim 1 , Cr claim 1 , Fe claim 1 , Ca claim 1 , Ba claim 1 , Cs claim 1 , Pb claim 1 , Pt claim 1 , Pd claim 1 , Ru claim 1 , Rh claim 1 , or Cd5. The method of claim 1 , wherein the SIFSIX-n-M composition comprises bidentate organic ligands.6. The method of claim 1 , wherein the SIFSIX-n-M composition comprises bidentate N-donor organic ligands.7. The method of claim 1 , wherein the SIFSIX-n-M composition comprises a SIFSIX-3-Cu metal organic framework.8. The method of claim 1 , wherein the SIFSIX-n-M composition comprises a SIFSIX-3-Zn metal organic framework.9. An apparatus for capturing and storing COon a vehicle claim 1 , comprising:{'sub': '2 ...
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