01-10-2020 дата публикации
Номер: US20200308044A1
Alkali free fluorophosphate-based glass system that is highly radiation resistance (for example, they remain transparent and do not solarize before, during, and after application of high energy radiation of 10Rad or (1 kGy) or greater) and hence, reusable and further, when used with Ce provide a mechanism for determining the existence of radiation. 1. An alkali free fluorophosphate based glass system , comprising of:a glass base composition, having:{'sub': 3', '2, 'barium metaphosphate Ba(PO), in mol percent;'}{'sub': 3', '3, 'aluminum metaphosphate Al(PO)in mol percent, and'}one or more fluorides;where the one or more fluorides are selected from a group consisting of:{'sub': '2', 'barium fluoride BaFand RFx in mol percent;'}{'sub': 'x', 'where R is selected from a group consisting of: Mg, Ca, Sr, Pb, Y, Bi, Al, Zn, and combinations thereof, and subscript x is an index representing an amount of fluorine (F) in the compound RF;'}one or more dopant in wt % over 100 wt % of the glass base composition;{'sub': 3', '2', '3, 'where the one or more dopant is selected from a group consisting of: SbF, SbO, or combinations thereof; and'}{'sub': 2', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '2', '4', '2', '3', '3', '2', '3', '3', '2', '3', '3', '2', '4', '2', '3', '3', '2', '3', '3, 'one or more co-dopants in wt % over 100 wt % of the glass base composition selected from a group consisting of: CeO, CeF, ErO, ErF, NdO, NdF, YbO, YbF, PrO, PrF, EuO, EuF, TbO, TbF, ZnO, ZnF, HoO, HoF, SmO, SmF, TmO, TmF, LuO, LuF, GdO, GdF, DyO, DyF, CuO, CuF, TiO, TiF, CrO, CrF, MoO, MoF, WO, WF, MnO, MnF, CoO, CoF, NiO, NiF, and combinations thereof.'}2. An alkali free fluorophosphate based glass system , comprising of:a glass base composition, having:{'sub': 3', '2, 'barium metaphosphate Ba(PO), in mol percent,'}{'sub': 3', '3, 'aluminum ...
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