16-02-2017 дата публикации
Номер: US20170044304A1
Принадлежит:
A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on. 1under protection of nitrogen or argon, successively adding 1 mole of substance A, 0.5-10 moles of solvent, 0.9-1.1 moles of substance B, and 0.005-0.05 moles of photosensitive free radical initiator into a reactor; irradiating with an ultraviolet light for 0.5-4.0 hours; and, after precipitating, separating, and drying, obtaining the polymer containing the multiple epoxy groups; wherein:the substance A is obtained through mixing at least one member selected from a group consisting of 1,3-propanedithiol, 1,4-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,8-octanedithiol, 3,6-dioxa-1,8-octanedithiol, bis(2-mercaptoethyl) ether, butylene glycol b is (3-mercaptopropionate), 2,3-dimercapto-1-propanol and 1,4-dithiothreitol in any proportion;the substance B is alkynyl glycidyl ether or a mixture of the alkynyl glycidyl ether and a substance C; and, the substance C is obtained through mixing at least one member selected from a group consisting of 1-octyne, 1-hexyne, undecyne, ...
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