06-07-2016 дата публикации
Номер: KR1020160079315A
Принадлежит:
The present invention relates to a benzooxaphosphinine oxide derivative having a novel structure and a method for preparing the same. More particularly, the benzooxaphosphinine oxide derivative according to the present invention includes a phosphaisocoumarin derivative and a phosphaisochromanone derivative. The benzooxaphosphinine oxide derivative according to the present invention has pharmacological and physiological activities, and thus can be used as an important intermediate for the synthesis of agricultural chemicals, such as herbicides, and various pharmaceuticals. In addition, the method for preparing a benzooxaphosphinine oxide derivative according to the present invention can provide various benzooxaphosphinine oxide derivatives efficiently through intermolecular C-H olefination/cyclization of each aryl phosphonic acid derivative or arylmethyl phosphonic acid derivative with a vinyl derivative in the presence of a palladium (Pd) catalyst and a silver (Ag) oxidant. COPYRIGHT KIPO ...
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