25-07-2023 дата публикации
Номер: CN116474823A
Принадлежит:
The invention discloses an application of 2, 6-dibromo-anthraquinone, and particularly relates to an application of 2, 6-dibromo-anthraquinone as a photocatalyst in preparation of 2, 5-furandicarboxaldehyde through photocatalytic oxidation of 5-hydroxymethylfurfural. Under the reaction condition of normal pressure and 50 DEG C, air is used as an oxygen source, dimethyl sulfoxide is used as a solvent, and visible light drives a photocatalyst 2, 6-dibromo anthraquinone to perform homogeneous photocatalytic oxidation on 5-hydroxymethylfurfural to selectively prepare 2, 5-furandicarboxaldehyde. According to the method, 2, 5-furandicarboxaldehyde is prepared through a green, energy-saving and environment-friendly photocatalytic means, heterogeneous separation of the photocatalyst and the product can be achieved through simple treatment, energy consumption can be effectively reduced, the production cost can be effectively reduced, meanwhile, the catalytic effect is good, few by-products are generated ...
Подробнее