11-05-2017 дата публикации
Номер: US20170130329A1
Provided is an oxide sintered body that, when used to obtain an oxide semiconductor thin film by sputtering, can achieve a low carrier concentration and a high carrier mobility. Also provided is a sputtering target using the oxide sintered body. The oxide sintered body contains, as oxides, indium, gallium, and at least one positive divalent element selected from the group consisting of nickel, cobalt, calcium, strontium, and lead. The gallium content, in terms of the atomic ratio Ga/(In+Ga), is from 0.20 to 0.45, and the positive divalent element content, in terms of the atomic ratio M/(In+Ga+M), is from 0.0001 to 0.05. The amorphous oxide semiconductor thin film, which is formed using the oxide sintered body as a sputtering target, can achieve a carrier concentration of less than 3.0×10cmand a carrier mobility of at least 10 cmVsec. 1. An oxide sintered body comprising indium , gallium , and a positive divalent element as oxides , whereina gallium content is 0.20 or more and 0.45 or less in terms of Ga/(In+Ga) atomic ratio,the total content of all the positive divalent elements is 0.0001 or more and 0.05 or less in terms of M/(In+Ga+M) atomic ratio,the positive divalent element is one or more selected from the group consisting of nickel, cobalt, calcium, strontium, and lead,the oxide sintered body includes;{'sub': 2', '3, 'an InOphase having a bixbyite-type structure;'}{'sub': 3', '2', '3', '2', '3', '3', '2', '3', '2', '3', '2', '3, 'and a GaInOphase having a β-GaO-type structure as a formed phase other than the InOphase, or a GaInOphase having a β-GaO-type structure and a (Ga, In)Ophase as a formed phase other than the InOphase;'}{'sub': 2', '4', '2', '4', '4', '7', '5', '6', '14', '12', '19', '2', '4', '3', '2', '6', '2', '4, 'and the oxide sintered body is substantially free of a NiGaOphase, a CoGaOphase, a CaGaOphase, a CaGaOphase, a SrGaOphase, a SrGaOphase, a SrGaOphase, and a GaPbOphase, which are a complex oxide composed of the positive divalent element ...
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