03-11-2016 дата публикации
Номер: US20160318013A1
Принадлежит:
A process for preparing an acrylamide-based crosslinking monomer including reacting in the presence of a catalyst an isocyanate compound containing at least two isocyanate groups with one of acrylic acid and methacrylic acid. 2. The crosslinked ion exchange membrane of claim 1 , wherein the ion exchange membrane is a cation exchange membrane.3. The crosslinked ion exchange membrane of claim 2 , wherein the ionic monomer is selected from the group consisting of sodium 4-vinylbenzenesulfonate claim 2 , 3-sulfopropyl acrylate potassium salt claim 2 , 2-acrylamido-2-methyl-1-propanesulfonic acid claim 2 , and 2-acrylamido-2-methyl-1-propanesulfonic acid salts.4. The crosslinked ion exchange membrane of claim 1 , wherein the ion exchange membrane is an anion exchange membrane.5. The crosslinked ion exchange membrane of claim 4 , wherein the ionic monomer is selected from the group consisting of 3-acrylamidopropyl trimethylammonium chloride claim 4 , 2-acryloyloxyethyl trimethylammonium chloride claim 4 , 2-methacryloyloxyethyl trimethylammonium chloride claim 4 , 3-methacryloylaminopropyl trimethylammonium chloride claim 4 , and vinylbenzyl trimethylammonium chloride.6. The crosslinked ion exchange membrane of claim 1 , wherein the acrylamide-based crosslinking monomer is produced by a process comprising:preparing a first solution comprising: (i) one of acrylic acid and methacrylic acid; (ii) a solvent selected from the group consisting of chloroform, dichloromethane, dimethylacetamide, ethylene glycol dimethyl ether, N-methylpyrrolidone, and tetrahydrofuran; and (iii) a catalyst selected from the group consisting of organometallic compounds, metal salts, tertiary amines, and combinations thereof;preparing a second solution by adding into and mixing with the first solution an isocyanate compound having at least two isocyanate groups, the isocyanate compound selected from the group consisting of aliphatic isocyanates, cycloaliphatic isocyanates, oligomer isocyanates, and ...
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