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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 26. Отображено 26.
27-08-2020 дата публикации

ALKYLATION REACTION APPARATUS AND REACTION SYSTEM, AND LIQUID ACID-CATALYZED ALKYLATION REACTION METHOD

Номер: WO2020169079A1
Принадлежит:

Provided is an alkylation reaction apparatus, characterized by comprising n reactors, wherein in the n reactors, there are m reactors, each of which is provided with three reaction zones as defined below, including a first reactor; in the order of alkylation reaction material flow directions, the three reaction zones are respectively an x reaction zone, a y reaction zone and a z reaction zone; and based on mixing intensities, a mixing intensityy reaction zone > a mixing intensityx reaction zone > a mixing intensityz reaction zone, where n ≥ 1 and n ≥ m. Further provided are an alkylation reaction system comprising the alkylation reaction apparatus and a liquid acid-catalyzed alkylation reaction method using the alkylation reaction apparatus or the alkylation reaction system.

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16-06-2023 дата публикации

Preparation method of furfural

Номер: CN116262732A
Принадлежит:

The invention discloses a method for preparing furfural, which comprises the following step of: catalyzing an intramolecular dehydration reaction of xylose-based carbohydrate in a double-liquid-phase reaction medium consisting of a low-boiling-point organic solvent-eutectic solvent by using a chlorine-containing sulfonic acid carbon-based solid acid catalyst. The used solid acid catalyst is high in surface sulfonic acid density and strong in acidity, and the used reaction medium can increase the solubility of xylose-based carbohydrate and the solvation effect on xylose. Through optimization of the catalyst and the reaction medium, the dehydration rate of xylose is effectively improved, the reaction time is shortened, and furfural is prevented from being decomposed due to long-time retention under a high-temperature acidic condition, so that the selectivity of furfural is improved.

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05-05-2023 дата публикации

Polyalkyl anthraquinone working solution and application thereof

Номер: CN116062702A
Принадлежит:

The invention relates to a multi-alkyl anthraquinone working solution, which comprises a solvent and a working carrier, and is characterized in that the working carrier is 2, 6-disubstituted alkyl anthraquinone, and the solvent is tetrabutyl urea and does not contain heavy aromatics. The working fluid has the advantages of being simple in composition, easy to blend, free of toxic and harmful heavy aromatics and capable of eliminating gas-phase burning explosion danger, the working fluid is used for replacing the working fluid in the prior art, a catalyst does not need to be replaced, a hydrogenation unit does not need to be modified and upgraded, the hydrogen efficiency can exceed 20 g/L, and the industrial application prospect is achieved.

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28-01-2016 дата публикации

METHOD OF COMBINING MICROALGAE CULTIVATION AND INDUSTRIAL WASTE GAS DENITRIFICATION AND SYSTEM USING SAME

Номер: WO2016011785A1
Принадлежит:

Provided are a method of combining microalgae cultivation and industrial waste gas denitrification and a system using same. The method comprises the following steps: (1) cultivating microalgae; (2) separating the solution of microalgae obtained in step (1) into a wet microalgae (microalgae gel) and a cultivation liquid residue; (3) using the cultivation liquid residue obtained in step (2) to absorb and immobilize NOx to denitrify industrial waste gas, nutrients obtained from step (3) for immobilizing NOx providing a nitrogen source for the microalgae cultivation in step (1). During the process of microalgae cultivation, effective micro-organisms (EM) are added to the solution of microalgae, the microalgae being preferably chlorella, scenedesmus, monoraphidium, or spirulina. The system comprises, optionally from upstream to downstream, an NOx immobilizing unit, a microalgae cultivator, a separator, and a recycling line for recycling the cultivation liquid residue from the separator back ...

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01-08-2023 дата публикации

Method for preparing furfural by using heteropolyacid-based phase transfer catalyst

Номер: CN116514746A
Принадлежит:

The invention discloses a method for preparing furfural, which comprises the following step: carrying out intramolecular dehydration reaction on xylose-based carbohydrate in a ternary two-phase reaction medium consisting of a low-boiling-point organic solvent, a protic solvent and an ionic organic ammonium chloride under the action of a heteropoly acid-based phase transfer catalyst. The catalyst used in the invention has the property of phase transfer, i.e., the solubility of the catalyst in a reaction medium at a high temperature is increased, and xylose dehydration is catalyzed in a liquid acid form; after the reaction is finished, the solubility is reduced and the catalyst is separated out in a solid form, so that the catalyst is convenient to recycle and separate, and the problems of low efficiency of a solid acid catalyst and difficult separation of a liquid acid catalyst are solved to a great extent. And an advanced reaction medium is coupled to increase the solubility of the xylosyl ...

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05-05-2023 дата публикации

Single-solvent working solution system and production method of hydrogen peroxide by anthraquinone process

Номер: CN116062701A
Принадлежит:

The invention relates to a single-solvent working solution system, which is used for producing hydrogen peroxide by an anthraquinone process, and is characterized in that the working solution system consists of a solvent and a working carrier, and the solvent is tetrabutyl urea and does not contain heavy aromatics; the working carrier is prepared from one or more of anthraquinone of 2-tert-amyl anthraquinone, tetrahydro-2-tert-amyl anthraquinone, 2-sec-amyl anthraquinone and tetrahydro-2-sec-amyl anthraquinone, and the working carrier is prepared from one or more of anthraquinone of 2-tert-amyl anthraquinone, tetrahydro-2-tert-amyl anthraquinone, 2-sec-amyl ...

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28-04-2023 дата публикации

Hydrogenation method for terephthalic acid

Номер: CN116023252A
Принадлежит:

The invention discloses a terephthalic acid hydrogenation method which is characterized in that terephthalic acid reacts with hydrogen in the presence of a catalyst, the catalyst is an active metal additive and an active metal palladium-loaded molecular sieve catalyst, and the active metal additive is selected from one or more of Ru, Rh, Os, Ir, Pt, Ag and Au; the catalyst is prepared by the following steps: (1) carrying out hydro-thermal treatment on a molecular sieve at 450-600 DEG C for 3-6 hours; and (2) impregnating the molecular sieve subjected to hydro-thermal treatment in an impregnating solution containing a metal additive and palladium, drying, roasting and reducing. According to the invention, the conversion rate and the selectivity of trans-1, 4-cyclohexanedicarboxylic acid are improved by heat treatment of the molecular sieve carrier and addition of the metal additive.

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28-04-2016 дата публикации

METHOD FOR PREPARING LOW-CARBON ALKENE

Номер: WO2016061906A1
Принадлежит:

Disclosed is a method for preparing a low-carbon alkene, the method comprising: continuously contacting an oxygen-containing compound raw material with catalyst to have a dehydration reaction so as to prepare low-carbon alkene, the reaction pressure P of the dehydration reaction being 1-2 MPa, and the weight hourly space velocity H of the dehydration reaction being 15-50 h-1. The preparation method of low-carbon alkene has a simple and continuous operation process, reduces investment, greatly increases production of low-carbon alkene and has a high safety.

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27-06-2023 дата публикации

Method for preparing 5-hydroxymethylfurfural by using temperature-sensitive heteropolyacid-based catalyst

Номер: CN116332884A
Принадлежит:

The invention discloses a method for preparing 5-hydroxymethylfurfural, which comprises the following step: under the catalytic action of a temperature-sensitive heteropolyacid-based catalyst, carrying out intramolecular dehydration reaction on fructosyl carbohydrate in a double-liquid-phase reaction medium consisting of a low-boiling-point organic solvent and a deep-eutectic solvent at 80-200 DEG C to obtain the 5-hydroxymethylfurfural. The solubility of the heteropolyacid catalyst is increased when the temperature of the heteropolyacid catalyst is increased in a reaction medium, fructose dehydration is catalyzed in a liquid acid form, and the fructose dehydration efficiency and the target product yield are greatly improved; after the reaction is finished, the solubility is reduced and the catalyst is separated out in a solid form, thereby facilitating separation and recycling of the catalyst and the product. The method meets the requirements of green chemistry, and creates good conditions ...

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27-03-2014 дата публикации

METHOD AND DEVICE FOR COPRODUCING CYCLOHEXANOL AND ALKANOL

Номер: WO2014044020A1
Принадлежит:

A method for coproducing cyclohexanol and alkanol comprises steps of cyclohexene esterification and cyclohexyl ester hydrogenation. Also disclosed are a method for further producing cyclohexanone or caprolactam, starting with the coproduction method, and a device for coproducing cyclohexanol and alkanol.

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24-06-2010 дата публикации

PREPARING PROCESS OF METHANOL, DIMETHYL ETHER AND LOWER OLEFIN FROM SYNTHESIS GAS

Номер: WO2010069133A1
Принадлежит:

Disclosed is a preparing process of methanol, dimethyl ether and lower olefin from synthesis gas, which comprises contacting synthesis gas with catalyst under the conditions of the conversion of synthesis gas to methanol, dimethyl ether and lower olefin. The catalyst contains amorphous alloys consisting of M component and X component, wherein the X component is B and/ or P, and the M component is two or more selected from subgroups of IIIA, IVA, VA, IB, IIB, IVB, VB, VIB, VIIB, VIII and lanthanum-series metal element of periodic table of chemical elements. The present method has very high conversion of carbon monoxide, high selectivity of objective product and high utilization ratio of carbon.

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28-04-2016 дата публикации

LOW-CARBON OLEFIN PRODUCTION METHOD

Номер: WO2016061905A1
Принадлежит:

Disclosed is a low-carbon olefin production method. In the method for producing low-carbon olefin by continuously bringing an alkane raw material and a catalyst into contact to subject to a dehydrogenation reaction, the reaction pressure P of the dehydrogenation reaction is made 0.6-2 MPa and the volume space velocity H of the dehydrogenation reaction is made 500-1000 h-1. The low-carbon olefin production method of the present invention is simple and continuous in operation and has the characteristics of low investment, big increase in yield of low-carbon olefin and high safety.

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03-06-2010 дата публикации

METHOD FOR PRODUCING METHANOL, DIMETHYL ETHER AND LIGHT OLEFINS FROM SYNTHESIS GAS

Номер: WO2010060279A1
Принадлежит:

A method for producing methanol, dimethyl ether and light olefins from synthesis gas is provided. In the process of the preparation, synthesis gas is in contact with a catalyst. The catalyst contains amorphous alloy which is composed of the first component Al and the second component. The second component is one or more elements selected from ⅠA, ⅢA, ⅣA, ⅤA, ⅠB, ⅡB, ⅣB, ⅤB, ⅥB, ⅦB, Ⅷ and lanthanide and their oxides, moreover, the second component is not Al. The characteristics of the preparation method are that the conversion ratio of CO is high, selectivity of objective product is high and the utilization ratio of carbon is high.

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25-04-2023 дата публикации

Sulfuric acid alkylation device system and method for reducing alkali liquor consumption

Номер: CN116004281A
Принадлежит:

The invention relates to a sulfuric acid alkylation device system and method for reducing alkali liquor consumption, which is characterized in that an acid gas buffer tank is arranged in front of a waste acid cracking furnace on the basis of the traditional sulfuric acid alkylation process; collecting a small amount of SO2-containing acidic gas at the top of the refrigerant tank, a small amount of SO2-containing gas-phase isobutane at the top of the reflux tank, a small amount of acid-containing light hydrocarbon volatilized at the top of the waste acid storage tank and gas-phase light hydrocarbon removed at the top of the light hydrocarbon removal tower; the waste acid degassing tank is connected with the compressor system, and gas-phase light hydrocarbon volatilized by the waste acid degassing tank is recycled at a first-section inlet of the compressor system. The method not only treats acid-containing gas, but also saves natural gas required for cracking waste acid, does not adopt an ...

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21-04-2022 дата публикации

METHOD AND SYSTEM FOR PREPARING HYDROGEN PEROXIDE

Номер: WO2022078427A1
Принадлежит:

Disclosed are a method and system for preparing hydrogen peroxide. The method comprises: 1) performing a hydrogenation reaction on a working solution containing alkyl anthraquinone in the presence of hydrogenation catalyst particles and hydrogen, separating to obtain circulating slurry and a hydrogenated liquid, and recycling the circulating slurry; 2) dividing the hydrogenated liquid into two portions, and regenerating the first portion of the hydrogenated liquid to obtain a regenerated hydrogenated liquid; 3) bringing the second portion of the hydrogenated liquid and the regenerated hydrogenated liquid to contact an oxygen-containing gas to perform an oxidation reaction to obtain an oxidant solution; and 4) extracting and separating the oxidant solution to obtain extract liquor and raffinate containing the hydrogen peroxide, and recycling the raffinate. The method can substantially eliminate the bed temperature difference of a reactor, effectively improve the hydrogenation reaction selectivity ...

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05-05-2023 дата публикации

Olefin hydroformylation reaction method

Номер: CN116063168A
Принадлежит:

The present invention relates to the technical field of olefin hydroformylation, and discloses an olefin hydroformylation reaction method, which comprises that in the presence of a cobalt-phosphine catalyst, C8-C30 olefin and synthesis gas are introduced into a reactor to carry out a contact reaction. By adopting the method, the stability of the catalyst can be enhanced, the loss of the cobalt-phosphine catalyst is reduced, the deposition of the catalyst in a reaction device is reduced, the continuous operation time of the device is prolonged, the loss of the catalyst in a product separation process is reduced, and the processing cost is reduced.

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28-01-2016 дата публикации

METHOD FOR CULTURING MICROALGAE AND METHOD OF COMBINATION OF SAME WITH DENITRATION

Номер: WO2016011784A1
Принадлежит:

Provided are a method for culturing microalgae and a method of the combination of same with denitration. During the process of culturing microalgae, EM bacteria are added into a microalgae suspension. The microalgae are preferably chlorella, scenedesmus, monoraphidium and spirulina. In the nutrient flow for culturing microalgae, at least one of a nitrogen source, phosphorus source and carbon source are provided in the form of an alkali metal nutrient salt. During the culture process, nitric acid and/or nitrous acid are used for adjusting the pH of the microalgae suspension. The combined method comprises the step of: (1) a culture step for culturing microalgae; (2) a separation step for separating the microalgae suspension obtained from step (1) into wet microalgae (algae mud) and culture raffinate; (3) a NOx absorption and fixation step, with the culture raffinate obtained from step (2) being used for completing the denitration of industrial waste gas; wherein the nutrient flow absorbing ...

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25-04-2023 дата публикации

Working solution for producing hydrogen peroxide by anthraquinone method and production method of hydrogen peroxide

Номер: CN116002627A
Принадлежит:

A working solution for producing hydrogen peroxide by an anthraquinone process comprises a solvent and a working solution carrier, and is characterized in that the solvent is diisobutyl carbinol and does not contain heavy aromatics, and the working solution carrier is a mixture of one or more alkyl anthraquinones of 2-tert-amyl anthraquinone, tetrahydro-2-tert-amyl anthraquinone, 2-sec-amyl anthraquinone and tetrahydro-2-sec-amyl anthraquinone. The working fluid does not contain toxic and harmful heavy aromatics, the gas-phase burning explosion danger can be eliminated, a working fluid system in the prior art is replaced with the working fluid system, a catalyst does not need to be replaced, device transformation and upgrading do not need to be carried out, and the hydrogen efficiency can reach 16 g/L.

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28-04-2023 дата публикации

Method and system for separating anthracene alkylation reaction product

Номер: CN116023218A
Принадлежит:

The invention relates to the technical field of alkyl anthracene production, in particular to a method and system for separating an anthracene alkylation reaction product, and the method comprises the following steps: (1) introducing a feed liquid containing the anthracene alkylation reaction product into a first distillation tower for reduced pressure distillation I; (2) introducing the first tower bottom product into an alkyl anthracene tank for gas-liquid separation to obtain a first gas phase and a first liquid phase; introducing the first liquid phase into a second distillation tower for reduced pressure distillation II; and (3) introducing the second tower top product into a condenser for condensation treatment to respectively obtain a second gas phase and a second liquid phase, refluxing a part of the second liquid phase into the second distillation tower, and introducing the rest of the second liquid phase into the monoalkyl anthracene tank for gas-liquid separation to obtain a ...

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05-05-2023 дата публикации

Hydrogen peroxide production method and alkylanthraquinone working solution

Номер: CN116062700A
Принадлежит:

The invention discloses a hydrogen peroxide production method, which comprises the steps of hydrogenation, oxidation and extraction of an alkyl anthraquinone working solution, and is characterized in that the alkyl anthraquinone working solution comprises 2, 6-disubstituted alkyl anthraquinone as a working carrier and diisobutyl carbinol as a solvent, and the solvent does not contain heavy aromatics. The working solution adopted by the method is simple in formula composition and easy to blend, the chemical property of 2, 6-disubstituted alkyl anthraquinone is stable, the working load is large, the anthraquinone degradation rate is low, the solvent does not contain heavy aromatics, the gas-phase burning explosion danger can be eliminated, and diisobutyl carbinol has high solubility on anthraquinone and anthrahydroquinone.

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17-03-2004 дата публикации

一种ZSM-5沸石与多孔金属复合材料及其制备方法

Номер: CN0001142026C
Принадлежит:

... 一种ZSM-5沸石与多孔金属复合材料含有多孔金属载体和直接晶化在该载体上的ZSM-5沸石,所述多孔金属载体至少含有一种多孔镍-铝、铁-铝或铜-铝合金,以多孔镍-铝、铁-铝或铜-铝合金为基准,多孔金属载体的孔体积为0.02~0.5毫升/克。该复合材料中沸石与多孔金属载体的结合更加牢固,沸石具有更高的热、水热稳定性,用该复合材料制备出的含铜催化剂具有独特的催化性能。 ...

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05-05-2023 дата публикации

Method for preparing alcohol through olefin hydroformylation reaction

Номер: CN116063155A
Принадлежит:

The invention relates to the field of hydroformylation reaction, and discloses a method for preparing alcohol through olefin hydroformylation reaction, and the method comprises the following steps: (1) in the presence of a cobalt-phosphine complex catalyst, introducing C8-C30 olefin and synthesis gas into a first reactor, and carrying out first contact reaction to obtain a first mixture; (2) introducing synthesis gas and the first mixture into a second reactor for second contact reaction to obtain a second mixture; the volume of the second reactor is smaller than that of the first reactor; (3) separating the second mixture to respectively obtain a light component and a heavy component; and (4) circulating the heavy components. The method is simple in process flow, high in olefin conversion rate, high in target product yield and low in alkane selectivity, can greatly reduce waste liquid discharge, and has a good industrial application prospect.

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08-08-2023 дата публикации

Method for preparing 1, 4-cyclohexanedimethanol through hydrogenation

Номер: CN116553999A
Принадлежит:

The invention relates to a method for preparing 1, 4-cyclohexanedimethanol through hydrogenation, which is characterized in that under the condition of ester hydrogenation reaction, dimethyl 1, 4-cyclohexanedicarboxylate is contacted with hydrogen in the presence of a catalyst, and the catalyst is a copper-magnesium-aluminum composite oxide or a lanthanum and/or cerium-loaded copper-magnesium-aluminum composite oxide. The method provided by the invention can improve the conversion rate and selectivity of 1, 4-cyclohexanedicarboxylic acid dimethyl ester hydrogenation.

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04-04-2023 дата публикации

Method for preparing delta-cyclovalerolactone

Номер: CN115894420A
Принадлежит:

The invention discloses a method for preparing delta-cyclovalerolactone, which comprises the following steps: in the presence of a hydrogenation catalyst, reacting furoic acid or a furoate derivative with hydrogen and alcohol to obtain a solution of an intermediate product, heating and distilling the solution of the intermediate product, removing the alcohol, and carrying out molecular lactone exchange reaction on the intermediate product to obtain the delta-cyclovalerolactone, wherein the hydrogenation catalyst is a supported metal catalyst. The method disclosed by the invention is green and environment-friendly, low in reaction temperature, low in energy consumption and high in yield of delta-cyclovalerolactone.

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05-05-2023 дата публикации

Method for continuously producing 5-hydroxymethylfurfural and 2, 5-furandicarboxylic acid

Номер: CN116063258A
Принадлежит:

The invention relates to a method for continuously producing 5-hydroxymethylfurfural and 2, 5-furandicarboxylic acid. According to the method, starting from the fructose-based carbohydrate, the important biomass-based platform compound 5-hydroxymethylfurfural and the functional high polymer material monomer 2, 5-furandicarboxylic acid are continuously produced, the separation and purification process of the 5-hydroxymethylfurfural is avoided in the production process of the 2, 5-furandicarboxylic acid, and the method has the advantages of being simple in process, low in generation and emission of three wastes, high in yield and the like. And the method is environment-friendly.

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08-12-2004 дата публикации

一种汽油吸附脱硫方法

Номер: CN0001179020C
Принадлежит:

... 一种含有机硫化物杂质的汽油吸附脱硫方法,是将汽油在流化床或淤浆床反应器中与一种以镍为主要活性组分的非晶态合金吸附剂进行接触,接触的条件为室温~120℃、常压~1.0兆帕。该方法不但工艺简单,吸附剂可再生使用,而且脱硫率可达60重量%以上。 ...

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