23-05-2013 дата публикации
Номер: US20130130160A1
Принадлежит:
A light pattern exposure method is by irradiating ArF excimer laser light to a resist film through a photomask. The photomask includes a transparent substrate and a pattern of optical film of a material comprising a transition metal, silicon, nitrogen and oxygen, with contents thereof falling in a specific range. The photomask may be irradiated with ArF excimer laser light in a cumulative dose of at least 10 kJ/cm. 1. A light pattern exposure method comprising irradiating a pattern of light to a resist film through a photomask using ArF excimer laser light as the light source , wherein{'sup': '2', 'the photomask used is such that it has been irradiated with ArF excimer laser light in a cumulative dose of at least 10 kJ/cm,'}said photomask comprising a transparent substrate and a pattern of optical film of a material comprising a transition metal, silicon, and nitrogen and/or oxygen, the transition metal having potentially a valence of 6, [{'br': None, 'sub': M', 'Si, '6×C/100−4×C/100≦−0.89\u2003\u2003(1)'}, {'br': None, 'sub': M', 'N', 'M', 'M', 'M', 'Si', 'M', 'N', 'M', 'O', 'Si', 'Si', 'Si', 'N', 'Si', 'O, '6C×3C/(6C×6C+6C×4C+6C×3C+6C×2C+4C×4C+4C×3C+4C×2C)≧0.094\u2003\u2003(2)'}], 'the contents of transition metal, silicon, nitrogen and oxygen in the optical film meeting both the formulae (1) and (2){'sub': M', 'Si', 'N', 'O, 'wherein Cis a transition metal content in atom %, Cis a silicon content in atom %, Cis a nitrogen content in atom % and Cis an oxygen content in atom %, except for an outermost surface region extending from the film surface remote from the substrate to a depth of 10 nm.'}2. The method of wherein the photomask has been treated for defect correction by directing a high-energy radiation beam in a fluorine base gas atmosphere.3. The method of wherein the transition metal is molybdenum.4. A photomask for use in a light pattern exposure method comprising irradiating a pattern of light to a resist film through the mask using ArF excimer laser light ...
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