21-03-2019 дата публикации
Номер: US20190086757A1
Принадлежит:
The disclosure relates generally to electrochromic devices wherein the self-bleaching behavior of an electrochromic polymer (ECP) film is suppressed, and related methods. In some embodiments, provided are ECP films on modified transparent conductive oxide substrates, such as a partially octadecyltrichlorosilane (OTS) covered indium tin oxide (ITO) substrate (POTS-ITO substrate), methods of preparing the ECP films, and electrochromic devices comprising the films. 1. An electrochromic device (ECD) comprising an electrochromic polymer (ECP) film on a modified transparent conductive oxide substrate which is a transparent conductive oxide (TCO) substrate partially or fully covered with a modification material selected from C-Calkyltrichlorosilane , TiO , ZnO , WO , MoO , VO , NiO , NiO , and NiO , HMDS (bis(trimethylsilyl)amine) , APTS ((3-aminopropyl)triethoxysilane) , and trimethoxy(2-phenylethyl)silane , poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) , poly(3 ,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) , or a combination thereof.2. The electrochromic device of claim 1 , wherein the transparent conductive oxide substrate comprises indium tin oxide (ITO) claim 1 , fluorine-doped tin oxide (FTO) claim 1 , aluminium-doped zinc oxide (AZO) claim 1 , or antimony-doped tin oxide (ATO) claim 1 , or a mixture thereof.3. The electrochromic device of claim 1 , wherein the modification material is C-Calkyltrichlorosilane.4. The electrochromic device of claim 1 , wherein the modification material is octadecyltrichlorosilane (OTS).5. The electrochromic device of claim 1 , wherein the modification material is in the form of a thin layer.6. The electrochromic device of claim 5 , wherein the thickness of a thin layer is less than about 100 nm.7. The electrochromic device of claim 1 , wherein the modification material fully covers the transparent conductive oxide substrate.8. The electrochromic device of claim 1 , wherein the modification material ...
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